Answer

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ANSWERS, HINTS & SOLUTIONS

CRT(Set-VI)
(Paper-2)

ANSWERS KEY
PHYSICS CHEMISTRY MATHEMATICS
Q. No. ANSWER ANSWER ANSWER
1.
C D C
2.
B C D
3.
B C A
4.
D C D
5.
C D C
6.
D B D
7.
A A B
8.
B C C
9.
A, B, D A, C A, D
10.
A, C, D B, C, D A, C, D
11.
A, B, C, D B, C A, C
12.
B, C A, D A, B, C, D
1.
(A) (q)
(B) (s)
(C) (q)
(D) (p)
(A) (s)
(B) (r)
(C) (q)
(D) (p)
(A) (r), (s)
(B) (s)
(C) (p)
(D) (q)
2.
(A) (p)
(B) (q)
(C) (s)
(D) (p)
(A) (p, t)
(B) (r)
(C) (r, t)
(D) (s)
(A) (p)
(B) (s)
(C) (q)
(D) (r)
1.
4 8 2
2.
2 6 4
3.
1 4 4
4.
2 6 7
5.
2 2 3
6.
4 3 4

A
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L

I
N
D
I
A

T
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S
T

S
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AITS-CRT(Set-VI)-Paper-2-PCM(S)-JEE(Adv)/13
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
2
P Ph hy ys si ic cs s PART I

SECTION A

2.
10 500
i 5mA mA
10 0.1 101
= =
+

G
5mA
5mA
10
0.1 i

5.
|
.
|
\
|

=
0
4
R 15
2 2
A
x R
16
15
R
g
dx
t ;
|
|
.
|
\
|
=
0
2
R 3 2
2
B
x
4
R 3
R
g
dx
t t
A
= t
B
.

7.
dN
N
dt
=

N t
0 0
dN
dt
N
=

Solving

t
N (1 e )
.

8.
( )
R I 2 I.N N =

i 3 i 3

i 2 i. j j
2 2 2 2
( | | | |
( | |
\ . \ .
=
i 3
j
2 2

9. B I, EI
2
,EB
2

10. V
C
= V
E
, V
B
V
A
= 2Brv

12. x = (1)t

SECTION C
2.
1
sin i =
2
sin r

3. apparent depth =
Real depth

5. E = Bl
F = ilB

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3
C Ch he em mi is st tr ry y PART II

SECTION A

6.
Na
+
Na +
2
H +

Fe
2
Fe
+
+
2
Ferrocene
+2

7.
H CH
3
O
OH
O
O
H
+
O
H
O H
Cl
O
O
H
O H

An aldehyde carbonyl group has less steric hindrance to nucleophilic attack and more +
charge on carbonyl carbon.

8.
( ) ( )
( ) ( )
( ) ( )
2
MS s M S ......... I
H S aq H HS ......... II
HS aq H S .......... III
++
+
+
+
+
+
U
U
U

To precipitate out as sulphide (I) reaction equilibrium must goes backward having common in
equilibrium (III) ion (S
--
) in forward direction ( ) ( ) HCl H Cl Major ............ IV
+
+
HCl cause shift back to equilibria (III) backward solubility of
3
Co ,Mn ,Zn ,Ni
+ ++ ++
are large in
comparison to
3
Hg ,Cu ,Cd ,Bi ,Pb
++ ++ ++ + ++

9. Benzene doesnt show unsaturation test.

10. Velocity of electron depends upon value of n.

SECTION-B

1. Since T.E. = KE + PE
2 2 2
Kze Kze Kze
zr zr r
=

4
2. (A)

H
D
Ph
Me
C
OH
O
O
OH
H
D
Ph
Me
H
COOH
H
D
Ph
Me
HOOC
H
Diastereomers

(B)

CH
3
CH
3
D H
H CH
3
O
NaOI
CH
3
CH
3
D H
COO H
Single optically active compound

(C)

CH
3
CH
3
D H
C H CH
2
O
C OH
O
CH
3
CH
3
D H
COOH H

(D) The given compound is a bridge head compound and enol formation doesnt occur.

SECTION C

1.
2 10
6
2 2 0.529 10
1.88 10
r n n
T
V Z Z

= =

3
, T n therefore ratio is 1 : 8

4. Since AX
4
is tetrahedral, therefore, total number of XAX is six.

5.
( )
x 3 3 x
g
FeCl xAgNO xAgCl Fe(NO )
56 35.5x 143.5x g
+ +
+

( )
x x
Wt. of FeCl mol. wt. of FeCl
Wt. of AgCl Mol. wt.of AgCl x unit
=

134.8 56 35.5x
304.8 143.5x
+
=

x = 2

6.
Br
CH
3
C H
3
2 5
/ NaOH C H OH
CH
3
C H
3
Ozonolysis
C H
3
C CH CH
3
CHO O
(A) (B)
(C)

5
M Ma at th he em ma at ti ic cs s PART III

SECTION A
1.
n
r r r r r
j 2
(n 1) terms
1 1 1 1 1
f(r) ..........
j 2 3 4 n
=
| |
= = + + + +
|
\ .

