Bi Tp Hirocacbon Bi Tp t Chy Cu 1: Hirocacbon mch h X trong phn t ch cha lin kt

v c hai nguyn t cacbon bc ba trong mt

phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO2 ( cng iu kin nhit ,p sut). Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l A. 4. B. 2. C. 3. D. 5.

Cu 2: t chy hon ton mt hirocacbon X thu c 0,11 mol CO2 v 0,132 mol H2O. Khi X tc dng vi kh clo (theo t l s mol 1:1) thu c mt sn phm hu c duy nht. Tn gi ca X l A. 2-Metylbutan. B. 2-Metylpropan. C. 2,2-imetylpropan. D. etan.

Cu 3: t chy hon ton 3,4g cht hu c A mch h thu c H 2O v CO2 .Hp th hon ton sn phm chy bng nc vi trong d thy khi lng bnh ng dd Ca(OH) 2 tng 14,6g v trong bnh c 25g kt ta .Cng thc phn t ca A l: A.C3H4 B.C5H8 C.C5H10 D.C4H8

Cu 4: t chy hon ton mt lng hirocacbon X. Hp th ton b sn phm chy vo dung dch Ba(OH)2 (d) to ra 29,55 gam kt ta, dung dch sau phn ng c khi lng gim 19,35 gam so vi dung dch Ba(OH)2 ban u. Cng thc phn t ca X l A. C2H6. B. C3H6. C. C3H8. D. C3H4.

Cu 5: t hon ton hn hp 2 hidrocacbon X, Y thuc cng mt dy ng ng (ankan, anken, ankin), hp thu sn phm chy vo 4,5 lit dung dch Ca(OH) 2 0,02M th thu c kt ta, khi lng dung dch tng ln 3,78g. Cho dung dch Ba(OH) 2 d vo dung dch thu c kt ta. Tng kt ca 2 ln nng 18,85g. Bit rng s mol X bng 60% tng s mol X, Y trong hn hp. Xc nh cng thc phn t ca X, Y?. A. C2H4 v C3H6 B. C3H4 v C5H6 C. C2H6 v C3H8 D. C2H2 v C4H6

Cu 6: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Zgp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta A. 40. B. 30 C. 20. D. 10.

Cu 7: Hn hp X gm mt ankan v mt anken c s mol bng nhau, s nguyen t cacbon ca ankan gp 2 ln s nguyn t cacbon ca anken. Ly a gam X th lm mt mu va 100gam dd Br 2 16%. t chy hon ton a gam X ri cho ton b sn phm chy vo dung dch Ca(OH) 2 d thu c 60 gam kt ta. CTPT ca chng l: A. C4H10 v C2H4 B. C2H6 v C4H8 C. C6H14 v C3H6 D. C8H18 v C4H8

Cu 8: t chy hon ton 11,2 lt hn hp kh X gm 2 hirocacbon thuc cng dy ng ng cn 40,32 lt O2 v to ta 26,88 lt CO2. Thm vo 22,4 lt hh X mt hirocacbon Y v t chy hon ton th thu c 60,48 lt CO2 v 50,4 gam H2O. Cc th tch o ktc. CTPT ca Y l: A. C3H6 B. C3H8 C. C4H8 D. C4H10

Cu 9: t chy hon ton mt hh c s mol bng nhau ca 2 hirocacbon c cng s nguyn t C trong phn t thu c 3,52g CO2 v 1,62g H2O .Cng thc phn t ca 2 hirocacbon l: A. C2H4 ,C2H6 B. C3H6, C3H8 C. C3H4, C3H8 D. C4H8 , C4H10

Cu 10: Hn hp X gm 1 ankan v 1 anken c cng s nguyn t cacbon trong phn t v c cng s mol. Bit m gam hh X lm mt mu va 80 gam dung dch Br 2 20%. t chy hon ton m gam hh X thu c 13,44 lt CO2 (ktc). CTPT ca ankan va anken l: A. C2H6 v C2H4 B. C3H8 v C3H6 C. C4H10 v C4H8 D. C5H12 v C5H10 Cu 11: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t ca X l A. C3H4. B. C3H6. C. C4H8. D. C3H8.

Cu 12: Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng khi lng ca CO2 v H2O thu c l A. 18,60 g. B. 18,96 g. C. 20,40 g. D. 16,80 g.

