THERMODYNAMIC MINERALS

*
:
:
.$
Thermodynamic Properties
of Minerals
and Related Substances at 298.15 K
and 1 Bar (lo5Pascals) Pressure
and at Higher Temperatures
GEOLOGICAL
SURVEY
BULLETIN
1452
A summary of the thermodynamic datafor minerals

at 298.15 K together with calculated valuesfor
thefunctions
AHIT, AGOf,,T'S& (HOT - H&)/T,
and (GI;.- H&,)lT at temperatures up to 1,800 K
Reprinted with corrections 1979
U N I T E D S T A T E S GOVERNMENT P R I N T I N G OFFICE, W A S H I N G T O N :
CONTENTS
Page
UNITED STATES DEPARTMENT OF THE INTERIOR
CECIL D. ANDRUS, Secretary

GEOLOGICAL SURVEY
H. William Menard, Director
Abstract . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1
Introduction ------------------------------------------I-------------------1
Physical constants and atomic weights - - - - _ - - - - _ _ - - - - _ _ - - - _ _ - - - - - - - - - - - - - - -2..
3
Reference states and transltlons ..............................................
Sources of data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
8
Methods of calculation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Y
Thermodynamic properties at 298.15 K _ - - - _ - _ _ - - - _ - - _ _ _ _ _ - - - - - - - - - - - - - - -12
-Thermodynamic properties at high temperatures _ - _ _ _ _ - - - - - _ - - - - - _ - - - - - - - - -30
References and notes - _ - - - - - - _ - - - - - - - ~ _ _ - ~ - - - - - 428
- 447
Index of names . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
-Index of formulas - - - - _ _ _ - - - - - _ _ - - - - _ - - - - - - - - - - - - - - - - - - -452
TABLES
Pd~
TABLE
1. Symbols, constants, and conversion factors _ _ _ _ - - - _ - - _ - - _ _ - _ - - - - - - - -3.
.
2. Atorn~cwe~ghtsfor I975 - 4
--
Library of Congress Cataloging in Publication Data

Robie, Richard A
1928Thermodynamic properties of minerals and related substances at 1 bar (lo5 pascals)
pressure and a t higher temperatures.
(Geological Survey bulletin; 1452)
Bibliography: p.
Includes index.
1. Mineralogy-Tables, etc. 2. Thermodynamics-Tables, calculations, etc. I. Hemingway, Bruce S., joint author. 11. Fisher, James Russell, 1940- joint author. 111. Title:
Thermodynamic properties of minerals and related substances . . . IV. Series: United
States. Geological Survey. Bulletin ; 1452.
QE75. B9 no. 1452 IQE366.81557.3'08s 77-608180
549'.12,
For sale by Superintendent of Documents, U.S. Governn~entPrinting Office

Washington, D.C. 20402
Stock Number 024-001-03065-9
THERMODYNAMIC PROPERTIES OF
MINERALS AND RELATED SUBSTANCES AT
298.15 K AND 1 BAR (lo5PASCALS) PRESSURE
AND AT HIGHER TEMPERATURES
ABSTRACT
Selected values for the entropy (S"), molar volume (v"), and for the enthalpy and Gibbs
free energy of formation (AH,, and AGr) are given for the elements, 133 oxides, and 212
other minerals and related substances a t 298.15 K. For those materials for which hightemperature heat-capacity or heat-content data are also available (H; - H;,,)/T, S,; (G; H,,,)/T, Cp, AH;,T, AG;,Tand log K,,, are tabulated a t 100 K intervals for temperatures up to
1,800 K. For substances that have solid-state phase changes or whose melting or boiling
point is less than 1,800 K, we have also tabulated the properties listed above a t the
temperature of the phase change so that the enthalpy or entropy changes associated with
the transformation form an integral part of the highZGmperature tables.
INTRODUCTION
The purpose of these tables of thermodynamic properties is to present

a critical summary of the available thermodynamic data for minerals and
related substances in a convenient form for the use of earth scientists. To
make the tables as useful as possible, we have tried (1) to include enough
auxiliary data so that a single set of tables would suffice for most calculations, (2) to insure internal consistency, and (3) to provide the means for
rapid revision and expansion as new data become available.
This compilation is divided into two sections. In the first section, we
give values for the entropy (S",,), molar volume (v",,), the enthalpy of
formation (AITf,,,,) and Gibbs free energy of formation (AGf,,,,), and the
logarithm of the equilibrium constant of formation (log Kf,,,,) for the
reference elements, minerals, several oxides, and other substances of
geological interest, where the subscript 298 implies 298.15 K. The tables
in the second section contain values for the thermodynamic properties at
100 K intervals for temperatures up to 1,800 K. The data are arranged in
order of their conventional mineralogical groups. Within each group (for
example, the oxides), the listing is by alphabetical order of the chemical
symbol of the principal cation.
The data have been taken from recent critical evaluations or have been
evaluated by the present authors, and uncertainties have been assigned
to the 298.15 K properties. The sources of data are indicated numerically
R E F E R E N C E STATES AND TRANSITIONS
THERMODYNAMIC PROPERTIES O F MINERALS
in the tables and listed in complete form following the tables. These tables
entirely supersede those of an earlier report on the same subject matter
by Robie and Waldbaum (1968).
The true differential heat capacity, C;, is rarely measured at temperatures above 400 K because of the ease with which the heat content, H; H",,, may be determined. From the heat-content measurements, one
may derive approximate values for C; at high temperatures by differentiation of the H; - Hi98versus temperature curve. Because many
users find it more convenient to use analytical expressions for heat
capacities rather than tabulated values, we have also provided equations
for the heat capacities at high temperatures.
In order to derive values of C i from the experimental heat-content
measurements, the measured values of H; - HiYswere fitted to polynomials having six or fewer terms, and constrained so that at 298.15 K,
H i - HigRwas identically equal to 0 and that the first derivative of the
fitted equation at 298.15 K had to equal the value of the heat capacity
obtained by low-temperature calorimetry. This procedure forces the
values of C i derived from the heat-content measurements to join
smoothly with the more accurate directly measured values of C, determined by low-temperature calorimetry.
The least-squares fitting was done by computer, using either the
program HINC written by D. W. Osborne of Argonne National Laboratory (D. W. Osborne, written com., 1975) or PHAS20 (Haas and Fisher,
1976). The equation used to fit the heat-content data was that suggested
by Haas and Fisher (1976).
H; - HiSs = A + BT + CT2 + D/T + ETM + FT3
The first four terms of this equation are those used by Kelley (1960). For
most phases, only four or five terms have been used. In fitting the data,
we have followed a general rule that the number of experimental points
should be approximately three times the number of constants used in the
equation. The tabulated values of the heat capacity, Cb, at temperatures
above 400 K were obtained by differentiation of the heat-content equation. The derived C; equation, and its range of validity, is listed at the
bottom of each high-temperature table.
Thermodynamic properties of gases at high pressures have not been
included in these tables. High pressure-high temperature functions of the
most geologically important gases, H,O and CO,, have been given by
Bain (1964), Hilsenrath and others (1955), Robie (1966), and Burnham
and others (1969).
PHYSICAL CONSTANTS AND ATOMIC WEIGHTS
The symbols and constants used in these tables are listed in table 1. The
units adopted for reporting the thermodynamic properties are those of
the International System of Units (SI) (Page and Vigoureux, 1972).
TABLE1.-Symbols,
T
K
J
mol
s;
G -H I T
CP
v;98
AH;
AH;
AH;
Temperature in kelvins.
Kelvin, the unit of temperature. I t is the fraction 11273.16 of the
thermodynamic temperature of the triple point of water.
Joule, the unit of energy (or work). One joule = 114.1840thermochemical calories or 10 cm3 bar.
Amount of substance of a system that contains a s many elementary
entities as there are atoms in 0.012 kilograms of carbon 12. I t is
identical with the gfw (gram formula weight).
Pressure in bars. One bar = 10' pascals or 0.1 MPa. The standard
~ equal to
atmosphere is equal to 101325 pascals. The k i l o g r a m . ~ m -is
98065.5 pascals.
superscript indicates that the substance is in its standard state, 1 bar
(lo5 pascals) for a condensed phase.
Enthalpy a t temperature T relative to 298.15 K i n J mol-l, also called
the heat content.
Enthalpy function in J mol-I K-I.
Entropy a t temperature T, in J *mol-I K-l.
Gibbs energy function in J mol-I K-I.
Heat capacity a t constant pressure in J mcl-I* K-l.
Volume of 1 mol o f a substance a t 1bar pressure and a t 298.15 K, in cm3,
or J bar-'.
Enthalpy of melting a t 1 bar pressure in J *m o l t .
Enthalpy of vaporization to the ideal gas a t 1 bar pressure a t the
normal boiling point in J. mol-l.
Enthalpy of formation from the elements in their standard reference
states in J mol-I.
Gibbs free energy of formation from the elements in their reference
states in J mol-I.
Equilibrium constant of formation.
Gas constant, 8.3143 ? 0.0008 J. K-I. mol-I.
Faraday constant, 96,487.0 ? 1.0 J. V-I. mol-l.
Avogadro's number, (6.022094 ? 0.000008) x 1023mol-1.
Common logarithm, base 10.
Natural logarithm, base e = 2.71828 . . .
Volt.
H; H - H
constants, a n d conversion factors
Values for the gas constant (R) and the Faraday constant (F)used ih
the calculations are those adopted by the CODATA Task Group (1976),
although their values differ slightly from the most recent least-squares
evaluation of the physical constants by Cohen and 'hylor (1973). For
Avogadro's number (used in calculating molar volumes from X-ray cell
dimensions), we have used the value of Deslattes and others (1974)
6.022094 ? 0.000008 x loz3mol-'.
For convenience, we also give values for the atomic weights for 1975
(scale C12 = 12.000) (Commission on Atomic Weights, 1976) in alphabetical order bytheir chemical symbol in table 2.
REFERENCE STATES AND TRANSITIONS
The reference states for AH; AG",, and log K, of the compounds are the
elements in their standard states at 1 bar pressure (lo5 pascals) and the
REFERENCL.: STATES AND TRANSITIONS

THERMODYNAMIC P R O P E R T I E S O F M I N E R A L S
--
-Element
Symbol
Atomi c
wetght
--
Element
Symbol
Actinium
Ac
227.0278
Sodium
Na
sllver
Ag
107.868
Niobium
Nb
Aluminum
Al
Neodymium
Nd
Americium
Am
Neon
Ne
N1
2 6 . 9 8 1 54
(243)
Argon
Ar
39.948
Nickel
Arsenic
As
74.9216
Neptunlum
NP
Astatine
At
Oxygen
Gold
Au
196.9665
Osmi um
0
0s
Boron
B a r 1 um
10.81
137.33
Phosphorus
Protactinium
P
Pa
Lead
Pb
Palladium
Pd
(210)
Ba
Beryllium
Bismuth
Bromine
Carbon
Calcium
Cadmi um
C e r i um
Chlorine
Cobalt
Chromium
welght
22.98977
92.9064
144.24
20.179
58.70
237.0482
15.9994
190.2
30.97376
231.0359
Polonium
Po
Promethium
Pm
Praseodymium
Pr
Platinum
Pt
Plutonium
Pu
Radium
Ra
Rubidium
Rb
R h e n i um
~e
Rhodium
Cesium
Radon
Copper
Ruthenium
Dysprosium
Sulfur
Erbium
Antimony
Europium
Scandium
Fluorine
Selenium
Iron
S i 1i c o n
F r a n c i urn
Samarium
G a l 1 i um
Tin
Gadolinium
Strontium
Germanium
Tantalum
Hydrogen
Terbium
He1 ium
T e c h n e t i um
Hafnium
Tellurium
Mercury
Thorium
Holmium
Titanium
Iodine
Thallium
Indium
Thulium
Iridium
Uranium
Potassium
83.80
138.9055
Krypton
Lanthanum
La
Lithium
Li
6.941
Lu
174.97
24.305
Lutetium
--
Atomi c
Kr
Magnesium
Mg
Manganese
Molybdenum
Mn
MO
Nitrogen
54.9380
95.94
14.0067
50.9414
Vanadium
Tungsten
Xenon
xe
Yttrium
Ytterbium
Y
Yb
173.04
Zinc
Zirconium
zn
Zr
65.38
91.22
183.85
131.30
88.9059
stated temperature. The standard states for the condensed elements are
the most stable form a t 1 bar pressure and the stated temperature. For
gaseous elements, the standard state is the ideal gas a t 1 bar pressure.
The reference pressure for the standard state adopted for these tables is
the bar, that is, 10" pascals. The reasons for this choice are:
a. In most modern high-pressure-high-temperature equilibrium
studies on minerals, the pressure is measured in bars.
b. The use of the bar as the standard pressure in conjunction with the
joule for energy (or work) simplifies conversion of the Pv term
(ernJ*bar) in high-pressure calculations of mineral equilibria. Thus,
1 joule = 10.0 cm" bar in contrast with 1 calorie = 41.2929 cm" atm
in terms of older (non-SI) units.
c. The standard atmosphere used as the reference pressure for most
thermochemical measurements, with the frequent exception of the
PvT properties of gases, is an arbitrarily adopted unit. In terms of
the S I base unit of pressure, the standard atmosphere is equal to
101325 pascals.
d. The effect of the change of reference pressure from 1 atmosphere, as
used in an earlier edition of these tables (Robie and Waldbaum,
1968), to the present choice of 1 bar has an insignificant effect upon
the tabulated values of the thermodynamic functions for the condensed phases and only a minor and constant effect for the gas
phases.
All data listed in these tables have been corrected to the standard state
P = 1 bar. For a condensed phase (liquid or solid), it can be readily shown
that the effect of changing the reference state from 1atmosphere to 1 bar
has only a trivial effect upon all the thermodynamic properties tabulated
in this report except for AG;.
For a gaseous phase, the reference state is the ideal gas, that is, one
that obeys the equation of state Pv=RT. From the equation of state, it
follows that:
V = RTIP
from which
(dv/dT)p=RIP, and (d'v/dT2)p= 0,
Then from standard thermodynamic relations
(~C~/~P)T=T(~'VI~T')~=O
and
(dSldP)T= -(av/arr),= -RIP
from which
dS= - (R1P)dP
F o r the change in pressure from P = 1 atm (1.0135 bar) t o 1.000 bar
1.000
THERMODYNAMIC P R O P E R T I E S O F MINERALS
Also, for an ideal gas,

dH=TdS+vdP=T(- RIP) dP+(RT/P)dP=O.
il
11
i
1
Thus, for a gaseous phase, C;, (H+-H",,,)/T, and AH",re independent of

pressure, but the numerical values of S; AGof,and (G;-H",,,)IT depend
upon the choice of pressure. Similarly it can be shown that the change of
the standard state from a pressure of 1atmosphere to 1bar does not affect
the enthalpy of formation (from the elements in their reference states)
but will cause a change in the Gibbs free energy of formation of a
condensed phase if and only if one of the reference elements (usually
oxygen) is a gas.
The entropies of the gaseous elements and .compounds were converted
to the standard state P= 1bar, using the above relations, before entering
the various thermodynamic data into the data bank. Inasmuch as the
computer program calculates AGkT from AH: and the entropies or Gibbs
energy functions of the constituent elements, the values of AGf,T are
automatically corrected to the 1 bar standard state.
The National Bureau of Standards Technical Note 270 series, the
J A N A F thermochemical tables, and the CODATA tables have retained
the use of the standard atmosphere as the reference pressure. The
authors hope that in the near future the General Conference of Weights
and Measures of the International Bureau of Weights and Measures will
recommend the elimination of the standard atmosphere as the reference
pressure.
Data are listed for the elements in their standard reference states, and
for a few in nonstandard states; for example, S,gas and the diamond form
of carbon. Melting and boiling points and their associated enthalpy
changes are listed a t the bottom of each table of high-temperature properties. A horizontal dashed line in the tables indicates a transition in the
phase. A dashed line in the columns AH: AhG;, and log K,, indicates a
transition in one of the reference elements. Transitions in the reference
elements are also listed separately a t the bottom of each table. Inasmuch
as most of the high-temperature "heat-capacity" data are actually heatcontent measurements and not true heat capacities (CF,), we have followed the practice of Kelley (1960) and have treated all the high-temperature transitions as first order at a single temperature. At the transition
temperature, the functions (H; - H",,)/T, S,", and AH; make a sFepwise
change; AGf., and (G; - Hkr)1T, are continuous, but their temperature
derivatives change abruptly. For those elements (and their compounds)
for which we have, of necessity, adopted a nonequilibrium phase as the
reference state (for example, S2gas above 716.9 K), there will also be a
discontinuity in both AG, and (G; - H",,,)/T at the transition temperature. These properties of the functions must be borne in mind when
interpolating in the tables.
R E F E R E N C E STATES AND TRANSITIONS
The reference state adopted for an element above its normal boiling or
sublimation temperature is not necessarily its equilibrium state. Thus, at
equilibrium, liquid sulfur boils a t 1bar pressure and approximately 716.9
K to a gas composed of S, S,, S,, S,, S,, etc., but for our reference table,
we have assumed the gas phase to be only S,. In these ambiguous cases,
we have chosen either the dominant species in the gas or that species for
which the best thermodynamic data are available as the reference state.
Enthalpies and Gibbs free energies of formation for multiple-oxide
phases using the binary oxides as reference states have also been computed and tabulated, inasmuch as many mineralogical equilibria involve
only binary or multiple-oxide phases; for example:
wollastonite anorthite
grossular
quartz
and because the enthalpies of formation of most multiple-oxide phases are

determined using the binary oxides as the reactants. Tables of the thermodynamic functions for temperatures above 298.15 K for multiple-oxide
phases calculated using the binary oxides as the reference phases immediately follow the appropriate table calculated from the elements
and are differentiated by the heading "FORMATION FROM THE
OXIDES" above the columns for AHA AG,, and log K, and by asterisks
immediately to the right of the entries for AH",nd AG,.
When using the binary oxides as the reference states, one must remember that in this convention, AH; and AG; for these reference oxides
are zero at all temperatures. For example, AG",,,,,,,for the reaction
2 wollastonite + anorthite = grossular + quartz
may be calculated from either the tabulated values of AG"fl,ooo(elements
as reference states), or AG",,,,()(oxides as reference states) for each of the
phases in the above reaction. Thus:
Both calculations must obviously give the same result within the rounding error. However, in estimating the uncertainty in the resulting value
of AG; for a reaction involving on& oxide phases, one should use the
uncertainties associated with the AG; values calculated from the oxides,
inasmuch as this value usually corresponds more closely to the actual
calorimetric reaction scheme from which the individual AG,".values were
obtained.
The user is cautioned not to mix values of AG; calculated from the
elements for one phase with those obtained from the oxides for another in
calculating AG;~of a reaction involving the two phases, because a mean-
THERMODYNAMIC PROPERTIES OF MINEBALS
METHODS OF CAI.CITI,ATION
ingless result ensues. If a reaction involves both multiple-oxide phases

and nonoxide phases, as in
CaF, + 2H,O=Ca(OH), + 2HF
fluorite steam portlandite
AG; for the reaction must be calculated using only values from the
calculated from the elements.
tabulated values of
tabulating the thermodynamic properties of aqueous ions has been given

