mL AgNO3
SeCN
Ag
E (v)
0.06363636
6.6E-15
-0.284
15
0.03846154
1.092E-14
-0.272
10
0.00129458
25
0.02
2.1E-14
-0.255
20
0.00168126
15
3.8668E-05
30
0.0125
3.36E-14
-0.243
27.5
0.00241678
23.75
9.8069E-05
35
0.00588235
7.14E-14
-0.223
32.5
0.00387593
30
0.00029183
39
0.0011236
3.738E-13
-0.181
37
0.01064033
34.75
0.0015032
39.5
0.00055866
7.518E-13
-0.163
39.25
0.03593002
38.125
0.01123986
39.6
0.00044643
9.408E-13
-0.157
39.55
0.05765783
39.4
0.07242603
39.7
0.00033445
1.2558E-12
-0.150
39.65
0.07425052
39.6
0.16592684
39.8
0.00022272
1.8858E-12
-0.139
39.75
0.10453249
39.7
0.30281974
39.9
0.00011123
3.7758E-12
-0.121
39.85
0.1784959
39.8
0.73963413
39.95
5.5586E-05
7.5558E-12
-0.103
39.925
0.35670542
39.8875
2.37612692
39.99
1.1112E-05
3.77958E-11
-0.062
39.97
1.03476137
39.9475
15.06791
40
3.2
2.05E-08
0.100
39.995
16.1871171
39.9825
606.094229
40.01
1.11099E-05
0.262
40.005
16.1850158
40
-0.21012543
40.05
5.55247E-05
0.303
40.03
1.03419003
40.0175
-606.033032
40.1
0.000110988
0.321
40.075
0.35613408
40.0525
-15.06791
40.2
0.000221729
0.339
40.15
0.17792456
40.1125
-2.37612693
40.3
0.000332226
0.349
40.25
0.10396115
40.2
-0.73963416
40.4
0.000442478
0.356
40.35
0.07367917
40.3
-0.30281978
40.5
0.000552486
0.362
40.45
0.05708648
40.4
-0.1659269
41
0.001098901
0.380
40.75
0.03535864
40.6
-0.07242612
45
0.005263158
0.420
43
0.01006826
41.875
-0.01124017
50
0.01
0.437
47.5
0.00330044
45.25
-0.00150396
55
0.014285714
0.446
52.5
0.00183404
50
-0.00029328
70
0.025
0.460
62.5
0.00095919
57.5
-8.7485E-05
POTENCIOMETRA
Primera Derivada
Segunda Derivada
0.400
0.300
0.200
0.100
0.000
0
10
20
30
40
50
60
70
80
-0.100
-0.200
-0.300
-0.400
mL AgNO3
17
15
Primera derivada
13
11
9
7
5
3
1
-1 38.5
39
39.5
40
40.5
41
mL AgNO3
POTENCIOMETRA
700
500
Segunda derivada
300
100
-100
39.5
39.6
39.7
39.8
39.9
40
40.1
40.2
40.3
40.4
40.5
-300
-500
-700
POTENCIOMETRA
mL AgNO3
Vol.
