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PART A PHYSICS

1.

Match List - I (Event) with List - II (Order 1.


of the time interval for happening of the
event) and select the correct option from
the options given below the lists.

List - I

A
-I(U) -II ( U
U U)
U

List - II

(a)

Rotation period
(i) 10 5 s
of earth

(a)

(b)

Revolution
period of earth

(b)

(c)

Period of a light
(iii) 10 215 s
wave

(c)

(d)

Period of a
sound wave

(d)

(ii) 10 7 s

(iv) 10 23 s

- I

U

U

- II
(i) 105 s
(ii) 107 s
(iii) 10215 s
(iv) 1023 s

(1)

(a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)

(1)

(a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)

(2)

(a)-(ii), (b)-(i), (c)-(iv), (d)-(iii)

(2)

(a)-(ii), (b)-(i), (c)-(iv), (d)-(iii)

(3)

(a)-(i), (b)-(ii), (c)-(iv), (d)-(iii)

(3)

(a)-(i), (b)-(ii), (c)-(iv), (d)-(iii)

(4)

(a)-(ii), (b)-(i), (c)-(iii), (d)-(iv)

(4)

(a)-(ii), (b)-(i), (c)-(iii), (d)-(iv)

English : 1

Set : 10

Hindi : 1

Set : 10

th

2.

1
A bullet looses of its velocity passing 2.
n

through one plank. The number of such


planks that are required to stop the bullet
can be :

3.

U U n
U U S
U

(1)

n2
2n21

(1)

n2
2n21

(2)

2n 2
n21

(2)

2n 2
n21

(3)

Infinite

(3)

(4)

(4)

A heavy box is to be dragged along a rough 3.


horizontal floor. To do so, person A pushes
it at an angle 308 from the horizontal and
requires a minimum force FA, while person

B pulls the box at an angle 608 from the

horizontal and needs minimum force FB.


If the coefficient of friction between the box
and the floor is

UU U U
U , A
308 U U
FA B
608 U U
FB

F
A
3
, the ratio F is :
5
B

(1)

(1)

(2)

5
3

(2)

5
3

(3)

3
2

(3)

3
2

(4)

2
3

(4)

2
3

English : 2

Set : 10

Hindi : 2

3
5

F
A
F
B

Set : 10

4.

What is Ffriction at point P ? It is assumed

UU U S
M U U
U a
P U F ?

(1)

Mg

(1)

Mg

(2)

Ma

(2)

Ma

(3)

Ma
2

(3)

Ma
2

(4)

Ma
3

(4)

Ma
3

Consider a cylinder of mass M resting on 4.


a rough horizontal rug that is pulled out
from under it with acceleration a
perpendicular to the axis of the cylinder.
that the cylinder does not slip.

English : 3

Set : 10

Hindi : 3

Set : 10

5.

5.

makes angle f with the horizontal. Then :

U h X
U U OX U
u
U Y
U # OY f

(1)

sin f5cos u

(1)

sin f5cos u

(2)

sin f5

1
cos u
2

(2)

sin f5

1
cos u
2

(3)

sin f5

2
cos u
3

(3)

sin f5

2
cos u
3

(4)

sin f5

3
cos u
4

(4)

sin f5

3
cos u
4

A particle is released on a vertical smooth


semicircular track from point X so that OX
makes angle u from the vertical (see figure).
The normal reaction of the track on the
particle vanishes at point Y where OY

English : 4

Set : 10

Hindi : 4

Set : 10

6.

A ball of mass 160 g is thrown up at an 6.


angle of 608 to the horizontal at a speed of
10 ms21. The angular momentum of the
ball at the highest point of the trajectory
with respect to the point from which the
ball is thrown is nearly (g510 ms22)

7.

608 U 10 ms21
160 g U U
U ,
,
(g510 ms22)

(1)

1.73 kg m2/s

(1)

1.73 kg m2/s

(2)

3.0 kg m2/s

(2)

3.0 kg m2/s

(3)

3.46 kg m2/s

(3)

3.46 kg m2/s

(4)

6.0 kg m2/s

(4)

6.0 kg m2/s

The gravitational field in a region is 7.


r
given by g 5 5N/kg i 1 12 N/kg j . The
change in the gravitational potential
energy of a particle of mass 2 kg when it is

L U
r
g 5 5N/kg i 1 12 N/kg j 2 kg
(7 m,23 m)
L S U :

taken from the origin to a point


(7 m,23 m) is :
(1)

71 J

(1)

71 J

(2)

13 58 J

(2)

13 58 J

(3)

271 J

(3)

271 J

(4)

1J

(4)

1J

English : 5

Set : 10

Hindi : 5

Set : 10

8.

The velocity of water in a river is 8.


18 km/hr near the surface. If the river is
5 m deep , find the shearing stress between
the horizontal layers of water. The
co-efficient of viscosity of water510 22

18 km/hr
5 m U , U
L
51022

poise.
(1)

1021 N/m2

(1)

1021 N/m2

(2)

1022 N/m2

(2)

1022 N/m2

(3)

1023 N/m2

(3)

1023 N/m2

(4)

1024 N/m2

(4)

1024 N/m2

9.

9.

In the diagram shown, the difference in


the two tubes of the manometer is 5 cm,
the cross section of the tube at A and B is
6 mm2 and 10 mm2 respectively. The rate

, UU U
5 cm A B S U
6 mm2 10 mm2
U (g510 ms22)

at which water flows through the tube is


(g510 ms22)
(1)

7.5 cc/s

(1)

7.5 cc/s

(2)

8.0 cc/s

(2)

8.0 cc/s

(3)

10.0 cc/s

(3)

10.0 cc/s

(4)

12.5 cc/s

(4)

12.5 cc/s

English : 6

Set : 10

Hindi : 6

Set : 10

10.

