Sebastian Teir
STEAM BOILER TECHNOLOGY The Basics of Steam Generation
Table of contents
Table of contents.................................................................................................................................. 2
Introduction.......................................................................................................................................... 3
Basics of boilers and boiler processes.................................................................................................. 5
A simple boiler................................................................................................................................. 5
A simple power plant cycle.............................................................................................................. 6
Carnot efficiency.............................................................................................................................. 6
Properties of water and steam.......................................................................................................... 7
Boiling of water ........................................................................................................................... 7
Effect of pressure on evaporation temperature ............................................................................ 8
Basics of combustion ....................................................................................................................... 9
Products of combustion................................................................................................................ 9
Types of combustion.................................................................................................................... 9
Combustion of solid fuels .......................................................................................................... 10
Combustion of coal .................................................................................................................... 10
Main types of a modern boiler ....................................................................................................... 10
Heat exchanger boiler model ......................................................................................................... 12
Heat exchanger basics................................................................................................................ 12
T-Q diagram............................................................................................................................... 12
Heat recovery steam generator model........................................................................................ 14
Heat exchanger model of furnace-equipped boilers .................................................................. 15
References...................................................................................................................................... 16
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STEAM BOILER TECHNOLOGY The Basics of Steam Generation
Introduction
The world energy consumption has doubled in the last thirty years and it keeps on increasing with
about 1.5% per year (Figure 1). While the earth's oil and gas reserves are expected to deplete after
less than a hundred years, the coal reserves will last for almost five hundred years into the future
(taking into account estimations of fossil fuel reserves that have not yet been found) (Figure 2). In
Finland, 50% of the electrical power produced, is produced in steam power plants. But there are
more reasons to why electricity generation based on steam power plant will continue to grow and
why there still will be a demand for steam boilers in the future:
The world-wide dependency upon fossil fuels for power production (Figure 1, Figure 2, and
Figure 3)
The cost of the produced electricity is low
The technology has been used for many decades and is reliable and available
Wind and solar power are still expensive compared to steam power
The environmental impact of coal powered steam plants have under the past decade been
heavily diminished thanks to improved SO
x
and NO
x
reduction technology
The paper industry uses steam boilers as a vital utility to recycle chemicals and derive
electricity from black liquor (pulping waste)
Waste and biofuels can effectively be combusted in a boiler [1]
Coal
Hydroelectricity
Nuclear energy
Natural gas
Oil
*Prior to 1994 Combustible Renewables & Waste final consumption has been estimated based on TPES.
**Other includes geothermal, solar, wind, heat, etc.
Figure 1: Evolution from 1977 to 2002 of world primary energy consumption by fuel (Mtoe) [2]
3
STEAM BOILER TECHNOLOGY The Basics of Steam Generation
Coal
Gas
Oil
Figure 2: The worlds reserves-to-production ratio for fossil fuels. [2]
Coal
Hydroelectricity
Nuclear energy
Natural gas
Oil
Figure 3: Regional primary energy consumption pattern 2002. [2]
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STEAM BOILER TECHNOLOGY The Basics of Steam Generation
Basics of boilers and boiler processes
In a traditional context, a boiler is an enclosed container that provides a means for heat from
combustion to be transferred into the working media (usually water) until it becomes heated or a gas
(steam). One could simply say that a boiler is as a heat exchanger between fire and water. The
boiler is the part of a steam power plant process that produces the steam and thus provides the heat.
The steam or hot water under pressure can then be used for transferring the heat to a process that
consumes the heat in the steam and turns it into work. A steam boiler fulfils the following
statements:
It is part of a type of heat engine or process
Heat is generated through combustion (burning)
It has a working fluid, a.k.a. heat carrier that transfers the generated heat away from the
boiler
The heating media and working fluid are separated by walls
In an industrial/technical context, the concept steam boiler (also referred to as steam generator)
includes the whole complex system for producing steam for use e. g. in a turbine or in industrial
process. It includes all the different phases of heat transfer from flames to water/steam mixture
(economizer, boiler, superheater, reheater and air preheater). It also includes different auxiliary
systems (e. g. fuel feeding, water treatment, flue gas channels including stack). [3]
The heat is generated in the furnace part of the boiler, where fuel is combusted. The fuel used in a
boiler contains either chemically bonded energy (like coal, waste and biofuels) or nuclear energy.
Nuclear energy will not be covered in this material. A boiler must be designed to absorb the
maximum amount of heat released in the process of combustion. This heat is transferred to the
boiler water through radiation, conduction and convection. The relative percentage of each is
dependent upon the type of boiler, the designed heat transfer surface and the fuels that power the
combustion.
A simple boiler
In order to describe the principles of a
steam boiler, consider a very simple case,
where the boiler simply is a container,
partially filled with water (Figure 4).
Combustion of fuel produce heat, which
is transferred to the container and makes
the water evaporate. The vapor or steam
can escape through a pipe that is
connected to the container and be
transported elsewhere. Another pipe
brings water (called feedwater) to the
container to replace the water that has
evaporated and escaped.
Since the pressure level in the boiler
should be kept constant (in order to have
Figure 4: Simplified boiler drawing.
stable process values), the mass of the steam that escapes has to be equal to the mass of the water
that is added. If steam leaves the boiler faster than water is added, the pressure in the boiler falls. If
5
STEAM BOILER TECHNOLOGY The Basics of Steam Generation
water is added faster than it is evaporated, the pressure rises. If more fuel is combusted, more heat is
generated and transferred to the water. Thus, more steam is generated and pressure rises inside the
boiler. If less fuel is combusted, less steam is generated and the pressure sinks.
A simple power plant cycle
The steam boiler provides steam to a heat
consumer, usually to power an engine. In a
steam power plant a steam turbine is used for
extracting the heat from the steam and turning it
into work. The turbine usually drives a generator
that turns the work from the turbine into
electricity. The steam, used by the turbine, can
be recycled by cooling it until it condensates
into water and then return it as feedwater to the
boiler. The condenser, where the steam is
condensed, is a heat exchanger that typically
uses water from a nearby sea or a river to cool
the steam. In a typical power plant the pressure,
at which the steam is produced, is high. But
when the steam has been used to drive the
turbine, the pressure has dropped drastically. A
pump is therefore needed to get the pressure
back up. Since the work needed to compress a
fluid is about a hundred times less than the work
G
Figure 5: Rankine cycle
needed to compress a gas, the pump is located after the condenser. The cycle that the described
process forms, is called a Rankine cycle and is the basis of most modern steam power plant
processes (Figure 5).
Carnot efficiency
When considering any heat process or power
cycle it is necessary to review the Carnot
efficiency that comes from the second law of
thermodynamics. The Carnot efficiency
equation gives the maximum thermal efficiency
of a system (Figure 6) undergoing a reversible
power cycle while operating between two
thermal reservoirs at temperatures T
h
and T
c
(temperature unit Kelvin).
H
C
H
C H
T
T
T
T T
=
= 1
max
(1)
The maximum efficiency as a function of the
steam exhaust temperature can be plotted by
keeping the cooling water temperature constant.
Assuming the temperature of the cooling water
is around 20C (a warm summer day), the curve
gets the shape presented in Figure 7. Larger
temperature difference leads to a higher thermal
Hot reservoir Qh
(temperature Th)
Cold reservoir Qc
(Temperature Tc)
Wcycle
=
Qh - Qc
Figure 6: Carnot efficiency visualized
.
6
STEAM BOILER TECHNOLOGY The Basics of Steam Generation
efficiency.
Although no practical heat process is fully
reversible, many processes can be calculated
precisely enough by approximating them as
reversible processes.
To give a practical example of the use of this
theory on steam boilers, consider the Rankine
cycle example presented in Figure 5. The
temperature of the hot reservoir would then be
the temperature of the steam produced in the
boiler and the temperature of the cold reservoir
would be the temperature of the cooling water
drawn from a nearby river or lake (Figure 8).
The formula in Equation 1 can then be used to
calculate the theoretical maximum thermal
efficiency of the process.
Properties of water and steam
Water is a useful and cheap medium to use as a
working fluid. When water is boiled into steam
its volume increases about 1,600 times,
producing a force that is almost as explosive as
gunpowder. The force produced by this
expansion is the source of power in all steam
engines. It also makes the boiler a dangerous
device that must be carefully treated.
The theoretical amount of heat that can be
transferred from the combustion process to the
working fluid in a boiler is equivalent to the
change in its total heat content from its state at
entering to that at exiting the boiler. In order to
be able to select and design steam- and power-
Carnot efficiency
0
0,1
0,2
0,3
0,4
0,5
0,6
0,7
200 400 600 800 1000
Temperature [K]
Figure 7: Carnot efficiency graph example.
Hot reservoir Qh
(temperature Th)
Cold reservoir Qc
(Temperature Tc)
Wp Wt
Figure 8: Carnot efficiency applied on the
Rankine cycle.
generation equipment, it is necessary to thoroughly understand the properties of the working fluid
steam, the use of steam tables and the use of superheat. These fundamentals of steam generation
will be briefly reviewed in this chapter. When phase changes of the water is discussed, only the
liquid-vapor and vapor-liquid phase changes are mentioned, since these are the phase changes that
the entire boiler technology is based on. [4]
Boiling of water
Water and steam are typically used as heat carriers in heating systems. Steam, the gas phase of
water, results from adding sufficient heat to water to cause it to evaporate. This boiler process
consists of three main steps: The first step is the adding of heat to the water that raises the
temperature up to the boiling point of water, also called preheating. The second step is the
continuing addition of heat to change the phase from water to steam, the actual evaporation. The
third step is the heating of steam beyond the boiling temperature of water, known as superheating.
7
STEAM BOILER TECHNOLOGY The Basics of Steam Generation
The first step and the third steps are the
part where heat addition causes a
temperature rise but no phase change, and
the second step is the part where the heat
addition only causes a phase change. In
Figure 9, the left section represents the
preheating, the middle section the
evaporation, and the third section the
superheating. When all the water has been
evaporated, the steam is called dry
saturated steam. If steam is heated beyond
its saturation point, the temperature begins
to rise again and the steam becomes
superheated steam. Superheated steam is
defined by its zero moisture content: It
contains no water at all, only 100% steam.
Evaporation
During the evaporation the enthalpy rises
drastically. If water is evaporated at
atmospheric pressure from saturated liquid
to saturated vapour, the enthalpy rise
needed is 2260 kJ/kg, from 430 kJ/kg (sat.
Evaporation of water
20
40
60
80
100
120
140
160
180
0 500 1000 1500 2000 2500 3000
Net enthalpy of water [kJ/kg water]
T
e
m
p
e
r
a
t
u
r
e
[
C
]
Phase change
Figure 9: Water evaporation plotted in a
temperature-enthalpy graph.
water) to 2690 kJ/kg (sat. steam). When the water has reached the dry saturated steam condition, the
steam contains a large amount of latent heat, corresponding to the heat that was led to the process
under constant pressure and temperature. So despite pressure and temperature is the same for the
liquid and the vapour, the amount of heat is much higher in vapour compared to the liquid.
Superheating
If the steam is heated beyond the dry saturated steam condition, the temperature begins to rise again
and the properties of the steam start to resemble those of a perfect gas. Steam with higher
temperature than that of saturated steam is called superheated steam. It contains no moisture and
cannot condense until its temperature has been lowered to that of saturated steam at the same
pressure. Superheating the steam is particularly useful for eliminating condensation in steam lines,
decreasing the moisture in the turbine exhaust and increasing the efficiency (i.e. Carnot efficiency)
of the power plant.
Effect of pressure on evaporation temperature
It is well known that water boils and evaporates at 100C under atmospheric pressure. By higher
pressure, water evaporates at higher temperature - e.g. a pressure of 10 bar equals an evaporation
temperature of 184C. The pressure and the corresponding temperature when a phase change occurs
are called the saturation temperature and saturation pressure. During the evaporation process,
pressure and temperature are constant, but if the vaporization occurs in a closed vessel, the
expansion that occurs due to the phase change of water into steam causes the pressure to rise and
thus the boiling temperature rises.
When 22,12 Mpa is exceeded (the corresponding temperature is 374C), the line stops (Figure 10).
The reason is that the border between gas phase and liquid phase is blurred out at that pressure. That
point, where the different phases cease to exist, is called the critical point of water.
8
STEAM BOILER TECHNOLOGY The Basics of Steam Generation
22,12 MPa
0.01
0.1
1
10
100
1000
0 100 200 300 400
Temperature [C]
P
r
e
s
s
u
r
e
[
b
a
r
]
Figure 10: Evaporation pressure as a function of evaporation temperature.
Basics of combustion
Combustion can be defined as the complete, rapid exothermic oxidation of a fuel with sufficient
amount of oxygen or air with the objective of producing heat, steam and/or electricity. The process
of combustion occurs with a high speed and at a high temperature. Essentially, it is a controlled
explosion. Combustion occurs when the elements in a fuel combine with oxygen and produce heat.
All fuels, whether they are solid, liquid or in gaseous form, consist primarily of compounds of
carbon and hydrogen called hydrocarbons (natural gas, coal fuel oil, wood, etc.), which are
converted in the combustion process to carbon dioxide (CO
2
) and steam. Sulphur, nitrogen, and
various other components are also present in these fuels.
Products of combustion
When the hydrogen and oxygen combine, intense heat and water vapor is formed. When carbon and
oxygen combine, intense heat and the compounds of carbon monoxide or carbon dioxide are
formed. These chemical reactions take place in a furnace during the burning of fuel, provided there
is sufficient air (oxygen) to completely burn the fuel. Very little of the released carbon is actually
"consumed" in the combustion reaction because flame temperature seldom reaches the vaporization
point of carbon. Most of it combines with oxygen to form CO
2
and passes out the vent. The final
gaseous product of combustion is called a flue gas. As mentioned in the introduction to this
segment, combustion can never be 100% efficient. All fuels contain moisture. Other fuel
components may form by-products, such as ash, and gaseous pollutants that need emission control
equipment. [5]
Types of combustion
There are three types of combustion:
Perfect Combustion is achieved when all the fuel is burned using only the theoretical
amount of air, but as stated earlier, perfect combustion cannot be achieved in a boiler.
Complete Combustion is achieved when all the fuel is burned using the minimal amount of
air above the theoretical amount of air needed to burn the fuel. Solid fuels, such as coal, peat
9
STEAM BOILER TECHNOLOGY The Basics of Steam Generation
or biomass, are typically fired at air factors 1.1 1.5, i.e. 110-150% of the oxygen needed
for perfect combustion.
Incomplete Combustion occurs when part of the fuel is not burned, which results in the
formation of soot and smoke.
Combustion of solid fuels
Solid fuels can be divided into high grade; coal
and low grade; peat and bark. The most typical
firing methods are grate firing, cyclone firing,
pulverized firing, and fluidized bed firing.
Pulverized firing has been used in industrial and
utility boilers from 60 MWt to 6000 MWt. Grate
firing (Figure 11) has been used to fire biofuels
from 5 MWt to 600 MWt and cyclone firing has
been used in small scale 3-6 MWt.
Figure 11:Photo of stoker or grate firing.
Combustion of coal
Oil and gas are always combusted with a burner, but there are three different ways to combust coal:
Fixed bed combustion (grate boilers, Figure 11)
Fluidized bed combustion (Figure 12)
Entrained bed combustion (pulverized coal combustion)
In fixed bed combustion, larger-sized coal is combusted
in the bottom part of the combustor with low-velocity
air. Stoker boilers also employ this type of combustion.
Large-capacity pulverized coal fired boilers for power
plants usually employ entrained bed combustion. In
fluidized bed combustion, fuel is introduced into the
fluidized bed and combusted. [4]
Main types of a modern boiler
In a modern boiler, there are two main types of boilers
when considering the heat transfer means from flue
gases to feed water: Fire tube boilers and water tube
boilers.
In a fire tube boiler (Figure 13) the flue gases from the
furnace are conducted to flue passages, which consist of
several parallel-connected tubes. The tubes run through
the boiler vessel, which contains the feedwater. The
tubes are thus surrounded by water. The heat from the
flue gases is transferred from the tubes to the water in
the container, thus the water is heated into steam. An
easy way to remember the principle is to say that a fire
tube boiler has "fire in the tubes".
Figure 12: Photo of fluidized bed
combustion.
10
STEAM BOILER TECHNOLOGY The Basics of Steam Generation
1. Turning chamber
2. Flue gas collection
chamber
3. Open furnace
4. Flame tube
5. Burner seat
6. Manhole
7. Fire tubes
8. Water space
9. Steam space
10. Outlet and circulation
11. Flue gas out
12. Blow-out hatch
13. Main hatch
14. Cleaning hatch
15. Main steam outlet
16. Level control assembly
17. Feedwater inlet
18. Utility steam outlet
19. Safety valve assembly
20. Feet
21. Inslulation
Figure 13: Schematic of a Hyrytys TTK fire tube steam boiler [6].
In a water tube boiler, the conditions are the
opposite of a fire tube boiler. The water
circulates in many parallel-connected tubes.
The tubes are situated in the flue gas channel,
and are heated by the flue gases, which are
led from the furnace through the flue gas
passage. In a modern boiler, the tubes, where
water circulates, are welded together and
form the furnace walls. Therefore the water
tubes are directly exposed to radiation and
gases from the combustion (Figure 14).
Similarly to the fire tube boiler, the water
tube boiler received its name from having
"water in the tubes".
A modern utility boiler is usually a water
tube boiler, because a fire tube boiler is
limited in capacity and only feasible in small
systems. The various designs of water tube
boilers are discussed further in Steam/water
circulation design
Figure 14: Simplified drawing describing the water
tube boiler principle. [7]
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STEAM BOILER TECHNOLOGY The Basics of Steam Generation
Heat exchanger boiler model
If a modern water tube boiler utilizes a furnace,
the furnace and the evaporator is usually the
same construction the inner furnace walls
consists solely of boiler tubes, conducting feed
water, which absorbs the combustion heat and
evaporates.
In process engineering a boiler is modelled as a
network of heat exchangers, which symbolizes
the transfer of heat from the flue gas to the
steam/water in boiler pipes.
For instance, the furnace, abstracted as a heat
exchanger (Figure 15), consists of the following
streams: the fuel (at storage temperature),
combustion air (at outdoors temperature) and
feedwater as input streams. The output streams
are the flue gas from the combustion of the fuel-
air mixture, and the steam.
Heat exchanger basics
The task of a heat exchanger is to transfer the
heat from one flow of medium (fluid/gas stream)
air
flue gas
feed water
process steam
fuel
Figure 15: Furnace heat exchanger model.
to another without any physical contact, i.e. without actually mixing the two media. The two
interacting streams in a heat exchanger are referred to as the hot stream and the cold stream (Figure
16). The hot stream (a.k.a. heat source) is the stream that gives away heat to the cold stream (a.k.a.
heat sink) that absorbs the heat. Thus, in a boiler the flue gas stream is the hot stream (heat source)
and the water/steam stream is the cold stream (heat sink).
There are two different main types of heat
exchangers: Parallel-flow and counter-flow. In a
parallel flow heat exchanger the fluids flow in
the same direction and in a counter flow heat
exchanger the fluids flow in the opposite
direction. Combinations of these types (like
cross-flow exchangers and more complicated
ones, like boilers) can usually be approximately
calculated according to the counter-flow type.
T-Q diagram
A useful tool for designing a heat exchanger is
the T-Q diagram. The diagram consists of two
axes: Temperature (T) and transferred heat (Q).
The hot stream and the cold stream are
represented in the diagram by two lines on top
of each other. If the exchanger is of parallel-
flow type, the lines proceed in the same
direction (Figure 17). If the exchanger is a
counter-flow (or cross-flow-combination, like a
hot stream
cold stream
Figure 16: A heat exchanger model.
12
STEAM BOILER TECHNOLOGY The Basics of Steam Generation
boiler), the lines points in the opposite direction
(Figure 18). The length of the lines on the Q-
axis shows the transferred heat rate and the T-
axis the rise/drop in temperature that the heat
transfer has caused.
Since the heat strays from a higher temperature
to a lower (according to the second law of
thermodynamics) the wanted heat transfer
happens by itself if and only if the hot stream is
always hotter than the cold stream. That is why
the streams must never cross. Since no material
has an infinite heat transfer rate, the pinch
temperature (Tpinch) of the heat exchanger
defines the minimum allowed temperature
difference between the two flows.
If the streams cross, the lines must be
horizontally adjusted (that is, external heating
and cooling must be supplied) in order to
correspond with the pinch temperature (Figure
19).
T
Q
T1
T2
hot stream
t2
t1 cold stream
Figure 17: T-Q diagram of a parallel-flow type
heat exchanger.
T
Q
T1
T2
t2
t1
deltaQ
Figure 18: T-Q diagram of a counter-flow type
heat exchanger.
T
Q
Tpinch
T1
T2
external heating
required
t1
t1
external cooling
required
Figure 19: Adjusted streams.
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STEAM BOILER TECHNOLOGY The Basics of Steam Generation
Heat recovery steam generator model
To give an example of the construction of a heat
exchanger model, a heat recovery steam
generator (HRSG) is constructed next as a heat
exchanger cascade. The HRSG is basically a
boiler without a furnace the HRSG extracts
heat from flue gases originating from fuel
combusted in an external unit. Since the HRSG
only deals with two streams (flue gases as the
hot stream and steam/water as the cold stream),
it represents the simplest heat exchanger model
of a modern boiler application. Since the heating
of water occurs in three steps (Figure 9), the heat
exchanger model is usually divided into at least
three units.
The heat exchanger unit, where the evaporation
occurs is called the evaporator. Assuming that
water enters the evaporator as saturated water
and exits as saturated steam, the heat transferred
from the flue gas is the required heat to change
the phase of water into steam. The phase change
occurs (water boils) at a constant temperature,
and therefore the steam/water stream
temperature will not change in the evaporator.
In order to preheat the water for the evaporator,
another heat exchanger unit is needed. This unit
is called economizer, and is a cross-flow type of
heat exchanger. It is placed after the evaporator
in the flue gas stream, since the evaporator
requires higher flue gas temperature than the
economizer.
The heat exchanger unit that superheats the
saturated steam is called superheater. The
superheater heats the saturated steam beyond the
saturation point until it reaches the designed
maximum temperature. It requires therefore the
highest flue gas temperature to receive heat and
is thus placed first in the flue gas stream. The
maximum temperature of the boiler is limited by
the properties of the superheater tube material.
Today's economically feasible material can take
temperatures of 550-600 C.
Economizer
Evaporator
Superheater
water
saturated
water
saturated
steam
Figure 20: Heat exchanger model of the HRSG.
T
Q
Eco Eva Sup
Figure 21: T-Q diagram of the HRSG model in
Figure 20.
The result is a heat exchanger cascade of a HRSG (with a single pressure level), which can be found
in Figure 20. The T-Q diagram of the model is visualized in Figure 21.
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STEAM BOILER TECHNOLOGY The Basics of Steam Generation
Heat exchanger model of furnace-equipped boilers
The order of the heat transfer units on the water/steam side is always economizer - evaporator -
superheater (downstream order). The temperature levels and the temperature difference between the
flue gases and the working fluid usually limits the arrangement variation possibilities of the heat
transfer surfaces on the flue gas side.
In a boiler with a furnace, adequate cooling has to be maintained and material temperature should
not exceed 600C. Thus the evaporator part of the water/steam cycle is placed in the furnace walls,
since the heat of the evaporation provides enough cooling for the furnace, which is the hottest part
of the boiler.
Since the furnace is inside the boiler, high flue gas temperatures (over 1000C) are obtained. After
the flue gas has given off heat for the steam production, it is still quite hot. In order to cool down
the flue gases further to gain higher boiler efficiency, flue gases can be used to preheat the
combustion air. The heat exchanger used for this purpose is called an air preheater.
The result is a heat exchanger model of a furnace-equipped boiler (e.g. PCF-boiler, grate boiler or
oil/gas boiler), which can be found in Figure 22. The T-Q diagram of the model is visualized in
Figure 23
Air preheater
Air in
Air out
Figure 22: Furnace equipped boiler with air
preheater.
T
Q
Eco
Eva Sup Air
Figure 23: T-Q diagram of the heat exchanger
model in Figure 22.
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STEAM BOILER TECHNOLOGY The Basics of Steam Generation
References
1. Vakkilainen E. Lecture slides and material on steam boiler technology, 2001
2. BP statistical review of world energy 2003. Web page, read September 2003.
http://www.bp.com/centres/energy/primary.asp
3. Ahonen V. Hyrytekniikka II. Otakustantamo, Espoo. 1978.
4. Combustion Engineering. Combustion: Fossil power systems. 3
rd
ed. Windsor. 1981.
5. Zevenhoven R., Kilpinen P. Control of pollutants in flue gases and fuel gases. Energy
Engineering and Environmental Protection Publications TKK-ENY-4, Espoo 2002.
ISBN 951-22-5527-8.
6. Hyrytys Oy. Web page, viewed at 8.9.2003.
http://www.hoyrytys.fi/vaporworks/hoyrykattilat/ttk_kattila.htm
7. American Heritage
C
]
Flue gas stream
Water/steam stream
Air stream
Furnace
Superheater
Economizer
Air preheater
Figure 3: Example of a heat load graph for a furnace equipped boiler.
Furnace
The furnace is the part of the boiler where the
combustion of the fuel takes place. The main
role of the boiler furnace is to burn the fuel as
completely and stably as possible. Leaving
unburned material will decrease the heat
efficiency and increase the emissions.
Combustion must be performed in an
environmentally sustainable way. The emissions
from the furnace must be as low as possible.
The furnace walls of a modern boiler consist of
vertical tubes that function as the evaporator part
of the steam/water cycle in the boiler. The boiler
roof is usually also part of the evaporator as well
as the flue gas channel walls in the economizer
Figure 4: Inside a recovery boiler furnace. [2]
and the air preheater parts of the boiler. Figure 4 shows a photograph from the inside of a recovery
boiler furnace.
Adequate furnace cooling is vital for the boiler. However, when burning very wet fuels as wood
chips, some parts of the furnace should not be cooled in order not to remove too much heat from
furnace. Thus a part of the furnace of boilers using such fuels consists of a refractory material,
which reflects the heat of combustion to the incoming wet fuel.
