Bi tp chng ANCOL - n thi i hc Ti liu lu hnh ni b

GV: Nguyn Ph Hot Nm hc: 2010 - 2011

Cu 1 (C-07). Cho cc cht c cng thc cu to nh sau: HOCH
2
-CH
2
OH (X); HOCH
2
-CH
2
-CH
2
OH
(Y); HOCH
2
-CHOH-CH
2
OH (Z); CH
3
-CH
2
-O-CH
2
-CH
3
(R); CH
3
-CHOH-CH
2
OH (T). Nhng cht tc
dng c vi Cu(OH)
2
to thnh dung dch mu xanh lam l
A. X, Y, R, T. B. X, Z, T. C. Z, R, T. D. X, Y, Z, T.
Cu 2 (C-07). C bao nhiu ru (ancol) bc 2, no, n chc, mch h l ng phn cu to ca nhau
m phn t ca chng c phn trm khi lng cacbon bng 68,18%?
A. 2. B. 3. C. 4. D. 5.
Cu 3 (C-07). Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H
2
SO
4
lm xc
tc) thu c hn hp Z gm hai ru (ancol) X v Y. t chy hon ton 1,06 gam hn hp Z sau
hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng
ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l
A. C
2
H
5
OH v C
3
H
7
OH. B. C
3
H
7
OH v C
4
H
9
OH.
C. C
2
H
5
OH v C
4
H
9
OH. D. C
4
H
9
OH v C
5
H
11
OH.
Cu 4 (B-2010). C bao nhiu cht hu c mch h dng iu ch 4-metylpentan-2-ol ch bng phn
ng cng H
2
(xc tc Ni, t
0
)?
A. 3 B. 5 C. 2 D. 4
Cu 5 (B-2010). t chy hon ton mt lng hn hp X gm 2 ancol (u no, a chc, mch h, c
cng s nhm -OH) cn va V lt kh O
2
, thu c 11,2 lt kh CO
2
va 12,6 gam H
2
O (cc th tch
kh o ktc). i tr ca V l
A. 14,56 B. 15,68 C. 11,20 D. 4,48

Cu 6 (CA-2008): t chy hon ton mt ru (ancol) a chc, mch h X, thu c H
2
O v CO
2
vi t l s mol tng ng l 3:2. Cng thc phn t ca X l
A. C
2
H
6
O
2
. B. C
2
H
6
O. C. C
3
H
8
O
2
. D. C
4
H
10
O
2
.
Cu 7 (CA-2008): t chy hon ton hn hp M gm hai ru (ancol) X v Y l ng ng k tip
ca nhau, thu c 0,3 mol CO
2
v 0,425 mol H
2
O. Mt khc, cho 0,25 mol hn hp M tc dng vi
Na (d), thu c cha n 0,15 mol H
2
. Cng thc phn t ca X, Y l:
A. C
2
H
6
O
2
, C
3
H
8
O
2
. B. C
2
H
6
O, CH
4
O. C. C
3
H
6
O, C
4
H
8
O. D. C
2
H
6
O, C
3
H
8
O.
Cu 8 (A-2008): Khi tch nc t ru (ancol) 3-metylbutanol-2 (hay 3-metylbutan-2-ol), sn phm
chnh thu c l
A. 3-metylbuten-1 (hay 3-metylbut-1-en). B. 2-metylbuten-2 (hay 2-metylbut-2-en).
C. 3-metylbuten-2 (hay 3-metylbut-2-en). D. 2-metylbuten-3 (hay 2-metylbut-3-en).
Cu 9 (A-2008): Khi phn tch thnh phn mt ru (ancol) n chc X th thu c kt qu:
tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ru (ancol) ng
vi cng thc phn t ca X l
A. 3. B. 4. C. 2. D. 1.
Cu 10 (B-2009): Cho cc hp cht sau:
(a) HOCH
2
-CH
2
OH. (b) HOCH
2
-CH
2
-CH
2
OH. (c) HOCH
2
-CH(OH)-CH
2
OH.
(d) CH
3
-CH(OH)-CH
2
OH. (e) CH
3
-CH
2
OH. (f) CH
3
-O-CH
2
CH
3
.
Cc cht u tc dng c vi Na, Cu(OH)
2
l:
A. (a), (b), (c). B. (c), (d), (f). C. (a), (c), (d). D. (c), (d), (e).
Cu 11 (A-2009): Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h thu c V
lt kh CO
2
( ktc) v a gam H
2
O. Biu thc lin h gia m, a v V l:
A.
5, 6
V
m a B. 2
11, 2
V
m a C. 2
22, 4
V
m a D.
5, 6
V
m a
Cu 12 (A-2009): un nng hn hp hai ancol n chc, mch h vi H
2
SO
4
c, thu c hn hp
gm cc ete. Ly 7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO
2
(
ktc) v 7,2 gam H
2
O. Hai ancol l
A. CH
3
OH v CH
2
=CH-CH
2
-OH. B. C
2
H
5
OH v CH
2
=CH-CH
2
-OH.
C. CH
3
OH v C
3
H
7
OH. D. C
2
H
5
OH v CH
3
OH.
Cu 13 (A-2009): Cho hn hp X gm hai ancol a chc, mch h, thuc cng dy ng ng. t
chy hon ton hn hp X, thu c CO
2
v H
2
O c t l mol tng ng l 3 : 4. Hai ancol l
A. C
2
H
4
(OH)
2
v C
3
H
6
(OH)
2
. B. C
2
H
5
OH v C
4
H
9
OH.
C. C
2
H
4
(OH)
2
v C
4
H
8
(OH)
2
. D. C
3
H
5
(OH)
3
v C
4
H
7
(OH)
3
.
ANCOL
Bi tp chng ANCOL - n thi i hc Ti liu lu hnh ni b