by F. D. Rossini (1950, Chemical thermodynamics: New York, John
Wiley, p. 320370).
The molar volumes of the condensed phases are principally from the
summary by Robie and others (1967), augmented by more recent precise
X-ray measurements of unit-cell parameters. Although our principal
sources of data for AH",, or AG",, have been solution or combustion
calorimetry, for many compounds the best available data are values of
AG",, calculated from solubilities, electrochemical cells, reduction equilibria, or decomposition pressure data; we have used these equilibrium
studies to supplement the calorimetric data whenever possible. For the
simpler gases, the thermodynamic constants calculated from spectroscopic data are usually the most precise.
In order to insure internal consistency in these tables and because of
the complex nature of many of the reaction schemes used to obtain AH",
or AG; we have corrected all the older data to the values adopted here.
For multiple-oxide compounds, the heats of formation are most commonly measured utilizing the binary oxides as reference phases. However, stoichiometric K,O cannot be prepared reproducibly, and FeO is
thermodynamically unstable. Furthermore, u-A1,0:,, corundum, is insoluble in all common aqueous calorimetric solvents. Consequently, mixed
sets of reactants such a s the alkali halides, aluminum hydroxide
(gibbsite), or an element have frequently been used as the reference
phases in H F solution calorimetry for determining A H b f aluminosilicates. For example, Barany (1964) measured the enthalpy change for
the reaction
3SiO2+3Al(OH),+ KC1+9.731H20= KAl,[AlSi,O,,,](OH),
+HC1*12.731H20
and by utilizing literature data for the enthalpies of formation of the other
phases, he calculated AH",,,,, for muscovite. Accordingly, any improvement of AH", of quartz, gibbsite, sylvite, or aqueous HC1 would alter the
enthalpy of formation of muscovite. Recent measurements of AH;,,,, of
gibbsite by Hemingway and Robie (1977) have shown that the value of
AH",,,, of gibbsite used by Barany (1964) to calculate the enthalpy of
formation of muscovite was in error by 11230J m o l l , and accordingly we
have corrected Barany's (1964) calorimetric value for AH",,,, of muscovite, and also several other aluminosilicates for which gibbsite was one of
the reactants, to accord with this new AH;,,,, of gibbsite.
SOURCES OF DATA
Many critical evaluations of thermochemical data have been particularly helpful in constructing these tables. For the thermodynamic functions of the elements at high temperatures, we have adopted the values
selected by Hultgren and others (1973). The CODATA (1976) key values
have been adopted when they differed significantly from those of
Hultgren and others (1973). For the sulfides, arsenides, tellurides,
selenides, and sulfosalts, the summaries by Mills (1974) and by Barton
and Skinner (1977) have been very helpful. The tabulations by Kelley
(1960) and by Kelley and King (1961) were particularly useful as a source
of the pre-1960 heat-content and heat-capacity data. We have also relied
heavily upon the critical evaluations of the National Bureau of Standards
Technical Note 270 series (Wagrnan and others, 1968, 1969, 1971; Parker
and others, 1971; Schumm and others, 1973) and of the JANAF thermochemical tables (Stull and Prophet, 1971; Chase and others, 1974,
1975).
In evaluating the data for the silicates, we have accepted the revised
values for AH", for those silicates given by Hemingway and Robie (1977),
which include corrections for the effect of the particle size of quartz and
'for the incorrect value of AH", of gibbsite (Al(OH),) used in earlier H F
solution calorimetry studies. For those aluminum silicates for which
definitive structural evidence of AVSi disorder was available we have
corrected the Siy8values for the configurational terms, that is, S i # 0,
arising from frozen-in AlISi disorder at 0 K, using the summary of Ulbrich
and Waldbaum (1976) as a guide. We have also added a correction to the
entropy of several manganese and iron compounds for which the accepted
value of SiY8was based upon measurements of the heat capacity only
above 50 K and for which other evidence indicated the existence of an
unextracted magnetic contribution to S;,, below 50 K (see, for example,
Robie, 1965, or Ulbrich and Waldbaum, 1976).
Values for the thermodynamic properties a t 298.15 K for the more
common aqueous ions are also listed in order to facilitate calculations of
aqueous equilibria. The reference state for the free energies of the
aqueous ions is the hypothetical ideal solution of unit molality. Values for
AG", are listed on the basis of the usual convention that AG",, AHo,,S o ,and
CL are identically 0 for aqueous H+ ion in the hypothetical 1 molal ideal
solution. A more complete discussion of the conventions adopted for
1.-
METHODS OF CALCULATION
Having chosen what we believe are the currently "best available"

values for H; - Hi,,, or Ci(T), S",,, and either AHo,,,,,or AG",,,, we have
calculated the Gibbs free energy function, and the enthalpy, free energy,
and the equilibrium constant of formation at 100 K intervals using the
following relations:
THERMODYNAMIC P R O P E R T I E S O F M I N E R A L S
10
METHODS O F CA1,CULATION
(GI - H",,)/T = ( H I - H",&/T - S;

AH0,., = AH",,,, + A(HI - H",J
AGf,.I.= AH;,,,, + TA[(Gi. - H",,)/Tl
and
log K,.,
-AGf.,/2.30258 RT
-hG"f.29$19.1444T
(4)
These values together with C;, S I and (H; - H",,,)/T are tabulated in the
second section.
A Fortran IV program was used for the above calculations. The essential feature of the program is that internally consistent thermodynamic
functions can be calculated for several hundred compounds in a single run
of the computer. This consistency is accomplished by first calculating the
thermodynamic functions for the reference elements and oxides and then
holding these data in storage for later computations involving substances
having these elements or oxides as reference phases. As new thermodynamic data become available, only a minimum number of changes in
the data base are needed to prepare a completely revised set of internally
consistent tables.
The input data supplied to the computer are the identifying name of the
substance, the entropy, the enthalpy, and Gibbs free energy of formation
a t 298.15 K and their uncertainties, and the entropy and enthalpy increments, Sq - S",,, and H I - H",,,, a t 100 K intervals, together with the
number of atoms of each element in the chemical formula. Auxiliary data
such as the melting and boiling points and enthalpies of melting and
vaporization are also included. The program computes the formula
weight of the compound on the basis of the atomic weights of the elements
(1975 scale) and values for SOT,
AG0f,T,log KIST,C"p (HOT - HiBB)/T,
and (GT
- Hg,,J/T a t 100 K intervals up to 1,800 K.
Although the absolute value of AGf,, or AH;, of the more complex
compounds is rarely known more accurately than +1,000 joules, these
quantities are tabulated to the nearest 10 joules. This procedure is
justified because the temperature derivatives of AG",, and AH;,
rounding off again tends to obscure small differences of major importance

in calculations of geological interest.
The uncertainties assigned to the properties apply only to the values at
298.15 K and were taken principally from the original sources of experimental data. By convention, the uncertainty interval reported for
calorimetric measurements is twice the standard deviation of the mean
(Rossini, 1956, p. 319); that is,
8 = 2 [ C (xi - x)*/n(n (7)
where xi is the value for an individual measurement, is the arithmetic
mean of all the measurements, and n is the number of observations.
For substances where AH",,,, is the directly measured quantity, the
free energy was calculated from
AGf,,,, = AH;,,,, - 298. 15AS"f,2!,n
(8)
and the uncertainty in the free energy was calculated from
+ ( 2 9 8 ~+~ 2) (~2 9 8 n , ~ ~ , ) ~ l "
a, =
(9)
where asis the uncertainty in the entropy of the substance, the wsi are
the uncertainties in the entropies of the i reference elements, and the ni
are the number of moles of each element in the chemical formula of the
substance. Uncertainties derived in this manner were rounded upward to
the nearest 10 joules.
For substances in which a,;is less than a,, the basic quantities used in
the calculation were AGf,n9x
and a,; derived from electrochemical cell
measurements, solubilities, or phase-equilibrium data. Hence, AH^,,,, is
a more indirectly derived quantity having a larger uncertainty. For these
substances, a, was calculated from
UH= [(a(;)*+ ( 2 9 8 ~+~1
) (298niuS:)*lM
~
(10)
Camera-ready copy of the tables of the thermodynamic properties, and
of the bibliography, were prepared from the output file (tape) of the
FORTRAN IV program, using the WYLBUR text editor and the extended print facility at the Computer Center of the National Institutes of
Health.
Several of the tables in the second section are incomplete because of the
lack of adequate data on the enthalpies of formation or entropies a t 298.15
K of these substances. The tables are nonetheless included, so that when
such data become available, one may readily calculate the remaining
functions using equations 2,3, and 4 given above, or use equilibrium data
and the third-law method to obtain the standard state enthalpy or Gibbs
'free energy change for the reaction (AH;, or A 4 ) , following the procedures illustrated, for example, by Robie (1965).
and
(dAHQf/dT),= AC;
are calculated from the heat-content data, which are known independently of the enthalpy or Gibbs free energy of formation. The practice of
rounding tabulated values of AG", or A H b n the basis of the uncertainty in
the absolute value does not utilize the full accuracy of the heat-capacity
information and destroys the necessary internal consistency between
AH"f,,, and the Gibbs free-energy function (eq. 3). Furthermore, in many
instances, the differences between AHofor AGf for polymorphs are often
known more accurately from phase-equilibria or calorimetric investigations than are the individual A H h r AGf values for a phase, so that
11
TBERIODlUA?.IC
12
PROPERTIES O r l I I E R A L S
.......................................................................................................
l a m e and f o r m u l a
rormula
weight
g
Entropy
S
J/.2??K
lolar
.olu.s
c.3
a~;,298
~1.01
, Log
~ ~
Kf ~R e f e r e n c e s
allo
~1.01
u.e
C;
AG;
and for.ula
P?C.Ul.
weight
'1
mt60P)I
S2g8
Jb01-K
8ol.r
rolome
ELEIEUTS
SILVER (REIEREUCX STATE)
A9
COBALT ( REFEREICE STATE)

CO
kg'
STD.
CO*'
Aaueous ION
STD. STATE.
= 1
AQUEOUS ION
STATE. a
1
ALUIIIIIII
A1
1
STD.
co"'
STD.
( RI~ERENCXSTATE)
STATE.
AQUEOUS IOU
= 1
CHPOllUl ( RETEBEYCE STATE)
LQUEWS IOU
1
STATE.
cr
STO.
AQUEOUS ION
STATE. rn = 1
CS*
STD.
AQUEOUS ION
STATE.
= 1
cut
STD.
AQUEOUS
ION
STATE,
= 1
CT++
APGON (RETXRZlCE STATE)

Ar
(IDEAL GAS )
ARSEIIC ( R I r E n I N C E STATE)
AS
GOLD (REIERZBCE STATE)
A"
BOUOU (RErmEYCE STATE)
8
BIRIUII (RETEBEYCE STATE)
81
ea"
STD.
cut*
AQUEOUS ION
STD. STATE. rn = 1
AQUEOUS l o r
STATE.
= 1
OrSPROSIUII (REFERENCE STATE)

DY
Be**
AQUEOUS IOU
STD. STATE, m = 1
BISIIUTH (RETEREUCE STATE)
8i
Bi***
AQUEOUS I 0 9
= 1
STD. STATE.
208.980
s s o n r v a ( R E F E R E N C ES T A T E )
Rc,
(LIQUID)
159.808
BROIINE (IDEAL GAS)
159.808
BT.
152. 32
0.04
54.58
0.20
245.U6 24789.2
0.05
3.4
0 107
107
rSro.
30910
200
3140
300
-0.550
0.053
35
3 5 107
AQUEOUS ION
= 1
srrre,
IRON ( REFERENCE STATE)
re
BrAQOEOUS ION
STD. STATE. m = 1
re*'
STo.
CARBON (REFERENCE STATE)

C
re*+'
AQUEOUS I O N
STD. STATE,
= 1
40.080
-53.10
2.00
CADIIIUII ( R E F E R E U C E
STATE)
Cd
112.400
51.80
0.17
~ d "
AQUEOUS ION
STD. STATE. rn = 1
112.400
-73.2U
0. 8 5
-75900
120
-77580
120
96.978
0.021
214 214
0 107
0107
-696200
850
-672000
850
117.732
0.1.9
161 261
140.120
-301.00
5.00
-5372~0
850
-503u00
850
88.26.
0.149
262 262
70.906
223.08
0.04
STD.
STATE,
AQUEOUS ION
= 1
35.453
56.73
-167080
C1AQUEOUS 1 0 1
0. 1 6
88
STD.
SrATE. m = 1
___________________----------------------------+-------------------------------------------------------
-13127U
110
cnionrve ( RsFessrca s r a r a )
Cl,
(IDEAL GAS)
24789.2
3.4
0107
21.999
0.01 9
35
AQUEOUS ION
STATE.
,1
107
-205.00
5.00
= 1
f l D n o c a ~( PerEnewcr s r r r e )
' a
(IDEAL GAS)
8'
STD.
13.591 262 262

0.021
140.120
Ce*"+
= m A N r u a ( R E F E R E N C E STATE)
ce
107
ce"'
STD.
.
.
20.77
0.02
-553540
1200
190. 120
A Q U E O U S IOU
69.46
d.37
13.005
0.003
-5U2830
1200
CERIUII ( R E T E R E N C S
ET A T E )
ce
STATE.
A Q U E O U SI U N
STATE, rn = 1
cIDOLINIUl (REIEPENCE STATE)

Cd
caf*
AQUEOUS ION
STD. STATE,
= 1
107
35
cmJ
~ ~ f 0 Log, Kf~ R~ e f e~r e n c e s
~fif0,~g~
J/.ol
J1.01
* fin
S d ~ ' c0
--------------------------------------------------------------------------------------------------!---1
H9,**
AQUEOUS ION
SFD- STATE. a = 1
14
TRERMODT NAnIC PROPERTIES OF NINERALS
_..._____._._______-----.-....---------.-.-----------------------.----.------------------------------------------------------------.
Entropy
molar
a ~ i , ~ A~ e C
~
,L O
~ ~s f~
~~ e f e r e n c e s
bn0
Formula
tntgopy
solar
s ; ~ v o~l u m e
Isme a n d f o r m u l a
s AG; C;
might
SZg8
V01u.e
g
J/.Ol.K
c
.
3
v.01
J/.0l
9
J/.oleK
c.3
__________..___..._-.--.-.-.-...---.-.-------------__.__..._______..__-..----------.---.-.-----------pormula
weight
Name a n d f o r m u l a
ELEIIENTS
ELEIIENTS
noLnIuN ( REFERENCE STATE)
no
164.930
75.02
1.67
18.74
0.01
IODINE (REFERENCE STATE)
253.809
1 1 6 . 15
0.08
51.29
0.06
253.809
260.68
0.06
1 2
IODI NE
I , (IDEAL GAS)
ISTD.
AQOEOUS ION
STATE, rn = 1
INDIUI ( REPERENCE STATE)
126.905
106.70
0.20
114.820
57.84
0.84
L,,
IRIOIUN
24189.2
1.4
15.753
0.005
0 107
107
0107
107
LEAD ( REPEIEUCE STATE)

Pb
62420
80
19329
80
-J.386
0.001
32
32 1 0 7
pb"
AQUEOUS 1 0 s
STD. STATE,
= 1
-56900
840
-51915
860
9.096
0.151
J5
35
pALLADIU0 (REPERLWCE S T l T E )
Pd
0101
~RISEODIIIIUII(REPERENCE STATE)
PT
107
pLATI1UM (REPERENCE STATE)

Pt
( REFERENCESTATE)
IT
p r u T o r I u n (RE?sRENCE STATE)
PY
POTASSIIIfl (PEFERENCE STATE)

K
'
K
STD.
RUBIDIUM (REPEREICE STATE)

Rb
AQUEOUSI O N
STATE,
= 1
Rb'
STD.
n n r m u a ( R E F E R E N C ESTATE)
KC
( I D E A L GAS)
LINTHANU.
La
RLiEUIU~ (REFERENCE S T i T E )
Re
(REFERENCE STATE)
L I T ~ I U( R
~ E F E R E N CSET A T E )
6.940
29.12
0.02
b.941
11.30
0. 3 5
Li
tit
STO.
A V U I O U SION
STATE, D = 1
L U T ~ ~ I O (I IREFERENCE STATE)
174.970
LU
17.77
0.01
32.68
0. 1 3
13.996
0.007
24.305
ng*'
STO.
24. 3 0 5 - 1 1 8 . 0 0
4. LO
13.017
0.007
50.96
0.84
n r ~ w n ~ u( RnE F E R E N CSE T ~ T E )
nq
AQUEO~ISIUN
STkTe.
' 1
M A N G A W E S(REFERENCE
~
STATE)
N"
54.938
32.01
0.08
nn"
54.938
-73.60
0. 8 5
95.940
28.66
0. 21
NITROGEN ( REFERENCE STATE)

(IDEAL GAS)
28.013
191.61
0.02
SODIUM (REFERENCE STATE)

Na
22.990
51.30
0.02
~ a '
~ 9 u E o u S ION
STD. STATE, m - 1
22.990
58.41
0.20
N r o s l u a ( R E ~ E R E N SCTEA T E )
Nb
92.906
36.40
0.42
10.828
0.005
1uu.240
71.09
4. 1 8
20.57
0.01
AQUEOUS ION
TO. S T A T E . n
N O L Y ~ ~ E N U( REFERENCE
N
STATE)
no
N,
w e o o r s l u n ( R E P E R E W ~ STATE)
E
W
d
NEON ( REPEREMCE STATE)
Ne
(IDEAL GAS)
146.32
0.02
NICKEL (REFERENCE STATE)
58.700
29.87
0.08
Ill**
AQUEOUS ION
' 1
STD. STATE,
58.700
-129.00
0.85
OXYGEN ( REPEREUCE STATE)

0,
( I D E h L GAS)
31.999
205.15
0.04
OShIUs ( REPERENCE STATE)
190.200
32.64
0.06
30.974
22.85
0.08
9.187
0.005
24189.2
3.4
21.812
0.010
-278455
90
-292620
110
0 107
107
RUTHENIUM ( BEFERENCE STATE)

8"
0107
107
SULWR (REPEREICE STATE)

S
-466850
840
-45Ud0D
lb70
-220700
120
-228000
850
0107
101
0107
107
0107
107
51.267
0.019
35
107
RADON ( R,??ERENCE STAT,?)

an
( IDEAL G A S )
35
3-79.679
0.149
STD.
2 1 4 214
0101
39.945
0.149
AQUEOUS 1 0 1
STATE, a = 1
DIATOIXC S U L P U R
S. (IDEAL G I s )
107
OmA-Aronxc SULFUR
(IDEAL GAS)
s.
I 6 3 203
AmI1*O*T ( REFERENCE STATE)

Sb
s,?LE*IUII ( REFERENCE STATE)
-~u0300
65
-261900
85
45.884
0.015
35
35
I*
,
StU.
STATE,
slLICOm
24789.2
3.4
0 107
107
0107
107
0107
107
0 107
107
-5uyu0
850
-45600
850
35
107
0 107
107
0 107
107
..
r w
6.588
0.003
24789.2
1.4
8.423
0.005
17.2
0.1
AQUtOUS ION
m r 1
(IEIERENCZ STATE)
S A a r B I u a ( II?EREuCZ
STATE)
TzD ( ~ E ? ~ I E v c ,STATE)
?
I.
srlo_arOn
IC
Oa
p n o s p n o ~(~R~E ~ Z ~ E UsCT Er r E )
7.354
0.007
0107
RRODIUR (REFERENCE STATE)