A large number of liquid drops each of 10.


radius r coalesce to from a single drop of
radius R. The energy released in the
process is converted into kinetic energy of
the big drop so formed. The speed of the

r
U R
, U
(
cU T, r)

big drop is (given surface tension of liquid


T, density r)
(1)

T1
1
2
R
rr

(1)

T1
1
2
R
rr

(2)

2T 1
1
2
r r
R

(2)

2T 1
1
2
r r
R

(3)

4T 1
1
2
r r
R

(3)

4T 1
1
2
r r
R

(4)

6T 1
1
2
r r
R

(4)

6T 1
1
2
r r
R

English : 7

Set : 10

Hindi : 7

Set : 10

11.

A black coloured solid sphere of radius R 11.


and mass M is inside a cavity with vacuum
inside. The walls of the cavity are
maintained at temperature T0. The initial
temperature of the sphere is 3T0. If the
specific heat of the material of the sphere

varies as aT 3 per unit mass with the


temperature T of the sphere, where a is a
constant, then the time taken for the sphere

, , U M
R U U U
U T0 U
U 3T0
cU c
T aT3 U U U ,
a SU , 2T0
UU (s SU U
SU )

to cool down to temperature 2T0 will be


(s is Stefan Boltzmann constant)

12.

(1)

Ma
3
ln
2
4 pR


(1)

Ma
3
ln
2
4 pR


(2)

Ma
16
ln
2
4 pR


(2)

Ma
16
ln
2
4 pR


(3)

Ma
16
ln
2
16 pR


(3)

Ma
16
ln
2
16 pR


(4)

Ma
3
ln
16 pR 2


(4)

Ma
3
ln
16 pR 2


A gas is compressed from a volume of 12.


2 m3 to a volume of 1 m3 at a constant
pressure of 100 N/m2. Then it is heated at
constant volume by supplying 150 J of
energy. As a result, the internal energy of
the gas :

100 N/m2 SU U
2 m3 1 m3 U U
SU U 150 J
USL U
U

(1)

Increases by 250 J

(1)

(2)

Decreases by 250 J

(2)

(3)

Increases by 50 J

(3)

(4)

Decreases by 50 J

(4)

English : 8

Set : 10


250 J U
50 J
50 J U
250 J

Hindi : 8

Set : 10

13.

attained is much less than radius of the

cU U M
08C
U UU U U ,
?(
) (kB U
SU )

earth. (kB is Boltzmann constant)


(1) 0

(1)

A gas molecule of mass M at the surface 13.


of the Earth has kinetic energy equivalent
to 08C. If it were to go up straight without
colliding with any other molecules, how
high it would rise ? Assume that the height

14.

(2)

273 k B
2 Mg

(2)

273 k B
2 Mg

(3)

546 k B
3 Mg

(3)

546 k B
3 Mg

(4)

819 k B
2 Mg

(4)

819 k B
2 Mg

A body is in simple harmonic motion with 14.


time period half second (T50.5 s) and
amplitude one cm (A51 cm). Find the
average velocity in the interval in which it
moves from equilibrium position to half of

S U (T50.5 s)
UUU (A51 cm) U U
U U S
S ,
U

its amplitude.
(1)

4 cm/s

(1)

4 cm/s

(2)

6 cm/s

(2)

6 cm/s

(3)

12 cm/s

(3)

12 cm/s

(4)

16 cm/s

(4)

16 cm/s

English : 9

Set : 10

Hindi : 9

Set : 10

15.

The total length of a sonometer wire 15.


between fixed ends is 110 cm. Two bridges
are placed to divide the length of wire in
ratio 6 : 3 : 2. The tension in the wire is
400 N and the mass per unit length is
0.01 kg/m. What is the minimum common

S U U
110 cm
6 : 3 : 2 U U
U 400 N U ,
0.01 kg/m cU
, U ,

frequency with which three parts can


vibrate ?

16.

(1)

1100 Hz

(1)

1100 Hz

(2)

1000 Hz

(2)

1000 Hz

(3)

166 Hz

(3)

166 Hz

(4)

100 Hz

(4)

100 Hz

The electric field in a region of space is 16.


given

by,

E 5 Eo i 1 2 Eo j

where

E05100 N/C. The flux of this field through


a circular surface of radius 0.02 m parallel

E 5 Eo i 1 2 Eo j

E 0 5100 N/C

Y-Z

U 0.02 m cU
U U l

to the Y-Z plane is nearly :


(1)

0.125 Nm2/C

(1)

0.125 Nm2/C

(2)

0.02 Nm2/C

(2)

0.02 Nm2/C

(3)

0.005 Nm2/C

(3)

0.005 Nm2/C

(4)

3.14 Nm2/C

(4)

3.14 Nm2/C

English : 10

Set : 10

Hindi : 10

Set : 10

17.

at one plate to 2 at the other. The


capacitance of capacitor is :

U U U U
A U U U d U
S Ul U
l U U 1 U U U 2
U M U U
U

(1)

0(112)A/d

(1)

0(112)A/d

(2)

0(211)A/2d

(2)

0(211)A/2d

(3)

0A/[d

(3)

0A/[d

(4)

0(221)A/[d

(4)

0(221)A/[d

100 W

The gap between the plates of a parallel 17.


plate capacitor of area A and distance
between plates d, is filled with a dielectric
whose permittivity varies linearly from 1

ln(2/1)]
ln(2/1)]

18.

ln(2/1)]
ln(2/1)]

18.

Four bulbs B1, B2, B3 and B4 of 100 W each

are connected to 220 V main as shown in

the figure. The reading in an ideal ammeter

U B1, B2, B3 B4
220 V
U

will be :
(1)

0.45 A

(1)

0.45 A

(2)

0.90 A

(2)

0.90 A

(3)

1.35 A

(3)

1.35 A

(4)

1.80 A

(4)

1.80 A

English : 11

Set : 10

Hindi : 11

Set : 10

19.

19.

