Iit-Jee 2012 Fst1 p2 Solns

18
Brilliant Tutorials Pvt. Ltd. IIT/B.MAT1/CPM/P(II)/Solns

CHEMISTRY
TEST-II
PART-I
SECTIONI
Single Correct Choice Type

1. (C)

2. (A) Pressure at the surface of lake, 10m atm 1 P
1
= column
1
V 10L =
Pressure at the bottom, m ) x 10 ( P
2
+ column
L 25 . 1 V
2
=
25 . 1 ) 10 ( 10 10 x + =
m 70 = x

3. (D)

4. (D)

5. (B)
CoCl
3
.xNH
3

3 n 3
NH . CoCl x
+ nCl

Let initial mole 1 0 0
1 n
m K T
f f
i =
m K ) n 1 (
f
+ = [ ] ionisation 100% for 1 =
) n 1 ( 1 . 0 86 . 1 558 . 0 + =
or n = 2
The number of Cl
dissociated is 2.
or, the formula is [ ]
2 5 3
Cl Cl ) NH ( Co

6. (A) Crust (in igneous rock)

7. (B) No. of H-bonds between 6NH
3
molecules = 1/2 6 = 3 (one H-bond is involved
between 2 molecules).
Total strength of all H-bonds = 30.8 14.4 = 16.4 kJ.
Hence strength of H-bond =
1
mol kJ 5 . 5
3
4 . 16

=

8. (D) For a reversible adiabatic process, entropy change of the system is zero.
19
SECTIONII
Multiple Correct Choice Type

9. (A, B, D)

M / M
n
E
+
for V, Fe and Hg are lower than that of . NO
3
So,
3
NO will oxidize V, Fe and Hg.

10. (C, D)

11. (A, B, C, D)
In all cases rearrangement occurs after formation of nitrene intermediate

12. (B, D)

SECTION III
Integer Type

13. Ans. 2

14. Ans. 1

15. A
2
(g) B(g) + ) g (
2
C

At t = 0 150 0 0
after 10 min. 150 x x x/2
Total pressure = 150 x + x + x/2 = 170
x = 40 mm.
Rate of disappearance of mm/min. 4
10
40
A
2
= =
Ans. 4

16. C
4
H
6

CH
3

(1) (2) (3) (4) (5)

Ans. 5

20
17. 4Zn + 10HNO
3

dilute
4Zn(NO
3
)
2
+ NH
4
NO
3
+ 3H
2
O
Ans. 1

18. HA

H
+
+ A

c(1 ) c c
K
a
=

1
c
2
10
4
=

1
) c (

For the diluted solution (pH = 3)
10
4
=

1
10
3
[ [H
+
] = c = 10
3
] or
1
1
10
1 10

= =

Hence =
11
1
c = 11 10
3

Volume of diluted solution =
c
1
=
11
10
3 +
L =
11
10
6
ml
j 9 10
4

a = 4.
Ans. 4

SECTION IV
Matrix-Type

19. (A) (p), (q), (r), (t) ; (B) (p), (q), (s) ; (C) (r), (t) ; (D) (p), (q), (r)

20. (A) (p), (r) ; (B) (p) ; (C) (q), (s) ; (D) (t)
21
PHYSICS
PART-II
SECTIONI

21. At = 0, charge on capacitor
1
C is
C CV Q = = =

20
2
20
10 2
6
0

For , 0 > t charge on capacitor
1
C is
0
Q Q = t cos where
LC
1
=
Now,
2
2
2
1
3
2
Li
C
Q
=

3
1
tan = t
C
Q
Q = = 3 10
2
3
0

(A)

22. In the frame of centre of the string

l
kq
d
kq
mv mv
2 2
2 2
2
1
2
1
= +

d
kq
l
kq
mv
2 2
2
= +

q
m m c
q
v v

l
kq
mv
kq
d
2
2
2
+
=
cm d 5 . 2
40
1
360
9
9 27
9 . 0
1 . 0
10 10 9
9 3
10 10 9
10 9
10 9
= = =
+
=

