THPT Kim Thnh - Gio vin: ng Xun Cng

ANEHIT XETON AXIT CACBOXYLIC Cu 1. Cc cu ghi di y, cu no ng: A. Anehit l cht kh yu hn xeton. B. Anehit no khng tham gia phn ng cng. C. Anehit no l hp cht c nhm CHO lien kt vi H hoc gc hirocacbon no. D. Cng thc phn t ca anehit no l CnH2nO. Cu 2. Cu 3. Oxi ho 4,6 gam hn hp ng mol ca 2 ancol no n chc thnh anehit th dung ht 7,95 gam CuO. Cho ton b lng anehit thu c tham gia phn ng trng gng c 32,4 gam Ag. Cc phn ng u hon ton. Hai ancol l: A. CH3OH v C2H5OH C. C2H5OH v C3H7OH B. CH3OH v C3H7OH D. CH3OH v C4H9OH Cu 4. Cho CaC2 phn ng vi H2O ri dn kh sinh ra vo dung dch gm HgSO4, H2SO4, H2O 800C th thu c hn hp X gm 2 cht kh. xc nh hiu sut phn ng ngi ta cho 2,02 gam X phn ng vi dung dch AgNO3 trong NH3 d, thu c 11,04 gam hn hp rn B. Hiu sut phn ng cng nc vo axetilen l: A. 60% B. 75% C. 80% D. 90% Cu 5. Chn cu ng: A. Anehit axetic c sn xut ch yu t axetilen. B. Axeton c sn xut ch yu t oxi ho ru izo propylic. C. Fomanehit thng c bn di dng kh ho lng. D. Ngi ta lau sch sn mu trn mng tay bng axeton. Cu 6. Chn cu sai: A. Axit cacbonic c nhm cacboxyl C. Axit lactic l axit -hiroxi propionic B. Axit cacbonic l axit cacboxylic D. Gim n c cha axit axetic. Cu 7. Chn cu sai: A. Gim n lm qu tm B. Nc p t qu chanh khng lm tan c CaCO3. C. Dng gim ty c sch cn bm trong phc nc nng. D. Phn ng ca CH3COOH v C2H5OH l phn ng este ho. Cu 8. Cht Y c cng thc phn t l C4H8O2 tc dng vi NaOH to thnh hp cht c cng thc l C4H7O2Na. Y thuc hp cht no sau y: A. Anehit B. Axit cacboxylic C. Ancol D. Xeton Cu 9. Chn cu sai: A. Anehit va c tnh kh va c tnh oxi ho. B. Anehit l hp cht lng tnh. C. Trong cng nghip, xeton c iu ch t cumen. D. Hiro h anehit to ra ancol bc 1. Cu 10. Cho 1 gam axit axetic vo ng nghim (1). Cho 1 gam axit fomic vo ng nghim (2). Cho vo c 2 ng nghim cng mt lng d bt CaCO3 n khi phn ng xy ra hon ton th th tch kh CO2 thu c (cng iu kin): A. 2 ng nghim bng nhau C. T ng nghim (2) nhiu hn ng (1) B. T ng nghim (1) nhiu hn ng (2) D. Khng so snh c. Cu 11. Hp cht X c cng thc phn t l C3H6O tc dng c vi AgNO3 trong dung dch NH3 d. X l: A. (CH3)2CO B. CH3COCH2CH3 C. CH2=CHCHO D. CH3CH2CHO Cu 12. Cho 14,5 gam hn hp gm axit acrylic v axit propionic phn ng va vi 10,6 gam Na2CO3. Khi lng ca axit acrylic trong hn hp l: A. 5,4 gam B. 3,7 gam C. 10,8 gam D. 21,6 gam Cu 13. Tnh in li ca axit fomic 0,46% (d=1g/ml) v c pH=3. A. 0,5% B. 1% C. 1,5% D. 2% Cu 14. Hai cht hu c X, Y n chc c cng thc n gin CH2O v MX < MY. X, Y l:

THPT Kim Thnh - Gio vin: ng Xun Cng

A. CH2O, C2H4O2 B. CH2O, C3H6O3 C. C2H4O2, C3H6O3 D. CH2O, C6H12O6 Cu 15. Cho dy bin ho: Axit axetic X Y ru metylic. X, Y ln lt l: A. CH3COONa, CH4 C. Cl2CH-COOH, NaOOC-CHO B. CH2Cl-COOH, CH2(OH)-COONa D. A, B u ng Cu 16. Anehit no sau y khng c C trong phn twr: A. anehit fomic B. anehit metcylic C. anehit benzoic D. A, B, C u ng Cu 17. Trong mt bnh kn cha hi cht X dng CnH2nO2 mch h v O2 (s mol O2 gp i s mol cn cho phn ng) 139,90C, 0,8 atm. t chy hon ton X sau a v nhit ban u, p sut trong bnh lc ny l 0,95 atm. X c cng thc phn t l: A. C2H4O2 B. CH2O2 C. C4H8O2 D. C3H6O2 Cu 18. Cho tt c cc ng phn n chc mch h c cng cng thc phn t l C2H4O2 ln lt tc dng vi Na, NaOH, NaHCO3. S phn ng xy ra l: A. 2 B. 5 C. 4 D. 3 Cu 19. t chy hon ton 0,1 mol axit cacboxylic cn va V lit O2 (kc) thu c 0,3 mol CO2 v o,2 mol O2. Tnh gi tr ca V: A. 8,96 lit B. 11,2 lit C. 6,72 lit D. 4,48 lit Cu 20. Cho cc cht: axit propionic (X), axit axetic (Y), ancol etylic (Z), imetyl ete (T). Dy gm cc cht c sp xp theo chiu tng dn nhit si l: A. T, Z, Y, X b. Z, T, Y, X c. T, X, Y, Z D, Y, T, X, Z Cu 21. trung ho 6,72 gam mt axit cacbylic Y (no, n chc) cn dng 200 gam dung dch NaOH 2,24%. Cng thc ca Y l: A. CH3COOH B. HCOOH C. C2H5COOH D. C3H7COOH Cu 22. t chy hon ton a mol mt anehit X mch h to ra b mol CO2 v c mol H2O. Bit b = a + c. Trong phn ng trng gng, 1 phn t X ch cho 2 phn t Ag. X thuc dy ng ng anehit: A. No, n chc C. Khng no, 1 ni i, n chc B. Khng no c 2 ni i, n chc D. No, hai chc Cu 23. Khi oxi ho hon ton 2,2, gam mt anehit n chc thu c 3 gam axit tng ng. Cng thc ca anehit l: A. HCHO B. C2H3CHO C. C2H5CHO D. CH3CHO Cu 24. Oxi ho 4,48 lit etilen (kc) bng kh O2 (xt: PdCl2, CuCl2) thu c cht X n chc. Ton b X tc dng vi HCN (d) thu c 7,1 gam CH3(CN)OH (xianohirin). Hiu sut ca qu trnh to xianohirin t etilen l: A. 70% B. 50% C. 60% D. 80% Cu 25. Cho 6. 6 gam mt anehit X n chc, mch h, phn ng vi lng d AgNO3 trong dung dch NH3 un nng. Lng Ag sinh ra cho phn ng ht vi HNO3 long thy thot ra 2,24 lit kh NO (sn phm kh duy nht, kc). Cng thc thu gn ca X l: A. CH3CHO B. HCHO C. C2H5CHO D. C2H3CHO Cu 26. Cho 0,1 mol anehit X tc dng vi lng dAgNO3 trong dung dch NH3 un nng thu c 43,2 gam Ag.Hiro ho X wocj Y. Bit 0,1 mol Y phn ng vi 4,6 gam Na. Cng thc ca X l: A. HCHO B. CH3CHO C. CHO-CHO D. CH3-CH(OH)-CHO Cu 27. Hn hp n mol X gm 2 axit HCOOH v CH3COOH. Ly 5,3 gam hn hp X tc dng vi 5,75 gam C2H5OH (c H2SO4 c lm xc tc) thu c m gam hn hp este. Hiu sut cc phn ng este ho u bng 80%. Gi tr ca m l: A. 10,12 B. 6,48 C. 8,1 D. 16,2 Cu 28. t chy hon ton a mol mt axit hu c Y thu c 2a mol CO2. Mt khc trung ho a mol Y cn va a mol NaOH. Cng thc ca Y l: A. HOOC-(CH2)2-COOH B. C2H5COOH C. CH3COOH D. HOOC-COOH Cu 29. Dy gm cc cht u tc dng vi AgNO3 trong dung dch NH3 l: A. anehit axetic, but-1-in, etilen C. axit fomic. Vinyl axetilen, propin

THPT Kim Thnh - Gio vin: ng Xun Cng

B. anehit axetic, axetilen, but-2in D. anehit fomic, axetilen, etilen Cu 30. Cho cc cht HCN, H2, dung dch KMnO4, dung dch Br2. S cht phn ng c vi (CH3)2CO (axeton) l: A. 2 B. 4 C. 1 D. 3 Cu 31. Cho s chuyn ho: Glucoz X Y CH3COOH. X, Y ln lt l: A. C2H5OH, CH2=CH2 C. CH3CHO, C2H5OH B. C2H5OH, CH3CHO D. CH3CH(OH)COOH, CH3CHO Cu 32. Cho 5,76 gam axit n chc, mch h X tc dng ht vi CaCO3 thu c 7,28 gam mui ca axit hu c. Cng thc ca X l: A. CH2=CH-COOH B. CH3COOH C. CHC-COOH D. C2H5COOH Cu 33. Cho 2,9 gam mt anehit phn ng hon ton vi lng d AgNO3 trong NH3 c 21,6 gam Ag. Cng thc ca anehit ny l: A. HCHO B. CH2=CH-CHO C. CHO-CHO D. CH3CHO Cu 34. Trong cng nghip, axeton c iu ch t: A. xiclopropan B. propan-1-ol C. propan-2-ol D. cumen Cu 35. Xt phn ng cng CH2=CH-CHO + NaHSO3 (dung dch bo ho, d) thu c sn phm hu c X. X ph hp vi cng thc cu to no sau y: A. CH2=CH-CH-OH OSO2Na SO3Na B. CH3 CH CH OH C. CH2 CH2 CH OH OSO2Na OSO2Na OSO2Na D. CH2 CH CH2OSO2Na OH OSO2Na Cu 36. Cho s : anehit fomic A. CH3CH2OH B. CHCh
Nh hp

