‫بسم ال الرحمن الرحيم‬

Name: ayedzahran

Group:
Day:

Experiment 9
"Stoichiometry of two chemical reaction"
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I. Observations and results:

A. Reaction between HCl and NaOH:

Table 1
ml 1 M HCl ml 1 M NaOH Temperature change
5 45 25-24=1 Cº
10 40 25-23.5=1.5 Cº
15 35 25.5-22.5=2 Cº
20 30 26-23=3 Cº
25 25 27-23=4 Cº
30 20 26-22.5=3.5 Cº
35 15 24-22=2 Cº
40 10 22.5-21.5=1 Cº
45 5 22-21.5=0.5 Cº

B. Reaction between H2SO4 and NaOH

Table 2
ml 1 M H2SO4 ml 1 M NaOH Temperature change
5 20 Cº 30.5-23=7.5
10 20 Cº 10.5=33.5-23
15 20 Cº 9.5=33-23.5
20 20 Cº 9=32-23
25 20 Cº 8=31-23
30 20 Cº 7.5=30.5-23
35 20 Cº 6.5=29.5-23
40 20 Cº 6=29-23
45 20 Cº 5.5=28-22.5
III. Answer the following questions:
1. If a substantial amount of heat is lost to the surroundings, how will this affect
the experimental value of each of Hccal and determined ΔH? Explain your answer
If a substantial amount of heat is lost to the surroundings the equation will
be Qhw=Qcw+Qcal+Qsurrounding , that’s mean the amount of heat of hot water
will goes to cold water, calorimeter and surrounding, but we can't account
the amount of heat of surrounding so that we will consider the equation is
Qhw=Qcw+Qcal , then the ΔH will be less than the actual amount (decrease),
the analyze of equation is :
Spwater *mhwater* (Th-Tf) = Spwater * mcwater * (Tf-Tc) + Hccal* ΔT2 and
Hccal = Spwater *mhwater* (Th-Tf) - Spwater * mcwater * (Tf-Tc) / (Tf-Tc)
= Spwater (mhwater* (Th-Tf) - mcwater* (Tf-Tc))/ (Tf-Tc)
Th , Tc , mhwater , mcwater & Spwater is constant
Tf decrease so that Th-Tf increase & Tf-Tc decrease, so the Hccal will
increase

2. Why is it necessary for all components to be at room temperature at the

beginning at the experiment
Because the temperature is the most part are necessary in this
experiment and when we change any of surroundings at the
beginning or final of experiment (especially temperature) the
numbers of the experiment will change, that’s will happen if the
temperature of room change after starting the experiment

Not: For experiment number, For calculation number, For the solution of
answers.