+

=

(B)

23.
5
4
53 sin
5 . 7
= =
d

m d 6
10
75
5
4
= =

(D)

B
20 m
22 m
37
d
16.5 m
9m
7.5m
12
16
53

22
24.
m
P
V
cm
= and
2
12
1
2
ml
l
P =
;

ml
P 6
=
If x be distance from centre of the rod
0
6
= x
ml
P
m
P

6
l
x =
So distance of the instantaneous centre of rotation from A =
3 6 2
l l l
=
(B)

25. The equation of current is given as
) sin( 4 2 + + = t i

T
dt t
i
T
rms
+ +
=
0
2
)] sin( 4 2 [

=
rms
i A 3 2
Heat produced per second =
5
4
10 ) 3 2 (
2

= 96 W

(A)

26. A 553 Hz B A = 1
B 554 Hz C B = 2
C 556 Hz C A = 3
D 561 Hz D C = 5
D B = 7
D A = 8
(C)

27.
D
ma f F =

P
ma f =

F
f
f

2
2
1
mR fR =
R a a
D P
=

m
f
m
f F
m
f 2
=
f f F f 2 =

m
F
a
F
f
P
4
,
4
= =

m
F
a
D
4
3
=
(C)

28. If is minimum, and
3
h is zero then buoyant force will be more than weight and if is in
between
1
and
2
the body can come to rest only between the two liquids
(C)
23
SECTIONII
29. Due to smaller coil B
0
=
2 / 3 2 2
2
0
) (
) ( 2
4 x R
N R I
+

Due to larger coil B =
2 / 3 2 2
2
0
] ) 3 ( ) 3 [(
3 ) 9 ( 2
4 x R
N R I
+
=
27
27
B
0
= B
0

(B, C)

30.
4
1
0
0
=
B
A
N
N

0
A
A A
dN
N
dt
= &
0
B
B B
dN
N
dt
=

0
0
A A
B B
N
1
N 8

2
1
=
B
A

2 =
B
A
T
T
2
2
= =
A
B
T
T years
After t years

4
2
1
0
t
A A
N N
|
\
|
= &
2
2
1
0
t
B B
N N
|
\
|
=
( )4
4 2 4
2
4
1
2
1
4
1
2
1
0
0
t
t t t
B
A
B
A
N
N
N
N
=
|
\
|
=
|
\
|
=

At 4 = t years
2
1
) 2 (
4
1
= =
B
A
N
N
&
4
1
=
B B
A A
N
N

At 8 = t years 1 =
B
A
N
N

2
1
=
B B
A A
M
N

At 12 = t years
B
A
N
N
= 2
(A, C)

31. gx v 2 = and m
L
v
m
L
x L
dt
d
dt
dm
= |
\
|
=
Normal reaction N =
dt
dm
v mg
L
x
\
|

=
L
mv
mg
L
x
2
+
|
\
|
=
L
gx m
mg
L
x ) 2 (
+
|
\
|
=
L
mgx 3

(A, C)

24
32. When only
2
S is open, l |
\
|
=
120
4
3
2
cm l 20
4
120
3
2
= =
When only
1
S is open, l =
120
4
2 cm l 60 =
When all three are closed, l =
120
4
2 cm l 60 =
When only
1
S is closed, l =
120
4
2 cm l 60 =

(A, B, C, D)