Cu 13: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l A. C2H4. B. CH4. C. C2H6. D. C3H8.

Cu 14: t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c s mol CO2 bng s mol H2O. Thnh phn phn trm v s mol ca X v Y trong hn hp M ln lt l A. 35% v 65%. B. 75% v 25%. C. 20% v 80%. D. 50% v 50%. Cu 15: t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng kh (trongkhng kh, oxi chim 20% th tch), thu c 7,84 lt kh CO2 ( ktc) v 9,9 gam nc. Th tch khng kh( ktc) nh nht cn dng t chy hon ton lng kh thin nhin trn l A. 56,0 lt. B. 78,4 lt. C. 70,0 lt. D. 84,0 lt.

Cu 16: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tchCH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi ca X so vi kh hiro l A. 25,8. B. 12,9. C. 22,2. D. 11,1.

Cu 17: t chy hon ton 4 lt hh 2 hirocacbon A,B thu c 6 lt CO 2 v 6 lt hi H2O (cc th tch o cng iu kin t0, p) .Cng thc phn t ca A,B l: A.CH4;C2H2 B. CH4; C3H4 C. C2H6; C2H2 D. C2H6 ;C4H6

Cu 18: Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H 2 bng 11,25. t chy hon ton 4,48 lt X, thu c 6,72 lt CO2 (cc th tch kh o ktc). Cng thc ca ankan v anken ln lt l A. CH4 v C2H4. B. C2H6 v C2H4. C. CH4 v C3H6. D. CH4 v C4H8. Cu 19: Cho 3,12 gam ankin X phn ng vi 0,1 mol H 2 (xc tc Pd/PbCO3, t0), thu c hn hp Y ch c hai hirocacbon. Cng thc phn t ca X l A. C2H2 B. C5H8 C. C4H6 D. C3H4

Cu 21: X,Y,Z l 3 hirocacbon mch h v u l cht kh iu kin thng .t chy mi kh vi s mol nh nhau s thu c lng nc bng nhau. Trn X vi O 2 2730C, p sut l p ( lng O2 ly gp i lng cn thit t chy ht X ) thu c hh A .t chy hon ton X sau a v 273 0C ,p sut p th tng th tch hh sau p/ gp 1,05 ln th tch hh A. Cng thc ca X,Y,Z l: A.C3H6 , C2H6 , C2H4 C. CH4 , C2H4 , C3H4 Phn ng Cng Cu 22. Hn hp A gm H2 v 2 hircacbon(mt no, mt cha no). Cho A vo bnh kn c niken lm xc tc, un nng bnh mt thi gian thu c hn hp B. Pht biu no sau y ng: A. S mol A - S mol B = s mol H2 tham gia phn ng. B. Tng s mol hircacbon c trong B lun bng tng s mol hircacbon c trong A C. S mol CO2 v H2O to ra khi t chy hon ton A bng s mol CO2 v H2O to ra khi t chy hon ton B D. C A, B, C u ng Cu 23: Trong mt bnh kn cha hn hp kh gm hidrocacbon A v hiro c Ni lm xc tc(th tch khng ng ke). Nung nng bnh mt thi gian thu c mot kh B duy nht. cng nhiet , p sut trong bnh trc khi nung nng gp 3 ln p sut sau khi nung nng. t chy mt lng B thu c 8,8 gam CO2 v 5,4 gam H2O. Cng thc phn t ca X l: A.C2H2 B.C2H4 C. C3H4 D. C4H4 B. C3H6 , C2H6 , C4H6 C. C B v C

Cu 24: un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu c hn hp kh Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d) th cn li0,448lt hn hp kh Z ( ktc) c t khi so vi O2 l 0,5. Khi lng bnh dung dch brom tng l

A. 1,20 gam.

B. 1,04 gam.

C. 1,64 gam

D. 1,32 gam.

Cu 25: un nng hn hp kh X gm 0,02 mol C2H2 v 0,03 mol H2 trong mt bnh kn (xc tc Ni), thu c hn hp kh Y. Cho Y li t t vo bnh nc brom (d), sau khi kt thc cc phn ng, khi lng bnh tng m gam v c 280 ml hn hp kh Z (ktc) thot ra. T khi ca Z so vi H2 l 10,08. Gi tr ca m l A. 0,328. B. 0,620. C. 0,585. D. 0,205.

