Jasmine Gosha

Final Lab Report

Chemistry 1212K
Spring 2014
Professor LeCroix/Finnegan
Tuesday 10AM-1PM

Table of Contents
Page 1 - Synthesis Procedure #1: & Analysis of % Halide
Page 2- Standardization of HCl
Page 3- Analysis of NH
3

Page 4- Preparation and Standardization of 0.1M Na
2
S
2
O
3

Page 5- Analysis of % C0+3 using Standardized 0.1M Thiosulfate



Overall Introduction:
The main purpose of the entire series of experiments was to help us learn calculate an
empirical formula from a compound we synthesized.
A. Synthesis Procedure #1:
I. Introduction: The purpose of this experiment is perform a synthesis of a cobalt
compound to obtain a batch of solid product.
II. Procedure: Refer to page 17 of the Georgia State University Chemistry 1212K Lab
Manual (Spring 2014)
III. Data
% yield: 46.43% yield
IV. Calculations
a. Sample Calculations
i. (g CoCl
2
.6H
2
O)/MW CoCl
2
.6H
2
O)= Moles Co
+2

ii. (g /MW)=Moles Co
+3

iii. (Moles Co
+3
/Moles Co
+2
) * 100= % yield of Co
b. Actual Calculations
i. (12 g CoCl
2
.6H
2
O)/237.93 CoCl
2
.6H
2
O)=.0504 Moles Co
+2

ii. (6.6728g Co(NH
3
)
6
Cl
3
H
2
O /285.28g/mol)=.0234 Moles Co
+3

iii. (.0234Moles Co
+3
/.0504 Moles Co
+2
) * 100=46.43 % yield of Co
V. Conclude: The percent yield of cobalt in the cobalt compound is 46.43%.
B. Analysis of % Halide
I. Introduction: The purpose of this experiment is to obtain the percent Halide (Cl
-
or
Br
-
) in the synthesized cobalt compound.
II. Procedure: Refer to page 23-25 of the Georgia State University Chemistry 1212K Lab
Manual (Spring 2014)
III. Data
Crucible
Mass of
Crucible(g)
Mass of
Co-
sample(g)
Mass of
precipitate(g)
%halide in
Co sample
Average % Average
Deviation
1 31.6777g .2435 .36178 36.75% 36.38% .37%
2 30.6817g .2480 .36105 36.01%

IV. Calculations:
1. Sample Calculations:
a. (Mass precipitate)(Molecular weight of Cl)/ (formula weight) = (grams of
Cl)
b. %Cl= (grams of Cl)/ (grams of Co) X 100
c. Average: (Crucible 1 %Halide)+(Crucible 2 %Halide)/2
d. % Deviations: (average Crucible 1%halide)+(average Crucible 2
%halide)/2
2. Actual Calculations:
Crucible 1 Crucible 2
(.36145g)(35.45g/mol)/(143.3g/mol)=.0895
gCl

(.0895g)/(.2435g)X100= 36.75%
(.36105g)(35.45g/mol)/(143.3g/mol)=.0893
gCl

(.0893g)/(.2435g)X100=36.01%

V. Conclude: The average percent Halide was 36.38%. .37%
C. Standardization of HCl
I. Introduction: The purpose of this experiment was to prepare and standardize an HCl
solution.
II. Procedure: Refer to page 25 of the Georgia State University Chemistry 1212K Lab
Manual (Spring 2014)
III. Formula: (HOCH
2
)
3
CNH
2
+ HCl (HOCH
2
)
3
CNH
3
+
+ Cl
-

IV. Data
Average Molarity: .2716+.2692+.2709/3=.2706M
Average Deviation= .0009M
V. Calculations
1. Sample Calculation:
a. Moles of THAM

