13

th
VXY (Date: 18-12-2011) Review Test-5
PAPER-2
Code-A
ANSWER KEY
CHEMISTRY
SECTION-2
PART-A
Q.1 A
[Only V-Group Batch]
Q.2 C
[Only XY Batch]
Q.2 B
Q.3 B
Q.4 C
Q.5 B
Q.6 A
Q.7 A
Q.8 D
Q.9 C
Q.10 A,B,C,D
Q.11 B,D
Q.12 A,B,C
PART-B
Q.1 (A) Q
(B) R
(C) S
PART-C
Q.1 0055 or 0057
[Only V-Group Batch]
Q.2 5291
[Only XY Batch]
Q.2 2143
Q.3 0006
Q.4 2590
Q.5 0818
PHYSICS
SECTION-1
PART-A
Q.1 A
Q.2 D
Q.3 A
Q.4 C
Q.5 D
Q.6 A or C
Q.7 C
Q.8 A
Q.9 D
Q.10 A,C
Q.11 A,B
Q.12 A,C,D
PART-B
Q.1 (A) P,R,S
(B) Q,S
(C) Q
PART-C
Q.1 0060
Q.2 0030
Q.3 0100
Q.4 0400
Q.5 0006
MATHS
SECTION-3
PART-A
Q.1 C
Q.2 B
Q.3 B
Q.4 B
Q.5 D
Q.6 C
Q.7 B
Q.8 C
Q.9 A
Q.10 B,C,D
Q.11 A,BC,D
Q.12 A,D
PART-B
Q.1 (A) R
(B) S
(C) P
PART-C
Q.1 0007
Q.2 0027
Q.3 0008
Q.4 0066
Q.5 0004
PHYSICS
Code-A Page # 1
PART-A
Q.1
[Sol. Since 'E' in region A doesn't change.
Q + (3Q)
Q
A
Q
Q
Q
Q
:
p.d. also doesn't change. ]
Q.5
[Sol. Lens behaves like a prism. Thus its deviation graph will be that of prism. ]
Q.8
[Sol.
2
1
KT =
2
1
Ie
x
2
e
2
=
I
KT 2
I =
2
KT 2
e
=
25
300 10 38 . 1 2
23


]
Q.11
[Sol. Solid sphere E =
r
R
GM
3
r s R
V =
( )
2 2
3
r R 3
R 2
GM

r s R
Spherical shell E = 0 r < R
V =
R
GM

r s R
M Mass of spherical shell
R Radius of the sphere
r Distance of the point from the centre of spherical shell ]
Q.12
[Sol. (A) T = constant
(C) WD
on

gas
= nRT ln
i
f
P
P
(D) if T = const. ; PV = const. ]
PHYSICS
Code-A Page # 2
PART-C
Q.1
[Sol.
R
380V
t = 4 min.
1
R
220V
t = 20 min.
2
R
180V
t = ?
3
|
|
.
|

\
|

. const
2
1
P
R
V
t
1
=
|
|
.
|

\
|

. const
2
2
P
R
V
t
2
=
|
|
.
|

\
|

. const
2
3
P
R
V
t
3
( ) o
2
1
V t
1
= ( ) o
2
2
V t
2
= ( ) o
2
3
V t
3
) t t ( t V t V
2 1 2
2
2 1
2
1
o =
o =
1 2
1
2
1 2
2
2
t t
t V t V

= 24400
(220
2
24400) 20 = (180
2
24400)t
3
t
3
= 60 min. ]
Q.2
[Sol.
C
q
=
0
C
q Q
q
|
|
.
|

\
| +
0
0
CC
C C
=
0
C
Q
+Q q
(Q q)
C
0
C
+q
q
q

C
q
=
0
C C
Q
+
=
0
0 0
C C
V C
+

10 C
10
+
12 = 3 C = 30 ]
Q.3
[Sol.
kx
70g
40g
T
2
T
1
T
1
T
2
T
1
= 70g + kx ...........(i)
T
2
= 40 g ...........(ii)
T
1
(0.3) = T
2
(0.6) ...........(iii)
70g + kx = 80g
kx = 10 g x = 1m ]
PHYSICS
Code-A Page # 3
Q.4
[Sol. R
0
=
0
0
A

