i. Phn ng oxi ha kh v nh lut bo ton electron. Cu 1.

Ho tan hon ton hn hp gm 0,05 mol Ag v 0,03 mol Cu vo dung dch HNO 3 thu c hn hp kh A gm NO v NO ! c" t# l$ %& mol t'ng (ng l ! ) 3* +h, t ch hn hp A ktc l) A* .,3/0 l t* 1* !,232 l t* C* !,!!3 l t* 4* 3,3232 l t* Cu 2. +56n 0,53 g 76t nh8m v9: 76t ;< !O3 v CuO 5: t:=n hnh ph>n (ng nh:$t nh8m thu c hn hp A* Ho tan hon ton A t5ong dung dch HNO 3 c hn hp kh gm NO v NO! c" t# l$ %& mol t'ng (ng l . ) 3* +h, t ch ?ktc@ kh NO v NO! lAn lt l) A* 0,!!3 l t v 0,/2! l t* 1* 0,/2! l t v 0,!!3 l t* C* !,!3 l t v /,2! l t* 4* /,2! l t v !,!3 l t* Cu 3* Ho tan hon ton m6t lng 76t %Bt vo dung dch HNO 3 loCng thu c hn hp kh gm 0,0.5 mol N!O v 0,0. mol NO* Dng %Bt C ho tan l) A* 0,5/g 1* 0,03g C* !,0g 4* .,3g Cu 4: 4En chFm G l t ?ktc@ hn hp ha: kh H! v CO Hua &ng %( Ing !0,0 gam hn hp gm 7a oJ:t l CuO, KgO v ;<!O3, un n"ng, ph>n (ng J>L 5a hon ton* Hn hp kh , h': thoMt 5a kh8ng cNn H! cOng nh CO v hn hp kh h': nL c" kh&: lng nh:Pu h'n kh&: lng G l t hn hp ha: kh H !, CO lQc Au l 3,/3 gam* +5ong &ng %( cNn ch(a m gam hn hp cMc chRt 5Bn* +5 %& cSa G l) A. 5,/00 l t B. !,T.! l t C. /,3T/ l t D. 3,503 l t Cu 5) Cho cMc ph>n (ng) a* Kg U HCl KgCl! U H! 7* CuO U HCl CuCl! U H!O c* KnO! U HCl KnCl! U Cl! U H!O d* KnCl! U HCl U H!VO3 KnVO3 U Cl! U H!O X Won Cl ch# "ng va: t5N l chRt khY t5ong ph>n (ng) A. a, c B. 7, a C. d D. c, d Cu 6: +5ong cMc ph>n (ng phZn hSL d9: ZL, ph>n (ng no kh8ng ph>: l ph>n (ng oJ: hoM khY A. 1* C* 4* Cu 7) [hMt 7:,u no d9: ZL kh8ng Qng\ A. [h>n (ng oJ: hoM X khY l ph>n (ng lu8n J>L 5a ng th]: %I oJ: hoM v %I khY* B. [h>n (ng oJ: hoM X khY l ph>n (ng t5ong " c" %I thaL ^: %& oJ: hoM cSa tRt c> cMc nguL_n t&* C. [h>n (ng oJ: hoM X khY l ph>n (ng t5ong " J>L 5a %I t5ao ^: <l<ct5on g:`a cMc chRt*
.

D. [h>n (ng oJ: hoM X khY l ph>n (ng t5ong " c" %I thaL ^: %& oJ: hoM cSa m6t %& nguL_n t& Cu 8) Cho .,35 gam hn hp gm Cu, Kg, Al tMc dang v9: dung dch HNO 3 d, thu c .,.! l t ?ktc@ hn hp kh NO v NO! c" t# kh&: %o v9: h:5o 7bng !0* +^ng kh&: lng mu&: n:t5at %:nh 5a l) A. //,25 gam B. 33, 35 gam C. /,225 gam D. 3, 335 gam Cu 9) Cho %' ph>n (ng ) * H$ %& cZn 7bng cSa cMc chRt ph>n (ng v %>n phcm lAn lt l) A. /, !!, 3, 3, .0, .3 B. 3, 3, /, 0, .!, ./ C. !, .0, ., ., .0, 3 D. 5, 2, .!, T, ./, !0 Cu 10) Cho 0,T/ gam Cu tMc dang v9: HNO 3 d, thu c 0,!!3 l t ?ktc@ kh d duL nhRt ?kh8ng c" %>n phcm khY khMc@* d ch# c" th, l) A. B. C. D. Cu 11: e, hNa tan 3 gam oJ:t ;< JOL cAn 5!,.3 ml dung dch HCl .0f ?d g .,05ghml@* C8ng th(c phZn tY cSa oJ:t %Bt l) A. FeO B. Fe2O3 C. Fe3O4 Cu 12:* [h>n (ng tI oJ: hoM, tI khY l) A* NH3NO3 N!O U !H!O C* Cl! U !NaOH NaCl U NaClO 3W! U 3H!O HWO3 U 5HW ?.@ 3i!VO3 3i!VO3 U i!V ?3@ !iClO3 !iCl U 3O! ?5@ 3HClO3 !Cl! U 2O! U !H!O ?2@ 1* !Al?NO3@3 Al!O3 U /NO! U 3h!O! 4* !iKnO3 i!KnO3 U KnO! U O! HgO !Hg U O! ?!@ NH3NO3 N!O U !H!O !H!O! !H!O U O! ?3@ ?0@ 3NO! U H!O !HNO3 U NO?/@