SECTION III

Integer Type
33.
|
\
|
=
2 2
2
4
1
3
1
3
1
R
\
|
=
16 9
7
9
1
R

R 7
16
= (where R = Rydbergs constant)
2083 3 . 911
7
16
A A = =
As R
qB
mv
=

m
qBR
v =

m
R B q
K
2
2 2 2
= &
m
R B e hc
2
2 2 2
=

19 3
4 8 2 19
10 6 . 1 10 1 . 9 2
10
16
91
10 88 . 3 ) 10 6 . 1 (
2083
12375

=
(

eV 4 94 . 1 94 . 5 = =
Ans.: 4

34. Charge in optical path = t t
1
2
t
|
|
\
|
= 1
1
2

t
|
|
\
|
= 1
2
1
2

25
t |
\
|
=
1
33 . 1
53 . 1
2

t =
33 . 1
20 . 0
10
33 . 1 2
6300
10

4
10
4 . 0
6300

= t m

40
63
= t m =
n 8
63
m
n = 5
Ans.: 5

35. Let x be maximum distance of person from
speaker I when he hears no sound (i.e.,
minima)
m
5
4
425
340
= =

2 2
2 2
5
2
2
) 4 . 2 (
|
\
|
+ =
|
\
|
+ = + x x x

25
4
5
4
25
144
2 2
+ + = +
x
x x

Speaker I
Speaker II
Pole
2.4m

25
140
5
4
=
x
20
140
= x
m x 7 =

Ans.: 7

2.4
x
2
+ x

36. ) ( qE mg
dt
dv
m + =
) ( qE mg
ds
dv
mv + =
10 ) 10 2 10 1 (
3
1
1 = + =
ds
dv
v
ds dv v
d

=
0
0
50
10

( )
d 10
2
50
0
2
=
m d
8
1000
2
250
20
2500
= = =
8 = n
Ans.: 8
26

37. Let acceleration of the ball be j a i a
y x

In the ground frame 75 tan
x y
a a =
In the frame of wedge
45 tan ) (
x y
a a a =
a a a
y y
= + 45 cot 75 cot

45 75

y

x

45 cot 75 cot +
=
a
a
y
&
45 cot 75 cot
75 cot
+
=
a
a
x

x y
Ball
a a a
2 2
+ =
45 cot 75 cot
75 cos
+
=
ec a
a
Ball

4
2
3
2
1
6 2
=
=
Ball
a m/s
2

ay
ax a

Ans.: 4

38.
2
u
u
x
=
45 sin v v
x
=
45 cos v v
y
=
t
m
qE u
v =
2
45 sin

45
45
45
V
45
y

gt
u
v =
2
45 cos
E
m
q
= 10
5 = E N/C
Ans.: 5
27
SECTIONIV
Matrix Type
39. The process is represented by ) (
3
3
3
0
0 0
0 0
0
V V
V V
P P
P P
=

0
0
0
4P V
V
P
P +
= ..... (i)
and
0
0
V
P
dV
dP
= ..... (ii)

nRT PV = nRdT VdP PdV = +
) 4 (
4
0
2
0
0
0
0 0
2
0
V V V
nRV
P
nRV
V V P V P
T + =
+
=

V
3V
0
4V
0
V
0
O 2V
0

T

Temperature is maximum when V = 2 V
0

nRdT VdP dV V V
V
P
= + + ) 4 (
0
0
0

) 2 (
2
) 4 (
2
3
2
3
0
0
0
0
0
0
V V
V
P
nRdT V V
V
P
nRdT PdV RdT n nCdT
+
+ = + =
R
V V
V V
C
(
+ =
) 2 ( 2
) 4 (
2
3
0
0
R
V V
V V
) 2 ( 2
) 4 10 (
0
0
=
R
V V
V V
C
|
|
\
|
=
0
0
2
2 5

For
0 0
2V V V < <

Ve Q T Ve C + = + = ,
For
0 0
5 . 2 2 V V V < < Ve Q T Ve C + = = ,
For
0 0
3 5 . 2 V V V < < Ve Q T Ve C = + = ,
(A) (p, r, s), (B) (p, r, s), (C) (q, t), (D) (q, r, s)

28
40.
dt
dv
m Bil mg =

dt
mdv
l
R
Blv
B mg = |
\
|

=
v t
v
R
l B
mg
Mdv
dt
0
2 2
0

= t
v
R
v l B
R
v l B
mg
m
0
2 2
2 2
) ln(
(
(
(
(

mg
R
v l B
mg t
mR
l B
ln ln
2 2 2 2
|
|
\
|
=

mR
t l B
mgR
v l B
2 2 2 2
1 ln =
|
|
\
|

|
|
\
|
=
MR
t l B
e
l B
mgR
v
2 2
1
2 2

K = Kinetic energy
2
4 4
2 2 3
2
) 1 (
2 2
1
2 2
mR
t l B
e
l B
R g m
mv
= =

2 4
2 2 3
l B
R g m
dt
dK
= ) 1 (
2 2
mR
t l B
e
mR
l B
2 2
) (
2 2
mR
t l B
e

) 0 ( = t at
dt
dK
= 0, ) ( = t at
dt
dK
=0
Power supplied by gravity = mgv =
|
|
\
|
mR
t l B
e
l B
R g m
2 2
1
2 2
2 2