= 100 O ....... (i)
A
0
l
0
= A(2l
0
)
A =
2
A
0
....... (ii)
R =
2 / A
) 2 (
0
0
l
= 400 O ]
Q.5
[Sol.
1
kq
1
+
2
kq
2
+
4
kq
4
= 10 .......... (1)
q
1
q
2
q
3
0
10
40
1
2
4 2
kq
1
+
2
kq
2
+
4
kq
3
= 0 .......... (2)
4
kq
1
+
4
kq
2
+
4
kq
3
= 40 .......... (3)
(1) (2)
2
kq
1
= 10
at r = 1.25 cm
V =
25 . 1
kq
1
+
2
kq
2
+
4
kq
3
=
25 . 1
20
+ (10 20) = 6 V ]
CHEMISTRY
Code-A Page # 1
PART-A
[Only V-Group Batch]
Q.2
[Sol.
HCl
CO
2

erisation dim
]
[Only XY Batch]
Q.2
[Sol.
OH



H

o = 2


~
H

o = 3


~
Et

H
o = 5

H
~

H
o = 6
]
Q.3
[Sol. (A)
S
F
F
F
F
See Saw
Due to the presence of l-p b.p repulson correct, bond angle is not perfectly 180
(B)
S
F
F
Br
Br
Br
(C)
S
Cl
T.B.P. Geometry
Cl
Cl
Cl
Cl
(D) Correct ]
Q.4
[Sol. Let the weight of metal oxide taken be 100
mass of oxygen = 16 mass of metal = 84
Equivalents of oxygen = Equivalents of metal
metal
E
84
8
16
=
E
metal
= 42
Equivalent weight of metal sulphate = Equivalent of metal + Equivalent of sulphate (SO
4
2
)
= 42 +
2
96
= 90 Ans ]
CHEMISTRY
Code-A Page # 2
Q.5
[Sol. Esters which give stable carbocation reacts with
1
AL
A Mech.]
Q.6
[Sol. (A) NCl
3
+ 3H
2
O NH
3
+ 3HOCl
(B) PCl
3
+ 3H
2
O H
3
PO
3
+ 3HCl
(C) AsCl
3
+ 3H
2
O H
3
AsO
3
+ 3HCl
(D) SbCl
3
+ H
2
O (SbO)
+
Cl + 2HCl ]
Paragraph for question nos. 7 to 9
Q.7
[Sol. Melting point o lattice energy o
ions of size
1
]
Q.8
[Sol. Polarization o
cation of size
1
o size of anion ]
Q.10
[Sol. NaOH + Na
2
CO
3
x mg y mg
106
y
40
x
+
= 0.1 17.5
106
y
= 2.5 0.1 = 0.25 y = 26.5 mg
40
x
= 1.75 0.25 = 1.50
x = 60 mg
[NaOH] =
100 40
60

= 0.015 M
[Na
2
CO
3
] =
100 106
5 . 26

=
100
25 . 0
= 0.0025 M ]
CHEMISTRY
Code-A Page # 3
Q.12
[Sol. (A)
O O O
O O
O O
Si Si
(B)
O O O
O O
O O
Cr Cr
(C)
O O O
O O
O O
S
S
(D) or
Si
Si Si
O
O
O
O
O
O O
O O
]
PART-B
Q.1
[Sol. (A)
O O
O
H
CHO
OH
CH
O
O
OH
A
(B)
O O O
O
O O
H
+ + O O
MeO
CHEMISTRY
Code-A Page # 4
(C)
Zn
CH COOMe
2
CH COOMe
2
Br
CH
O
+
PhCHCH COOMe
2
PhCHCH COOH
2
OH OH
H
+
H O
2
| o
A
CH=CHCOOH
]
PART-C
Q.1
[Sol. A + B P
r
1
= Rate = k
1
[A] [B] at T
1
r
2
=
4
] B ][ A [ k
2
r
2
= 2r
1
4
] B ][ A [ k
2
= ] B ][ A [ k 2
1
8
k
k
1
2
=
= 2
3 .... (i)
T
2
= 25 + 3 10 = 55C Ans.
Alternatively
ln (