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STEAM BOILER TECHNOLOGY Heat Exchangers in Steam Boilers
If the flue gas temperature after furnace is
too high, the smelting of ash can occur such
problems as ash deposition on superheater
tubes. High temperature corrosion of
superheater tubes can appear as well. Figure
5 presents an example of a temperature
distribution in a two-pass boiler.
Membrane wall
Nowadays, the furnace is generally
constructed as a gas-tight membrane wall.
The membrane wall construction consists of
tubes, which have been welded together
separated by a flat iron strip, called the
membranes. The membranes act as fins to
increase the heat transfer. They also form a
continuous rigid and pressure tight
construction for the furnace. The most
common furnace tube used is a finned
carbon steel tube that forms the membrane
wall. A drawing visualizing a typical
membrane tube wall can be found in Figure
6.
Convection evaporators
In boilers with low steam pressure, the share
of the heat needed for evaporation is bigger
than when considering a high-pressure
boiler. Thus the furnace-wall evaporator
cannot provide enough heat for evaporation
process in low-pressure boilers. Convection
evaporators supply the supplementary heat
needed for complete evaporation. They are
normally placed after the superheater stage
in boiler process. Convection evaporators
can cause local tube overheat problems with
partial loads.
Boiler bank
A boiler bank is a convection evaporator
that uses two drums: one on the top of the
evaporator tubes, and another in the bottom.
A boiler bank is usually used in parallel
with the natural circulation based
evaporator/furnace, as in Figure 7. Boiler
banks are less common nowadays and are
nowadays typically used in low pressure
and small boilers.
Figure 5: Furnace temperature distribution.
Gas tight modern tube wall
Insulation wool
Outer wall
Figure 6: Modern gas-tight membrane tube wall
construction. Unfinned wall tubes are welded
together with metal strips.
Figure 7: Boiler generating bank (marked with
green colour).
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STEAM BOILER TECHNOLOGY Heat Exchangers in Steam Boilers
Economizer
After the feedwater pump, the water has the
required pressure and temperature to enter the
boiler. The pressurized water is introduced
into the boiler through the economizers. The
economizers are heat exchangers, usually in
the form of tube packages.
The purpose of economizers is to cool down
the flue gases leaving the superheater zone,
thus increasing the boiler efficiency. The
limiting factor for cooling is the risk of low
temperature corrosion, i.e. dew point of water.
Economizers are placed after the superheater
zone in the flue gas channel. They are usually
constructed as a package of tubes fastened on
the walls of the flue gas channel.
Figure 8: Economizer tube from a recovery boiler.
[2]
Flue gases are cooled down with feedwater, which gets preheated up to its saturation temperature.
In order to prevent the feedwater from boiling before it has entered the furnace/evaporator, the
temperature of the feedwater exiting the economizer is usually regulated with a safety margin below
its saturation temperature (about 10C). The heated water is then led to the steam drum.
The economizer shown in Figure 8 consists of two long-flow, vertical sections. Each economizer
section is comprised of straight vertical finned tubes, which are connected in parallel to one another.
The tubes are connected at the top and bottom to larger headers. This kind of vertical tube packages
is typical for chemical recovery boilers. Other boilers use packages of horizontal tubes. The bundles
are placed in the second pass of the boiler, behind the superheaters. Here, the water is utilizing the
heat of the flue gases that is left from the superheaters, before the flue gases leave the boiler. The
flue gas temperature should always stay above the dew point of the gases to prevent corrosion of the
precipitators and ducts.
Superheater
The superheater is a heat exchanger that overheats (superheats) the saturated steam. By
superheating saturated steam, the temperature of the steam is increased beyond the temperature of
the saturated steam, and thus the efficiency of the energy production process can be raised.
Superheated steam is also used in facilities that don't produce electricity.
The benefits of using superheated steam are:
Zero moisture content
No condensate in steam pipes
Higher energy production efficiency
The superheater normally consists of tubes conducting steam, which are heated by flue gases
passing outside the tubes. The tubes are usually connected in parallel using headers, with steam
entering from one header and exiting in another header. There can be several superheater units in
107
STEAM BOILER TECHNOLOGY Heat Exchangers in Steam Boilers
the same boiler, as well as reheaters, which is a superheater for heating external steam (steam
already used in a process outside the boiler). [2]
Types of superheater surfaces
Superheaters can be divided into convection
based and radiation based superheaters.
Radiation superheaters
Radiation based superheaters are used to gain
higher steam temperatures and the heat is mainly
transferred by radiation. These superheaters
have to be placed within reach of the flame
radiation. Thus radiant superheaters are usually
integrated as tubes in the boiler-walls or built as
panels hanging from the boiler roof. The
radiation superheater is located in the top of the
furnace, where the main means of heat transfer
is radiation.
Convection superheaters
Convection superheaters are the most common
superheaters in steam boilers. Convection based
superheaters are used with relatively low steam
temperature, and the heat from the flue gases is
mainly transferred by convection. They are
placed after the furnace protected from the
Figure 9: Panel superheaters in production. [2]
corrosive radiation of the flames. This type of superheater can also be protected from radiation by a
couple of rows of evaporator tubes. Convection based superheaters can hang from the boiler roof or
they can be placed in the second pass of the boiler (in a two-pass design), and are called back-pass
superheaters.
Panel superheater
The panel superheater (shown in Figure 9 and
Figure 10) functions on both radiation and
convention heat transfer, depending on its
location in the boiler. It consists of tubes that are
tightly bundled in thin panel walls, which hang
from the roof in the exhaust of the furnace. The
distance between the panels is usually about
300-500 mm. The tubes are laid out according to
the inline arrangement. This kind of superheater
can be located e.g. first in the flue gas stream
after furnace in which coal with low heating
value is burned (brown coal). The panel
superheater is resistant to fouling and can
withstand high heat flux.
Figure 10: Panel superheaters installed. [2]
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STEAM BOILER TECHNOLOGY Heat Exchangers in Steam Boilers
Wing wall superheater
The wing wall superheater is a kind of panel superheater that extends from a furnace (Figure 11).
The bank of tubes, which are welded together, is usually built in the front wall of boiler. It has
become popular especially in CFB applications. The tube is often made of carbon steel. The wing
wall superheater receives heat mainly through radiation.
Wing wall
superheater
Convection
superheater
Panel
superheater
Back-pass
superheater
Radiation
superheaters
Figure 11: Arrangement of various types of superheater units.
Back-pass superheater set
Convection superheaters, located in the flue gas
channel (Figure 11 and Figure 12) where the
flue gas starts flowing downwards, are called
back-pass superheaters. In large CFB, coal and
oil boilers horizontal tube arrangements are
commonly used. Back-pass superheater tubes
hang from the back-pass roof.
Reheater
A reheater is basically a superheater that
superheats steam exiting the high-pressure stage
of a turbine. The reheated steam is then sent to
the low-pressure stage of the turbine. By
reheating steam between high-pressure and low-
pressure turbine it is possible to increase the
electrical efficiency of the power plant cycle
beyond 40%. The reheat cycle is used in large
Figure 12: Back-pass superheater. [1]
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STEAM BOILER TECHNOLOGY Heat Exchangers in Steam Boilers
power boilers since it is feasible economically only
in larger power plants. Reheater design is very much
similar to superheater design because both operate at
high temperature conditions. The effect of the
reheater in a T-S diagram is plotted in Figure 13.
Connections of superheater elements
Considering the steam flow, superheater elements
are usually connected in series, e.g. first convection
stage and then radiant stage. When looking in the
direction of the flue gas flow, the radiant stage is
placed before the convectional stage of the
superheaters. The steam temperature that can be
reached with convection type superheaters is
significantly lower than that reached with radiant
type superheaters. Thus, boilers having high live
steam temperature use radiant type superheaters as
final superheater.
T
S
A
B
C
D
Figure 13: The reheater (line C-D) in a
power plant cycle, plotted in a T-S diagram
for steam/water.
The small amount of saturated water still remaining in steam evaporates in the first superheater
section. This makes solid impurities of boiler water stick on inner surface superheater tubes and
thus decreases the heat transfer coefficient of the tubes. Superheater stages are therefore placed in
counter-current order, i.e. the first superheater stage is situated at the lowest flue gas temperature.
Superheated
Steam OUT
Saturated
Steam IN
Feedwater
IN
Reheater
IN
Reheated
Steam OUT
Superheater II
Superheater III
Reheater II
Superheater I
Reheater I
Figure 14: Connection of superheater and reheater stages.
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STEAM BOILER TECHNOLOGY Heat Exchangers in Steam Boilers
However, the superheater situated at the hottest
spot within the boiler (normally convective
superheater) is not usually the final superheater
because of the possible overheating problems.
Thus, the convective superheater is connected in
forward-current order in relation to flue gas flow
to provide enough cooling for superheater tubing
(Figure 14)
The superheater banks are connected to
proceeding banks by interconnecting piping, i.e.
pipes connect each ends of an outlet header to
the opposite ends of the next superheater's inlet
headers, as shown in Figure 15. This cross-over
of steam flow assures even distribution of steam
circulation through the entire superheater system
Figure 15: Cross-connections of superheater
headers. [2]
and minimized temperature variations from one side of the boiler to the other.
Air preheater
Air preheaters have two important functions in a
steam boiler: they cool the gases before they
pass to the atmosphere (thereby increasing the
efficiency), and they raise the temperature of the
incoming combustion air (thereby drying solid
fuel faster). The heated air from air preheaters is
also used for transporting the fuel in PCF boilers
and fluidized bed boilers. Air preheaters can be
of a regenerative or recuperative type. [3]
Regenerative air preheaters
In regenerative air preheaters no media for heat
transfer is used - they use the heat accumulation
capacity of a slowly rotating rotor for
transferring the heat. The rotor is alternately
heated in the flue gas stream and cooled in the
air stream, heat-storage being provided by the
mass of the packs consisting of closely spaced
metal sheets (Figure 16), 0.5-0.75 mm thick,
which absorb and give off heat on both sides.
The rotor is divided into pie-shaped 'baskets' of
theses metal sheets, which in turn pick up heat
from flue gases and release it into the
combustion air, as shown in the drawing in
Figure 17.
Figure 16: Heat transfer surfaces of the rotor.
[4]
Figure 17: The heat-transfer principle of a
regenerative air preheater. [4]
Regenerative air preheaters occupy little space; about 1/4 or 1/6 of the space required by
recuperative air preheaters and can be produced cheaply. Without exaggeration it can be claimed
that they have rendered possible the low flue-gas exit temperatures achieved today. Their reduced
tendency to dew point corrosion should also be stressed, in particular where sulphur-containing
fuels are used. Moreover, any sheet metal packs that have become corroded can be replaced easily
111
STEAM BOILER TECHNOLOGY Heat Exchangers in Steam Boilers
and quickly. They can also be cleaned easily by
playing a jet of steam over the gaps in the packs
of sheet metal.
The Ljungstrom air preheater (Figure 18) has
acquired exceptional importance; since the last
war it has found wide acceptance in Europe. The
Rothmhle air preheater (Figure 19) is another
type of regenerative air preheater, where the
duct rotates around the battery of plates, which
is fixed.
The problem of regenerative air preheaters is the
gas leakage from one side to another. This can
cause fires due to air leakage if flue gases
contain high amount of combustibles (due to
poor combustion).
Recuperative air preheaters
In a recuperative air heater the heat from a high-
temperature flowing fluid (flue gas) passes
through a heat transfer surface to cooler air. The
heating medium is completely separated at all
times from the air being heated. The
recuperative principle implies the transfer of
heat through the separation partition, with the
cool side continuously recuperating the heat
conducted from the hot side. Thus, the
advantage of recuperative air preheaters in
general is the lack of leakage because the sealing
is easier to implement here than in the
regenerative type. The separating surface may be
composed of tubes or plates. The rate of flow is
determined by temperature differential, metal
Figure 18: A photograph of a Ljungstrom air
preheater. [4]
Figure 19: Rotmhle air preheater. [1]
conductivity, gas film conductivity, conductivity of soot, and ash and corrosion deposits. The
cumulative effect of these factors may be large. There are two types of recuperative heat
exchangers: tubular and plate preheaters.
Tubular recuperative air preheater
Tubular air preheater is comprised of a nest of long, straight steel or cast-iron tubes expanded into
tube sheets at both ends, and an enclosing casing provided with inlet and outlet openings. If the
tubes are placed vertically, the flue gases pass through or around them (Figure 20). If the tubes are
placed horizontally, the flue gases only pass around them (Figure 21). The design, which usually
provides a counter-flow arrangement, may consist of a single pass or multiple passes with either
splitter (parallel to tubes) or deflecting (cross-tube) baffling. Traditionally the tubes were made of
cast iron for good corrosion resistance. Thus the whole preheater was heavy and needed massive
foundations.
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STEAM BOILER TECHNOLOGY Heat Exchangers in Steam Boilers
Flue gas
Air
Figure 20: Straight (vertical) air preheater
design.
Flue gas
Air
Figure 21: Two-pass (horizontal) air preheater
design.
Plate recuperative air preheater
A newer, alternative design is the plate-frame type recuperative air preheater. It offers the same heat
transfer capacity with reduced unit weight and size. Plate air preheater consists of a series of thin,
flat, parallel plates assembled into a series of thin, narrow compartments or passages, all suitably
cased. Flue gas and air pass through alternate spaces in counter-flow directions. The plate air
preheater may be arranged more compactly than the tubular type. Because of cleaning difficulties,
however, its use is diminishing.
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STEAM BOILER TECHNOLOGY Heat Exchangers in Steam Boilers
References
1. Vakkilainen E. Lecture slides and material on steam boiler technology, 2001
2. Andritz. Recovery Boiler Operation Manual, Ahlstrom Machinery Corporation 1999. CD-
rom. http://www.andritz.com/
3. Combustion Engineering. Combustion: Fossil power systems. 3
rd
ed. Windsor. 1981.
4. Alstom. Air preheater company web page, read September 2003.
http://www.airpreheatercompany.com/airpreheaters.asp
114
Boiler Calculations
Sebastian Teir, Antto Kulla
STEAM BOILER TECHNOLOGY Boiler Calculations
Table of contents
Table of contents.............................................................................................................................. 116
Steam/water diagrams used in boiler calculations ........................................................................... 117
Temperature-heat (T-Q) diagram................................................................................................. 117
Temperature-entropy (T-s) diagram............................................................................................. 118
Application of the T-s diagram................................................................................................ 119
Pressure-enthalpy (p-h) diagram.................................................................................................. 120
Enthalpy-entropy (Mollier, h-s) diagram..................................................................................... 121
Determination of steam/water parameters ....................................................................................... 122
Given parameters ......................................................................................................................... 122
Pressure losses.............................................................................................................................. 122
Procedure for determination of specific enthalpies and mass flow rates..................................... 122
Superheaters and reheaters........................................................................................................... 123
Spray water group mass flow....................................................................................................... 124
Calculations of heat load.............................................................................................................. 125
Evaporator................................................................................................................................ 125
Superheater............................................................................................................................... 125
Reheater ................................................................................................................................... 125
Economizer .............................................................................................................................. 126
Air preheater ............................................................................................................................ 126
Determination of boiler efficiency................................................................................................... 126
Standards...................................................................................................................................... 126
Major heat losses.......................................................................................................................... 126
Heat loss with unburned combustible gases ............................................................................ 126
Heat loss due to unburned solid fuel........................................................................................ 127
Heat loss due to wasted heat in flue gases ............................................................................... 127
Heat loss due to wasted heat in ashes ...................................................................................... 127
Losses due to heat transfer (radiation) to the environment ...................................................... 128
Losses of blowdown, sootblowing and atomizing steam......................................................... 128
Internal power consumption......................................................................................................... 128
Calculating boiler efficiency........................................................................................................ 129
Direct method........................................................................................................................... 129
Indirect method ........................................................................................................................ 129
References........................................................................................................................................ 130
116
STEAM BOILER TECHNOLOGY Boiler Calculations
Steam/water diagrams used in boiler calculations
Temperature-heat (T-Q) diagram
The T-Q diagram is a useful tool for designing heat exchangers. It can also be used to present the
heat transfer characteristics of an existing heat exchanger or heat exchanger network. The T-Q
diagram consists of two axes: The current stream temperature on the y-axis and the amount of heat
transferred on the x-axis. Sometimes the streams are marked with arrowheads to clarify the
direction of the streams, but these are not necessary: since heat cannot move from the colder stream
to the hotter stream according to the second law of thermodynamics, the directions of the streams
are explicitly determined: The hot stream transfers its heat to the cold stream, thus the flow
direction of the hot stream is towards lower temperature and the flow direction of the cold stream is
towards higher temperatures. For the same reason, the hot stream is always above the cold stream in
the T-Q diagram (Figure 1).
Figure 1: Examples of T-Q diagrams for a parallel flow heat exchanger (left), and a counter (or
cross) flow heat exchanger (middle). The hot stream is marked with red color and the cold with
blue color.
When designing or
reviewing heat
exchanger networks, the
T-Q diagram gets useful.
The T-Q diagram is
therefore applied when
designing boilers;
especially the heat
exchanger surface
arrangement can be
clearly visualized with a
T-Q diagram (Figure 2).
0
200
400
600
800
1000
1200
1400
1600
0 % 10 % 20 % 30 % 40 % 50 % 60 % 70 % 80 % 90 % 100 %
Share of heat load [%]
T
e
m
p
e
r
a
t
u
r
e
[
C
]
Flue gas stream
Water/steam stream
Air stream
Furnace
Superheater
Economizer
Air preheater
Figure 2: Example of a T-Q diagram representing the heat surfaces in a
furnace equipped boiler.
117
STEAM BOILER TECHNOLOGY Boiler Calculations
Temperature-entropy (T-s) diagram
The T-s diagram represents the
various phases of steam/water with
temperature as a function of the
specific entropy. It is often used to
visualize steam power processes. The
T-s diagram is also commonly used
for displaying reversible processes
(or real processes simplified as
reversible processes), which in the T-
s diagram appear as closed curves
(loop).
The left border, up to the critical
point, is the border where the liquid
is saturated (Figure 3). That is, the
water is still liquid and contains no
steam. But if we go further right
(increase the entropy), steam bubbles
starts to form in the water. In other
words, saturated water starts to boil
when heat is added and entropy is
increased.
The enclosed region in the middle is
the region where water is a mixture
of vapor and liquid. Steam that
contains water in any form, either as
Critical point
p
=
c
o
n
s
t
a
n
t
p
=
c
o
n
s
t
a
n
t
p = constant
p = constant
v
=
c
o
n
s
t
a
n
t
v
=
c
o
n
s
t
a
n
t
Liquid-vapour region
S
a
t
u
r
a
t
e
d
v
a
p
o
u
r
S
a
t
u
r
a
t
e
d
l
i
q
u
i
d
X = 0,2 X = 0,9
T
e
m
p
e
r
a
t
u
r
e
Entropy
Figure 3: Simplified T-s diagram of steam/water.
minute droplets, mist or fog, is called wet steam. The quantity called x in the diagram represents
the amount (percentage by weight) of dry vapor in the wet steam mixture. This quantity is called the
quality of steam. For instance, if there is 10% moisture in the steam, the quality of the steam is 90%
or 0.9. The temperature of wet steam is the same as dry saturated steam at the same pressure.
The right border, down from the critical point, is the line where steam is saturated. When steam is
heated beyond that border, steam is called superheated.
Water boils under constant temperature and pressure, so a horizontal line inside the enclosed region
represents a vaporization process in the T-s diagram. The steam/water heating process in the boiler
represented by the diagram in figure 2 can also be drawn in a T-s diagram (Figure 4), if the boiler
pressure is assumed to be e.g. 10 MPa.
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STEAM BOILER TECHNOLOGY Boiler Calculations
Figure 4: Detailed T-s diagram of the PCF boiler steam/water heating process from figure 2 (note:
color of the steam/water process line is changed from blue to red).
Application of the T-s diagram
Consider the simple steam power plant
based on the Rankine cycle, as
visualized in (Figure 5). The plant
consists of a steam boiler (superheater,
evaporator and economizer), turbine
with generator, condenser and a feed
pump. The Rankine cycle consists of
the following processes:
1-2: Expansion of high-pressure
steam in the turbine
(isentropic)
2-3: Condensation of low- pressure
steam in the condenser (isobaric and
isothermal)
Superheater
1
2
3
4
5
6
Evaporator/
Furnace
Economizer
G
Turbine & Generator
Pump
Condenser
Figure 5: Rankine cycle
3-4: Compression of water in the feed pump (isentropic)
4-5: Heating of water in the economizer at a high pressure (isobaric)
5-6: Evaporation of water in the evaporator at a high pressure (isobaric)
6-1: Heating of steam in the superheater at a high pressure (isobaric)
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STEAM BOILER TECHNOLOGY Boiler Calculations
The process can be visualized by drawing the
process into a T-s diagram (
Figure 6). Since the process is assumed to be
isentropic, the expansion and compression
lines are strictly vertical. If the losses in the
turbine and pump were considered, the
vertical lines would be slightly tilted so that
entropy increases. [1]
Pressure-enthalpy (p-h) diagram
Another tool used in boiler calculation is the
pressure-enthalpy diagram for steam/water
(Figure 7). With the p-h diagram it is easy to
visualize the partial shares of the total heat
load on different heat exchanger surfaces in
the boiler: drawing the steam heating process
in the boiler onto the p-h diagram will give a
Entropy
T
e
m
p
e
r
a
t
u
r
e
q
q
w
w
x = 0
x = 1
4
5
1
2 3
6
Figure 6: T-s diagram of the Rankine cycle in
Figure 5.
horizontal line (if we simplify the process and set pressure losses to zero). Figure 7 shows the same
boiler steam/water process from Figure 4, drawn in the steam/water p-h diagram.
Figure 7: Detailed p-h diagram of the PCF boiler steam/water heating process (red line) from
Figure 4.
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STEAM BOILER TECHNOLOGY Boiler Calculations
Enthalpy-entropy (Mollier, h-s) diagram
The most frequently used tool for determining
steam properties is probably the enthalpy-
entropy (h-s) diagram, also called Mollier
diagram (Figure 8). If two properties of the
steam state are known (like pressure and
temperature), the rest of the properties for
steam (enthalpy, entropy, specific volume and
moisture content) can be read from the
diagram. A more detailed h-s diagram can be
found in Figure 9. Since the diagram is very
large, the diagram is usually found as two
versions, consisting of zoomed portions of the
original: one for steam properties (Figure 8)
and another for water properties.
Critical point
p
=
c
o
n
s
t
a
n
t
p
=
c
o
n
s
t
a
n
t
T = constant
T = constant
Liquid-vapour region
X = 0,96
X
= 0,90
S
a
t
u
r
a
t
e
d
v
a
p
o
u
r
Figure 8: Mollier (h-s) diagram, simplified
version.
Figure 9: Large-scale Mollier h-s diagram for steam.
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STEAM BOILER TECHNOLOGY Boiler Calculations
Determination of steam/water parameters
Given parameters
Normally in a steam boiler design assignment the parameters describing the live (output) steam, e.g.
mass flow, pressure and temperature are given. If the steam boiler to be designed has a reheat cycle,
also reheat pressure and temperature are given. Reheat steam mass flow can be given as well. These
parameters are used to determine the rest of the steam/water parameters. [2]
Pressure losses
The pressure losses in the heat exchanger units of the boiler are estimated according to the
following approximations:
Economizer: the pressure loss is 5-10% of the pressure of the feedwater entering the
economizer.
Evaporator:
Once through boilers: in once-through boilers the pressure loss of the evaporator is between
5 and 30%.
Forced and natural circulation boilers: the pressure drop in the evaporator part of drum-
based boilers does not affect the pressure loss of the main steam/water flow through the
boiler. This means that saturated steam leaving the steam drum has the same pressure as the
feedwater entering the steam drum. The pressure loss of the evaporator has to be overcome
using the driving force (natural circulation) or circulation pump (forced circulation).
Superheater: the total pressure drop of all superheater packages is less than 10% of the
pressure of the superheated steam.
Reheater: the pressure drop in the reheater is about 5% of the pressure of reheated steam
Pressure losses of connection tubes between different heat transfer surfaces (e.g. between
evaporator and superheater) can be neglected in these calculations.
Procedure for determination of specific enthalpies and mass flow rates
1. The specific enthalpy of the superheated steam can be determined with an h-s diagram if both
the temperature and the pressure of the steam are known. Thus, the specific enthalpies for live
(superheated) steam and reheated steam can be calculated.
2. The total pressure loss of the superheater stages should be chosen. Thus, the pressure in steam
drum (drum-type boilers) or pressure after evaporator (once-through boilers) can be calculated
by adding the pressure loss over the superheater stages to the pressure of the superheated steam.
3. Specific enthalpy of saturated water and steam (in the steam drum) can be read from an h-s
diagram or steam tables, as the pressure in the steam drum is known.
In once-through boilers the determination of specific enthalpy after the evaporator is based on
the temperature. The reason for this is the unclear state of supercritical steam after the
evaporator in once-through circulation. The temperature after the evaporator in once-through
boilers is typically between 400 and 450C.
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STEAM BOILER TECHNOLOGY Boiler Calculations
4. For removal of salts and minerals concentrated in the steam drum, a part of the water in steam
drum is removed as blowdown water from the bottom of the steam drum. Normally the mass
flow rate of blowdown is 1-3% of the mass flow rate of feedwater coming into steam drum.
5. In principle, the feedwater coming into steam drum should be saturated water. To prevent the
feedwater from boiling in the transportation pipes, the temperature of the feedwater reaching the
steam drum is 15-30C below saturation temperature. This temperature difference is called the
approach temperature. The feedwater is then called subcooled (in contrast to supercooled).
When the temperature in the steam drum and the value of the approach temperature are known,
the temperature after the economizer can be determined. The water pressure after the
economizer can be assumed to be equal to the pressure in the steam drum and specific enthalpy
after the economizer can then be read from a h-s diagram.
In once through boilers the pressure after the economizer can be calculated by adding the
pressure loss in the evaporator to the pressure after evaporator. The temperature after the
evaporator is normally between 300 and 350C (can be chosen as a unique value for the boiler).
Knowing the pressure and the temperature, the specific enthalpy after the evaporator can be
defined.