A square frame of side 10 cm and a long


straight wire carrying current 1 A are in
the plane of the paper. Starting from close
to the wire, the frame moves towards the
right with a constant speed of 10 ms21 (see
figure). The e.m.f induced at the time the

10 cm

U U U 1 A
U $ U
U , U SU
10 ms21 U ( ) U
x510 cm U
U l

left arm of the frame is at x510 cm from


the wire is :
(1)

2 mV

(1)

2 mV

(2)

1 mV

(2)

1 mV

(3)

0.75 mV

(3)

0.75 mV

(4)

0.5 mV

(4)

0.5 mV

English : 12

Set : 10

Hindi : 12

Set : 10

20.

of intensity B, the magnetic field Bs inside

U
B
U ,
U Bs U

(1)

Bs52B

(1)

Bs52B

(2)

Bs50

(2)

Bs50

(3)

Bs5B

(3)

Bs5B

(4)

Bs<B but Bs 0

(4)

An example of a perfect diamagnet is a 20.


superconductor. This implies that when a
superconductor is put in a magnetic field
the superconductor will be such that :

English : 13

Set : 10

Bs<B U Bs 0

Hindi : 13

Set : 10

21.

21.

Figure shows a circular area of radius R

where a uniform magnetic field B is going


into the plane of paper and increasing in
magnitude at a constant rate. In that case,
which of the following graphs, drawn
schematically, correctly shows the

B $
U SU U U h U
S , M ,
- U l E(r) U
?

variation of the induced electric field


E(r) ?

(1)

(1)

(2)

(2)

English : 14

Set : 10

Hindi : 14

Set : 10

22.

(3)

(3)

(4)

(4)

If denote microwaves, X rays, infrared, 22.

l SU U, X
U, U, U, U, UU U
U M, X, I, G, U, R U V
, U UU

gamma rays, ultra-violet, radio waves and


visible parts of the electromagnetic
spectrum by M, X, I, G, U, R and V, the
following is the arrangement in ascending
order of wavelength :
(1)

R, M, I, V, U, X and G

(1)

(2)

M, R, V, X, U, G and I

(2)

(3)

G, X, U, V, I, M and R

(3)

(4)

I, M, R, U, V, X and G

(4)

English : 15

Set : 10

U G
M, R, V, X, U, G U I
G, X, U, V, I, M U R
I, M, R, U, V, X U G
R, M, I, V, U, X

Hindi : 15

Set : 10

23.

A ray of light is incident from a denser to


a rarer medium. The critical angle for total 23.
internal reflection is uiC and the Brewsters
angle of incidence is u iB , such that
sinu iC /sinu iB 5h51.28. The relative
refractive index of the two media is :

24.

U U
U U
uiC U SUU uiB
U sinuiC/sinuiB5h51.28

(1)

0.2

(2)

0.4

(1)

0.2

(3)

0.8

(2)

0.4

(4)

0.9

(3)

0.8

(4)

0.9

The diameter of the objective lens of


microscope makes an angle b at the focus 24.
of the microscope. Further, the medium
between the object and the lens is an oil of
refractive index n. Then the resolving
power of the microscope.


U b ; S
n

(1)

Increases with decreasing value of n

(2)

Increases with decreasing value of b

(1)

(3)

Increases with increasing value of

(2)

n sin 2b

(3)

(4)

U
b U
n sin 2b

Increases with increasing value of


1
n sin 2b

English : 16

(4)

Set : 10

Hindi : 16

1
n sin 2b

Set : 10

25.

In a Youngs double slit experiment, the 25.


distance between the two identical slits is
6.1 times larger than the slit width. Then
the number of intensity maxima observed
within the central maximum of the single

mU , M SU
U SU 6.1
SU U
U

slit diffraction pattern is :


(1)

(1)

(2)

(2)

(3)

12

(3)

12

(4)

24

(4)

24

English : 17

Set : 10

Hindi : 17

Set : 10

26.

Match List - I (Experiment performed) 26.


with List - II (Phenomena discovered/
associated) and select the correct option
from the options given below the lists :

List - I
Davisson
(a) and Germer
Experiment

-I ( ) -II (h
/h )

- I

List - II
(i)

Wave nature of
electrons

Millikans oil
Charge of an
(b) drop
(ii)
electron
experiment

- II

(a)

U U U

(i)

U U
U

(b)

(ii)

Rutherford
experiment

(iii)

Quantisation of
energy levels

(c)

UUU

(iii)

SU
U

Franck (d) Hertz


experiment

(iv)

Existence of
nucleus

(d)

- U

(iv)

(c)

(1)

(a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)

(1)

(a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)

(2)

(a)-(i), (b)-(ii), (c)-(iv), (d)-(iii)

(2)

(a)-(i), (b)-(ii), (c)-(iv), (d)-(iii)

(3)

(a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)

(3)

(a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)

(4)

(a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)

(4)

(a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)

English : 18

Set : 10

Hindi : 18

Set : 10

27.

A piece of wood from a recently cut tree 27.


shows 20 decays per minute. A wooden
piece of same size placed in a museum
(obtained from a tree cut many years back)
shows 2 decays per minute. If half life of
C14 is 5730 years, then age of the wooden
piece

placed

in

the

museum

is

U U
U 20 U
U (
U U ) U 2
; C14 5730 ,
U

approximately :
(1)

10439 years

(1)

10439

(2)

13094 years

(2)

13094

(3)

19039 years

(3)

19039

(4)

39049 years

(4)

39049

28.

28.

Given : A and B are input terminals.


Logic 1 5 > 5 V
Logic 0 5 < 1 V
Which logic gate operation, the following
circuit does ?
(1)

AND Gate

(2)

OR Gate

(3)

XOR Gate

(4)

NOR Gate

English : 19

Set : 10

A B U
1 5 > 5 V
0 5 < 1 V
U - U
U U ?
(1) AND U
(2) OR U
(3) XOR U
(4) NOR U
Hindi : 19

Set : 10

29.