mEq
mEq
mEq
mEq
Ce4+
Ce4+
HNO2
NO3-
Ce3+
0.4
3.6
0.4
0.579
10
0.8
3.2
0.8
0.589
7.5
0.00208492
15
1.2
2.8
1.2
0.596
12.5
0.00138577
10
-0.00013983
25
0.607
20
0.00108921
16.25
-3.9542E-05
40
3.2
0.8
3.2
0.625
32.5
0.00118807
26.25
7.9083E-06
49
3.92
0.08
3.92
0.657
44.5
0.00357876
38.5
0.00019922
49.5
3.96
0.04
3.96
0.666
49.25
0.018082
46.875
0.00305331
49.6
3.968
0.032
3.968
0.669
49.55
0.0289448
49.4
0.03620935
49.7
3.976
0.024
3.976
0.673
49.65
0.03724078
49.6
0.0829598
49.8
3.984
0.016
3.984
0.678
49.75
0.05238141
49.7
0.15140626
49.9
3.992
0.008
3.992
0.687
49.85
0.08936275
49.8
0.36981348
49.95
3.996
0.004
3.996
0.696
49.925
0.17846725
49.8875
1.18805988
49.99
3.9992
0.0008 3.9992
0.717
49.97
0.51749506
49.9475
7.53395142
50
0.804
49.995
8.73130592
49.9825
328.552434
50.01
0.0008
0.977
50.005
17.3020976
50
857.079166
50.05
0.004
1.018
50.03
1.03447561
50.0175
-650.704879
50.1
0.008
1.036
50.075
0.35641951
50.0525
-15.0679131
50.2
0.016
1.054
50.15
0.17820976
50.1125
-2.3761301
50.3
0.024
1.064
50.25
0.10424603
50.2
-0.73963732
50.4
0.032
1.072
50.35
0.07396373
50.3
-0.30282293
50.5
0.04
1.078
50.45
0.05737073
50.4
-0.16593004
51
0.08
1.095
50.75
0.03564195
50.6
-0.07242925
60
0.8
1.155
55.5
0.00657778
53.125
-0.00611877
75
1.178
67.5
0.00157054
61.5
-0.00041727
90
3.2
1.190
82.5
0.00080559
75
-5.0996E-05
POTENCIOMETRA
E (v)
Primera Derivada
Segunda Derivada
1.3
1.2
1.1
1.0
0.9
0.8
0.7
0.6
0.5
0
10
20
30
40
50
60
70
80
90
100
50.2
50.4
50.6
50.8
51
mL de Ce4+
Primera derivada
13
11
9
7
5
3
1
-1 49
49.2
49.4
49.6
49.8
50
mL Ce4+
POTENCIOMETRA
1000
800
600
Segunda derivada
400
200
0
49.5
49.6
49.7
49.8
49.9
50
50.1
50.2
50.3
50.4
50.5
-200
-400
-600
-800
POTENCIOMETRA
mL de Ce4+
mL
KMnO4
mEq
2+
Fe
mEq
MnO4-
mEq
mEq
3+
2+
Fe
E (v)
Primera Derivada
Segunda Derivada
Mn
0.5
0.5
0.491
1.5
0.517
1.5
0.02521735
1.5
1.5
0.537
2.5
0.02084921
-0.00436814
0.5
0.563
3.5
0.02521735
0.00436814
4.5
0.25
2.25
2.25
0.583
4.25
0.04169841
3.875
0.02197475
4.9
0.05
2.45
2.45
0.627
4.7
0.10892113
4.475
0.14938382
4.95
0.025
2.475
2.475
0.645
4.925
0.36163991
4.8125
1.12319459
4.96
0.02
2.48
2.48
0.651
4.955
0.57889602
4.94
7.24187042
4.97
0.015
2.485
2.485
0.658
4.965
0.74481562
4.96
16.5919593
4.98
0.01
2.49
2.49
0.669
4.975
1.04762814
4.97
30.2812524
4.99
0.005
2.495
2.495
0.687
4.985
1.7872551
4.98
73.9626954
4.995
0.0025
2.4975
2.4975
0.705
4.9925
3.56934492
4.98875
237.611977
4.999
0.0005
2.4995
2.4995
0.746
4.997
10.3499012
4.99475
1506.79028
2.5
2.5
2.5
2.5
1.064
4.9995
318.026118
4.99825
123070.487
