MATERIAL BALANCE FOR SPEARLUBE NSL

MAIN MIXER

300.3

A
kg Fentamine
B
35.035 kg IPA
C
125.125 kg Acetic Acid
270.27

kg NP10

F
10000
Component
IPA
HAc
Water
Fentamine
NP10

D
9279.27

Assumption:
Basis:
10000

kg Water

0.1
% loss due to tank accumulation
kg Spearlube NSL

Loss:
10000

0.001

10

kg loss

A
A

+ B
+ B

+ C
+ C

+ D
+ D

+ E
+ E

=
=

=
=

0.027
270.27

x
10010
kg Fentamine

Isopropyl Alcohol Balance:

B
=
B
=

0.0035
35.035

x
kg IPA

10010

Acetic Acid Balance:

C
C

=
=

0.0125
x
125.125 kg Hac

10010

D
D

=
=

0.927
x
9279.27 kg Water

10010

E
E

=
=

OMB:

Fentamine Balance:
A
A

Water Balance:

NP10 balance:
0.03
300.3

x
kg NP10

10010

F
10000

kg Spearlube NSL
%
0.35
1.25
92.7
2.7
3
100

Mass
35
125
9270
270
300
10000

MATERIAL BALANCE FOR SPEARCLEAN LA

MAIN MIXER

1652.271 kg Na. Gluconate

A

D
10000

B
1652.271 kg Na. Metasilicate

Component
Na. Gluconate
Na. Metasilicate
EDTA
Water

C
6705.45876 kg EDTA Solution
Component
EDTA
Water

Assumption:
Basis:
10000

%
3.490795
96.5092
100

kg
234.0738
6471.385
6705.459

0.1
% loss due to tank accumulation
kg Spearclean LA

Loss:
10000

0.001

10

kg loss

A
A

+
+

B
B

+
+

C
C

=
=

OMB:

Na. Gluconate Balance:

A
A

=
=

0.165062
x
10010
1652.271 kg Na. Gluconate

Na. Metasilicate Balance:

B
=
B
=

0.165062
x
10010
1652.271 kg Na. Metasilicate

EDTA Balance:
C
C

=
=

0.023384
x
234.0738 kg EDTA

10010

C
C

=
=

0.646492
x
6471.385 kg Water

10010

Water Balance:

D
10000

kg Spearclean LA
%
16.5062
16.5062
2.3384
64.6492
100

kg
1650.62
1650.62
233.84
6464.92
10000

ENERGY BALANCE
MAIN MIXER
Assumptions:
Raw materials enter the mixer at room temperature (25C)

Temperature Inlet:
Temperature outlet:
Cp Values:
Water
EDTA
Na.Gluconate
Na. Metasilicate

298.15
308.15

K
K
Unit
J/kmol K
J/mol K
J/mol K
J/mol K

Reference
Table 2-153 Perry's
Table 2-350 Perry's
Table 2-350 Perry's
Table 2-350 Perry's

MW (kg/kmol)
18.01528

Subtotal (kmol)
358.857592
0.800164249
5.87116739
12.89546875
378.4243924

72459.65845
374.7
268.63
119.27

Calculation of kmoles (Outlet)

Mass (kg)
Water
6464.92
EDTA
233.84
Na.Gluconate
1650.62
Na. Metasilicate
1650.62
Mixture
10000

Temp. Diff.

292.24

281.14
128

Calculation of kmoles (Inlet)

Water
EDTA
Na.Gluconate
Na. Metasilicate

Mass (kg)
6471.38492
234.07384
1652.27062
1652.27062

Calculation of kmoles (Accumulation)

Mass (kg)
Water
6.46492
EDTA
0.23384
Na.Gluconate
1.65062
Na. Metasilicate
1.65062

MW (kg/kmol)
18.01528
292.24
281.14
128

Subtotal (kmol)
359.2164496
0.800964413
5.877038557
12.90836422

MW (kg/kmol)
18.01528
292.24
281.14
128

Subtotal (kmol)
0.358857592
0.000800164
0.005871167
0.012895469

Hloss=Hgain
H=nCpT
Calculation of Q
Water
EDTA
Na.Gluconate
Na. Metasilicate
Total