Rh
I1
20. 179
W I
AQUEOUS ION
STAT,?, rn
1
7.989 263 263

0.119
P
..........................................................................................
-------------
( I K r E n a r c z STATE)
A I I ~ O , ~ ~ a~
J/m01
J/.ol
~L O
~ K~
~~
References
S
duo
?---!c0
AGO
PROPERTIES AT 298.15
17
_______..___.___.__---.----------------.-------------------------.----.------------------------nolar
! A H ; , ~ ~ ~a ~ : , ~ l o~g ~K~ R e f e r e a c e s
Formula
Entropy
Formula
mtiopy
molar
.HfoTZq8 . 3 ~ ; , 2 9 ~ Loq Kf
sefere~ces
name a n d f o r m u l a
weight
sZg8 volume
Ad
allo
l a m e a n d formula
weight
S298
volume
.7/.o1-K
co3
J/.ol
q
c.1
J/m01-K
w.01
V.01
AG:
9
.,/no1
---------- ----- ...................................................................................
C'
C'
:---!
&Go
___.________.______-...------.-------------.------.--------.---------------------------------SULFIDES.
ARSENIOES.
TELLURIDES.
SELENIOES.
AN0 SULFUSALTS
ELEIEUTS
COVELLITE
CUS
TITANIUU (REFERENCE STATE)

Ti
47.900
30.63
0.08
10.631
0.010
0107
107
CHALCOCITE
cu2s
THALLIUI (REFERENCE STATE)

T1
204.370
64.18
0.21
17.21
0.02
U107
107
CHALCOPYRITE
cuPeSl
BoRUITE
C",FeS.
T H u L l u a (REFERENCE STATE)
T.
T ROILIT E
FeS
uRANrun ( R E F E R E N C STATE)
E
U
,,+*+
PYRRHOTITE
Fe. .,IS
AQUEOUS ION
STO.
STATEI
STD.
STATE.
' 1
PIBITE
AQUEOUS ION
m = 1
?as.
IARCASITE
FeS 2
VANAOIUU (REFERENCE STATE)
v
FERROSELITE
FeSe,
FROHBERGITE
FeTe,
xewou (REFERENCE STATE)

xe
( IoEAL GAS )
YTTRIUI (REFERENCE STATE)
Y
I T T E R B I U ~ (REFERENCE STATE)
Yb
88.906
44.43
0.25
15.038
0.007
0 107
107
U ~ D R O G E USULFIDE ( roeu GAS)

R*J
173.040
59.83
0.17
24.03
0.01
0107
107
SrD.
us-
AQUEOUS ION
STATE, m = 1
CIUNA8AR
B9S
ZIUC (ItEFEREUCE STATE)

2"
2ntt
AQUEOUS ION
STD. STATE. n = 1
65.380
-109.60
0.70
zIRcowrua ( REFERENCE s r r r e )
91.220
38.99
14.016
0.17
0.007
-153390
200
-147160
220
15.80U
0.019
35
IBTACIUNABAR
89s
35
ALIBANOITE
ZT
URHANE (IDEAL GAS)

CH.
16.043
186.26
0.21
179.552
104.43
3.35
17.030
192.78
0.08
24789.2
3.4
0107
mas
107
-14810
335
-50708
377
8.864
0.066
262 2 6 2 2 4 7
RAUERITE
mas*
24937
1319
19912
1715
-3.489
0.300
108 109 115
Ilos*
-45940
350
-16410
350
IIOLIROENITE
COHENITE
Fe,C
AIMONIA
( IOEAL
GAS)
nn,
UH,
STO.
21.23
0.01
24789.2
3.4
1.675 1 4 7 1 1 5 247
0.061 2 1 5
~ILLERITE
IiS
BEAZLEUOODITE
Ii a s
UN-IOUIZEO
STATE, m = 1
EALEuA
Pbs
NH.*
AQUEOUS ION
STO. STATE, b = 1
CL~USTHALITE
PbSa
SULFIDES.
ARSENIOES. TELLURIDES,
SELEIIDES.
AN0 SULPOSALTS
AL~AITE
Rke
ACANTHITE (ARGENTITE)
80
11 11>
247.796
142.84
0.42
34.19
0.04
-32346
879
-40080
837
7.012
0.147
REALGAR
ASS
106.982
63.51
0.61
29.8
0.24
-71340
2090
-70320
2100
11.120
0.368
'74
ORPIIENT
AS&,
24b.023
163.60
0.40
70.51
0.25
-169030
4200
-168410
4220
19.505
0.739
262 2 6 1
230
BISUUTHIUITE
81.S~
514.141
200.90
3.30
75.52
0.04
-143090
1050
-140560
1070
14.626
0.187
230 1 6 1
262
72.140
56.65
27.72
-474880
2100
-UbY850
2100
82.316
0.368
120
11
144.U60
10.29
1.67
-149600
1255
-145630
1381
25.514120
0.242
Aq z s
OLDHAUITE
CaS
GREEUOCKIT E
CdS
1.25
0.09
29.934
0.015
COOPERIT 8
Pts
262
S I I B U ~ ~
S~.S,
"
sas
32
2
65
"AIUIC
sag,
SULFIDE
31
------------------- ______________.____----------------------------------------------------------
orm mu la
Naae and f o r m u l a
weight
g
~ntropy
a ~ O f , ~ ~ ~
J/.01
c.3
J/.0l
AG;
19
.......................................................................................................
~ ~ f 0L O, K*
~ ~ ~eferenCea
~ Ano
~
aolar
s ; ~ volume
~
3/.01.K
COP
?oc.u~*
ram* a n d f o r m u l a
weight
......................
EntcOPJ
'Molar
s ; ~ ro1u.e
~
, b ~ ~~ ; ~ ,
L~o g ~K f ~ R e f e r e n c e s
--
----.----__.__._____________----.-------------------------------------------------------------SULFIDES,
ARSENIOES.
TELLURIDES.
SELENIOES,
AND SOLFOSALTS
OXIDES AND HYDROXIDES
DICESIUU
csro
YURTZITE
zns
UONOXIDE
CESIUM H!DROXIOE
CBOH
OXIDES AND BYOROXIDES
TEuORITE
CUO
CORUNDUU
A1.0,
281.810
146.87
0.44
149.913
98.74
4.18
79.545
42.63
0.21
CO.=
STO.
H,CO,
STO.
CALCIUH OXIDE
ran
172.119
CERIUU SESQUIOXIDE (HEXAGONAL,

ce20,
CERIUH SESQUIOXIOE (HEXAGONAL.
celOl
COBALTOUS OXIDE
r-0
e)
328.238
62.30
0.08
1 54.18
0.62
23.853
0.026
47
.75
0.05
-1088680
1464
- 1 7 9 68240000
-1025380
2929
- 1 7 0 78949000
179.643
0.513
2 9 91.472
.225
2 7 9 2 38
5 130
8)
52.97
11-64
0.34
0.02
-237990
1255
-21b194
1297
37.526
0.227
1 2 0 2 6 3 164
164
382.518
155.64
0.85
44.171
0.010
-1897860
1920
-1808879
2000
316.909
0.350
235 1 3 5 207
EUROPIUM OXIDE
EuO
167.959
62-76
0.85
20.475
0.008
-592040
8370
-556082
8370
97.424
1.466
2 3 5 2 3 5 166
EUROPIUMS E S Q U I 0 I I D E (MONOCLINIC)
351.918
146.44
44.02
-1651420
-1555158
272.958
281 1 3 5 1 1 0
8.50
0.05
8400
351.918
68.887
..,o
71.846
8400
1.472
57
48.29
0.03
210
57.59
12.04
-266270
-245155
91.950
120 109
0.22
0.04
837
879
0.154
247 247
59-60
1.67
12.00
0.05
-272043
-251156
2091
2176
0.381
87.40
0.21
30.274
0.012
-824640
1255
-74'683
1297
130.267
0.127
78
247
46
44.001
44
247 247 247
HEHATITE
r e s ,
159.692
IACIIETITE
re,o+
231.539
146.14
0.42
44.524
0.008
-1115726
2092
-1012566
2134
137.398
0.374
79
84
247
88.854
60.38
0.63
20.82
0.01
-559330
-488550
85.591
139
13
187.438
84.98
0.42
28.941
0.006
-1089100
850
-998342
850
0.149
C A D O ~ I ~SESQUIOXIDE
~ ~ M
(UOWOCLINIC)
OdzO,
362.498
151.88
0.85
43.4
0.04
-1819620
-1732338
303.500
3600
3600
0.631
crDoLINIun S E S Q U I O X I O E
( CUBIC)
GdzO,
362.498
G E B f l ' ~ ~ DIOXIDE
~fl
(QUARTZ TYPE)
GIO,
101.589
55.27
0.27
0.04
900
0.158
G ~ R ~ A N I UDM
IOXUE
coo*
104.589
64.50
0.30
28.6
0. 1
-526350
-475180
83.250
630
710
0.124
18.069
0.003
-285830
42
-237141
84
41.506
0.015
35
35 247
196
-230025
45
-157328
27.563
35
35
90
0.016
-241814
42
-228569
40.044
84
0.015
-1144740
1255
-1088276
1297
190.662
0.227
GLASS
18.015
69.95
0.08
ON-
17.007
-10.71
0.20
18.015
188.72
0.04
AQUEOUS ION
SrO. STITE.
730
'
21.44
2U789.2
3.4
174.906
800
-497071
17.086
59-33
0.42
20.823
0.008
" O ~ ~ ~ I O
K I T
up0
216.589
70.27
0.34
19.32
0.02
-90789
-58528
50
60
0.011
158.16
0.32
UU.90
0.02
-1880700
4850
-1791373
5000
313.842
0.876
120 263 129
P o T a s ~ ~ HIDPOIIOI
~ l l
R0H
---___
56.105
78.5
uu
79
120 2 6 1 203
145
28,
1 3 5 210
210
-551030
210.489
377.859
44
78
750
a a r M I ~DIOXIDE
~
OfO*
SESQUIOXIDE (CUBIC)
MU
47.585
0.008
WIT KR
RzO ( L I Q U I D )
"0.0,
0.227
235 235 2 0 1
103
328.238
74.933
310.341
0.701
8ot'1v~
22.699
-1771385
4000
1 1 3 21 30 55 2 0 2
7"
'.v-
-129564
1255
-1863130
3930
8*0 ( I D E A LGAS )
CERIANITE
ceo.
-157320
45.683
0.010
sTr.111
-"-
12.22
0.03
149.79
0.85
GLLLIUM SESQUIOXIDE
Ga203
32
32
372.998
GOETHITE
l o o ( OH )
ON-IONIZED
STATE, m = 1
31
~ y s p R o s I u ns E s Q o I o x I o E ( C U B I C )
P E ~ R O U SO X I O E(STOICHIOMETRIC)
re0
uCO3AQUEOUS ION
STO. STATE, m = 1
64.944
0.149
2 6 3 263 164
164
Pe.
IQUEOUS ION
STATE,
= 1
-370690
850
25.584
1.107
EU.0,
CLRBON DIOXIDE
Co, (IDEAL GAS)
-416716
837
-146030
6318
UOSTITE
CARBON BONOKIDE
Co ( IDEAL GAS)
59
-168610
6276
EUROPIUU SESQUIOXIDE (CUBIC)
BERYLLIUH OXIDE (BETA)

Be0
59 236
23.437
0.016
EuIO.
BARIUU OXIDE
BaO
54.023
0.208
93.14
1.67
ETzOs
BORIC OXIDE
B.0.
-308360
1190
143.091
ERBIUH SESQUIOXIOE (CUBIC)
GIBBSITE
Al(OH)x
-315975
1170
CUPRITE
Cu.0
DY.03
DIASPORE
AlO(0H)
59.62
0.07
110 262 119

83
1 6 1 119
35
35 247
196
1 2 0 264 188
10.251 247 247 247

258
235 235 207
THERlODINlnIC PROPEBTIES OF IIINERALS
20
.......................................................................................................
pormula
weight
g
name a n d f o r m u l a
mtiopy
sZg8
J/.ol.K
nolar
volume
c.'
J/.d
, d~:,2g8
~
~
L O K~
~
References
1a. &
'
.......................................................................................................
&so
na.e
COP
dGDf
a n d formula
-------- ...........................
?ormula
weight
e n S2g8
tgopy
v01u.e
nolar
DILITHIUI IONOXIDE
LitO
L I T H I U ~ HYDROXIDE
Lion
LOTETIUE SESQUIOXIDE (CUBIC)

LUzO,
PERICLAS E
ngo
PRASEODYIIOI OXIDE
PrO1..~.
RHENIUR DIOXIDE (OPrHORHon8IC)
Be02
IHENIUI TRIOXIDE
sea,
DIRHENIOI HEmOYIoE
Be,07
BIXBPITE
SULIUB DIOXIDE
SOz (IDEAL GAS)
m,o.
SULFUR THIOXIDE
SO, (IDEAL GAS)
nOLYBDENUl DIOXIDE
no01
SO.AQUEOUS ION
STD. STATE,
= 1
LIOLYBDITE
MOO,
20.'AQUEOUS ION
STD. STATE, n = 1
NITROGEN DIOXIDE
NO, (IDEAL GAS)
AQUEOUS ION
STD. s r r T e , m = 1
SCAMDIU1 SESQUIOXIDE
SC 10,
QUARTZ
sloa
NIOBIOH DIOXIDE
AbO,
DINIOBIUii PENTOXIDE
NbrO.
NEODYllIUil SESQUIOXIDE (IEXAGOQhl)
Nd203
BUNSENITE
NiO
PEOSPHORUS tlOUOIIDE
PO (IDEAL GAS)
PHOSPHORUS PENTOXIDE
P20.
PHOSPHORUS PENTOXIDE ( DIIERIC)
(P,015r
. -.-
283.889
PO.--AQUEOUS ION
STD. STATE, m = 1
ORTHOPHffiPHORIC 8CID ( CRISTAL )
8.00.
O R T H O P H ~ ~ ~ P H OACID
R I C (LXQUID)
Rap01
LTTHARGE ( RED)
Pbo
231.00
118.8
0.80
0.4
94.971
-222.00
4.20
97.995
110.54
0.42
97.995
150.78
4.20
223.399
66.32
0.84
48.52
0.01
23.91
0.05
-2940000
8400
-2675794
8400
468.791
1.470
215 215 2 ~ 7
-1259550
-1001510
175.469
2 6 1 262
850
850
0.149
-1266920
2090
-1112290
2510
194.869
0.440
32
32
32
-1254200
2090
-1111700
2510
194.766
0.440
32
32
32
-219409
830
-189202
900
33.148
0.158
32
32
32
___________________--------------------------------------------------------------
d~ ~~ : ~ ,
~L O~ ~K~~
f f f C'
f _p
AGO
OXIDES AN0 HrOROXIOES

LAU'TXAWI SESQUIOXIDE
Lapol
g
J/.ol.K
cml
J/mol
J/mol
S
---------------------------------------------------------------
OXIDES AND HIDBOXIDES
uo3
21
.......................................................................................................
P R O P E R T I E S AT 2 9 8 . 1 5
23
-.----..-..--.--... .--------------------~--..-..--.....-~.
.---.-..-.------.--..---____.______________--------------------.----------------.---------------------
Formula
EntEopy
Molar
an:,298
A G : , ~ ~ ~L O Q
~
Formula
fefferences
Entgopl
Molar
s~g,298
A G : , ~ ~ ~ L o g Kf
Reterences
d tlo
~ a m ea n d f a r a u l a
weight
S298
volume
.,%Go
,no !..
s AG: C;
v
J/mol-K
C D ~
J/.ol
J/mol
S
c"
.!
cn'
v.01
J/.Ol
.-.
- .. ......
.-.-......-..-.._____.___________.---.----.--.----------.-----------------------------------.---.----
Name and f o r m u l a
weight
S298
J/nol.K
PolUDZ
- --
---
MULTIPLE O X I D E S
O X I D E S AND H Y D R O X I D E S
CALcIun FERRITE
TERBIUn SESQUIOXIDE ( C U B I C )
c ~ F P z ~ .
Tb20,
DICALCIUU F E R R I T E
cdtFeiO5
T E R B I U l OXIDE
TbO1.71.
TERBIUM OXIDE
TbO,..
1.
COBALT S P I N E L
TELLURITE
TeO.
c0,o.
HERCY NIT E
F e l l 201
THOBIdNITE
Tho.
CHROlITE
F e c r ,O.
T I T A N I U n MONOXIDE
Tin
ILflENITE
PeTiO,
RUTILE
TiO,
TITINOMAGNETITE
Pe.TLO.
ANATASE
TiO,
PS EUOOBROOKIT E
OITITANIUN TRIOXIDE
Ti&.
Fe,TiO,
ALPHA)
TRITITANIUM PENTOXIDE (ALPHA)

Ti,O.
SPINEL
flqA1,o.
TETRATITANIUM IiEPTOXIDE
Ti.0,
THULIUM S E S Q U I O X I D E
TnzOi
URANINITE
u0.
URANIUM T R I O X I D E ( GAHNA)
UO3
VANADIUN n 0 N O X I D E
VO
KARELIANITE
V,O,
DIYANADIUn TETROXIDE
HALIDES
v.0.
DIYANADIUH PENTOXIDE
v.05
TUNGSTEN D I O X I D E
YO 2
TUNGSTEN T R I O X I D E
UO3
YTTRIUM S E S Q U I O X I D E ( C U s I C )
YzO,
YTTERBIU~ sEsQuIoxIDE (CUUIC)
YbzO3
ZINCITE
Z"0
BADDELEYI-E
Zr01
MULTIPLE OXIDES
120
TIALITE
AlzTLO-
181.861
109.62
0.84
CHRYSOBERYL
BeAl.0.
126.974
66.28
0.13
21
48.75
0.05
34.32
0.023
-2300780
2800
-2178460
2800
381.659
0.149
214 2 1 4
67
__..____..______.__---.---------.---.------.------------.-----.----------------------------------
25
THEHIODY NLIIC PROPERTIES OF NINERALS

^___--------------------------------------------------------.--.-------.--------------.---..--.--------
- - --
.- - - -. ___._._.._._.___...----.---.---.-----.-.----.-----------------------.-....---.-.---.---.----Formula
E ~ ~ C ~ P~ Y0 1 a r
~ n f O , e~ . ~~ ~f 0 , ~~ ~ o~ K~
g
References
l a s e and f o r m u l a
reiqht
s;98 v o l u m e
~
~
~ ~~ t ~ on nolar
p y u
n n~i , 2 y m ~ a ~ : , ~L O~ ~K ~f
References
no
reiqht
S298
volume
4
J/.OI.K
cml
~/mol
J/.o~
s LC'
& n o c0
Name a n d f o r a u l a
-------------------------.----.--j/rnol.n
c
.
3
~/mo1
J/mol
5
AG;
c",
--
-- -
----- ...........................
- - - -- ___._.___.._._.___.-.-.-.-.-.--.-.-.--------------------
:---!
. -.
-.
.
-. -.
-.
.-.-.-.--.-...-..--.----.
CARBONITES AND NITRlTES