X Y anehit axetic. Cng thc cu to ca Y: C. CH2OH-CH2OH D. CH3COOCH=CH2

Cu 37. Cho s : anehit fomic X Z ancol metylic. Cng thc cu to ca Z: A. CH2OH-COONa B. HCHO C. CH4 D. CH3COOCH3 Cu 38. Tronh nhng cht cho di y, nhng cht no c th iu ch axit axetic ch bng mt phn ng: (1) CH2=CH2; (2) CHCh; (3) CH2=CHCl; (4) CH3-CHCl2; (5) CH2OH-CH2OH; (6) C2H5OH A. (2), (6) B. (1), (2), (3), (6) C. (2), (3), (5), (6) D. C 6 cht Cu 39. Cho phn ng: (CH3)2C=CH-CH3 + KMnO4 + H2SO4 (CH3)2CO + CH3COOH + MnSO4 + K2SO4 +H2O H s cn bng ca cc cht trong phn ng theo th t l: A. 6, 5, 9, 6, 5, 3, 3, 9 B. 5, 6, 9, 5, 5, 6, 3, 9 C. 6, 5, 9, 6, 5, 6, 3, 9 D. 5, 6, 9, 5, 6, 3, 6, 9 Cu 40. Cht hu c X mch h c cng thc phn t C4H6O3 tc dng c vi Na v dung dch NaOH, lm mt mu dung dch brom, c th trng hp hoc trng ngng. Trong cc cng thc ghi di dy, cng thc ph hp vi X l: A. CH2OH-COOCH=CH2 C. CH2OH-CH=CH-COOH B. CHO-CH2-CH2-COOH D. D. CHO-CH2COCH2OH Cu 41. Cu 42. Mt axit hu c c cng thc n gin C3H6O=2. Cng thc phn t v tn ca axit l: A. C6H12O4 : axit aipic C. C3H6O2 : axit propylic B. C3H6O2 : axit propionic D. C6H12O6 : axit hexanoic Cu 43. Axit fomic c th tc dng vi tt c cc cht trong nhm cht no sau y: A. dung dch NH3, dung dch NaHCO3, Cu, CH3OH B. dung dch AgNO3/NH3, dung dch NaCl, Fe, CH3OH C. dung dch AgNO3/NH3, dung dch NaOH, Fe, CH3OH D. dung dch Na2CO3, dung dch Na2SO4, Na, CH3OH Cu 45. C bao nhiu phn ng ho hc xy ra khi cho cc cht sau tc dng tng i mt: CH3CHO, CH2=CH-COOH, H2, dung dch NaOH, dung dch NaHCO3

Nh hp

THPT Kim Thnh - Gio vin: ng Xun Cng

A. 5 B. 6 C. 7 D. 8 Cu 46. Cho 60 gam axit axetic tc dng vi 60 gam ancol etylic (xc tc H2SO4 c) thu c 60 gam este. Hiu sut phn ng l: A. 50% B. 52,27% C. 68,18% D. 76,66% Cu 47. X l axit n chc no, trong phn t c 1 lin kt i Cu=C. X tc dng vi dung dch Brom ly d cho sn phm cha 65,04% brom theo khi lng. Cng thc phn t ca X: A. C3H4O2 B. C4H6O2 C. C5H8O2 D. C5H6O2 Cu 48. un nng hn hp axit fomic v axit axetic vi glixerol (c H2SO4 c lm xc tc) thu c bao nhiu loi este ch cha mt loi nhm chc: A. 2 B. 4 C. 6 D. 8 Cu 49. Axit X mch nhnh, c cng thc C4H6O2. X l nguyn liu sn xut:: A. cao su Buna B. t nylon-6,6 C. t Lapxan D. thu tinh Plexiglas Cu 50. Cho nc brom vo hn hp phenol v axit axetic n khi ngng mt mu nc brom th lc thu c 33,1 gam kt ta trng. trung ho nc lc cn dung ht 248 ml dung dch NaOH 10% (D=1,11). % phenol v axit axetic trong hn hp u ln lt l: A. 28,66%, 71,34% B. 71,34%, 28,66% C. 30%, 70% D. Kt qu khc:.. Cu 51. Cho 4 cht: (1) axit axetic; (2) axit fomic; (3) anehit fomic; (4) ancol metylic .. Cu 52. Cho 6 cht: (1) axit oxalic; (2) axit axetic; (3) axit fomic; (4) axit cacbonic; (5) phenol; (6) axit clohiric. mnh ca axit xp theo th t tng dn: A. (10, (20, (3), (4), (5), (6) C. (5), (4), (2), (3), (1), (6) B. (6), (5), (4), (3), (2), (1) D. (1), (3), (5), (2), (4), (6) Cu 53. phn bit 3 cht: axit fomic, fomon v glixerol ngi ta dung th nghim no trong s cc th nghim sau: Th nghim (1): Dng Na sau dung dung dch AgNO3/NH3. Th nghim (2): Dng qu tm v dung dch AgNO3/NH3. Th nghim (3): Dng dung dch Na2CO3, sau dung dung dch AgNO3/NH3. A. (1), (2) B. (1), (3) C. (2), (3) D. (1), (2), (3) Cu 54. Cht no sau u khi tc dng vi dung dch AgNO3/NH3 c kh bay ra: A. HCOONa B. HCOOCH3 C. HCOOH D. HCOOCH=CH2 Cu 55. Ba cht hu c X, Y, Z u cha 3 nguyn t C, H, O, mch h, n chc v u tan trong nc. (MX > MY > Mz). t chy 1 mol mi cht u cho 2 mol nc. X, Y, Z ln lt l: A. HCHO, CH3CHO, C2H5CHO C. HCOOH, CH3COOH, C2H5COOH B. CH3OH, CH3CHO, CH3COOH D. C2H5OH, CH3CHO, CH3COOH Cu 56. Mt anehit n chc c cng thc cu to: CH3 CH - CH2 CH CH CH3 CHO CH3 C2H5 Tn ca anehit trn theo IUPAC l: A. 2 etyl 3 - metyl heptan 2 - al C. 2,4,5 trimetyl heptanal B. 2 etyl - 3.5 imetyl hexanal D. 3,4,6 trimetyl heptanal Cu 57. Gi tn cht hu c sau: CH2=CH-CH2C)-CH(CH3)2 A. vinyl propyl xeton C. Anlyl isopropyl xeton B. Anlyl isopropyl xeton D. 5-metyl hex 2- en 4-on Cu 58. An ehit tham gia phn ng cng H2 v phn ng trng gng, chng t anehit c tnh cht: A. ch c tnh oxi ho C. c c tnh oxi ho v tnh kh B. ch c tnh kh D. khng c tnh oxi ho v tnh kh Cu 59. Cu 60. tch axeton ra khi hn hp axeton v ancol etylic, ta dung cch no sau y: A. Dng dung dch NaHSO3 sau ly tinh th cho tc dng vi HCl B. Dng dung dch AgNO3/NH3 sau dung dung dch HCl C. Dng dung dch AgNO3/NH3 sau dung dung dch NaHSO3 D. Dng c 3 cch A, B, C u c

