1

Case Name:PD Insecticide Plant (Final Malathion Plant).hsc

LEGENDS
Burlington, MA
USA

3
4
5
6

Unit Set:

SI

Date/Time:

Fri Dec 14 20:38:10 2012

Workbook:
Case (Main)

7
8
9

Material Streams

10
11 Name

DEM

DDPA

12 Vapour Fraction
13 Temperature
14 Pressure
15 Molar Flow
16 Mass Flow
17 Liquid Volume Flow
18 Heat Flow

23 Molar Flow
24 Mass Flow
25 Liquid Volume Flow
26 Heat Flow

1.0000

0.0000

0.0000

(C)

*
25.00

*
25.00

*
53.00

53.00

*
25.00

(kPa)

*
101.3

*
101.3

101.3

101.3

*
101.3

*
2.250

*
2.000

0.0000

2.250

*
1.000

(kg/h)

387.4

316.4

0.0000

703.8

18.02

(m3/h)

0.3998

0.2606

0.0000

0.5861

1.805e-002

(kgmole/h)

(kJ/h)

-1.814e+006

31 Molar Flow
32 Mass Flow
33 Liquid Volume Flow
34 Heat Flow

39 Molar Flow
40 Mass Flow
41 Liquid Volume Flow
42 Heat Flow

0.0000

0.0000

0.0000

0.0000

25.00

106.1

*
25.00

25.00

(kPa)

101.3

101.3

101.0

101.2

101.3

0.0000

3.250

1.604

1.646

2.250

(kg/h)

0.0000

721.8

177.9

543.9

703.8

(m3/h)

0.0000

0.6041

0.1583

0.4459

0.5861

(kJ/h)

0.0000

(kgmole/h)

47 Molar Flow
48 Mass Flow
49 Liquid Volume Flow
50 Heat Flow

55 Molar Flow
56 Mass Flow
57 Liquid Volume Flow
58 Heat Flow

0.0000

0.0000

0.0000

0.0000

*
105.7

105.7

106.1

*
25.00

(kPa)

101.2

102.3

102.3

103.0

*
102.3

1.646

0.0000

1.743

1.604

*
1.000

(kg/h)

543.9

0.0000

179.4

177.9

18.02

(m3/h)

0.4459

0.0000

0.1597

0.1583

1.805e-002

(kgmole/h)

(kJ/h)

2.509e+005

63 Molar Flow
64 Mass Flow
65 Liquid Volume Flow
66 Heat Flow

-5.076e+005

-4.720e+005

-2.849e+005

Waste Water 2 86% Malathion 2DEM & Water Waste

1.0000

0.0000

1.0000

0.0000

1.0000

(C)

90.53

90.53

*
280.0

280.0

*
280.0

(kPa)

102.3

102.3

102.3

102.3

102.3

0.0000

2.604

1.542

0.2012

0.0000

(kgmole/h)
(kg/h)

0.0000

195.9

115.0

64.36

0.0000

(m3/h)

0.0000

0.1763

0.1066

5.310e-002

0.0000

(kJ/h)

0.0000

1.063e+004

0.0000

-7.569e+005

86% Malathion Waste Water

-3.965e+005

To WTP

To ETP

To WTP 2

0.0000

1.0000

0.0000

0.0000

0.0000

(C)

280.0

105.7

*
25.00

*
25.00

*
25.00

(kPa)

102.3

102.3

102.3

102.3

102.3

0.0000

0.8608

0.8608

0.0000

1.542

(kg/h)

0.0000

16.55

16.55

0.0000

115.0

(m3/h)

0.0000

1.661e-002

1.661e-002

0.0000

0.1066

(kJ/h)

0.0000

-2.084e+005

-2.487e+005

0.0000

(kgmole/h)

Malathion Inlet

Naphthalene

-5.195e+005

Aromatic Hydrocarbon
57% Malathion (EC)
Sulphuric Acid

0.0000

0.0000

0.0000

0.0024

0.0000

(C)