5.01
2.5
0.005
2.5
2.5
1.139
5.005
7.53241951
5.00225
-56453.3998
5.05
2.5
0.025
2.5
2.5
1.148
5.03
0.20689512
5.0175
-293.020976
5.1
2.5
0.05
2.5
2.5
1.151
5.075
0.0712839
5.0525
-3.01358263
5.2
2.5
0.1
2.5
2.5
1.155
5.15
0.03564195
5.1125
-0.47522602
5.3
2.5
0.15
2.5
2.5
1.157
5.25
0.02084921
5.2
-0.14792746
5.4
2.5
0.2
2.5
2.5
1.158
5.35
0.01479275
5.3
-0.06056459
5.5
2.5
0.25
2.5
2.5
1.159
5.45
0.01147415
5.4
-0.03318601
2.5
0.5
2.5
2.5
1.163
5.75
0.00712839
5.6
-0.01448585
2.5
2.5
2.5
1.167
6.5
0.0035642
6.125
-0.00475226
7.5
2.5
1.25
2.5
2.5
1.168
7.25
0.00229483
6.875
-0.00169249
2.5
2.5
2.5
1.170
8.25
0.00161119
7.75
-0.00068364
POTENCIOMETRA
1.2
1.1
1.0
0.9
0.8
0.7
0.6
0.5
0.4
0
5.02
5.04
5.06
5.08
10
mL de KMnO4
Primera derivada
250
200
150
100
50
0
4.9
4.92
4.94
4.96
4.98
5.1
-50
mL de KMnO4
POTENCIOMETRA
140000
120000
100000
Segunda derivada
80000
60000
40000
20000
0
4.9
4.92
4.94
4.96
4.98
5.02
5.04
5.06
5.08
-20000
-40000
-60000
-80000
mL de KMnO4
POTENCIOMETRA
5.1
Problema 21.28
Un electrodo selectivo para iones litio arroja los potenciales indicados en la tabla
siguiente, para las disoluciones patrn de
indicadas y tres muestras de
concentracin desconocida.
Disolucin (
0.100 M
+1.0
0.050 M
-30.0
0.010 M
-60.0
0.001 M
-138.0
Desconocida 1
-48.5
Desconocida 2
-75.3
(a) Trace una curva de calibrado del potencial del electrodo frente a
determine si el electrodo se comporta segn la ecuacin de Nernst.
POTENCIOMETRA
Disolucion(M)
E (v)
Logaritmo
0.1
1.00E-03
-1
0.05
-3.00E-02
-1.30103
0.01
-6.00E-02
-2
0.001
-1.38E-01
-3
Desconocida1
-4.80E-02
-1.6951952
Desconocida2
-7.50E-02
-2.1006006
2.00E-02
0.00E+00
-3.5
-3
-2.5
-2
-1.5
-1
-0.5
0
-2.00E-02
-4.00E-02
E (v)
-6.00E-02
-8.00E-02
y = 0.0666x + 0.0649
R = 0.9856
-1.00E-01
-1.20E-01
-1.40E-01
-1.60E-01
Logaritmo
POTENCIOMETRA
0.02017 M
0.00793 M
Problema 21.29
Se utiliza un electrodo de fluoruro para determinar la cantidad de flor en muestras
de agua potable. Los resultados de la tabla siguiente se obtienen para cuatro
disoluciones patrn y dos desconocidas. Se usan condiciones constantes de fuerza
inica y pH.
0.02
41.4
61.5
100.2
Desconocida 1
38.9
Desconocida 2
55.3
POTENCIOMETRA
Disolucion(M)
E (v)
Logaritmo
5.00E-04
2.00E-05
-3.30103
1.00E-04
4.14E-02
-4
5.00E-05
6.15E-02
-4.30103
1.00E-05
1.00E-01
-5
Desconocida1
3.89E-02
-3.94932432
Desconocida2
5.53E-02
-4.22635135
]. Determine si el
1.20E-01
1.00E-01
E (v)
8.00E-02
y = -0.0592x - 0.1949
R = 0.9991
6.00E-02
4.00E-02
2.00E-02
0.00E+00
-6
-5
-4
-3
Logaritmo
-2
-1
POTENCIOMETRA