THPT Kim Thnh - Gio vin: ng Xun Cng

CU HI TRC NGHIM
HA HU C C NHM CHC CHNG : RU Cu 1: iu no sau y ng khi ni v nhm nh chc : A. l hp cht hu c c nhng tnh cht ha hc nht nh. B. l nhm cc nguyn t gy ra nhng phn ng ha hc c trng cho mt loi hp cht hu c C. l nhm nguyn t quyt nh tnh cht ha hc c trng cho mt loi hp cht hu c. D. B v C ng . Cu 2: Hydrat ha 2-metylbut-2-en th thu c sn phm chnh l : A. 3-metyl-butan-1-ol B. 3-metyl-butan-2-ol C. 2-metyl-butan-2-ol. D. 2-metyl-butan-1-ol Cu 3: Phn ng no sau y khng xy ra : A. C2H5OH + HBr B. C2H5OH + NaOH. C. C2H5OH + Na D. C2H5OH + CuO Cu 4: Gi tn ancol sau y: CH 3 C2H5CCH 2CHC 2H5 OH CH3 A. 4-etyl-2,4-dietyl hexan-2-ol B. 5-etyl-3,5-dimetylheptan-3-ol C. 2,4-dietyl-4-metylhexan-2-ol D. 3,5-dimetylheptan-3-ol. Cu 5: Trong cc cht sau y, cht no c ng phn v tr ? 1. CH3OH 2. C2H5OH 3. CH3CH2CH2OH 4. (CH3)2CHOH A. 1,2 B. 2,3 C. 3,4 D. 2,4 Cu 6: Cht no l ancol bc II: 1) metanol 2) etanol 3) propan-2-ol 4) 2-metylpropan-2-ol 5) butan-2-ol A. 1,2,3. B. 2,3,4 C. 3,4,5 D. 3,5 Cu 7: Chn pht biu ng : A. Nhit si ca ancol etylic cao hn ancol metylic v thp hn ancol propylic. B. so snh nhit si ca cc ancol ta phi da vo lin kt hydro. C. Ancol metylic trng thi kh . D. Ancol d tan trong nc. Cu 8: ancol etylic tan trong nc v : A. Phn ng vi nc. B. To c lin kt hidro vi nc. C. in li thnh ion. D. Cho c lin kt hidro vi ancol . Cu 9: Cng thc no sau y l cng thc chung ca ancol no n chc: A. CnH2n + 2Ox ( vi x 2) B. CnH2n + 2O C. CnH2n + 1OH D. CnH2nO Cu 10: Nhit si ca cc cht sau y c xp theo th t : A. C2H5Cl > C2H5OH > CH3-O-CH3. B. CH3-O-CH3 > C2H5OH > C2H5Cl. C. C2H5OH > C2H5Cl > CH3-O-CH3. D. C2H5OH > CH3-O-CH3 > C2H5Cl.