Heat produced in the wire at the rate = R
R
v l B
R i
2
2 2 2
2
=
2 2
2 2
l B
R g m
=
2
2 2
1
|
|
\
|
mR
t l B
e
Acceleration of the conductor =
dt
dv
=
mR
t l B
e g
2 2

(A) (p, s); (B)(r); (C)(t); (D)(q)

29
MATHEMATICS
PART-III
SECTION I
41. (A) Put t y =
2

( ) ( ) 0 1 2
2 2
= + + t x e
dx
dt
e e
x t x

( ) ( ) 0 1 2
2 2
= + +
t x x
e e
dt
dx
t xe
Put =
2
x
e
( ) 0 1 = + +
t
e
dt
d
t

1 1
=
t
e
t dt
d
t

Solution is ( ) c e t
t
+ = 1
( ) c e y e
y x
= +
2
2
2
1 .

42. (C)
( )
( ) ( ) 2 2 2 ... 6 . 4 . 2
1 2 ... 5 . 3 . 1
+
=
n n
n
t
n

( )
( ) ( )
( ) ( ) [ ] 1 2 2 2
2 2 2 ... 6 . 4 . 2
1 2 ... 5 . 3 . 1
+ +
+
= n n
n n
n

( )
( )
( )
( ) 2 2 ... 6 . 4 . 2
1 2 ... 5 . 3 . 1
2 ... 6 . 4 . 2
1 2 ... 5 . 3 . 1
+
+
=
n
n
n
n

( )
( ) 2 2 ... 6 . 4 . 2
1 2 ... 5 . 3 . 1
2
1
+
+
=
n
n
S
n

2
1
=
S .

43. (A) Let l AB =
= sin 2a l and = cos a r
Now,
3
5
3
4 a
l
a
< <

6
5
sin
3
2
< <
36
25
cos 1
9
4
2
< <

A B
a
r

3
5
cos
6
11
< < a r a
3
5
6
11
< <
Hence, the required probability

4
1
36
9 36
11
9
5
2
2
= =
\
|

=
a
a
.
30

44. (D) ( ) ( ) ( )
30 2
30 2 1
... 1 ... x x x x x x + + + + =
( ) ( ) ( )
30 2 1
ln ... ln ln + + + x x x
( )
30 2
... 1 ln x x x + + + + =
Differentiate both sides w.r.t x.

30 2
29 2 30
1
... 1
30 ... 3 2 1 1
x x x
x x x
x
i i
+ + + +
+ + + +
=

=

Put 1 = x .

45. (B) The graph of x x y ln = is

x
y
(1/e, 1/e)

46. (C) Normal at ( ) tan 2 , sec is
3
tan 2
2
sec
=
y x

Intercepts are
2
tan 3
, sec 3

Let ( ) |
\
|
+ =
2
tan
sec 3 f
( ) |
\
|
+ =
2
sec
tan sec 3 ' f
( ) |
\
|
+ + |
\
|
+ =
2
sec
tan tan sec 3
2
tan sec
sec sec 3 ' '
2
f
( ) 0 ' = f
2
1
sin =
4
5
4
+ =
( ) ( ) ( ) ( ) 1 1 2 3 1 2 2 3
4
5
' ' + = |
\
|
f
0 2 3 < =
Maximum at
4
5
= .

31
47. (D) Clearly, CA is the radius of the
largest circle and BA is the radius
of the smallest circle.
Required difference 10 2 = = r .