Cu 13) Cho cMc ph>n (ng oJ: hoMX khY %au)

+5ong %& cMc ph>n (ng oJ: hoMX khY t5_n, %& ph>n (ng oJ: hoMX khY n6: phZn tY l A* 2 B. 3 C. 4 D. 5 Cu 14: CMc chRt no %au ZL Pu tMc dang v9: dung dch ;<?NO3@3\ A* Kg, ;<, Cu* 1* Al, ;<, Ag *C* N:, jn, ;<4* C> A v C Pu Qng* CZu .5) +5ong ph>n (ng) 3NO! U H!O !HNO3 U NO* ih NO! "ng va: t5N no %au ZL\ A* ChRt oJ: hoM* C* D chRt oJ: hoM nhng ng th]: cOng l chRt khY* 4* ih8ng l chRt oJ: hoM cOng kh8ng l chRt khY*
!

1* ChRt khY*

CZu ./) ih: cho jn vo dung dch HNO 3 thu c hn hp kh A gm N!O v N! kh: ph>n (ng k=t thQc cho th_m NaOH vo lk: thRL g:>: ph"ng kh 1, hn hp kh 1 " l) A* H!, NO! * 1* H!, NH3* C* N!, N!O* 4* NO, NO! Cu 17)* Ho tan hon ton m gam ;< JOL 7bng dung dch H!VO3 lc n"ng thu c kh A v dung dch 1* Cho kh A hRp tha hon ton 7-: dung dch NaOH d tko 5a .!,/ gam mu&:* Klt khMc, c8 ckn dung dch 1 thm thu c .!0 gam mu&: khan* C8ng th(c cSa %Bt oJ:t ;< JOL l) A* ;<O 1* ;<3O3 C* ;<!O3 4* +Rt c> Pu %a: Cu 18* Cho iW tMc dang v9: iKnO3 t5ong m8: t5]ng H!VO3, ng]: ta thu c .,5.g KnVO3 th<o ph'ng t5mnh ph>n (ng %au) .0iW U !iKnO3 U 0H!VO3 /i!VO3 U 5W! U !KnVO3 U 0 H!O V& mol :ot tko thnh v iW tham g:a ph>n (ng t5_n l) A*0,000!5 v 0,0005 1*0,0!5 v 0,05* C*0,!5 v 0,50* 4*0,00!5v 0,005 Cu 19 ) * HCL chnn ph'ng Mn Qng* [h>n (ng oJ: hoM X khY J>L 5a haL kh8ng t5ong cMc t5]ng hp %au ZL\ eng c" th, tMc dang v9: ) A* dung dch mu&: %Bt WW tko thnh mu&: ng WW v g:>: ph"ng %Bt* 1* dung dch mu&: %Bt WWW tko thnh mu&: ng WW v g:>: ph"ng %Bt* C* dung dch mu&: %Bt WWW tko thnh mu&: ng WW v mu&: %Bt WW* 4* kh8ng th, tMc dang v9: dung dch mu&: %Bt WWW* Cu 20: HNa tan hon ton !,3g k:m lok: Kg vo dung dch HNO 3 loCng, g:> %Y ch# thu c G l t kh N ! duL nhRt ?ktc@* o:M t5 cSa G l A* 0,/2! l t 1*/,2!l t C*0,330 l t 4*3,30 l t Cu 21: Cho %' ph>n (ng);<3O3 U HNO3 ;<?NO3@3 U NO U H!O Vau kh: cZn 7bng, h$ %& cSa phZn tY cMc chRt l ph'ng Mn no %au ZL\ A* 3, .3, T, ., 2 C* 3, !/, T, !, .3 A* ;<Cl3 1* CuCl! 1* 3, !0, T, ., .3 4* !, !0, /, ., .3 C* jnCl! 4* ;<VO3