6. The pressure before the economizer can be calculated by adding the pressure loss in the
economizer to the feedwater pressure after economizer. The feedwater temperature might be
stated in the boiler design assignment. If it is not given, it should be chosen from the range of
200-250C. The mass flow rate before the economizer is the blowdown mass flow rate added to
the mass flow rate from the steam drum to the superheaters.
Superheaters and reheaters
Reheating takes usually place in two stages.
The pressure before the reheater is the reheated
steam pressure added on the pressure loss in
the reheater. The steam goes through a high-
pressure turbine before it enters the reheater. In
the high-pressure turbine, the specific enthalpy
of steam decreases according to the isentropic
efficiency of the turbine. Isentropic efficiency
is normally between 0.85 and 0.95. A part of
the low-pressure steam coming from high-
pressure turbine continues to the high-pressure
feedwater heater (closed-type feedwater
heater). However, the mass flow rate of
reheated steam is still 85-90% of that of the
live steam.
Superheating and reahiting is often applied in
three stages having spray water groups
between each other to regulate steam
temperature when necessary. Spray water
group dimensioning is usually based on a
I II III
354
410
435
475
505
535
t C
Heat load
Figure 10: An example of the heat load share of
superheater stages.
steam temperature decrease of 15-40C by water spraying. Spray water originates normally from
the feedwater line before the economizer. Thus the pressure difference is the pressure loss of the
123
STEAM BOILER TECHNOLOGY Boiler Calculations
heat transfer surfaces between the economizer inlet and the location of the spray water nozzle. An
example of a possible heat load share between the superheater stages is shown in Figure 10.
Pressure loss in superheaters can be divided into equal partial pressure losses corresponding to each
superheater stage. Pressure loss of the spray nozzles can be neglected. Temperature rise over all
superheaters can be divided into quite similar parts along the same principle.
Spray water group mass flow
Normally the mass flow rate of superheated steam (live steam) is known. Thus, mass flow rate
calculations start usually by calculating the mass flow rate of spray water to the last spray water
group (which is in this example between the second and third superheater stages). The mass flow
rates can be solved with energy and mass balance equations. With the equations below (equation 1),
the mass flow rate of steam after second superheater stage and mass flow rate of spray water to the
last spray water group can be calculated. The mass flow rate of spray water to the first spray water
group can be calculated along the same procedure:
1 , 2 , SHIII SHIII SPRAY SPRAYII SHII SHII
SHIII SPRAYII SHII
h m h m h m
m m m
= +
= +
& & &
& & &
(1)
where is the mass flow rate of steam after second superheater stage [kg/s], the mass
flow rate of spray water to second spray water group, the mass flow rate of superheated
steam (live steam), the specific enthalpy of steam after second superheater stage [kJ/kg],
the specific enthalpy of spray water (feedwater), and the specific enthalpy of steam
before third superheater stage. Figure 11 shows a flow chart with the symbols visualized of the
boiler arrangement used in this calculation model.
SHII
m&
SPRAYII
m&
SHIII
m&
2 , SHII
h
SPRAY
h
1 , SHIII
h
Reheat
IN
Air
IN
Coal
IN
HP Steam
OUT
Flue Gas
OUT
Ash
OUT
Feedwater
IN
HP Steam
OUT
SHIII RH SHI SHII
SPRAYII SPRAYI
EVAP
ECO
1 2
1 2 1 2 1 2
1
2
APH
1
2
Figure 11: Flow chart of the PCF boiler arrangement used in this heat load calculation model.
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STEAM BOILER TECHNOLOGY Boiler Calculations
Calculations of heat load
When the steam parameters and mass flows have been determined, the heat load of the heat
exchanger units can be calculated. The heat load is the heat transferred by a heat exchanger
(calculated in kW).
Evaporator
The heat load of the evaporator part of the boiler can be calculated as:
( ) (
2 2 ECO BD ECO SH EVAP
h h m h h m + = & & ) (2)
where is the mass flow of steam before superheater [kg/s], h
SH
m& the specific enthalpy of saturated
steam at steam drum pressure [kJ/kg], the specific enthalpy after economizer the mass
flow of blowdown water from steam drum, and h
2 ECO
h
BD
m&
the specific enthalpy of saturated water at steam
drum pressure [kg/s].
Superheater
Normally superheating takes place in three or four stages in a big boiler. This calculation example is
based on three stage superheating. The heat load of the first superheater stage is
( ) h h m
SHI SH SHI
=
2 ,
& (3)
where is the specific enthalpy of steam after the first superheater stage. In the second
superheater stage the heat load added can be calculated as:
2 , SHI
h
( )
1 , 2 , SHII SHII SHII SHII
h h m = & (4)
where is the mass flow of steam before the second superheater [kg/s], the specific
enthalpy of steam after the second superheater stage [kJ/kg], and the specific enthalpy of
steam before the second superheater stage. Similarly, the heat load added in third superheater stage
can be calculated as:
SHII
m&
2 , SHII
h
1 , SHII
h
( )
1 , 2 , SHIII SHIII SHIII SHIII
h h m = & (5)
wher = Mass flow of steam before third superheater [kg/s], the specific enthalpy of
steam after third superheater stage [kJ/kg], and the specific enthalpy of steam before third
superheater stage [kJ/kg].
SHIII
m&
2 , SHIII
h
1 , SHIII
h
Reheater
The heat load of the reheater stage can be calculated as:
(
1 2 RH RH RH RH
h h m = & ) (6)
where is the mass flow rate of steam in the reheater [kg/s], the specific enthalpy of steam
after the reheater [kJ/kg] , and the specific enthalpy of steam before the reheater.
RH
m&
2 RH
h
1 RH
h
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STEAM BOILER TECHNOLOGY Boiler Calculations
Economizer
The heat load of the economizer can be calculated as:
(
1 2 ECO ECO ECO ECO
h h m = & ) (7)
where is the mass flow rate of feedwater in the economizer [kg/s], the specific enthalpy
of feedwater after the economizer [kJ/kg], and the specific enthalpy of feedwater before the
economizer.
ECO
m&
2 ECO
h
1 ECO
h
Air preheater
In order to calculate the heat load for the air preheater, we need to know the combustion air mass
flow, the temperature of the flue gases and the incoming air. The combustion air fed into air
preheater, is taken from upper part of the boiler room. The temperature of the combustion air before
the air preheater is therefore between 25 and 40C (in Finnish conditions). The flue gases exiting
the boiler are usually kept above 130-150C in order to prevent corrosion. The enthalpies can be
taken from tables:
(
1 2 APH APH
FUEL
AIR
FUEL APH
h h
m
m
m =
&
&
& ) (8)
where is the mass flow rate of fuel fed into the boiler [kg/s],
FUEL
m&
FUEL
AIR
m
m
&
&
the mass flow rate of
combustion air divided by the mass flow rate of fuel fed into the boiler, the specific enthalpy
of combustion air before the air preheater [kJ/kg], and
A
h e specific enthalpy of combustion air
after the air preheater.
1 APH
h
2 PH
th
Determination of boiler efficiency
Standards
There are two main standards used for definition of boiler efficiency. Of those, the German DIN
1942 standard employs the lower heating value (LHV) of a fuel and is widely used in Europe. The
American ASME standard is based on higher heating value (HHV). However, this chapter
calculates the efficiency according to the DIN 1942 standard. [2]
It should be marked that with the DIN standard it is possible to reach boiler efficiencies over 100%,
if the condensation heat of the flue gases is recovered.
Major heat losses
Heat loss with unburned combustible gases
The typical unburned combustible gases are carbon monoxide (CO) and hydrogen (H2). In large
boilers usually only carbon monoxide can be found in significant amounts in flue gases. Assuming
that flue gases contain only these two gases, the losses [kW] can be calculated as:
2 2
, , 1 H l H CO l CO L
H m H m + = & & (9)
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STEAM BOILER TECHNOLOGY Boiler Calculations
where is the mass flow of carbon monoxide [kg/s], the mass flow of hydrogen, the
lower heating value (LHV) of carbon monoxide (10.12 MJ/kg), and
2
the lower heating value
(LHV) of hydrogen (119.5 MJ/kg). If a relevant amount of some other flue gas compound can be
found in the flue gases, it should be added to the equation.
CO
m&
2
H
m&
CO l
H
,
,H l
H
Heat loss due to unburned solid fuel
Unburned fuel can exit the furnace as well as bottom ash or fly ash. The heating value of ashes can
be measured in a specific laboratory test. The losses [kW] of unburned solid fuels can be calculated
as:
ubs l ubs L
H m
, 2
= & (10)
where is the total mass flow of unburned solid fuel (bottom ash and fly ash in total) [kg/s], and
the lower heating value (LHV) of unburned solid fuel (fly ash and bottom ash in total)
[kJ/kg]. Some estimates of the losses with unburned solid fuels are presented in Table 1:
ubs
m&
ubs l
H
,
Table 1: Estimates of losses with unburned solid fuel. [2]
Boiler type Heat loss per heat input of fuel
Oil fired boiler 0,2 - 0,5 %
Coal fired boiler, dry ash removal 3 %
Coal fired boiler, molten ash removal about 2 %
Grate boiler 4-6 %
Heat loss due to wasted heat in flue gases
Flue gases leave the furnace in high temperature and thus they carry significant amount of energy
away from boiler process. The heat loss due to wasted heat in flue gases is much larger than any
other loss; therefore this is the most dominating factor affecting the boiler efficiency. To decrease
flue gas losses, flue gas exit temperature should be decreased. However, the acid dew point of flue
gases restricts the flue gas temperature to about 130-150C for sulfur containing fuels. The losses
caused by the sensible heat of flue gases can be calculated as:
=
i
i
fuel
i
fuel L
h
m
m
m
&
&
&
3
(11)
where is the fuel mass flow [kg/s], the mass flow of a flue gas component, and the
specific enthalpy of a flue gas component (e.g. CO
2
) [kJ/kg].
fuel
m&
i
m&
i
h
Heat loss due to wasted heat in ashes
Ash can exit the furnace either as bottom ash from bottom of the furnace or as fly ash with flue
gases. The losses related to the sensible heat of ash can be calculated as:
fa fa p fa ba ba p ba L
T c m T c m + =
, , 4
& & (12)
127
STEAM BOILER TECHNOLOGY Boiler Calculations
where is the mass flow of the bottom ash [kg/s], the specific heat of the bottom ash
[kJ/(kgK)], the temperature difference between the bottom ash temperature and the reference
temperature [C], the mass flow of fly ash, the specific heat of fly ash, the
temperature difference between the fly ash temperature and the reference temperature [C]. Usually
the reference temperature is 25C.
ba
m&
ba p
c
,
ba
T
fa
m&
fa p
c
, fa
T
In recovery boilers the bottom ash is removed as molten ash in temperature of about 700-800C. In
addition, the amount of bottom ash divided by the amount of fuel is about 40%. The loss of sensible
heat of ash is therefore of great importance in recovery boilers.
Losses due to heat transfer (radiation) to the environment
The main form of heat transfer from boiler to boiler room is radiation. It is proportional to the outer
surface area of the boiler and is usually 200-300 W/(m
2
K) for a well-insulated boiler having its
outer surface temperature below 55C. Another possibility to determine the heat transfer losses to
the environment is to use a table from the DIN 1942 standard, presented in Table 2.
Table 2: Estimations of heat transfer losses by radiation. [2]
Mass flow rate of steam [t/h]
Combustion method
10 20 40 60 80 100 200 400 600 800
Pulverized firing - 1,3 1,0 0,9 0,75 0,7 0,55 0,4 0,35 0,3
Grate 1,5 1,1 0,9 0,7 - - - - - -
Loss [%]
Oil/gas fired boiler 1,3 0,9 0,7 0,6 0,55 0,4 0,3 0,25 0,2 0,2
Losses of blowdown, sootblowing and atomizing steam
Blowdown water from the steam drum and sootblowing steam (used to remove soot from heat
exchanger surfaces within the boiler) use a part of the steam produced by the boiler. This lowers the
boiler efficiency. In addition, steam is sometimes also used to atomize fuel in the burners. The
losses can be calculated as:
atomizing atomizing sb sb bd L
h m h m h m + + = & & &
6
(13)
bd
m& is the mass flow of blowdown water [kg/s], h is the specific enthalpy of saturated water
(blowdown water from steam drum) [kJ/kg], is the mass flow of sootblowing steam, is the
specific enthalpy of steam used for sootblowing (when leaving the boiler), is the mass flow
of atomizing steam, and the specific enthalpy of steam used for atomizing the fuel (when
leaving the boiler) [kJ/kg].
sb
m&
sb
h
atomizing
m&
atomizing
h
Internal power consumption
The power plant itself consumes a part of the electricity produced. This is due to the various
auxilary equipments required, like feedwater pumps, circulation pumps and air/flue gas blowers. In
forced circulation boilers the share of electricity consumed by the circulation pump is about 0.5% of
the electricity produced by the plant. The power consumption of the flue gas fan and the air blower
are 0.75 1% each.. The largest power consumer is the feed water pump (about 2%).
128
STEAM BOILER TECHNOLOGY Boiler Calculations
Normally the internal power consumption is about 5% of the electricity produced by the power
plant. Since the power used is electrical (and taken from the grid), the internal power consumption
share is reduced from the final boiler efficiency in boiler calculations.
Calculating boiler efficiency
There are two different means of calculating the boiler efficiency: The direct method and the
indirect method.
Direct method
In the direct method, the boiler efficiency is directly defined by the exploitable heat output from the
boiler and by the fuel power of the boiler:
input
output
= (14)
where is the exploitable heat output from boiler, and the fuel power of the boiler.
output
input
The direct method can be used for steam boilers where it is possible to measure the fuel heat input
accurately.
Indirect method
Indirect method determines the efficiency of a boiler by the sum of the major losses and by the fuel
power of the boiler:
input
losses
=1 (15)
where
losses
is the sum of the major losses within the boiler, and is the fuel power of the
boiler.
input
The indirect method provides a better understanding of the effect of individual losses on the boiler
efficiency and is used for boilers where the fuel heat flow is difficult to measure (eg. Biomass and
peat fired steam boilers).
129
STEAM BOILER TECHNOLOGY Boiler Calculations
References
1. Khartchenko N. V. Advanced energy systems. Taylor & Francis 1998, U.S.
ISBN 1-56032-611-5
2. DIN 1942 standard. "Abnahmeversuche an Dampferzeugern".
130
Thermal Design of Heat Exchangers
Sebastian Teir, Anne Jokivuori
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
Table of contents
Table of contents.............................................................................................................................. 132
General design issues....................................................................................................................... 133
Heat transfer modes ..................................................................................................................... 133
Conduction............................................................................................................................... 133
Convection ............................................................................................................................... 133
Radiation.................................................................................................................................. 134
Pressure losses.............................................................................................................................. 134
Definition ................................................................................................................................. 134
Gas side pressure drop for inline tube arrangement................................................................. 135
Gas side pressure drop for staggered tube arrangement .......................................................... 135
Choice of tube surface.................................................................................................................. 136
Sizing of heat transfer surfaces .................................................................................................... 136
Furnace design ................................................................................................................................. 137
Furnace strain level ...................................................................................................................... 138
Tube wall design.......................................................................................................................... 139
Load characteristics...................................................................................................................... 140
Fuel type effect on furnace size ................................................................................................... 140
Typical furnace outlet temperatures............................................................................................. 140
Furnace air levels ......................................................................................................................... 141
CFB furnace design...................................................................................................................... 142
BFB furnace design...................................................................................................................... 143
Heat recovery steam generator (HRSG) design........................................................................... 144
Furnace dimensioning, stirred reactor.......................................................................................... 146
Superheater design........................................................................................................................... 146
Design velocity ............................................................................................................................ 147
Design spacing............................................................................................................................. 147
Tube arrangement ........................................................................................................................ 147
Economizer design........................................................................................................................... 149
Design method ............................................................................................................................. 149
Air preheater design......................................................................................................................... 151
References........................................................................................................................................ 152
132
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
General design issues
Heat transfer modes
Conduction
Conduction is the transfer of heat from one part of a body at a higher temperature to another part of
the same body at a lower temperature, or from one body at a higher temperature to another body in
physical contact with it at a lower temperature. The conduction process takes place at the molecular
level and involves the transfer of energy from the more energetic molecules to those with a lower
energy level.
Heat power [W] by conduction is:
s
t t
A
2 1
= (1)
Heat power depends on the heat transfer area (A), temperature difference (t
1
-t
2
), thermal
conductivity of material () and the thickness of separating wall (s). The thermal conductivity is a
property of the material; metals conduct well heat whereas gases not. An example of thermal
conductivities in various materials is shown in Table 1. [1]
Table 1: Thermal conductivities for various materials.
Material Thermal conductivity [W/(m*K)]
Copper 370
Aluminium 210
Steel 45
Stainless steel 20
Insulations 0,03-0,1
Convection
Convection is heat transfer between a moving fluid or gas and a fixed solid. Convection can be
natural or forced: if a pump, a blower, a fan, or some similar device induces the fluid motion, the
process is called forced convection. If the fluid motion occurs as a result of the density difference
produced by the temperature difference, the process is called free or natural convection.
Heat power by convection can be calculated as:
(
2 1
t t A
c
= ) (2)
The heat transfer coefficient
c
varies much depending on e.g. flow velocity, type of fluid motion
and pressure. Heat transfer coefficients of liquids are much higher than those of gases, as can be
seen in the comparison presented in Table 2.
133
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
Table 2: Convection heat transfer coefficients for various fluids.
Fluid Heat transfer coefficient [W/(m
2
K)]
Steady water 100-500
Water flow 500-10000
Water boiling 1000-60000
Steady air 3-15
Air flow 10-100
Radiation
Radiation, or more correctly thermal radiation, is electromagnetic radiation emitted by a body by
virtue of its temperature and at the expense of its internal energy. All heated solids and liquids, as
well as some gases, emit thermal radiation.
The importance of radiation heat transfer will increase, when the temperature becomes higher.
Radiation heat transfer is the main heat transfer mode for the furnace and radiation superheaters.
Emitted heat by radiation can be calculated as:
) (
4 4
w f fw r
T T A = (3)
where
fw
is the view factor between the flame and the water walls:
1
1 1
1
+
=
w f
fw
(4)
where
f
is the emissivity of the flame (typically 0.35-0.85),
w
the emissivity of the water walls
(typically 0.6), the Stefan-Boltzmann constant (5.6787*10
-8
W/m
2
K
4
), A the effective water wall
surface (m
2
), T
f
the average gas temperature in the furnace and T
w
the average water wall surface
temperature surrounding the flame.
Radiation heat can also be expressed as
(
2 1
t t A
rad
= ) (5)
where
rad
is the radiation heat transfer coefficient.
Pressure losses
Definition
The difference between pressure gage readings in parts of a system operating with a positive
pressure relative to that of the atmosphere is generally called pressure drop. The pressure drop on
the gas side is equal to the friction losses, according to VDI Wrmeatlas [1]:
f gs
p = p (6)
134
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
Gas side pressure drop for inline tube arrangement
For inline tube arrangement the pressure drop coefficient for heat transfer surface with horizontal
tubes is:
d r r
p n = p (7)
where n
r
is the number of tube rows in the heat transfer unit, p
d
dynamic pressure calculated at
the gas side using the mean temperature and the smallest area. The single row pressure drop
r
for
inline tube arrangement is calculated as
) 1 (
2000
1000 Re
+ = e
t l r
(8)
where
Re ) 4 (
) 75 . 0 ) 6 . 0 (( 280
6 . 1
5 . 0
2
t
l
s s s
s
l t
l
+
= (9)
) 1 )( 1 ( 03 . 0
0.85) - (s
)
s
0.94
- (1
1.2 + (0.22 10 =
1.3
t
0.6
l 1.5) - /s 0.47(s
t
l t
+
l t
s s (10)
where
l
is the laminar part of the pressure drop coefficient,
t
is the turbulent part of the pressure
drop coefficient, s
t
is the dimensionless transverse pitch (s =
o
), s
l
is the dimensionless
longitudinal pitch (s =
o
) and Re is the Reynolds number, calculated at the gas side mean
temperature and smallest area.
S / d
t t
S / d
l l
Gas side pressure drop for staggered tube arrangement
The single row pressure drop
r
for staggered tubes is calculated similarly to inline tube
arrangement, with the following exceptions:
+ =
1000
200 Re
1 e
t l r
(11)
( )
( ) Re 4
75 . 0 6 . 0 280
6 . 1
2 5 . 0
c s s
s
l t
l
l
+
= (12)
where
2 / 1 2 ; )
2
(
/2 1 - 2s s ; s = c
2
2
t l t
< + =
t l
t
s s s
s
c
l
(13)
135
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
( )
3 3
08 . 1
1 01 . 0 1 4 . 0
85 . 0
2 . 1
5 . 2
+ =
l
t
t
l
t
t
s
s
s
s
s
(14)
Choice of tube surface
Surfaces used in tubular heat transfer units can be finned or unfinned (smooth surface). Heat
transfer properties can be improved using finned tubes, because the fins enlarge the tubular heat
transfer area.
The tubes in the economizer are usually finned,
because the heat transfer properties of the flue
gas side are not as good as on the water side.
Economizers are made of cast iron or steel
tubes. Cast iron tubes are easily equipped with
fins, but also steel tubes can be equipped with
fins. Finned tubes are more difficult to clean
than unfinned tubes, thus economizers with
unfinned steel tubes are used in boilers burning
fuels with a high ash content.
Figure 1, Figure 2, and Figure 3 provide some
examples on finned steel tubes. Spiral finned
tubes are often used in heat recovery steam
generators. By bending fins heat transfer
properties can also be improved. Steel tube with
aluminium fins endures better in corrosive
conditions. Compound composition conists of a
cast iron tube equipped with fins and steel tube
inside. A compound composistion endures
higher pressure.
In air preheaters finned steel tubes are not used,
since the heat transfer properties are practically
the same on both air and flue gas sides. When
cast iron tubes are used, heat transfer surfaces
are usually finned on both sides to improve the
heat transfer.
Superheaters and furnaces use unfinned tubes.
Sizing of heat transfer surfaces
When sizing the heat transfer surface of a heat
exchanger the heat power to be transferred and
Figure 1: Spiral finned tubes.
Figure 2: Finned tubes.
stream temperatures of inlets and outlets have to be known. The heat power is proportional to the
area of the heat exchanger, heat transfer coefficient and temperature difference (between the
streams):
lm
T kA = (15)
136
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
The mean logarithmic temperature difference in equation 15 can be calculated as:
min
max
min max
ln
T
T
T T
T
lm
= (16)
where T
max
is the largest temperature difference and T
min
the smallest temperature difference:
T
max
= t
h1
-t
c2
T
min
= t
h2
-t
c1
(17)
where the inlet and outlet temperatures are
explained in Figure 4.
The heat surface area can be calculated from
equation 15, when temperatures and the heat
transfer coefficient have been determined, which
is the capability of the heat exchanger to transfer
heat between two fluids.
Figure 3: Parallel finned tube.
Figure 4: Heat exchanger stream descriptions
(for a cross-flow heat exchanger), used in
equation 17.
Furnace design
The main parameters for the furnace sizing are furnace dimensions (height, depth, width and
configuration), furnace wall construction and desired furnace outlet temperature.
The heat transfer surface area of furnace consists of sides, base and beak, which is an "L"-formed
bending of the evaporator tubes that protect the superheaters from radiation. Most of utility and
industrial boiler furnaces have a rectangular shape. A large number of package boilers have a
cylindrical furnace. Furnace bottom for typical PCF boiler is double inclined or v-form, as shown in
Figure 5. Flat bottom is more typical for grate and fluidized bed boilers.
The ratio of height and width varies 1-5 for boilers with two-pass layout. The larger the boiler is,
the larger is also the ratio. The largest boilers have a width of 20 m and a height of 100 m. The fuel
and vaporization efficiency determines the size of the furnace. To be able to dimension furnaces the
overall mass balance, heat balance and heat transfer must be specified.
137
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
The overall furnace (gas side) mass balance is
sootb ash fi air fg
m m m m m & & & & & + + =
(18)
where the streams are described in Figure 6.
is the sum of all the fuel streams into the
boiler and is the sootblowing steam. The
furnace heat balance can be specified similarly:
fi
m&
sootb
m&
exit loss net fur
= (19)
where the heat fluxes are shown in Figure 7. If
the gas side temperatures and emissivities are
known, the furnace heat flux absorbed by the
furnace walls can be expressed as
( )
w g eff c w dg
g dg
w dg w dg
w
eff fur
T T A T
T A
+
+
=
)
(
4
4
(20)
where A
eff
is the effective heat transfer surface,
the Stefan-Boltzmann constant,
w
and
the emissivity of the wall and the (dusty) gas
respectively, the absorbability of the (dusty)
gas,
dg
dg
c
the convective heat transfer coefficient,
and and the temperature of the gas and
wall respectively. The effect of convective term
is usually fairly small, often less than 10%.
g
T
w
T
Furnace strain level
The furnace is preliminarily dimensioned with a
suitable strain level. The volume (marked with a
V in Figure 5) strain level is calculated as the
following:
h
b2
b1
V
A
Figure 5: Furnace dimensions. The painted
areas are the total effective furnace heat
transfer area.
fg
m&
air
m&
fi
m&
ash
m&
sootb
m&
Figure 6: Fuel/flue gas side mass balance.
h b b
q
fuel
V
2 1
= (21)
where is the heat released from the fuel in the furnace and other variables furnace dimensions
according to Figure 5. The strain level depends largely on different fuels. Reference values on strain
levels from different fuels are presented in Table 3.
pa
The area strain level is calculated as the heat power in the furnace per base area of the furnace
(marked with an A in Figure 5):
138
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
2 1
b b
q
fuel
F
= (22)
Table 3: Strain level effects of various fuels.
Fuel
Strain level
[kW/m3]
Coal 145-185
Peat ~175
Oil, natural gas 290-690
fur
exit loss
net
Figure 7: Furnace heat balance.
If the electric power of power plant is known, strain levels for the volume and base area can be
chosen from the graphs in Figure 8, and thereby the physical dimensions of the furnace can be
determined.
6
5
4
3
2
[MW/m3]
0,25
0,20
0,15
0,10
0,05
[MW/m2]
0 200 400 600 MWe 0 200 400 600 MWe
Figure 8: Charts for selecting strain levels of the furnace.