=(grams of THAM/ MW of THAM)
b. Molarity= Moles of THAM/HCL Liters used in titration
2. Actual Calculations
a. Trial 3
i. (.9508 g of THAM/ 121.14 of THAM)= .007849 Moles of THAM
ii. .007849 Moles of THAM/.0289L HCL = .2716M
b. Trial 4
i. (.9524 g of THAM/ 121.14 of THAM)= .007862 Moles of THAM
ii. .007862 Moles of THAM/.0292L HCL = .2692M
c. Trial 5
i. (.9549 g of THAM/ 121.14 of THAM)= .007883 Moles of THAM
ii. .007883 Moles of THAM/.0291L HCL = .2709M
Trial: THAM
weight (g)
Initial
Volume (mL)
Final Volume
(mL)
Total
Volume (L)
Molarity Deviation
1 .9582 0 29.2 .0292 omitted
2 1.0631 .3 32.60 .0323 omitted
3 .9508 0 28.9 .0289 .2716M .0010M
4 .9524 0 29.2 .0292 .2692M .0014M
5 .9549 0 29.1 .0291 .2709M .0003M
VI. Discuss: The first two titrations are excluded from the calculations because the
results were yellow instead of green. The results turned yellow too quickly before a
good reading was recorded.
VII. Conclude: The average molarity of the standardization of HCl was .2706M .0009M.
D. Analysis of % NH
3

I. Introduction: The purpose of this experiment is obtain the % NH
3
in the synthesized
cobalt compound using the previously prepared HCl solution
II. Procedure: Refer to page 26-28 of the Georgia State University Chemistry 1212K Lab
Manual (Spring 2014)
III. Formula: NH
3
+HCl NH
4
+
+ Cl
-

IV. Data
Trial: Weight
(g)
Initial
Volume
(mL)
Final
volume
(mL)
Total
volume
(L)
%NH
3
Deviation
1 .3762 0 28.5 .0285 34.85% .03%
2 .3703 0 29.2 .0292 36.27% 1.45%
3 .3740 0 27.1 .0271 33.33% 1.49%
Average % NH
3
= 34.85+36.27+33.33/3= 34.82%
Average Deviation= .99%
V. Calculations
1. Sample Calculations:
a. Molarity HCL*Liters titrated =Moles HCL
b. Moles HCL*formula weight = Grams NH
3

c. (gram NH
3
/gram sample) * 100= %NH
3

2. Actual Calculations:
a. Trial 1
i. .2706M HCL*.0285L =.007712 Moles HCL
ii. .007712 Moles HCL* 17 g/mol = .1311 g NH
3

iii. ( .1331 g NH
3
/.3762 g) * 100= 34.85 %NH
3

b. Trial 2
i. .2706M HCL*.0292L =.007902 Moles HCL
ii. .0087902 Moles HCL* 17 g/mol =.1343g NH
3

iii. ( .1343 g NH
3
/ .3703g) * 100= 36.27%NH
3

c. Trial 3
i. .2706M HCL*.0271L = .007333Moles HCL
ii. .007333 Moles HCL* 17 g/mol = .1247 g NH
3

iii. ( .1247g NH
3
/ .3740 g) * 100= 33.33%NH
3

VI. Conclude: The average percent of NH
3
is 34.82% .99%.
E. Preparation and Standardization of 0.1M Na
2
S
2
O
3

I. Introduction : The purpose of this experiment is to prepare and standardize the
Na
2
S
2
O
3
solution.
II. Procedure: Refer to page 29 of the Georgia State University Chemistry 1212K Lab
Manual (Spring 2014)
III. Formula: KIO
3
+ 6HCl + 6 Na
2
S
2
O
3
3 Na
2
S
4
O
6
+ KI + 3H
2
O + 6 NaCl
IV. Data:

Avera
ge
Molar
ity
=.105
1M+.1059M+.1070M/3=.1060M
Average Deviation = .0006
V. Calculations
3. Sample Calculation:
a. Moles of KIO
3
=(grams of KIO
3
/ MW of KIO
3
)
b. Moles of Na
2
S
2
O
3
= (6) X (Moles of KIO
3
)
c. Molarity= Moles of Na
2
S
2
O
3
/Liters of used in titration
4. Actual Calculations:
a. Trial 1:
i. Moles of KIO
3
: (.1121g/214g/mol)=.0005238 Moles KIO
3