Cu 22; +5ong m8: t5]ng H!VO3, dung dch no lm mRt mu iKnO3\ Cu 23: p ph>n (ng no %au ZL, H!O khng "ng va: t5N chRt oJ: hoM haL chRt khY\ A* NaH U H!O NaOH U H! 1* !Na U !H!O !NaOH U H! C* !;! U !H!O 3H; U O! 4* Al3C3 U .!H!O 3Al?OH@3 U 3CH3
3

Cu 24: Cho ph'ng t5mnh nh:$t hoM hnc

1 1 tocao I 2 + H2 HWq 2 2

H g X!/,52 kr

Hs: lng nh:$t to> 5a l 7ao nh:_u kh: cho 0,5 mol phZn tY :ot tMc dang hon ton v9: h:5o\ A* !/,52 kr C* !/,25 kr 1* !2,/5 kr 4* 53,.3 kr

Cu 25) e, m gam pho: 7o %Bt ?A@ ngo: kh8ng kh , %au m6t th]: g:an 7:=n thnh hn hp ?B@ c" kh&: lng .! gam gm %Bt v cMc oJ:t ;<O, ;< 3O3, ;<!O3* cho 1 tMc dang hon ton v9: dung dch HNO3 thRL g:>: ph"ng 5a !,!3 l t kh NO duL nhRt ? ktc@*ih&: lng t nh th<o gam cSa m l) A* ..,0* 1* .0,0 C* T,0 4* 0,0 Cu 26* Cho .,33g hn hp gm k:m lok: K v oJ:t cSa n" KO, c" %& mol 7bng nhau, tMc dang h=t v9: H!VO3 lc, un n"ng* +h, t ch kh VO !?ktc@ thu c l 0,!!3l:t* Cho 7:=t 5bng hoM t5 l9n nhRt cSa K l WW* +mm k:m lok: K* Cu 27) NhQng . thanh nh8m nlng 50g vo 300ml dung dch CuVO 3 0,5K* Vau m6t th]: g:an lRL thanh nh8m 5a cZn nlng 5.,30g* Hs: kh&: lng Cu thoMt 5a l 7ao nh:_u\ A. 0,64g B. 1,28g C. 1,92g D. Cu 28: HNa tan 3,5Tg Al 7bng dung dch HNO3 thu c hn hp kh NO v N!O c" t# kh&: h': &: v9: h:5o 7bng ./,25* +h, t ch NO v N!O thu c - ktc l) A* !,!3 l t v /,2! l t* 1* !,0./ l t v 0,/2! l t* C. 0,672 l !" 2,016 l . D. 1,972 l !" 0,448 l . Cu 29) Ho tan hon ton m gam ;< 3O3 vo dung dch HNO3 loCng d, tRt c> lng kh NO thu c <m oJ: hoM thnh NO ! 5: %ac vo n9c ctng dNng kh O ! , chuL,n h=t thnh HNO3* Cho 7:=t th, t ch kh oJ: ?ktc@ C tham g:a HuM t5mnh t5_n l 3,3/ l:t* ih&: lng m cSa ;<3O3 l g:M t5 no %au ZL\ A* .3T,! gam* 1* .3,T! gam* C* .,3T! gam* 4* .3T! gam* Cu 30* Ho tan 2,0g hn hp 76t Al v Kg t5ong dung dch HCl d* Vau ph>n (ng kh&: lng dung dch aJ:t tung th_m 2,0g* ih&: lng nh8m v mag:< t5ong hn hp Au l) A* !,2g v .,!g 1* 5,3g v !,3g C* 5,0g v 3,/g 4* .,!g v !,3

B"# $% & lu$n

1. Cho ag hn hp A gm ;<O, CuO, ;< 3O3 ?c" %& mol 7bng nhau@ tMc dang vva S v9: !50ml dung dch HNO3 thu c dung dch 1 v 3,.3/ l:t hn hp NO ! v NO c" t# kh&: %o v9: h:5o l !0,.33* + nh a v CK cSa HNO3* 2. HNa tan h=t 3,33.g hn hp Al v Kg t5ong HNO 3 loCng thu c dung dch A v .,5/0l:t ?ktc@ hn hp ha: kh ?Pu kh8ng mu@ c" kh&: lng !,5Tg, t5ong " m6t kh 7 h"a nZu t5ong kh8ng kh * .*+ nh thnh phAn f vP th, t ch m: kh t5ong hn hp* !* + nh %& mol HNO3 C tham g:a ph>n (ng* 3* C8 ckn dung dch A thu c 7ao nh:_u gam mu&: khan\ 3* +h:=t lFp cMc ph'ng t5mnh ph>n (ng oJ: h"a X khY %au th<o ph'ng phMp thung 7bng <l<ct5on) [h>n (ng oJ: h"a X khY lok: kh8ng c" m8: t5]ng .@ H15 U H!VO3 lc* n"ng 15! U VO! U H!O !@ Cl! U VO! U H!O HCl U H!VO3
0