Long range radio transmission is possible 29.


when the radiowaves are reflected from
the ionosphere. For this to happen the
frequency of the radiowaves must be in the

U UU SU
UU U U
UU U U

range :
(1)

80 - 150 MHz

(1)

80 - 150 MHz

(2)

8 - 25 MHz

(2)

8 - 25 MHz

(3)

1 - 3 MHz

(3)

1 - 3 MHz

(4)

150 - 500 kHz

(4)

150 - 500 kHz

English : 20

Set : 10

Hindi : 20

Set : 10

30.

30.

In an experiment for determining the


gravitational acceleration g of a place with
the help of a simple pendulum, the
measured time period square is plotted

U S U
L U g ,
U UU

against the string length of the pendulum


in the figure.
What is the value of g at the place ?

S U g

(1)

9.81 m/s2

(1)

9.81 m/s2

(2)

9.87 m/s2

(2)

9.87 m/s2

(3)

9.91 m/s2

(3)

9.91 m/s2

(4)

10.0 m/s2

(4)

10.0 m/s2

English : 21

Set : 10

Hindi : 21

Set : 10

PART B CHEMISTRY
31.

Ionization energy of gaseous Na atoms is 31.


495.5 kJmol 21 . The lowest possible
frequency of light that ionizes a sodium
atom is (h56.626310234 Js,
NA56.02231023 mol21)

32.

B U
U U
495.5 kJ 21 U U
U
(frequency) ? (h56.626310234 Js,
NA56.02231023 21)

(1)

7.503104 s21

(1)

7.503104 s21

(2)

4.7631014 s21

(2)

4.7631014 s21

(3)

3.1531015 s21

(3)

3.1531015 s21

(4)

1.2431015 s21

(4)

1.2431015 s21

Choose the correct statement with respect 32.


to the vapour pressure of a liquid among

the following :
(1)

Increases linearly with increasing

(1)

temperature
(2)

Increases

non-linearly

with

(2)

Decreases linearly with increasing

(3)

increasing temperature
(3)

temperature
(4)

Decreases

non-linearly

with

increasing temperature

English : 22

Set : 10

(4)

U U

U U

U U
U
U U
U

Hindi : 22

Set : 10

33.

Which one of the following molecules is 33.

paramagnetic ?

34.

(1)

N2

(1)

N2

(2)

NO

(2)

NO

(3)

CO

(3)

CO

(4)

O3

(4)

O3

Zirconium

phosphate

[Zr 3 (PO 4 ) 4 ] 34.

dissociates into three zirconium cations of

charge 14 and four phosphate anions of


charge 23. If molar solubility of zirconium
phosphate is denoted by S and its solubility
product by Ksp then which of the following

relationship between S and K sp


correct ?

is

U $S$U [Zr3(PO4)4] U
14 U U U
U 23 U $S$U
U $S$U U
S U Ksp
-
S U Ksp ?

(1)

S5{Ksp/(6912)1/7}

(1)

S5{Ksp/(6912)1/7}

(2)

S5{Ksp/144}1/7

(2)

S5{Ksp/144}1/7

(3)

S5(Ksp/6912)1/7

(3)

S5(Ksp/6912)1/7

(4)

S5{Ksp/6912}7

(4)

S5{Ksp/6912}7

English : 23

Set : 10

Hindi : 23

Set : 10

35.

For the decomposition of the compound, 35.


represented as
NH2COONH4(s) 2NH3(g)1CO2(g)

the Kp52.931025 atm3.


If the reaction is started with 1 mol of the

Kp52.931025 atm3

compound,

the

total

pressure

1
U S

at

equilibrium would be :

36.

NH2COONH4(s) 2NH3(g)1CO2(g)

(1)

1.9431022 atm

(1)

1.9431022 atm

(2)

5.8231022 atm

(2)

5.8231022 atm

(3)

7.6631022 atm

(3)

7.6631022 atm

(4)

38.831022 atm

(4)

38.831022 atm

For the reaction,

36.

3A12B C1D,

3A12B C1D

the differential rate law can be written

as :
(1)

d [C ]
1 d [A ]
n
m
5
5 k [A ] [ B ]
3 dt
dt

(1)

d [C]
1 d [A ]
n
m
5
5 k [A ] [ B ]
3 dt
dt

(2)

d [A ]
d [C ]
n
m
5
5 k [A ] [ B ]
dt
dt

(2)

d [A ]
d [C ]
n
m
5
5 k [A ] [ B ]
dt
dt

(3)

d [C ]
1 d [A ]
n
m
52
5 k [A ] [ B ]
3 dt
dt

(3)

d [C]
1 d [A ]
n
m
52
5 k [A ] [ B ]
3 dt
dt

(4)

d [C ]
1 d [A ]
n
m
5
5 k [A ] [ B ]
3 dt
dt

(4)

d [C]
1 d [A ]
n
m
5
5 k [A ] [ B ]
3 dt
dt

English : 24

Set : 10

Hindi : 24

Set : 10

37.

Sulphur dioxide and oxygen were allowed 37.


to diffuse through a porous partition.
20 dm3 of SO2 diffuses through the porous

partition in 60 seconds. The volume of O2


in dm3 which diffuses under the similar
condition in 30 seconds will be (atomic

U U $U UU U
U U U
20 dm3 SO2 U 60 U
S U O2
dm3 30 U ($U
U 532 )

mass of sulphur532 u) :

38.

(1)

7.09

(1)

7.09

(2)

14.1

(2)

14.1

(3)

10.0

(3)

10.0

(4)

28.2

(4)

28.2

The observed osmotic pressure for a 38.


0.10 M solution of Fe(NH4)2(SO4)2 at 258C

is

10.8

atm.

The

expected

and

experimental (observed) values of Vant

U Fe(NH4)2(SO4)2 0.10 M
U (UU) 10.8 atm
U U U
() U

258 C

Hoff factor (i) will be respectively :


(R50.082 L atm k2mol21)

(R50.082 L atm k221)

(1)

5 and 4.42

(1)

(2)

4 and 4.00

(2)

(3)

5 and 3.42

(3)

(4)

3 and 5.42

(4)

English : 25

Set : 10

U 4.42
4 U 4.00
5 U 3.42
3 U 5.42
5

Hindi : 25

Set : 10

39.

structure is :

U () U S
U cU U

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

The total number of octahedral void(s) per 39.


atom present in a cubic close packed

40.