280.0

*
25.00

*
25.00

174.0

*
25.00

(kPa)

102.3

*
101.3

*
101.3

101.3

0.2341

0.5016

(kgmole/h)

0.2012

(kg/h)

64.36

(m3/h)

5.310e-002

(kJ/h)

1.063e+004

Acetone

60 Vapour Fraction
62 Pressure

0.0000

Vapour 2 (No Flow)

Decanter Inlet

59 Name
61 Temperature

-2.598e+005

380.7

52 Vapour Fraction
54 Pressure

-4.796e+004

0.0000

51 Name
53 Temperature

-4.720e+005

(C)

44 Vapour Fraction
46 Pressure

-5.447e+005

Malathion Product
Decanter Outlet Decanter
1
Outlet Wash
2
Drum InletWater
2
2

43 Name
45 Temperature

-2.849e+005

25.00

36 Vapour Fraction
38 Pressure

-2.358e+005

1.0000

35 Name
37 Temperature

0.0000

(C)

28 Vapour Fraction
30 Pressure

-6.825e+005

Vapour Output (No

Malathion
Flow) 2Mixture
Upper
WithStream
Water (Malathion
PURE Malathion
& DEM
Cooled
(100%)
Mixture)
Malathion Mixt

27 Name
29 Temperature

Vapour Output (No

Malathion
Flow) Mixture
Water
0.0000

20 Vapour Fraction
22 Pressure

All

0.0000

19 Name
21 Temperature

Fluid Pkg:

6.625e-002
*
8.491

8.763e-003
6477

0.0000

0.0000

*
25.00

25.00

(kPa)

*
101.3

101.2

0.1435

1.875

(kg/h)

106.1

*
8.333

3.313e-002

9.499e-002

4.503e-003

1.399e+004

3.109e+004

-6.789e+004

95% Malathion (TC)

(C)
(kgmole/h)

*
33.29

*
101.3

8.496e-002

*
8.333

(m3/h)

1.055e-002

(kJ/h)

-3.564e+004

560.5
0.4609
-1.515e+005

67
68
69

Aspen Technology Inc.

Licensed to: LEGENDS

Aspen HYSYS Version 7.3 (25.0.0.7336)

Page 1 of 4
* Specified by user.

1
2

Case Name:PD Insecticide Plant (Final Malathion Plant).hsc

LEGENDS
Burlington, MA
USA

3
4
5
6

Unit Set:

SI

Date/Time:

Fri Dec 14 20:38:10 2012

Workbook:
Case (Main) (continued)

7
8
9

Compositions

10
11 Name

DEM

DDPA

Fluid Pkg:

All

Vapour Output (No

Malathion
Flow) Mixture
Water

12 Comp Mole Frac (H2O)

*
0.0000

*
0.0000

0.0000

0.0000

*
1.0000

13 Comp Mole Frac (Malathion)

*
0.0000

*
0.0000

0.0236

0.8889

*
0.0000

14 Comp Mole Frac (H2SO4)

*
0.0000

*
0.0000

0.0000

0.0000

*
0.0000

15 Comp Mole Frac (Acetone)

*
0.0000

*
0.0000

0.0000

0.0000

*
0.0000

16 Comp Mole Frac (O,O Dimethyl dithiophosphoric

*
*
0.0000
acid (DDPA)*)
1.0000

0.0000

0.0000

*
0.0000

17 Comp Mole Frac (DiEMaleate)

*
0.0000

0.9764

0.1111

*
0.0000

18 Comp Mole Frac (Sodium O,O-dimethyl0.0000

*
*
phosphorodithioate*)
0.0000

0.0000

0.0000

*
0.0000

19 Comp Mole Frac (Naphthalene)

*
0.0000

*
0.0000

0.0000

0.0000

*
0.0000

20 Comp Mole Frac (2-M-Naphtln)

*
0.0000

*
0.0000

0.0000

0.0000

*
0.0000

21 Name

*
1.0000

Vapour Output (No

Malathion
Flow) 2Mixture
Upper
WithStream
Water (Malathion
PURE Malathion
& DEM
Cooled
(100%)
Mixture)
Malathion Mixt