THPT Kim Thnh - Gio vin: ng Xun Cng

Cu 11: Cho bit ng phn no ca C4H9OH khi tch nc s to 2 olefin ng phn : A. Ancol isobutylic. B. Butan-1-ol. C. 2-metylpropan-2-ol D. Butan-2-ol. Cu 12: Cho s bino ha : +CuO/t C4H10O B B khng cho phn ng trng bc, cu to ca C4H10O phi l : A. CH3CHOHCH2CH3. B. CH3CH(CH3)CH2OH. C. CH3CH2CH2CH2OH. D. CH3C(CH3)2OH. Cu 13: Cu(OH)2 tan trong glixerol l do : A. Glixerol c tnh axit . B. Glixerol c H linh ng. C. Glixerol to phc vi ng II hidroxit. D. Glixerol to c lin kt hidro. Cu 14: Cht no sau y c nhit si cao nht : A. CH3OCH3 B. C2H5OH. C. H2O. D. CH3CHO. Cu 15: Cho hn hp Z gm 2 ancol c cng thc phn t CxH2x+2O v CyH2yO. Bit x + y = 6 v x khc y v khc 1. Cng thc phn t 2 ancol l : A. C3H7OH v CH3OH. B. C4H10O v C3H6O. C. C2H6O v C4H8O. D. C4H10O v C2H4O. Cu 16: un nng hn hp 2 ancol no n chc vi H2SO4 c 140oC thu c 21,6 gam H2O v 72 gam hn hp 3 ete. Bit 3 ete thu c c s mol bng nhau v phn ng xy ra hon ton, vy ng thc phn t ca 2 ancol trn l : A. C3H7OH v CH3OH B. CH3OH v C2H5OH C. C2H5OH v C3H7OH D. CH3OH v C4H9OH. Cu 17: Ancol A khi tc dng vi Na cho V H 2 bng vi V hi ancol A dng. Mt khc t chy ht 1 th tch hi ru A thu c cha n 3VCO2 (cc th tch o trong cng iu kin). vy tn gi ca ancol A l: A. ancol etilic. B. Propan-1,2-diol. C. Glixerol . D. Etylenglicol. Cu 18: Trn 0,5mol C2H5OH v 0,7 mol C3H7OH. Sau dn qua H2SO4 c nng. Tt c ancol u b kh nc ( khng c ru d). Lng anken sinh ra lm mt mu 1 mol Br2 trong dung dch . Cc phn ng xy ra hon ton. Vy s mol H2O to thnh trong s kh nc trn l: A. 1mol B. 1,1mol C. 1,2mol D. 0,6mol Cu 19: Mt hp cht hu c A c cha 10,34% hidro. Khi t chy A th ch thu c CO2 v H2O. Bit rng VCO2 = V H 2O (hi) v s mol O2 cn dng gp 4 ln s mol A. Vy cng thc phn t ca A l : A. C3H6O B. C4H8O. C. C2H6O D. C4H10O Cu 20: Khi un nng m1 gam ancol X vi H2SO4 c lm xc tc nhit thch hp thu c m2 gam hp cht Y. T khi hi ca Y so vi X l 0,7 ( hiu sut phn ng l 100%). Cng thc phn t ca X l: A. C2H5OH. B. C3H7OH. C. C4H9OH. D. CH3OH. Cu 21: Khi t chy hon ton 1 mol ancol a chc cn 3,5 mol O2 th cng thc phn t ca ru y l: A. CH2OH-CH2OH B. CH2OH-CHOH-CH2OH. C. CH3-CHOH-CH2OH. D. CH2OH-CH2-CH2OH. Cu 22: C 4 cht lng : Glixerol(1), phenol(2), benzen(3), ancol anlylic(4). Cc th nghim cho kt qu sau:

THPT Kim Thnh - Gio vin: ng Xun Cng

A
Dd Br2 NaOH Cu(OH)2
Phn ng Phn ng khng

B
khng khng Phn ng

C
Phn ng khng khng

D
khng khng khng

Kt qu no sau y ph hp ? A. A(1); B(2); C(3); D(4). B. A(2); B(3); C(1); D(4). C. A(4); B(3); C(2); D(1). D. A(2); B(1); C(4); D(3). Cu 23: Pht biu no sau y sai : A. Ancol c nhit si cao bt thng v ancol c lin kt hidro vi nc. B. Phenol c tnh axit l do nh hng ca vng benzen ln nhm OH . C. Do nh hng qua li gia cc nhm OH nn C3H5(OH)3 tc dng c vi Cu(OH)2. D. Phenol v ancol thm u c cha hidro linh ng. Cu 24: Trong s cc ng phn cha nhn thm c cng thc phn t C7H8O. S lng ng phn tc dng c vi NaOH c: A. 2. B. 3. C. 4. D. 5. Cu 25: S lng cc ng phn ancol c cng thc phn t C5H12O l : A. 6. B. 7. C. 8. D. 9 Cu 26: Tch nc t 3-metylbutan-2-ol vi xc tc H2SO4 c , to 170oC thu c sn phm chnh l: A. 2-metylbut-2-en. B. 2-metylbut-3-en. C. 3-metylbut-2-en. D. 3-metylbut-1-en. Cu 27: Khi tch nc t hn hp CH3OH v C2H5OH c xc tc H2SO4 c to cao thu c s sn phm hu c ti a: A. 4. B. 3. C. 2. D. 1. Cu 28: Mt ancol no Y mch h c s C bng s nhm chc. Bit 9,3g Y tc dng vi Na d thu c 0,15 mol H2 (ktc). Cng thc cu to ca Y l: A. CH3OH B. C3H5(OH)3. C. C2H4(OH)2. D. C4H6(OH)4. Cu 29: Tn ca ancol: HO-CH2CH2CH(CH3)-CH3 A. 2-metylbutan-4-ol B. ancol isoamylic. C. 3,3-dimetylpropan-1-ol. D. 3-metylbutan-1-ol. Cu 30: t chy 1 ancol no n chc X thu c 4,4g CO2 v 2,16g nc. X khng b oxi ha bi CuO nung nng. Cng thc cu to ca X l: A. CH3)2C(OH)CH2CH3. B. (CH3)3COH. C. (CH3)2CH-CH2-CH2OH. D. (CH3)2CH-CH2OH. Cu 31: Xem cc hp cht: CH3
X1: CH3-CH-CH 3 OH X3: CH3-CH-CH 2-OH CH3 X5: CH3-CH-CH 2-OH NH2 X2: CH3-C-CH 3 OH X4: CH3-C-(CH 2)2OH O