GV: Nguyn Ph Hot Nm hc: 2010 - 2011
Cu 14 (A-2009): t chy hon ton 0,2 mol mt ancol X no, mch h cn va 17,92 lt kh O
2
(
ktc). Mt khc, nu cho 0,1 mol X tc dng va vi m gam Cu(OH)
2
th to thnh dung dch c
mu xanh lam. Gi tr ca m v tn gi ca X tng ng l
A. 4,9 v propan-1,2-iol. B. 9,8 v propan-1,2-iol.
C. 4,9 v glixerol. D. 4,9 v propan-1,3-iol.
Cu 15: Cng thc phn t tng qut ca ru 2 chc c 1 ni i trong gc hirocacbon l
A. C
n
H
2n + 2
O
2
. B. C
n
H
2n - 2
O
2
. C. C
n
H
2n
O
2
. D. C
n
H
2n 2a
O
2
.
Cu 16: Ancol etylic c nhit si cao hn imetyl ete l do
A. ancol etylic c cha nhm OH. B. nhm -OH ca ancol b phn cc.
C. gia cc phn t ancol c lin kt hiro. D. ancol etylic tan v hn trong nc.
Cu 17: Ancol etylic tan v hn trong nc l do
A. ru etylic c cha nhm OH. B. gia ru v nc to c lin kt hiro.
C. nhm -OH ca ru b phn cc. D. nc l dung mi phn cc.
Cu 18: Theo danh php IUPAC, hp cht (CH
3
)
2
C=CHCH
2
OH c tn gi l
A. 3-metylbut-2 en-1-ol. B. 2- metylbut-2-en-4-ol.
C. pent-2-en-1-ol. D. ancol isopent-2-en-1-ylic.
Cu 19: Cht hu c X c cng thc phn t l C
4
H
10
O. S lng cc ng phn ca X c phn ng vi
Na l
A. 4. B.5. C. 6. D.7.
Cu 20: Khi t chy hon ton 1 ancol thu c
2 2
CO H O
n n . Ancol l
A. ancol no, n chc. B. ancol no.
C. ancol khng no, a chc. D. ancol khng no.
Cu 21: Ch dng cc cht no di y phn bit 2 ancol ng phn c cng CTPT l C
3
H
7
OH?
A. Na v H
2
SO
4
c. B. Na v CuO.
C. CuO v dung dch AgNO
3
/NH
3
. D. Na v dung dch AgNO
3
/NH
3
.
Cu 22: Ch dng ho cht no sau y phn bit hai ng phn khc chc c CTPT l C
3
H
8
O?
A. Al. B. Cu(OH)
2
. C. CuO. D. dd AgNO
3
/NH
3
.
Cu 23: S lng ng phn ancol bc 2 c cng CTPT C
5
H
12
O l
A. 2. B. 3. C. 4. D. 5.
Cu 24: S lng ng phn c cng CTPT l C
5
H
12
O, khi oxi ho bng CuO (t
0
) to sn phm c phn
ng trng gng l
A. 2. B. 3. C. 4. D. 5.
Cu 25: Cho 4 ancol sau: C
2
H
5
OH, C
2
H
4
(OH)
2
, C
3
H
5
(OH)
3
, HO-CH
2
-CH
2
-CH
2
-OH. Ancol khng ho
tan c Cu(OH)
2
l
A. C
2
H
4
(OH)
2
v HO-CH
2
-CH
2
-CH
2
-OH. B. C
2
H
5
OH v C
2
H
4
(OH)
2
.
C. C
2
H
5
OH v HO-CH
2
-CH
2
-CH
2
-OH. D. Ch c C
2
H
5
OH.
Cu 26: Cht hu c X mch h, c ng phn cis - trans c CTPT C
4
H
8
O, X lm mt mu dung dch
Br
2
v tc dng vi Na gii phng kh H
2
. X c cu to l
A. CH
2
=CH-CH
2
-CH
2
OH. B. CH
3
-CH=CH-CH
2
OH.
C. CH
2
=C(CH
3
)-CH
2
OH. D. CH
3
-CH
2
-CH=CH-OH.
Cu 27: Ba ancol X, Y, Z u bn v khng phi l ng phn ca nhau. t chy hon ton mi cht
u thu c CO
2
v H
2
O vi t l s mol 3 : 4. CTPT ca ba ancol l
A. C
3
H
8
O; C
3
H
8
O
2
; C
3
H
8
O
3
. B. C
3
H
8
O; C
3
H
8
O
2
; C
3
H
8
O
4
.
C. C
3
H
6
O; C
3
H
6
O
2
; C
3
H
6
O
3
. D. C
3
H
8
O; C
4
H
8
O; C
5
H
8
O.
Cu 28: Mt ancol no, a chc X c cng thc tng qut: C
X
H
Y
O
Z
(y=2x+z). X c t khi hi so vi
khng kh nh hn 3 v KHN tc dng vi Cu(OH)
2
. Cng thc ca X l
A. HO-CH
2
-CH
2
OH. B. CH
2
(OH)-CH(OH)-CH
3
.
C. CH
2
(OH)-CH(OH)- CH
2
OH. D. HO-CH
2
-CH
2
-CH
2
OH.
Cu 29: Ancol no, a chc X c cng thc n gin nht l C
2
H
5
O. X c CTPT l
A. C
4
H
10
O
2
. B. C
6
H
15
O
3
. C. C
2
H
5
O. D. C
8
H
20
O
4
.
Cu 30: Khi un nng CH
3
CH
2
CH(OH)CH
3
(butan-2-ol ) vi H
2
SO
4
c, 170
0
C th thu c sn phm
chnh l
A. but-1-en. B. but-2-en. C. ietyl ete. D. butanal.
Cu 31: Cho cc ancol sau: CH
3
-CH
2
-CH
2
-OH (1); (CH
3
)
2
CH-OH (2); CH
3
-CH(OH)-CH
2
-OH (3);
CH
3
-CH(OH)-C(CH
3
)
3
(4). Dy gm cc ancol khi tch nc ch cho mt olefin duy nht l
A. (1), (2). B. (1), (2), (3). C. (1), (2), (4). D. (2), (3).
Bi tp chng ANCOL - n thi i hc Ti liu lu hnh ni b


