REAKSI

REAKSI-REAKSI TRIGLISERIDA

NAMA NIM HARI/TANGGAL KELOMPOK ASISTEN

: MASHYTA DWI PRATIWI : H311 11 258 : KAMIS / 14 MARET 2013 : II (DUA) : ARKIEMAH HAMDA

LABORATORIUM BIOKIMIA JURUSAN KIMIA FAKULTAS MATEMATIKA DAN ILMU PENGETAHUAN ALAM UNIVERSITAS HASANUDDIN MAKASSAR 2013

Reaksi 1. Tes Akrolein a. Lilin

O CH3 (CH2)14 C OCH2 (CH2)14 CH3 + KHSO4

b. Gliserol

H2C

HC OH H2C OH

KHSO4

CH + 2H2O
CH CH2

akrolein
c. Minyak Kelapa Kopra
O

CH2

C O

(CH2)16

CH3

CH2

OH O

CH

C O

(CH2)16

CH3

KHSO4

CH

OH

3 C9H18=C8H15

OH

CH2

(CH2)16

CH3

CH2

OH

CH2
CH CH O

2 H2O

Akrolein

d. Minyak Wijen
O H2C O C O HC H2C O O C O C (CH 2)16CH 3 (CH 2)16CH 3 (CH 2)16CH 3

KHSO 4

H2C

OH O O OH H 2C CH C H

HC

OH

3C9H18

C8H15 C

2H2O

H2C

OH

Akrolein

e. Minyak Sawit Mentah

O H2C O C O HC H2C O O C O C (CH 2)16CH 3 (CH 2)16CH 3 (CH 2)16CH 3

KHSO 4

H2C

OH O O OH H 2C CH C H

HC

OH

3C9H18

C8H15 C

2H2O

H2C

OH

Akrolein

f. Mentega
O H2C O C O HC H2C O O C O C (CH 2)16CH 3 (CH 2)16CH 3 (CH 2)16CH 3

KHSO 4

H2C

OH O O OH H 2C CH C H

HC

OH

3C9H18

C8H15 C

2H2O

H2C

OH

Akrolein

g. Minyak VCO
O H2C O C O HC H2C O O C O C (CH 2)16CH 3 (CH 2)16CH 3 (CH 2)16CH 3

KHSO 4

H2C

OH O O OH H 2C CH C H

HC

OH

3C9H18

C8H15 C

2H2O

H2C

OH

Akrolein

h. Minyak Kemiri
O H2C O C O HC H2C O O C O C (CH 2)16CH 3 (CH 2)16CH 3 (CH 2)16CH 3

KHSO 4

H2C

OH O O OH H 2C CH C H

HC

OH

3C9H18

C8H15 C

2H2O

H2C

OH

Akrolein

2. Tes Kolorimetri a. Lilin

O

H3C

(CH2)14

OCH2

(CH2)14

CH3

+ NaOCl

ONa

OH

H3C

(CH2)14

C OCl

OCH2

(CH2)14

CH3

b. Gliserol
H2C OH H2C ONa

HC

OH

3NaOCl

HC

ONa

3HOCl

H2C

OH

H2C

ONa

H2C HCl p HC

OH H2SO 4

H2C

OH

3NaCl

HC

OH
H2C 3 O

3H2O

H2C

OH

c. Minyak Kelapa Kopra

O H 2C O C O HC H2C O O C O C (CH 2)16CH 3 (CH 2)16CH 3 (CH 2)16CH 3 H2C ONa O

3NaOCl

HC

ONa

3C9H18

C8H15 C

OCl

H2C

ONa

H2C HCl p HC

OH H2SO 4

H2C

OH

3NaCl

HC

OH
H2C 3 O

3H2O

H 2C

OH

d. Minyak Wijen
O H 2C O C O HC H2C O O C O C (CH 2)16CH 3 (CH 2)16CH 3 (CH 2)16CH 3 H2C ONa O

3NaOCl

HC

ONa

3C9H18

C8H15 C

OCl

H2C

ONa

H2C HCl p HC

OH H2SO 4

H2C

OH

3NaCl

HC

OH
H2C 3 O

3H2O

H 2C

OH

e. Minyak Sawit Mentah

O H 2C O C O HC H2C O O C O C (CH 2)16CH 3 (CH 2)16CH 3 (CH 2)16CH 3 H2C ONa O

3NaOCl

HC

ONa

3C9H18

C8H15 C

OCl

H2C

ONa

H2C HCl p HC

OH H2SO 4

H2C

OH

3NaCl

HC

OH
H2C 3 O

3H2O

H 2C

OH

f. Mentega
O H 2C O C O HC H2C O O C O C (CH 2)16CH 3 (CH 2)16CH 3 (CH 2)16CH 3 H2C ONa O

3NaOCl

HC

ONa

3C9H18

C8H15

OCl

H2C

ONa

H2C HCl p HC

OH H2SO 4

H2C

OH

3NaCl

HC

OH
H2C 3 O

3H2O

H 2C

OH

g. Minyak VCO
O H 2C O C O HC H2C O O C O C (CH 2)16CH 3 (CH 2)16CH 3 (CH 2)16CH 3 H2C ONa O

3NaOCl

HC

ONa

3C9H18

C8H15 C

OCl

H2C

ONa

H2C HCl p HC

OH H2SO 4

H2C

OH

3NaCl

HC

OH
H2C 3 O

3H2O

H 2C

OH

h. Minyak Kemiri
O H 2C O C O HC H2C O O C O C (CH 2)16CH 3 (CH 2)16CH 3 (CH 2)16CH 3 H2C ONa O

3NaOCl

HC

ONa

3C9H18

C8H15 C

OCl

H2C

ONa

H2C HCl p HC

OH H2SO 4

H2C

OH

3NaCl

HC

OH
H2C 3 O

3H2O

H 2C

OH

i. Blanko
OH

H2O

NaOCl

H2O