Now
r 2
S f(r)
=
=
=
r r r
r 2 r 2 r 2
1 1 1
.....
2 3 n

= = =
| | | | | |
+ + +
| | |
\ . \ . \ .

=
2 2 2
1 1 1
3 2 n
..........
1 1 1
1 1 1
2 3 n
+ + +

=
( )
(n 1) terms
1 1 1 1
..........
1.2 2.3 3.4 n 1 n
+ + + +

( )
n 1
1
T
n n 1
=
( )
( )
n n 1
n n 1

=
1 1
n 1 n

n = 2; T
2
=
1 1
2 1
+
n = 3; T
2
=
1 1
3 2
+
n = 4; T3 =
1 1
4 3
+
..
..

n 1
1 1
T
n n 1
= +

S =
1
1
n
=
n 1 2012
n 2013
=
So n = 2013

2. E
1
; non unit factor of A is selected
E
2
: non unit factor of B is selected
H : selected factor divides C

1
H 7
P
E 24
| |
=
|
\ .
and
2
H 7
P
E 12
| |
=
|
\ .

1
1 7
E
2 24
P
1 7 1 7
H
.
2 24 2 12
| |
=
|
\ .
+
=
7
7 1
24
21
21 3
24
= =

3. n(S) = 9 35!
n(E) = 7 33! 2
p(E) =
7 33! 2
9 35 34 33!

=
1
9 5 17

M C F

4. The situation for six non derivable points should be like
6

5. 4x
2
+ 2x 1 = 0

2 4 16
,
8
+
= =
2 2 5
8

=
1 5
4

Clearly || < 1 and || < 1 and + =
1
2
, =
1
4

So ( )
r r
r 1
=
+
=
( )
( )
2 3 2 3
..... ..... + + + + + + =
1 1

+

=
( )
( ) ( )
2
1 1 1
+ +
=
+ +
=
1 1
2 2
0
1 1
1
2 4
+
=
+

6.
( )
5 20 15 10 5
4 3 2
f x x x x x 1
f(x)
x x x x 1
+ + + +
=
+ + + +
=
( ) ( ) ( ) ( )
20 15 10 5
5
x 1 x 1 x 1 x 1 5
x 1
x 1
+ + + +
| |
|
\ .

=
( )
20 15 10
5 5 5 5
x 1 x 1 x 1 5
x 1 1
x 1 x 1 x 1 x 1
x 1
(

+ + + +
(

=
( )
4 3 2
5
Q x
x x x x 1
+
+ + + +

7. cos 2x + c sin x = 2c 7
1 2 sin
2
x + c sin x 2c + 7 = 0
2sin
2
x c sin x + 2c 8 = 0
sin x =
( )
2
c c 8 2c 8
4

sin x =
c 4
2
or 2
since sin x 2

c 4
1 1
2

2 c 6
= {2, 3, 4, 5, 6}
For trace 18 diagonal elements has to be 6, 6 and 6 so number of symmetric matrices
= 1 5 5 5 = 125

8.
( )
2
x x x x x
2
P xln a b c d .......... 1000 dx
= + + + + +

=
( ) ( ) ( )
2
x
x x x
2
x ln a b c .......... 1000 dx
+ + + +

=
( )
( )
( )
2
x
x x x x
x
2
a b c d .......... 1000
x ln dx
1000
| |
+ + + + +
|
|
\ .

=
( )
2
x
2
P xln 1000 dx

2P = ln (1000)
2
2
2
x dx

7
2P = ln (1000)
| |
1
16
3

P =
8
ln1000
3
= 8 ln (10)

10. Let f(x) = ax
3
+ bx
2
+ cx + d

2
3 2
x 0
sin x 1
lim
3
ax bx cx d
=
+ + +

for the limit to exist d = 0, c = 0, b = 3 and a can be any real number but a 0
So f(1) = a + b + c + d which can be any real number except 3.

