T = ( RT*2 ) xB Hfus nA >> nB

Kf = RT*2. M Hfus

XB = nB = nB.M = mB.M nA 1 kg y A = pA p 1/c " 1/co = k2 !

Tr = T Tc

p = pA + pB = xA.pA* + xB.pB* ln c/co = k1!

a = 27R2Tc2 64 Pc b = RTc 8Pc Vc = 3b

yB = pB p $ k = A# %/RT
Vr = V Vc Vc = 3b

Pr = P Pc

Tc = 8a Pc = a 27b2 27Rb ( P + an2/V2 ) ( V nb ) = n R T

P Vm = RT ( 1 + B/Vm + C/Vm2 + ..) P Vm = RT { 1 + B/RT(P) + C/(RT)2 (P2) + /(RT)3 (P3) + ..!

T = ( RT*2 ) xB Hfus nA >> nB

Kf = RT*2. M Hfus

XB = nB = nB.M = mB.M nA 1 kg y A = pA p 1/c " 1/co = k2 !

Tr = T Tc

p = pA + pB = xA.pA* + xB.pB* ln c/co = k1!

a = 27R2Tc2 64 Pc b = RTc 8Pc Vc = 3b

yB = pB p $ k = A# %/RT
Vr = V Vc Vc = 3b

Pr = P Pc

Tc = 8a Pc = a 27b2 27Rb ( P + an2/V2 ) ( V nb ) = n R T

P Vm = RT ( 1 + B/Vm + C/Vm2 + ..) P Vm = RT { 1 + B/RT(P) + C/(RT)2 (P2) + /(RT)3 (P3) + ..!

nA >> nB

XB = nB = nB.M = mB.M nA 1 kg y A = pA p 1/c " 1/co = k2 ! yB = pB p $ k = A# %/RT

p = pA + pB = xA.pA* + xB.pB* ln c/co = k1! 1 %& ln &(% x) %(& x)