GV: Nguyn Ph Hot Nm hc: 2010 - 2011
Cu 32: Khi cho etanol i qua hn hp oxit ZnO v MgO 450
0
C th thu c sn phm chnh c cng
thc l
A. C
2
H
5
OC
2
H
5
. B. CH
2
=CH-CH=CH
2
.
C. CH
2
=CH-CH
2
-CH
3
. D. CH
2
=CH
2
.
Cu 33 (B-2007): X l ancol (ru) no, mch h. t chy hon ton 0,05 mol X cn 5,6 gam oxi, thu
c hi nc v 6,6 gam CO
2
. Cng thc ca X l
A. C
3
H
5
(OH)
3
. B. C
3
H
6
(OH)
2
. C. C
2
H
4
(OH)
2
. D. C
3
H
7
OH.
Cu 34 (A-2007): Cho 15,6 gam hn hp 2 ancol (ru) n chc, k tip nhau trong dy ng ng tc
dng ht vi 9,2 gam Na, thu c 24,5 gam cht rn. Hai ancol l
A. CH
3
OH v C
2
H
5
OH. B. C
2
H
5
OH v C
3
H
7
OH.
C. C
3
H
5
OH v C
4
H
7
OH. D. C
3
H
7
OH v C
4
H
9
OH.
Cu 35: t chy hon ton m gam hn hp hai ancol n chc A v B thuc cng mt dy ng ng,
ngi ta thu c 70,4 gam CO
2
v 39,6 gam H
2
O.i tr ca m l
A. 3,32. B. 33,2. C. 16,6. D. 24,9.
Cu 36: t chy hon ton mt ancol n chc X thu c 4,4 gam CO
2
v 3,6 gam H
2
O. Cng thc
phn t ca X l
A. CH
3
OH. B. C
2
H
5
OH. C. C
3
H
5
OH. D. C
3
H
7
OH.
Cu 37: t chy hon ton 0,1 mol mt ancol no, mch h cn 5,6 lt kh O
2
(ktc). Cng thc phn t
ca ancol l
A. CH
4
O. B. C
2
H
6
O. C. C
2
H
6
O
2
. D. C
2
H
8
O
2
.
Cu 38: Cho 2,84 gam hn hp X gm hai ancol n chc, l ng ng k tip tc dng va vi Na
to ra 4,6 gam cht rn v V lt H
2
(ktc). i tr ca V l
A. 2,240. B. 1,120. C. 1,792. D. 0,896.
Cu 39: t chy mt ru a chc, thu c H
2
O v CO
2
vi t l mol tng ng l 3:2. CTPT ca
ru l
A. C
5
H
12
O
2
. B. C
4
H
10
O
2
. C. C
3
H
8
O
2
. D. C
2
H
6
O
2
.
Cu 40: Cho 10,6 gam hn hp X gm hai ancol no n chc l ng ng lin tip tc dng vi Na d
thu c 2,24 lt kh H
2
(ktc). Cng thc ca 2 ru trong X l
A. CH
3
OH v C
2
H
5
OH. B. C
3
H
7
OH v C
2
H
5
OH.
C. C
3
H
7
OH v C
4
H
9
OH. D. C
4
H
9
OH v C
5
H
11
OH.
Cu 41: Cho 9,2gam glixerol tc dng vi Na d thu c V lt kh H
2
0
0
C v 1,2 atm. i tr ca V l
A. 2,798. B. 2,6. C. 2,898. D. 2,7.
Cu 42: Cho ancol X c CTCT thu gn l CH
3
-CH(CH
3
)-CH(OH)-CH
2
-CH
3
.