260026985.5
2998215.439
15771716.96
15380425.58
294177343.5
294177.3435

J
kJ

10

Calculation of Heat of Mixing

Moles (kmol)
Heat of Mixing
378.4243924

Q (J)
294177.3435

Heat of Mixing (J/kmol)

777.3741582

MATERIAL BALANCE FOR SPEARLUBE SDL

MAIN MIXER
11.39138

9396.387

kg NP10

kg Surfactant
A

56.94689 kg Acetic Acid

G
10000
Component
Surfactant
IPA
EDTA
NP10
HAc
SLES
Water

B
113.89378 kg SLES
E
317.48717

Assumption:
Basis:

10000

kg IPA

F
113.89378
1138.9378

kg EDTA
kg Water

0.1
% loss due to tank accumulation
kg Spearlube SDL

Loss:
10000

0.001

10

kg loss

A
A

+ B
+ B

+ C
+ C

+ D
+ D

+ E
+ E

+ F
+ F

A
A

=
=

0.9387
9396.387

x
kg Surfactant

10010

E
E

=
=

0.031717
317.48717

10010

kg IPA

F
F

=
=

0.011378
113.89378

x
kg EDTA

10010

C
C

=
=

0.001138
11.39138

x
kg NP10

10010

D
D

=
=

0.005689
56.94689

x
kg Acetic Acid

10010

B
B

=
=

0.011378
113.89378

x
kg SLES

10010

OMB:

Surfactant Balance:

Isopropyl Alcohol Balance:

EDTA Balance:

NP10 Balance:

HAc Balance:

SLES Balance:

=
=

ENERGY BALANCE
Cp Values
Surfactant
SLES
NP10
IPA
Acetic Acid
EDTA

132448.4053
608230
1012610
156880.4353
123864.2201
374700

Unit
J/kmol K
J/kmol K
J/kmol K
J/kmol K
J/kmol K
J/kmol K

Reference
Table 2-350 Perry's
Table 2-350 Perry's
Table 2-350 Perry's
Table 2-153 Perry's
Table 2-153 Perry's
Table 2-350 Perry's

Hloss=Hgain
H=nCpT

Inlet Temp:
Outlet Temp:
Difference

For Surfactant:
Inlet Temp:
Outlet Temp:
Difference

K
372.15
313.15
-59

Cp (J/kmol K)
132448.4053
608230
1012610
156880.4353
123864.2201
374700

Q (J)
-1198003070
2474057.636
314591.5991
12431162.76
1761952.236
2190459.863
-1178830846

kmoles
153.306
0.271176
0.020712
5.282648
0.948325
0.389727
160.2186

Mass of Output
9.396387
146.5836372
125.9115858
892.656765
340.1492094
165.3764112
48.8612124
120.2737536
30.0684384
7517.1096
9396.387

%
0.1
1.56
1.34
9.5
3.62
1.76
0.52
1.28
0.32
80
100

Cp (J/kmol K)
305578
253550
201530
357590
409510
461638.1
513650
498530
483410
72459.65845
132448.4053

Q (J)
-1178830846

Heat of Mixing (J/kmol)

-7357640.464

C
25
40

K
298.15
313.15
15

Mass (kg)
9396.387
113.89378
11.39138
317.48717
56.94689
113.89378
10010

MW (kg/kmol)
61.291706
420
550
60.1
60.05
292.24

Calculation of Q

Surfactant
SLES
NP10
IPA
Acetic Acid
EDTA
Total

Calculation of Cp of Surfactant
Component
Na.Caprolate
Na.Caprylilate
Na.Caprilate
Na.Laurate
Na.Myrystilate
Na.Palmitate
Na.Stearate
Na.Oleate
Na.Linoleate
Water
Total

MW (Soap)
138.14176
166.19176
194.24176
222.30176
250.35176
278.40176
306.46176
304.44176
304.43176
18.01528
61.291706

Calculation of Heat of Mixing

Moles (kmol)
Heat of Mixing
160.2185989

EDTA MIXER

114.0075598 kg EDTA

kg Spearlube SDL
%
93.87
3.1717
1.1378
0.1138
0.5689
1.1378
100

1140.075598
Assumption:
Basis:

113.89378

kg Water

0.1
% loss due to tank accumulation
kg EDTA in EDTA solution

Loss:
1252.83158

0.001

1.2528316

A
A

+
+

B
B

=
=

C
1252.8316

A
A

=
=

0.090909
114.0075598

x
kg EDTA

1254.0844

B
B

=
=

0.90909
1140.075598

x
kg Water

1254.0844

374700
72459.65845

Unit
J/kmol K
J/kmol K

Reference
Table 2-350 Perry's
Table 2-153 Perry's

Q (J)

kmol

OMB:

EDTA Balance:

G
10000

Water Balance:

ENERGY BALANCE
Cp Values
EDTA
Water

Hloss=Hgain
H=nCpT

Inlet Temp:
Outlet Temp:
Difference

C
25
65

K
298.15
338.15
40

Mass (kg)

MW (kg/mol)

Calculation of Q
Cp (J/kmol k)

EDTA
Water
Total

113.89378
1138.9378
1252.83158

292.24
18.01528

374700
72459.65845

Calculation of Heat of Mixing

Moles (kmol)
Q (J)
Heat of Mixing (J/kmol)
Heat of Mixing
63.61038178 189079108.8
2972456.752

5841226.302 0.3897269
183237882.5 63.220655
189079108.8 63.610382

SAPONIFICATION TANK

1889.21272 kg Coco Oil

1252.83158 kg EDTA solution
Component
EDTA
Water

kg loss

%
9.0909
90.909
99.9999

kg
113.8938
1138.938
1252.832

Component
Caproic
Caprylic
Capric
Lauric
Myristic
Palmitic
Stearic
Oleic
Linoleic

Assumption:
Basis:

%
0.5
7.8
6.7
47.5
18.1
8.8
2.6
6.4
1.6
100

0.1
9396.387

% loss due to tank accumulation

kg Surfactant

Loss:
9396.387

0.001

A
A

+
+

B
B

Coco Oil

NaOH

%
0.5
7.8
6.7
47.5
18.1
8.8
2.6
6.4
1.6
100

MW
116.16
144.21
172.26
200.32
228.37
256.42
284.48
282.46
282.45

Subtotal
0.5808
11.24838
11.54142
95.152
41.33497
22.56496
7.39648
18.07744
4.5192
212.41565

OMB:

Chemical Reaction:

Component
Caproic
Caprylic
Capric
Lauric
Myristic
Palmitic
Stearic
Oleic
Linoleic

Calculation for the Composition of Product Stream

Component
Na.Caprolate
Na.Caprylilate

MW (Soap)
138.14176
166.19176

MW (Oil)
116.16
144.21

Mass of Output
9.405783387
146.7302208

Na.Caprilate
Na.Laurate
Na.Myrystilate
Na.Palmitate
Na.Stearate
Na.Oleate
Na.Linoleate
Total

194.24176
222.30176
250.35176
278.40176
306.46176
304.44176
304.43176

172.26
200.32
228.37
256.42
284.48
282.46
282.45

126.0374974
893.5494218
340.4893586
165.5417876
48.91007361
120.3940274
30.09850684
1881.156677

148.185715
Water in B

+ Water in B
=

+ Water in EDTA
6237.503195

B
%NaOH

=
=

6566.62194
5.011994718

%
0.5
7.8
6.7
47.5
18.1
8.8
2.6
6.4
1.6
100

Cp (J/kmol K)
286940
234920
182900
263360
390980
443000
495020
479900
464780
317880.74

Hf (J/kmol)
-421350
-462610
-503870
-545130
-586390
-627650
-668910
-668910
-668910

%
0.1
1.56
1.34
9.5
3.62
1.76
0.52
1.28
0.32
80
100

Cp (J/kmol K)
305578
253550
201530
357590
409510
461638.1
513650
498530
483410
72459.65845
132448.4053

Hf (J/kmol)

Water Balance:

NaOH Balance:

ENERGY BALANCE
Cp Values
Coco Oil
Component
Caproic
Caprylic
Capric
Lauric
Myristic
Palmitic
Stearic
Oleic
Linoleic
Total
Surfactant
Component
Na.Caprolate
Na.Caprylilate
Na.Caprilate
Na.Laurate
Na.Myrystilate
Na.Palmitate
Na.Stearate
Na.Oleate
Na.Linoleate
Water
Total
Sodium Hydroxide
Calculation of Specific Heat of NaOH (Table 2-173 Perry's)