22 Comp Mole Frac (H2O)

0.9977

0.3077

0.6235

0.0000

0.0000

23 Comp Mole Frac (Malathion)

0.0000

0.6154

0.2206

1.0000

0.8889

24 Comp Mole Frac (H2SO4)

0.0000

0.0000

0.0000

0.0000

0.0000

25 Comp Mole Frac (Acetone)

0.0000

0.0000

0.0000

0.0000

0.0000

26 Comp Mole Frac (O,O Dimethyl dithiophosphoric

0.0000
acid (DDPA)*)
0.0000

0.0000

0.0000

0.0000

27 Comp Mole Frac (DiEMaleate)

0.0769

0.1559

0.0000

0.1111

28 Comp Mole Frac (Sodium O,O-dimethyl0.0000

phosphorodithioate*)
0.0000

0.0000

0.0000

0.0000

29 Comp Mole Frac (Naphthalene)

0.0000

0.0000

0.0000

0.0000

0.0000

30 Comp Mole Frac (2-M-Naphtln)

0.0000

0.0000

0.0000

0.0000

0.0000

31 Name

0.0023

Malathion Product
Decanter Outlet Decanter
1
Outlet Wash
2
Drum InletWater
2
2

32 Comp Mole Frac (H2O)

0.0000

0.6967

0.6575

0.6235

*
1.0000

33 Comp Mole Frac (Malathion)

1.0000

0.1795

0.2030

0.2206

*
0.0000

34 Comp Mole Frac (H2SO4)

0.0000

0.0000

0.0000

0.0000

*
0.0000

35 Comp Mole Frac (Acetone)

0.0000

0.0000

0.0000

0.0000

*
0.0000

36 Comp Mole Frac (O,O Dimethyl dithiophosphoric

0.0000
acid (DDPA)*)
0.0000

0.0000

0.0000

*
0.0000

37 Comp Mole Frac (DiEMaleate)

0.1238

0.1396

0.1559

*
0.0000

38 Comp Mole Frac (Sodium O,O-dimethyl0.0000

phosphorodithioate*)
0.0000

0.0000

0.0000

*
0.0000

39 Comp Mole Frac (Naphthalene)

0.0000

0.0000

0.0000

0.0000

*
0.0000

40 Comp Mole Frac (2-M-Naphtln)

0.0000

0.0000

0.0000

0.0000

*
0.0000

41 Name

0.0000

Vapour 2 (No Flow)