Danh php IUPAC ca X
l
A. 2-metyl pentan-3-ol. B. 2-metyl pentanol-3.
C. 4-metyl pentan-3-ol. D. 4-metyl pentanol-3.
Cu 43: Tch nc mt hp cht X thu c but-1-en duy nht. Danh php quc t ca X l
A. 2-metyl propan-1-ol. B. butan-1-ol.
C. butan-2-ol. D. pentan-2-ol.
Cu 44: Cho mt ru n chc X qua bnh ng Na d thu c kh Y v khi lng bnh tng 3,1 g.
Ton b lng kh Y kh c (8/3) gam Fe
2
O
3
nhit cao thu c Fe. Cng thc ca X l.
A. CH
3
OH. B. C
2
H
5
OH. C. C
3
H
5
OH. D. C
3
H
7
OH.
Cu 45: Cng thc tng qut ca ru no, 3 chc l
A. C
n
H
2n-3
(OH)
2
. B. C
n
H
2n+1
(OH)
3
. C. C
n
H
2n-1
(OH)
3
. D. C
n
H
2n+2
(OH)
3
.
Cu 46 (A-2010). t chy hon ton m gam hn hp 3 ancol n chc, thuc cng dy ng ng, thu
c 3,808 lt kh CO
2
(ktc) v 5,4 gam H
2
O. i tr ca m l
A. 5,42. B. 5,72. C. 4,72. D. 7,42.
Cu 47 (A-2010). Anken X hp nc to thnh 3-etylpentan-3-ol. Tn ca X l
A. 3-etylpent-3-en. B. 2-etylpent-2-en. C. 3-etylpent-2-en. D. 3-etylpent-1-en.
Cu 48 (C-2010). Cho 10 ml dung dch ancol etylic 46
0
phn ng ht vi kim li Na (d), thu c V
lt kh H
2
(ktc). Bit khi lng ring ca ancol etylic nguyn cht bng 0,8 g/ml. i tr ca V l
A. 4,256 B. 0,896 C. 3,360 D. 2,128
Cu 49 (C-2010). ng vi cng thc phn t C
3
H
6
O c bao nhiu hp cht mch h bn khi tc dng
vi kh H
2
(xc tc Ni, t
0
) sinh ra ancol?
A. 3 B. 4 C. 2 D. 1
Bi tp chng ANCOL - n thi i hc Ti liu lu hnh ni b


GV: Nguyn Ph Hot Nm hc: 2010 - 2011
Cu 50 (C-07). t chy hon ton mt ru (ancol) X thu c CO
2
v H
2
O c t l s mol tng
ng l 3 : 4. Th tch kh oxi cn dng t chy X bng 1,5 ln th tch kh CO
2
thu c ( cng
iu kin). Cng thc phn t ca X l
A. C
3
H
8
O
3
. B. C
3
H
4
O. C. C
3
H
8
O
2
. D. C
3
H
8
O.

PHN N TCH NC CA ANCOL (RU) N CHC
Cu 1 (C-07). Khi thc hin phn ng tch nc i vi ru (ancol) X, ch thu c mt anken duy
nht. Oxi ho hon ton mt lng cht X thu c 5,6 lt CO
2
( ktc) v 5,4 gam nc. C bao nhiu
cng thc cu to ph hp vi X?
A. 5. B. 4. C. 3. D. 2.
Cu 2 (B-2010). t chy hon ton m gam hn hp X gm ba ancol (n chc, thuc cng dy ng
ng), thu c 8,96 lt kh CO
2
(ktc) v 11,7 gam H
2
O. Mt khc, nu un nng m gam X vi H
2
SO
4

c th tng khi lng ete ti a thu c l
A. 7,85 gam B. 7,40 gam. C. 6,50 gam. D. 5,60 gam.
Cu 3 (A-2010). Tch nc hn hp gm ancol etylic v ancol Y ch to ra 2 anken. t chy cng s
mol mi ancol th lng nc sinh ra t ancol ny bng 5/3 ln lng nc sinh ra t ancol kia. Ancol Y
l
A. CH
3
-CH
2
-CH(OH)-CH
3
. B. CH
3
-CH
2
-CH
2
-OH.
C. CH
3
-CH
2
-CH
2
-CH
2
-OH. D. CH
3
-CH(OH)-CH
3
.
Cu 4 (CA-08): Khi un nng hn hp ru (ancol) gm CH
3
OH v C
2
H
5
OH (xc tc H
2
SO
4
c,
140
0
C) th s ete thu c ti a l
A. 4. B. 2. C. 1. D. 3.
Cu 5 (B-08): un nng mt ru (ancol) n chc X vi dung dch H
2
SO
4

c trong iu kin nhit
thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca X l
A. C
3
H
8
O. B. C
2
H
6
O. C. CH
4
O. D. C
4
H
8
O.
Cu 6 (B-08): un nng hn hp gm hai ru (ancol) n chc, mch h, k tip nhau trong dy
ng ng vi H
2
SO
4
c 140
0
C. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba
ete v 1,8 gam nc. Cng thc phn t ca hai ru trn l
A. CH
3
OH v C
2
H
5
OH. B. C
2
H
5
OH v C
3
H
7
OH.
C. C
3
H
5
OH v C
4
H
7
OH. D. C
3
H
7
OH v C
4
H
9
OH.
Cu 7: un nng mt ancol no, n chc X vi H
2
SO
4
c nhit thch hp thu c cht hu c Y.
T khi hi ca Y so vi X l 0,7. CTPT ca X l
A. C
2
H
5
OH. B. C
3
H
7
OH. C. C
4
H
9
OH. D. C
5
H
11
OH.
Cu 8: Thc hin phn ng tch nc hn hp X gm ba ru vi H
2
SO
4
c 170
0
C, thu c sn
phm ch gm hai anken v nc. Hn hp X gm
A. ba ru no, n chc C. hai ru ng phn v mt ru l CH
3
OH.
B. ba ru no a chc. D. ba ru no, n chc trong c hai ru l ng
phn.
Cu 9: Cho hn hp A gm hai ru no, n chc l ng ng lin tip tch H
2
O (H
2
SO
4
c, 140
0
C )
thu c ba ete. Trong c mt ete c khi lng phn t bng khi lng phn t ca mt trong hai
ru. A gm
A. CH
3
OH.v C
2
H
5
OH. B. C
2
H
5
OH v C
3
H
7
OH.
C. C
2
H
5
OH v C
4
H
9
OH. D. C
3
H
7
OH v C
4
H
9
OH.
Cu 10: un nng 15,2 gam hn hp 2 ru no n chc, l ng ng k tip vi H
2
SO
4
c 140
O
C,
thu c 12,5 gam hn hp 3 ete (h = 100%). Cng thc ca 2 ru l
A. C
3
H
7
OH v C
4
H
9
OH. B. CH
3
OH v C
2
H
5
OH.
C. C
2
H
5
OH v C
3
H
7
OH. D. CH
3
OH v C
3
H
7
OH.
Cu 11: Thc hin phn ng tch nc mt ancol no n chc X vi H
2
SO
4
c nhit thch hp,
thu c cht hu c Y. T khi hi ca Y so vi X l 1,4375. Cng thc ca X l
A. C
2
H
5
OH. B. C
3
H
7
OH. C. CH
3
OH. D. C
4
H
9
OH.
Cu 12: Chia 27,6 gam hn hp 3 ancol n chc thnh 2 phn bng nhau. Phn 1 cho tc dng ht vi
Na, thu c 3,36 lt kh H
2
(ktc). Phn 2 tch nc thu c m gam hn hp 6 ete (h=100%). i tr
ca m l
A. 24,9. B. 11,1. C. 8,4. D. 22,2.
Bi tp chng ANCOL - n thi i hc Ti liu lu hnh ni b