=
2 1
a
1
2
T
1
T
1
R
E
k
k
ln 2 =
(

308
1
298
1
R
E
a
.... (ii)
when k
2
= 8 k
1
, [from equation (i)]
ln 8 =
(

T
1
298
1
R
E
a
...... (iii)
from equation (ii) and (iii)
3 =
T 10
298 308 T 308
308
10
T
298 T
308
1
298
1
T
1
298
1

=

T (in K) =
) 30 308 (
298 308

= 330.16 K
T = 57.15 C ]
CHEMISTRY
Code-A Page # 5
[Only V-Group Batch]
Q.2
[Sol. (a) +
Cl
3
AlCl 5 H-atoms
(b) +
Cl

2
ZnCl
2 H-atoms
(c) +
3 3
CMe C O C C Me
| | | |
O O

3
AlCl
C
Me
Me
Me
9 H-atoms
(d) +
H
|
Cl C C Me
| | |
O Me

3
AlCl
CCH
Me
Me
O
1 H-atoms ]
[Only XY Batch]
Q.2
[Sol. (a)
O
| |
CH CH CH C CH
2 2 3
=
O H
O
2
3
CH C CH COOH + CO
2 2 2
CH C CH + CO
3 3 2
O
O
| o
A
(2)
(b)
O

O H
O
2
3


O
COOH
O
|
o

A
CO
2
(1)
(c)
O H
O
2
3


O
O
O
HOOC
HOOC
O
|
|
o
o
+ 2CO
2
+ 2CO
2
A
(4)
CHEMISTRY
Code-A Page # 6
(d)
O H
O
2
3


A
HOOC
COOH 4
3
2
1
2CO +
2
O
+ CO
2
(3)
2143 ]
Q.3
[Sol.
Cu
+2
O S O

O
O
O S O

O
O
OH
2
OH
2
H
H
O
H
2
O
H
2
O
Crystalline polymeric structure ]
Q.4
[Sol. MeV 75 . 232 He Y X
4
2
A
Z
238
92
+ +
Y
234
90
Z = 90
AM =
931
75 . 232
100 = 25 Ans. ]
Q.5
[Sol. CH
4
(g) + 2O
2
(g) CO
2
(g) + 2H
2
O(l) 890 ....(i)
2H
2
O (l) 2H
2
O(g) +(402)
____________________________________________
CH
4
(g) + 2O
2
(g) CO
2
(g) + 2H
2
O (g) ....(ii)
AH = 810 kJ/mole
T
10 810
3

= AS =
3
3
10 270
10 810

= 3 J/K
o
) comb (
S A
= 3 (118.5) 2 = 240 J/K mole
AG = AH + TAS = 890 + [300 (240)]/1000 = 818 kJ / mole ]
MATHEMATICS
Code-A Page # 1
PART-A
1. Given, 2b = a + c 2sin B = sin A + sin C 2
|
.
|

\
|
2
B
cos
2
B
sin 2
= |
.
|

\
|
|
.
|

\
| +
2
C A
cos
2
C A
sin 2
2
2
B
sin =
|
.
|

\
|
2
90
cos =
2
1

2
B
sin =
2 2
1

2
B
cos =
8
1
1
=
2 2
7
Hence, sin B = 2 sin
2
B
cos
2
B
=
4
7
Ans.]
2. Given,
k

) x (cos i

a + + =

and ( ) k

x sin 4 3 j

) x (cos i

) x sin x (sin b
2
+ =

Now,
b a

< 0 (sin
2
x sin x) (1 sin
2
x) + (3 4 sin x) < 0

2
1
< sin x < 1 x e |
.
|

\
| t t
2
,
6
Ans.]
3. Let, I =
}
+
+
1
0
2
2
dx
) 2 x ( ) 1 x (
) 2 x ( 2 ) 1 x (
=
} |
|
.
|