Decanter Inlet

Waste Water 2 86% Malathion 2DEM & Water Waste

42 Comp Mole Frac (H2O)

0.9921

0.7681

0.7418

0.0111

0.7613

43 Comp Mole Frac (Malathion)

0.0000

0.1359

0.1062

0.9442

0.1068

44 Comp Mole Frac (H2SO4)

0.0000

0.0000

0.0000

0.0000

0.0000

45 Comp Mole Frac (Acetone)

0.0000

0.0000

0.0000

0.0000

0.0000

46 Comp Mole Frac (O,O Dimethyl dithiophosphoric

0.0000
acid (DDPA)*)
0.0000

0.0000

0.0000

0.0000

47 Comp Mole Frac (DiEMaleate)

0.0960

0.1520

0.0447

0.1318

48 Comp Mole Frac (Sodium O,O-dimethyl0.0000

phosphorodithioate*)
0.0000

0.0000

0.0000

0.0000

49 Comp Mole Frac (Naphthalene)

0.0000

0.0000

0.0000

0.0000

0.0000

50 Comp Mole Frac (2-M-Naphtln)

0.0000

0.0000

0.0000

0.0000

0.0000

51 Name

0.0079

86% Malathion Waste Water

To WTP

To ETP

To WTP 2

52 Comp Mole Frac (H2O)

0.0115

0.9922

0.9922

0.7613

0.7418

53 Comp Mole Frac (Malathion)

0.9497

0.0000

0.0000

0.1068

0.1062

54 Comp Mole Frac (H2SO4)

0.0000

0.0000

0.0000

0.0000

0.0000

55 Comp Mole Frac (Acetone)

0.0000

0.0000

0.0000

0.0000

0.0000

56 Comp Mole Frac (O,O Dimethyl dithiophosphoric

0.0000
acid (DDPA)*)
0.0000

0.0000

0.0000

0.0000

57 Comp Mole Frac (DiEMaleate)

0.0078

0.0078

0.1318

0.1520

58 Comp Mole Frac (Sodium O,O-dimethyl0.0000

phosphorodithioate*)
0.0000

0.0000

0.0000

0.0000

59 Comp Mole Frac (Naphthalene)

0.0000

0.0000

0.0000

0.0000

0.0000

60 Comp Mole Frac (2-M-Naphtln)

0.0000

0.0000

0.0000

0.0000

0.0000

0.0388

61
62
63
64
65
66
67
68
69

Aspen Technology Inc.

Licensed to: LEGENDS

Aspen HYSYS Version 7.3 (25.0.0.7336)

Page 2 of 4
* Specified by user.

1
2

Case Name:PD Insecticide Plant (Final Malathion Plant).hsc

LEGENDS
Burlington, MA
USA

3
4
5
6

Unit Set:

SI

Date/Time:

Fri Dec 14 20:38:10 2012

Workbook:
Case (Main) (continued)

7
8
9

Compositions (continued)

10
11 Name

Malathion Inlet

Naphthalene

Fluid Pkg:

All

Aromatic Hydrocarbon
57% Malathion (EC)
Sulphuric Acid

12 Comp Mole Frac (H2O)

0.0111

*
0.0000

*
0.0000

0.0045

*
0.0000

13 Comp Mole Frac (Malathion)

0.9442

*
0.0000

*
0.0000

0.3788

*
0.0000

14 Comp Mole Frac (H2SO4)

0.0000

*
0.0000

*
0.0000

0.0000

*
1.0000

15 Comp Mole Frac (Acetone)

0.0000

*
0.0000

*
0.0000

0.0000

*
0.0000

16 Comp Mole Frac (O,O Dimethyl dithiophosphoric

*
0.0000
acid (DDPA)*)
0.0000

*
0.0000

0.0000

*
0.0000

17 Comp Mole Frac (DiEMaleate)

*
0.0000

*
0.0000

0.0179

*
0.0000

18 Comp Mole Frac (Sodium O,O-dimethyl0.0000

*
phosphorodithioate*)
0.0000

*
0.0000

0.0000

*
0.0000

19 Comp Mole Frac (Naphthalene)

0.0000

*
1.0000

*
0.0000

0.1321

*
0.0000

20 Comp Mole Frac (2-M-Naphtln)

0.0000

*
0.0000

*
1.0000

0.4667

*
0.0000

21 Name

0.0447

Acetone

95% Malathion (TC)

22 Comp Mole Frac (H2O)

*
0.0000

0.0000

23 Comp Mole Frac (Malathion)

*
0.0000

0.8781

24 Comp Mole Frac (H2SO4)

*
0.0000

0.0453

25 Comp Mole Frac (Acetone)

*
1.0000

0.0765

26 Comp Mole Frac (O,O Dimethyl dithiophosphoric

*
0.0000
acid (DDPA)*)
0.0000
27 Comp Mole Frac (DiEMaleate)

*
0.0000

0.0000

28 Comp Mole Frac (Sodium O,O-dimethyl0.0000

*
phosphorodithioate*)
0.0000
29 Comp Mole Frac (Naphthalene)