3@ C U H!VO3
o

t
0

CO! U VO! U H!O

t , Pt 3@ NH3 U O! N!O U H!O

5@ ;<3O3 U Al

t
0

Al!O3 U ;<

/@ CuO U H!

Cu U H!O

2@ NO! U O! U H!O HNO3 0@ O3 U iW U H!O O! U W! U iOH T@ H!V U Cl! U H!O H!VO3 U HCl .0@ H!O! U [7V [7?VO3@ U H!O ..@ Kg U HCl KgCl! U H! G:=t cMc ph'ng t5mnh ph>n (ng oJ: h"a X khY %au th<o ph'ng phMp thung 7bng <l<ct5on) .@ H!V U VO! *** U H!O !@ Al U HNO3 ?loCng@ *** U NO U H!O 3@ VO! U H!O U 15! H!VO3 U ***
5

3@ ;<VO3 U HNO3 *** U NO! U *** 5@ V U H!VO3 *** U H!O /@iKnO3 U i!VO3 U iOH i!VO3 U *** U*** 4. 4En ha: lung kh Cl! : Hua ha: dung dch ?.@ iOH loCng v ngu6:q dung dch ?!@ iOH lc v un n"ng* G:=t v cZn 7bng ph'ng t5mnh ph>n (ng oJ: h"a khY* N=u lng mu&: iCl %:nh 5a t5ong ha: dung dch 7bng nhau thm tw l$ th, t ch clo : Hua ha: dung dch iOH ?.@ v ?!@ 7bng 7ao nh:_u\ 5: Trn 0.81 gam bt nhm vi Fe 2O3 v CuO r i !"t n#ng !$ ti%n hnh &h'n (ng nhi)t nhm thu !c h*n h+& ,. H-a tan hon ton , trong .ung ./ch H0O3 !un n#ng thu !c 1 23t 4h3 0O 5 6'n &h7m 4h8 .u9 nh:t ; < !4tc. T3nh th$ t3ch 1= Bi 1 : H-a tan 1> gam h*n h+& ? g m hai 4im 2o@i Ag v ,2 vo .ung ./ch B g m H0O3 v H2COD !Ec thu !c 0.1 mo2 m*i 4h3 CO 2F 0OF 0O2F 02O. T3nh &hGn trHm 4h"i 2+ng cIa ,2 v Ag trong ?= !: Trn J0 gam bt Fe vi 30 gam bt 2u huKnh r i !un n#ng 5 4hng c# 4hng 4h3 ; thu !+c ch:t rLn ,. H-a tan , bMng .ung ./ch aNit HCO . !+c .ung ./ch P v 4h3 C. Q" chR9 C cGn 1 23t O 2 5 !4tc ;. Pi%t cRc &h'n (ng N'9 ra hon ton. T3nh giR tr/ 1= ": H-a tan hon ton 12 gam h*n h+& FeF Cu 5 tS 2) mo2 1T1 ; bMng aNit H0O3F thu !c 1 23t 5 < !4tc; h*n h+& 4h3 ? 5 g m 0O v 0O 2 ; v .ung ./ch B 5 chS ch(a 2 mu"i v aNit . ;. TS 4h"i ? !"i vi H2 bMng 1U. T3nh giR tr/ cIa 1= #T H*n h+& ? g m 2 4im 2o@i , v P !(ng trc H trong .V9 !i)n h#a v c# h#a tr/ 4hng !Wi trong cRc h+& ch:t. Chia m gam ? thnh 2 &hGn bMng nhauT XYhGn 1T H-a tan hon ton trong .ung ./ch ch(a aNit HC2 v H 2COD 2oVng t@o ra 3.3J 23t 4h3 H2. XYhGn 2T TRc .Zng hon ton vi .ung ./ch H0O3 thu !c 1 23t 4h3 0O 5 6'n &h7m 4h8 .u9 nh:t ;= Pi%t cRc th$ t3ch 4h3 !o < Q[TC. T3nh giR tr/ cIa 1=