A and B, which of the following is true ?

U A U B
?

(1)

DHmixing < 0 (zero)

(1)

(2)

DHmixing > 0 (zero)

(2)

(3)

A2B interaction is stronger than

(3)

For an ideal solution of two components 40.

A2A and B2B interactions


(4)

A2A, B2B and A2B interactions


are identical

41.

Consider the reaction :

41.

41
21
H 2 SO 3(aq)1Sn (aq)
1H 2 O (l ) Sn (aq)
1HSO24(aq)13H1(aq)

Which of the following statements is

U B2B U S U
A2B USU
(4) A2A, B2B U A2B USU

Sn41 is the oxidizing agent because

- ?
(1)

it undergoes oxidation
(2)

Sn41is the reducing agent because

(2)

it undergoes oxidation
(3)

H2SO3 is the reducing agent because

(3)

H2SO3 is the reducing agent because

(4)

it undergoes oxidation
(4)

it undergoes reduction
English : 26

Set : 10

A2A

41
21
H 2 SO 3()1Sn()
1H 2 O(l ) Sn()
1HSO24()13H1
()

correct ?
(1)

DH < 0 (zero)
DH > 0 (zero)

Sn41 U


Sn41

H2SO3

H2SO3

Hindi : 26

Set : 10

42.

Which one of the following has largest 42.

ionic radius ?

43.

(1)

Li1

(1)

Li1

(2)

O2

(2)

O2

(3)

B31

(3)

B31

(4)

F2

(4)

F2

22

An octahedral complex with molecular 43.


composition M.5NH 3 .Cl.SO 4 has two
isomers, A and B. The solution of A gives
a white precipitate with AgNO3 solution

and the solution of B gives white


precipitate with BaCl2 solution. The type
of isomerism exhibited by the complex is :

44.

22

U M.5 NH3.Cl.SO4 cU
U A U B A
AgNO3 $
U B BaCl2 $
U mU -
U

(1)

Linkage isomerism

(1)

(2)

Ionisation isomerism

(2)

(3)

Coordinate isomerism

(3)

(4)

Geometrical isomerism

(4)

() -
-
-
-

following redox reaction ?

- U
?

Cr2O7221Fe211 C 2 O 242

Cr2O7221Fe211 C 2 O 242

How many electrons are involved in the 44.

Cr311Fe311CO2 (Unbalanced)

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

English : 27

Set : 10

Hindi : 27

Cr311Fe311CO2

()

Set : 10

45.

Amongst LiCl, RbCl, BeCl2 and MgCl2 the 45.


compounds with the greatest and the least
ionic character, respectively are :

46.

(1)

LiCl and RbCl

(2)
(3)

RbCl and BeCl2


MgCl2 and BeCl2

(4)

RbCl and MgCl2

Nickel(Z528)

combines

with

a 46.

uninegative monodentate ligand to form


a diamagnetic complex [NiL 4 ] 22 . The
hybridisation involved and the number of

LiCl, RbCl, BeCl2 U MgCl2


U U
U
(1) LiCl U RbCl
(2) RbCl U BeCl2
(3) MgCl2 U BeCl2
(4) RbCl U MgCl2
(Z528) U
U U [NiL4]22,
U U U U
U U

unpaired electrons present in the complex


are respectively :

47.

(1)

sp3, two

(1)

sp3,

(2)

dsp2, zero

(2)

dsp2,

(3)

dsp2, one

(3)

(4)

sp3, zero

(4)

Which of these statements is not true ?


(1)
(2)

NO1 is not isoelectronic with O2


B is always covalent in its
compounds

(3)

In aqueous solution, the Tl1 ion is


much more stable than Tl (III)

(4)

LiAlH4 is a versatile reducing agent

in organic synthesis.

English : 28

Set : 10

47.

dsp2,
sp3,

- ?
(1) NO1 O2 U
(2) U

(3) , Tl (III) Tl1


S
(4) LiAlH4

Hindi : 28

Set : 10

48.

Example of a three-dimensional silicate 48.

- U U

is :

49.

(1)

Zeolites

(2)

Ultramarines

(3)

Feldspars

(4)

Beryls

$U
(2) UU
(3) USU
(4) U
16 S U
S$
(1)

Amongst the following, identify the 49.


species with an atom in 16 oxidation
state :

50.

51.

(1)

[MnO4]2

(1)

[MnO4]2

(2)

[Cr(CN)6]32

(2)

[Cr(CN)6]32

(3)

Cr2O 3

(3)

Cr2O3

(4)

CrO2Cl2

(4)

CrO2Cl2

as Malachite :

U S

(1)

Cu 2O

(1)

Cu 2O

(2)

Cu 2S

(2)

Cu2S

(3)

CuFeS2

(3)

CuFeS2

(4)

Cu(OH)2.CuCO3

(4)

Cu(OH)2.CuCO3

Which one of the following ores is known 50.

The major product formed when 1, 1, 12 51.


trichloro - propane is treated with aqueous
potassium hydroxide is :
(1)

Propyne

(2)

1 - Propanol

(3)

2 - Propanol

(4)

Propionic acid

English : 29

Set : 10

1, 1, 12 UU U
UU

(1)
(2) 1 -
(3) 2 -
(4) U

Hindi : 29

Set : 10

52.

Which one of the following is an example 52.

of thermosetting polymers ?

53.

(1)

Neoprene

(1)

(2)

Buna -N

(2)

(3)

Nylon 6, 6

(3)

(4)

Bakelite

(4)

The correct IUPAC name of the following 53.

- N
6, 6
U

compound

is :

54.

(1)

4 - methyl - 3 - ethylhexane

(2)

3 - ethyl - 4 - methylhexane

(3)

3, 4 - ethylmethylhexane

(4)

4 - ethyl - 3 - methylhexane

Which one of the following substituents at 54.