The effective heat transfer surface area of the furnace, consisting of sides, base and beak, can be
calculated as following (assuming the beak adds 0.4*base area):
2 1
2 2 lb lb EPRS + (23)
The first two terms forms the effective projected radiant surface (EPRS), which is a widely used
concept.
Tube wall design
When the size of the furnace has been dimensioned, the tube size and material can be chosen and
the wall thickness can be calculated according to the SFS 3273, DIN or another applicable standard.
Then input velocity of water to furnace is chosen and number of necessary tubes is calculated.
The diameter of an evaporator tube is usually 30-80 mm and the wall thickness can be calculated
from the following equation:
139
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
2 1
2 2
C C
p p
n
p d
s
l
u
+ +
+
(24)
where d
u
is the outside diameter of tube, p the design pressure,
l
the design strength, n a safety
factor (usually 1.5), the strength factor (usually 1.0), C
1
an additional thickness, (normally 10%
of the wall thickness) and C
2
an additional thickness considering corrosion.
Load characteristics
When designing a steam-generating unit it is necessary to determine the following load
characteristics:
1. Minimum, normal and maximum load
2. Time duration of each load rate
3. Load factor
4. Nature of the load (constant or fluctuating)
The load factor is the actual energy produced by a power plant during a given period, given as a
percentage (share) of the maximum energy that could have been produced at full capacity during
the same period.
The design will determine the boiler's ability to carry a normal load at a high efficiency as well as to
meet maximum demand and rapid load changes. It will also determine the standby losses and the
rapidity with which the unit can be brought up to full steaming capacity. In smaller boiler sizes it is
possible to select a standardized unit that will meet the requirements; larger units are almost always
custom designed.
Fuel type effect on furnace size
The most important item to consider when designing a utility or large industrial steam generator is
the fuel the unit will burn. The furnace size, the equipment to prepare and burn the fuel, the amount
of heating surface and its placement, the type and size of heat recovery equipment, and the flue gas
treatment devices are all fuel dependent. The major differences among boilers that burn coal,
biomass, oil or natural gas result from the ash in combustion products.
Firing oil in the furnace produces relatively small amounts of ash. Natural gas produces no ash. For
the same power output, due to larger volumetric flue gas flow, coal-burning boilers must have
larger furnaces. The velocities of the combustion gases in the convection-based heat exchangers
must be lower, due to the high ash content of coal. Figure 9 presents an example of the relative sizes
of furnaces using three different fuels: natural gas, oil and coal. The power of the boiler is the same
in all three cases. Peat, biomass and recovery boilers are even bigger than coal fired boilers.
Typical furnace outlet temperatures
Furnace outlet temperature is the flue gas temperature after the radiation-based heat transfer
surfaces before entering the convection-based heat transfer surfaces. The outlet temperature
depends on the characteristics of the combusted fuel. If the temperature is too high, ash layers build
up on the surface of the superheater tubes. This leads to poorer heat transfer, increased corrosion
and it can even block flow paths.
140
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
h
b2
1,05*b1
1,2*h
1,5*h
b1
1,06*b2
1,1*b1
1,12*b2
Oil
Natural gas
Coal
Figure 9: Boiler fuel type effect on furnace size.
The following factors affect the choice of furnace outlet temperature:
Ash characteristics; the control of ash behaviour at superheaters is a key design parameter
Fuel (gas and oil have low ash content and can have higher outlet temperatures)
Choice of superheater material
Desired superheating temperature
Table 4 presents some typical furnace outlet temperatures.
Table 4: Typical furnace outlet temperatures on various boiler types.
Fuel type Furnace outlet temperature [C]
Biomass, circulating fluidized bed 900 - 1000
Peat, pulverized firing 950 - 1000
Coal, high volatiles 950 - 1000
Recovery boiler 900- 1050
Biomass, fluidized bed 1050 - 1150
Natural gas 900- 1200
Oil 900- 1200
Furnace air levels
The type of fuel determines the quantity of air required for combustion. It is necessary to provide air
in excess of this quantity to assure complete combustion. The amount of this excess air is
determined by the following factors:
1. Composition, properties, and condition of fuel when fired
2. Method of burning the combustible
141
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
3. Arrangement and proportions of the grate or furnace
4. Allowable furnace temperature
5. Turbulence and thoroughness of the mixing of combustion air and volatile gases
Excess air reduces efficiency by lowering the furnace temperature and by absorbing heat that would
otherwise be available for steam production.
NOx is formed when nitrogen of air reacts with oxygen of air in high temperature, over 1400C.
NOx can be reduced decreasing temperature, decreasing air excess, or using low-NOx-burners. In
using low-NOx-burner air will be fed into flame in two or three phases.
CFB furnace design
When dimensioning a circulating fluidized bed (CFB) furnace the high content of sand has to be
taken into consideration. This means that the temperature profile and thus the heat transfer near to
the furnace wall differs from other types of furnaces.
The furnace of a CFB (circulating fluidized bed) boiler contains a layer of granular solids, which
have a diameter in the range of 0.1-0.3 mm. It includes sand or gravel, fresh or spent limestone and
ash. The operating velocity of the flue gas stream in a CFB boiler is 3-10 m/s. The solids move
through the furnace at much lower velocity than the gas; solids residence times in the order of
minutes are obtained. The long residence times coupled with the small particle size produce high
combustion efficiency and high SO
2
removal with much lower limestone feed than in conventional
furnaces. Figure 10 shows a flow chart of a typical CFB boiler.
After the furnace flue gas moves through a cyclone (named compact separator in Figure 10), where
solids are separated from the gas and are returned to the furnace. Flue gas from the cyclone
discharge enters the convection back-pass in which the superheaters, reheaters, economizers and air
preheaters are located. A dust collector separates the fly ash before the flue gas exits the plant. The
combustion air from the fan pneumatically transports the solids for creating the circulating fluid.
The design of the furnace in a CFB boiler depends on:
required velocity of gas
time of complete combustion of fuel
heat required for vaporization.
The amount of cyclones also has an influence on the shape of furnace. Flue gas must flow to the
cyclone fast enough (20 m/s), and the diameter of the cyclone must be below 8 m in order to get an
efficient removal of solids.
Circulating fluidized bed boilers have a number of unique features that make them more attractive
than other solid fuel fired boilers. Fuel flexibility is one of the major attractive features of CFB
boilers. A wide range of fuels can be burned in one specific boiler without any major change in the
hardware. The combustion efficiency of a CFB boiler is high. It is generally in the range of 99,5 to
97,5 %. Sulphur capture in a CFB is very efficient, due to the possibility to inject sulphur absorbing
limestone directly into the bed. A typical CFB boiler can capture 90 % of the sulphur dioxide. The
low emission of nitrogen oxides is also a major attractive feature of CFB boilers.
CFB furnace design is explained in detail in the chapter about CFB boiler design.
142
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
Fuel
Steam Drum
Steam
Water
Steam Outlet
To Ash Silos
Fly Ash
Feed Water Inlet
Dust Collector
Induced Draft
Fan
Primary Air Fan
Secondary Air Fan
Economizer
Downcomer
Combustion
Chamber
Bottom
Ash
Limestone
Water
Wall
Air
heater
Compact
Separator
compact.eng/comflow.ds4/0801/tap
Foster Wheeler CFB
Flow Chart
Figure 10: Flow chart of a CFB boiler. [2]
BFB furnace design
Bubbling fluidized bed (BFB) boilers use a low
fluidizing velocity, so that the particles are held
mainly in a bed, which have a depth of about 1
m and a definable surface. Sand is often used to
improve bed stability, together with limestone
for SO
2
absorption. As the coal particles are
combusted and become smaller, they are
elutriated with the gases, and subsequently
removed as fly ash. In-bed tubes are used to
control the bed temperature and generate steam.
The flue gases are normally cleaned using a
cyclone, and then pass through further heat
exchangers, raising steam temperature.
In the furnace (Figure 11 and Figure 12) of a
BFB boiler size of a grain of sand is about 1-3
mm and the operating velocity is 0.7-2 m/s. Fuel
is fed onto the bed mechanically. Thanks to the
large heat capacity of the bed, a BFB furnace is
able to burn very moist fuel. Moist fuel will dry
fast, when it is fed to the sand bed. Many
Figure 11: Inside a BFB boiler furnace. [4]
143
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
different kinds of fuels can be combusted in a
BFB furnace. The wall area covered by the bed
is free from water tubes, in order to protect the
tubes from excessive erosion (Figure 11). This is
called a refractory lining.
The temperature of a BFB furnace outlet is 700-
900C, and the air factor is usually 1.1-1.4. Air
is fed in several phases. The temperature of air
varies from 20 to 400C. The overall thermal
efficiency of a BFB boiler power plant is around
30%.
BFB furnaces with an atmospheric operational
pressure are mainly used for boilers up to about
25 MWe, although there are a few larger plants
where a BFB boiler has been used to retrofit an
existing unit.
Heat recovery steam generator
(HRSG) design
Heat recovery steam generators (HRSGs) are
used in power generation to recover heat from
hot flue gases (500-600 C), usually originating
from a gas turbine or diesel engine. The HRSG
consists of the same heat transfer surfaces as
other boilers, except for the furnace. Since no
fuel is combusted in a HRSG, the HRSG have
(instead of a furnace) convention based
evaporator surfaces, where water evaporates into
Figure 12: BFB-boiler, Hrnsand
Energi&Milj Ab. [3]
steam. However, a HRSG can be equipped with a supplementary burner (as can be seen in Figure
13) for raising the flue gas temperature. A HRSG can have a horizontal or vertical layout,
depending on the available space.
When designing a HRSG, the following issues should be considered:
the pinch-point of the evaporator and the approach temperature of the economizer
the pressure drop of the flue gas side of the boiler
optimization of the heating surfaces
The pinch-point (the smallest temperature difference between the two streams in a system of heat
exchangers) is found in the evaporator, and is usually 6-10C, which can be seen in Figure 14. To
maximize the steam power of the boiler, the pinch-point must be chosen as small as possible. The
approach temperature is the temperature difference of the saturation temperature in the evaporator
and the output of the economizer. This is often 0-5C. The pressure drop (usually 25-40 mbar) of
the flue gas side has also an effect on the efficiency of power plant. The heat transfer of the HRSG
is primarily convective. The flow velocity of the flue gas has an influence on the heat transfer
coefficient.
144
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
The evaporator of heat recovery boiler can be of
natural or forced circulation type. The heat
exchanger type of the evaporator can be any of
parallel-flow, counter-flow or cross-flow. In
parallel-flow arrangement the hot and cold fluids
move in the same direction and in counter-flow
heat exchanger fluids move in opposite
direction.
Heating surfaces of a heat recovery steam
generator are usually heat transfer packages,
which consist of spiral-finned tubes. The
thickness of the fin is 1-2 mm, the height 8-16
mm and the fin distance 3.2-8 mm. Tube sizes
vary a lot.
Flue Gas
OUT
Flue Gas
IN
Fuel
IN
HP Steam
OUT
Feedwater
IN
Superheater
Evaporator
Economizer
Supplementary burner
Figure 13: Process scheme of single-pressure
HRSG with a supplementary burner.
0
100
200
300
400
500
600
700
0 % 10 % 20 % 30 % 40 % 50 % 60 % 70 % 80 % 90 % 100 %
Share of heat load [%]
T
e
m
p
e
r
a
t
u
r
e
[
C
]
Flue gas stream
Water/steam stream
Evaporator Superheater Economizer
Figure 14: Example of a heat load graph for a HRSG boiler.
145
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
Furnace dimensioning, stirred reactor
One of the most used furnace dimensioning methods is the stirred reactor model. The furnace is
approximated as being filled with a homogenous three-atom gas and a dust mixture at a uniform
temperature and pressure. At the furnace exit the temperature is decreased by a specified amount.
The stirred reactor furnace dimensioning process is as follows:
1. Guess initial furnace dimensions; shape, height, width, depth
2. Guess furnace exit temperature, T
exit
3. Calculate heat transfer using flue gas temperature T
fg
= T
exit
+T
4. Calculate furnace exit temperature from heat balance with calculated heat transfer
5. If the mode does not converge, then return to step 2
6. If the calculated furnace exit temperature differs from the desired one, return to step 1
The typical values of T to use for the different types of furnaces can be seen in Table 5. The stirred
reactor model is not optimal for designing a recovery boiler furnace.
Table 5: Typical values of T for various types of furnaces.
Boiler type
T [C]
PCF (molten), coal 200 (100-300)
PCF (dry), coal 180 (100-250)
Grate firing, coal 130 (100-180)
PCF, lignite 120 (100-150)
Oil and gas 150 (100-200)
BFB 130 (100-150)
CFB 0
Superheater design
The production of steam at higher temperature than the saturation temperature is called
superheating. The temperature added to the saturation temperature is called the degree of superheat.
Superheated steam has no moisture; hence it is less erosive and corrosive than wet saturated steam
carrying droplets. In order to have a sustainable turbine operation, the steam cannot contain any
moist at all.
The design procedure for a superheater can be divided into the following steps:
Tube size and material are chosen. Wall thickness is calculated.
Flow velocity in tube is chosen, number of tubes is calculated, tube construction and width
of heat exchanger are chosen.
Height of heat exchanger is calculated according to the chosen flue gas velocity.
Internal heat transfer coefficient (for the inside, water side of the tube) is calculated.
External heat transfer coefficient (for the outside, gas side of the tube) is calculated.
Thermal resistance of dirt layer is calculated.
Thermal resistance/tube length is calculated.
Conductance is calculated
146
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
Necessary tube length is calculated.
Necessary number of passages is calculated.
Assumed values are iterated.
Main dimensions are calculated.
Inside and outside pressure losses are calculated.
Heat exchangers are drawn to the technical drawing of boiler.
Design velocity
Superheaters transfer heat from flue gas to steam (gas phase of water). Heat transfer between two
gases is not very effective compared to heat transfer from gas to fluid. For that reason, steam must
flow fast enough (10-20 m/s) in order to give the superheater tubes enough cooling. Lower steam
pressure weakens the heat transfer rate, so with lower pressures, steam must have a greater velocity
(15-40 m/s).
When flue gas is cooled, its volume decreases. In order to keep a constant flow rate of the flue gas,
the cross-sectional flow area decreases as well. In the radiant superheater, the velocity of gas is very
small (< 5 m/s). In the convection superheater, the velocity can be quite large (15-30 m/s). The
maximum velocity depends on the fuel used. To limit pressure-part erosion from fly ash, the flue
gas velocity must not exceed certain limits. Depending upon the ash quantity and abrasiveness, the
design velocity is generally 16-18 m/s. A furnace that burns coals yielding a heavy loading of
erosive ash (usually indicated by a high silica/aluminium content) may have a design velocity of
approximately 15 m/s. Such velocities are based on the predicted average gas temperature entering
the tube section, at the maximum continuous rating of the steam generator fired at normal excess-air
percentage.
Design spacing
Superheater of boiler consists of banks of tubes. A system of tubes is located in the path of the
furnace gases in the top of furnace. Heat transfer in superheaters is based mainly on radiation, but in
the primary superheaters convection often plays a major role.
A superheater must be built so that it superheats approximately the same amount of steam from low
to high loads. This can be achieved by a proper choice of radiative and convective superheating
surfaces. Changing tube lengths between passes can control temperature differences. The outermost
tube that receives the most radiative flux should be shorter than the rest of the tubes. Proper
superheater arrangement also eliminates much of the problems with uneven or biased flue gas flow.
Figure 15 and Figure 16 shows examples of the arrangement of superheater and reheater surfaces in
the form of a process scheme.
Tube arrangement
Tubes in superheaters can be arranged according to inline or staggered arrangement (Figure 17).
Inline tube arrangement is preferred for fouling, PCF, bark and recovery boilers. Staggered
arrangement is preferred for oil, gas and heat recovery steam generator. As free space with
staggered arrangement is much smaller than with inline arrangement the reason for decreased
fouling with inline is evident. The heat transfer for a staggered arrangement is better than for an
inline arrangement.
The superheater tube diameter is usually 30-50 mm. For convection heat surfaces the dimension a
(Figure 17) is 80-200 mm and b is 60-150 mm. For radiation heat surfaces a is over 500 mm
and b is approximately the same as the external tube diameter.
147
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
Superheated
Steam OUT
Saturated
Steam IN
Feedwater
IN
Superheater I
Superheater II
Superheater III
Figure 15: An example of superheater block arrangements.
Superheated
Steam OUT
Saturated
Steam IN
Feedwater
IN
Reheater
IN
Reheated
Steam OUT
Superheater II
Superheater III
Reheater II
Superheater I
Reheater I
Figure 16: An example of superheater and reheater block arrangements.
The number of tubes in the superheater is calculated according to the average flow velocity and
volume flow. In the convection superheater the width of the superheater is the same as the width of
the furnace. When the number of tubes is known, all tubes are preliminarily placed next to each
other in the flue gas channel. If the cross-sectional area of the flue gas pass between two tubes
(dimension a in Figure 17) becomes too small, the tubes have to be placed in two or more rows.
148
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
D
i
r
e
c
t
i
o
n
o
f
g
a
s
f
l
o
w
Inline Staggered
C
l
e
a
r
l
a
n
e
b b
a
Figure 17: Inline and staggered tube arrangement.
Economizer design
An economizer consists of an arrangement of tubes through which the feed water is passed
immediately before entering the boiler. The combustion gases leaving the boiler convection
surfaces pass over these tubes. As the entering feed water has a lower temperature than that of the
boiler steam, the heat transfer is more effective at this point than in the convection surfaces of the
boiler. This fact has prompted the present trend in boiler design to increase the economizer surface
and proportionally decrease the evaporator heating surface. Economizers can be made of cast iron
or steel tube. Finned tubes are used, unless the flue gases origins from fuels with high ash content.
Design method
The following variables will be chosen
Inside and outside tube diameters d
i
and d
o
, from which we can calculate the wall thickness:
2
i o
d d
= (25)
Distance of tubes in direction of flow and in side direction: s
1
and s
2
(named a and b in
Figure 17)
The size of flue gas channel: b
1
and b
2
The number of tubes in one row (counter-flow) can then be calculated as:
2
2
s
b
M = (26)
The cross-sectional area of the flue gas channel can then be calculated from equation 27.
A
fg
= b
1
b
2
Md
o
b
1
(27)
149
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
Holes of flow-through area combined circle are:
U = (M+1)*(2* b
1
-2*(s
1
- d
o
)) (28)
The hydraulic diameter can then be calculated as:
U
A
d
fg
h
=
4
(29)
Then s
1
/d
o
, s
2
/d
o
, C and m can be read from charts. [5]
The average flue gas temperature of the economizer is:
2
sup fgeco fg
f
T T
T
+
= (30)
The outside convection heat transfer coefficient is calculated from the following equation (turbulent
gas flow):
31 , 0
Pr Re = =
m
fg
h oc
C
d
Nu
->
31 , 0
Pr Re =
m
h
fg
oc
C
d
(31)
where
fg
is the thermal conductivity of the flue gas, Pr is Prandtl number, of flue gas,
o
the
outside convectional heat transfer coefficient and Re Reynolds number, which can be calculated as:
fg h
w d
= Re (32)
where w
fg
is the flue gas velocity in the flue gas channel, d
h
the hydraulic diameter of the channel
(Equation 30) and the cinematic viscosity of flue gas.
The needed tube surface area in the economizer can then be calculated as:
k
G
A = (33)
where G is the conductance (kW/K) and k the heat transfer coefficient, which can be calculated
according to equation 35:
dirt
o
o i i
o
m
d
d
d
k
+
+ + =
1
1 1
(34)
150
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
where d
i
and
d
o
are the inside and the outside tube diameter [m] respectively,
i
and
o
the inside
and outside heat transfer coefficient respectively, the tube wall thickness, the thermal
conductivity and m
dirt
the heat transfer resistance of a tube with a dirt layer on its surface. The
outside heat transfer coefficient is the sum of the outside radiative and convective heat transfer
coefficients:
o
=
oc
+
rad
(35)
The surface area of one tube is:
A
t
= * d
o
*b
1
(36)
The number of tube rows in depth direction is:
M A
A
N
t
= (37)
And the depth of the economizer is:
h
e
= N* s
1
(38)
Air preheater design
Recuperative air preheater design is similar to other convective heat transfer surfaces. The tubes of
air preheaters are larger than the tubes of superheaters and economizers: the diameter is about 50-80
mm.
Wall thickness is sized according to the strength of the construction, because the pressure difference
between air and flue gases is small. The flue gas velocity in the air preheater is 10-14 m/s in the
tubular heat exchanger type, 9-13 m/s in the plate heat exchanger type, 10-11 m/s in a finned tube
heat exchanger, and 13-15 m/s if both sides of the heat exchanger are finned.
In a vertical tube heat exchanger flue gas flows inside tubes and number of tubes can be chosen
according to the flue gas velocity and volume flow. By choosing suitable tube divisions, dimensions
of horizontal cross section of heat exchanger can be calculated. Air is flowing horizontally outside
tubes. By choosing air velocity height of heat exchanger can be calculated. According thermal
sizing length of heat exchanger can be found. In horizontal tube heat exchanger air flows inside
tubes and number of tubes can be chosen according to the air velocity and volume flow.
Regenerative air preheaters are usually made of enamel coated ceramic elements. This is popular,
because ceramics are non-combustibles and have a low low-temperature corrosion rate. Another
option is metallic dimple elements. Metallic elements have higher efficiency, require lower height
and have lower pressure drop. Problems are a possible high corrosion rate of metallic elements.
151
STEAM BOILER TECHNOLOGY Thermal Design of Heat Exchangers
References
1. VDI Wrmeatlas.
2. Pictures and schematics supplied by Foster Wheeler. http://www.fwc.com/
3. Picture supplied by Hrnsand Energi&Milj Ab, Fortum. http://www.fortum.com
4. Photograph by Rintala T., Fortum. http://www.fortum.com
5. Alvarez H. Energiteknik del 1 and Energiteknik del 2. Studentlitteratur, Lund. 1990. p. 368
6. M. Huhtinen, A. Kettunen, P. Nurminen, H. Pakkanen, Hyrykattilatekniikka, Oy Edita Ab,
Helsinki 1994, ISBN 951-37-1327-X
7. Opetusmoniste kevt 2000: Ene-47.110 Yleinen energiatekniikka, er 1, HUT
8. Opetusmoniste kevt 2000: Ene-47.124 Hyrykattilatekniikka, er 1, HUT
9. Opetusmoniste kevt 2000: Ene-47.124 Hyrykattilatekniikka, er 2, HUT
10. V. Meuronen, 4115 Hyrykattiloiden suunnittelu, Opetusmoniste 1999, LTKK, ISBN 951-
764-382-9
11. Combustion Engineering. Combustion: Fossil power systems. 3
rd
ed. Windsor. 1981.
12. Vakkilainen E. Lecture slides and material on steam boiler technology. 2001.
152
Circulating Fluidized Bed Boilers
Dianjun Zhang, Sebastian Teir
STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boilers
Table of contents
Table of contents.............................................................................................................................. 154
Introduction to fluidized bed boilers................................................................................................ 155
Fluidized bed principles............................................................................................................... 155
Basic principles of CFB boilers ................................................................................................... 157
Characteristics of CFB systems ................................................................................................... 159
The advantages of CFB boilers.................................................................................................... 160
Combustion in CFB boilers ............................................................................................................. 161
Fuel flexibility.............................................................................................................................. 162
Combustion zones in a CFB boiler .............................................................................................. 162
Heat transfer in a CFB boiler ........................................................................................................... 163
Bed to wall heat transfer .............................................................................................................. 163
Bubbling bed to external heat surfaces ........................................................................................ 164
Heat transfer and part-load operation........................................................................................... 164
Load control in CFB boiler .......................................................................................................... 165
Emissions ......................................................................................................................................... 165
SO
2
Emissions.............................................................................................................................. 165
NOx - emissions........................................................................................................................... 166
Particulate matter (PM) emission................................................................................................. 168
Carbon monoxide and hydrocarbons ........................................................................................... 168
References........................................................................................................................................ 169
154
STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boilers
Introduction to fluidized bed boilers
In order to control emission levels from coal combustion, advanced combustion technologies and
pollutant capture technologies are utilized. Pulverized coal (PC) combustion with flue gas cleaning
using a desulfurization plant, including bag-house filters for desulfurization and electrostatic
precipitators for fly ash, is the commonly used technology. But one of the shortages of PC boilers is
that high combustion temperature in the furnace causes high NOx formation. During the recent
decades, fluidized bed combustion (FBC) has been developed and put into use rapidly due to its
good features, such as SO
2
removal during combustion, low NOx emissions and multi-fuel
flexibility.
The fluidization process was invented by Fritz Winkler in 1921. The process used for coal burning
was developed and promoted by Douglas Elliott in 1960s. After that Lurgi of Germany and
Alhlstrm Group in Finland developed FBC further. Foster Wheeler, Babcock & Wilcox, and Lurgi
are currently the largest FBC boilers manufacturers.
Fluidized bed boilers can be categorized into three main types, bubbling fluidized bed (BFB),
atmospheric circulating fluidized bed (ACFB, commonly referred to as CFB), and pressurized
circulating fluidized bed (PCFB). This chapter will focus on CFB boilers.
Fluidized bed principles
Fluidization is a phenomenon where fine solids are transformed into a fluid-like state through
contact with a fluid, either gas or liquid. Under the fluidized condition, gravitational forces on
granular, solid particles are offset by the fluid drag on them. Thus, the particles remain in a semi-
suspended condition and take on many of the physical characteristics of a fluid.
As the gas velocity increases through a bed of particles many changes occur in the gas/solid contact
mode. At low velocities the gas is essentially flowing through a fixed bed of particles, while at high
velocities the solids are entirely entrained in the gas stream. When comparing various combustion
technologies, stoker-fired boilers operate with a fixed bed, while pulverized boilers operate with
solids completely entrained. The furnace of a CFB boiler operates in a regime somewhere between
these two extremes.
The principle of fluid bed systems can also be explained by examining the relationship between
differential gas pressure across a bed of particles and the superficial gas velocity through that bed
(Figure 1).