ii. Moles of Na
2
S
2
O
3
=6*(.0005238mol)=.003143 Moles Na
2
S
2
O
3

iii. Molarity: (.003143 Moles Na
2
S
2
O
3
/.0299L Na
2
S
2
O
3
)= .1051M
b. Trial 2:
i. Moles of KIO
3
: (.1118g/214g/mol)=.0005224 Moles KIO
3

ii. Moles of Na
2
S
2
O
3
=6*(.0005224mol)=.003134 Moles Na
2
S
2
O
3

iii. Molarity: (.003134 Moles Na
2
S
2
O
3
/.0296L Na
2
S
2
O
3
)=.1059M
c. Trial 3:
i. Moles of KIO
3
: (.1198g/214g/mol)=.0005598 Moles KIO
3

ii. Moles of Na
2
S
2
O
3
=6*(.0005598mol)=.003359 Moles Na
2
S
2
O
3

iii. Molarity: (.003359 Moles Na
2
S
2
O
3
/.0314L Na
2
S
2
O
3
)=.1070M
VI. Conclude: The average molarity of the Na
2
S
2
O
3
solution is .1060M .0006M.
F. Analysis of % C0
+3
using Standardized 0.1M Thiosulfate
I. Introduction: The purpose of this experiment it obtain the percent cobalt in the
synthesized cobalt sample.
II. Procedure: Refer to page 31 of the Georgia State University Chemistry 1212K Lab
Manual (Spring 2014)
III. Formula: 2 Co(NH
3
)
4
Cl
3
+ 2 S
2
O
3
2-
2 Co
+2
+ S
4
O
6
2-
+ 8 NH
3
+ 6 Cl
-

IV. Data
Trial: Weight
KIO
3
(g)
Weight
KI (g)
Initial
Volume
(mL)
Final
Volume
(mL)
Total
Volume
(L)
Molarity
Na
2
S
2
O
3

Deviation
1 .1121 3.0678 0 29.9 .0299 .1051M .0009
2 .1118 3.0934 0.3 29.9 .0296 .1059M .0001
3 .1198 3.0167 0 31.4 .0314 .1070M .0010
Trial Weight
Co (g)
Initial Volume
(mL)
Final
Volume (mL)
Total
Volume (L)
% Co
+3
Deviation
1 .5122 .20 17.7 .0175 21.2% .2%
2 .5106 .40 17.8 .0174 21.28% .12%
3 .5096 .30 17.6 .0173 21.2% .2%
Average % Co
+3
= 21.2+21.28+21.2/3= 21.4% Co
+3
Average Deviation= .17%
V. Calculations
1. Sample Calculations
a. (Molarity Na
2
S
2
O
3
*Liters Na
2
S
2
O
3
)=Moles S
2
O
3
-2

b. (moles Co
+3
*formula weight)= Grams of Co
+3

c. (Grams Co
+3
/Grams of sample) * 100=% Co
+3

2. Actual Calculations:
a. Trial 1
i. (.1060M Na
2
S
2
O
3
*.0175 L Na
2
S
2
O
3
)=.001855Moles S
2
O
3
-2

ii. (.001855moles Co
+3
*58.93g/mol)= .1081 g Co
+3

iii. (.1081 g Co
+3
/.5122 g) * 100= 21.2% Co
+3

b. Trial 2
i. (.1060M Na
2
S
2
O
3
*.0174 L Na
2
S
2
O
3
)=.001844Moles S
2
O
3
-2

ii. (.001844moles Co
+3
*58.93 g/mol)= .1087 g of Co
+3

iii. (.1087 g Co
+3
/.5106 g) * 100= 21.28% Co
+3

c. Trial 3
i. (.1060M Na
2
S
2
O
3
*.0173 LNa
2
S
2
O
3
)=.001834Moles S
2
O
3
-2

ii. (.001834moles Co
+3
*58.93 g/mol)=.1081 g of Co
+3

iii. (.1081g Co
+3
/.5096 g) * 100= 21.2% Co
+3


VI. Conclude: The average percent Cobalt in this Compound is 21.4% .17%.
Overall Conclusion:
The total percentages equal 92.6% and leaving the last 7.4% to be water. The
empirical formula of the cobalt compound is Co(NH
3
)
6
Cl
3
H
2
O.