ACTIVITY COEFFICIENTS OF ACIDS, BASES, AND SALTS

Petr Vanysek
This table gives mean activity coefficients at 25C for molalities in the range 0.1 to 1.0. See the following table for definitions, references, and data
over a wider concentration range.

AgNO3
AlCl3
Al2(SO4)3
BaCl2
BeSO4
CaCl2
CdCl2
Cd(NO3)2
CdSO4
CoCl2
CrCl3
Cr(NO3)3
Cr2(SO4)3
CsBr
CsCl
CsI
CsNO3
CsOH
CsOAc
Cs2SO4
CuCl2
Cu(NO3)2
CuSO4
FeCl2
HBr
HCl
HClO4
HI
HNO3
H2SO4
KBr
KCl
KClO3
K2CrO4
KF
K3Fe(CN)6
K4Fe(CN)6
KH2PO4
KI
KNO3
KOAc
KOH
KSCN
K2SO4
LiBr
LiCl
LiClO4
LiI
LiNO3
LiOH
LiOAc
Li2SO4
MgCl2
MgSO4
MnCl2
MnSO4

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

0.734
0.337
0.035
0.500
0.150
0.518
0.2280
0.513
0.150
0.522
0.331
0.319
0.0458
0.754
0.756
0.754
0.733
0.795
0.799
0.456
0.508
0.511
0.150
0.5185
0.805
0.796
0.803
0.818
0.791
0.2655
0.772
0.770
0.749
0.456
0.775
0.268
0.139
0.731
0.778
0.739
0.796
0.798
0.769
0.441
0.796
0.790
0.812
0.815
0.788
0.760
0.784
0.468
0.529
0.150
0.516
0.150

0.657
0.305
0.0225
0.444
0.109
0.472
0.1638
0.464
0.103
0.479
0.298
0.285
0.0300
0.694
0.694
0.692
0.655
0.761
0.771
0.382
0.455
0.460
0.104
0.473
0.782
0.767
0.778
0.807
0.754
0.2090
0.722
0.718
0.681
0.382
0.727
0.212
0.0993
0.653
0.733
0.663
0.766
0.760
0.716
0.360
0.766
0.757
0.794
0.802
0.752
0.702
0.742
0.398
0.489
0.107
0.469
0.105

0.606
0.302
0.0176
0.419
0.0885
0.455
0.1329
0.442
0.0822
0.463
0.294
0.279
0.0238
0.654
0.656
0.651
0.602
0.744
0.761
0.338
0.429
0.439
0.0829
0.454
0.777
0.756
0.768
0.811
0.735
0.1826
0.693
0.688
0.635
0.340
0.700
0.184
0.0808
0.602
0.707
0.614
0.754
0.742
0.685
0.316
0.756
0.744
0.792
0.804
0.736
0.665
0.721
0.361
0.477
0.0874
0.450
0.0848

0.567
0.313
0.0153
0.405
0.0769
0.448
0.1139
0.430
0.0699
0.459
0.300
0.281
0.0207
0.626
0.628
0.621
0.561
0.739
0.759
0.311
0.417
0.429
0.0704
0.448
0.781
0.755
0.766
0.823
0.725

0.673
0.666
0.599
0.313
0.682
0.167
0.0693
0.561
0.689
0.576
0.750
0.734
0.663
0.286
0.752
0.740
0.798
0.813
0.728
0.638
0.709
0.337
0.475
0.0756
0.442
0.0725

0.536
0.331
0.0143
0.397
0.0692
0.448
0.1006
0.425
0.0615
0.462
0.314
0.291
0.0190
0.603
0.606
0.599
0.528
0.739
0.762
0.291
0.411
0.426
0.0620
0.450
0.789
0.757
0.769
0.839
0.720
0.1557
0.657
0.649
0.568
0.292
0.670
0.155
0.0614
0.529
0.676
0.545
0.751
0.732
0.646
0.264
0.753
0.739
0.808
0.824
0.726
0.617
0.700
0.319
0.481
0.0675
0.440
0.0640

0.509
0.356
0.014
0.391
0.0639
0.453
0.0905
0.423
0.0553
0.470
0.335
0.304
0.0182
0.586
0.589
0.581
0.501
0.742
0.768
0.274
0.409
0.427
0.0559
0.454
0.801
0.763
0.776
0.860
0.717

0.646
0.637
0.541
0.276
0.661
0.146
0.0556
0.501
0.667
0.519
0.754
0.733
0.633
0.246
0.758
0.743
0.820
0.838
0.727
0.599
0.691
0.307
0.491
0.0616
0.443
0.0578

0.485
0.388
0.0142
0.391
0.0600
0.460
0.0827
0.423
0.0505
0.479
0.362
0.322
0.0181
0.571
0.575
0.567
0.478
0.748
0.776
0.262
0.409
0.431
0.0512
0.463
0.815
0.772
0.785
0.883
0.717
0.1417
0.636
0.626
0.518
0.263
0.654
0.140
0.0512
0.477
0.660
0.496
0.759
0.736
0.623
0.232
0.767
0.748
0.834
0.852
0.729
0.585
0.689
0.297
0.506
0.0571
0.448
0.0530

0.464
0.429
0.0149
0.391
0.0570
0.470
0.0765
0.425
0.0468
0.492
0.397
0.344
0.0185
0.558
0.563
0.554
0.458
0.754
0.783
0.251
0.410
0.437
0.0475
0.473
0.832
0.783
0.795
0.908
0.718