GV: Nguyn Ph Hot Nm hc: 2010 - 2011
Cu 13: Chia hn hp 2 ru no n chc thnh 2 phn bng nhau. t chy hon ton phn 1, thu
c 2,24 lt kh CO
2
(ktc). Phn 2 tch nc hon ton thu c 2 anken. S gam H
2
O to thnh khi
t chy hon ton 2 anken trn l.
A. 3,6. B. 2,4. C. 1,8. D. 1,2.
Cu 14: t chy hon ton hn hp X gm 2 ancol (ru) n chc, thuc cng dy ng ng, thu
c 13,2 gam CO
2
v 8,28 gam H
2
O. Nu cho X tch nc to ete (h=100%) th khi lng 3 ete thu
c l
A. 42,81. B. 5,64. C. 4,20. D. 70,50.
Cu 15: Cho 15,6 gam hn hp 2 ancol n chc qua bnh ng Na (d) thy khi lng bnh tng 15,2
gam. Cng lng hn hp trn, nu tch nc to ete (h = 100%) th s gam ete thu c l
A. 12,0. B. 8,4. C. 10,2. D. 14,4.
Cu 16: un nng mt ancol n chc X vi H
2
SO
4
c nhit thch hp thu c cht hu c Y v
nc. T khi hi ca Y so vi X l 1,609. Cng thc ca X l
A. CH
3
OH. B. C
3
H
7
OH C. C
3
H
5
OH. D. C
2
H
5
OH.
Cu 17: un nng 12,90 gam hn hp X gm 2 ru no, n chc, bc 1, l ng ng k tip trong
H
2
SO
4
c 140
o
C thu c 10,65 gam hn hp Y gm 3 ete (h = 100%). Tn gi ca 2 ru trong X
l
A. metanol v etanol. B. etanol v propan-2-ol.
C. etanol v propan-1-ol. D. propan-1-ol v butan-1-ol.
Cu 18: Cho 3-metylbutan-2-ol tch nc iu kin thch hp, ri ly anken thu c tc dng vi
nc (xc tc axit) th thu c ancol (ru) X. Cc sn phm u l sn phm chnh. Tn gi ca X l
A. 3-metylbutan-2-ol. B. 2-metylbutan-2-ol.
C. 3-metylbutan-1-ol. D. 2-metylbutan-3-ol.
Cu 19: Cho m gam hn hp 2 ru no, n chc, bc 1, l ng ng k tip tc dng vi Na d thu
c 1,68 lt kh 0
o
C; 2 atm. Mt khc cng un m gam hn hp trn 140
o
C vi H
2
SO
4
c thu c
12,5 gam hn hp 3 ete (h=100%). Tn gi 2 ru trong X l
A. metanol v etanol. B. etanol v propan-1-ol.
C. propan-1-ol v butan-1-ol. D. pentan-1-ol v butan-1-ol.
Cu 20: un nng 16,6 gam hn hp X gm 3 ru no n chc vi H
2
SO
4
c 140
o
C thu c 13,9
gam hn hp 6 ete c s mol bng nhau. Mt khc, un nng X vi H
2
SO
4
c 180
o
C thu c sn
phm ch gm 2 olefin v nc. Cc phn ng xy ra hon ton. Tn gi ca 3 ru trong X l
A. metanol, etanol v propan-1-ol. B. etanol, propan-2-ol v propan-1-ol.
C. propan-2-ol, butan-1-ol v propan-1-ol. D. etanol, butan-1-ol v butan-2-ol.
Cu 21: t chy hon ton 20,64 gam hn hp X gm 3 ru n chc, thuc cng dy ng ng, thu
c 42,24 gam CO
2
v 24,28 gam H
2
O. Mt khc, un nng 20,64 gam hn hp X vi H
2
SO
4
c
140
o
C (vi hiu sut phn ng ca mi ru l 50%), th thu c m gam hn hp 6 ete. i tr ca m
l
A. 17,04. B. 6,72. C. 8,52. D. 18,84.
Cu 22: Cho 8,5 gam gam hn hp X gm 3 ru n chc tc dng ht vi Na, thu c 2,8 lt kh H
2