Specific Heat

Mol Fraction cal/g C

0.02321255 0.999409

J/kmol K
167373.024

Mole Fraction
cal/g C

0
1

0.5
0.985

Calculation of Q
Heats of Reaction
Caproic
Caprylic
Capric
Lauric
Myristic
Palmitic
Stearic
Oleic
Linoleic
Total

J
31876.4887
453818.913
363273.032
2434631.58
886128.981
414677.707
118617.073
293917.806
73481.8652
5070423.44

Heats of Solution
Caproic
Caprylic
Capric
Lauric
Myristic
Palmitic
Stearic
Oleic
Linoleic
Total

Total Q

Moles (kmol) Cp (J/kmol K)

0.06808791
286940
0.88289709
234920
0.64886921
182900
4.01953373
263360
1.3600438
390980
0.59461473
443000
0.15959601
495020
0.39545832
479900
0.09886783
464780

15126861.9 J

Q (J)
78148.5768
829640.735
474712.7141
4234337.609
2126999.697
1053657.303
316012.8642
759121.7936
183807.1561
10056438.45

NaOH MIXER

9396.387

kg Surfactant
329.448

6566.62194
Component
NaOH
Water

Component
Na.Caprolate
Na.Caprylilate
Na.Caprilate
Na.Laurate
Na.Myrystilate
Na.Palmitate
Na.Stearate
Na.Oleate
Na.Linoleate
Water

kg NaOH Solution
%
5.011994718
94.98800528
100

%
0.1
1.56
1.34
9.5
3.62
1.76
0.52
1.28
0.32
80
100

Assumption:
Basis:

6566.62

Loss:
6566.62
OMB:
=

9.396387

=
=

C
9396.387

Surfactant

kg loss

A
A
NaOH Balance:
A
A
Water Balance:

Water

B
B

ENERGY BALANCE
Reference
Table 2.2 Perry's
Table 2.2 Perry's
Table 2.2 Perry's
Table 2.2 Perry's
Table 2.2 Perry's
Table 2.2 Perry's
Table 2.2 Perry's
Table 2.2 Perry's
Table 2.2 Perry's

Conversion
Mass of Input
8.787879271
141.4695433

Calculation of Specific Heat of NaOH (Table 2-173 Pe

Mole Fraction
Mole Fraction
cal/g C

0.02321
0
1

Hloss=Hgain
H=nCpT

Inlet Temp:
Outlet Temp:
Difference

0.9
Mass of NaOH Mass of Water
2.723516303
1.226263215
35.31588349
15.90097654

Moles of Water
0.068067952
0.882638324

Calculation of Q

C
25
279.65

124.1935668
894.6588845
345.103558
169.4123437
50.44652496
124.1123972
31.02801997
1889.212718

25.95476841
160.7813491
54.40175194
23.78458924
6.383840335
15.81833285
3.954713114
329.1187447

11.68613447
72.39180241
24.49438881
10.7090113
2.874324111
7.122204367
1.780609579
148.1857148

0.648679037
4.018355663
1.359645191
0.594440459
0.159549233
0.395342419
0.098838851

NaOH
Water
Total

Calculation of Outlet Temperature

Heat of Solution
Theo. Outlet Temp.
=
kg Water

Mass (kg)
329.448
6243.74
6573.19

kcal/mol
10.18
K
552.8

7524.62671
Cp of Water
True Outlet Temp.

kg NaOH Solution
%

72459.7
C
95

Calculation of Mass of Water Required

H=nCpT=Q
Inlet Temp. of Water

Mass of Water
Inlet Temp:

368.15

C
25
72871.5

K
Calculation of Viscosity of NaOH

Reference
n x Hf (J)
Table 2-340 Perry's -31876.48873
Table 2-340 Perry's -453818.9128
Table 2-340 Perry's -363273.0321
Table 2-340 Perry's -2434631.578
Table 2-340 Perry's -886128.9811
Table 2-340 Perry's -414677.7065
Table 2-340 Perry's -118617.0733
Table 2-340 Perry's -293917.8064
Table 2-340 Perry's -73481.86525

Outlet Temp:
Reference

Inlet Temp:
Outlet Temp:

99
372.15

n (kmol)
0.075653231
0.980996764
0.720965789
4.466148585
1.511159776
0.660683034
0.177328898
0.439398135
0.109853142
C
K

n x Hf (J)
0
0
0
0
0
0
0
0
0
na
0
552.8004984 K
372.15
K

n (kmol)
0.068087908
0.882897087
0.64886921
4.019533726
1.360043798
0.594614731
0.159596008
0.395458321
0.098867828
na

Water Generation
0
0
0
0
0
0
0
0
0
na
0

Calculation of Density of NaOH (Table 2-92 Perry's)

80
4
1.0139
8
1.056
5.011994718
1.02455

Temp. Diff.:

C
6566.62194 kg NaOH Solution

kg NaOH
Component
%
NaOH
5.011994718
Water
94.98800528
100

6243.741 kg Water

0.1
% loss due to tank accumulation
kg NaOH Solution

0.001

6.566622

+
+

B
B

=
=

C
6566.622

=
=

0.050119947
329.4478635

x
kg NaOH flakes

6573.189

=
=

0.949880053
6243.740698

x
kg Water

6573.189

pecific Heat of NaOH (Table 2-173 Perry's)

cal/mol K
J/kmol K
0.999409
167373.024
0.5
0.985

K
298.15
552.8004984
254.6504984

kg loss

MW (kg/mol)
40
18.01528
19.11715301

Cp (J/kmol K)

Q (J)

167373.024

14654900302

utlet Temperature
J/kmol
42621624

Reference
Table 2-182 Perry's

C
279.6504984
J/kmol K

Table 2-153 Perry's

K
348.15

ass of Water Required

K
298.15
kg

scosity of NaOH

mPa s / cP
0.3752279
0.330167926
0.352697913

ensity of NaOH (Table 2-92 Perry's)

100
95
1.0009
1.0432
1.011601844
1.014837811

Temp
90
100
95

COCO OIL HEATER

1891.10193 kg Coco Oil

Assumption:
Basis:

1889.213 kg Heated Coco Oil

0.1
% loss due to tank accumulation
1889.213 kg Heated Coconut Oil

Loss:
1889.213

A
A
A

=
=
=

0.001

1.889213

OMB:
Loss
+
1.889212718
+
1891.10193 kg Coco oil

ENERGY BALANCE
Cp Values (Table 2-353 Perry's)
Component
Caproic
Caprylic
Capric
Lauric
Myristic
Palmitic
Stearic
Oleic
Linoleic
Total

Inlet Temp:
Outlet Temp:
Difference

%
0.5
7.8
6.7
47.5
18.1
8.8
2.6
6.4
1.6
100

Cp (J/kmol K)
286940
234920
182900
263360
390980
443000
495020
479900
464780
317880.74

C
25
95

K
298.15
368.15
70

Calculation of Q
Mass (kg) MW (kg/kmol) Cp (J/kmol K)
Q (J)
Coco Oil
1889.213
212.41565
317880.74
197904926

B
1889.213

kg loss

RAW MATERIALS REQUIRED FOR OPERATION

NaOH STORAGE TANK
Spearlube SDL

1 Month Operation
329.4478635 kg

6588.95727

1891.10193 kg

37822.03861

COCONUT OIL STORAGE TANK

Spearlube SDL

ISOPROPYL ALCOHOL STORAGE TANK

Spearlube SDL
Spearlube NSL

NP10 STORAGE TANK

Spearlube SDL
Spearlube NSL

ACETIC ACID STORAGE TANK

Spearlube SDL
Spearlube NSL

EDTA STORAGE TANK

Spearlube SDL
Spearclean LA

317.48717 kg
35.035 kg
352.52217 kg

7050.4434

11.39138 kg
300.3 kg
311.69138 kg

6233.8276

56.94689 kg
125.125 kg
182.07189 kg

3641.4378

114.0075598 kg
234.07384 kg
348.0813998 kg

6961.627995

SODIUM METASILICATE STORAGE TANK

Spearclean LA
1652.27062 kg

33045.4124

SODIUM GLUCONATE STORAGE TANK

Spearclean LA
1652.27062 kg

33045.4124

FENTAMINE STORAGE TANK

Spearlube NSL

270.27 kg

5405.4

Viscosity
Coco Oil
EDTA Solution

Density