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WORKSHEET 1
ST
 
EQUILIBRIUM
Drs. HARIYANTO Public Senior High School 3 Malang Jl.Sultan Agung Utara 7 Malang Phone (0341) 324768 e-mail : harry0501light@yahoo.com  blog : http://hariyantobhawikarsu.wordpress.com 
REVERSIBLE REACTION
Based on the products of reaction can or not react to produce the ractants, chemical reaction is classified into reversible and irreversible. What is reversible reaction? Or what is irreversible reaction? Please do the following acticity!
Apparatus and matterial
No Apparatus / material size Quantity
1 Beaker glass 50 mL 2 pieces 2 Graduated cylinder 10 mL 2 pieces 3 Pipets - 2 pieces 4 Stirring rods - 2 pieces 5 Petri dish - 1 pieces 6 Copper(II)sulfate - 2 grams 7 Aqueous Sodium iodide 1 M 20 mL 8 Aqueous Sodium sulfate 1 M 20 mL 9 Wash bottle - 1 10 Aquadest - 50 mL
Procedure
1.
 
Place 1 gram of PbSO
4
 into beaker glass. Pour 10 mL of aqueous NaI 1 M, and drop by pipet into beaker glass and stir this mixture. Observe and write all the changes 2.
 
Decantate that solution from the beaker glass, and wash the precitipation with aquadest. 3.
 
Move a half of precitipation to other beaker glass. Drop carefully the aqueous Na
2
SO
4
 1 M about 10 mL and stir this mixture. Observe the color changes of this precitipation and compare the colors in the both beaker glass and write your observation.
Observation Matterial The changes ie :color)
PbSO
4
 + NaI ……………………………………………………………………………… Precitipation I + Na
2
SO
4
 ………………………………………………………………………………
Questions
The chemical equations of the experiment above are written in the following equations: I. PbSO
4
(aq) + 2 NaI (aq) PbI
2
 (s) + Na
2
SO
4
 (aq) II. PbI
2
 (s) + Na
2
SO
4
 (aq) PbSO
4
(aq) + 2 NaI (aq)
 
No Questions Answers
1 How is the relation between reaction I and II? ………………………………………..
ACTIVITY 1
 
2 Are the products of reaction I react to produce the reactants? ……………………………………….. 3 That reaction is called the reversible reaction, so what is the reversible reaction? ……………………………………….. 4 The opposite of reversible is irreversible, so what is irreversible reaction? ………………………………………..
THE ANALOGY OF DYNAMIC EQUILIBRIUM
Before we define the terms of equilibrium and dynamic equilibrium, please do the following activity.
Apparatus and matterial
No Apparatus/matterial Size Quantity
1 Test tube rack - 1 pieces 2 The test tube 2 pieces (identic) 3 Pipe - 2 pieces (different diameter) 4 The color liquid (KMnO
4
) 10 mL 5 Petri dish - 1 buah
Procedure TUBE A TUBE B
KMnO
4
EMPTY
1.
 
Fill the tube A 10 mL of aqueous KMnO
4
. Place the pipe 1 into the tube A 2.
 
Place the glass pipe 2 into the tube B that is no any solutions. 3.
 
By using the pipe 1 move the solution in the tube A to the tube B. And move the solution in tube B into tube A by using the pipe 2 until the volume of the solutions in the both tubes are constant.
Observation and the analogies.
If the tube A is analogized as reactants, and the tube B is products. The volume of solution is analogized as concentration of substances, complete the following table!
No Experiments Analogy in equilibrium
1
The initial Volume : a.
 
tube A is full of solution b.
 
tube B is no solutions The initial concentration : a.
 
the concentration of reactants : ………………………………………………………………… b.
 
the concentration of
 
- TUBE A AND B ARE IDENTIC - DIAMETER PIPE 1 > PIPE 2
PIPE 2
PIPE 1
ACTIVITY 2
 
products : …………………………………………………………………
2
The Volume of solution when the solution is moved a.
 
The solution in tube A moves to tube B, and in the same time the solution in tube B moves to tube B continuously. b.
 
The Volume of solutios in tube A and tube B 1)
 
The volume of solution in tube A is
decreasing
tube B is
increasing.
 2) When the equilibrium is reached, the volume of solutions in he both tube are constant Concentration of substances when reaction is processing a.
 
The process of reactions i ………………………………………………………………… ………………………………………………………………… b.
 
The concentration of reactant and product : 1) the initial concentration of Reactants………………………………… Products …………………………………… 2)When the equilibrium is reached, concentration of reactants and products are ………………………………………………………………… …………………………………………………………………
Questions
 
No
Questions
 Answers
1
The changes of ractants to products (the forward reaction) or the products to reactants (the reverse reaction), a.
 
Occurs in the same time or not?  b.
 
Occurs continuously or not? c.
 
The rate of the forward reaction and the reverse reaction are equal or not?
……………………………………….. ……………………………………….. ……………………………………….. 2
How is the changes of concentration of reactants or products when the equilibrium is reached?
……………………………………….. ……………………………………….. 3
If the answers of questions no 1, 2, and 3 are the characterictic of the dynamic equilibrium, define the dynamic equilibrium, please!
……………………………………….. 4
The equilibrium reaction symbolized by two directions ( ), please write the equilibrium equation between reactants (R) and Products (P)
………………………………………..
CONCLUSION
Based on the activity 1 and 2, please conclude the definition of reversible reaction, irreversible reaction, equilibrium, and dynamic equilibrium

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