(ktc). Mt khc, un nng 8,5 gam hn hp X vi H
2
SO
4
c 140
o
C (vi hiu sut phn ng ca mi
ru l 80%), th thu c m gam hn hp 6 ete. i tr ca m l
A. 6,7. B. 5,0. C. 7,6. D. 8,0.
Cu 23: t chy hon ton mt ancol n chc X thu c 4,4 gam CO
2
v 3,6 gam H
2
O. Nu cho
lng X trn tch nc to ete (h=100%) th s gam ete thu c l
A. 3,2. B.1,4. C. 2,3. D. 4,1.
Cu 24: Cho 15,6 gam hn hp X gm 2 ancol (ru) n chc, k tip nhau trong dy ng ng tc
dng ht vi 9,2 gam Na, thu c 24,5 gam cht rn. Nu cho 15,6 gam X tch nc to ete (h =
100%) th s gam ete thu c l
A. 10,20. B. 14,25. C. 12,90. D. 13,75.
Cu 25 (A-07): Khi tch nc t mt cht X c cng thc phn t C
4
H
10
O to thnh 3 anken l ng
phn ca nhau (tnh c ng phn hnh hc). Cng thc cu to thu gn ca X l
A. CH
3
CH(OH)CH
2
CH
3
. B. (CH
3
)
3
COH.
C. CH
3
OCH
2
CH
2
CH
3
. D. CH
3
CH(CH
3
)CH
2
OH.
Cu 26: un nng 2,3-imetylpentan-2-ol vi H
2
SO
4
c, 170
0
C, thu c sn phm chnh l
A. (CH
3
)
2
C=C(CH
3
)-CH
2
-CH
3
. B. CH
3
-CH=C(CH
3
)-CH(CH
3
)
2
. .
C. CH
3
-CH
2
-CH(CH
3
)-C(CH
3
)=CH
2
. D. CH
2
=CH-CH(CH
3
)-CH(CH
3
)
2
.

Bi tp chng ANCOL - n thi i hc Ti liu lu hnh ni b


GV: Nguyn Ph Hot Nm hc: 2010 - 2011
OXI HO ANCOL (RU) BC 1, 2
Cu 1 (B-2010). Hn hp X gm 1 ancol v 2 sn phm hp nc ca propen. T khi hi ca X so vi
hiro bng 23. Cho m gam X i qua ng s ng CuO (d) nung nng. Sau khi cc phn ng xy ra
hon ton, thu c hn hp Y gm 3 cht hu c v hi nc, khi lng ng s gim 3,2 gam. Cho Y
tc dng hon ton vi lng d dung dch AgNO
3
trong NH
3
, to ra 48,6 gam Ag. Phn trm khi
lng ca propan-1-ol trong X l
A. 65.2% B. 16.3% C. 48.9% D. 83.7%
Cu 2 (A-2010). Oxi ho ht 2,2 gam hn hp hai ancol n chc thnh anehit cn va 4,8 gam
CuO. Cho ton b lng anehit trn tc dng vi lng d dung dch AgNO
3
trong NH
3
, thu c
23,76 gam Ag. Hai ancol l
A. CH
3
OH, C
2
H
5
CH
2
OH. B. CH
3
OH, C
2
H
5
OH.
C. C
2
H
5
OH, C
3
H
7
CH
2
OH. D. C
2
H
5
OH, C
2
H
5
CH
2
OH.
Cu 3 (CA-08): Oxi ho ancol n chc X bng CuO (un nng), sinh ra mt sn phm hu c duy
nht l xeton Y (t khi hi ca Y so vi kh hiro bng 29). Cng thc cu to ca X l
A. CH
3
-CHOH-CH
3
. B. CH
3
-CH
2
-CHOH-CH
3
.
C. CH
3
-CO-CH
3
. D. CH
3
-CH
2
-CH
2
-OH.
Cu 4 (CA-09): Oxi ho m gam etanol thu c hn hp X gm axetanehit, axit axetic, nc v
etanol d. Cho ton b X tc dng vi dung dch NaHCO
3
(d), thu c 0,56 lt kh CO
2
( ktc).
Khi lng etanol b oxi ho to ra axit l
A. 4,60 gam. B. 2,30 gam. C. 5,75 gam. D. 1,15 gam.
Cu 5 (B-2008): Oxi ho 1,2 gam CH
3
OH bng CuO nung nng, sau mt thi gian thu c hn hp
sn phm X (gm HCHO, H
2
O v CH
3
OH d). Cho ton b X tc dng vi lng d Ag
2
O (hoc
AgNO
3
) trong dung dch NH
3
, c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH
3
OH l
A. 76,6%. B. 80,0%. C. 65,5%. D. 70,4%.
Cu 6 (A-2008): Cho m gam hn hp X gm hai ru (ancol) no, n chc, k tip nhau trong dy
ng ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t
khi hi so vi H
2
l 13,75). Cho ton b Y phn ng vi mt lng d Ag
2
O (hoc AgNO
3
) trong
dung dch NH
3
un nng, sinh ra 64,8 gam Ag. Gi tr ca m l
A. 7,8. B. 8,8. C. 7,4. D. 9,2.
Cu 7 (B-2009): Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng.
Oxi ho hon ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c
hn hp sn phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO
3
trong NH
3
, thu c
54 gam Ag. i tr ca m l
A. 15,3. B. 13,5. C. 8,1. D. 8,5.
Cu 8: Cho C
2
H
5
OH qua bnh ng CuO, nung nng thu c hn hp hi X cha ti a
A. 2 cht. B. 3 cht. C. 4 cht. D. 5 cht.
Cu 9: Oxi ho m gam hn hp X gm 2 ancol (ru) n chc, bc 1, l ng ng k tip, thu c
hn hp Y gm anehit (h = 100%). Cho Y tc dng vi lng d Ag
2
O trong dung dch NH
3
, thu c
86,4 gam Ag. Mt khc, nu cho m gam X tc dng ht vi Na th thu c 3,36 lt kh H
2
(ktc). Cng
thc ca 2 ru trong X l
A. CH
3
OH v C
3
H
7
OH. B. CH
3
OH v C
2
H
5
OH.
C. C
2
H
5
OH v C
3
H
7
OH. D. C
3
H
5
OH v C
4
H
7
OH.
Cu 10: Oxi ho 4,96 gam X l mt ancol (ru) n chc bc 1 (h=100%), ri ly anehit thu c
cho tc dng ht vi lng d Ag
2
O trong dung dch NH
3
, thu c 66,96 gam Ag. Cng thc ca X l
A. CH
3
OH. B. C
2
H
5
OH. C. C
3
H
7
OH. D. C
3
H
5
OH.
Cu 11: Cho 12,4 gam hn hp X gm 2 ancol (ru) n chc, bc 1 l ng ng k tip qua H
2
SO
4

