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PEMERIKSAAN NITRIT (NO2) SEBAGAI N

1. Metode : Kolorimetri 2. Prinsip Re !si :


"
#

NO2

di ,ot si! n d'n N-(1-N %til) etilen di min di(idro!lorid . rn $n'$ !emer ( n peri!s d'n / r : Mem0 ndin'! n den' n st nd r Mem0 / 0sor0 n/e . rn d l m spe!t1o d'n 2 +34 nm ! d rn& di0 / d l m !$r5e ! li0r si 4. Pen'' n''$:
K(lor 0e0 s* N6l4* ion-ion: S0* 7n* Bi* 8e* P0* A'* Pt* 6$ mem0eri! n . rn mer ( p ls$ d n ! d r Nitrit &' rend (. 9i! pemeri!s n dit$nd dpt di .et! n den' n men''$n ! n: 1 ml 6"6l4:1 ltr ir ; "'6l2:1 ltr ir.

p": 2 ) 2*+

# S$l% nil mid &' tel (

3. B ( n:

1) Re 'en Nitrit 2) < r$t n st nd r ind$! nitrit: 1 ml 2 1 m' NO2 4) < r$t n st nd r !er= nitrit: 1 ml 2 >*1 m' NO2 3) A?$ dest +) "2SO3 3 N 0,o @) KMnO3 >*>1 N A) As m O!s l t >*>1 N 1) 2) 4) 3) +) @) T 0$n' Nessler Per l t n Titr si d' 0$ret s m Pem n s d n 6r$st n' Erlenme&er Pipet 'ondo! Pipet $!$r

+. Al t:

@. 6 r Ker= :

. St nd ris si l r$t n !er= NO2: Am0il 2+ ml KMnO3 >*>1 N !e dlm Erlenme&er 2+> ml # + ml "2SO3 3 N 0,o # 2+ ml lrtn st nd r !er= ! n dist nd ris si. NO2 &'

P n s! n + menit pd @B ) A> o6 # 2+ ml As. O!s >*>1 N Titr si d' KMnO3 >*>1 N rose tipis / t t ml titr si 0 ml Per(it$n' n ! nd$n' n NO2 per ml lrtn st nd r !er= nitrit se0 ' i N:
C(2+ # 0) D % KMnO3E ) 2+ D % s.o!s D >*>1 D 24 -------------------------------------2+

2 ! m' N 0. Pemeri!s n S mpel: B$ t deret st nd r !er= lrt n NO2: p d 1> t0n' nessler F +> ml ti p t0' diisi l r$t n NO2 (1 ml 2 >*1 m'): >*+G 1*>G 1*+G 2*>G 2*+G 4*>G HH..G +*> ml # A?. +> ml. Am0il +> ml s mpel t0n' Nessler < r$t n deret st nd r d n s mpel di t s m sin'-m sin' di # sep$/$! sendo! (>*1 'r m) re 'en NO2 Go=o! 0ol !-0 li! t$n''$ 4> menit B ndin'! n . rn s mpel d'n deret st nd r / ri &' p lin' s m .

6 t t ml l r$t n st nd r pd t0' &' . rn n& s m ts0 mis.: 2*+ ml

A. Per(it$n' n:

1>>>

K d r NO2 2---- D 2*+ D ! 2 HHm':l N

+>
6/: ! 2 ! nd$n' n NO2:ml se0 ' i N &' didpt d ri st d ris si.

Pem0$ t 1 0 'i 1> 0 'i I> 0 'i

n Re 'en Nitrit: n N p(t&l mine n As m S$l% nil t n As m T rtr t

di'er$s d l m mortir disimp n d l m . d (:temp t & n' !erin'. Pem0$ t n l r$t n st nd r ind$! nitrit:
1*+ 'r m N NO2 dil r$t! n dlm A?. d 1 ltr diperole( ! nd$n' n NO2 2 BM NO2 --------- D 1+>> m' NO2 2 BM N NO2 3@ --- D 1+>> m' NO2 2 1>>> m' NO2

@I t $ 1 ml ~ 1 m' NO2