For a fixed bed, the log of differential pressure is proportional to the log of gas velocity and
represents the frictional pressure drop of the gas through the bed.
As the gas velocity increases beyond the minimum fluidization velocity, the bed begins to expand
and the particles become fluidized. A distinct bed level is visible in the fluid bed. As the gas flow
rate through the fixed bed increases, the pressure drop continues to rise until the superficial gas
velocity reaches the critical minimum fluidization velocity, U
mf
.. At that point the gravitational
forces are overcome by the buoyant drag forces on the particles and they become suspended (i.e.,
fluidized). The minimum fluidizing velocity depends on many factors including particle diameter,
gas and particle density, particle shape, gas viscosity, and bed void fraction. The following formula
calculates the minimum fluidizing velocity:
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boilers
+ = 7 . 33
) (
0408 . 0 7 . 33
2
2
g
s g s p
s p
s
mf
g d
d
U
(1)
where
g
is dynamic viscosity
d
p
is particle diameter
g
is gas density
p
is particle density
g is acceleration of gravity
FIXED BED BUBBLING TURBULENT CIRCULATING
PARTICLE
MASS FLOW
ENTRAINMENT
VELOCITY
MIN FLUID
VELOCITY
VELOCITY (LOG)
p
(LOG)
Figure 1: Regimes of fluidized bed systems. [1]
At velocities above U
mf
, the pressure drop through the bed remains constant and equals the weight of
solids per unit area as the drag forces on the particles barely overcome gravitational forces. The
following equation shows the pressure drop:
gH p
s g
) 1 )( ( = (2)
where
g
is gas density
p
is particle density
is ratio of empty volume in bed
g is acceleration of gravity.
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boilers
As gas velocity is further increased above the minimum fluidization velocity, the differential
pressure remains almost constant until the bed material begins to elutriate at the entrainment
velocity of the so-called bubbling bed. The degree of turbulent mixing of the solids continues to
increase between the minimum fluidization and the entrainment velocity.
Beyond the entrainment velocity or the terminal velocity, the particles are carried out of the vessel
and an inventory of particles can only be maintained by collecting and recirculating the entrained
particles back to the vessel or by adding additional solid particles. The entrainment velocity marks
the transition from a bubbling bed to a circulating bed. Beyond this velocity, the differential
pressure becomes a function of velocity and solid recirculation rate. The terminal velocity for a
fluidized bed can be calculated as
( )
g
C
d
U
d g
g p p
t
=
3
4
(3)
where C
d
is the drag coefficient.
In the context of its use in power generation, the circulating fluidized bed may be defined as a high
velocity gas-solid suspension where particles are elutriated by the fluidizing gas. The particles are
recovered and returned to the base of the furnace at a rate high enough to cause a degree of solid
refluxing that will insure a uniform temperature level in the furnace.
The CFB mode of fluidization is characterized by a high slip velocity between the gas and solids
and by intensive solids mixing. High slip velocity between the gas and solids, encourages high
mass transfer rates, that enhance the rates of the oxidation (combustion) and desulfurization
reactions, critical to the application of CFBs to power generation. The intensive mixing of solids
insures adequate mixing of fuel and combustion products with combustion air and flue gas
emissions reduction reagents. [1]
Basic principles of CFB boilers
A Circulating Fluidized Bed (CFB) operates under a special fluid dynamic condition, in which the
fine solids particles are transported and mixed through the furnace at a gas velocity exceeding the
average terminal velocity of the particles. The major fraction of solids leaving the furnace is
captured by a solids separator and recirculated back to the lower part of the furnace. The high
recycle rate intensifies solids mixing and evens out combustion temperatures in the furnace.
Figure 2 and Figure 3 shows a schematic diagram of a CFB boiler. The boiler can be divided into
two sections. The first section consists of the furnace, solid separator, recycle device, and possible
external heat exchanger surfaces. The second section of the boiler is called back-pass where the heat
of the high temperature flue gas is absorbed by the reheater, superheater, economizer, and air-
preheater, which are installed one after one in downstream order.
Coal and limestone (sorbent for SO
2
capture) is injected from the lower part of the furnace into the
sand bed. The injected coal and limestone is fluidized by primary air (less than stoichiometrical
amount) entering the furnace through an air distributor or grate in the furnace floor. Coal is heated
by hot segregated particles in the bed above its ignition temperature so that it can be burnt. The
sulfur in the coal reacts with limestone, thus lowering the possibility of SO
2
formation and
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boilers
emissions from the furnace. Secondary air is injected at some height above the grate to complete the
combustion.
Bed solids are well mixed throughout the height of the furnace to ensure the uniform bed
temperature in the range of 800-900C. Some particles segregate and return to the bed before
leaving the furnace, while some particles are captured in a gas-solid separator (e.g. cyclone) and are
recycled back to the furnace (Figure 4). The separator is designed for a very high solid collection
efficiency with nearly 100% efficiency for particles greater than 60 microns in diameter.
MLARENERGI AB
VSTERS, SWEDEN
Furnace
Cyclone
Backpass
Recycling of
solids
Furnace and
cyclone
INTREX
Superheater
Superheaters
and reheaters
Economizer
Air
preheater
Primary air
supply
Secondary
air supply
Figure 2: Shematics of a CFB boiler (157 MWth, 55.5/48 kg/s, 170/37 bar, 540/540 C). [1]
Finer dust that escapes from the separator is collected by bag-house filters or electrostatic
precipitators (Figure 3), which are installed downstream after the boiler.
The collected solids are returned to the combustion chamber via the loop seal, which provides a
pressure seal between the positive pressure in the lower furnace and the negative draft in the solids
separator. This prevents the furnace flue gas from short circuiting up the separator dipleg and
collapsing the separator collection efficiency. The recirculation system has no moving parts and its
operation has proven to be simple and reliable. By injecting small amounts of high pressure
fluidizing air into the loop seal, the solids movement back to the lower furnace is maintained.
Typically gravity / mechanical feeding of fuel directly into the combustor have proven satisfactory
for meeting the desired level of efficient mixing.
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boilers
Electrostatic
precipitator
Furnace
(water walls)
Superheaters
and reheaters External heat
transfer surfaces
Air
preheater
Economizer
Figure 3: CFB boiler in Rovaniemi, Finland (95.8 MWth, 38 kg/s, 115 bar, 535C). [1]
Characteristics of CFB systems
CFB systems operate in a fluid dynamic region
between that of a Bubbling Fluidized Bed (BFB)
and a transport reactor (pulverized combustion).
This fluidization regime is characterized by high
turbulence, solid mixing and the absence of a
defined bed level. Instead of a well defined
solids bed depth, the solids are distributed
throughout the furnace with a steadily
decreasing density from the bottom to the top of
the furnace.
CFB is characterized by:
High fluidizing velocity of 4.0-6.0 m/s.
Dense bed region in lower furnace
without a distinct bed level
Water-cooled membrane walls
(evaporator).
Optional in-furnace heat transfer surfaces
located above the dense lower bed
Figure 4: Cutaway of a CFB furnace and
cyclone. [3]
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boilers
Solids separator to separate entrained particles from the flue gas stream and recycle them to
the lower furnace.
Aerated sealing device, loop seal, which permits return of collected solids back to the
furnace
The advantages of CFB boilers
Compared with PC boilers, CFB boilers have a number of unique features that make them more
attractive in energy production. Table 1 compares different types of boilers with CFB boilers.
Extensive fuel flexibility: In the furnace bed, fuel particles constitute less than 1-3% by weight of all
bed solids. The rest are non-combustibles, such as sorbents, flue ash and sand. This feature makes
CFB boilers flexible enough to use a wide range of fuels, coal (with ash content up to 40-60%),
peat, bark, wood waste, and straw.
High combustion efficiency: Normally the combustion efficiency of CFB boilers is 97.5-99.5%. The
good result is due to the following factors:
Good gas-solid mixing.
High burning rate.
Long combustion zone (40m).
The majority of unburned fuel particles are recycled back to the furnace and combusted.
Efficient sulfur removal: The long combustion zone in the furnace gives a long reaction time for the
sorbents to react with SO
2
. The average residence time of gas in the combustion zone is 3-4
seconds. The furnace temperature of CFB boilers is also ideal for the capture of sulfur (850C
optimal). SO
2
reacts with CaO in calcined sorbents and forms calcium sulfate. SO
2
removal during
combustion is much cheaper and simpler than flue gas desulfurization.
Table 1: Comparison of boiler types.
Items Stoker boilers BFB boilers CFB boilers PC boilers
Height of bed of fuel burning
zone (m)
0,2 1-2 15-40 27-45
Superficial velocity m/s 1,2 1,5-2,5 4-8 4-6
Excess air % 20-30 20-25 10-20 15-30
Grate heat release rate MW/m
2
0,5-1,5 0,5-1,5 3-5 4-6
Coal size mm 32-6 6-0 6-0 <0,001
Turndown ratio 4:1 3:1 3-4:1 2:1
1)
Combustion efficiency % 85-90 90-96 95-99 99
NOx emission ppm 400-600 300-400 50-200 400-600
SO2 capture in furnace % None 80-90 80-90 small
1)
Turndown ratio can be bigger using supporting oil firing.
Low NOx emission: Low emission of NOx is a major attractive feature of CFB boilers. Combustion
air in stages (primary and secondary air) and low combustion temperature in the limits the
formation of NOx. This is a major advantage of CFB boilers compared to PC boilers.
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boilers
Compact structure: Due to the high combustion efficiency and high heat release rate at 3.5-
4.5MW/m
2
, the cross section area of furnace is quite small compared to the furnaces of bubble
fluidized bed boilers, and is close to the area of PC boiler furnaces. Therefore, fewer coal-feeding
points are needed. Normally a 100MWth CFB needs only one feeding point, while BFB boiler
needs 20 to 30 points for the same capacity. This makes retrofitting of existing PC boilers or oil
fired boilers into CFB boilers for suitable.
Good turndown and load following capacity: One good feature of the CFB boiler is its quick
response to varying loads: approximately 4% of its capacity per minute. The output turndown ratio
can be 3-4:1. Thus CHP plants with CFB boilers can be used as base load plants or peak load plants.
Typical operating parameters for CFB boilers is shown in Table 2.
Table 2:Typical operating parameters for CFB boilers. [4]
Volume heat load 0.10.3 MW/m
3
Cross section heat load 0.75 MW/m
2
Total pressure drop 1015 kPa
Bed material particle size 0.10.5 mm
Fly ash particle size < 100 m
Bottom ash particle size 0.5-10 mm
Fluidizing velocity 310 m/s
Temperature of primary air 20400 C
Temperature of secondary air 20400 C
Bed temperature 850950 C
Temperature after the cyclone 850950 C
Excess air ratio 1.11.3
Density of bed 10100 kg/m
3
Recirculation ratio 10100
Combustion in CFB boilers
The research of combustion in CFB boilers mainly focus at receiving good combustion efficiency
since it impacts operation cost. In addition to time, temperature, and turbulence, which impacts
combustion efficiency, the excellent internal and external re-circulation of hot solids at combustion
temperature provides a longer residence time and good heat transfer to heating surfaces. Besides,
high efficiency of combustion can also ensure efficient SO
2
capture during the combustion.
In typical full load operation, about 40-50% of the heat generated by combustion is absorbed by the
water-cooled membrane walls of the combustion chamber. Also, the high circulating solids and
back-mixing intensity provide the high heat transfer rate typical of circulating fluidized beds.
Typically, a CFB furnace operates at a temperature level of 800-900C. The reasons are:
Low combustion temperature prevents sand and ashes from fusing
The temperature ensures the optimum sulfur capture reaction during combustion
Alkali metals in coal cant be vaporized at this a low temperature. Therefore, the risk of
fouling caused by condensing of vaporized alkali metals on heating surfaces is reduced.
The formation of thermal NOx is reduced at lower temperatures
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boilers
The amount of primary air needed for initial fluidization of the bed material has to be maintained
under all conditions. The proportion of the total air that is introduced as primary air varies from 40
to 70 % depending on the fuel. The remaining portion of the combustion air is typically divided
between upper and lower secondary air levels. The distribution of air between primary and
secondary air location is important to avoid excessively high temperatures in the lower combustion
chamber and to insure good combustion efficiency as well as low NOx production.
Fuel flexibility
Fuel flexibility is one of the major attractions of the CFB technology. Fresh fuel and combustible
matter make up less than 1 - 3% by weight of the hot solids present in the furnace. The remaining
hot solids are noncombustibles: sorbents, sand and other inerts such as fuel ash. This large source
of thermal energy, provides an extremely stable combustion environment that is insensitive to
variations in fuel quality.
The special fluid dynamic condition of the CFB provides excellent gas-solid and solid-solid mixing.
Thus fuel particles fed to the furnace are quickly dispersed into the large mass of bed solids, that
rapidly heat the fuel particles above their ignition temperature without any significant drop in the
temperature of the bed solids. This feature of a CFB furnace allows it to burn any fuel without
auxiliary fuel support, provided its heating value is enough to raise the combustion air and the fuel
itself above its ignition temperature. Thus, a wide range of fuels can be burned in one specific
boiler without any major change in the hardware. CFB boilers have been designed to burn a wide
variety of fuels and fuel qualities, including plant wastes, de-inking sludge, sewage waste, tire
derived fuel, low ash fusion coals, petroleum coke and others in combination or alone.
To maintain the combustor temperature within an optimum range, it is necessary to absorb a certain
portion of the generated heat in the combustion zone. The amount of heat that must be absorbed
varies from one fuel to another. Some CFBs accomplish this variation in furnace absorption for
different types of fuels by means of an external heat exchanger. In boilers without the external heat
exchanger the fluid dynamic condition of the furnace must be adjusted to alter the heat absorbed by
the furnace. Typical means of altering the furnace heat absorption are: changing air split and/or
excess air, flue gas recycle, and changing bed inventory.
Combustion zones in a CFB boiler
The furnace can be divided into three distinct zones, from the combustion point of view, i.e. lower
zone (below secondary air injection ports), upper zone (above secondary air injection ports), and hot
gas-solid separator. These zones are shown in Figure 5.
At the lower zone, the bed is fluidized by primary combustion air, which is about 40-80% of the
stoichiometric quantity of the air required for the coal feed. Also char particles, re-circulated by the
separator, are feed to this zone. To prevent the boiler tubes from possible corrosion and erosion, the
walls in this zone are lined by refractory material. This zone is denser than the other zones, and also
serves as an insulated storage of hot solids. The preserved solids can be used for controlling the
boiler load. When the load increase, the primary air quantity increases and more solids are
transported to the upper zone to enhance the heat transfer in the furnace. Fuel fed into the lower
combustion chamber mixes quickly and uniformly with bed materials. There is no visible bed level
in the CFB combustor. Instead the bed density decreases progressively with height.
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boilers
The secondary air is injected at the interface
between the lower and upper zone of the
furnace, thus the upper zone is the oxygen
rich zone, where most of the combustion
occurs. Char particles are transported
upwards through the core of the furnace and
slide down the wall, mainly entrapped by
falling clusters. Thus char particles take
several turns through the furnace before they
are entirely combusted.
Unburned char particles are captured by the
gas-solid separator and transported back to
the bed for continued combustion. Fine
particles that have entrained into larger ones
are captured, but others escape from the
cyclone.
Normally the residence time of particles is
longer than the time needed for complete
burn-out. This ensures complete combustion.
Heat transfer in a CFB boiler
A boiler is a facility to convert energy,
therefore energy conversion efficiency is
bound to be the first consideration to design
and operate it. Heat transfer has to be
Upper
zone
Lower
zone
Gas/solid
separator
Figure 5: CFB furnace sections.
understood by designers.
Figure 2 and Figure 3 illustrate the heat transfer (HT) sections of a CFB boiler.
The following heat transfer processes are involved in CFB boilers.
Gas to particle
Bed to water walls
Bed to the surfaces immersed in the furnace
Bubbling bed to immersed surfaces in the external heat exchanger
Circulating particles to particle separator/cyclone
Gas to water and steam in the back pass
The most important and interesting processes are bed to water walls and the heat transfer in external
heat exchanger.
Heat transfer from gas to particles takes place in the bed. Above the bed, the heat transfer rate is
decreased due to the decreasing temperature difference between gases and particles. The main heat
transfer mechanism is convective HT.
Bed to wall heat transfer
Fine particles move upwards through the core of the bed, and then most of them flow downwards
along the wall of the bed in the form of clusters, others move down or up in dispersed phase.
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boilers
Clusters transfer heat to the walls through conduction and radiation, dispersed particles transfer
through convection and radiation. Particle suspension density is a major factor to influence heat
transfer.
Heat transfer coefficient increases proportionally to the square root of the density. Thus HT rate at
lower part of the bed is higher than the upper part. Heat transfer coefficient isnt affected by bed
fluidization velocity considerably, but it decreases along the height of the bed due to the
temperature difference between cluster and wall and reaches an asymptotic value after a certain
height. The coefficient increases with bed temperature, which will be attributed to the higher
radiation and thermal conductivity when high temperature. In the case of short heat transferring
surfaces finer particles result in high coefficients but the influence is less significant for longer
surfaces.
A complete analysis of bed to wall heat transfer is quite complex. Through the solving equations of
mass, momentum and energy balance on both gas and particles near the wall can help get a detailed
comprehension, but it is complex. A simplified method found by Basu (1988) based on the cluster
renewal model can explain the mechanism quite well. Since the wall is either covered by clusters or
bared to gas, the time-averaged overall heat transfer coefficient can be written as the sum of
convective and radiative HT coefficient:
( ) ( )(
dr d c cr c c r conv
h h h h h h h ) + + + = + = 1 (4)
The key to solve the problem is to find the time averaged fraction of the wall area covered by the
clusters c, and the convective and radiative heat transfer coefficients to the clusters and dispersed
phase. At the lower zone of the furnace, two heat transfer processes are dominant, but at the upper
part, where a majority of heat transfer surfaces are located, radiation is dominant.
Bubbling bed to external heat surfaces
The external heat exchanger helps the CFB boiler to meet a variable load and enhances fuel
flexibility. Tubes are immersed in the bed to supplement the heat transfer within the furnace itself.
Obtaining the heat transfer coefficient of bed to tubes is the key issue in HT design. It depends on a
number of factors, such as particle size, bed temperature and fluidizing velocity.
Heat transfer and part-load operation
As described above, the particle suspension density impacts heat transfer dramatically. Thus the
load control of CFB boiler can be realized by changing the density.
( )(
s b r b
T T h C A Q + =
5 . 0
* ) (5)
No matter how high the load is, the bed density at the lower section of the boiler is always very
high. But as the load decrease, the density at upper section is decreased and the bed is dilute. At
70% of full load, particle concentration at upper section of the furnace where most of heat transfer
surfaces are located is weak. Therefore, convection heat transfer becomes weak, while radiation
process becomes dominant. If the load is reduced to 40%, the bed operates like a bubbling fluidized
bed boiler, and radiation can be regarded as the only process of heat transfer.
In the back-pass section, heat transfer from gas to heat exchanger occurs mainly by convection and
partly by gas radiation at temperatures above 600C.
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boilers
Load control in CFB boiler
The load control means a control of the heat absorption by water or steam from the furnace and
other heating surfaces of the boiler. Several ways can be used for the control purpose.
Through control of the solids flow through the external heat exchanger surfaces
By dividing the bubbling bed into two sections, one with heat exchanger surfaces, and one
without.
Control bed density by adjusting solid recirculation from the bubbling bed to the furnace
By adjusting gas velocity through the lower section of the bed to change the solid density at the
upper section of the bed
Emissions
SO
2
Emissions
Circulating fluidized bed combustors in general have the advantage of removing SO
2
from the flue
gas in the combustion chamber during the fuel combustion. The sulfur is captured by sorbent
particles that make up the entrained bed material. The sorbent is either limestone or dolomite and
has the ability, after being calcined in the combustor, to capture sulfur effectively. The reactions are
as follows:
for limestone
2 3
CO CaO CaCO +
(6)
Sulfur dioxide reacts with calcium oxide to calcium sulfate according to the reaction
4 2 2
1/2 CaSO O SO CaO + +
(7)
and for dolomite
MgO CaSO O SO MgO CaO + + + +
4 2 2
2 / 1
(8)
The reaction products leave the combustor along with fuel ash.
The limestone requirement needed for achieving a desired sulfur capture is a measure of the sulfur
reduction efficiency. This requirement is normally specified as Ca/S-mole ratio, which is the ratio
between the molar flow of calcium in the limestone feed and the molar flow of sulfur in the fuel.
The limestone calcining conditions effects the sulfur absorption reaction. The calcining conditions
in fluidized bed combustion are good and no inertization of limestone occurs.
Sulfur capture characteristics of different limestones vary by wide margins. Generally, younger and
more amorphous limestone has a better reactivity, i.e., ability to absorb SO
2
.
When limestone is crushed for CFB combustion, the surface area of the particles increase. This
improves the limestones ability to capture sulfur and reduces sensitivity to the reaction
temperature. On the other hand it should be remembered that retention time in the combustor is
also affected by the particle size of a sorbent. Friability of the sorbent and the collection efficiency
of the solids separator must also be considered in the efficient utilization of sorbent.
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boilers
Limestone consumption is also affected by the fuel quality. This is a result of the capability of fuel
ash to absorb part of the sulfur. Thus, the Ca/S - ratios defined for different fuels cannot necessarily
be compared with each other. The fuel volatility also affects the distribution of sulfur in the
combustion chamber and thus affects the local concentrations of sorbent and SO
2
.
A high sulfur capture ratio is easy to achieve when the sulfur content of the fuel is high. If the sulfur
content in the fuel is low, the remaining SO
2
content is low. This requires a greater surplus of
unreacted limestone to achieve the same sulfur reduction percentage.
From the point of view of the sulfur reduction, in the circulating fluidized bed combustion the
optimal reaction temperature is 840 880C. This temperature range is also sufficient for good
combustion efficiency.
Distribution of combustion air between the primary (grid fluidizing) air and secondary air has an
effect on the intensity of turbulence in the gas-particle suspension, and therefore on the
effectiveness of the gas-solids contact. In CFB combustion the intensive fluidization (i.e. higher
ratio of primary air) leads to a high concentration of solids also in the upper part of the combustor
and also minimizes reducing atmosphere, giving an advantage in sulfur capture. The NOx
emission, however, tends to increase due to the highly oxidizing atmosphere in the lower bed.
With a suitable staging of the combustion air it is possible to reduce the NOx emissions without a
significant reduction in sulfur capture. By increasing the bed inventory it is possible to increase
solids concentration in the gas-solids suspension. Recycling of fly ash increases the solids
concentration as well as the retention time of lime particles in the CFB system.
The reaction of SO
2
with calcium oxide to calcium sulfate requires oxygen as shown in Equation 4
above. In practice, noticeable reduction in sulfur capture has not been observed until the O2 content
in the flue gas has dropped below 2.5%, or when the staging of the combustion air has been very
strong.
NOx - emissions
One of the primary incentives for burning coal in the CFB is its low NOx emission level.
Compared to a pulverized coal combustor, the fluidized bed is operated at a much lower combustion
temperature (850 900 C) and subsequently, NOx compounds are formed primarily from fuel
nitrogen with negligible amounts of thermal NOx (less than 5%). Figure 6 gives the temperature
effect on the various NOx formation reactions.
The formation mechanism of nitrogen oxides in combustion is very complicated. During initial fuel
pyrolysis, NH
3
and HCN are the major precursors of NOx emissions. Char from the fuel tends to
reduce the nitrogen oxides forming from the volatiles, but also generates them when it combusts
itself. The nitrogen oxides are mostly nitrogen monoxide, NO, and nitrous oxide, N
2
O. Only a
minor part of NO is oxidized to NO
2
. Of these oxides, typically only NO and NO
2
are under
regulation. NO forms into NO
2
in the back-pass section and atmosphere.
Generally speaking, the best strategy for limiting NOx generation from fuel nitrogen in a CFB
combustor is the application of staged combustion. Then the sub-stoichiometric firing at the lower
furnace location limits the NOx formation while the injection of the secondary air at higher furnace
locations insures combustion efficiency with high carbon burnout and CO and hydrocarbon
conversion.
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boilers
0
300
600
900
1200
1500
1800
2100
1000 1200 1400 1600 1800 2000 2200
Temperature oC
N
O
a
n
d
N
O
2
m
g
/
m
3
Prompt
Fuel
Thermal
Figure 6: Temperature effect on NOx formation in various reactions.
Staged combustion is an integral part of the design of a CFB combustor. One, two or three levels of
air ports (dependant on design fuel(s)) are located above the primary air distributor plate. Multiple
levels of air staging allow for more flexibility in staging air ratios to obtain optimal NOx reduction
for various types of fuels, while still ensuring high combustion and sulfur capture efficiencies. The
high CO concentration produced in the first stage, i.e., in the lower bed section coupled with high
amounts of entrained chars are major contributors to the low NOx emissions from a CFB fluidized
bed boiler.
The use of flue gas recirculation in the CFB has been shown to help in the reduction of NOx,
especially in boilers designed for a wide variety of fuels. Flue gas recirculation helps to maintain
the gas flow throughout the combustion chamber and boiler convection section when switching
from a low grade fuel, (wood wastes and lignite) to a higher heating value / lower moisture fuel
(bituminous coal and petroleum coke). This practice allows both combustion and steam
temperature to be effectively controlled under a wide variety of operating conditions.
Under typical operating conditions in the CFB, fuels of various ranks have been found to emit low
levels of NOx, ranging from 70 - 180 ppm. By appropriate application of the methods described
above, it is possible, in most cases, to maintain NOx emissions below 120 ppm.
By injecting ammonia or urea into the solids separator, higher NOx reduction can be achieved. This
method, patented by Foster Wheeler, is in continuous use in several Foster Wheeler CFBs
worldwide. In these boilers, the NOx emission is controlled by the ammonia injection to 40 - 65
ppm. Ammonia/urea selectively reduces NO to molecular nitrogen. The optimum temperature
range for the NOx reduction reactions is 800 950C that matches the typical combustion
temperature of the CFB.
Combustion at 800-900C creates small amounts of N
2
O, which is a greenhouse gas. The formation
of N
2
O increases with increasing combustion pressure.