0.629
0.618

0.253
0.650
0.135
0.0479
0.456
0.654
0.476
0.766
0.742
0.614

0.777
0.755
0.852
0.870
0.733
0.573
0.688
0.289
0.522
0.0536
0.455
0.0493

0.446
0.479
0.0159
0.392
0.0546
0.484
0.0713
0.428
0.0438
0.511
0.436
0.371
0.0194
0.547
0.553
0.543
0.439
0.762
0.792
0.242
0.413
0.445
0.0446
0.488
0.850
0.795
0.808
0.935
0.721

0.622
0.610

0.243
0.646
0.131
0.0454
0.438
0.649
0.459
0.774
0.749
0.606

0.789
0.764
0.869
0.888
0.737
0.563
0.688
0.282
0.544
0.0508
0.466
0.0463

0.429
0.539
0.0175
0.395
0.0530
0.500
0.0669
0.433
0.0415
0.531
0.481
0.401
0.0208
0.538
0.544
0.533
0.422
0.771
0.802
0.235
0.417
0.455
0.0423
0.506
0.871
0.809
0.823
0.963
0.724
0.1316
0.617
0.604

0.235
0.645
0.128

0.421
0.645
0.443
0.783
0.756
0.599

0.803
0.774
0.887
0.910
0.743
0.554
0.689
0.277
0.570
0.0485
0.479
0.0439

ACTIVITY COEFFICIENTS OF ACIDS, BASES, AND SALTS (continued)

NH4Cl
NH4NO3
(NH4)2SO4
NaBr
NaCl
NaClO3
NaClO4
Na2CrO4
NaF
NaH2PO4
NaI
NaNO3
NaOAc
NaOH
NaSCN
Na2SO4
NiCl2
NiSO4
Pb(NO3)2
RbBr
RbCl
RbI
RbNO3
RbOAc
Rb2SO4
SrCl2
TlClO4
TlNO3
UO2Cl2
UO2SO4
ZnCl2
Zn(NO3)2
ZnSO4

0.1

0.2

0.3

0.770
0.740
0.439
0.782
0.778
0.772
0.775
0.464
0.765
0.744
0.787
0.762
0.791
0.766
0.787
0.445
0.522
0.150
0.395
0.763
0.764
0.762
0.734
0.796
0.451
0.511
0.730
0.702
0.544
0.150
0.515
0.531
0.150

0.718
0.677
0.356
0.741
0.735
0.720
0.729
0.394
0.710
0.675
0.751
0.703
0.757
0.727
0.750
0.365
0.479
0.105
0.308
0.706
0.709
0.705
0.658
0.767
0.374
0.462
0.652
0.606
0.510
0.102
0.462
0.489
0.140

0.687
0.636
0.311
0.719
0.710
0.688
0.701
0.353
0.676
0.629
0.735
0.666
0.744
0.708

0.320
0.463
0.0841
0.260
0.673
0.675
0.671
0.606
0.756
0.331
0.442
0.599
0.545
0.520
0.0807
0.432
0.474
0.0835

0.4
0.665
0.606
0.280
0.704
0.693
0.664
0.683
0.327
0.651
0.593
0.727
0.638
0.737
0.697
0.720
0.289
0.460
0.0713
0.228
0.650
0.652
0.647
0.565
0.753
0.301
0.433
0.559
0.500
0.505
0.0689
0.411
0.469
0.0714

0.5

0.6

0.649
0.582
0.257
0.697
0.681
0.645
0.668
0.307
0.632
0.563
0.723
0.617
0.735
0.690
0.715
0.266
0.464
0.0627
0.205
0.632
0.634
0.629
0.534
0.755
0.279
0.430
0.527

0.517
0.0611
0.394
0.473
0.0630

0.636
0.562
0.240
0.692
0.673
0.630
0.656
0.292
0.616
0.539
0.723
0.599
0.736
0.685
0.712
0.248
0.471
0.0562
0.187
0.617
0.620
0.614
0.508
0.759
0.263
0.431

0.532
0.0566
0.380
0.480
0.0569

0.7
0.625
0.545
0.226
0.689
0.667
0.617
0.648
0.280
0.603
0.517
0.724
0.583
0.740
0.681
0.710
0.233
0.482
0.0515
0.172
0.605
0.608
0.602
0.485
0.766
0.249
0.434

0.549
0.0515
0.369
0.489
0.0523

0.8
0.617
0.530
0.214
0.687
0.662
0.606
0.641
0.269
0.592
0.499
0.727
0.570
0.745
0.679
0.710
0.221
0.496
0.0478
0.160
0.595
0.599
0.591
0.465
0.773
0.238
0.441

0.571
0.0483
0.357
0.501
0.0487

0.9

1.0

0.609
0.516
0.205
0.687
0.659
0.597
0.635
0.261
0.582
0.483
0.731
0.558
0.752
0.678
0.711
0.210
0.515
0.0448
0.150
0.586
0.590
0.583
0.446
0.782
0.228
0.449

0.595
0.0458
0.348
0.518
0.0458

0.603
0.504
0.196
0.687
0.657
0.589
0.629
0.253
0.573
0.468
0.736
0.548
0.757
0.678
0.712
0.201
0.563
0.0425
0.141
0.578
0.583
0.575
0.430
0.792
0.219
0.461

0.620
0.0439
0.339
0.535
0.0435