C
B
(3, 2)
A(a, b)

48. (A) Let = = = c b a

( ) ( ) ( )a b x a b x
.
2
( ) ( ) ( )b c x b c x

+ .
2
( ) ( ) ( ) 0 .
2

= + c a x c a x

( )
( )
( )
( )
( ) ( )
( )
( (
+ + + + + =

2
3x a b c a.x a b.x b c.x c a.b a b.c b c.a c 0

Now, any vector x
can be expressed in terms of three non-coplanar vectors c b a
, ,
as

= + +
2 2 2
a x b x c x
x a b c
a c
b

( ) 0 3
2 2

= x c b a x
( ) c b a x

+ + =
2
1
.

SECTION II

49. (B, C, D)
Put
t
x
1
= in u or v u v =
dx
x
x
x
dx
x x
x
v u

+ |
\
|

+
=
+ +
+
= +
0
2
2
0
2 4
2
9
1
1
1
1 7
1

|
|
|
|
\
|

=
0
1
3
1
tan
3
1
x
x

3 2 2 3
1
=
(
\
|

= .
50. (B, C)
( ) 3 , 0 , 3 = Q and R = (3, 2, 1).

51. (B, C)
Let ( ) ( ) ( ) z C P y B P x A P = = = , ,
Given ( ) ( )
4
1
1 1 = z y x (i)
32
( ) ( )
8
1
1 1 = z y x (ii)
( ) ( ) ( )
4
1
1 1 1 = z y x (iii)
1
1
=
x
x

2
1
= x and
2
1
1
=
y
y

3
1
= y
4
1
= z
( ) ( ) ( ) ( )
24
1
= = = xyz C P B P A P C B A P
( ) ( ) ( ) ( )
(
= + + = + + =

1 1 1 1
P A B C P A B C P A B C P A B C
4 8 8 2
.

52. (A, B, C, D)
( )
x
x
x
x f
2 2
2 2
2 2
3
=
( )
x
x x
2 1
2 1
2 2 1
4 + = (Applying
3 2 1 1
C C C C + + )
( )
x
x x
x
x
2 1
2 2 0
0 2 0
4
+ = (
3 2 2 2 1 1
, R R R R R R )
( ) ( ) 4 2
2
+ = x x
( ) ( ) ( ) 2 2 3 '
3
+ = x x x f
( ) x f
3
has a local maximum at 2 = x
( )
x
x
x
x
x f
2 2 2
2 2 2
2 2 2
2 2 2
4
= ( ) ( ) 6 2
3
+ = x x
( ) ( ) ( ) 4 2 4 '
2
4
+ = x x x f
( ) ( ) ( ) 2 2 12 ' '
4
+ = x x x f .

SECTION III
Integer Type

53. Let the 199
th
roots of unity be

198 2 1
,..., , , 1 , where
199
2 j i
j
e
=
Now, ( ) ( ) ( ) ( )
198 2 1
199
... 1 1 = x x x x x
( )
=
= + + +
198
1
197 198
1 ...
j
j
x x x
33
Put 1 = x .
( )

= =
|
|
\
|
= =
198
1
198
1
199
2
1 1 199
j j
j i
j
e

=

|
|
\
|
|
|
\
|
=
198
1
199 199 199
199
j
j i j i j i
e e e
\
|
|
|
\
|
=
198
1
199
199
sin 2 199
j
j i
j
i e
Take modulus on both sides.
|
\
|
|
\
|
|
\
|
=
199
198
sin 2 ...
199
2
sin 2
199
sin 2 199
A = 199.
Ans. 9

54. The given equation is possible only if
1 6 sin 5 sin 4 sin 3 sin 2 sin = = = = = x x x x x
There is no real x which satisfies all the above relations simultaneously.
Ans. 0

55. Let ( )
2
2
1
1
1
sin , cos t y t x = =

1
0 t and
4
0
2
2
t

4 4
0
2 2
a

1
4
0 +
a (i)