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boilers
Particulate matter (PM) emission
Current particulate matter emission control technology is readily capable of maintaining extremely
low stack PM emissions, virtually eliminating fugitive dust emissions created by materials
handling. Depending on the specific application, a reverse-air baghouse filter, a pulse-jet baghouse
filter or an electrostatic precipitator (ESP) is used. PM emissions from the entire plant are
minimized by the application of fugitive dust control to all material handling equipment. The
exhaust from these control systems, after passing through local bag-houses, can be used as
combustion air.
Carbon monoxide and hydrocarbons
Both carbon monoxide and hydrocarbon emissions are controlled by efficient gas-solids mixing,
sufficient combustion temperature and excess air. Unfortunately both of these factors contribute to
an increase in NOx formation. Thus, the emission level of both must be balanced against the NOx
emission.
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boilers
References
1. CFB Engineering Manual, extract supplied by Foster Wheeler. http://www.fwc.com/
2. Pictures and schematics supplied by Foster Wheeler. http://www.fwc.com/
3. Pictures supplied by Kvaerner Power Division. http://www.kvaerner.com/powergeneration/
4. Huhtinen and Hotta. Combustion of fossil fuels. 2000
169
Circulating Fluidized Bed Boiler Design
Dianjun Zhang, Sebastian Teir
STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boiler Design
Table of contents
Table of contents.............................................................................................................................. 172
Introduction...................................................................................................................................... 173
Combustion calculation.................................................................................................................... 173
Chemical reactions....................................................................................................................... 174
Air required.............................................................................................................................. 174
Sorbent requirement................................................................................................................. 174
Solid waste produced ............................................................................................................... 174
Gaseous waste products ........................................................................................................... 175
Heat and mass balances.................................................................................................................... 175
Heat balance................................................................................................................................. 175
Mass balance................................................................................................................................ 177
Control of particle size in bed...................................................................................................... 177
Furnace Design ................................................................................................................................ 178
Grate heat release rate (GHRR) ................................................................................................... 178
Cross section of the furnace......................................................................................................... 179
Shape of the furnace..................................................................................................................... 179
Air nozzles ................................................................................................................................... 180
Fuel feed ports.............................................................................................................................. 180
Limestone feed ports.................................................................................................................... 180
Secondary air injection port ......................................................................................................... 180
Recycled solid entry..................................................................................................................... 180
Bed solid drain ............................................................................................................................. 181
Height of the primary zone .......................................................................................................... 181
Effect of Fuel ............................................................................................................................... 181
Boiler performance modeling ...................................................................................................... 181
Design of heating surfaces ............................................................................................................... 181
Arrangement of heat exchanger surfaces..................................................................................... 182
Heat distribution........................................................................................................................... 184
Gas-solid separators ......................................................................................................................... 184
Cyclones....................................................................................................................................... 184
U-Beams particle separators ........................................................................................................ 185
Recycling of solids....................................................................................................................... 186
Bottom Ash Removal System...................................................................................................... 187
References........................................................................................................................................ 188
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boiler Design
Introduction
Figure 1 illustrates the structure of CFB boiler. This chapter focuses on the design issues of CFB
boilers. The design of CFB boilers involves the following major steps.
Combustion calculation
Heat and mass balance calculation
Furnace design
Heat absorption by medium (water and steam)
Mechanical component design
Design for combustion and emission performance
Combustion calculation
Based on the boiler design capacity and fuel proximity analysis, stoichiometric calculation is carried
out. It is the basis of boiler design. The amount of fuel, combustion air, sorbent injection, flue gas
flow, etc. for the capacity is determined. Based on these calculations, the equipment can be
dimensioned, such as coal and sorbent feeder, forced combustion air fan, induced flue gas fan, and
ash handling system.
Figure 1: Structure of a CFB boiler in Germany with flue gas treatment facilities (94 MWth, 33.4
kg/s, 89 bar, 480C). [2]
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boiler Design
Chemical reactions
In CFB boilers, the following chemical reactions take place.
S of kg kJ CaSO O SO CaO
MgCO of kg kJ CO MgO MgCO
CaCO of kg kJ CO CaO CaCO
sulphur of kg kJ SO O S
heat O H
m
nCO O
m
n H C
carbon of kg kJ CO O C
m n
. . / 15141
2
1
. . / 1183
. . / 1830
. . / 9260
2 4
. . / 32790
4 2 2
3 2 3
3 2 3
2 2
2 2 2
2 2
+ = + +
+ =
+ =
+ = +
+ + =
+ +
+ = +
(1)
In addition to the calculated stoichiometric combustion air, an excess air of around 20% is
demanded for complete combustion and desulfurization.
Air required
The dry air required for complete combustion of a unit weight of coal (M
da
) is determined by the
formula below.
coal of kg kg S A S
O
H C M
da
. . / . 34 . 4
8
34 . 34 53 . 11
+ +
+ = (2)
The moisture content in the air must be considered when calculating the amount of air required.
(
m da wa
X M EAC M + = 1 * ) (3)
where
EAC = excess air coefficient, equals 1.2
X
m
= the weight of moisture in the air, 0.013kg/kg of air
Sorbent requirement
If the amount of CaO in ashes can be neglected, the sorbent required for sulfur retention in one unit
weight of coal (L
q
) can be calculated as
R
X
S
L
CaCO
q
3
32
100
= (4)
where
X
CaCO3
= the weight fraction of CaCO
3
in the sorbent
R = the calcium to sulfur molar ratio in the feed of sorbent and coal
Solid waste produced
Waste solids (W
a
) in a CFB boiler include ashes of coal, sulfur retention reaction products, and
unreacted CaO and MgO.
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boiler Design
( )
CaO c inert q
MgCO q
sor
CaCO q
sor a
X E ASH X L
X L
SE
X L
E
S
W + + + +
+ = 1
84
40
32 100
56
32
136
3 3
(5)
where
E
sor
= the fraction of sulfur captured in the bed
X
inert
= weight fraction of inert in limestone
E
c
= fraction efficiency of combustion
ASH = weight fraction of ash in coal
Gaseous waste products
The weight of carbon dioxide (W
CO2
) produced from fixed carbon in coal is 3.66 times the weight
of the coal. In addition, reaction of sulfur retention produces also CO
2
. Thus the total mass of CO
2
produced will be
+ + =
3
3
19 . 1 1 375 . 1 66 . 3
2
CaCO
MgCO
CO
X
X
SR C W (6)
Heat and mass balances
Heat balance
Moisture loss is the heat loss to vaporize moisture in the sorbent, and can be calculated by
Sexit ml q ml
H X l Q = (7)
Calcination loss takes place during the calcinations reaction of calcium carbonate and magnesium
carbonate.
Calcination loss from CaCO3=
HHV rate feed Fuel
CaCO of rate feed
* . .
100 * 1830 * . . .
3
% (8)
Calcination loss from MgCO3=
HHV rate feed Fuel
MgCO of rate feed
* . .
100 * 1183 * . . .
3
% (9)
Sulfate credit is the heat gain when sulfur dioxide reacts with calcined limestone due to the
exothermic reaction. The value of the heat gain can be calculated by
Percentage heat gain
HHV
S E
HHV fed fuel of kg
converted sulfur of kg
sor
100 * 15141 *
* . . .
100 * 15141 * . . .
= = % (10)
Unburned carbon loss in ash is normally in the range of 0.5-2%. Higher furnace and efficient
cyclone can ensure lower loss of combustibles. If X
c
denotes the fraction carbon in solid waste, the
loss can be calculated as
Unburned carbon loss in ash =
HHV
W X
a c
100 * 33488 *
% (11)
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boiler Design
Dry flue gas loss is due to the sensible heat carried away by the dry flue gas at the boiler exit
temperature, and can be calculated as
Dry flue gas loss = 100 *
HHV
H H
i e
% (12)
H
e
is the sensible heat of dry flue gases at the boiler exit temperature, and H
i
is the sensible heat in
fuel and air at ambient temperature. The lower the flue gas temperature is, the more efficient is the
boiler. But low flue gas temperature causes condensation of H
2
O and SO
2
in the air preheater.
Commercial CFB boilers are designed an exit temperature of around 130C after the air preheater.
Figure 2 shows the minimum average cold-end temperature of coal burning.
Moisture loss of fuel is caused by heating water content of fuel into steam and can be calculated by
multiplying moisture content of fuel with flue gas enthalpy H
f
.
Moisture loss of fuel = 100 *
HHV
H M
f f
% (13)
Moisture loss of air is due to the heating of moisture in air from ambient temperature to the flue gas
exit temperature. It can be calculated as
Moisture loss of air = 100 *
HHV
H X
e m
% (14)
where
X
m
= moisture content of the combustion air
H
e
= the enthalpy of steam at the exit flue gas temperature
150
155
160
165
170
175
180
185
190
195
0 1 1.5 2 2.5 3 3.5 4 4.5 5
Sulfur content of coal %
T
e
m
p
e
r
a
t
u
r
e
o
C
Figure 2: Minimum average cold-end temperature of coal burning.
Loss due to hydrogen burning = 100 *
* 9
HHV
H H
f
% (15)
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boiler Design
Radiation and convection heat loss: Due to the large external surface of the furnace, external heat
exchanger and cyclone, the heat loss through radiation and convection is considerable, 0.2-0.5% of
the total heat released from the furnace.
Sensible heat in ash: The ash from the furnace or bed is collected partly as fly ash from the
baghouse filter or ESP and partly as bed drain. The bed drain (20-80% of the total ash) at furnace
temperature is cooled at an ash cooler, by heating air, so that the ash can be transported by trucks.
But the ash temperature is still 300C. Still, the fly ash is collected at 140C, which makes a
considerable heat loss.
FD fan credit means that part of the power to forced draft fans is converted into heat through
fractional losses as heat gain of air.
Unaccounted loss is about 1.5%.
Mass balance
The mass balance of a CFB boiler can be listed as follows:
Solid input into furnace
Fuel
Sorbent
Supplemental bed material
Solid output from the furnace
Drain from external heat exchanger
Drain from back pass
Drain from bed
Drain from baghouse or ESP
Solids leaving from stack
Others
Solids reinjection into the furnace is needed due to the fact that the escape of fly ash from cyclone
exceeds the feed of ash and sorbent to the furnace. This condition will lead to the depletion of
furnace inventory of bed particles. In order to keep the inventory stable, part of the fly ashes
collected at the baghouse filter or ESP has to be reinjected in to the furnace continuously. The
reinjection of fly ash into the furnace can improve combustion efficiency and sulfur capture.
For combustion of coal with very low ash or sulfur content, an inert material, such as sand, is added
into the bed to maintain the inventory.
Normally, 30-100% of solid waste passes through the baghouse filter or ESP, and the bed drain is
only as low as 3-5% of the total solid waste. For conservative design, the collection equipment for
fine dust is selected for the disposal of 100% of solid waste, and the bed drain may be designed for
50% of the total solid waste.
Control of particle size in bed
Maintaining enough bed solids in the furnace of a CFB boiler serves the following purposes:
Supports sulfur capture reaction
Helps producing a good axial and lateral heat transfer and maintaining uniform temperature
in the furnace
Supports heat transfer and controls heat transfer rate to the furnace wall
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boiler Design
Transports heat to the external heat exchanger, and to some extent to the back-pass
The realization of these functions depends on the solid size that must be kept within the limits.
Coarser particles tend to congregate near the bottom of the furnace, while finer particles are
entrained out of the cyclone as fly ash. Finer bed solids result in higher bed density in the upper
regions of the furnace than from by coarser solids. The benefit is that a higher heat transfer
coefficient is gained in the most parts of the furnace. The control of the inventory of fine bed solids
is guided by the loss through entraining, bottom ash, and decrepitation of finer sizes, and the gain is
due to fresh ash feed and decrepitation of coarser sizes.
Furnace Design
The success of any CFB boiler design and operation depends on the furnace design. The most
important aspects of the furnace design are furnace temperature, solid inventory and distribution,
limestone and fuel particle size, gas residence time, furnace depth and furnace heating surfaces.
The furnace is designed on the basis of the heat and mass balances. The furnace temperature
impacts the SO
2
capture, NOx emissions, combustion efficiency, and the heat transfer to the furnace
walls. The furnace temperature is set regarding fuel properties and emission control consideration,
normally 800-900C.
The dimensions of the furnace are set by the velocity and residence time of gas-solids. The
dimension design of the furnace of a CFB boiler involves three main aspects:
Furnace cross section
Furnace height
Furnace openings
The shape and size of furnace cross section comes from combustion considerations. Furnace height
is determined from heat transfer and solid residence time. Furnace openings are determined from
the feeding of air, fuel and sorbent, and affect the mechanical design of the boiler.
Ash and moisture content of coal, and its other properties such as reactivity, mechanical attrition,
ash properties, sulfur content, heating value, have important effects on the overall design and
performance of a CFB boiler. Table 1 illustrates the effect of coal properties on the design and
performance of a CFB boiler.
Grate heat release rate (GHRR)
One important criterion for the design of CFB boilers is a high grate heat release rate per unit cross
section of the furnace. This function of the mass flow rate of combustion air passing through the
furnace was derived by Waters in 1975.
[ ] EAC
U
GHRR
0
3 . 3
= MW/m
2
(16)
where U
0
is the superficial gas velocity through the furnace and EAC the excess air coefficient. For
large capacity CFB boilers, the depth of furnace is so large that it is not easy to have a good mixing
of coal volatiles.
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boiler Design
Table 1: Effect of coal properties on CFB design.
Coal property Design parameter Performance
Friability Cyclone grade-efficiency Boiler efficiency, carbon carryover
Reactivity Air flow distribution Boiler efficiency, carbon carryover ,CO
emission
Inherent vs.
extraneous ash
Ash removal, ash split, heat absorption
surface design
Ash carryover, bed drain, dust collector
loading
Ash chemistry Ash removal, back-pass flow area,
heating surface design
Bed agglomeration, tube fouling
Moisture Heat absorption, dimensional
requirements, capacity of cyclone and
downstream equipment
Thermal efficiency, excess air
Heating value Dimensional requirements Capacity, thermal efficiency
Sulfur content Sorbent handling equipment Emission, bed drain requirement
Cross section of the furnace
The furnace cross section is mainly determined by the average velocity of the cross section for a
given heat output of the boiler. High velocity can bring a high grate heat release rate, but can cause
erosion of the furnace and requires a high fan power. The grate heat release rate now is taken
generally of the order 3-4MW/m
2
of upper section of the bed. The fluidization velocity for
avoidance of furnace erosion shouldnt exceed 5m/s.
Shape of the furnace
Normally CFB boiler furnace has a rectangular cross section. The combustion chamber is designed
to contain a slight negative pressure and consists of a membrane wall gas-tight enclosure. When the
cross section of furnace is determined, the width and breadth of the section have to be decided
according to the consideration below.
Heating surface necessary in the furnace
Secondary air penetration into the furnace
Solids feeding/lateral dispersion
The breadth of the furnace should not be too large, so that it results in a poor penetration of the
secondary air into the furnace and non-uniform dispersal of volatile matter. A suitable breadth of
the furnace should be selected on the basis of simulation. Normally it is less than 8 meters.
The lower combustion chamber section has an air distribution grid for introducing the primary air
and a bottom ash removal system. The lower combustion chamber also has openings for the
recirculated solids, secondary air nozzles, fuel, limestone, make-up sand and recycled fly ash feed,
startup burners and bed lances as required. There are no heat transfer tubes inside the high-density
lower combustor. In this region, a rapid change of solids flow pattern occurs, thus heat transfer wall
tubing is protected by a thin layer of abrasion-resistant refractory. It is designed tapered upwards to
maintain similar superficial velocities above and below the secondary air level under all operating
179
STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boiler Design
load, and to minimize the risk of agglomeration under a low load and formation of clinker near the
grid.
Air nozzles
To distribute the air in the fluidized bed special nozzles are needed. The nozzles introduce primary
air, which is used for the combustion and fluidization of the bed particles. The nozzles must also
keep the bed material from entering the air system. Primary air is delivered through a cooled
membrane wall bottom (Figure 3). Replaceable nozzles are used because the erosion on the lower
part of the furnace is high. Most typical nozzle types are S-type and Cap-type.
Fuel feed ports
As mentioned before, CFB boilers require less
fuel feed points than PC boilers due to the
efficient combustion and compact structures.
The number of ports of feed points is a function
of the fuel characteristics and degree of lateral
mixing in the specific design of the furnace.
According to experiences, one feed point can
serve 9-27m
2
of bed area. The points locate
within the refractory lined substoichimetric
lower zone of the furnace and as low as possible
below secondary air ports in order to have
longer solid residence time. In some designs,
fuel with high moisture or sticky fuel are fed
into the loop seal so that fuel can be heated and
partly devolatilized and well mixed before
entering the bed.
Limestone feed ports
Due to the slow reaction rate, the location of the
sorbent feed point is less critical. Limestone is
Figure 3: Air distribution nozzles.
finer and used in smaller quantity, and can be injected into the bed pneumatically. Sometimes it is
injected into the recycled solids in order to mix better with bed materials.
Secondary air injection port
Air staging is used to reduce the formation of NOx. Primary air enters the bed from the bottom of
the bed grid to support the bed. Secondary air, 40-60% of combustion air, is injected into the bed
from above the refractory lined section. Thus substoichiometric combustion occurs in the lower
furnace zone. Above the secondary air injection, superficial velocity increases and unburned fuel in
substoichiometric zone will be combusted continuously. The injection ports should be located along
the wider side of the furnace cross section in order for the secondary air to be able to penetrate into
the depth of the furnace within a reasonable height.
Recycled solid entry
Solids collected by the cyclone or impact separator are returned to the furnace through a solid entry
port to extend the burning and reaction of unburned carbon and unreacted sorbent. The port is
located below the secondary air level. The selection of the port is based on the principle of pressure
balance between the solid return leg and the furnace pressure above the port.
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boiler Design
Bed solid drain
The purpose of bed drain is to extract bed solids from the lowest section of the bed in order to
maintain the required level of solid mass in the bed (bed inventory) and the size distribution of
solids. Figure 4 shows a size classifier drain pipe of CFB boilers. Solids drop through a vertical
tube, where air enters from the sides at such a rate that it entrains finer particles of solids into the
bed, while the heavier coarse fraction ash drops through the pipe to the silo. By hanging the
transport air velocity, the solid size distribution in the bed can be adjusted. The drain pipe should be
designed to prevent solids from blocking.
Height of the primary zone
The purpose of the primary air zone in the
furnace is to heat, gasify and pyrolyze fresh
coal. It also serves a thermal storage device. The
deeper the primary zone is, the higher the
pressure drop is, which require more fan power.
A depth of 2-3 meters is common nowadays.
Effect of Fuel
The fuel burnt, such as coal, peat, wood barks,
has a significant effect on the design and
operation of the CFB boilers. A stoichoimetric
fuel analysis must be done. Heat value of the
fuel governs coal feeding. Sulfur content decides
the sorbent injection rate.
Boiler performance modeling
Performance modeling is an important tool for
designers of CFB boilers. At the design stage, a
prediction of the boiler performance can help to
determine the most economic size of the boiler
for the best performance. When the boiler is
built, the simulation can be used for operation
optimization. The design can be evaluated by the
following criteria.
Primary air
Transport air
Oversize ash
Bed Bed
Figure 4:Drain pipe of solid ash.
Unburned carbon loss
Distribution of volatile, oxygen, and carbon along the height and across the cross section of
the furnace
Flue gas composition at the exit of the cyclone, especially the emission of SO
2
and NOx.
Heat release and absorption pattern in the furnace
Solid waste generated
Design of heating surfaces
The design of heating surfaces is affected by the fuel type used. For high sulfur content fuel, the
combustion temperature must be at around 850C for optimum sulfur capture. Fuels with low sulfur
and reactivity have to be combusted at a higher temperature and EAC for good combustion
efficiency. The fuel type determines where the heating surfaces are placed. For instance, low quality
coal will carry a high percentage of the generated heat out of the furnace, and less heat will be
181
STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boiler Design
absorbed in the primary loop, therefore more heating surface should be arranged at the backpass of
the furnace (Figure 5). Conversely, if high grade fuel is used, a large part of the heat generated is
absorbed in the CFB loop, which means that a superheater or reheater should be placed in the loop
(Figure 5). According to the heat duty of each heating surface and energy balance of the process,
the heat transfer area of each surface can be determined.
Arrangement of heat exchanger surfaces
Heating surfaces in a CFB, visualized in Figure 6, include the following heat exchangers:
Economizer
Evaporator (consists of furnace wall tubes)
Superheater
Reheater (optional)
Air preheater
The economizer is located at the
backpass between the superheater and
air preheater. The flue gas velocity
through the economizer is in the range
of 7.6 to 10.7 m/s depending on the fuel
and ash characteristics, while the
velocity of the steam/water mixture in
the tubes is about 1 m/s. The
economizer tube spacing and inline
arrangement minimize tube erosion and
fouling potential. The economizer flue
gas outlet temperature is selected
considering the feedwater temperature
plus 42 to 56C for the optimum heat
absorption split between the
economizer and air preheater. The
economizer feed water outlet
temperature is normally limited to 42C
less than the saturation temperature in
order to avoid evaporation in the
economizer at partial loads.
The evaporator consists normally of
the walls of the furnace; through which
water vaporize from water to saturated
steam. The typical overall heat transfer
Furnace
Backpass
Furnace and
cyclone
INTREX
Superheater
Superheaters
and reheaters
Economizer
Air
preheater
Figure 5: Placement of heat transfer surfaces. [1]
coefficient of the furnace wall is in the range of 150 to 200W/m
2
K.
Saturated steam from the evaporator is heated in the superheater, which is located in the backpass,
to the required steam temperature, normally 540C, before it is led to the turbine for expansion
work. The flue gas velocity through the superheater is as low as 7.6 to 8.5m/s and uniform across
the channel area in order to reduce erosion. The steam velocity in the tubes is about 20 m/s.
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boiler Design
Steam that has partially expanded in a HP turbine can be led back to the boiler and reheated in a
reheater. The reheater is located in the back-pass.
The air preheater, where combustion air is heated by the flue gas, is located after the economizer in
the flue gas channel. Tubular air preheaters are used for recovering the remaining heat in the flue
gas to meet the boiler efficiency
requirement. Similarly to the economizer,
the spacing of the tubes is arranged
according to inline arrangement to
minimize fouling potential and erosion.
Flue gas flows on the outside of the tubes
with a flue gas velocity of 9 to 12 m/s. It
should prevent entering air from saturation
and cold end tube corrosion, which is true
especially for burning of fuel with high
sulfur content.
A special heating surface is the external
heat exchanger, embedded in bubbling
recycled solid bed (Figure 6). Heat
absorbed in the heat exchanger is
fluctuating in order to keep bed
temperature and excess air relatively
unaffected. If the total heat duty of the
superheater and
reheater is larger than the maximum heat
that can be absorbed by these two heating
surfaces in back pass and furnace, the
external heat exchanger is needed.
Furnace
(water walls)
Superheaters
and reheaters External heat
transfer surfaces
Air
preheater
Economizer
Figure 6: Placement of heat transfer surfaces. [1]
The INTREX (Integral Recycling Heat
Exchanger) heat exchanger by Foster Wheeler is
a heat exchanger located in the bubbling bed
(Figure 5 and Figure 7). It contains one or more
tube bundles to cool circulating solids. Solids
enter from the furnace via slots (called internal
solids circulation) or from the separator (called
external solids circulation). Solids return to the
furnace via the solids return channels or through
slots in the common wall. The immersed tube
bundles can perform superheat or reheat duty
and have a very efficient heat transfer due to the
high temperature difference. By controlling the
rate of fluidizing airflow in the chamber and/or
the solids return channels, the heat absorbed in
the immersed tube bundles can be controlled,
which in turn can control furnace temperature or
steam temperature.
Figure 7: INTREX heat exchanger. [2]
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boiler Design
Heat distribution
In general, heat duty distribution of different heat transfer components is designed as below.
Sub-cooled part: 20%
Evaporation: 52%
Superheat: 28%
But the actual distribution is
Economizer: 10%
Furnace: 60%
Superheat: 30%
The economizer and air heater heat duty split requires a careful evaluation. The heat transfer
coefficient of the economizer is 56.8 to 65.1W/m
2
K, around 2 to 3 times higher than that of the air
preheater.
Gas-solid separators
Two different gas-solid separators are used in CFB boilers for different reasons. Cyclone or other
impingement separators are used within the CFB boiler loop to trap hot solids and return them to
the bed. This makes the residence time of fuel in the furnace long enough for complete combustion.
This is called the primary particles collection. Electrostatic precipitators (ESP) or bag-house filters
are used at the cold end stream of the boiler process to reduce fine particle emission to the
atmosphere. This is called the secondary collection. These chapters are focused upon the primary
separators, since they are a unique feature for CFB boilers.
The solids separator is a vital part of the CFB technology. The solids separator is primarily designed
to provide an efficient separation of the entrained solids from the hot flue gas and return most of the
unburned carbon and available calcined limestone for more efficient use. Sand and inert ash
particles are also returned. These particles are needed to maintain the proper bed inventory and
quality. The separator, located at the outlet of the combustion chamber, collects particles greater
than 60 microns with 99.5% or higher efficiency. The solids captured in the separator are
recirculated through a non-mechanical sealing device back to the combustion chamber.
Cyclones
Cyclones are commonly used for the separation of hot solids. It has a simple construction, since it
has no moving parts, and a high efficiency. Cyclones are located in the hot loop of CFB boiler, and
hot particles are entrapped and recycled to the furnace bed. Flue gas flows out from the top of the
cyclones to the backpass. The efficiency of the cyclone can be improved by several factors:
Higher entry velocity of the mixture of gas and solids
Larger size of solid
Higher density of particles
Smaller radius of the cyclone
Lower viscosity
To evaluate the probability of particles captured, one cut-off size is defined as the size of particles
that are likely to be collected with 50% efficiency by a given cyclone.
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STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boiler Design
( )
g p in c
th
V N
L
d
=
2
9
(17)
where, N
c
is the effective number of turns made by the gas-solid stream in the separator, normally 5
is assumed.
Higher mixture inlet velocity to the cyclone helps to capture much finer particles and increase
efficiency, but the pressure drop of gas through the cyclone increases. The aim of the design is to
find the optimum velocity.