Cu 26. Hn hp X gm C 2H2 v H2 c cng s mol. Ly mt lng hh X cho qua cht xc tc Ni, nung nng mt thi gian c hh Y gm C 2H4, C2H6, C2H2 v H2 d. Dn Y qua bnh ng dd brom d thy khi lng bnh tng 10,8 gam v thot ra 4,48 lt hh kh Z (ktc) c t khi so vi H 2 bng 8. Th tch O2 (ktc) t chy hon ton hh Y trn l: A. 4,48 lt C. 26,88 lt C. 33,6 lt D. 22,4 lt

Cu 27: Dn V lt ( ktc) hn hp X gm axetilen v hiro i qua ng s ng bt niken nung nng, thu c kh Y. Dn Y vo lng d AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 12 gam kt ta. Kh i ra khi dung dch phn ng va vi 16 gam brom v cn li kh Z. t chy hon ton kh Z thu c 2,24 lt kh CO2 ( ktc) v 4,5 gam nc. Gi tr ca V bng A. 11,2. B. 13,44. C. 8,96. D. 5,60.

Cu 28:Trong bnh kn cha 1 mol hh kh X gm H2, C2H4, C3H6 v 1 t bt xc tc. un nng bnh mt thi gian thu c hh Y. T khi i vi H2 ca X l 7,6 v ca Y l 8,455. Tnh s mol H2 p/ ? A. 0,05 B. 0,08 C. 0,1 D. 0,12

Cu 30. Hn hp kh A cha eilen v hiro. T khi ca A i vi hiro l 7,5. Dn A i qua cht xuc tc Ni nung nng th thu c hh kh B c t khi i vi hiro l 9,0. Hiu sut phn ng cng hiro ca etilen l: A. 33,3% B. 66,7% C. 25% D. 50%

Cu 31: Hn hp X gm 0,15 mol metan , 0,09 mol axetilen , 0,2 mol hiro . Nung nng hh X vi xt Ni thu c hh Y .cho Y qua dd Brom d thy khi lng bnh ng nc Br 2 tng 0,82g v thot ra hh kh A .t khi hi ca A so vi H2 l 8 . s mol mi cht trong hh A l: A . 0,15;0,06 ;0,06 B.0,15 ; 0,07; 0,05 C. 0,15; 0,08 ; 0,09 D. 0,12 ; 0,1 ; 0,06

Cu 32. Hn hp X gm mt anken A, mt ankan B v H 2. Ly 392 ml hh X cho i qua ng cha Ni nung nng. Kh i ra khi ng chim th tch 280 ml v ch gm 2 ankan. T khi ca hn hp ny so vi khng kh bng 1,228. Cc th tch khi o cng iu kin. CTPT ca A v B l: A. C2H4 v CH4 B. C3H6 v C2H6 C. C3H6 v CH4 D. C4H8 v C3H8

Cu 33. un nng m gam hn hp X gm C2H2, C2H4 v H2 vi xc tc Ni n phn ng xy ra hon ton, thu c 8,96 lt (ktc) hn hp Y (c t khi so vi hir bng 8). t chy hon ton cng lng hn hp X trn, ri cho sn phm chy hp th hon ton trong dung dch nc vi trong d th khi lng kt ta thu c l A. 20 gam B. 40 gam C. 30 gam D. 50 gam

Cu 34. Ho tan ht hn hp rn gm CaC 2, Al4C3 v Ca vo H2O thu c 3,36 lt hn hp kh X c t khi so vi hiro bng 10. Dn X qua Ni un nng thu c hn hp kh Y. Tip tc cho Y qua bnh ng nc brom d th c 0,784 lt hn hp kh Z (t khi hi so vi He bng 6,5). Cc kh o iu kin tiu chun. Khi lng bnh brom tng l A. 2,09 gam B. 3,45gam C. 3,91 gam D. 1,35 gam

Cu 35. (H 2009-KB) Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht.T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thuc hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cuto ca anken l A. CH2 =C(CH3)2. B. CH2 =CH2 . C. CH2=CH-CH2-CH3. D. CH3-CH=CH-CH3

Cu 36. Hn hp X gm mt hirocacbon th kh v H 2 (t khi hi ca X so vi H2 bng 4,8). Cho X i qua Ni un nng n phn ng hon ton thu c hn hp Y (t khi hi ca Y so vi CH 4 bng 1). CTPT ca hirocacbon l A. C2H2 B. C3H6 C. C3H4 D. C2H4