IUPAC
(1) 4 - - 3 -
(2) 3 - - 4 -
(3) 3, 4 -
(4) 4 - - 3 -
S U

para-position is most effective in


,
stabilizing the phenoxide

U S U

S ?

ion ?
(1)

2CH3

(1)

2CH3

(2)

2OCH3

(2)

2OCH3

(3)

2COCH3

(3)

2COCH3

(4)

2CH2OH

(4)

2CH2OH

English : 30

Set : 10

Hindi : 30

Set : 10

55.

amine is treated with NaNO2 and HCl

NaNO2 U HCl
U U

(1)

Diazomethane

(1)

(2)

Methylalcohol

(2)

(3)

Methylcyanide

(3)

(4)

Nitromethane

(4)

The final product formed when Methyl 55.


is :

56.

Which one of the following compounds 56.


will

not

be

soluble

in

sodium

U$

U
U

- U U
?

bicarbonate ?

57.

(1)

2, 4, 6 - Trinitrophenol

(1)

(2)

Benzoic acid

(2)

(3)

o - Nitrophenol

(3)

(4)

Benzene sulphonic acid

(4)

Williamson synthesis of ether is an example 57.


of :
(1)

Nucleophilic addition

(2)

Electrophilic addition

(3)

Electrophilic substitution

(4)

Nucleophilic substitution

English : 31

Set : 10

UU$
$ U
o - U$
$ $ U
2, 4, 6 -

U
U ?
(1) $
(2) U$
(3) U$ S
(4) $ S

Hindi : 31

Set : 10

58.

The reason for double helical structure of 58.


DNA is the operation of :

59.

(1)

Electrostatic attractions

(2)

van der Waals forces

(3)

Dipole - Dipole interactions

(4)

Hydrogen bonding

Among the following organic acids, the 59.


acid present in rancid butter is :
(1)

Pyruvic acid

(2)

Lactic acid

(3)

Butyric acid

(4)

Acetic acid

English : 32

Set : 10

- DNA U UU
U U ?
(1) SUl
(2) UU
(3) m - m USU
(4) U
U U
- ?
(1) L U
(2) U U
(3) UU U
(4) U U

Hindi : 32

Set : 10

60.

In a set of reactions p - nitrotoluene yielded 60.

a product E

The product E would be :

p - UU

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

English : 33

Set : 10

Hindi : 33

Set : 10

PART C MATHEMATICS
61.

62.

Let f : RR be defined by f(x)5

f : RR , f(x)5

then f is :

(1)

both one - one and onto

(1)

(2)

one - one but not onto

(2)

(3)

onto but not one - one

(3)

(4)

neither one - one nor onto.

(4)

For all complex numbers z of the form 62.


11ia, a e R, if

63.

x 21
61.
x 11

z25x1iy,

then :

U
U
U U
U U

11ia, a e R
z

U
, :

z25x1iy

y 2 24x1250

(1)

y 224x1250

(2)

y 2 14x2450

(2)

y 214x2450

(3)

y 2 24x1450

(3)

y 224x1450

(4)

y 2 14x1250

(4)

y 214x1250

3x 21x15 5x23, where x 63.

is real, has :
(1)

no solution

(2)

exactly one solution

(3)

exactly two solutions

(4)

exactly four solutions.

English : 34

Set : 10

mU U ,

f :

(1)

The equation

x 21
x 11

U 3x 21x15 5x23, x S
, / :
(1)
(2) U
(3) U
(4) U U

Hindi : 34

Set : 10

64.

A is symmetric and B is skewsymmetric,

A B 333 A
B ,

then the matrix AB2BA is :

AB2BA :

(1)

skewsymmetric

(1)

(2)

symmetric

(2)

(3)

neither

Let A and B be any two 333 matrices. If 64.

symmetric

nor

(3)

I or 2I, where I is an identity matrix.

(4)

skewsymmetric
(4)
65. If
65.

Dr 5

r
n
2

1
n ( n 2 1)
2

2r 2 1

3r 2 2

n2 1

( n 2 1 )2

then the value of

n2 1

r5 1

1
( n 2 1 )( 3n 1 4 ) ,
2

Dr :

Dr 5

depends only on a

(2)

depends only on n

(1)

(3)

depends both on a and n

(2)

(4)

is independent of both a and n.

(3)
(4)

Set : 10

2r 2 1

3r 2 2

n2 1

( n 2 1 )2

1
( n 2 1 )( 3n 1 4 )
2

r
n
2

1
n ( n 2 1)
2

(1)

English : 35

2I , I

n2 1

r5 1

Dr

a U U
n U U
a n U U
a n S

Hindi : 35

Set : 10

66.

Two women and some men participated 66.


in a chess tournament in which every
participant played two games with each
of the other participants. If the number of
games that the men played between themselves exceeds the number of games that
the men played with the women by 66,

U U
L
U L
U L
mU U 66
, L ,
, U

then the number of men who participated


in the tournament lies in the interval :

67.

(1)

[8, 9]

(1)

[8, 9]

(2)

[10, 12)

(2)

[10, 12)

(3)

(11, 13]

(3)

(11, 13]

(4)

(14, 17)

(4)

(14, 17)

The coefficient of x1012 in the expansion of 67.


(11x n 1x 253 ) 10 ,

(where n 22 is any

(11xn1x253)10,

) U

( n 22 Z

x1012

positive integer), is :
(1)

(2)

10C

(3)

4n

(4)

253C

English : 36

Set : 10

(1)

(2)

10C

(3)

4n

(4)

253C

Hindi : 36

Set : 10

68.

The number of terms in an A.P. is even; 68.


the sum of the odd terms in it is 24 and
that the even terms is 30. If the last term

, 10 2 ,

1
, then the
2
number of terms in the A.P. is :

exceeds the first term by 10

69.

U
24 30
U

(1)

(1)

(2)

(2)

(3)

12

(3)

12

(4)

16

(4)

16

3n
1
n , where [n] denotes 69.
Let f(n) 5 1
100
3

f(n)5 3 1 100 n ,

the greatest integer less than or equal to n.