Mechanical design of the solids separator varies in both construction and shape. Based on customer
preference, fuel fired, unit size and/or cycle condition the separator walls may be steam cooled,
water cooled or of refractory construction. The conventional solids separator design is a refractory
lined, uncooled cyclone. This type of cyclone is lined with a two-layer refractory (Figure 8). The
inner refractory layer is abrasion resistant material to resist the erosive effects of high velocity ash
particles. The outer refractory layer, against the metal shell, provides insulation to minimize heat
loss and protect the carbon steel outer casing from overheating. The amount of refractory in this
type of cyclone is very large and therefore high maintenance costs and availability problems are
envisioned. Typically, a cooled separator design is preferred (Figure 8).
Solid Separator for
Foster Wheeler CFB
Mineral wool
Refractory ca. 50 mm
Membrane wall
FEATURES
Square
Integrated with furnace
No expansion joints
Membrane walls
Water or steam cooled
Normal insulation
Figure 8: Cyclone design from Foster Wheeler. [2]
U-Beams particle separators
Babcock & Wilcox Ltd (B & W) uses a primary particle separator that functions by impact force.
Figure 9 shows the location of the U-Beams in the CFB process. B & W's primary solids collectors
consists of 2 rows of U-Beams located within the furnace at the gas exit and 4 additional rows of U-
Beams located immediately downstream of the in-furnace U-Beams. Solids collected by the front
185
STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boiler Design
two rows discharge downward directly to the furnace along the rear wall, and return by gravity to
the furnace through opening distributed across the width of the unit. Solids collected by 4 additional
rows of U-Beams return to solid storage hopper. Figure 10 shows a schematic of the U-Beams.
The U-Beams are made of stainless steel. Individual U-beams are in the form of channels, 152 mm
wide by 178 mm deep. Two bolts through the water-cooled roof suspend each beam, protected by
an enclosure. Dynamics (gas and solids)
stresses, static (dead load) stresses, design
temperatures and material creep strength are
used to design the U-Beams.
A pan at the lower ends of each U-Beam in
alignment accommodates horizontal and
vertical expansion. These pans also form a gas
barrier at the bottom discharge end of the
beams to prevent gas bypassing and improve
particle collection.
The erosion is low due to the chromium oxide
layer that forms on the stainless steel at the
furnace operating temperatures. Lower gas
velocity through the U-beam and design with
all impact angles at 90 degrees is also
favorable. Figure 11 shows the gas flow
through U-Beams. [4]
Recycling of solids
In a solids return from uncooled cyclone to
combustor, a loop seal (Figure 12) is used to
provide the gas seal for pressure difference
between lower furnace and separator. Loop
seal has similar mechanical structure as the
cyclone, i.e. it is manufactured of carbon steel
plate and lined with a two-layer refractory.
This further increases the amount of
refractories. A split loop seal design is used
particularly in larger units to provide two
solids outlets from one cyclone. The bottom of
the loop seal is fluidized with high-pressure
air.
Expansion joints are provided at the inlet of
the uncooled cyclone and in loop seal to
compensate different thermal expansion of
combustor and cyclone.
Figure 9: Locations of U-Beams. [4]
Figure 10: U-Beams solid separator. [4]
With cooled separators a wall seal -design is used to provide the gas seal. The wall seal is
constructed of water cooled panel walls, which minimize the amount of refractories. The bottom of
the wall seal is fluidized with high-pressure air.
186
STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boiler Design
Using a water cooled separator no expansion
joints are required, since there is no
temperature difference between the separator
and furnace. In case of a steam cooled
separator a flexible connection is provided at
separator inlet and a small expansion joint at
the outlet to wall seal.
Bottom Ash Removal System
The bottom ash removal rate is controlled to
maintain a constant bed material inventory in
the furnace. In addition, the bottom ash
removal system performs one or more of the
following important functions:
Provide cooling of the bottom ash
material.
Classify the bottom ash material and
return light particles to help maintain
furnace bed quality.
Recover heat from the ash.
Improve carbon burn out.
Improve sulfur capture reactions
Figure 11: Gas flow through U-Beams. [4]
Figure 12: Loop seal. [ 5]
187
STEAM BOILER TECHNOLOGY Circulating Fluidized Bed Boiler Design
References
1. CFB Engineering Manual, extract supplied by Foster Wheeler. http://www.fwc.com/
2. Pictures and schematics supplied by Foster Wheeler. http://www.fwc.com/
3. Pictures supplied by Kvaerner Power Division. http://www.kvaerner.com/powergeneration/
4. Pictures supplied by Babcock & Wilcox, http://www.babcock.com
5. Vakkilainen E. Lecture slides and material on steam boiler technology. 2001.
188
Recovery Boilers
Esa Vakkilainen
STEAM BOILER TECHNOLOGY Recovery Boilers
Table of contents
Table of contents.............................................................................................................................. 190
Kraft recovery principles ................................................................................................................. 191
Function of recovery boilers ........................................................................................................ 192
First recovery boilers ................................................................................................................... 193
Development of recovery boiler technology................................................................................ 193
Improving air systems.................................................................................................................. 194
Multilevel air............................................................................................................................ 195
Vertical air................................................................................................................................ 195
Black liquor dry solids content ................................................................................................ 195
High temperature and pressure recovery boiler ........................................................................... 197
Safety ........................................................................................................................................... 197
Chemical processes in the furnace................................................................................................... 198
Smelt ............................................................................................................................................ 199
Reduction and sulfidity................................................................................................................ 199
Sodium......................................................................................................................................... 200
Recovery boiler design..................................................................................................................... 201
Key recovery boiler design alternatives....................................................................................... 201
Key design specifications......................................................................................................... 201
Single drum.............................................................................................................................. 202
Screen or screenless boiler....................................................................................................... 202
Evolution of recovery boiler design............................................................................................. 203
Two drum recovery boiler........................................................................................................ 204
Modern recovery boiler............................................................................................................ 204
Current recovery boiler ............................................................................................................ 206
State of the art and current trends ............................................................................................ 206
Steam generation...................................................................................................................... 207
Heat transfer surface design and material selection......................................................................... 207
Furnace design and materials....................................................................................................... 208
Furnace tube materials ............................................................................................................. 208
Membrane materials................................................................................................................. 210
Refractory and studs................................................................................................................. 210
Superheater design and materials................................................................................................. 210
Effect of steam outlet temperature........................................................................................... 210
Typical materials...................................................................................................................... 211
Sealing the roof ........................................................................................................................ 211
Boiler bank design and materials................................................................................................. 212
Economizer design and materials ................................................................................................ 212
References........................................................................................................................................ 213
190
STEAM BOILER TECHNOLOGY Recovery Boilers
Kraft recovery principles
In the pulping process of a paper mill, spent cooking chemicals and dissolved organics are separated
from the pulp during washing. This black, alkaline liquor was at first dumped. Chemical recovery
systems were used earlier, but it was in the 1930s and 40s when modern type of regeneration of
spent liquor was widely adopted. Invention of new types of equipment and an increase in mill size
led to a favorable economic situation: it was cheaper to process black liquor than to buy new
chemicals.
Recovery of black liquor has also other advantages. Concentrated black liquor can, when burnt,
produce energy for generation of steam and electricity. In the most modern pulp mills, this energy is
more than sufficient to cover all internal power use.
Makeup
chemicals
Green liquor
White liquor
Bark
Pulp
Sales
Bleaching
chemicals
Causticizing
Bleaching
Drying
Sludges
Roundwood
Chips
Electricity
Chemical mftg
Recovery boiler
Evaporator
Talloil prod.
Weak liquor
Soap
Cooking
Bark boiler
Wood handling
Black liquor
Sales
Pulp
Lime kiln
Figure 1: Kraft mill unit operations.
The principal Kraft recovery unit operations are (Figure 1), evaporation of black liquor, combustion
of black liquor in recovery boiler furnace including of formation of sodium sulfide and sodium
carbonate, causticizing of sodium carbonate to sodium hydroxide, and regeneration of lime mud in a
lime kiln.
There are other minor operations to ensure continuous operation of the recovery cycle. Soap in the
black liquor can be removed and tall oil produced. Control of sodium - sulfate balance is done by
addition of makeup chemicals such as sodium sulfate to mix tank or removal of recovery boiler
flyash. Removal of recovery boiler flyash removes mostly sodium and sulfur, but serves as purge
for chloride and potassium. Buildup of non-process elements is prevented by disposal of dregs and
grits at causticizing. Malodorous gases are processed by combustion at the recovery boiler or lime
kiln. In some modern and closed mills chloride and potassium removal processes are employed.
With additional closure new internal chemical manufacturing methods are sometimes applied.
191
STEAM BOILER TECHNOLOGY Recovery Boilers
Figure 2: One of the latest recovery boilers constructed, Gruv from Kvaerner.
Function of recovery boilers
Concentrated black liquor contains organic dissolved wood residue in addition of cooking
chemicals. Combustion of the organic portion of chemicals produces heat. In the recovery boiler
heat is used to produce high pressure steam, which is used to generate electricity in a turbine. The
turbine exhaust, low pressure steam is used for process heating.
Combustion in the recovery boiler (Figure 2) furnace needs to be controlled carefully. High
concentration of sulfur requires optimum process conditions to avoid production of sulfur dioxide
and reduced sulfur gases emissions. In addition to environmentally clean combustion, reduction of
inorganic sulfur must be achieved in the char bed.
The recovery boiler process has several unit processes:
1. Combustion of organic material in black liquor to generate steam
2. Reduction of inorganic sulfur compounds to sodium sulfide
3. Production of molten inorganic flow of mainly sodium carbonate and sodium sulfide and
dissolution of said flow to weak white liquor to produce green liquor
4. Recovery of inorganic dust from flue gas to save chemicals
5. Production of sodium fume to capture combustion residue of released sulfur compounds
192
STEAM BOILER TECHNOLOGY Recovery Boilers
First recovery boilers
The modern recovery boiler has a few strong ideas that have remained unchanged until today. It
was the first recovery equipment type where all processes occurred in a single vessel. The drying,
combustion and subsequent reactions of black liquor all occur inside a cooled furnace. This is the
main idea in Tomlinsons work.
Secondly the combustion is aided by spraying the black liquor into small droplets. Controlling
process by directing spray proved easy. Spraying was used in early rotary furnaces and with some
success adapted to stationary furnace by H. K. Moore. Thirdly one can control the char bed by
having primary air level at char bed surface and more levels above. Multiple level air system was
introduced by C. L. Wagner.
Recovery boilers also improved the smelt removal. It is removed directly from the furnace through
smelt spouts into a dissolving tank. Some of the first recovery units employed the use of Cottrells
electrostatic precipitator for dust recovery.
Babcock & Wilcox (B&W) was founded in 1867 and gained early fame with its water tube boilers.
The company built and put into service the first black liquor recovery boiler in the world in 1929
[1]. This was soon followed by a unit with completely water cooled furnace at Windsor Mills in
1934. After reverberatory and rotating furnaces the recovery boiler was on its way.
The second early pioneer, Combustion Engineering based its recovery boiler design on the
pioneering work of William M. Cary, who in 1926 designed three furnaces to operate with direct
liquor spraying and on work by Adolph W. Waern and his recovery units.
Recovery boilers were soon licensed and produced in Scandinavia and Japan. These boilers were
built by local manufacturers from drawings and with instructions of licensors. One of the early
Scandinavian Tomlinson units employed a 8.0 m high furnace that had 2.8*4.1 m furnace bottom
which expanded to 4.0*4.1 m at superheater entrance [2]. This unit stopped production for every
weekend. In the beginning economizers had to be water washed twice every day, but after
installation of shot sootblowing in the late 1940s the economizers could be cleaned at the regular
weekend stop.
The construction utilized was very successful. One of the early Scandinavian boilers (Figure 3) 160
t/day at Korsns, operated still almost 50 years later [3].
Development of recovery boiler technology
The use of Kraft recovery boilers spread fast as functioning chemical recovery gave Kraft pulping
an economic edge over sulfite pulping [4]. The first recovery boilers had horizontal evaporator
surfaces, followed by superheaters and more evaporation surfaces. These boilers resembled the
state-of-the-art boilers of some 30 years earlier. This trend has continued until today. Since a halt in
the production line will cost a lot of money the adopted technology in recovery boilers tends to be
conservative.
The first recovery boilers had severe problems with fouling [5]. Tube spacing wide enough for
normal operation of a coal fired boiler had to be wider for recovery boilers. This gave satisfactory
performance for a week, before a water wash was required. Mechanical sootblowers were also
quickly adopted. To control chemical losses and lower the cost of purchased chemicals electrostatic
precipitators were added. Lowering dust losses in flue gases has more than 60 years of practice.
193
STEAM BOILER TECHNOLOGY Recovery Boilers
One should also note square headers in the 1940
recovery boiler, Figure 3. The air levels in
recovery boilers soon standardized to two: a
primary air level at the char bed level and a
secondary above the liquor guns.
In the first tens of years the furnace lining was
of refractory brick. The flow of smelt on the
walls causes extensive replacement and soon
designs that eliminated the use of bricks were
developed.
Improving air systems
To achieve solid operation and low emissions
the recovery boiler air system needs to be
properly designed. Air system development
continues and has been continuing as long as
recovery boilers have existed [6]. As soon as the
target set for the air system has been met new
Figure 3: Korsns recovery boiler 1943. [3]
targets are given. Currently the new air systems have achieved low NOx, but are still working on
lowering fouling. Table 1 visualizes the development of air systems.
Table 1: Development of air systems. [6]
Air system Main target But also should
1st generation Stable combustion of black
liquor
2nd generation high reduction Burn liquor
3rd generation decrease sulfur emissions Burn black liquor, high
reduction
4th generation low NOx, ... Burn black liquor, high
reduction and low sulfur
emission
5th generation decrease superheater and boiler
bank fouling
Burn black liquor, high
reduction, low emissions
The first generation air system in the 1940s and 1950s consisted of a two level arrangement;
primary air for maintaining the reduction zone and secondary air below the liquor guns for final
oxidation [7]. The recovery boiler size was 100 300 tds/d and black liquor concentration 45 55
%. Frequently to sustain combustion auxiliary fuel needed to be fired. Primary air was 60 70 % of
total air with secondary the rest. In all levels openings were small and design velocities were 40
45 m/s. Both air levels were operated at 150
o
C. Liquor gun or guns were oscillating. Main problems
were high carryover, plugging and low reduction. But the function, combustion of black liquor,
could be filled.
The second generation air system targeted high reduction. In 1954 CE moved their secondary air
from about 1 m below the liquor guns to about 2 m above them [7]. The air ratios and temperatures
remained the same, but to increase mixing 50 m/s secondary air velocities were used. CE changed
their frontwall/backwall secondary to tangential firing at that time. In tangential air system the air
nozzles are in the furnace corners. The preferred method is to create a swirl of almost the total
194
STEAM BOILER TECHNOLOGY Recovery Boilers
furnace width. In large units the swirl caused left and right imbalances. This kind of air system with
increased dry solids managed to increase lower furnace temperatures and achieve reasonable
reduction. B&W had already adopted the three-level air feeding by then.
Third generation air system was the three level air. In Europe the use of three levels of air feeding
with primary and secondary below the liquor guns started about 1980. At the same time stationary
firing gained ground. Use of about 50 % secondary seemed to give a hot and stable lower furnace
[8]. Higher black liquor solids 65 70 % started to be in use. Hotter lower furnace and improved
reduction were reported. With three level air, higher dry solids and a hotter furnace the sulfur
emissions could be kept on an acceptable level.
Fourth generation air systems are the multilevel air and the vertical air. As the feed of black liquor
dry solids to the recovery boiler have increased, achieving low sulfur emissions is not anymore the
target of the air system. Instead, low NOx and low carryover are the new targets.
Multilevel air
The three-level air system was a significant improvement, but better results were required. Use of
CFD models offered a new insight of air system workings. The first to develop a new air system
was Kvaerner (Tampella) with their 1990 multilevel secondary air in Kemi, Finland, which was
later adapted to a string of large recovery boilers [9].
Kvaerner also patented the four level air system, where additional air level is added above the
tertiary air level. This enables significant NOx reduction.
Vertical air
Vertical air mixing (Figure 4) was invented by
Erik Uppstu [10]. His idea is to turn traditional
vertical mixing to horizontal mixing. Closely
spaced jets will form a flat plane. In traditional
boilers this plane has been formed by secondary
air. By placing the planes to 2/3 or 3/4
arrangement improved mixing results. Vertical
air has a potential to reduce NOx as staging air
helps in decreasing emissions [11].
In vertical air mixing, primary air supply is
arranged conventionally. Rest of the air ports are
placed on interlacing 2/3 or 3/4 arrangement.
Black liquor dry solids content
As fired black liquor is a mixture of organics,
inorganics and water. Typically the amount of
water is expressed as mass ratio of dried black
liquor to unit of black liquor before drying. This
ratio is called the black liquor dry solids content.
Figure 4: Principle of vertical air (Kaila and
Saviharju, 2003).
If the black liquor dry solids content is below 20 % or water content in black liquor is above 80 %
the net heating value of black liquor is negative (Figure 5). This means that all heat from
combustion of organics in black liquor is spent evaporating the water it contains. The higher the dry
195
STEAM BOILER TECHNOLOGY Recovery Boilers
solids content is, the less water the black liquor contains and the hotter the adiabatic combustion
temperature is.
The black liquor dry solids content has always been limited by the ability of available evaporation
technology to handle highly viscous liquors [12]. The virgin black liquor dry solids contents of
recovery boilers are shown in Figure 6 as a function of purchase year of the boiler.
-10.0
-5.0
0.0
5.0
10.0
15.0
0 10 20 30 40 50 60 70 80
BLACK LIQUOR DRY SOLIDS, %
N
E
T
H
E
A
T
I
N
G
V
A
L
U
E
,
M
J
/
k
g
d
r
y
s
o
l
i
d
s
90
Figure 5: Net heating values of typical Kraft liquors at various concentrations.
50
55
60
65
70
75
80
85
90
1975 1980 1985 1990 1995 2000 2005
Delivery year
V
i
r
g
i
n
d
r
y
s
o
l
i
d
s
,
%
Average
Maximum
Figure 6: Virgin black liquor dry solids contents as a function of the purchase years of recovery
boilers.
According to Figure 6 the average dry solids content of virgin black liquors has increased. This is
especially true for latest very large recovery boilers. Design dry solids contents for green field mills
have been either 80 or 85 % dry solids. 80 % (or before that 75 %) dry solids has been in use in
Asia and South America. 85 % (or before that 80 %) has been in use in Scandinavia and Europe.
196
STEAM BOILER TECHNOLOGY Recovery Boilers
High temperature and pressure recovery boiler
Development of recovery boiler main steam pressure and temperature was rapid in the beginning,
(Figure 7). By 1955, not even 20 years from birth of recovery boiler highest steam pressures were
10.0 MPa and 480
o
C. The pressures and temperatures used then backed downward somewhat due to
safety [13]. By 1980 there were about 700 recovery boilers in the world [8].
0
100
200
300
400
500
600
1937 1942 1947 1952 1957 1962 1967 1972 1977 1982 1987 1992 1997 2002 2007
Delivery year
S
t
e
a
m
t
e
m
p
e
r
a
t
u
r
e
,
o
C
,
S
t
e
a
m
p
r
e
s
s
u
r
e
,
b
a
r
0
1000
2000
3000
4000
5000
6000
C
a
p
a
c
i
t
y
,
t
d
s
/
d
Temperature
Pressure
Capacity
Figure 7: Development of recovery boiler pressure, temperature and capacity.
Safety
One of the main hazards in operation of recovery boilers is the smelt-water explosion. This can
happen if even a small amount of water is mixed with the solids in high temperature. Smelt-water
explosion is purely a physical phenomenon.
The smelt water explosion phenomena have been studied by Grace [14]. The liquid - liquid type
explosion mechanism has been established as one of the main causes of recovery boiler explosions.
In the smelt water explosion even a few liters of water, when mixed with molten smelt can violently
turn to steam in few tenths of a second. Char bed and water can coexist as steam blanketing reduces
heat transfer. Some trigger event destroys the balance and water is evaporated quickly through
direct contact with smelt. This sudden evaporation causes increase of volume and a pressure wave
of some 10 100000 Pa. As the surface areas are large in the boiler, the force caused by this
pressure wave is usually sufficient to cause all furnace walls to bend out of shape. Safety of
equipment and personnel requires an immediate shutdown of the recovery boiler if there is a
possibility that water has entered the furnace. All recovery boilers have to be equipped with a
special automatic shutdown sequence.
The other type of explosions is the combustible gases explosion. For this to happen the fuel and the
air have to be mixed before the ignition. Typical conditions are either a blackout (loss of flame)
without purge of furnace or continuous operation in a substoichiometric state. To detect blackout
flame monitoring devices are installed, with subsequent interlocked purge and startup. Combustible
gas explosions are connected with oil/gas firing in the boiler. As also continuous O
2
monitoring is
practiced in virtually every boiler the noncombustible gas explosions have become very rare.
197
STEAM BOILER TECHNOLOGY Recovery Boilers
Chemical processes in the furnace
Recovery boiler processes efficiently capture inorganic and organic chemicals in the black liquor.
Efficient inorganic chemicals processing can be seen as high reduction rate. The furnace also
disposes of all organics in black liquor. This means stable and complete combustion. Reduction
(removal of oxygen) and combustion (reaction with oxygen) are opposite reactions. It is difficult to
achieve both at same unit operation, furnace.
Other furnace requirements are even more complex. A recovery boiler should have a high thermal
efficiency. It should produce low fouling ash. Processes in the recovery boiler should be
environmentally friendly and produce a low level of harmful emissions. In spite of successes,
optimizing recovery boiler chemical processes is difficult. Processes are complex and there are
several streams to and from the recovery boiler.
Na
2
S
Na
2
CO
3
Volatiles
Combustion
CO
2
Drying
H
2
O
Devolatilization
H
2
S
SO
2
Na
2
SO
4 Na
2
CO
3
Reduction
Carbon
Reoxidation
of Na
2
S
Gasification
Na
2
S
Na
NaOH
Spraying
Droplets
Char combustion
Release of Na
Figure 8: Some of the reactions in the lower furnace.
There are many simultaneous reactions going on in the lower furnace, Figure 8. First there are the
black liquor combustion processes. Drying occurs when water is evaporated, Devolatilization
occurs when droplet size increases and gases generated inside the droplet are released. Finally char
combustion takes place when carbon is burned off. In the lower part of the furnace there are char
bed reactions. These consist mostly of inorganic salt, especially melt reactions. In the upper furnace
there is volatiles combustion. Almost all other combustion reactions are concluded. Sodium sulfate
and carbonate fume formation with other aerosol reactions take place. There are a multitude of
chemical reactions taking place in the recovery boiler. The best way to study them is to look at them
main component by main component.
198
STEAM BOILER TECHNOLOGY Recovery Boilers
Smelt
The smelt is the product of inorganic reactions in the recovery furnace. At the same time the carbon
is consumed by the residual inorganic portion melts. Inorganics flow out of the furnace through
smelt spouts (Figure 9). The amount of smelt inside recovery boiler furnace has been measured by
Kelly et al. [15]. They found the smelt content per furnace unit area to be about 250 kg/m
2
for a
decanting CE unit and about 140 kg/m
2
for a B&W unit. The residence times found were 44 and 25
minutes respectively.
Figure 9: Smelt flow from char bed. [16]
Smelt temperature is about 100
o
C higher than initial deformation temperature [3]. In older low
solids boilers the smelt temperatures are 750 810
o
C [17]. In modern boilers with a high content of
dry solids the typical smelt temperatures are 800 850
o
C. The smelt flow corresponds typically
from 0.400 to 0.480 kg per kilogram of incoming black liquor dry solids flow.
Reduction and sulfidity
The main process property of the smelt is the reduction. Reduction is the molar ratio of Na
2
S to
Na
2
SO
4
,
SO Na
+ S
Na
S
Na
= Reduction
4 2 2
2
(1)
The higher the reduction the lower the amount of sodium that reaches the cook unusable. Reduction
rates of 95 ... 98 % are not uncommon in well operated recovery boilers. Usually the reduction
efficiency increases as the char bed temperature increases. From thermodynamical equilibrium we
can note that there should be very little of sodium oxides and thiosulfate.
Sulfidity is the molar ratio of sodium sulfide to the total alkali content.
2
K +
Na
S
= Sulfidity
2
tot
(2)
199
STEAM BOILER TECHNOLOGY Recovery Boilers
This equation is widely in use because of ease of measuring Sulfidity depends on the liquor
circulation of the mill. Too high a sulfidity causes operating problems for the recovery boiler.
Especially increased sulfidity increases SO
2
and TRS emissions [18].
80
82
84
86
88
90
92
94
96
98
100
0 5 10 15 20 25 30 35 40 45
Alkali in weak white liquor, g(NaOH)/l
R
e
d
u
c
t
i
o
n
,
S
/
(
S
+
S
O
4
)
95 % reduction in WWL
90
85
80
75
70
Figure 10: Effect of weak white liquor composition on reduction in green liquor, reduction is smelt
95 %, sulfidity 35 %.
Often the typical mill analysis of reduction rate is done for green liquor. Alkali in the green liquor
will typically result in lower values that what is measured in smelt, Figure 10. Typically in modern
mills the reduction in green liquor is 2 3 percent units lower that in the smelt.
Sodium
Sodium is released during the black liquor combustion and char bed reactions through vaporization
and reduction of sodium carbonate. Sodium release increases as a function of temperature. At the
beginning of combustion a large portion of sodium is connected to the organic portion of the black
liquor. At the end of volatiles release almost all of it is inorganically bound.
0
5
10
15
20
25
30
35
40
0 2 4 6 8 10 12 14 16 18
CO3(ESP), w-%
N
a
-
r
e
l
e
a
s
e
g
/
k
g
k
a
Figure 11: Sodium release to ESP ash as function of carbonate in ash in industrial boilers.
200
STEAM BOILER TECHNOLOGY Recovery Boilers
Sodium release in Kraft recovery boilers increases with increasing lower furnace temperature
(Figure 11). It has been assumed that in industrial boilers all of the ESP dust is from reactions with
vaporized sodium. In addition the amount of sodium released as a function of carbonate in ESP dust
seems to increase. Increase in carbonate indicates increase in lower furnace temperature [19].