Cht no b oxi ha bi CuO s to ra sn phm c phn ng trng gng ? A. X1; X2; X4. B. X3; X4; X5. C. X2; X3; X4. D. X2; X4; X5. Cu 32: S lng ng phn mch h c cng thc phn t C4H10O l : A.4 B. 6 C. 7 D. 8 Cu 33: Khi hydrat ha 2-metylbut-2-en th thu c sn phm chnh l: A. 3-metylbutan-1-ol B. 3-metylbutan-2-ol. C. 2-metylbutan-2-ol. D. 2-metylbutan-1-ol. Cu 34: Ancol n no cha 6 nguyn t cacbon c s lng ng phn ancol bc mt l :

THPT Kim Thnh - Gio vin: ng Xun Cng

A. 5 B. 6 C. 7 Cu 35: Cho cc cht sau: D. 8

1- CH2OH-CHOH-CH2OH. 4- CH2OH-CH2OH 2- CH2OH-CHOH-CH=O. 5- HOOC-COOH. 3- CH2OH-CHOH-COOH. 6- H2N-CH2COOH.

Chn p n ng : A. Hp cht a chc: 1, 2, 3. B. Hp cht a chc: 1, 3, 6. C. Hp cht tp chc : 2, 3, 6. D. Hp cht tp chc: 2, 3, 4. Cu 36: Trong cc mnh sau y : 1- Hp cht hu c c hai nhm chc tr ln trong phn t l hp cht c nhiu nhm chc. 2- hp cht hu co c hai nhm chc l hp cht tp chc. 3- Hp cht hu c c hai hay nhiu nhm chc ging nhau trong phn t l hp cht a chc. 4- Hp cht hu c c hai hay nhiu nhm chc khng ging nhau trong phn t l hp cht tp chc. Cc mnh ng v hp cht c nhiu nhm chc l: A. 1,2,3. B. 1,3,4. C. 1,2,4. D. 1,2,3,4. Cu 37: Glixerol tc dng c vi Cu(OH)2 do: A. c nhiu nhm OH . B. c nhiu nhm OH gn vo cc nguyn t C k cn nhau. C. glixerol l ru a chc. D. glixerol trng thi lng. Cu 38: Cho cc cht: 1) CH2OH-CH2OH ;
2) CH2OH-CHOH-CH2OH; 3) C3H7CHO; 4) CH2OH-CH2-CH2OH; 5) CH3-CH2-O-CH3 ; 6) C6H5OH.

Cht no tc dng vi Na v Cu(OH)2 ?

A. 1,2,3,4. C. 1,2,5. B. 1,2,4,6. D. 1,2. A
+H2O H2SO4, toC

Cu 39: Cho chuiHphn ng : o 2SO4, 170 C

CH3-CH2-CH2-OH

A v B ln lt l: A. propen; propan-2-ol B. propylen; propan-1-ol C. di-propylete; ancol propylic D. propen; propanal Cu 40: t chy mt ete A n chc thu c kh CO2 v hi nc theo t l mol H2O : CO2 = 5 : 4. Vy ete A c to ra t : A. ancol etylic. B. ancol metylic v ancol propylic. C. ancol metylic v ancol isopropylic. D. A, B, C u ng. Cu 41: Thc hien 2 th nghiem sau: Th nghiem 1 cho t t natri kim loai vao ancol etylic, th
nghiem 2 cho t t natri kim loai vao nc th: A.Th nghiem 1 phan ng xay ra manh liet hn phan ng 2. B.Th nghiem 2 phan ng xay ra manh liet hn phan ng 1. C.Ca 2 th nghiem 1 va 2 eu xay ra phan ng nh nhau. D.Ch co th nghiem 1 xay ra phan ng, con th nghiem 2 phan ng khong xay ra.