HALIDES
74.551
82.59
0.20
37.524
0.004
-436470
140
-408554
140
95.211
89.62
0.84
40.81
0.10
-641310
460
-591785
5
125.844
118. 24
0.21
"2.11
0.17
-481290
837
53.~91
95.02
0. 40
35.06
0.05
58.443
72.12
0.21
129.606
218.106
71 .577 2 1 5 2 1 5 2 4 7
0.025
173
nuaITE
cang.(Co,
1.
mAVITE
CdCOs
103.679
0.095
1 2 0 21Q 169
247 247
-440488
879
77.172
0.150
34 2 1 4 1 6 9
147
-315190
290
-201776
290
35.701
0.051
215 215 247
AzLIHIIE
cuI(OH)z(CO=)z
27.015
0.003
-411260
110
-384212
110
67.313
0.019
2 1 5 2 1 5 247
SIDERITE
?BCO,
97.66
0.2
36.7
0.07
-305330
80
-259010
80
4 5 - 3 8 ) 2 6 3 263
0.011)
135.98
2.09
47.09
0.05
-359400
293
-314033
711
55.018
0.125
154.259
139.75
1. 26
57.3
0.3
-721740
4180
-654507
5020
114.667 247 247 141

0.879
ORANIUn TRICHLORIDE
UCl
314.388
158.95
0.UO
62.04
0.06
-891190
4000
-823820
144.J3O
5000
0.676
ORANIOU TETRACHLORIDE
UC1.
319.841
196.60
0.50
77.6
0.03
-101d39U
3000
-928850
3000
162.731
0.526
Y ANAOIUl DICHLORIOE
121.847
97.07
1. 26
-451870
8500
-405661
8500
71.074 1 2 0 2 6 4 1 2 5
1 .'+MY
DIUSOWITE
raAlco,( o n ) ,
v & n h u I u n TRICHLORIDE
VCI,
157.300
130.96
1.7
54.46
0. 1
-580740
850
-511399
850
89.595 1 2 0 2 6 4 1 2 5
0.149
ceuussrr E
PbCO,
ALunINUn TRIPLUORIDE
AlP,
83.977
66.48
0."
26.15
0.1
-1510400
1300
-1431076
1300
150.720
0.22d
147 ~ 4 751
2 1 5 215 111
STEOI~~IANITE
srco,
FLUORITE
car2
78.077
68.87
0. 34
14.542
0.007
-1229260
420
-1176920
1120
206.192
0.074
120 215 175
SnITnso~xr~
ZlCO,
HALITE
Mac1
COTUNNITE
PbCl.
VC1,
nY OROGEN FLUORIDE
nr ( I D E A L GAS)
SELLAITE
20.006
CRYOLITE
Na,AlF.
URANIIII
TETRAFLUORIDE
57.25
0.42
19.61
0.01
U1.988
51.30
0.08
1V.984
0.005
209.9~1
238.45
1. b7
314.023
151.67
0. 1 7
u F.
IODARGY RITE
Aql
COCCINITE
24789.2
J.4
b2.302
n4Fz
YILLIbUnIlE
NaF
173.18
0.OU
-173300
700
-275~00
700
- 1 1 2 4 2 ~ 0 -1071064
1200
1100
48.249
0.123
187.617
0.210
-576550
670
-546319
670
95.713
0.117
70.81
0.20
-3309544
0180
-314UY15
"00
550.978
0.753
46.88
0.08
-18535UO
5000
-1762800
5100
108.637
0.894
40
12b 247 115

215 215
70
d9
70
233
70
35
89
133
70
35 217
IESoUBHONII E
llgC0,- 3Ht0
HIDROIAGNESITE
51q0.UCOz. 58,O
AUTINITE
a~,(o~),co,.3~,o
RHODKHBOS ITE
bC0.
IITPOBIHIT E
B(. UO,),
1 4 7 215 175
CbLCIUI NIrRATE
C'(WO,)*
115 115
110,
2U7 267 l a 1
n 1 6 1 ~NITRITE
~ ~ I
~g(wo,),
7 0 233
uIrm
'0
41.301
0.04
-61140
1674
-6h254
1757
11.607
0.308
1 2 0 263 115
261
U54.3yq
71.84
1). 10
-105uJ7
1674
-102203
2552
11.906
0.4u7
163 163
32 2U7
~5.dl
0.06
-1210850
2 3 0
-1lJ22lU
1240
198.359
0.391
120
181.31
6.28
IIAGNFSITE
nqc0.
2 ~ 4 . 7 7 ~115.48
1.67
n41,
nALACHIrE
cu,(CO,)( 08).
31
CARBONATES AND NITRITE5

SULFATES AND BORATES
197.349
112.13
2.09
196. 1 8 2
ARAGONITE
CaCu,
VATERITE
CdCOI
100.08~
87.99
0. 20
34.15
0.05
-1207'30
141J
-1127793
1464
197.586
0.256
2 4 3 2 l U 11'
100.089
91.71
0. 20
36.934
0.015
-1207370
1339
-1128842
1
197.769
0.242
1 4 3 21n
100.089
118.104
- 1 1 2 5 5 ~ 0 197.191
J7.63
0.07
48.7
0.4
-1498290
1170
1500
0.26J
-1361600
1130
238.548
0.198
.256
lo6
239.32
1. 20
-3U40840
-1099852
543.084
1800
1880
0.329
162 162 1 3 9
P R O P E R T I E S AT 2 9 8 . 1 5
T H E B I O D Y N A l I C P R O P E Q I I E S O F LIlYERALS
26
27
------------------------------------------------------------------------------------------------------Formula
Name and formula

N a m e and f o r m u l a
Entropy
reiqht
9
J/nollK
nolac
volume
cm'
, a ~ g , ~ 9a ~~
J/wl
------------------ -------.........................................................................
PHOSPHATES,
SULFATES AND BOBATES
IOLIBDATES.
CHROIATES.
URINATES.
IND TUNGSTITBS
FLUORAPATITE
Ca,(PO.),P
STRENGITE
FeP0..2Hs0
POYELLITE
canoo,
P K R R I C SULFATE
Pe2(S0.)a
SZOIOLNOKITE
~eso.-H.O
D l C E S I U n URANATE
CS.UO.
D I S O O I U U URANATE ( A L P H A )
NIzUOA
S U L F U R I C ACID ( L I Q U I D )
H2SO.
T R I S O D I U I URANIUM OXIDE
Na,UO.
ARCANITE
K.50.
POTASSIUB
ALUIIUUI
K A l ( S o . ).
SCHEELITE
Cauo.
SULPATE
FERHERITE
FeUO,
ALUNITE
KzA~~(O~)IO(SO
) +I
HUEBNERITE
mnuo,
EPSOIITE
MgS0.-7H20
STOLZITE
PbUO.
U ~ N G A N E S SULPATE
E
llllso.
IASCAGNITE
(NH+ )iSO.
OPTHO AND RING STRUCTURE S I L I C A T E S

KYANITE
lil.SIOS
AUDILUSITE
A1,SiOs
R E T G E R S I T ~ (ALPHA.
GREEN
UULLITE ( 3 - 2 )
3A1,0,-2Si0,
UiS0.-6H20
ANGLESITE
PbSO.
CELESTITE
brsv.
ZINKOSITE
Z"S0.
GEHLENITE
Ca.Al,sio,
BIANCHITE
zns0.-bH20
BORAX
Na,H.O,-
10HzO
PHOSPHATES,
MOLYBDATES,
CHROIATES.
URINATES.
AND TUNGSTATES
BERLINITE
IlPO.
.(
YHITLOCKIT E
PO. )Z
ca
BIDROXIAPATITE
Ca.(PO,).OH
: , 1~.09 ~nf ~
J/mol
......................
556.367
390.37
1.67
159.6
0.2
-6669259
5000
-6286093
5000
1101.302
0.876
120 2 1 4
150
.................................................................................
52
References
AH'
c0
:---!
AGO
TBBRllODXllABIC P B O P E D T I E S O F I I I E P A L S
PROPERTIES AT 2 9 8 . 1 5
L O Kf
~
l a m e and f o r m l l l a
Befarences
&no
S A G O c0
5--!
r o r m ~ 1 a ~ ~ t r a solar
p ~
, a ~ : , ~ ~a ~ ~ ;
weight
s'&~ volume
3'
J/mol.K
c.1
~/mol
~/mol
--.-----...---------------.-n a m e a n d formula
FRAEEWORK STRUCTUBE S I L I C A T E S
PORSTERITE
Ig.si0.
ALBITE
ua A l S i P .
IOU
laAlSi.0.
GLASS
l a AlSi.0.
CHAIN AND BAND STRUCTURE S I L I C A T E S

DEHYDRATED ANALCInE
naAlSi.0.
SHEET STRUCTURE S I L I C A T E S
CA-Al PYROXENE
CaA1.SiO.
DIOPSIDE
caag(sio,),
XAOLINITE
AltSi20r(OH).
ALPBA SPODUIENE
LiAlSi.0.
BETA SPODUIENE
LiAlSi,O.
EUCRYPTITE
LiAlSiO.
CLIUOENSTATITE
IgSiOl
RHODONITE
Insio.
TREBOLITE
ca,w,[si.o,,l(oH),
PRA!iEYORK STRUCTURE S I L I C A T E S
HEXAGONAL ANOATBITE
CaAl,si,o.
LEONRABDITE
Ca.Al.Si.0,.-7~.0
BlGB SAUIDINE
KAlSi,O.
K11Si.O.
KAISilO.
GLASS
KALIOPBILLITE
KAlSiO.
rf ~
L~ O ~~
---- - ..................................................
ORTBO AND RING STRUCTURE S I L I C A T E S
TEPHBOITE
an,sio.
29
Beterances
S
A
h 68'O
c0
!---!
PROPERTIES AT HIGH TEUPERATURES

30
FORHULA WEIGHT
SILVER (REFERENCE STATE)

.................................................................................
Aq:
Face-centered
c u b i c c r y s t a l s 298.15
t o neltinq point
1 2 3 4 K.
ALUUIUUU (REFERENCE STATE)

.................................................................................
107.868
1:
L i q u i d 1234
Face-centered
FOBUULA YEIGHT
t o melting point
9 3 3 K.
26.982
Liquid
933
t o 1800 K.
................................................................................
................................................................................
PORBATIOU PROM THE ELEMENTS

GIBBS
EUTHALPY
FREE EUEPGX
FORHATION FROH THE ELEUENTS

GIBBS
TEHP.
(H;-H;~~)/T
S;
.................................................................
kJ / r n O l
K
J/.oL-K
J/nol.K
J/mOl-K
J/aol.K
kJ/mol
................................................................................
298.15
0.000
UNCERTAINTY
42.55
0.21
42.55
0.21
25.40
0.000
0.000
298.15
0.000
UNCEBTAI NTY
0.000
_______~____~______------------------------------------------------------------MELTING POINT
1234
ENTHALPY OF HELTING
4 9 8
31
THERUODY NAUIC PROPERTIES OF BIN EBALS
1 1 . 9 4 5 kJ
5.745
H:
kJ
BOILING P O U T
ENTHALPY OF VAPORIZATION
flOMR VOLUHE
2436
154.303
1.0272
10.272
28.35
0.08
28.35
0.08
24.31
,A
-., ---
,,.,a
................................................................................
BELTING POINT
933.25 K
E~THALPY OF HELTING
10.711 k J
BOILING POINT
2793
190.775 kJ
kJ
'2098
J/bX
cm3
H:
TRANSITIONS IN
4.565
kJ
HOLAB VOLUUE
0.9999
9.999
R E F E R E N C E STATE E L E M E U T S
J/bar
cm3
TRANSITlONS I N REFERENCE STATE ELEHENTS
HEAT CAPACITY EQUATION

C;
................................................................................COMPILED
REFERENCE
107
35
4-10-76
27.237 6 . 5 6 7 4 ~ 1 0 - ~T
(EQUATION VALID FROH
298
1 . U 3 1 0 x 1 0 - 5 TZ
9 3 3 . 2 5 K)
1 . 0 9 1 6 ~ 1 0 5 T-2
--..............................................................................
REFERENCE. 1U7
35
COUPILED
32
THERMOOY N l MIC PROPERTIES OP IINERAZS

PROPEPTIES AT H I G H TEMPERATORES
FORMULA UEIGHT
ARGQN (REFERENCE STATE)

..
. -. .-. .-. .-. -. .-. .-. -. .-. .-. .-. .-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
33
39.948
ARSENIC ( REPERENCE STATE)
PORMULA YEIGBT
74.922
...................................................................................
Ar:
I d e a l g a s 298.15
to
1800 K.
t o s u b l i r a t i o n p o i n t 8 7 5 K.
Rhombohedra1 c c y s t a l s 298.15
AS:
Ideal
t e t r a t o m i c g a s 8 7 5 t o 1 8 0 0 K.
___________________--------_----------------------------A-----------------------
EflRIATION PROI THE ELEMENTS

GIBBS
TEnP.
( H ; - H ; ~ )/T
~
J/mol-K
-(G;-H:~~)/T
S;
J/mol.K
J/mol.K
C;
J/nol-K
ENTHALPY
kJ/mol
Log K f
FREE ENERGY
TEMP-
kJ/.Ol
___________________--------__--_-------_----------*-----------------------------
298.15
0.000
UNCERTAINTY
154.84
0.02
154.84
0.02
20.79
0.000
-------------------------------------------------------------------------------
0.000
0.000
(';-~;98
)/T
-(G:-H~~~)/T
S:
C:
MRIIATIOY FROB THE ELIMEITS

GIBBS
FREE E N E R G V
Log Kf
EITBALPY
.
_--------------------------------------------------------------------------------
298.15
0.000
UNCERTAINTY
35.69
0.84
35.69
0.84
24.65
0.000
0.000
0.000
400
500
600
700
BOO
875
___________________-----_------------------------------------------------------UELTIUG POINT
ENTHALPY OF IELTING
Hi
83.80 K
1. 176 kJ
6. 197 k J
BOIL1 NG POINT
EYTHALPY OF VAPOBIZATION
MOLAR VOLUHE
87-30 K
6.561
kJ
2478.92 00 J < a r
24789.200
cm
-------_-----------------------------------------------------------------------HELTING POINT
BOIL1 W POINT
875
ENTEALPY OF MELTING
kJ
ENTHALPI OF VAPORIZATION
34.828
kJ
kJ
MOLAB VOLUME
'i98
TRANSITIONS IN REPERENCE STATE ELEHENTS
H:
5.130
1.2963
12.963
TRANSITIONS I N REPERENCE STATE ELEIENTS
_-_________________------*--------------------------_---------------------------
REFERENCE
107
35
COMPIL ED
3-11-76
BEAT CAPACITY EQUATIOMS
____________________--_----_-_--__--------_------------------------------------C;
C:
20.845 + 6.3265110-3 T
( EQUATION VALIO FROM
21.139
9.1839110-5
T
(EQUATION VALIO PROM
+
298
875
52.398 T - 0 - s
8 7 5 K)
9.1807
T-0-,
1200 K)
9.8777110.
T-*
1.1342110.
T-2
J/bar
cm3
34
PROPERTIES AT HIGH TElPEBATURES
THERlOOYUAlIC PROPERTIES OF BINERALS
GOLD ( REFERENCE STATE)

.................................................................................
Face-centered
Au:
1336.15
FORIULA UEIGHT
t o m e l t i n g p o i n t 1336.15
K.
BORON (REFERENCE STATE)
196.966
FORLIULA WEIGHT
...............................................................................
E h o m b o h e d r a l c r y s t a l s 298.15
8:
t o 1800 R.
t o melting p o i n t 2300 K.
................................................................................
PORIATION FROB THE ELEMENTS

GIBBS
(H;-H:~~
)/T
- ( G ; - H ; ~ ~)IT
S;
C;
ENTHALPY
l o g K~
FREE E N E R G Y
47.49
0.21
25.32
400
500
600
700
800
900
1000
55.00
60.82
65.64
69.76
73.38
76.63
79.61
48.49
50.39
52.55
54.72
56.83
58.85
60.77
25.88
26.27
26.57
26.92
27.36
27.94
28.67
6.512
10.428
13.093
15.043
16.554
17.784
18.835
0.000
.ooo
.000
.000
.000
.000
.ooo
.ooo
1336. 1 5 K
0.000
0.000
12.364
- HP)
4 9 8
6.017
kJ
kJ
J/mol-K
J/mol.K
5.90
0.08
11.09
5.90
0.08
FORIATION PBOl TBB ELEnEUTS

GIBBS
FREE E N E R G Y
LO^ K~
EYTHALPY
kJ/mol
0.000
0.000
0.000
-000
.000
.000
-000
.000
.000
.(roo
-000
-000
8ELTING POINT
3130
2300
ENTHALPY OF MELTING
ENTHALPY OF IELTING
C;
.ooo
.000
.000
.000
-000
BOILING POINT
J/mol.K
298.15
0.000
UNCERTAINTY
................................................................................
HELTING POINT
J/mol.K
-(G;-H&~)/T
k~j.01
................................................................................
K
J/aol-K
J/mol-K
J/nol.K
J/mol-K
kJ/mol
................................................................................
47.49
0.21
( H ; - H ~ ~ ~ ) / T S;
TEIP.
kJ/mol
298.15
0.000
UNCERTAINTY
10.810
Llquld
___________________------------------------------------------------------------TEIP.
35
ENTHALPY OF VAPORIZATlON
335.054
lOLAR VOLUIE
1.0215 J / b a r
10.215
co3
kJ
22.552
- ~H:
BOIL1 N
G POINT
1.222 k J
4275
ROLAR VOLUNE
kJ
0.4386
4.386
TRANSITIONS I N REFERENCE STATE ELElENTS
J/bar
cm3
TRANSITIONS I N REFEEENCE STATE ELEUEYTS
HEAT CAPACITY
4UATION
HEAT CAPACITY EQUATIONS

0
C;
41.968
1.7696~10-' T
(EQUATION VALID FROU
1 . 1 2 3 2 ~ 1 0 - 5 Tz
2 9 8 - 1 3 3 6 . 1 5 K)
+
Cp
2.1606x102
T-o-s
' 66.520 -
-'
107
107
298
4 . 9 0 6 7 ~ 1 0 - 6 Tz
9 . 3 5 2 7 ~ 1 0 2 T-0-5
1 8 0 0 K)
107
107
................................................................................
1800 K )
................................................................................
REFERENCE
................................................................................
REFERENCE
- 1 . 8 4 3 1 ~ 1 0 * T-2
@OATION VALID PROI 1 3 3 6 . 1 5
1.7059~10-2 T
.2.8390xlOS T-z
( EQUATION VALID FROI
COlPILED
5-03-76
COlPILED
5-04-76
36
PROPERTIES AT RLGU TKBPKRATORKS
THERIODJIIAHIC PBOPERTIES OP BINEBALS
37
-------------------------===-------____---____-_----__---------===_______---___------------
B L g L L ~ O n ( E K F E B E ~ ~ STATE
CE
FORKILA WEIGHT
9.012
ssss=205==================I===============================----LI==I====I===EISI==-=
Ba:
8A RIUB ( REFERENCE STATE)

