P
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u
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o
n
l
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U
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W
I
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L
Y
!
!
!
Elements that exist as gases at 25
0
C and 1 atmosphere
5.1
P
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u
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!
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5.1
P
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a
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u
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o
n
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.
U
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W
I
S
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L
Y
!
!
!
Compressibilit of Gases
.ole1s 2aw
P collision rate with wall
Collision rate number densit
'umber densit 1(V
P 1(V
Charles1 2aw
P collision rate with wall
Collision rate average Ginetic energ of gas molecules
0verage Ginetic energ T
P T
5.)
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L
Y
!
!
!
8inetic theor of gases and I
0vogadro1s 2aw
P collision rate with wall
Collision rate number densit
'umber densit n
P n
P
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u
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o
n
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y
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U
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I
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L
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!
!
!
)hemistry in A$tion* Super )old Atoms
Gaseous Eb 0toms
1.) x 10
;)
8
.ose;Einstein Condensate
P
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L
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!
!
!
Gas diffusion is the gradual mixing of molecules of one gas
with molecules of another b virtue of their Ginetic properties.
5.)
'+
-
1) g(mol
+Cl
-* g(mol
'+
4
Cl
r
1
r
2
M
2
M
1
&
P
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L
Y
!
!
!
Gas effusion is the is the process b which gas under
pressure escapes from one compartment of a container to
another b passing through a small opening.
5.)
r
1
r
2
t
2
t
1
M
2
M
1
& &
'icGel forms a gaseous compound of the formula
'i$C>%
x
5hat is the value of x given that under the same
conditions methane $C+
4
% effuses -.- times faster than
the compound6
r
1
& -.- x r
2
M
1
& 1* g(mol
M
2
&
r
1
r
2
$ %
2
x M
1
& $-.-%
2
x 1* & 1)4.2
5=.) 9 x 2= & 1)4.2 x & 4.1 J 4
P
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!
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Ceviations from ?deal .ehavior
1 mole of ideal gas
PV & nRT
n =
PV
RT
& 1.0
5.=
Eepulsive /orces
0ttractive /orces
P
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Effect of intermolecular forces on the pressure exerted b a gas.
5.=
P
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Y
!
!
!
5.=
Van der Waals equation
nonideal gas
P 9 $V K nb% & nRT
an
2
V
2
$ %
L
corrected
pressure
L
corrected
volume
P
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U
s
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L
Y
!
!
!