*
0.0000

0.0000

30 Comp Mole Frac (2-M-Naphtln)

*
0.0000

0.0000

31

Energy Streams

32
33 Name

Q-100

34 Heat Flow

(kJ/h)

35 Name

Q-102
2.261e+006

Q-107

36 Heat Flow

(kJ/h)

37 Name

Q-104

(kJ/h)

0.4268

0.0000

Operation Name

Operation Type

Conversion Reactor DDPA

Q-100

44

48

Feeds
DEM

43 CRV-100 Reactor

47

V-100 Wash Drum

Tank

V-102 Wash Drum

Tank

Products

Cooled Malathion Mixture

Malathion Mixture With Water
No
Water
Vapour Output (No Flow) 2
Wash Drum Inlet 2

Decanter Inlet

Water 2

Vapour 2 (No Flow)

Q-103

56
57
58
59
60
61

E-101

Cooler

E-102

Cooler

E-100

Cooler

E-103

Cooler

E-104

Cooler

Malathion Mixture

Cooled Malathion Mixture

No
Q-101

Malathion Product

PURE Malathion (100%)

Q-105

Waste Water

To WTP
Q-107

DEM & Water Waste To ETP

Q-110
Waste Water 2

To WTP 2
Q-111

Decanter Inlet

Decanter Outlet 1

63

Q-106

Waste Water

V-101 Decanter

3 Phase Separator

Decanter Outlet 2

67

P-100

68 V-101 Separator
69

*
500.0

*
500.0

No

*
500.0

No

*
500.0

No

*
500.0

No

*
500.0

No

*
500.0

No

*
500.0

Q-106

65
66

No

*
500.0

*
Upper Stream (MalathionNo
& DEM Mixture)
2500

62
64

*
500.0

Q-102

51

55

Calc Level

Q-100

Malathion Mixture With

Malathion
Water Product

54

Ignored

Vapour Output (No Flow)No

50 T-100 Distillation Column

Distillation

53

0.0000

Malathion Mixture

49

52

1.217e+005

Unit Ops

42

46

2.989e+005

Q-108

1.230e+005

40

45

Q-105
1.684e+006

Q-109
4.091e+004

All

Q-111

39
41

Q-103
2.407e+004

Q-106

4.034e+004

Q-110

38 Heat Flow

Q-101
1.361e+006

Fluid Pkg:

Pump
Separator

Aspen Technology Inc.

Licensed to: LEGENDS

Upper Stream (Malathion

Wash&Drum
DEM Inlet
Mixture)
2
Q-104
Decanter Outlet 2

86% Malathion 2

No

Aspen HYSYS Version 7.3 (25.0.0.7336)

*
500.0

Page 3 of 4
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5
6
8
9

Operation Name

Date/Time:

Fri Dec 14 20:38:10 2012

Operation Type

V-101 Separator

Separator

15 V-100 Separator

Separator

13

SI

Unit Ops (continued)

10
12

Unit Set:

Workbook:
Case (Main) (continued)

11

Case Name:PD Insecticide Plant (Final Malathion Plant).hsc

14

Feeds
Q-109

Q-109
Decanter Outlet 1

86% Malathion

Q-108

DEM & Water Waste

MIX-101

Mixer

20 MIX-102

Mixer

18

Ignored

Calc Level

No

*
500.0

No

*
500.0

No

*
500.0

No

*
500.0

No

*
500.0

Q-108

16
17

Products
Waste Water 2

86% Malathion
Naphthalene

19

Malathion Inlet

86% Malathion 2
57% Malathion (EC)

Malathion Inlet
Aromatic Hydrocarbon

21

Sulphuric Acid

22
23 MIX-100

Mixer

95% Malathion (TC)

Acetone
PURE Malathion (100%)

24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69

Aspen Technology Inc.

Licensed to: LEGENDS

Aspen HYSYS Version 7.3 (25.0.0.7336)

Page 4 of 4
* Specified by user.