APPENDIKS

VII. Analisa dengan Spektrofotometer Sinar Tampak

A!br0ken!!
Preparasi larutan
- Pembuatan larutan kalium sulfat 100 ppm, 250 mL
Diketahui : ppm = 100 ppm
V

= 250 mL

Dijawab :
mg
ppm = L
mg
100 = 0,25
25
= mg
0,025 = gr
gr
mol = BM
0,025
mol = 96
= 2,604.10-4
Mol x BM = gr
2,604.10-4 x 174
= 0,045 gram
Jadi, untuk membuat larutan kalium sulfat 100 ppm sebanyak 250 mL
diperlukan kalium sulfat sebanyak 0,045 gram
- Pembuatan larutan asam klorida 2 M sebanyak 50 mL
Diketahui : M
=2M
V
= 50 mL
Dijawab :
% 1000
M
BM
1,19 0,37 1000
M
36,5
M = 12,063

V1.M1
V1. 12,063

= V2.M2
= 50.2

V1

= 8,2898 mL

Jadi, untuk membuat larutan asam klorida 2 M sebanyak 50 mL dibutuhkan

8,2898 mL asam klorida 37%
B!br0ken!!
Pengenceran
Diketahui
: ppm = 100 ppm
V2
= 50 mL
Ppm2 = 5 ppm, 20 ppm, 35 ppm, 50 ppm, 65 ppm, 80 ppm
Dijawab
:
1. ppm1.V1 = ppm2.V2
100.V1 = 5.50
V1
= 2,5 mL
2. ppm1.V1 = ppm2.V2
100.V1 = 20.50
V1
= 10 mL
3. ppm1.V1 = ppm2.V2
100.V1 = 35.50
V1
= 17,5 mL
4. ppm1.V1 = ppm2.V2
100.V1 = 50.50
V1
= 25 mL
5. ppm1.V1 = ppm2.V2
100.V1 = 65.50
V1
= 32,5 mL
6. ppm1.V1 = ppm2.V2
100.V1 = 80.50
V1
= 40 mL
C!br0ken!!
Penentuan Gelombang Maksimal
Diketahui

Dijawab

D!br0ken!!

Diketahui

Dijawab

: = 420 nm
%T = 16,3
:

%T
100
A =
16,3
log
100
=
= 0,7878
log

Kurva Kalibrasi
: ppm = 5 ppm
%T = 86,6

:A

log

%T
100

86,6
100
=
= 0,0625
: %T air sampel = 95,3
%T
log
100
: A=
95,3
log
100
=
= 0,02091
Penetuan kadar sulfat dalam air sampel
log

Diketahui
Dijawab

E!br0ken!!

ppm (X)
5

A (Y)

X2

X.Y

0,0625

25

0,3125

20

0,2125

400

4,2500

35

0,3478

1225

12,1730

50

0,4685

2500

24,2500

65

0,5622

4225

36,5430

80

0,6576

6400

52,6080

= 255
Sampel
X

a=

= 1,0224
= 420
n ( XY ) ( X ) (Y)
Y

2
X

= 14775
A = 0,0209

n ( X2 ) -(X )2
6 ( 130,1365 )( 225 ) (1,0224)
=
2
6 ( 14775 ) -(225)
550,779
=
38025
= 0,0145
( X 2 ) ( Y ) - (X)(XY)
b=
n ( X2 ) -(X )2
( 14775 )( 1,0224 ) - (225)(130,1365)
=
2
6 ( 14775 ) -(225)
14174,7525
=
38025
= -0,3728
Persamaan garis regresi
Y= a+ b

XY

= 130,1365

0,0209 = 0,0145(x) + (-0,3728)

0,0145(x) = 0,3937
x = 27,1517
Jadi, kadar SO4 dalam air sampel (air PDAM) sebanyak 27,1517 ppm