Cu 37: Cho 6,72 lt (ktc) hn hp kh X gm C2H4, C3H4 li t t qua b.nh ng dung dch Br2 d, sau phn ng thy khi lng b.nh tng 10,8 gam. Thnh phn phn trm v th tch ca C2H4 v C3H4 trong hn hp X ln lt l A. 33,3% v 66,7%. B. 20,8% v 79,2%. C. 25,0% v 75,0%. D. 30,0% v 70,0%. Cu 38: Cho 0,74 gam hn hp X gm CH4 v anken X qua b.nh cha dung dch Br2 d. Sau phn ng thy khi lng b.nh ng dung dch brom tng 0,42 gam v th tch thot ra khi b.nh gim 1/3 so vi th tch hn hp X ban u. X c s ng phn cu to l A. 2. B. 1. C. 3. D. 4. Cu 39: Dn hn hp X gm CnH2n v H2 (c s mol bng nhau) qua Ni nung nng thu c hn hp Y. T khi hi ca Y so vi X l 1,6. Hiu sut ca phn ng l A. 40%. B. 60%. C. 65%. D. 75%. Cu 40: Trong b.nh kn cha hn hp kh X gm C2H4 v H2 vi lng nh bt Ni (cht rn chim th tch khn ng k). T khi ca X so vi H2 bng 6,2. un nng b.nh mt thi gian thu c hn hp kh Y c t khi hi so vi H2 bng 8. Hiu sut ca phn ng hiro ho C2H4 l A. 62,50%. B. 56,25%. C. 43,75%. D. 37,50%. Cu 41: Hn hp X gm mt anken v hiro c t khi so vi H2 bng 6,4. Cho X i qua bt Ni nung nng c hn hp Y c t khi so vi H2 bng 8 (gi thit cc phn ng xy ra hon ton). Cng thc phn t ca anken l A. C3H4. B. C3H6. C. C4H8. D. C5H10.

Cu 42: T khi hi ca hn hp X (gm 2 hirocacbon mch h) so vi H2 l 11,25. Dn 1,792 lt X (ktc) i tht chm qua b.nh ng dung dch brom d, sau phn ng thy khi lng b.nh tng 0,84 gam. Hai hirocacbon c trong X ln lt l A. CH4 v C3H4. B. CH4 v C3H6. C. C2H4 v C3H6. D. C2H6 v C3H4. Cu 43: Hn hp kh X gm mt ankin v H2 c t khi so vi CH4 l 0,5. Nung nng hn hp X c xc tc Ni phn ng xy ra hon ton, thu c hn hp kh Y c t khi hi so vi CH4 l 1. Cho hn hp Y qua dung dch brom d th. khi lng b.nh cha dung dch brom tng ln bao nhiu gam? A. 0 gam. B. 8 gam. C. 16 gam. D. 24 gam.

Cu 44: Cho hn hp X gm 0,2 mol axetilen v 0,35 mol H2 vo b.nh kn c xc tc Ni nung nng. Sau mt thi gian thu c hn hp Y gm 4 kh. Khi cho Y li qua dung dch brom d thy c 4,48 lt (ktc) kh Z bay ra. T khi ca Z so vi H2 l 4,5. tng khi lng ca b.nh brom l A. 5,2 gam. B. 2,05 gam. C. 5,0 gam. D. 4,1 gam. Cu 45: un nng 5,14 gam hn hp kh X gm metan, hiro v mt ankin vi xc tc Ni, thu c hn hp kh Y. Cho hn hp Y tc dng vi dung dch brom d thu c 6,048 lt hn hp kh Z (ktc) c t khi i vi hiro bng 8. tng khi lng dung dch brom l A. 0,82 gam. B. 1,62 gam. C. 4,6 gam. D. 2,98 gam.

Cu 46 (C - 2009): Hn hp kh X gm 0,3 mol H2 v 0,1 mol vinylaxetilen. Nung X mt thi gian vi xc tc Ni thu c hn hp kh Y c t khi so vi khng kh l 1. Nu cho ton b Y sc t t vo dung dch brom (d) th. c m gam brom tham gia phn ng. Gi tr ca m l A. 16,0. B. 3,2. C. 8,0. D. 32,0.