Z ,

Then

56
f ( n ) is equal to :
n5 1

56
f ( n)
n5 1

(1)

56

(1)

56

(2)

689

(2)

689

(3)

1287

(3)

1287

(4)

1399

(4)

1399

English : 37

Set : 10

Hindi : 37

3n

[n]

U U U U ,

UU

Set : 10

70.

If the function

2 1 cos x2 1
, x p

2
f (x ) 5 ( p 2 x )
k
, x5p

71.

70.

is continuous at x5p, then k equals :

x5p U

(1)

(1)

(2)

1
2

(2)

1
2

(3)

(3)

(4)

1
4

(4)

1
4

Let f: R R be a function such that 71.


?f(x)?

x2,

for all x e R. Then, at x50, f is :

(1)

continuous but not differentiable

(2)

continuous as well as differentiable

(3)

neither continuous nor differentiable

(4)

differentiable but not continuous.

English : 38

Set : 10

2 1 cos x2 1
, x p

2
f (x ) 5 ( p 2 x )
k
, x5p

, k UU :

f: R R x e R
?f(x)? x2 , x50 U f :
(1) U
(2)
(3) U
(4) U

Hindi : 38

Set : 10

72.

If non-zero real numbers b and c are such 72.


that min f(x) > max g(x), where
f(x)5x212bx12c2 and

U S b c
min f(x) > max g(x), f(x)5x212bx12c2
g(x)52x222cx1b2 (x e R) ,

g(x)52x222cx1b2 (x e R) ;

73.

then

c
lies in the interval :
b

(1)

1
0,
2

(1)

1
0,
2

(2)

1 1
2 , 2

(2)

1 1
2 , 2

(3)

2 , 2

(3)

2 , 2

(4)

(4)

2 ,

If the volume of a spherical ball is 73.


increasing at the rate of 4p cc/sec, then
the rate of increase of its radius
(in cm/sec), when the volume is 288p cc,

c
b

U , :

2 ,

U 4p /.
U U , 288p
, U (/. ) U ,
:

is :
(1)

1
6

(1)

1
6

(2)

1
9

(2)

1
9

(3)

1
36

(3)

1
36

(4)

1
24

(4)

1
24

English : 39

Set : 10

Hindi : 39

Set : 10

74.

If m is a non - zero number and 74.

x 5m21 1 2 x 4 m21

x 2 m 1 x m 11

d x5 f ( x )1c ,

(2)

x 5m

2m x 2m 1 x m 1 1

x 4m

2m x 2m 1 x m 1 1

(3)

(4)

( x 5m 2 x 4 m )
2
2 m ( x 2 m 1 x m 1 1)

2 m x 5m 1 x 4m

English : 40

Set : 10

d x5 f ( x )1c

f(x) :

x 5m

2m x 2m 1 x m 1 1

(2)

x 2 m 1 x m 11

(1)

)
2
( x2m 1 xm 1 1)

x 5m21 12 x 4 m21

then f(x) is :
(1)

x 4m

2m x 2m 1 x m 1 1

(3)

)
2
( x2m 1 xm 1 1)

(4)

( x 5m 2 x 4 m )
2
2 m ( x 2 m 1 x m 1 1)

Hindi : 40

2 m x 5m 1 x 4m

Set : 10

75.

Let

function

F( x ) 5

the

be

defined

as 75.

et
1 t dt , x > 0 then the value of
x

integral

et
1 t 1 a dt ,
x

et
dt , x > 0
1 t

F , F( x ) 5

et

U , 1
t1 a
a > 0 ,

where

dt

mU
,

a > 0, is :

76.

(1)

ea[F(x)2F(11a)]

(1)

ea[F(x)2F(11a)]

(2)

e2a[F(x1a)2F(a)]

(2)

e2a[F(x1a)2F(a)]

(3)

ea[F(x1a)2F(11a)]

(3)

ea[F(x1a)2F(11a)]

(4)

e2a[F(x1a)2F(11a)]

(4)

e2a[F(x1a)2F(11a)]

The area of the region above the x-axis 76.


bounded by the curve y5tan x, 0 x
and the tangent to the curve at x5

p
2

p
is :
4

y5tan x, 0 x

x5

p
4

U , :

1
1
log 2 2
2
2

(1)

1
1
log 2 2
2
2

(2)

1
1
log 2 1
2
2

(2)

1
1
log 2 1
2
2

(3)

1
( 1 2 log 2 )
2

(3)

1
( 1 2 log 2 )
2

(4)

1
( 1 1 log 2 )
2

(4)

1
( 1 1 log 2 )
2

Set : 10

U S U mU U , x

(1)

English : 41

p
2

Hindi : 41

Set : 10

77.

78.

dy
1y tan x5sin 2x and y(0)51, then 77.
dx
y(p) is equal to :

If

dy
1y tan x5sin 2x
dx
y(p) UU :

(1)

(1)

(2)

21

(2)

21

(3)

25

(3)

25

(4)

(4)

The circumcentre of a triangle lies at the 78.


origin and its centroid is the mid point of
the line segment joining the points
(a211, a211) and (2a, 22a), a 0. Then
for any a, the orthocentre of this triangle

y(0)51

U U
, (a211, a211) (2a, 22a),
a 0 UU ,
a U
U S ,

lies on the line :


(1)

y22ax50

(1)

y22ax50

(2)

y2(a211)x50

(2)

y2(a 211)x50

(3)

y1x50

(3)

y1x50

(4)

(a21)2x2(a11) 2y50

English : 42

(4)

Set : 10

(a21) 2x2(a11) 2y50

Hindi : 42

Set : 10

79.

If a line L is perpendicular to the line 79.


5x2y51, and the area of the triangle
formed by the line L and the coordinate

U L, U 5x2y51 U
U L mU
5 , U L U x15y50 U :

axes is 5, then the distance of line L from


the line x15y50 is :

80.