Cu 42: Mt ancol no c cng thc nguyn : (C2H5O)n. Cng thc phn t ca ancol l... A. C2H5O B. C4H10O2 C. C6H15O3 D. C8H20O4 Cu 43: Mt ancol no, n chc, bc 1 b tch mt phn t nc to anken A. C 0,525 gam anken A tc dng va vi 2g brm. Ancol ny l... A. Butan-1-ol B. Pentan-1-ol C. Etanol D. Propan-1-ol Cu 44 : Cho 16,6 gam hn hp gm ancol etylic v ancol propylic phn ng ht vi Na d thu c 3,36 lit H2 (ktc). % v khi lng cc ru trong hn hp l :

THPT Kim Thnh - Gio vin: ng Xun Cng

A. 27,7% v 72,3% B. 60,2% v 39,8% C. 40% v 60% D. 32% v 68% Cu 45 : X l mt ancol no, a chc, mch h c s nhm -OH nh hn 5. C 7,6 gam ancol X phn ng ht vi Natri cho 2,24 lt kh (o ktc). Cng thc ho hc ca X l... A. C4H7(OH)3 B. C2H4(OH)2 C. C3H5(OH)3 D. C3H6(OH)2 Cu 46 : A l ng ng ca ru etylic c t khi hi so vi oxi bng 2,3125. S ng phn c mch cacbon khng phn nhnh ca A l... A. 1 B. 2 C. 3 D. 4

PHENOL
Cu 1 : Cho hp cht c CTCT l :
CH3 OH

Trong 3 tn gi sau y, tn gi no ng? 1. 2-metylphenol 2. O-cresol 3. 2-metyl-1-hidroxibenzen. A. Ch c 1. B. 1, 2 C. Ch c 2. C. c 3 u ng. Cu 2: Khi cho Phenol tc dng vi nc brom, ta thy: A. mt mu nu ca nc brom. B. to kt ta gch. C. to kt ta trng. D. to kt ta xm bc. Cu 3 : Cho hp cht thm c cng thc phn t : C7H8O. C bao nhiu ng phn ng vi cng thc trn ? A. 3 B. 4 C. 5 D. 6 Cu 4 : phn bit gia phenol v ru benzylic, ta c th dng thuc th no trong cc thuc th sau y : 1. Na ; 2.dd NaOH ; 3. nc brom A. Ch c 1 B. Ch c 2. C. 1 v 2. D. 2 v 3. Cu 5 : Hy chn pht biu ng : A. Phenol l cht c nhm OH, trong phn t c cha nhn benzen. B. Phenol l cht c nhm OH khng lin kt trc tip vi nhn benzen. C. Phenol l cht c nhm OH gn trn mch nhnh ca hidrocacbon thm. D. Ru thm l cht c nhn benzen, mi thm hnh nhn. Cu 6 : C bao nhiu ng phn ru thm c cng thc phn t C8H10O ? A. 5 B. 4 C. 3 D. 2 Cu 7 : Hy chn cu ng khi so snh tnh cht ha hc khc nhau gia ancol etylic v phenol . A. c hai u phn ng c vi dung dch NaOH. B. C hai u phn ng c vi axit HBr. C. Ancol etylic phn ng c vi NaOH cn phenol th khng. D. Phenol phn ng vi dung dch NaOH cn ancol etylic th khng. Cu 8 : Cho 3 cht : (X) C6H5OH, (Y) CH3C6H4OH ; (Z) C6H5CH2OH. Nhng hp cht no trong s nhng hp cht trn l ng ng ca nhau ? A. (X) ; (Y) B. (Y) ; (Z) C. (X) ; (Z) D. (X) ; (Y) ; (Z). Cu 9 : Pht biu no sau y sai : A. Phenol l axit yu, khng lm i mu qu tm. B. Phenol l axit yu, nhng tnh axit vn mnh hn axit cacbonic. C. Phenol cho kt ta trng vi dung dch nc brom.

THPT Kim Thnh - Gio vin: ng Xun Cng

D. Phenol rt t tan trong nc lnh. Cu 10 :Mt hn hp X gm ancol etylic v phenol tc dng vi natri d cho ra hn hp 2 mui c tng khi lng l 25,2 gam. Cng lng hn hp y tc dng va vi 100ml dung dch NaOH 1M. Tnh s mol mi cht trong hn hp X v th tch hidro bay ra (ktc) trong phn ng gia X v Natri . A. 0,1mol ancol ; 0,1mol phenol ; 2,24 ltH2 B. 0,2mol ancol ; 0,2mol phenol ; 4,48 ltH2 C. 0,2mol ancol ; 0,1mol phenol ; 3,36 ltH2 D. 0,18mol ancol ; 0,06mol phenol ; 5,376 lt H2. Cu 11 : Oxi ha 21,6g o-cresol bng dung dch K2Cr2O7 0,5M mi trng H2SO4. Tnh th tch dung dch K2Cr2O7 cn thit v khi lng sn phm hu c thu c. A. 0,4lt ; 28,8g. B. 0,3lt ; 25,8g. C. 0,5lt ; 30,2g. D. 0,4lt ; 27,6g. Cu 12 : C bao nhiu ng phn ng vi cng thc phn t C8H10O u phn ng c vi dung dch NaOH ? A. 6. B. 7. C. 8. D. 9. Cu 13 : C cc pht biu sau y : 1. C2H5OH v C6H5OH u phn ng d dng vi HBr. 2. C2H5OH c tnh axit yu hn C6H5OH. 3. C2H5ONa v C6H5ONa phn ng hon ton vi nc cho ra tr li C2H5OH v C6H5OH. Chn pht biu sai : A. ch c 1 B. ch c 2. C. ch c 3. D. 1 v 3. Cu 14 : C 3 cht (X)C6H5OH ; (Y)C6H5CH2OH ; (Z)CH2=CH-CH2OH. Khi cho 3 cht trn phn ng vi Na kim loi, dung dch NaOH, dung dch nc brom. Pht biu no sau y sai : A. (X) ; (Y) ; (Z) u phn ng vi Na. B. (X) ; (Y) ; (Z) u phn ng vi NaOH. C. (X) ; (Z) phn ng vi dung dch brom, cn (Y) th khng phn ng vi dd brom D. (X) phn ng vi dd NaOH, (Y) ; (Z) khng phn ng vi dd NaOH. Cu 15 : Phn ng no sau y chng minh phenol c tnh axit yu: A. C5H5ONa + CO2 + H2O B. C6H5ONa + Br2 C. C6H5OH + NaOH D. C6H5OH + Na. Cu 16 : Cho a (mol) hp cht hu c X c cng thc phn t C 7H8O2 tc dng vi natri d thu c a (mol) kh H2(ktc). Mt khc, a (mol)X ni trn tc dng va vi a (mol) Ba(OH)2. Trong phn t X c th cha: A. 1 nhm cacboxyl COOH lin kt vi nhn thm. B. 1 nhm CH2OH v 1 nhm OH lin kt vi nhn thm C. 2 nhm OH lin kt trc tip vi nhn thm. D. 1 nhm O CH2OH lin kt vi nhn thm Cu 17: Phn ng no di y ng : A. 2C6H5ONa + CO2 + H2O 2C6H5OH + Na2CO3
B. C6H5OH + HCl C6H5Cl + H2O C. C2H5OH + NaOH C2H5ONa + H2O D. C6H5OH + NaOH C6H5ONa + H2O

