I.

1 b
2 d
3 b
4 d
5 a
6 a
7 c
8 b
9 d
10 b
11 c
12 c
13 b
14 d
15 d
II.
1 a
2 a
3 a
4 a
5 c
6 c
7 c
8 d
9 c
10 a
11 c
12 c
13 b
14 d
15 d
III.
1.
A. -[(50)(4.186)(29.1-37.9)+(50)(4.186)(29.1-20.9)]/[29.1-20.9]=15.31J/K
B. qrxn=-[(15.31)(.65)+(50)(4.186)(.65)+(50)(4.186)(.65)]=-282.0415
qrxn/n=[-282.0415]/[.01]=-28204.15 J/mol
2. n=(58)[(4.186)(1000)(10)/2877x10^3]=.845g
3.
A. dU=-637522.428 J/mol
-640x10^3=dU-(4-3)(8.314)(298)
dHf=(4)(-92.3)+(1)(-910.9)-(-640.1)=-640 kJ/molK
dS=(4)(186.69+41.84)-[239.3+(2)(130.58)+205]=83.4 J/molK
dG=(-640x10^3)-(298)(83.4)=-664853.2
B. T<-7673.86
4. dH=(2)(2)(799)+(3)(2)(460)-(351)(2)-(414)(6)-(3)(498.7)+40.65=1314.55kJ/mol
5.dH=23.7
dU=nRT+dH=23700+195.9=23895.9
w=-nRT=-(12/60.1)(8.314)(118)=-195.95
q= 23895.9 +195.9=24095
dS=ndH/T=(12/60.1)(23.7x10^3/391)=12.102
dG=(23.7x10^3)-(391)(12.102)=18968.118
6. kroo kroo kroo kroo

7. -31.2kJ
8. ((4.63x10^3)^-1)(x^2-.19x+9.025x10^-3)=.491+x
x=0.04522
NO2=0.095-0.04522=0.0498
N2O4=0.491+0.04522=0.53622
9 kroo kroo kroo kroo
10 kroo kroo kroo kroo
11
a b
b f
c b
d f
e f
f ns
g b
h f
i f