(1)

7
5

(1)

7
5

(2)

5
13

(2)

5
13

(3)

7
13

(3)

7
13

(4)

5
7

(4)

5
7

The equation of the circle described on the 80.


chord

3x1y1550

x21y2516

of

the

circle

x21y2516 3x1y1550
U :

as diameter is :

(1)

x 21y 213x1y21150

(1)

x 21y 213x1y21150

(2)

x 21y 213x1y1150

(2)

x 2 1y 2 13x1y1150

(3)

x 21y 213x1y2250

(3)

x 2 1y 2 13x1y2250

(4)

x 21y 213x1y22250

(4)

x 21y 213x1y22250

English : 43

Set : 10

Hindi : 43

Set : 10

81.

A chord is drawn through the focus of the 81.


parabola y256x such that its distance from

U y256x U
U U

5
, then its
the vertex of this parabola is
2

5
2

U :

slope can be :

82.

(1)

5
2

(1)

5
2

(2)

3
2

(2)

3
2

(3)

2
5

(3)

2
5

(4)

2
3

(4)

2
3

y2
x2
2
5 1
4
5

The tangent at an extremity (in the first 82.

quadrant) of latus rectum of the hyperbola

U ( Z ) U S

y2
x2
2
5 1 ,meets x - axis and y - axis
4
5

U x- y- A B

at A and B

respectively. Then

(OA) 2 2(OB) 2 , where O is the origin,


equals :
(1)

(2)

16
9

(3)

(4)

English : 44

20
9

4
3

Set : 10

U , (OA)22(OB)2, O
, UU :
(1)

(2)

16
9

(3)

(4)

Hindi : 44

20
9

4
3

Set : 10

83.

Equation of the line of the shortest distance 83.


between the lines

y
x
z
5
5
and
1
21
1

y11
x21
z
5
5
22
0
1

y11
x21
z
5
5 is :
0
22
1

84.

y
x
z
5
5
1
21
1

U U :

(1)

y
x
z
5
5
1
21
22

(1)

y
x
z
5
5
1
21
22

(2)

y11
x21
z
5
5
21
22
1

(2)

y11
x21
z
5
5
21
22
1

(3)

y11
x21
z
5
5
21
1
1

(3)

y11
x21
z
5
5
1
21
1

(4)

y
x
z
5 5
22
1
2

(4)

y
x
z
5 5
22
1
2

If

the

angle

2(x11)5y5z14

between
and

the
the

line 84.
plane

p
2x2y1 l z1450 is
, then the value
6
of l is :

U
l

135
7

(1)

135
7

(2)

45
11

(2)

45
11

(3)

45
7

(3)

45
7

(4)

135
11

(4)

135
11

Set : 10

2(x11)5y5z14

2x2y1 l z1450

(1)

English : 45

Hindi : 45

p
,
6

Set : 10

85.

r
r
If x 5 3i 2 6 j 2 k , y 5 i 1 4 j 2 3k 85.
and

r
z 5 3i 2 4 j 2 12k ,

then the
r r
r
magnitude of the projection of x 3y on z

r
r
x 5 3i 2 6 j 2 k , y 5 i 1 4 j 2 3k
r r
r
r
z 5 3i 2 4 j 2 12k x 3y z U

U :

is :

86.

(1)

12

(1)

12

(2)

15

(2)

15

(3)

14

(3)

14

(4)

13

(4)

13

Let A and E be any two events with 86.


positive probabilities :
Statement - 1 : P(E/A) P(A/E)P(E)
Statement - 2 : P(A/E) P(AE).
(1)

Both the statements are true

(2)

Both the statements are false

(3)

Statement - 1 is true, Statement - 2 is

A E U

-1 : P(E/A) P(A/E)P(E)
-2 : P(A/E) P(AE).
(1)
(2)
(3) -1 , -2

false
(4)

Statement - 1 is false, Statement - 2

(4)

-1 , -2

is true.

English : 46

Set : 10

Hindi : 46

Set : 10

87.

Let x , M and s 2 be respectively the mean, 87.


mode and variance of n observations

n
U

x1, x2, ..., xn


x , M s 2 di52xi2a,

x1, x2, ..., xn and di52xi2a, i51, 2, ..., n,


where a is any number.

i51, 2, ..., n ,

Statement I : Variance of d1, d2, ..., dn is


s2.

I : d1, d2, ..., dn U

Statement II : Mean and mode of

II : d1, d2, ..., dn


2 x 2a 2M2a

d 1 , d 2 , ..., d n are 2 x 2a and 2M2a,


respectively
(1)

Statement I and Statement II are

s2

(1)

I II

(2)

I II

(3)

I II

(4)

I II

both false
(2)

Statement I and Statement II are


both true

(3)

Statement I is true and Statement II


is false

(4)

Statement I is false and Statement II


is true

88.

periodic function with period :

f ( x )5 sin 4x 1 cos 2x
:

(1)

2p

(1)

2p

(2)

(2)

(3)

p
2

(3)

p
2

(4)

p
4

(4)

p
4

The function f ( x )5 sin 4x 1 cos 2 x , is a 88.

English : 47

Set : 10

Hindi : 47

Set : 10

89.

90.

43p
21
is : 89.
The principal value of tan cot
4

3p
4

(1)

(2)

3p
4

(3)

(4)

p
4

p
4

The contrapositive of the statement if I 90.


am not feeling well, then I will go to the

43p

tan21 cot

3p
4

(1)

(2)

3p
4

(3)

(4)

p
4

p
4

SS , UUU

doctor is :
(1)

If I am feeling well, then I will not


go to the doctor

(2)

If I will go to the doctor, then I am


feeling well

(3)

If I will not go to the doctor, then I


am feeling well

(4)

If I will go to the doctor, then I am


not feeling well.

(1)

SS , UUU

(2)

UUUU , SS

(3)

UUUU ,
SS
UUUU , SS

(4)

-o0o-

English : 48

-o0o-

Set : 10

Hindi : 48

Set : 10

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