--------------------------)I==___
POBBOLA YEIGM
137.330
--------========
Body - c e n t e r e d c u b i c c r y s t a l s 298.15 t o s e c o n d - o r d e r lambda-anomaly i n

h e a t c a p a c i t y a t 582.53 K .
Beta c r y s t a l s 582.53 t o s e c o n d - o r d e r lambdaanomaly i n h e a t c a p a c i t y a t 768.13 K .
Gamna c r y s t a l s 768.13 t o m e l t i n g
p o i n t 1002 K.
L i q u i d 1002 t o b o i l i n g p o i n t 2169 K.
................................................................................
TEBP.
HI-H
)IT ~ S;
~ ~ - ( G ; - H ; ~ ~)IT
J/mol. K
J/mol-K
J/mol-K
62.42
0.84
62.42
0.84
cOp
a e x a g o n a l c l o s e packed c r y s t a l s 298.15
meltlug
kJ/mOl
k J/mOl
B e t a c r y s t a l s 1527 t o
L i q u i d 1560 t o 1800 K.
......................................................................
___------
FOBUATIOU FROB THE ELEBEIITS

GIBBS
ENTHALPY
PBEE E U E B G Y
~ o g
J/mol-K
p o i n t 1560 K.
t o 1527 I .
( R ; - B ~ ~ ~ ) / T S;
I(
j/.ol.K
-(<-H;~~)/T
J/mol-K
JDo1.K
C;
YORBATIOU FROB THE ELElSllTS

GIBBS
EUTRALPY
YBBKElERCI
Log Kf
J/mol.K
kJ/mol
kJ/mOl
--------------------------------------------------------------------------------
------- ........................................................................
298.15
0.000
UNCERTAINTY
298.15
0.000
~ICLITAIUT~
9.54
0.08
9.54
0.08
16.41
0.652
7.906
10.368
12.314
13.907
15.250
16.411
14.88
19.54
23.68
27.37
30.72
33.78
36.61
10.23
11.63
13.31
15.06
16.81
18.53
20.20
19.81
21.90
23.39
24.55
25.54
26-44
27.28
-000
-000
-000
-000
-000
.000
.000
.000
-000
000
-000
-000
.000
-000
.000
-000
.OOO
-000
.OOO
-000
.00U
17.438
18.363
19.213
20.005
20.755
20.964
39.25
41.73
44.08
46.33
48.48
49.00
21.81
23.37
24.87
26.33
27.73
28.03
28.12
28.97
29.85
30.77
31.74
31.84
-000
000
-000
-000
.000
.000
.000
.000
.OOO
.000
000
000
.OOO
.OOO
-000
-000
.000
.000
22.638
22.840
50.67
51.34
28.03
28-49
32.22
32.22
-000
-000
-000
.000
-000
-000
30.669
30.638
30.569
30.507
59.16
60.00
61.79
63.47
28.49
29.36
31.22
32.96
29.46
29.45
29.45
29.45
.000
.000
.W0
-000
.000
-000
.000
000
-000
.000
.000
.OOO
28.09
0.000
0.000
0.000
600
0.000
0.000
0.000
................................................................................
...............................................................................
................................................................................
................................................................................
HE LTI NG POI NT
1002
ENTHALPY OP BELTIWG
498
BOILING POINT
7.749
ENTHALPY OF VAPORIZATIOU
6.912
kJ
IOLAB VOLUHE
2169
kJ
mlZIUG POIUT
L'TH~p~OPBELTING
43.154
2.5318110-3 T
(EQUATION VALID PROH 1002
1800 K)
................................................................................
REPEREWE
107
107
1560
801 LI W i POI YT
2795
EIITRALPY OF VAPORIZATIOU
326.51 9 k J
12.213kJ
1.954 k J
nA'SITfOu~
TRANSITIONS I N REPWEUCE STITE ELEHENTS
C;
COBPILED
7-27-76
___________________-------------------------------------------------------------
I N REFERENCE STATE ELEHEUTS
BOLAB VOLUBE
0.4880
4.880
J/bar
cm3
P R O P E R T I E S AT HIGH T E I P E B A T U R E S
38
THERIOOYNABIC
F O R I U L A WEIGHT
BISHUTH (REFERENCE S T A T E )
...................................................................................
R h o m b o h e d r a 1 c r y s t a l s 298.15
Bi:
39
P R O P E R T I E S OF I I N E R A L S
to melting
p o i n t 544.5
K.
208.980
544.5 t o
Liquid
B R o u ~ E( R E F E R E N C E S T A T E )
PORBULA Y E I G H T
159.808
...............................................................................
t o b o l l l n g p o i n t 3 3 2 K.
~ i q u l d298.15
8r2:
I d e a l d l a t o m l c gas 332 t o
1 8 0 0 K.
..........................................................................
___---
................................................................................
FORHATION FROII T H E ELEBENTS
GIBBS
TEBP.
(H;-H,OY8)/T
- ( G - H ~ ~ ~ C:) / T
S;
ENTHALPY
P R E E ENERGY
~ ~ a p . ( H ; - H : ~ ~ )/T
~ / n o l . ~ ~/mol-K
~/mol-K
~/mol-K
kJ/mol
0.000
56.74
0.42
UNCERTAINTY
56-79
0.42
25.41
0.000
J/mol-K
C;
J / m o l -K
J/mol.K
152.32
0.04
152. 3 2
0.04
36.06
kJ/no1
kJ/.0l
.............................................................................
kJ/mol
................................................................................
298.15
-(G;-H~~~)/T
L O 9 Kf
J/moleK
S;
FURHATIOM FROB T H E E L E I E N T S
GIRBS
ENTHALPY
P R E E ENERGY
L o g Kf
298.15
0.000
0.000
0.000
0.000
0.000
0.000
.000
.000
................................................................................
.0o0
UNCERTAINTY
1600
7.837
160.36
152.53
96.69
96.694
86.535
76.618
70.040
65.371
61.886
59.184
57.032
249.33
256.16
264.40
271.17
276.93
281.94
286.36
290.33
152.53
169.63
187.78
201. 13
211.56
220.05
227.18
233. 30
36.33
36.73
37.07
37.29
37.45
37.57
37.67
37.76
-000
-000
.000
.000
.000
-000
55.278
53.820
52.593
51.544
50.640
49.852
49.159
48.546
293.93
297.22
300.25
303.06
305.68
308.13
310.44
312.62
238.65
243.40
247.66
251. 51
255.04
258.28
261.28
264.07
37.84
37.91
37.98
38.05
38.11
38.18
38.24
3.3.31
.000
-000
-000
-000
-000
-000
.000
w 0
.ooo
.ooo
-000
-000
-000
-000
.ooo
.ooo
.000
-000
.000
-000
-000
.000
.000
.000
-000
-000
-000
-000
.000
-000
.ooo
.ooo
.ooo
.ooo
-000
-000
000
.000
.000
-000
.000
.000
--------------------------------------*-----------------------------------------
-__-_______________------------------------------------------------------------544.52
W L T I N G POINT
11.297
ENTHALPY O F B E L T I N G
'z98
BOILING POINT
kJ
IIOLAR VOLUBE
~ L T I U GPOINT
265.90
B O I L 1 NG P O I N T
332
E P T H A L p ~O P B E L T I N G
10.573
ENTHALPY O F V A P O R I Z A T I O N
29.556
k J
24.520
kJ
IIOLAR VOLUBE
kJ
ENTHALPY O F V A P O R I Z A T I O U
6. 4 2 7 k J
H:
1835
2.1309
21.309
5.U580
54.580
J b a r
cm3
TB'nS1nO~~
IN
REFERENCE S T A T E E L E I E N T S
J/bar
cu3
T R A N S I T I O N S I N R E F E R E N C E S T A T E ELEIIENTS
CAPACITY
HEAT C A P A C I T Y
EQUATION
EC! UATIONS
Ci
= 18-426
1.7289~10-2 T
( EQUATION V A L I D FROB
C;
26.852
C;
29.827
+
1.3663~10-7 T2
( EQUATION V A L I D FROB
332
4 . 1 8 0 2 ~ 1 0 - ~Tz
298 - 544.52 K )
22.423 T-O.5
1800 K )
9.5885.10.
T-*
107
1.3600rl0Z
i 0 . 5
+
EQUATION V A L I D FROM
544.52
1 . 9 2 1 3 ~ 1 0 T-'
~
- 1800 K)
...........................................................................
_-_________________------------------------------------------------------------REFERENCE
76
107
COBPILED
4-1 0-76
-_______-__________-------------------------------------------------------------
COMPILED
3-11-76
40
THERHODYNAMIC PROPERTIES 0 1 HINERALS

PROPERTIES AT HIGH TEMPERATORES
CARBON ( REFERENCE STATE)

-.............................................................................
- - - - - - - -- -
P O B H ~ L A WEIGHT
41
12.01 1
FORMULA WEIGHT
12.011
..................................................................
C:
G r a p h i t e 298.15
t o 1 8 0 0 K.
C:
~ r a m o n d2 9 8 . 1 5
t o 1800 L
___________________------------------------------------------------------------(H;-H&,~)/T
TEHP.
FORHATION PROH THE ELEMENTS

GIBBS
SOT
- ( G ~ - H ; ~ ~ ) / T cOp
ENTHALPY
FREE ENERGY
K
~ / m o l . ~ J/mol-~
J / ~ o ~ . K J/mol-K
kJ/mol
kJ/mol
___________________-------------------------------------------------------------
298.15
0.000
UNCERTAINTY
5.74
0.01
5-74
0.01
8.53
0.000
0.000
_________------_----------------------------------------------------------------
l o g K~
0.000
TEaP.
( H ; - H ; ~ ~ )/T
J/mol-K
-(G;-H;~~)/T
S;
J/Uol-K
298.15
0.000
UKERTAINTY
J/mol- K
2. 38
0.01
C;
POBUATION PROH THE ELEHENTS

GIBBS
ENTHALPY
FREE ENERGY
LO^ K~
J/mol- K
kJ/mol
kJ/mol
2.38
0.01
6.13
1.895
0.042
2.900
0.084
-0.508
0.015
5.873
7.479
8.890
10.132
11.233
4.76
7.42
10.13
12.76
15.27
17.63
19.86
2.67
3.35
4.26
5.28
6.38
7. 50
8.63
10.23
13.59
lb.12
18-01
19.47
20.64
21.62
1.686
1.547
1.455
1.393
1.351
1.324
1.316
3.274
3.687
4.125
4.578
5.031
5.491
5.956
-0.428
-0.385
-0.359
-0. 342
-0.328
-0.319
-0.311
12.218
13.110
13.929
14.693
15.416
16.111
16.788
17.457
21.96
23.95
25.86
27.68
29.44
31.15
32.83
34.47
9.74
10.84
11.93
12.99
10.02
15.04
16.04
17.01
22.50
23.34
24.18
25.07
26.02
27.06
28.21
29.49
1.330
1.374
1.457
1.591
1.787
2.059
2. Y19
2.883
6.423
6.882
7.333
7.793
8.222
8.651
9.032
9.435
-0.305
-0.300
-0.295
-0.291
-0.286
-0.282
-0.278
-0.274
___________________------------------------------------------------------------UELTING POINT
ENTHALPY OP HELTI NG
'2"98
kJ
1.050
kJ
BOILING POINT
HOUR VOLUME
----------------_---------------------------------------------------------------
kJ
E L T I NG POINT
0.5298 J/baC
5.298
cB3
E ~ ~ T H A L POY
P BELTING
BOIL1 NG POINT
ENTH ALPY OF VAPORIZATION
kJ
0.523 kJ
TRANSITIONS I N REFERENCE STATE ELEHENTS
HOLAB VOLUME
kJ
0.3417
3.417
T B A n = ~ rn~ R
~ E ~P E ~R E N C E S T A T E E L E H E N T S
J b a c
ca3

C w A C I T y QUATION
98-445
_--_______________-------------------------------------------------------------REFERENCE
107
107
COMPILED
3-11-76
3.6554~10-ZT
1 . 2 1 6 6 ~ 1 0 6 T-2
(EQUATION VALID PRO8
298
1 . 0 9 7 7 ~ 1 0 - * Tz
1 . 6 5 9 0 ~ 1 0 . T-0-S
1800 K)
--------------------------------------------------------------107
87
COMPILED
5-19-76
PROPERTIES AT HIGH TEUPERATURES

42
43
THERUODYNAUIC PROPERTIES OF UINERALS

FORUULA YEIGHT
CALCIUn (REFERENCE STATE)
FORUULA Y EIGHT
Ca:
Alpha c r y s t a l s ( f a c e - c e n t e r e d c u b i c ) 298.15 t o 7 2 0 K .
Beta c r y s t a l s
( b o d y - c e n t e r e d c u b i c ) 7 2 0 t o m e l t i n g p o l n t 1 1 1 2 K. L i q u l d 1 1 1 2 t o b o l l i n g
p o i n t 1755 K .
I d e a l monatomic g a s 1755 t o 1800 K.
~ ~ l a g o n ca llo s e p a c k e d c r y s t a l s 2 9 8 . 1 5
Cd:
594.18
t o b o i l i n g p o l n t 1039 K.
t o m e l t i n g p o l n t 594.18
( H;-H;~~)/T
TERP.
J/mol-K
-(G;-H;~~)/T
S;
J/mol.K
J/mol- K
C:
J/mol- K
kJ/mol
kJ/mol
-------------------------------------------------------------------------------298.15
0.000
UNCERTAINTY
41.63
0. 42
41.63
0.42
25-30
0.000
0.000
0.000
( N ; - H ~ ~ ~ ) / TS ;
TEnP.
Llquld
K.
I d e a l monatomic g a s 1 0 3 9 t o 1 8 0 0 K.
-------------------------------------------------------------------------------PORNATION FROU THE ELEUENTS

GIBBS
ENTHALPY
FREE E N E R G Y
LO^ K~
112.410
.......................................................
40.080
................................................................................
................................................................................
-(G:-H;~~)/T
PORIATION PROR THE ELEUENTS

GIBBS
ENTHALPY
FREEENERGY
~ o K=
g
C;
~/.ol-K
J/mol*K
J/aol-K
J/mol-K
kJ/mol
kJ/mol
298.15
0.000
VYCEBTAINTY
51.80
0.17
51.80
0.17
25.98
0.000
6.760
10.958
13.811
59.59
65.78
70.79
52.83
54.82
56.98
27.14
28.37
29.53
-000
.OOO
.OOO
-000
.00U
-000
.000
.000
-000
24.232
24.285
25.059
25.640
81.21
81-48
86.06
90.03
3
96.66
97.97
56.98
57.19
61.00
64.39
67.44
70.21
71.44
29.71
29.71
29.71
29.71
29.71
29.71
29.71
.OOO
.000
-000
.000
-000
-000
-000
.000
.000
000
-000
-000
-000
.000
-000
.OOO
000
-000
-000
.000
-000
___________~__---_-------------------------------------------------------------
500
594.18
0.000
0.000
___________________---------------------------------------------------------594.18
800
26.453
26.529
___________________-----------------------------------------------------------
1112
BOILING POINT
122.455
193.90
71.44
20.79
-000
-000
.0 0 0
1100
1200
13U0
116.817
108.814
102.043
96.239
91.209
86.807
82.924
79.472
194.88
196.69
198.35
199.89
201.33
202.67
203.93
205.12
78.06
87.88
96.31
103.65
110.12
115.86
121.01
125.65
20.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
.000
.OOO
000
.000
.000
-000
-000
-000
.000
-000
.000
000
000
000
-000
-000
.000
.000
-000
.000
-000
-000
-000
.000
BELT1 NG POINT
1755
4 9 8
H:
8.535kJ
5.707
UOLAR VOLUUE
kJ
.
.
.
594.18
BOILING POINT
1039
E I T H a L p ~ OF UELTING
ENTHALPYOFRELTING
-----------_--------------------------------------------------------------------
................................................................................
UELTING POINT
1039
153.675
6. 1 9 2 W
6.251
UOLAR VOLUnE
99.667
kJ
kJ
kJ
1.3005 J / b a r
13.005
cm3
T B h N S I I ~N ~R E
~F ~
E R~E N C E S T A T E E L E U E N T S
TRANSITIONS I N REFERENCE STATE ELEUENTS
CAPACITY E Q U A T I O N S
HEAT CAPACITY QUATIONS
C:
' 3-8115x10-2 T
- 1 . 2 8 7 7 ~ 1 0 s T-2
298
107
3 . 0 0 U U ~ 1 0 2 T-0.5
594. 1 8 K)
~1 0 7 ~
107
~
...........................................................................
_________-____----_------------------------------------------------------------107
298
~z
.......................................................................
-0.34497
4.1256~10-2 T
- 8 . 5 2 8 5 ~ 1 0 3 T-2
( a U A T 1 O N VALID FROn 7 2 0 - 1 1 1 2 K)
REFERENCE
1. 4 3 3 6 x 1 0 - s
720 K)
P
C;
1.3402~10s T-2
(EQUATION VALID FROB
CO~PILED
4- 1 0 - 7 6
~________-____------------------------------------------------------------------
LOUPILED
5-06-76
44
THBRIODINILUC PROPERTIES OF IIINERALS
CERIUH (REFERENCE S T I T E )
PBOPERTIES AT HIGH TEMPEBATOBES
FORMULA YEIGHT
------------------------------===========z==============================r==*===m
..............................
Ce:
A l p h a c r y s t a l s ( f a c e c e n t e ~ e dc u b l c ) 2 9 8 . 1 5 t o 9 9 9 K .
140. ( 2 0
C a o I I N ~(REFERENCE STATE)
1 0 7 1 K.
(H;-H;~~
)IT
J/uiol'K
5;
B e t a c r y s t a l s 999
- ( G ~ - H ; ~ ~ ) / T :C
J/.Ol.K
d r a t o m l c g a s 298. 15 t o 1 8 0 0 K.
FORBATION PROM THE ELEMENTS

GIBBS
ENTHALPY
FREE EPEBGY
L~~
J/Do~-K
J/m0lSK
kJ/mol
Kf
------
........................................................................
ZUIP.
(,,;-H;~~)/T
kJ/mol
69.46
8.37
69.46
8. 37
26.93
0.000
400
500
6 00
700
800
900
999
7.030
11.422
14.592
17.076
19.139
20.927
22.344
77.56
84.03
89.57
94.50
98.98
103.13
106.81
70. 53
72.61
74.98
77.42
79.84
$2.20
84-47
28.29
29.70
31.20
32.77
34.40
36.07
37.76
-000
-000
-000
-000
0 00
0bb
-000
999
1000
107 1
25.452
25.519
26.318
109.92
110.01
112.65
84.47
84.49
86.33
37.61
37.61
37.61
-000
-000
000
107 1
31.416
117.75
86.33
37.70
.
.0 0 0
1100
1200
1300
1400
1500
1600
1700
1800
31,582
32.092
32.523
32.892
33.213
33.493
33.741
33.960
118.70
121.98
124.99
127.79
130.39
132.81
135. 11
137.26
87.12
89.89
92.47
94.90
97.18
99. 3 3
101. 37
103.30
37.70
37.70
37.70
37.70
37.70
37.70
37.70
37.70
.OOO
.OOO
.000
-000
.000
.000
.OOO
.OOO
0-000
.
.
................................................................................
................................................................................
U E L T I NG P O I N T
ENTHALPY OF MELTING
':98
1071
5.460
J/mol-K
223.08
0.04
223.08
0 . 04
33.98
8.830
8
2
4
22.629
24.251
25.565
233.26
241.22
247.84
253.M
258.44
262.82
266.76
229.43
227.02
229.96
232.93
235.81
238. 57
241. 1 9
35.26
36.03
36.54
36.88
37.13
37.31
37.45
-000
.000
.000
.000
-000
.OOO
-000
26.650
27.563
28.342
29.016
29.603
30.123
30.585
31.001
270.34
273.61
276.63
279.42
282.03
284.48
286.78
288.96
243.69
246.05
248.29
250.40
252.43
252.36
256.19
257.96
37.56
37.65
37.73
37.80
37.87
37.95
38.03
38.11
.000
.OOO
.OOO
-000
-000
.000
-000
.000
aerrrc
kJ
t F I a A ~ p l OF MELTING
C;
14.017 +
1.9292~10'2 T
( EQUATIONV A L I D FROM
172. 16 K
POINT
HOLAR VOLUHE
flA'S1rlOn~
H E A T CAPACITY EQUATIONS
+
298
1 . 4 4 6 9 ~ 1 0 2 T-0.5
999 K )
1 . 0 8 0 2 ~ 1 0 5 T-.
J/mol. K
kJ/aOl
0.000
0.000
0.000
.OOO
-000
000
000
-000
-000
.OOO
-000
-000
-000
-000
.000
-000
-000
.
.
.U00
-000
.000
-000
-000
-000
.000
.000
-000
.000
-000
.OOO
-000
.000
-000
-000
...............................................................................
BOILI UG P O I N T
kJ/nol
J/mol-K
7. 280 k J
H:
1100
1200
1100
(400
c;
0.000
800
900
(000
-(G;-H;~~)/T
S;
PORUATION FROM THE 6LEIENTS