4
2
2 1
= +
a
t t and
16
4
2 1
= t t

16 4
4
1
2
1
=
|
|
\
|
t
a
t
0
16 4
4
1
2
2
1
=
t
a
t
Since,
1
t is real, 0 D

16
4
16
4 4 2
a
4
2
a (ii)
The value of a satisfying (i) and (ii) is 2.
Ans. 2

34
56. The required conditions are
(1) ( ) 0 6 1 2 3 > + + 4 >
(2) ( ) 0 2 1 8 < + +
7
6
>
(3) ( ) 0 9 1 3 < + +
2
3
<

2
3
7
6
< <
C(6,1)
x8y+2=0 x+3y9=0
3x2y+6=0 A(0,3) B(2,0)
P(,+1)

The integral values are 0, 1.
Ans. 2

57.

=
|
|
\
|
dx
dx
y d
dx
y d
d
8
2
2
2
2

1
2
2
8 ln c x
dx
y d
+ =
0
1
= c

x
e
dx
y d
8
2
2
=

2
8
8
c
e
dx
dy
x
+ =

8
1
8
1
0
2
= = c

8
1
8
=
x
e
dx
dy

3
8
8
8
c
x
e
y
x
+
=

64
7
64
1
8
1
3
= = c

64
7 8
8
+
=
x e
y
x

64 = .
Ans. 8

58. Number of numbers when 1, 2, 3, 4, 5 are used = 5! = 120.
Number of numbers when 0, 1, 2, 4, 5 are used = 5! 4! = 96.
Required number = 120 + 96 = 216.
216
3
= n n = 6.
Ans. 6
35

SECTION IV

Matrix Type

59. (A) s; (B) p; (C) t; (D) s.

Sol.: (A) { }
= =
3
0
2
3
2
1
3 2 , , 1 min dx x x

x
y
1 2 3
y=x y
=
2
x

y
=
x
2

(B) { }
=
2
2
2 ] [ , min dx x x

x
y
1
2
1 2

(C) { }
0
cos , sin max dx x x

+ =
4 /
0 4 /
sin cos dx x dx x
2 1 1
2
1
2
1
+ = + + = .

x
y
1
/4
y=cosx
y=sinx

(D) { }
0
1 , cos 1 , sin 2 min dx x x
( ) ( )

+ + =
6 / 5
2 / 6 / 5
2 /
0
sin 2 1 cos 1 dx x dx dx x

x
y
/2 5/6
y
=
1
c
o
s
x

y=2sinx
y=1

|
|
\
|
+
=
2
3
1 2
3
1
2
3 1
6
5
+
= .

60. (A) q, r; (B) r, s, t; (C) p, r; (D) q, t.
Sol.: (A) ( ) ( ) x x = +
1 1
cos 1 2 tan 2
( ) ( ) x x = +
1 2 tan 2 cos
1

( )
( )
x
x
x
=
+ +
+
2
2
1 2 1
1 2 1

36
0 2
3
= x x 0 = x ,
2
1

0 = x and
2
1
= x satisfy the given equation.

(B) ( )
2 1 1
1 2 sin cos 2 x x x =

Put = cos x 0
( ) ( ) =

sin cos 2 sin cos cos 2
1 1

( ), cos sin 2 sin
1
=

since 0
( ) =

2 sin sin 2
1

Now, ( ) =
2 2 sin sin
1
if
2
2
2

4 4
1 ,
2
1
x .

(C)
4 2
1
tan
2
1
tan
1 1

= |
\
|
+
+
+ |
\
|

x
x
x
x

2
1
tan 1 tan
2
1
tan
1 1 1
=
+
+

x
x
x
x

3 2
1
2
1
1
2
1
1
2
1
=
+
+
x
x
x
x
x
x
x

1 2
2
= x
2
1
= x
Both values satisfy the given equation.

(D)
2
tan 1 sin
2 1 2 1

= + +

x x x x

2
1
1
cos 1 sin
2
1 2 1

=
+
+ +

x x
x x

1
1
1
2
2
+
= +
x x
x x
1 , 0 = x
Both values satisfy the given equation.

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can be expressed in terms of three non-coplanar vectors c b a

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