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ICE 203 PHYSICAL CHEMISTRY

Department of Chemical Engineering Faculty of Industrial Technology Parahyangan Catholic University August 2013

Schedule and Contents

Week
I II III IV V VI VII VIII-IX

Topic
INTRODUCTION; IDEAL GAS LAW KINETIC THEORY OF GAS;REAL GAS LAW PHYSICAL TRANSFORMATION OF PURE SUBSTANCES, PHASE TRANSFORMATION SIMPLE MIXTURES SIMPLE MIXTURES PHASE DIAGRAMS PHASE DIAGRAMS MID TERM EXAM

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Schedule and Contents

Week X XI XII XIII XIV XV Topic
CHEMICAL EQUILIBRIUM CHEMICAL EQUILIBRIUM EQUILIBRIUM ELECTROCHEMISTRY

EQUILIBRIUM ELECTROCHEMISTRY PROCESSES AT SOLID SURFACES SURFACE AND COLLOID CHEMISTRY

Grading
Mid Term Exam (UTS) Final Exam (UAS) Assignments+Quiz 40% 40% 20%

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Text Books
Peter Atkins,Julio De Paula. Physical Chemistry (2006), 8th ed, Oxford University Press.
Gilbert W Castellan. Physical Chemistry (1983), 3rd ed, Addison Wesley.

Ira N Levine. Physical Chemistry (2002), 6th ed,McGrawHill

David W Ball. Physical Chemistry (2011), Thomson.

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IDEAL GAS

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Charles law

V T (absolute)
Charles Extrapolation

By graphing the volume of the gas against temperature, 0C had no significance, but all measured gases seem to converge to a common zero point: absolute zero We must always use absolute temperatures (Kelvin scale) with the gas laws!

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Avogadros Law (n and V)

In the previous laws, the amount of gas was always constant. However, the amount of a gas (n) is directly proportional to the volume of the gas, meaning that as the amount of gas increases, so does the volume. Mathematically, we write:
nV

For a before and after situation: V1 V2 = n1 n2

~ = =

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Molar Volume and STP

Standard temperature and pressure (STP) are defined as 0C and 1 atm. At standard temperature and pressure, one mole of any gas occupies 22.4 L. The volume occupied by one mole of gas (22.4 L) is called the molar volume.

1 mole Gas = 22.4 L

NA

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Example -1

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Example -1

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Illustrating Daltons Law

Consider the two flasks, one containing nitrogen, the other containing half as many molecules of oxygen Since the flasks are the same size and the temperature is the same, the pressure in the oxygen flask is half that of the nitrogen

p=p +p
N2

O2

If we combine the oxygen with the nitrogen (making a sort of synthetic air), we find that the pressure obtained is the sum of the individual pressures

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++ = =

==

+ +

== (xA+xB)p=+ p

Example - 2

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KINETIC THEORY OF GAS

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= =

= =

= =

= =

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PROBLEMS
1

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7. Oxygen gas is normally sold in 49.0 L steel containers at a pressure of 150.0 atm. What volume would the gas occupy if the pressure was reduced to 1.02 atm and the temperature raised from 20oC to 35 oC? 8. A sample of gas contains 12.45 g of H2, 60.67 g of N2, and 2.38 g of NH3. If the total pressure of the gas is 1.50 atm, what are the partial 9. pressures of the gases? Calculate the density of gas mixture ! Silane, SiH4, reacts with O2 to give silicon dioxide and water SiH4(g) + 2 O2(g) SiO2(s) + 2 H2O(g)

If SiH4 is mixed with O2 in the correct stoichiometric ratio, and if the total pressure of the mixture is 120 mm Hg, what are the partial pressures of SiH4 and O2? When the reactants have been completely consumed, what is the total pressure in the flask

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10. A sample of helium gas at 33C, and you want to increase the average speed of helium atoms by 10.0%. To what temperature should the gas be heated to accomplish this?

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