GIBES
ENTHALPY
FREE ENERGY
L O K~
..............................................................................
298.15
0.000
UNCERT IINTY
70.906
~ l q u l d1 0 7 1 t o 1 8 0 0 K.
...............................................................................
TE~P.
FORHULA UEIGHT
ylss=S'=S==r=======I-rE============================================================
Ideal
t o meltlng polnt
45
POINT
BOILING
6. 4 0 6 kJ
ENTHALPY OF VADORIZATIOl
9.180
MOLAR VOLUME
kJ
239.10
20.410
2478.9200
24789.200
J/bar
cm3
I N BEFEBENCE STATE ELEMEBTs
~ EQUATIO"
~
46-956
4-0158110-'
T
(XQuATrou V A L I D FROM
+
298
9 . 9 2 7 4 ~ 1 0 - 7 T*
1800 K )
2.0495x102
T-0-5
................................................................................
REPEBENCE
107
107
................................................................................
------____
35
CONPILED
3-11-76
46
T H E R H O D Y N A H I C P R O P E R T I E S O F U I NEHALS
COBALT ( REFERENCE S T A T E )
EFERENCE S T A T E )
A l p h a c r y s t a l s ( h e x a g o n a l c l o s e p a c k e d ) 298.15 t o 7 0 0 K Beta crystals

( f a c e c e n t e r e d c u b i c ) 7 0 0 t o melting p o i n t 1 7 6 8 K.
L l q u l d 1 7 6 8 t o 1 8 0 0 X.
C u r l e p o i n t a t 1394 K .
Co:
4 -7
P R O P E R T I E S AT H I G H T E H P E R A T U B E S
FOBNULA
c u b i c c r y s t a l s 298. 1 5 t o r n e l t l n g
Body-centered
polnt
51.996
WEIGHT
2 1 3 0 K.
_______________-~-_----------------------------------------------------------FOHUATION
(H;-H;~~)/T
TEHP.
K
J/mol-K
- ( G % - H ~ ~ ~ ) / T
C;
S;
J/mol.
J/mol.
J/mol.
ENTHALPY
K
FROU T H E E L E H E N T s
GIBBS
F R E E ENERGY
Log
FOBHATION FROB T H t
K~
TIIIIP.
( H ; - H ~ ~)/T
~
30.04
0.42
30.04
0.42
24-31
400
500
600
700
6.542
10.710
13.752
16.138
37.58
43-68
48.96
53.64
31.04
32.97
35.21
37.49
26.56
28.19
29.70
31 - 0 5
700
800
900
1000
16.780
18.625
20.283
21.820
54.27
58.50
62.45
66-20
37.49
39.88
42.17
44.38
30.58
32. 58
34.55
36.85
110 0
1200
1300
1394
1400
1500
1600
1700
1768
23.313
24.834
26.446
28.150
28.236
29.115
29.727
30.21 3
30.500
69.84
73.46
77.12
80.67
80.88
83.72
86.23
88.53
90.00
46-53
48.63
50.67
52.52
52.64
54.60
56.50
58. 32
59.50
39.77
43. 52
48.26
53.70
44.22
39.75
38.28
37.78
37.74
-(G;-H&~)/T
J/molmK
J/MOl.K
C;
ENTHALPY
ELEHENTS
GIBBS
F R E E ENERGY
L o g Kt
kJ/mol
kJ/mol
________-_________~----------------------------------------------------------298.15
0.000
UNCERTAINTY
S;
j/sol-K
J/mol-K
kJ/mol
kJ/mol
0.bUU
0.000
0.000
0.000
.0 0 U
700
800
901,
1000
6.257
10.206
12.993
15.117
16.841
18.313
19.624
30.85
36.64
41-55
45.85
49.70
53.25
56.56
24.59
26. 43
28.56
30.73
32.86
34.94
36.94
25.45
26.48
27. 38
28.36
29.47
30.73
32.13
-000
.OOO
-000
.OOO
000
-000
.000
.DO0
.OOO
.000
-000
00U
-0uu
-000
.U00
.000
.000
-000
.000
00u
1100
1200
1300
1400
20.830
21.969
23.065
24.136
59.69
62.69
65.59
68.41
38.86
40.72
42.53
44-27
33.67
35.33
37.12
39-01
1500
1600
25.193
26.247
71.17
73.88
45.98
47.63
41.01
43. 12
.000
.00U
.000
.000
.u00
.000
-000
.ooo
.0UO
.00U
-000
.OOO
.OOO
.ooo
-000
-000
.u00
.000
1780
1000
27.304
28.368
76.56
79.21
49. 26
50.84
45. 32
47.61
.0 0 0
.ooo
-000
-000
.ooo
-000
500
____-______-___.___----------------------------------------------------------
1768
1800
59.50
60.30
99.16
99.98
39.660
39.678
40.50
4U.50
_____________~~____------------------------------------------------------------1768
HELTING P O I N T
16.191
ENTHALPY OF n E L T l N G
'2098
SOILING POINT
3201
kJ
E N T H A L P Y OF V A P O R I Z A T I O Y
376.551
LR"~pY
2130
OF HELTING
2945
16.933
344.314
kJ
4.058
kJ
HULAii VOLUUE
kJ
UOLAR VOLUUE
4. 7 6 6 k J
0.7131
J/bar
7.231
cm3
T R A N S I T I O N S IN REFERENCE STATE ELEUENTS
''
HEAT C A P A C I T Y E Q U A T I O N S
Ci=
4. 1 8 q q ~ 1 0 - 2 T
1.5b46xlUs T-2
(EQUATION VALID
1.6498~10-5 T L
107
107
1'3Mbqx10-2
+
T-'"
M-b742r105
3. 4 6 8 7 x 1 0 - 6
298
4.9535~102 T-0.5
298 -
l d g ~K )
700 K )
7 . 9 7 2 7 ~ 10-5
700
1394 K )
T*
T-2
( E Q U A ~ l O V~ A L I D PROW
FRon
2.8332~102
0. 1 9 7 9 1 T
( E Q U A T I O N V A L I D FROH
REFERENCE
2-6875110'
T~
4.056Yx103
T-O.'
................................................................
COUPILEU
5-19-76
THERMODY NAMIC PROPERTIES OF MINEBALS
CESIUB [ REFERENCE STATE)
FORMULA WEIGHT
-------------
.................................................................................
Body-centered
cs:
301.55
t o b o i l i n g p o i n t 942 K .
132.905
Liquid
K.
PROPERTIES AT HIGH TEMPERATURES
I1
COPPEH ( e e r a a e w c e S T A T E )
FORIATION FROB THE ELEMENTS
P a c e - c e n t e r e d c u b i c c ~ y s t a l s298.15
cu:
31.18
0.000
0.000
0.361
85.43
85.06
32.46
301.55
400
500
600
700
800
900
942
7.298
15.175
18.746
20.390
21.250
21.896
22.636
23.024
92.37
103.68
111.07
116.30
120.37
123.90
127.26
128.69
85.06
88.50
92.32
95.91
99.12
102.00
104.62
105.67
42.75
35.94
30.45
27.14
26.06
27.14
30.31
32.35
.OOOO
-000
-000
-000
.000
.000
000
-000
942
1000
93.844
89.606
199.51
200.75
105.67
111. 14
20.79
20.79
-000
.OOO
1100
1200
1300
1400
1500
lb0U
1700
1800
83.350
78.137
73.726
69.945
66.668
63.800
61.270
59.021
202.73
204.54
206.21
207.75
209.15
210.50
211.77
212.97
119.38
126.40
132.48
137.80
142.48
146.70
150.50
153.95
20.79
20.79
20.80
20.80
20.80
20.80
20.80
10.81
.000
-000
-000
.OOO
.OOO
.000
.000
000
L i q u i d 1356
KJBMATION PROM THE ELEMEWS

GIBES
FREE ENERGY
J/mol.K
,J/mol.K
298.15
0.000
ONCERTAINTY
0.000
.000
................................................................................
301.55
63.546
t o 1800 K .
85.23
0. 40
t o m e l t i n g p o i n t 1356 K.
K
J/mol-K
J/mol-K
J/mol-K
J/mol. K
kJ/mol
kJ/mol
................................................................................
85.23
0.40
O O R M U U WEIGHT
=======================L=========================================================
................................................................................
I d e a l monatomic g a s 942 t o 1800 K .
................................................................................
298.15
0.000
UNCERTAINTY
49
J/moleK
33.15
0.08
33.15
0.08
J/mol. K
kJ/mol
24.45
0.000
kJ/eol
0.00y
0.000
400
500
600
700
ROO
900
1000
..................................................................
................................................................................
..................................................................
BELTING POINT
301.55
ENTHALPI OP MELTING
2.092
BOILING POINT
kJ
MELTING POINT
942
67.712
K
kJ
-4
"98
~11:
7.711
kJ
MOLAR VOLUME
1356.55
E ~ T B I L P I OP MELTING
13.054 kJ
5.004
kJ
BOILING POIYT
2836
EWTHALPY OF VAPOBIZATIOU
300.340
kJ
MOLAR VOLUME
0.7113 J / b a r
7.113
cm3
T~AMSITIONSI N REFEaENCE STATE ELEMEUTS
TRANSITIONS I N REFERENCE STATE ELElElTS
REAT CAPACITY EQUATION

C;
C;
= -9.2360~10-2 T
C:
8 . 6 4 0 0 ~ 1 0 - S TZ
i . 3 8 9 6 ~ 1 0 * T-2
EQUATION VALID FROB
301.55
20.783 t 7 . 1 9 2 2 ~ 1 0 - * Tz
( e p u r T r o r V A L I O Pnon 942
942 K )
- 1800 K )
...............................................................................
REPEBEWCE
107
35
1 . 3 5 4 9 ~ 1 0 3 T-0's
n
29.764 +
1.6124~10-3 T
(EQUATION VALID PROM
p
~107 ~
U
35
298
3 . 4 1 1 0 ~ 1 0 - 7 Tz
1356.55 K)
1 . 0 0 6 7 ~ 1 0 2 T-0.5
-----...........................................................................
COMPILED
5-12-76
52
PROPERTIES AT HIGH TEIIPERATUBXS
THERIODYUAIIC PROPERTIES OF IIYERALS
EOROPIUI (REPERENCE STATE)

.............................................................................
...........................
Eu:
Body-centered
FORIULA UEIGBT
151.960
p L u o a r NE ( a e r ~ ~ e a cSTATE)
e
53
FORIULA WEIGHT
37.997
.......................................................
t o n e l t i n g p o i n t 1 0 9 0 K.
Liquid
I d e a l d i a t o m i c gas 2 9 8 . 1 5
p,:
t o 1 8 0 0 K.
1 0 9 0 t o b o i l i n g p o i n t 1 8 7 0 K.
----___-___________-------------------------------------------------------------_-___--------------------------------------------------------------------------POBIATIOY PROl THE ELEIEYTS

TEap.
(H;-Hig8)/l'
SOT
- ( G $ - H ~ ~ ~ ~ ) / C:
T
PORIATIOY PRO0 THE BLEIIEYTS

GIBES
EUTHALPI
FREE EUEBCI
l o g Kf
K
J/mol.K
J/mol.K
J/mol - K
J/mol-K
kJ/mol
kJ/mol
-______-___________-------------------------------------------------------------
298.15
0.000
UNCERTAINTY
80.79
0.16
80.79
0. 1 6
27. 1 2
0.000
0.000
0.000
................................................................................
nELTING POINT
1090
ENTHALPl OF IELTING
9.213
BOILING P O U T
1870
kJ
143.500
kJ
k~
nomu
-------------------------------------------------------------------------------I E L T I W GPOINT
53.48
BOILING POIUT
84.95
E~THALPI OP EELTIUG
0.510
kJ
EUTHALPI OF VAPOBIZATION
6.535
kJ
8.825
k~
HOLIR VOLUIE
VOLU~E
'0298
TRANSITIONS I N BEPERENCE STATE ELElEUTS
n:
2478.9200
24789.200
J/bar
cn3
TBAISITIOYS I N REFEEEYCE STATE ELEIIEWTS
HEAT CAPACITY EQOATIOYS

BEIT CAPACITY EQUATION
C;
3.1897~10-2 T
+ 3.0408~10T
~ -0-5
(EQUATION VALID FROB 2 9 8 - 5 0 3 . 1 5
K)
1 . 8 0 2 9 ~ 1 0 5 T-2
(EQUATIOU VALID PRO8
- 1 . 9 9 1 9 ~ 1 0 ' T-2
EQUATION VALID PROn
503.15
107
107
REFERENCE
1 0 9 0 K)
................................................................................
REFERENCE
298
1 8 0 0 K)
---------_--_---__--------------------------------------------------------------
COlPILED I
4-15-76
_-_____---____------------------------------------------------------------------
107
35
COlPILED
PROPERTIES
THEBIODY NAIIC PBOPERTIES OF 8INERALS
54
IRON ( REFERENCE STATE)
FOR8ULII YElGHT
55.847
................................................................................
A l p h a c r y s t a l s ( b o d y - c e n t e r e d c u b i c ) 2 9 8 . 1 5 t o 1 1 8 4 K.
Curie point
l o 4 2 K.
Gamma c r y s t a l s ( f a c e - c e n t e r e d c u b i c ) 1 1 8 4 t o 1 6 6 5 K.
Delta
Llquid from
c r y s t a l s ( b o d y - c e n t e r e d c u b i c ) 1 6 6 5 t o m e l t i n g p o i n t 1809 K.
1 8 0 9 K.
Fe:
................................................................................
FORRATION FROn THE ELERENTS
AT HIGH TEMPERATURES
G A L L I ~( R
~EFERENCE STATE
..................................................................................
Ga:
O r t h o r h o m b i c c r y s t a l s 298.15
TERP.
( H ; - H ~)/T~ ~
J/mol-K
-(GT-H2q8)/T
S;
J/mol- K
J/mol.K
C:
J/mol-K
ENTHALPY
kJ/mol
L i q u i d 302.9
to
-- ..............................................................................
POR8ATION PRO8 THE ELEUEhTS
GIBES
ENTHALPY
FREE ENERGY
Log Kf
FREE ENERGY
K.
69.720
b o i l i n g p o i n t 2 4 7 8 K.
GIBES
D
FOBHULA WEIGHT
kJ/mol
................................................................................
298.15
0.000
UNCEBT RINTY
27.28
0.13
27.28
0. 1 3
24.98
0.000
0.000
0.000
RELTING POINT
BOLL1 NG POINT
31 35
13.807
kJ
349.590
kJ
4.489
kJ
1809
40.83
0.21
302.90
ENTHALPY OF RELTING
ENTHRLPY OP UELTING
G98
40.83
0.21
26.22
0.0u0
0.000
0.000
................................................................................
................................................................................
flELTING POINT
298. 1 5
0-000
UNCERTAINTY
'0298
~ O L A BvoLunE
HE
BOILING POINT
2478
5. 5 9 0 k J
ENTHALPY OP VAPORlZATION
L58.72U
5.573
NOLAB VOLUflE
1.1790 J / b a r
11.790
cm3
kJ
TRANSITIONS I N REPERENCE STATE ELEHENTS
TRANSITIONS I N REFERENCE STATE ELEMENTS

_____-----__-_-__-_------------------------+------------------------------------
REFERENCE
107
107
COMPILED
6-13-66
................................................................................
C;
31.155 1.0116~10-3 T
1 . 2 6 6 6 ~ 1 0T
~- 0 . 5
EQUATION VALID FRO8 3 0 2 . 9 0 - 7 0 0 K )
4.4944x105
T-?
-----------__-___--------------------------------------------------------------R E F E R ~ ~1 0~7 ~
107
--__............................................................................
COMPILED
4-13-76
57
THERMODYNAIIIC PROPERTIES OF HINERALS

GERMANIUM (REFERENCE STATE )
FORMULA HEIGHT
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
GAOOLIUIUH (REFERENCE STATE)
...............................................................................
~ d :
FORMULA WEIGHT
157.250
Ge:
~ l p h ac r y s t a l s ( h e x a g o n a l c l o s e p a c k e d ) 298.15 t o 1 5 3 3 K.
~ i q u i d1 5 8 5 to
( b o d y - c e n t e r e d c u b i c ) 1 5 3 3 t o m e l t i n g p o i n t 1 5 8 5 K.
1800 K.
Pace-centered
c u b i c c r y s t a l s (diamond
L i q u i d 1210.4
t o b o i l i n g p o i n t 3107 K.
s t r u c t u r e ) 298.15
................................................................................
FORMATION
FORMATION FROM THE ELEMENTS

GIBHS
(H;-H;~~)/T
TEMP.
SOT
COP
-(G;-H;~~)/T
ENTHALPY
FREE EUERGY
( H ; - H ~)/T
~ ~
TEUP.
LO^
72.590
..--------=----
-(G;-H&~)/T
S;
C;
ENTHALPY
to 1 2 1 0 . 4
____
K.
-----------
man
T H E ELEHENTS
GIBBS
FREE ENERGY
LO^ K,
K~
kJ/mol
K
J/aol-K
J/mol-K
J/mOl- K
J/aol. K
k~/mol
___________________------------------------------------------------------------0.000
0.000
298.15
0.000
ULEERTAI NTY
68."
1. 2 5
68.45
1.25
26.15
0. 0 0 0
.000
-000
-000
-000
.ooo
.000
UOO
................................................................................
------------....................................................................
3539
MELTING POINT
ENTHALPY OF MELTING
4 9 8
1585
BOI L l NG POINT
1 0 - 0 5 4 kJ
9.079
~ L T I N GP O I N T
K
kJ
1210.4
ENTHAL~YOF HELTING
ENTHALPYOF VAPORIZATION
359.380
598
MOLAB VOLUME
1.9890
19.890
J/baE
cm3
TRANSITIONS I N
H:
BOIL1 NG POINT
36.945
kJ
4.627
k~
MOLAR VOLUME
3107
330.915
kJ
REFERENCE S T A T E ELEMENTS
HEATCAPACITY EQUATION
- - --- - - - - - - - - - ..................................................................
CO~PILE~
REFERENCE
107
107
37-79"
1 3 8 8 8 1 0 T
8 . 8 3 5 9 ~ 1 0 - * Tz
1 . 7 5 8 3 ~ 1 0 2 T-0.5
5-15-7:
- 7 . 6 9 7 2 ~ 1 0 * T-2
( EQUATION VALID FROM
198
1210. 4 K )
--__------......................................................................
P
---_
1~ 0 7 ~
~ 1 0~7
~
COMPILED
4-12-76
58
PROPERTIES AT HIGB TEIPERATURES
THERIODYNAIIC PROPERTIES OP IIUERALS
HELIUU ( REFERENCE STATE)