Sodium content in black liquors is around 20 w-%. This means that sodium release in recovery
furnace is about 10% of the sodium in black liquor.
Much studied reactions involving sodium are hydroxide formation, reduction reactions, and sulfate
formation with hydroxides, sulfate formation with chlorides, sulfate formation with carbonate and
carbonate formation.
Recovery boiler design
In a pulp mill there are three main recovery
boiler purposes. The first is to burn the
organic material in the black liquor to
generate high pressure steam. The second is
to recycle and regenerate spent chemicals in
black liquor. The third is to minimize
discharges from several waste streams in an
environmentally friendly way. In a recovery
boiler, concentrated black liquor is burned in
the furnace and at the same time reduced
inorganic chemicals emerge molten. A
modern recovery boiler, Figure 12, has
evolved a long way from the first recovery
boilers.
One noticeable trend has emerged in recent
years. The average size of recovery boiler has
grown significantly in each year (Figure 13).
Figure 12: Typical recovery boiler in operation,
Gruvn. [20]
The nominal capacity of new recovery boilers at the beginning of the 1980s was 1700 metric tons of
dry solids per day. This was regarded as the maximum at that time. By year 2000 more than ten
recovery boilers, capable of handling 2500 3500 metric tons of dry solids per day were built. At
2002 a recovery boiler with nominal capacity of 4450 tds/d was bought. The maximum design
capacity has increased because there is less water in black liquor, liquor spraying is now more
uniform, new computer controls mean better stability and controllability and most importantly, new
pulping lines of corresponding capacity can be built.
Key recovery boiler design alternatives
There are alternative solutions for designing recovery boilers. Major recovery boiler design options
are; screen or screenless superheater area design, single drum or two-drum, lower furnace tubing
material; furnace bottom tubing material, vertical or horizontal boiler bank and economizer
arrangement and number and type of air levels.
Key design specifications
When sizing a recovery boiler some key design specifications are usually given to the boiler vendor
to do the design. Typically given are dry solids capacity (without ash), black liquor gross heat value
(without ash), black liquor elementary analysis (without ash), black liquor dry solids content from
evaporation (without ash), desired main steam conditions, feed water inlet temperature and
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STEAM BOILER TECHNOLOGY Recovery Boilers
economizer flue gas outlet temperature. Sometimes the desired superheated steam temperature
control point is also given in % of MCR (Maximum continuous rating).
0
500
1000
1500
2000
2500
3000
3500
4000
4500
1975 1980 1985 1990 1995 2000 2005
Delivery year
C
a
p
a
c
i
t
y
,
t
d
s
/
d
Average
Maximum
Figure 13: Size of recovery boiler versus startup year.
Black liquor dry solids flow is the key design criteria. It establishes the required size of the boiler.
With elementary analysis and dry solids one can calculate the heat released in the furnace. With
water and steam values the MCR steam flow is established. It should be noted that when black
liquor is sprayed to the furnace it contains ash collected from the electrostatic precipitator and ash
hoppers. Because ash free black liquor is the input flow to the recovery plant, it is usually chosen as
the design base.
Single drum
All modern recovery boilers are of single drum type. The single drum has replaced the two drum (or
bi-drum) construction in all but the smallest, low pressure boilers. The same trend but 20 years
earlier happened with coal fired boilers.
Screen or screenless boiler
One of the key design issues is whether or not to have a screen in the recovery boiler (Figure 14). A
screen is a low temperature heat surface that is put in front of the superheater area. Almost always
the screen is an evaporative surface. There are a few screens with saturated steam entering them, but
the experience has not been too favorable.
Benefits of the screen are
- Screen stops part of the carryover from furnace
- Screen blocks radiation from the furnace and reduces superheater surface temperatures. A
screen protects superheater from corrosion
- Screen itself is cold surface with very minor corrosion
- Screen captures unburnt liquor particles. Less unburnt reaches superheater surfaces,
especially lower bends. This decreases superheater corrosion rates.
- Screen evens out the flow somewhat. This blocking effect is small if the screen is not covered
with deposits.
- Screenless superheater section is higher and so has higher building volume and cost.
Negative issues with the screen are
202
STEAM BOILER TECHNOLOGY Recovery Boilers
- There has been number of cases where
fallen deposits have caused the screen to
rupture. This has caused boiler explosions
and long shutdown times for repairs.
- Superheater surfaces are more affected
with radiation behind the screen than
behind the nose
- Screen captures heat. This reduces
superheating.
Fear of boiler accidents caused by fallen
deposits caused the boiler purchasers in US to
avoid buying new boilers with screen. In
Scandinavia boilers with screen have been
bought all the time. Even in US some new
boilers with screen have been bought.
NEWRCB17
EkV, 11.1993
Figure 14: Screen at left, screenless boiler at
right.
Evolution of recovery boiler design
There have been significant changes in the Kraft pulping process in recent years [21, 22, 23].
Increased use of new modified cooking methods and oxygen delignification has increased the
degree of organic residue recovery. Black liquor properties have reflected these changes (Table 2).
Table 2: Development of black liquor properties. [19]
Property Two drum Modern Current
1982 1992 2002
Liquor dry solids, kg dry solids/ton pulp 1700 1680 1780
Sulphidity, Na
2
S/(Na
2
S+NaOH) 42 45 41
Black liquor HHV, MJ/kg dry solids 15.0 13.9 13.0
Liquor dry solids, % 64 72 80
Elemental analysis, % weight
C 36.4 34 31.6
H 3.75 3.5 3.4
N 0.1 0.1 0.1
Na 18 18.4 19.8
S 5.4 5.9 6
Cl 0.2 0.4 0.8
K 0.75 1.0 1.8
Cl/(Na+K), mol-% 0.70 1.37 2.49
K/(Na+K), mol-% 2.39 3.10 5.07
Net heat to furnace, kW/kg dry solids 13600 12250 11200
Combustion air
*
required,
m
3
n/kg dry solids
4.1 3.7 3.4
Flue gas
*
produced, m
3
n/kg dry solids 4.9 4.3 3.9
* At air ratio 1.2
Changes in investment costs, increases in scale, demands placed on energy efficiency and
environmental requirements are the main factors directing development of the recovery boiler [24].
Steam generation increases with increasing black liquor dry solids content. For a rise in dry solids
content from 65% to 80% the main steam flow increases by about 7%. The increase is more than
203
STEAM BOILER TECHNOLOGY Recovery Boilers
2% per each 5% increase in dry solids. Steam generation efficiency improves slightly more than
steam generation itself. This is mainly because the drier black liquor requires less preheating.
There are recovery boilers that burn liquor with solids concentration higher than 80%. Unreliable
liquor handling, the need for pressurized storage and high pressure steam demand in the
concentrator has frequently prevented sustained operation at very high solids. The main reason for
the handling problems is the high viscosity of black liquor associated with high solids contents.
Black liquor heat treatment (LHT) can be used to reduce viscosity at high solids [25].
For pulp mills the significance of electricity generation from the recovery boiler has been
secondary. The most important factor in the recovery boiler has been high availability. The
electricity generation in recovery boiler process and steam cycle can be increased by elevated main
steam pressure and temperature or by higher black liquor dry solids [26].
Increasing main steam outlet temperature increases the available enthalpy drop in the turbine. The
normal recovery boiler main steam temperature 480C is lower than the typical main steam
temperature of 540C for the coal and oil fired utility boilers. The main reason for choosing a lower
steam temperature is to control superheater corrosion. Requirement for high availability and use of
less expensive materials are often cited as other important reasons.
Two drum recovery boiler
Most of the recovery boilers operating today are of two drum design. Their main steam pressure is
typically about 8.5 MPa and temperature 480 C. The maximum design solids handling capacity of
the two drum recovery boiler is about 1700 tds/d. Three level air and stationary firing are employed.
The two drum boiler (Figure 15) represents one successful stage in a long evolutionary path and
signified a design with which the sulfur emissions could be successfully minimized. Main steam
temperature was increased to 480 C using this design.
Two drum recovery boilers are constructed with water screen to protect superheaters from direct
furnace radiation, lower flue gas temperatures and to decrease combustible material carry-over to
superheaters. The two drum boiler was the first type to use vertical flow economizers, which
replaced horizontal economizers because of their improved resistance to fouling.
Modern recovery boiler
The modern recovery boiler is of a single drum design, with vertical steam generating bank and
wide spaced superheaters. The most marked change around 1985 was the adoption of single drum
construction. The construction of the vertical steam generating bank is similar to the vertical
economizer. Vertical boiler bank is easy to keep clean. The spacing between superheater panels
increased and leveled off at over 300 but under 400 mm. Wide spacing in superheaters helps to
minimize fouling. This arrangement, in combination with sweetwater attemperators, ensures
maximum protection against corrosion. There have been numerous improvements in recovery boiler
materials to limit corrosion [27, 28, 29, 30].
The effect of increasing dry solids concentration has had a significant effect on the main operating
variables. The steam flow increases with increasing black liquor dry solids content. Increasing
closure of the pulp mill means that less heat per unit of black liquor dry solids will be available in
the furnace. The flue gas heat loss will decrease as the flue gas flow diminishes. Increasing black
liquor dry solids is especially helpful since the recovery boiler capacity is often limited by the flue
gas flow.
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STEAM BOILER TECHNOLOGY Recovery Boilers
A modern recovery boiler (Figure 16), consists
of heat transfer surfaces made of steel tube;
furnace-1, superheaters-2, boiler generating
bank-3 and economizers-4. The steam drum-5
design is of single-drum type. The air and black
liquor are introduced through primary and
secondary air ports-6, liquor guns-7 and tertiary
air ports-8. The combustion residue, smelt exits
through smelt spouts-9 to the dissolving tank-10.
The nominal furnace loading has increased
during the last ten years and will continue to
increase [31]. Changes in air design have
increased furnace temperatures [32, 33, 34, 35].
This has enabled a significant increase in hearth
solids loading (HSL) with only a modest design
increase in hearth heat release rate (HHRR). The
average flue gas flow decreases as less water
vapor is present. So the vertical flue gas
velocities can be reduced even with increasing
temperatures in lower furnace.
The most marked change has been the adoption
of single drum construction. This change has
been partly affected by the more reliable water
quality control. The advantages of a single drum
boiler compared to a bi drum are the improved
safety and availability. Single drum boilers can
be built to higher pressures and bigger
capacities. Savings can be achieved with
decreased erection time. There is less tube joints
in the single drum construction so drums with
improved startup curves can be built.
The construction of the vertical steam generating
bank is similar to the vertical economizer, which
based on experience is very easy to keep clean
[36]. Vertical flue gas flow path improves the
cleanability with high dust loading [37]. To
minimize the risk for plugging and maximize the
efficiency of cleaning both the generating bank
and the economizers are arranged on generous
side spacing. Plugging of a two drum boiler
bank is often caused by the tight spacing
between the tubes.
The spacing between superheater panels has
increased. All superheaters are now wide spaced
to minimize fouling. This arrangement, in
combination with sweetwater attemperators,
Figure 15: Two drum recovery boiler.
Figure 16: Modern recovery boiler.
205
STEAM BOILER TECHNOLOGY Recovery Boilers
ensures maximum protection against corrosion. With wide spacing plugging of the superheaters
becomes less likely, the deposit cleaning is easier and the sootblowing steam consumption is lower.
Increased number of superheaters facilitates the control of superheater outlet steam temperature
especially during startups.
The lower loops of hottest superheaters can be made of austenitic material, with better corrosion
resistance. The steam velocity in the hottest superheater tubes is high, decreasing the tube surface
temperature. Low tube surface temperatures are essential to prevent superheater corrosion. A high
steam side pressure loss over the hot superheaters ensures uniform steam flow in tube elements.
Current recovery boiler
Recovery boiler evolution is continuing strongly. Maximizing electricity generation is driving
increases in main steam pressures and temperatures. If the main steam pressure is increased to 10.4
MPa and temperature 520
o
C, then the electricity generation from recovery boiler plant increases
about 7 %. For design dry solids load of 4000 tds/d this means an additional 7 MW of electricity.
The current recovery boiler can be much larger than the previous ones. Boilers with over 200 square
meter bottom area have been bought. Largest recovery boilers are challenging circulating fluidized
boilers for the title of largest bio-fuel fired boiler.
The superheater arrangement is designed for optimum heat transfer with extra protection to furnace
radiation. Mill closure and decreased emissions mean higher chloride and potassium contents in
black liquor. Almost all superheaters are placed behind the bullnose to minimize the direct radiative
heat transfer from the furnace. Increasing superheating demand with increasing pressure decreases
the need for boiler bank and water screen arrangement.
The higher main steam outlet temperature requires more heat to be added in the superheating
section. Therefore the furnace outlet gas temperature has increased. The alternative is to
significantly increase superheating surface and decrease boiler bank inlet flue gas. If boiler bank
inlet gas temperature is reduced the average temperature difference between flue gas and steam is
also decreased. This reduces heat transfer and substantially more superheating surface is needed.
This approach has been abandoned because of increased cost. With increasing dry solids content the
furnace exit temperature can safely increase without fear of corrosion caused by carryover.
Increasing recovery boiler main steam temperature affects the corrosion of the superheaters.
Designing for higher recovery boiler main steam pressure increases the design pressure for all boiler
parts. The recovery boiler lower furnace wall temperatures increase with higher operating pressure.
New better but more expensive lower furnace materials are used. The air flow per unit of black
liquor burned in the recovery boiler furnace decreases. Therefore the number of air ports will
decrease.
State of the art and current trends
Recovery boiler design changes slowly. There are however some features that boilers bought today
have in common. State of the art recovery boiler has the following features;
One drum boiler with 3-part superheater and water screen (optional)
Steam design data 9.2 MPa / 490
o
C
Design black liquor dry solids 80% with pressurized heavy liquor storage tank
Liquor temperature control with flash tank, indirect liquor heaters for backup
DNCG combustion in the boiler
Low emissions of TRS, SO
2
and particulates
206
STEAM BOILER TECHNOLOGY Recovery Boilers
Flue gas cleaning with ESP (no scrubbers)
The design changes occurring can be listed. Current trends for recovery boilers are
Higher design pressure and temperature due to increasing demands of power generation
Use of utility boiler methods to increase steam generation
Superheater materials of high-grade alloys
Further increase in black liquor solids towards 90% by concentrators using elevated steam
pressure
Combustion of biological effluent treatment sludge and bark press filtrate effluent
CNCG burner (LVHC gases)
Dissolving tank vent gases returned to the boiler
Advanced air systems for NOx control
Steam generation
Steam generation will depend on recovery boiler design parameters. A rough estimate can be seen
from Figure 17. About 3.5 kg
steam
/kg
BLdry solids
is often used as a base value. Specific steam
production can be used to size the other components in recovery boiler plant.
Both black liquor dry solids and higher heating value affect the steam generation. Also black liquor
sulfidity and main steam values affect the steam generation efficiency. For accurate steam
generation one should always calculate the mass and energy balances.
0
0.5
1
1.5
2
2.5
3
3.5
4
4.5
5
60 65 70 75 80 85
Black liquor dry solids, %
S
t
e
a
m
f
l
o
w
,
k
g
/
k
g
d
s
Mill operating data
Figure 17: Specific steam generation kg
steam
/kg
BLdry solids
as function of black liquor dry solids.
Heat transfer surface design and material selection
When recovery boilers are designed one of the most difficult questions that arise is; what kind of
materials should one use for different parts of the boiler. Corrosion is typically divided into areas
based on location of corrosion; water side corrosion, high temperature corrosion and low
temperature corrosion
Water side corrosion occurs in the steam/water side of the boiler tubes. Most often the cause is
impurities in the feedwater. High temperature corrosion occurs typically in the superheaters. Low
207
STEAM BOILER TECHNOLOGY Recovery Boilers
temperature corrosion occurs in the economizers and air heaters. Low temperature corrosion is often
associated with formation of acidic deposits.
Furnace design and materials
Recovery boiler furnace walls and floors have long been under investigation for better materials.
Especially the floor construction and materials affect the recovery boiler safety [38]. Most of the
critical leaks in the furnace occur in the lowest 3 m of furnace walls. Figure 18 shows some of the
used possibilities for lower furnace construction. The lowest is studding and refractory. Corrosion
protection with studs is excellent, but this solution requires large amount of maintenance and repair
work. The middle picture shows membrane wall with welded corrosion protection of alloyed
material. Welded furnace wall is of comparable price to compound tubing, top, which is the most
used recovery boiler wall construction. All new recovery boilers are of membrane design. Tangent
tubing was phased out late 1980s [3].
It is important to protect the floor tubes from
high temperatures. Proper design of water
circulation lowers maximum temperatures.
Sufficient water flow needs to be maintained
in the tubes to cool them and to remove
created steam bubbles. Usually the
requirement is flow velocities 0.5 m/s in all
tubes.
The floor angle in modern boilers needs to be
upwards with the flow. As bottom tubes are
supported by steel beams they hang a little.
Floor angle helps to avoid parts where steam
bubbles could get stuck. Depending on the
distance between the support tubes, the angle
needs to be from 2.5 to 4 degrees. Smelt
spouts need to be high enough so that all
floor is covered with frozen smelt layer.
Especially critical is the area farthest from
the smelt spouts and the area right in front of
the smelt spouts. In practice it seems that 200
300 mm is enough. Too much height will
cause problems when we try to empty the
bed for shutdown.
Furnace tube materials
Some of the most typical furnace tube
materials are listed in Table 3. Many more
have been tried and for one reason or another
abandoned. Carbon steel was the material of
choice before the compound tubing. Upper
furnace from above the highest air level is
always made from carbon steel. Carbon steel
Figure 18: Different recovery boiler walls: lowest
refractory with studs, middle protective welded
cladding, and highest finned membrane wall made
from composite tubes.
seems to resist most corrosive conditions at oxygen rich conditions. Carbon steel has also been
lately used as floor material, Figure 19. Floors with carbon tube are not susceptible to SCC
208
STEAM BOILER TECHNOLOGY Recovery Boilers
corrosion. It should be noted that bare carbon tubes can not resist firing of black liquor or contact
with the smelt. Some care should be taken when operating recovery boilers with carbon steel floors.
Table 3: Properties of typical floor tube materials.
Carbon
steel
304L Sanicro 38
(Alloy 825)
Sanicro 65
(Alloy 625)
Main elements Fe 20Cr10Ni 20Cr40Ni 20Cr60Ni
Thermal expansion, 10
6
/C 13.5 17.5 14.9 13.9
Thermal cond., W/mC 41 19 16 14
SCC resistance Excellent Low High Excellent
Corrosion resistance Low Moderate Excellent High
Extensive research related to corrosion of different materials in molten polysulfides has been
carried out in Finland. This research showed that Sanicro 38-type composite material had the best
corrosion resistance among the steels studied [39]. Test panels made of Sanicro 38 installed in 1991
and 1994 have not shown any alarming corrosion. Nor have there been any reported cracking found
in recovery boiler bottoms made from Sanicro 38 since 1995. This highly alloyed material seems to
have good corrosion resistance, but it is fairly expensive.
Figure 19: Modern carbon steel furnace bottom (Andritz).
Stainless steel 304L seems to last well in the furnace walls above the char bed. It is very resistant to
sulfidation. SCC in the tubes at the furnace bottom tubes has made manufactures and recovery
boiler owners search for replacement materials in that area [40].
Suppliers current recommendations are to use modified alloys in the front and rear bends and close
to the side walls. To facilitate weld inspection the whole lower furnace is often made of modified
alloys up to and over the primary air ports. The present favorite is Sanicro 38 composite tube. In
addition of high content of chrome and nickel the tube has about the same thermal expansion
coefficient that the carbon steel.
209
STEAM BOILER TECHNOLOGY Recovery Boilers
Sanicro 65 (Alloy 625) composite tubing is another possibility. It has very favorable properties
considering thermal fatigue and stress corrosion cracking. There are some reports of failure. Thus,
the use of 625 needs more study at the moment. Another area under research is the air port cracking
[41]. Primary air ports and smelt openings seem to exhibit cracking. Thermal cycling and smelt
contact are suspected causes.
Use of compound tubing has about 30 year history in recovery boilers. Compound tubing is
expensive and the selection of materials is limited. Some competing alternatives are chromizing of
tubes [42, 43]. Another popular method is spray of plasma coating. Compound surface can also be
replaced by welded surface. Of all above methods quality control is easiest with compound tube.
Membrane materials
Membrane materials should be similar to the tube material used. Carbon steel fin is used in the case
of carbon steel tubes. Either composite membrane or totally stainless steel membrane is used in case
of composite floor tubing.
Fins receive thermal radiation and need to conduct heat to the tube proper. Fin surface is thus at
higher temperature than the tube surface. In high heat flux areas and with wide fins this can lead to
tube cracking. A composite membrane has better thermal conductivity as compared to solid
material, which is important especially in case of wide tube spacing.
Refractory and studs
Small studs can be welded to tube and then covered with refractory. Refractory is also a fair
corrosion protection. It should be remembered that both refractory and studs need regular
replacement. It is also impossible to inspect a floor for faults after it has been studded. Because of
this neither refractory nor studs is anymore widely used in recovery boilers
Superheater design and materials
Recovery boilers suffer from superheater corrosion. Corrosion is the main problem that limits the
ability of Kraft recovery boiler to produce electricity [44]. In coal fired boilers much higher
superheater temperatures are typically used. In comparison to coal fired boilers Kraft recovery
boilers have higher rates of alkali metals, chloride in gaseous form and often highly reducing
conditions caused by carryover particles On the other hand contents of some high temperature
corrosion causing substances like antimony, vanadium and zinc are typically low.
Loss of tube thickness can be caused by sulfidation, alkali or chloride corrosion. Typically
superheaters exhibit higher corrosion resistance if their tube materials have higher contents of
chromium [45].
Effect of steam outlet temperature
Main steam temperature is the main parameter that affects the choice of superheater materials. The
rule of thumb is to keep the superheater surface temperature below the first melting temperature of
deposits [46]. Corrosion rates in final superheaters are increased because superheater material
temperatures are high. As can be seen there typically is some temperature range where the corrosion
rate is acceptable. Increasing tube temperature by some tens of degrees can significantly increase
corrosion rate.
Steam side heat transfer coefficients in typical recovery boiler superheaters are low. Superheater
surface temperature can be tens of degrees higher than the bulk steam temperature. It can easily be
seen that surface temperatures and thus corrosion rates are greatly affected by superheater
210
STEAM BOILER TECHNOLOGY Recovery Boilers
positioning. Furnace radiation can effectively be reduced by placing a screen to block radiation heat
flux. Therefore placing the hottest superheaters behind the nose or screen will significantly decrease
corrosion.
Typical materials
Typical primary superheater materials, when they are protected from direct furnace radiation are
carbon steel. Secondary and tertiary superheater materials contain often 1 to 3% Cr. These kinds of
materials are easy to weld and have good corrosion protection. T22/10CrMo910 material can
usually be used up to 495
o
C steam outlet temperatures [47]. With higher temperatures and higher
chloride and potassium contents in the black liquor it is advisable to use higher chromium
containing tubes.
Figure 20: Effect of chromium content on corrosion rate in laboratory tests. [48]
Fujisaki et al. [48] found that recovery boiler
superheater corrosion is much reduced when
chrome content of the superheater tube is
increased, Figure 20. Similar trend was found
from Swedish studies in Norrsundet recovery
boiler [49]. They found that alloyed austenitic
materials 304L and Sanicro 28 had much better
corrosion resistance than high alloyed ferritic
materials SS2216 and X20. Stainless steel lower
bends in hottest superheaters have been used for
tens of years.
Sealing the roof
Superheater tubes and the furnace roof need to
for a gas tight construction. This is usually done
by box made of steel plate, Figure 21. If the
sealing is not tight or leaks corrosive salt builds
on top of the roof. Superheaters need to be
Figure 21: Superheater roof seal box
arrangement.
211
STEAM BOILER TECHNOLOGY Recovery Boilers
supported. Hanger rods are tied to seal box. Individual tubes hang from horizontal supports inside
the box. Thermal movement needs to be accounted for. This means that superheater tubes can not
hang from headers.
Boiler bank design and materials
Two drum boiler banks in recovery boilers suffer form mud drum corrosion [43]. This type of
corrosion is caused by steam from sootblowing wetting the salt at tube joints in lower drum. The
progress of the near drum corrosion can be monitored with ultrasonic equipment [50].One
problematic failure type is caused by vibrations from sootblowing. The longer the free tube length
the higher the resulting stress at joins. Industry practice states that maximum length of free tubes is
some 8 meters. Typically longer tubes are too flexible and will vibrate too much. This will create
cracks and faults in few years.
Finned design causes temperature differences
between fin and tube. This will create high
stresses at fin ends. To prevent these stresses cut
fins are preferred, Figure 22.
Some plugging problems have been reported on
the lower end of the boiler bank [3]. If lower
headers are located too close to each other they
trap falling material. Placing a sootblower close
to the lower end is also critical.
Economizer design and materials
Modern economizers are of vertical design.
Earliest horizontal economizers had severe
plugging problems and were replaced by cross
flow design. Cross flow economizer had lower
heat transfer coefficients and was more prone to
plugging than the modern vertical economizer.
In economizers the loss of tube thickness can be
caused by gas side corrosion; sulfidation and
acid dew point corrosion or water side erosion
corrosion.
Figure 22: Upper end of vertical flow boiler
generating bank showing left straight fin and
right cut fin, which minimizes thermal stresses
around weld. [51]
Lower ends of economizers in recovery boilers suffer from water side erosion corrosion. Typically
the symptoms are worst in the first few meters of economizer tube.
Recovery boiler economizers have hundreds of weld joints. Each weld even after inspection is
potentially problematic. Therefore the preference was to avoid unnecessary welds and use only
continuous tubes without butt welds. Largest boilers have economizer lengths of 27 meters. Carbon
steel tubes maximum length is some 23 meters. So in the newest boilers this preference can not be
adhered to. Attention should be paid to qualification of welds in economizer tube joints.
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STEAM BOILER TECHNOLOGY Recovery Boilers
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th
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213
STEAM BOILER TECHNOLOGY Recovery Boilers
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