\
|
+

1
0
2
dx
) 1 x (
2
2 x
1
=
1
0
1 x
2
| 2 x | n
|
.
|

\
|
+
+ l
= (0 + 1) (ln 2 + 2) = (1 + ln 2) = (ln e + ln 2) = ln(2e). Ans.]
4. Given, a
2
+ b
2
+ c
2
+ d
2
= 25
As, (a b)
2
+ (b c)
2
+ (c d)
2
+ (d a)
2
> 0
2(a
2
+ b
2
+ c
2
+ d
2
) > 2(ab + bc + cd + ad)
ab + bc + cd + da s 25 Ans.]
5. f(x) is decreasing in 2 s x < 0 and increasing in 0 s x < 1. So
f(0

) > f(0)
a > 3. Ans.]
6. To have a non-trivial solution, we must have
k 2 k 1 k
2 k k 1 k
1 k 1 k k
+
+ +
+
= 0 2k + 1 = 0 k =
2
1
.
MATHEMATICS
Code-A Page # 2
Paragraph for question nos. 7 to 9
Sol. Differentiate both sides with respect to x, we get f(x) = x x
2
f(x)
f(x) =
2
x 1
x
+
Also, f '(x) =
2
2
x 1
x 1
+

= 0 x 1
x= 1
x=1 (0,0)
(1, 1/2)
(1, 1/2)
Graph of f(x) =
x
1+x
2
Y
X
Clearly, distance between the local maximum and local minimum of the curve
y = f(x) is
|
.
|

\
|

2
1
2
1
= 1.
Now, verify alternatives. Ans.]
10. Given, f (x) =
( )

=
s < t
o
0 x , 0
1 x 0 , x 2 sin 1 x 2
Note: for o = 0, f (x) is not defined at x =
2
1
e [0, 1] ......(1)
f(x) is continuous at x = 0, 1 but for continuous at x =
2
1
,

|
.
|

\
|
2
1
f =
+
|
.
|

\
|
2
1
f =
|
.
|

\
|
2
1
f
) x 2 ( sin 1 x 2 Lim
2
1
x
t
o

= 0; put x =
2
1
h
h 2 sin ) h 2 ( Lim
0 h
t
o

= 0 o > 0 ......(2)
Hence, (1) (2) o > 0. ]
Note: f (x) is differentiable at x =
2
1
o > 0 and hence differentiable in (0, 1).
11. Given f (x) = sin x
}
t
0
dt ) t ( f + cosx 2 dt ) t ( ' f
2
0
+
}
t
or f(x) = a sin x + b cos x + 2
where a = ( )
}
t
t + = + +
0
2 a 2 dt 2 t cos b t sin a a = 2t
MATHEMATICS
Code-A Page # 3
and b = ( ) dt t sin b t cos a
2
0
}
t
= a b or b =
2
a
= t
f(x) = 2 t sin x t cos x + 2.
Now verify alternatives. ]
12.
(A) b a b a

= +
b a

= 0, hence
b a

= 0 (A) is correct.
(B) Volume of tetrahedron OABC equals
6
1
| | c b a

(B) is incorrect.
(C)
( ) c b a

denotes a vector in the plane of b and a

and perpendicular to c

(C) is incorrect.
(D)
b a

= c a

( ) c b a

= 0 .....(1)
b a

= c a


( ) c b a

= 0 .....(2)
From equation (1) and (2), we get
c b

= 0
Hence
c b

=
(D) is correct. ]
PART-B
1.
(A) AC + CB will be least when B, C and A' are the same line.
Now the line BA' cuts the y-axis at
3
13
= =
(2, 7)
A
x
y
(0,y)
B
(4, 1)
C
O
A'
(2, 7)
(A' is the image of A is y-axis)

q
p
=
3
13
p = 13 and q = 3
p q = 10. Ans.
(B) We have | | 16
1 2 1
1 1 1
1 1 1
c b a
c c c b c a
c b b b b a
c a b a a a
2
2
=