================== ..............................................................
HYDROGEN (REFERENCE STATE)

POBUULA UEIGHT
2.016
................................................................................
-----------
59
PORIULA WEIGHT
4.003
He:
I d e a l d l a t o m r c g a s 2 9 8 . 1 5 t o 1 8 0 0 K.
H,:
I d e a l g a s 298.15
t o 1 8 0 0 K.
................................................................................
___________________------------------------------------------------------------FURHATION PROM THE ELEIENTS
GIBBS
TEUP.
( H ; - H ~)/T
~ ~
J/aol-K
- ( G ; - H ~ ~ ~ ) / T C:
S;
J/mol-K
J/mol-K
ENTBALPY
J/mol-K
FREE EYEPGY
kJ/mol
Log Kf
!reap.
( H ; - H ; ~ ~)/T
kJ/mol
S;
J/Mo~-K
J/nolsK
298.15
0.000
UNCERTAINTY
126.15
0.01
-(G;-H;~~)/T
J/mol.K
C;
PORIATION FROI THE ELEIELlTs

GIBBS
ENTHALPY
PREE ENERGY
Log Kf
J/mol.K
kJ/mol
kJ/mol
___----------------------------------------------------------------------------___________________------------------------------------------------------------298.15
0.000
UUCERT AINTY
130.68
0.04
130. 6 8
0.04
28.84
0.000
400
500
600
700
800
900
1000
7.407
11.774
14.690
16.783
18.375
19.639
20.681
139.23
145.75
151.09
155.61
159.55
163.06
166.22
131.82
133.98
136.40
138.83
141.17
143.42
145.54
29.22
29.25
29.29
29.42
29.62
29.90
30.22
.000
1100
1200
1300
1400
1500
1600
1700
1800
21.564
22.332
23.012
23.626
24.185
24.702
25.184
25.635
169.12
171.80
174.29
176.63
178.84
180.94
182.93
184.83
147.56
149.U7
151.28
153.00
154.65
156.24
157.75
159.19
30.58
30.98
31.39
31.81
32.24
32.67
33.10
33.52
.0 0 0
0.000
0.000
-000
.000
.000
.000
-000
.000
-000
.000
-000
-000
-000
-000
.ooo
.ooo
.ooo
.ooo
-000
.ooo
.0 0 0
.000
.000
.000
-000
.ooo
.ooo
126.15
0.01
20.79
0.000
0.000
0.000
.ooo
.ooo
.ooo
.000
.000
.OD0
.000
.000
-000
.u00
.000
.000
.OD0
.ooo
.ooo
.ooo
.ooo
.000
----------_--_--_--------------------------------------------------------------___________________------------------------------------------------------------KELTING POINT
13.80
ENTHALPY OF IELTIUG
0. 117 kJ
'0298
H:
BOIL1 U
G POINT
20.27
~ E L T I N GP O I N T
0.904
kJ
EWHALPY OF BELTING
BOLA8 VOLUIE
8.468 k J
2478.92 00 J/baE
24789.200
cn3
498
H:
TRANSITIONS I N
HERT CAP ACITY EQUATION
C:
7.4424
1.1707~10-2 T
-5.1041X105
T-I
(EQUATION VALID FROM
298
1.3899xl0-'
T'
4.1017~10'
T - O ' ~
1800 K )
___________________----------------------------------------------------------cOUP~LB
REFERENCE
107
35
3-11-7
___________________------------------------------------------------------------
BOILI UG POINT
kJ
6. 1 9 7 k J
IOLAB VOLUUE
REFERENCE STATE ELEUENTS
4.21 K
kJ
2478.9200
24789.200
Jhar
cm3
60
THERUODYNAUIC P R O P E E T I E S OF NIYEEALS
P R O P E B T I E S AT B I G 8 TEHPERATURES
FORUULA YBIGIIT
178. 490
=z============5==============-===================================================
HAPNIUH ( REFERENCE S T A T E )
uERcURY ( REFERENCE S T A T E )
61
200.590
H)RHULA HEIGHT
...................................................................................
A l p h a c r y s t a l s ( h e x a g o n a l c l o s e p a c k e d ) 298. 15 t o 2013 K.
Hf:
(body-centered
l i q u i d 298.15
H ~ :
c u b i c ) 2103 t o m e l t l n g p o r n t 2500 K .
___________________--------------------------------------------------------------
t o b o i l i n g p o i n t 629.0
I d e a l m o n a t o m i c g a s 629.0
K.
1800 K .
FORUATION FROB THE E L E l E N T S

GIBBS
( H ~ - H ;)/T~ ~
TEHP.
-(G;-H;~~)/T
S;
C:
EYTHALPY
FREE EYBBG?
Log Xf
t o
TEUP.
(H;-H02q8)/~
-(G;-H;&)/T
S;
FORRATION FROR THE ELEnENTS

GIBBS
ENTHALPY
FREE ENERGY
~ o K~
g
C;
kJ/mol
K
J/mol-K
J/mol.K
J/mol.K
J/nol-K
kJ/mol
K
J/m0lSK
J/mol.K
J/mol. K
J/mOl- K
kJ/mol
kJ/mol
___________________-----------------------------------------------------------................................................................................
43.56
0.21
43.56
0.21
25.64
UNCERTAINTY
298.15
0,000
1100
500
600
700
800
900
1000
51.22
57.22
62.27
66.65
70.55
74.07
77.30
44.57
46.52
48.74
50.99
53.20
55.32
57.36
26.52
27.30
28.06
28.81
29.56
30.31
31.07
80.30
83.10
85.74
88.24
90.62
92.90
95.08
97.18
59.31
61.18
62.97
64.69
66.34
67.93
69.46
70.94
31.83
32.59
33.35
34.12
34.88
35.65
36.42
37.19
6.645
10.698
13.528
15.657
17.349
18.747
19.941
20.987
21.922
22.772
23.554
24.284
24.971
25.621
26.243
1100
1200
1300
1400
1500
1600
1700
1800
0.000
0.000
0.000
298.15
0.000
75.90
0.08
uNCERTAI NTY
75.90
0.08
27.96
0.000
0.000
0.000
-000
-000
-000
000
-000
.000
000
.
.OOO
.000
-000
.000
.W0
.OOO
.OOO
000
___________________-----------------------------------------------------------------_----__---___---------------------_------__------_------------nE L T I NG P O I YT
ENTHALPY O F NELTIYG
498
H%
B O I L 1 YG POINT
4876
24.058
kJ
EYTHALPY O F VAPORIZATION
575.141
kJ
5.845
kJ
UOLAR VOLUnE
2500
234.29
BELTING P O I N T
E I T H I L P ~OF UELTING
:'98
H:
TRANS1 T I O N S I N BEFEREYCE S T A T E ELEBENTS
TEA~SITIOUS IN
HEAT CAPACITY EQUATIOll
BEAT C A P A C I T Y EQUATION
C:
+ 7.8597110-3 T
(EQUATION V A L I D P R o a
22.465
+
298
25.261 ~ - 0 - s
ieoo K )
107
107
BOILING POIHT
629.0
2.297
kJ
59.214
kJ
9.343
kJ
HOLAR VOLUBE
BEFW E N C E S T A T E ELEIIENTS
1.4822 J / b a r
14.822
cn3
5.5918~10~
T - ~
-7.9563110l
REFERENCE
T-Z
( E Q U A T I O N V A L I D FROB
298
629 K )
---_............................................................................
"
107
~
107 ~
COHPIL ED
62
PROPERTIES AT H I G H TEHPERATURES
THEEHODYNAHIC PROPEETIES OF HINERALS
HOLHIUI! ( REFERENCE STATE)
FORUULA YEIGHT
............................................................................
164.930
A l p h a c r y s t a l s ( h e x a g o n a l c l o s e p a c k e d ) 298.15 t o 1 7 0 1 K.
L l q u l d 1743 t o
( b o d y - c e n t e r e d c u b ~ c )1 7 0 1 t o melting p o l n t 1 7 4 3 K.
b o l l ~ n g p o l n t 2 9 6 8 K.
Ho:
63
IODINE ( REFERENCE STATE)

FOBHULA YEIGHT 2 5 3 . 8 0 9
__==============================================================================
-C r y s t a l s 298.15
1 :
p o i n t 4 5 8 K.
K.
L i q u i d 386.75 t o b o i l i n g
I d e a l d i a t o m i c g a s 4 5 8 t o 1 8 0 0 K.
___-___-___-_______------------------------------------------------------------- --- _---------------------------------------------------------------------------FORflATION FROB THE ELEflhNTS

GIBBS
( H ~ - H ~ ~ ~ S;
) / T - ( G ~ - H & ~ ) / T C;
TEHP.
J/mol- K
J/mol.K
J/mol-K
ENTHALPY
J/mol-K
FREE ENERGY
l o g K~
TENP.
)/T
5;
-(G;-H;~~)/T
C:
POBUATION FROH THE ELEHENTS

GIBBS
ENTHALPY
FREE ENERGY
Log K f
kJ/mol
kJ/mol
___________________------------------------------------------------------------L98.15
0.000
UNCERTAINTY
75.02
1.67
75.02
1. 6 7
27. 1 1
0.000
400
500
600
700
800
900
1000
7.037
11.224
14.028
16.070
17.674
19.023
20.232
83.14
89.38
94.49
98.86
102.71
106.23
109.50
76.10
78.16
80.46
82.79
85.04
87.21
89.27
27.91
28.00
28.14
28.55
29.30
30.41
31.88
.000
-000
.000
-000
000
-000
-000
1100
1200
1300
1400
1500
1600
1700
1701
21.371
22.488
23.616
24.777
25.989
27.264
28.611
28.634
112.62
115.65
118.62
121.57
124.54
127.53
130.57
130.58
91.25
93.16
95.U0
96.79
98.55
100.27
101.96
101.96
33.71
35.90
38.45
41.36
44.61
48.22
51.17
52.13
-000
000
.000
.old0
.000
-000
.000
1701
1793
31.391
31.309
133.34
134.06
101.96
102.74
28.03
28.03
.000
-000
1743
1800
38.297
38.476
141.04
142.45
102.74
103.97
43.93
43.93
-000
.OD0
0.000
0.000
.ooo
-------__-__-____-_-------------------------------------------------------------
................................................................................
HELTI NG POINT
1743
ENTHALPY OF MUTING
G98
H:
BOILING POINT
12. 1 8 0 kJ
7.996
2968
240.980
kJ
ULTING POINT
386.75
BOILING POINT
ENTHALPYO F NELTING
15.648
kJ
G98
HOLAB VOLUHE
kJ
TRANSITIONS I N REFERENCE STATE ELEBENTS
H:
13. 1 9 6 k J
TRANSITIONS I N
REFERENCE STATE ELEHENTS
HOLAB VOLUUE

C;
19.256
1.3024~10-ZT
- 6 . 8 1 6 2 ~ 1 0 5 T-2
( E Q U A T I O NV A L I D FBoa
298
1 . 6 5 3 4 ~ 1 0 - 5 T2
3.0961~102
T - O . ~
1701 K )
___________________-----------------------------------------------------------REFERENCE
107
107
- 4 . 8 7 8 4 ~ 1 0 1 T-2
EQUATION VALID FROfl
458 -
1800 K )
458
41.700
kJ
5.1290 J h a r
5 1 . ~ 9 ~cm3
64
PROPERTIES AT H I G H TEBPERATORES
THERBOOYNABIC PROPERTIES OF BINERALS
INDIUll ( REFERENCE STATE)

................................................................................
In:
T e t r a g o n a l c r y s t a l s 298.15
FORBULA HEIGHT
K.
IRIOIUB ( REFERENCE STATE)
114.820
L i q u i d 429.76
FORBULA HEIGHT
..........................................................................
to
Ir:
Face-centered
65
192.220
t o 1 8 0 0 K.
b o i l i n g p o i n t 2346 K.
................................................................................
GIBBS
( H G - H ; ~)IT
~
TEHP.
J/nol.
-(G$-H:~~)/T
S;
J/nol-K
C;
ENTHALPY
J/m01-K
J/m01-K
kJ/mol
TEMP-
~ o g
K~
FREE E N E R G Y
57.84
0.84
57.84
0.84
26.73
-(G>H;~~)/T
S;
C;
kJ/nol
................................................................................
298.15
0.000
UNCERTAINTY
(8;-~:98)/~
EURBATION FROB THE ELEBENTS

GI88S
EUTHALPY
FREE ENERGY
Log K~
0.000
0.000
0.000
400
429.76
7.030
8.632
65.94
68.78
58.91
60.15
28.97
30.33
.000
-000
.000
-000
.000
.000
429.76
50 0
600
700
800
900
1000
16.227
18.076
19.962
21.293
22.280
23.040
23.645
76.38
80.14
85.50
90.02
93.91
97.34
100.41
60. 1 5
62.06
65.54
68.73
71.63
74.30
76.76
29.47
29.44
29.33
29.23
29.15
29.10
29.07
.DO0
.OOO
.OOO
.000
.000
.0U0
-000
-000
.OOO
.OOO
.000
-000
.000
.00U
.OOO
-000
.OOO
.OOO
-000
.000
000
1100
1200
1300
1400
1500
1600
1700
1800
24.137
24.548
24.895
25.194
25.453
25.681
25.882
26.061
103.18
105.71
108.03
110.19
112.20
114.07
115.84
117.50
79.04
81.16
83.13
a5.00
86.75
88.39
89.96
91.44
29.06
29.06
29.07
29-08
29.09
29.10
29.10
29.10
.000
.000
.000
-000
-000
.000
-000
.000
-000
-000
-000
-000
.OOO
.OOO
.OOO
00U
.OOO
-000
-000
-000
.OOO
-000
.OOO
.000
298.15
0.000
UNCERTAINTY
35.48
0.17
35.48
0.17
24.93
0.00U
0.000
0.000
___________________-------------------------------------------------------------
-___-______________------------------------------------------------------------- ................................................................................
BELTING POINT
2716
K
BOILING POINT
WLTING POINT
429.76
ENTHALPY OF BELTING
'0298
BOILING POINT
3. 2 6 4 W
2346
231.450
kJ
TRANSITIONS IN REFERENCE STATE ELEBENTS
- 4 . 4 9 5 1 ~ 1 0 5 T-2
REFERENCE
107
107
298
429.76
429.76
K)
1 8 0 0 K)
COMPILED
5-06-76
26. 1 3 7 k J
5. 2 6 8 k J
N I N~ REFERENCE
~ ~ ~ STATE
~ ~ ELEHENTS
~
CAPACITY EQUATION
8 . 2 7 3 7 ~ 1 0 5 T-2
( EQUATION VAL10 FROn
ENTHALPYOF BELTING
~2098 - H:
noLAR V O L U B E
6.602 kJ
NOLAB VOLURE
4701
604.075
kJ
0.8519 J / b a r
8.519
cm3
T H E R M O D YN A M I C
66
PROPERTIES
POTASSIUU (REFERENCE STATE )
FORUULA UEIGHT
..... .. ..... .. ..... .. ..... .. ..... .. ..... ..... .. ..... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Body-centered
K:
336.4
t o boiling point
1030 K.
PROPERTIES
U F MINERALS
t o meltlnq point
336.4
K.
39.098
AT
HIGH
TEMPERATUBES
67
FORMULA WEIGHT
.......................................................
83.800
Liquid
I d e a l monatomic g a s 1030 t o 1 8 0 0 K.
t o 1800 K.
I d e a l gas 298.15
_________-_________-------------------------------------------------------------................................................................................
TEuP.
( H;-H;98)/~
J/@o~-K
-(G~-H:~~)/T Ci
S;
~ / m o l - ~ .l/moleK
FORNATION FHUU THE ELEMENTS

GI885
ENTHALPY
F R E E ENERGY
Lo9
J/molmK
map.
k J/no 1
kJ/mol
o
o
( H~-H298)/~
J/mOl.K
SOT
-(G;-H;~~)/T
J/mOl-K
J/mol-K
C;
PJRNATION FROB THE E L E ~ N T s

GIBBS
FREE ENERGY
l o gK f
EITHBLP~
~ / m o l . ~
__--____-__________-------------------------------------------------------------................................................................................
kJ/rnol
298.15
0.000
UNCEBTAI NTY
336.35
3.483
336.35
400
500
600
700
64.68
0.20
64-68
0. 2 0
29-55
68.38
64.92
32-25
.000
.000
.000
.000
0.lJOU
0.000
900
1000
1030
10.424
13.830
17.284
19.465
20.961
22.065
22.934
23.658
23.855
75.32
80.83
87.78
93.31
97.93
101.91
105.4J
108.61
109.51
64.92
67-00
70.50
73.85
76.97
79.85
82.50
84.95
85.65
32.14
31.55
30.69
30.10
29.82
29.81
3D.DU
30.36
30.51
1030
101.445
187.10
85.65
20.79
.0 0 0
1100
1200
1300
1400
1500
1600
1700
1800
96.312
90.019
84.694
80.129
76.173
72.712
69.657
66.943
187.47
189.28
190.94
192.49
193.92
195.26
196.53
197.72
91.16
99.26
196.25
112.36
117.75
122.55
126.87
130.78
20.79
20.79
20.79
10.80
20.80
20.61
20.82
20.82
.000
.000
.000
.OOO
-000
.UOO
000
OD0
nb L,
0.000
0.000
298. 1 5
UUCERTAINTY
.ooo
-000
.ooo
.000
.000
.000
________--______--_-------------------------------------------------------------
164.08
164.08
0.02
0.02
20.79
0.000
0.000
0.000
-000
.0oo
-000
- 0 00
-000
00u
.000
-000
5.292
8.392
10-457
11-933
13.040
13-900
14-589
170.19
174.83
178.62
181.82
18u.60
187.04
189.23
164.90
166.44
168.16
169.89
171.56
173. 14
174.64
20.79
20.79
20.79
20.79
20.79
20.79
20.79
-000
000
-000
.000
.000
.ooo
.ooo
.000
.000
.000
15-152
15.622
16-019
16-359
16-655
16.912
17-141
17.343
191.22
193.02
19'4.69
196.23
197.66
199.00
200.26
201.45
176.07
177.40
178.67
179.87
181.01
182.09
183.12
184.11
20.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
-000
.ooo
.000
-000
.ooo
-000
-000
-000
.0 0 0
.000
.0 0 0
000
-000
-000
-000
-000
.000
-000
-000
.000
.000
-000
-000
-000
.000
-000
-000
.
.
................................................................................
____~_______--_____------------------------------------------------------------~ L T I N GP O I N T
115.78 K
BOLLING POINT
336. 35 K
UELTING POINT
1030
BOILIUG POINT
EYTHALpyOF MELTING
ENTHALPY OF NELTING
2.334
ENTHALPY OF V A P U R I Z A T I U N
kJ
1.636
kj
~ Y - Y I Bk~
6. 197 kJ
HOZY8
HP,
7.088
kJ