Cu 18: Cho cc phng trnh phn ng theo dy chuyn chuyn ha sau :

C6H6
Cl2, Fe dd HCl

(B)

C6H5OH

dd NaOH, p,tocao

(C)

Hiu sut ca qu trnh trn l 80%, nu lng benzen ban u l 2,34 tn, th khi lng phenol thu c l : A. 2,82 tn B. 3,525 tn C. 2,256 tn D. 2,526 tn Cu 19: Mt dd X cha 5,4g cht ng ng ca phenol n chc. Ch odd X phn ng vi nc brom (d), thu c 17,25g hp cht cha 3 nguyn t brom trong phn t, gi s phn ng xy ra hon ton. Cng thc phn t cht ng ng ca phenol l: A. C7H7OH. B. C8H9OH B. C9H11OH. D. C10H13OH. Cu 20: iu ch natri phenolat t phenol th cho phenol phn ng vi :

THPT Kim Thnh - Gio vin: ng Xun Cng

A. dung dch NaCl. B. dung dch NaOH. C. dd NaHCO3 . D. B v C ng. Cu 21: Pht biu no sau y ng: (1). Phenol c tnh axit mnh hn etanol v nhn benzen ht electron ca nhm OH bng hiu ng lin hp, trong khi nhm C2H5 li y electron vo nhm OH . (2). Phenol c tnh axit mnh hn etanol v c minh ha bng phn ng phenol tc dng vi dung dch NaOH cn etanol th khng. (3). Tnh axit ca phenol yu hn H2CO3 v sc CO2 vo dung dch C6H5ONa ta s c C6H5OH khng tan. (4). Phenol trong nc cho mi trng axit, qu tm ha . A. (1); (2); (4). B. (2); (3). C. (1); (3). D. (1); (2); (3). Cu 22: Cho cc cht c cng thc cu to:
CH3 OH
OH

1) 2) 3) Cht no thuc loi phenol ? A. (1) v (2). B. (2) v (3). C. (1) v (3). D. (1); (2) v (3) Cu 23: Ha cht duy nht dng nhn bit 3 cht lng ng ring bit trong ba bnh mt nhn : phenol, stiren v ru etylic l... A. natri kim loi. B. qu tm. C. dung dch naOH. D. dung dch brom. Cu 24: Cho cht sau y m-HO-C6H4-CH2OH tc dng vi dung dch NaOH. Sn phm to ra l:
ONa
OH

CH2

OH

A.
CH 2ONa ONa

B.
ONa

CH2ONa

C.
CH2OH

D.
CH2OH

Cu 25: Cho m(gam) phenol C6H5OH tc dng vi natri d thy thot ra 0,56 lt kh H2 (ktc). Khi lng m cn dng l... A. 4,7g. B. 9,4g. C. 7,4g D. 4,9g Cu 26: Cho nc brom d vo dung dch phenol thu c 6,62 gam kt t trng (phn ng hon ton). Khi lng phenol c trong dung dch l: A. 18,8g B. 1,88g. C. 37,6g D. 3,76g Cu 27: Cho 47 gam phenol tc dng vi hn hp gm 200 gam HNO3 68% v 250 gam H2SO4 96% to axit picric (phn ng hon ton). Nng % HNO3 cn d sau khi tch kt t axit picric ra l: A. 27,1g B. 5,425g. C. 10,85g. D. 1,085g Cu 28: Chn cu ng: Phenol c th tc dng vi A. HCl v Na B. Na v NaOH. C. NaOH v HCl. D. Na v Na2CO3.