= =

Ans.
(C) Let S = .......
3
14
3
10
3
6
3
2
1
4 3 2
+ + + + + .........(1)
.......
3
10
3
6
3
2
3
1
3
S
4 3 2
+ + + + =
........(2)
MATHEMATICS
Code-A Page # 4
Now, (1) (2) gives,
S
3
1
1
|
.
|

\
|

= ........
3
4
3
4
3
4
3
1
1
4 3 2
+ + + + +
|
.
|

\
|

3
1
1 S = |
.
|

\
|
+ + + + ......
3
1
3
1
1
3
4
3
4
2 2

|
|
|
.
|

\
|

+ =
3
1
1
1
3
4
3
4
S
3
2
2
= 2
3
6
3
2
3
4
2
3
3
4
3
4
2
= = + = + S = 3. Ans.]
PART-C
1. S
k
=
}

1
0
k 2
dx ) x 1 ( x =
}

1
0
k 2
dx x ) x 1 ( =
}
+ +
+
1
0
2 k 1 k k
dx ) x x 2 x ( =
3 k
1
2 k
2
1 k
1
+
+
+

+
Now,

=

n
1 k
k
n
S Lim =


=

=
|
.
|

\
|
+

|
.
|

\
|
+

+
1 k 1 k
3 k
1
2 k
1
2 k
1
1 k
1
=
3
1
2
1

=
6
1
=
q
p
(p + q) = 7. Ans.
2. Let g(x) = 1 + 12 x 3x
2
So, g '(x) = 12 6x = 0 x = 2
Also, f(x) = ( ) | x | g = 1 + 12 | x | 3x
2
global maximum of f (x) at (x = 2 or 2) = 13
(2, 13) (2, 13)
2 2 O
y
x
(5, 14)
Graph of f (x) = 1 + 12 |x| 3x
2
and global minimum of f (x) occurs at x = 5.
Note that f(5) = 61 75 = 14.
Hence difference = 13 ( 14) = 27. Ans.]
3. r = 1 (Given)
r =
s
A
= 1 A = s
60
30
A
B C
r=1
Also, r = (s b) tan
2
B
= s b
1 = s b s = b + 1
A = 1 + b = 1 + 2R (Using b = 2R sin B)
r = 4Rsin
2
A
sin
2
B
sin
2
C
1 = 2 2R |
.
|

\
|
2
1
|
.
|

\
|
2
1
|
|
.
|

\
|

2 2
1 3
2R =
1 3
4

=
( ) 1 3 2 +
A = 1 + 2R = 1 +
( ) 1 3 2 +
=
3 3 2 +
Ans.
MATHEMATICS
Code-A Page # 5
4. F (1) =
}

dx e x
x
= e
x
x e
x
= e
x
(x + 1)
F (2) =
}

dx x e
2 x
= e
x
(x
2
+ 2x + 2)

) 2 ( F
) 1 ( F
=
1 ) 1 x (
) 1 x (
2
+ +
+

}
dx
) 2 ( F
) 1 ( F
=
}
+ +
+
dx
1 ) 1 x (
) 1 x (
2
(x + 1)
2
+ 1 = t (x + 1) dx =
2
1
dt
=
2
1

}
t
dt
=
2
1
ln(t) =
t n l

2
dx
) 2 ( F
) 1 ( F
e
|
|
|
.
|

\
|
}
=
( )
2
t
= t = (x + 1)
2
+ 1
Hence ( )
}
+ +
5
2
2
dx 1 ) 1 x ( =
5
2
x
3
) 1 x (
(

(
+
+
3
= (72 + 5) (9 + 2) = 77 11 = 66 Ans.]
5. Clearly,
5 y 2
3 y
+
+
= 3 (1 cos x)
2
, where x e R
But 0 s (1 cos x)
2
s 4 3
5 y 2
3 y
1 s
+
+
s y e |
.
|

\
|
,
5
12
3
8
,
a =
3
8
and b =
5
12
Hence, (3a 5b) = 3 |
.
|

\
|
3
8

|
.
|

\
|
5
12
5 = 8 + 12 = 4 Ans.]