c 140
o
C, thu c 9,7 gam hn hp 3 ete. Nu oxi ho X thnh anehit ri cho anehit thu c tc
dng ht vi lng d Ag
2
O trong dung dch NH
3
th thu c m gam Ag. Cc phn ng xy ra hon
ton. Gi tr ca m l
A. 64,8. B. 48,6. C. 86,4. D. 75,6.
Cu 12: Oxi ho hn hp X gm C
2
H
6
O v C
4
H
10
O thu c hn hp Y gm 2 anehit. Cho Y tc dng
vi dung dch AgNO
3
trong NH
3
(d) thu c m gam Ag. Cng lng X nh trn, nu cho tc dng
vi Na d th thu c 1,12 lt kh H
2
(ktc). i tr ca m l.
A. 5,4. B. 10,8. C. 21,6. D. 16,2.
Bi tp chng ANCOL - n thi i hc Ti liu lu hnh ni b


GV: Nguyn Ph Hot Nm hc: 2010 - 2011
Cu 13: Oxi ho mt ancol X c cng thc phn t C
4
H
10
O bng CuO nung nng, thu c cht hu c
Y khng tham gia phn ng trng gng. Tn gi ca X l
A. butan-1-ol. B. butan-2-ol
C. 2-metyl propan-1-ol. D. 2-metyl propan-2-ol.
Cu 14: Oxi ho 18,4 gam C
2
H
5
OH (h = 100%), thu c hn hp X gm anehit, axit v nc. Chia X
thnh 2 phn bng nhau. Phn 1 cho tc dng vi lng d Ag
2
O trong dung dch NH
3
th thu c 16,2
gam Ag. Phn 2 tc dng va vi V lt dung dch NaOH 0,5M. i tr ca V l
A. 0,50. B. 0,65. C. 0,25. D. 0,45.
Cu 15 v 16: Oxi ho X l ru n chc, bc 1 c anehit Y. Hn hp kh v hi sau phn ng
c chia thnh 3 phn bng nhau. Phn 1 cho tc dung vi Na d, thu c 5,6 lt kh H
2
(ktc). Phn
2 cho tc dng vi Ag
2
O trong dung dch NH
3
(d) thu c 64,8 gam Ag. Phn 3 t chy hon ton
thu c 33,6 lt kh (ktc) CO
2
v 27 gam H
2
O.
Cu 15: Tn gi ca X l
A. ru metylic. B. ru etylic. C. ru allylic. D. ru iso-butylic.
Cu 16: Hiu sut qu trnh oxi ha X thnh Y l
A. 40%. B. 50%. C. 60%. D. 70%.
Cu 17: Oxi ho 12,8 gam CH
3
OH (c xt) thu c hn hp sn phm X. Chia X thnh 2 phn bng
nhau. Phn 1 cho tc dng vi Ag
2
O trong dung dch NH
3
d thu c 64,8 gam Ag. Phn 2 phn ng
va vi 30 ml dung dch KOH 2M. Hiu sut qu trnh oxi ho CH
3
OH l
A. 60%. B. 70%. C. 80%. D. 90%.
Cu 18: t chy hon ton 0,01 mol mt ancol (ru) no Y cn 0,025 mol O
2
. Nu oxi ho 0,02 mol Y
thnh anehit (h=100%), ri cho ton b lng anehit thu c tc dng ht vi Ag
2
O trong dung dch
NH
3
th s gam Ag thu c l
A. 4,32. B. 6,48. C. 8,64. D. 2,16.
Cu 19 v 20: Cho 18,8 gam hn hp A gm C
2
H
5
OH v mt ru ng ng X tc dng vi Na d thu
c 5,6 lt kh H
2
(ktc). Oxi ho 18,8 gam A bng CuO, nung nng thu c hn hp B gm 2 anehit (h
= 100%). Cho B tc dng vi Ag
2
O trong dung dch NH
3
(d) thu c m gam Ag.
Cu 19: Tn gi ca X l
A. propan-2-ol. B. metanol. C. propan-1-ol. D. butan-1-ol.
Cu 20: i tr ca m l
A. 86,4. B. 172,8. C. 108,0. D. 64,8.
Cu 21: Hn hp X gm 2 ru no n chc c s nguyn t cacbon chn. Oxi ho a gam X c 2
anehit tng ng. Cho 2 anehit tc dng vi Ag
2
O

