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PHOTOACOUSTIC AND PHOTOTHERMAL SPECTROMETERS

EKO SATRIA 20213030

PHOTOACOUSTIC SPECTROSCOPY

System Components

LASER
Microphones Cylindical chamber

PHOTOTHERMAL SPEKTROSKOPI
Basic Processes in Photothermal Spectroscopy

Mechanism for Excited State Relaxation

The Main Components

Common detection techniques used in photothermal spectroscopy


Thermodynamic Parameter Temperature Measured Property TemperatureInfrared Emission Acoustic Wave Refractive Index Detection Technique CalorimetryPhotothermal Radiometry Photoacoustic Spectroscopy Photothermal Lens Photothermal Interferometry Photothermal Deflection Photothermal Refraction Photothermal DiffractionSurface Deflection

Pressure Density

Surface Deformation

Four methods used for photothermal spectroscopy

Excitation Schemes in Photothermal Spectroscopy


Excitation Signal Short-lived transient, magnitude decreases with time Long-lived transient, magnitude increases with time Periodic modulation, magnitude and phase are functions of frequency Detection Peak magnitude estimation and transient waveform analysis Steady-state magnitude estimation and transient waveform analysis Periodic wave magnitude and phase analysis using frequency selective filters or lock-in amplifiers

Pulsed

Continuous

Modulated

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