11. Tr(A) = Tr(B) 2

2
+
4
+ 2
2
= 2
2
+
2
2 + 2 1 2
(
2
2 + 1) + (
4
2
2
+ 1) + (
2
+ 2 + 1) = 0
( 1)
2
+ (
2
1)
2
+ ( + 1)
2

= 1, 1, = 1
if = 1, = 1 and = 1

1 2 1
C 1 1 1 1
2 0 1
= =
if = 1, = 1, = 1

1 2 1
C 1 1 1 5
2 0 1
= =

12. For the ellipse
2 2
2 2
x y
1
a b
+ = , a, b I
Equation of director circle x
2
+ y
2
= a
2
+ b
2

a
2
+ b
2
= 25
a = 3 and b = 4 or a = 4, b = 3

2 2
x y
1
9 16
+ =
2 2
x y
1
16 9
+ =
Put y = x Put x = y

12
x y
5
= =
12
x y
5
= =
Equation of tangents Equation of tangents

12x 12 y
1
5.9 5 16
= 9x 16y = 60
16x 9y = 60

SECTION B

1. (A) any point is (t, 1 t)
the chord with this as mid point
y(1 t) 2a(x + t) = (1 t)
2
4at
t
2
2t + (2a
2
2a + 1) = 0
for two distinct chords
4 4.1. (2a
2
2a + 1) > 0 a (0, 1)
lr (0, 4)

(B) ( ) ( ) P 1,0 , Q 4,0
(x 1)(x 4) + y
2
+ y = 0
8
the length of tangent from (0, 0) is 4 2 =
(C) m
1
m
2
= 1
(D) 1 | h | 0 > 1 h 1 < <

2. Let x 2 cos = + and y 2 sin = +
x y 4 sin cos + = + + maximum of (x + y) is 4 2 +
x y cos sin = maximum of x y is 2
f( ) xy 4 2(sin cos ) sin cos = = + + +
f '( ) 2(cos sin ) cos2 0 tan 1 = + = = or 2 sin cos 0 + + = rejected

1
f 4 2 2
4 2
| |
= + +
|
\ .

2
x 2 cos (2 sin )( sin ) (2 cos ) cos
g( ) g'( )
y 2 sin
(2 sin )
+ + +
= = =
+
+

2 2
1
g'( ) 0 2sin sin 2cos cos 0 sin cos
2
= + + + = + =

1
1
cos
4
2 2
| |
=
|
\ .
. Let
1
1
cos
2 2
| |
=
|
\ .

cos
4
| |

|
\ .
7 1
4
= and
7 1
sin
4 4
| |
=
|
\ .

Maximum value of
x
y
is
7 7
7 7
+

4 7
3
+
=

SECTION C

1. Point may lie on the same side of the line or atleast one on the line so
4[a
2
+ 2b(a + b + c) + 4] 0
a
2
+ (2b)a + 2b(b + c) + 4 0
D 0
4b
2
4[2b
2
+ 2bc + 4] 0
b
2
2bc 4 0
b
2
+ 2bc + 4 0
D 0; 4c
2
16 0
c
2
4 0
2 c 2
Max value of c = 2

2.
1
2
M 2
1
= =
for the maximum value of slope in an extreme case that
line should be the tangent to the semi circle with
positive slope.
tangent through (6, 2)
y + 2 = m(x + 6)
y = mx + (6m 2)
for tangent (6m 2)
2
= 25m
2
+ 25
(5, 0)
(6, 2)
m
2

m
1

(5, 0)
11m
2
24m 21 = 0

12 375
m
11
+
=

12 375
m 2,
11
|
+
|
|
.

9
so a = 2, b =
12 375
11
+

[a + b] = 4

3. Let
( )
6
log cosx t =

( ) ( )
1 2 1 2
sin t 1 cos 3t 7
2

+ =
Possible only if
2 2
t 1 3t 7 1 =
Possible t 2 =

( )
6
log cosx 2 =
2
cosx 6 = or
2
6

2
1
cosx
6
=
If x [0, 4] total 4 possible solutions.

4.
( ) ( )
1 1
k 2
2 k
k
0 0
S x 1 x dx 1 x x dx = =

=
( )
1
k k 1 k 2
0
x 2x x dx
+ +
+
=
1 2 1
k 1 k 2 k 3
+
+ + +

Now
n
k
n
k 1 k 1 k 1
1 1 1 1
lim S
k 1 k 2 k 2 k 3

= = =
| | | |
=
| |
\ + + . + + \ .

=
1 1 1 p
2 3 6 q
= =
p + q = 7

5. ax
2
+ bx + c = 0
Quadratic has equal roots b
2
4ac = 0

2 2 2
a c b
cosB
2ac
+
=

2 2
a c 4ac
cosB
2ac
+
=

2 2
a c 4ac
1 1
2ac
+
< <

a c
2 4 2
c a
< + <

a c
2 6
c a
< + <

sinA sinC
2 6
sinC sinA
< + <
So total 3 integers {3, 4, 5}

6.
1 2 1 2
z z z z + = + z
1
, z
2
0 are collinear
z
1
= rz
2
(r > 0)

( )
2
2
a 1 r 1
r 2 4
b r r
+
= = + +

Answer

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