trong dung dch NH
3
(d) thu 21,6 gam Ag. Nu
t a gam X th thu c 14,08 gam CO
2
. Bit cc phn ng xy ra hon ton v 1 trong 3 ete l ng
phn ca 1 trong 2 ru. Tn gi ca 2 ru trong X l
A. metanol v etanol. B. etanol v butan-2-ol.
C. etanol v butan-1-ol. D. hexan-1-ol v butan-1-ol.
Cu 22: t chy hon ton m gam mt ancol (ru) n chc X thu c 4,4 gam CO
2
v 3,6 gam
H
2
O. Oxi ho m gam X (c xc tc) thu c hn hp Y (h = 100%). Cho Y tc dng ht vi dung dch
AgNO
3
trong NH
3
thu c 30,24 gam Ag. S mol anehit trong Y l
A. 0,07. B. 0,04. C. 0,06. D. 0,05.
Cu 23: phn bit ancol bc 3 vi ancol bc 1 v bc 2, ngi ta c th dng
A. CuO (t
o
) v dung dch Ag
2
O trong NH
3
. B. CuO (t
o
).
C. Cu(OH)
2
. D. dung dch H
2
SO
4
c 170
o
C.
Cu 24: Cho 15,6 gam hn hp X gm 2 ancol n chc, bc 1 qua ng cha 35,2 gam CuO (d), nung
nng. Sau khi phn ng hon ton thu c 28,8 gam cht rn v hn hp hi Y c t khi so vi hiro
l
A. 27,5. B. 13,75. C. 55,0. D. 11,0.
Cu 25: Chia hn hp A gm CH
3
OH v mt ru ng ng (X) thnh 3 phn bng nhau. Phn 1 cho tc
dng vi Na d thu c 336 ml H
2
(ktc). Oxi ho phn 2 thnh anehit (h=100%), sau cho tc dng Ag
2
O
trong NH
3
d thu c 10,8 gam Ag. Phn 3 t chy hon ton thu c 2,64 gam CO
2
. Cng thc phn t
ca X l
A. C
2
H
6
O. B. C
3
H
8
O. C. C
4
H
10
O. D. C
5
H
12
O.
Cu 26: Chia 30,4 gam hn hp X gm 2 ru n chc thnh 2 phn bng nhau. Cho phn 1 tc dng
vi Na d thu c 3,36 lt H
2
(ktc). Phn 2 cho tc dng hon ton vi CuO nhit cao thu c
hn hp Y cha 2 anehit (h = 100%). Ton b lng Y phn ng ht vi Ag
2
O trong NH
3
thu c
86,4 gam Ag. Tn gi 2 ru trong X l
Bi tp chng ANCOL - n thi i hc Ti liu lu hnh ni b


GV: Nguyn Ph Hot Nm hc: 2010 - 2011
A. metanol v etanol. B. metanol v propan-1-ol.
C. etanol v propan-1-ol. D. propan-1-ol v propan-2-ol.
Cu 27: un nng m gam hn hp X gm CH
3
OH v C
2
H
5
OH vi H
2
SO
4
c 140
O
C thu c 2,7
gam nc. Oxi ho m gam X thnh anehit, ri ly ton b lng anehit thu c cho tc dng vi
dung dch AgNO
3
trong NH
3
(d) thy to thnh 86,4 gam Ag. Cc phn ng xy ra vi hiu sut 100%.
Phn trm khi lng ca C
2
H
5
OH trong X l
A. 25,8%. B. 37,1%. C. 74,2%. D. 62,9%.
Cu 28: t chy hon ton hn hp 2 ru l ng ng k tip thu c 17,6 gam CO
2
v 12,6 gam
H
2
O. Cng lng hn hp , nu oxi ha thnh anehit (h = 100%), sau cho anehit trng gng th
thu c m gam Ag. i tr ca m l
A. 64,8. B. 86,4. C. 108,0. D. 162,0.
Cu 29 (B-07): Cho m gam mt ancol (ru) no, n chc qua bnh ng CuO (d), nung nng. Sau khi
phn ng hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp hi thu c c t khi so
vi hiro l 15,5. i tr ca m l
A. 0,92. B. 0,32. C. 0,64. D. 0,46.
Cu 30: Cho m gam hn hp X gm C
2
H
5
OH v C
2
H
4
(OH)
2
tc dng ht vi Na, thu c 4,48 lt kh
H
2
(ktc). Nu cho m gam X tc dng ht vi CuO, nung nng th khi lng Cu thu c l
A. 6,4 gam. B. 16,0 gam. C. 8,0 gam. D. 12,8 gam.
Cu 31 (C-2010). Oxi ho khng hon ton ancol isopropylic bng CuO nung nng, thu c cht hu
c X. Tn gi ca X l
A. metyl phenyl xeton B. propanal
C. metyl vinyl xeton D. imetyl xeton
Cu 32 (C-2010). Cho 4,6gam mt ancol no, n chc phn ng vi CuO nung nng, thu c 6,2
gam hn hp X gm anehit, nc v ancol d. Cho ton b lng hn hp X phn ng hon ton vi
lng d dung dch AgNO
3
trong NH
3
, un nng, thu c m gam Ag. i tr ca m l
A. 16,2 B. 43,2 C. 10,8 D. 21,6