NOLAB VOLUME
MULAR VOLUME
T P A N S 1 ~ l o N s I N REFERENCE STATE ELEMENTS
TRANSITIONS I N
kJ
2478.9200
24789.200
J/bar
cm3
REFERENCE STATE ELEMENTS
-----___
........................................................................
C;
= -8.9054
COMPILED
3-11-76
1.5236~10-2 T
(EQUATION VALID FRUn J i b . 4
C;
7 . 8 4 5 7 ~ 1 0 T~
-'.*
7 - 7 8 b 4 x 1 0 5 T-2
1 0 3 0 K)
20.801 - 5 . 1 8 3 2 ~ 1 0 - 5 T
+
3 . 5 7 J 7 ~ 1 0 - ~T2
(EQUATION VALID FROR 1U30 - 1 8 0 0 K)
___________________------------------------------------------------------------REFERENCE
107
35
_________-_________------.---------------------------------------
68
LANTHANUH ( REFERENCE STATE)

..... ..... .. ... .. ... .. ..... ..... ..... ..... ..... .. ... .. ... .. ... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
La:
PROPERTIES AT HIGB TEUPEBATUBES
THERUODYNAUIC PROPERTIES OF IINERALS
FORUULA WEIGHT
138.906
A l p h a c r y s t a l s ( h e x a g o n a l c l o s e p a c k e d ) 2 9 8 . 1 5 t o 5 5 0 K.
Gamma c r y s t a l s ( b o d y - c e n t e r e d
c u b i c ) 5 5 0 t o 1 1 3 4 K.
L
i
q
u
i
d
1
1
9
3
t
o
1
8
0
0
K.
p
o
l
n
t
1
1
9
3
K
.
m
e
l
t
i
n
g
c u b i c ) 1134 t o
( face-centered
(H;-H:~~)/T
J/mol.K
-(G>H;~~)/T
S;
J/moL-K
J/mol-K
C:
J/mol. K
PORIATION FROU THE ELEIENTS

GIBBS
ENTHALPY
FREE ENERGY
LO^ K~
kJ/mol
PoRauLa WEIGHT
~ i : C r y s t a l s 2 9 8 . 1 5 t o m e l t i n g p o i n t 4 5 3 . 6 9 K.
L i q u i d 453.69
I d e a l m o n a t o m i c g a s 1 6 1 8 t o 1 8 0 0 K.
p o i n t 1 6 1 8 K.
6.940
K t o boiling
.......................................................................
................................................................................
TEUP.
LITHIUH (BEPERENCE STATE)

................................................................................
69
TEIP.
H;-~ig8
)/T
5;
-(G;-H:~~)/T
C;
FORIATION FROU THE ELEIENTS

GIBBS
ENTHALPY
FREE ENERGY
Log RE
kJ/mol
................................................................................
298. 1 5
0.000
UNCERTAINTY
56.90
2. 51
56.90
2.51
27.10
0.000
0.000
0.000
................................................................................
MELTING POINT
1193
----------------_--------------------------------------------------------+------
BOIL1 NG POINT
3730
IELTING P O I N T
413.670
kJ
ENTHALPY OP UELTING
ENTHALPY OF UELTING
6.197
kJ
4 9 8 -
6.665
kJ
UOLAR VOLUUE
BOIL1 YG POINT
1618
3.000
kJ
145.554
kJ
4.632
kJ
UOLAR VOLUUE
C; =
1.6025~10-2 T
+
4. 8 1 8 3 x 1 0 2 T-0-5
(EQUATION VALID FROU 2 9 8 - 550 K )
4.96171105
C; =
1.9885~10-2 T
t
4.4020~102 T-0-5
(EQUATION VALID PROH 5 5 0 - 1 1 3 4 K)
7 . 6 1 5 0 1 1 0 ~ T-2
T-2
107
................................................................................
+ 6.7350~10-2 T
(EQUATION VALID FROI
C;
= -38.655
C:
+ 8 . 5 5 3 7 ~ 1 0 2 T-0.5
2 9 8 - 453.70 K)
11.835 + 9 . 1 1 8 3 ~ 1 0 - 3 T
- 2 . 2 2 6 5 ~ 1 0 - 6 Tz
EQUATION VALID FBUI 4 5 3 . 7 0 - 1 6 1 8 K )
5.51421105
3.1789110z
T-2
T-a-5
................................................................................
................................................................................
107
TRANSITIONS X N REFERENCE STATE ELEMENTS
TRANSITIONS I N REFERENCE STATE ELENENTS
REFERENCE
453.70
~ ~ ~ P I L E D
4-30-76
QPERENCE
107
35
--__............................................................................
COIPILED
5-12-76
70
THERIODY N A n I C
PROPERTIES O F I I N E R A L S
LUTETIUM ( R E F E R E N C E S T A T E )
._--__-__--_-_-____-_----------------...............................................................................
P B O P E R T I E S A T HIGH
FORMULA WEIGHT
174.970
TEMPERATURES
I A G N E S I U B ( REPER ENCE S T A T E )
71
P O B I U L A WEIGHT
-- -
24.305
.................................................................................
H e x a g o n a l c l o s e p a c k e d c r y s t a l s 298.15
Lu:
t o m e l t l n g p o l n t 1 9 3 6 K.
922 t o b o i l i n g p o i n t
................................................................................
KIXHATION
( H;-H;~~)/T
TEMP.
K
J/mol-K
S;
J/mol-K
-(G;-H;~~)/T
C;
J/mol. K
J/mol. K
ENTHALPY
kJ/mol
t o m e l t i n g p o i n t 9 2 2 K.
Liquid
................................................................................
FROB THE ELEBENTS

GIBBS
F R E E ENERLY
1 3 6 1 K.
FORMATION FROM T H E ELEMENTS

GIBBS
ENTHALP Y
P B E E ENERGY
L o g Kf
kJ/mol
................................................................................
298.15
0.000
UNCERTAINTY
50.96
0.84
50.96
0.84
26.76
400
500
600
700
800
900
1000
6.830
10.844
13.550
15.536
17.097
18.398
19.533
58.84
64.84
69-78
74.01
77.75
81.14
84.28
52-01
54.00
56.23
58.47
60.65
62.74
64.75
26.86
26.96
27.23
27.71
28.38
29.24
30.29
1100
1200
1300
1400
1500
1600
1700
1800
20.565
21.533
22.466
23.382
24.296
25.217
26.155
27.1 13
87.22
90.02
92.71
95.33
97.89
100.41
101.90
105. 38
66.66
68.49
70.24
71.95
73.59
75.19
76.75
78.27
31.51
32.90
34.45
36.17
38.04
40.U7
42-25
44.58
0.000
0.000
0.000
298.15
0.000
UNCERTAINTY
-000
.000
000
000
-000
-000
-000
.000
-000
.000
.U0U
.000
-000
.000
.000
-000
-000
.000
.000
.O00
-000
.000
.u00
U00
000
.ooo
-000
-000
000
.000
32.68
0.13
32.68
0. 13
24.84
0.000
0.000
0.000
-000
.ooo
.0 0 0
.000
-000
.ooo
-000
.000
-000
-000
-000
.ooo
.000
.
.
.0 0 0
.000
_______-____-__-___------------------------------------------------------------- ................................................................................
3668
K
nELTING POINT
ENTHALPY OF 8 E L T I N G
4 9 8
HE
TRANSITIONS
1936
BOILING POINT
18.648
kJ
ENTHALPY OF V A P O R I Z A T I O N
355.910
kJ
6.389
kJ
I O L A R VOLUIE
1.7770
17.770
J/baC
m L T I NG P O I N T
cm3
IN R E F E R E N C E S T A T E E L E B E N T S
C;
ENTHALer O F B E L T I N G
'02'38
HEIT
17.027 +
7 . 0 4 0 7 ~ 1 ~ - 6 TZ
+
2 . 0 4 3 8 ~ 1 0 ~T - 0 . 5
( E Q U A T I O N V A L I D PROM
298 - 1800 K )
H:
TRANSITIONS
HEAT C A P A C I T Y EQUATION
L.4L28x105
922
BOILING POINT
1361
8.954
kJ
127.421
kJ
5.000
kJ
BOLAB V O L U I E
1.3996
13.996
J/bar
IN
CAPACITY
cm3
EQUATIONS
T - ~
--__............................................................................
_____________._____-----------------------------------------------------------
REFERENCE
107
107
CO~PILED
4-1 7-76
~ E ~ E B E N C E107
107
-- - .............................................................................
___________-__--___-------------------------------------------------------------
COBPILED
4- 1 0 - 7 6
P R O P E R T I E S AT HIGH TEBPERATURES
73
THERRODYIAHIC PROPERTIES O F HINERALS
72
MANGANESE ( R E F E R E N C E S T A T E )
FORHULA WEIGHT
_ _-__-_________
BOL~BDENVB(REFERENCE STATE )
.................................................................................
54.938
PORHULA WEIGHT
95.940
_ _ . - _ __
_
__
-_
- _ __
_ __
_ __
_ __
_ __
___
_
_-_
_.
_
__
_
_--_
-_
-_-_
-_
-_---_
-------_
------------------------------------------------ -- -- -- - - - - - - -
A l p h a c r y s t a l s 2 9 8 . 1 5 t o 9 8 0 K.
B e t a c r y s t a l s 9 8 0 t o 1 3 6 0 K.
Gamma
D e l t a c r y s t a l s 1410 t o m e l t l u g p o l n t 1 5 1 7 K.
c r y s t a l s 1 3 6 0 t o 1410 K.
L l q u l d 1 5 1 7 t o b o r l ~ n gp o l n t 2 3 3 5 K.
iln:
no:
Body-centered
t o m e l t i n g p o i n t 2 8 9 0 K.
................................................................................
____~_____~____~___------------------------------------------------------------FORHATIOB FROM T H E ELEHENTS

GIBBS
( H ; - H ~ ~ ~ ) / T
TENP.
J/.O~.K
-(G;-H;~~)/T
C;
~ / m o l - ~ ~ / m o l . ~ J/mol.~
TE~P.
l o 9 K~
FREE E N E R G Y
ENTHALPY
400
500
600
700
800
900
9H0
6.945
11.404
14.677
17.251
19.374
21.173
22.349
0.000
0.000
32.01
0.08
32.01
0.08
26. 1 9
40.01
46.53
52.18
57.22
61.79
65.98
69.05
33.07
35. 1 3
37.50
39.97
42-42
44.81
46.10
28-30
30. 16
31.89
33.49
34.93
36.18
37.04
.000
-000
-000
-000
.000
-000
.0 0 0
.ooo
.ooo
.ooo
000
-000
.000
.00 0
- ( G ; - B ~ ~ ~ ) / T C;
---
_______________~___------------------------------------------------------------298.15
298.15
0.000
UNCERTAINTY
S;
,
................................................................................
kJ/mol
kJ/mol
( H;-H;~~)/T
P O R I A T I O N FROB T H E ELEBElFTS
GIBES
ENTHALPY
F R E E ENERGY
Log Kf
0.000
0.000
UNCERTAIUTP
28.66
28.66
0.21
0.21
24.02
0.000
0.000
0.000
.000
.000
-000
.000
-000
0b0
000
___________________------------------------------------------------------------980
1000
24.696
24.960
71.40
72.12
46.70
47. 1 6
37. 59
37.68
-000
-000
1100
1200
1300
1360
26.13h
27.152
28.044
28.516
75.73
79.07
82.17
84.01
49-59
51.92
54. 13
55.49
38.11
38.54
38.97
39.15
.000
1360
1400
1410
29.476
30.468
30.561
84.97
86.75
87.07
55.49
56.28
56.51
42.41
43-43
43.51
1517
32.865
91.86
59-00
"6-1
1517
1600
1700
1800
40.814
41.084
41.375
41.633
99.81
102. 1 3
104.92
107.55
59-00
61.05
63.55
65.92
46.02
46.02
46.02
46.02
-000
-000
-000
.ooo
.0 0 0
.ooo
.00u
-000
-000
.ooo
.ooo
.ooo
.ooo
-000
___________________------------------------------------------------------------.000
.0 0 0
.000
-000
.0 0 0
-000
.000
.0 0 0
-000
.000
.00 0
.00 0
-000
.000
-000
___________________------------------------------------------------------------.ooo
- 0 00
-000
1410
31.893
88.41
56.51
45-23
1500
32.716
91.21
58.49
45.97
-000
-000
.ooo
.ooo
___________________-------------------------------------------------------------
.0 0 0
.000
-000
.000
.000
.000
-000
.000
.ooo
IELTING POINT
2890
BOILING POIllT
4912
_ . _ _ _ _ _ _ _ _ _ _ _ _ _ - _ _ _ - - - - - - - - - - - - - - - -E--~ TH AL PYO
P -BE LTIN
G- - 32.540
kJ- - - - - - - - - - - - - - - - - - - - - - - - - - - - - -
n E L T I NG P O I NT
1517
BOILING POINT
2335
kJ
226.065
kJ
ENTEALPY O P V A P O R I Z A T I O N
';98
ENTHALPY O F H E L T I N G
12.058
~ ; 9 8- B:
4.996
0.7354
7.354
~ O L A RV O L U ~ E
kJ
J/baE
cm3
4.594
TRIUSITIONS
k.l
598.070
~ O L A RVOLUBE
R E P W E N C E STATE ELEBENTS
IN
kJ
0.9387
J/bar
9.387
cm3
T R A N S I T I O N S I N REPERENCE S T A T E ELEHENT5
BEAT C A P A C I T I E Q U A T I O N
HEAT L A P A C I T Y E Q U A T I O N S
4.1345x10-2
L:
34.139
4.4926110-a
T
(EQUATION VALID F R O l
1 . 3 7 4 5 ~ 1 0 - 5 T2
3.13291102
-- ..............................................................................
T - O ' ~
~ C ~ ~ R E U C 1E0 7
-
C;
2.7217~10T
~- 2
( EQUATION V A L I D FROH
0
298 -
980 K )
107
---.............................................................................
COBPILED
4-23-76
33.387 +
4.2936110-~ T
(EQUATION VALID FRon
9 8 0 - 1360 K )
____~_______~~__~__-------------------------------------------------------------
REFERENCE
107
107
COHPILB~
5-12-76
___~____-__________-----------------------------------------
74
PROPERTIES AT HIGH TEIPEBATURES
THERIODYNAUIC PROPERTIES OF IlNERALS

FORIULA WEIGHT
NITROGEN (REFERENCE STATE)
28.013
................................................................................
SooIUH (REFERENCE STATE)

....................................................................
N,:
t o 1 8 0 0 K.
PORIATION
FURMATION PROM THE ELEMEUTS

GIBBS
( H ; - H ~)IT
~ ~
s:
-(G~-H;~~)/T
cOp
ENTHALPY
FBEE E N E R G Y
22 - 9 9 0
..............................................................................
................................................................................
TE~P.
FORNULA WEIGHT
B o d y - c e n t e r e d c u b l c c r y s t a l s 298.15 t o m e l t l o g p o l n t 3 7 0 . 9 8 K.
L~quld
3 7 0 . 9 8 t o f r c t i v e b o a l i n g p o l n t 1 1 7 5 K.
I d e a l monatomrc g a s 1175 t o
1 8 0 0 K.
T h e e q u l l l b r r u n b o l l l o g p o l n t o f t h e r e a l g a s 1s 1 1 5 4 K.
Na:
I d e a l d i a t o m i c g a s 298.15
75
l o g K~
TE~P.
( H ; - H : ~ ~)IT
J/mol-K
kJ/mol
-(<-H;~~)/T
S;
J/mOl.K
J/mol.K
C;
EITHALPY
J/mol-K
FRon T H E E L E N E W S
GIBBS
FREE ENERGY
kJ/mol
kJ/mol
K
J/mol.K
J/mol.K
J/mol-K
J/mol-K
kJ/mol
................................................................................
___________________------------------------------------------------------------298.15
0-000
51.30
51.30
28.23
298.15
0.000
UNCERTAINTY
191.61
0.02
191.61
0.02
29. 1 2
0.000
0.000
0.000
0.000
UNCERTAINTY
0.02
0.02
370.98
5-808
57.63
51.82
31.97
370.98
12.811
14.188
17.554
19.655
21.063
22.066
22.823
23.428
64.63
67.15
72.07
79.57
84.13
88.01
91.41
94.45
51.82
52.96
56.52
59.91
63.07
65.94
68.59
71.02
31.84
31.51
30.55
29.80
29.27
28.95
28.84
28.94
23.943
24.295
97.23
99. 15
73-29
74.85
74.85
77.10
85.28
92.41
98.69
104.27
109.27
113.78
0.000
0.000
.0OU
.000
.GO0
................................................................................
-000
.ooo
.ooo
-000
.000
.0O0
.000
.00O
-000
-000
-000
-000
-000
.u00
.O00
-000
29.26
29.65
.000
.uuo
20.79
20.79
20.79
20.79
20.79
20.79
20.90
20.79
-000
-000
-000
-000
-000
-000
.ou0
-000
-000
.00O
OU0
.000
.000
................................................................................
1175
1200
107.367
105.564
99.043
93.453
88.609
84.370
80.630
77.306
182.22
182.66
184.32
185.86
187.30
188.64
189.90
191.09
.ooo
.000
-000
.0 0 0
.w 0
-000
-000
K~
.ooo
.OOO
-000
-000
.O00
-000
.O00
-000
000
.000
.GOO
000
-000
-000
.ooo
-000
................................................................................
___________________------------------------------------------------------------UELTING POINT
63.14
ENTHALPY OF nELTING
4 9 8
- H:
0.720
kJ
8.669
kJ
BOIL1 NG POINT
ENTHALPY OP VAPORIZATIOU
NOLAR VOLUBE
77.35
5.586
2478.9200
LU789.200
K
kJ
J/bar
cn3
TRANS1 TIONS I N REFERENCE STATE ELEBENTS
mLT1NG POINT
E n T H A ~ OF
~ ~ MELTING
C;
................................................................................ conPILED
REFERENCE
107
24 7
35
247
................................................................................
3- 11-76
BOILIYG POINT
2.598
kJ
ENTHALPY OP VAPORIZATION
6.460
kJ
IOLAR VOLUUE
T B A N I sN REFEBENCE
~ ~ ~ ~STATE
~ ~ ELEMENTS
'EAT
370.98
1175
97.610
2.3812
23.812
kJ
J/bar
cm3
CAPACITY E Q U A T I O N
37-482 - 1 . 9 1 8 3 ~ 1 0 - 2 T
(EQUATION VALID FROI
+
1 . 0 6 4 4 ~ 1 0 - 5 T*
370.98 - 1175 K )
.................................................................
35
.............................................................................
COIPILED
7-24-76
PROPERTIES AT HIGH TEHPERATOBES
77
THERIODY UAIIC PROPERTIES OF IIIU GRALS

POBI0I.A YEIGHT
NIOBIUH ( REFERENCE STATE)

...............................................................................
92.906
NEODYHIVN (REFERENCE STATE)

................................................................................
Body-centered
t o a e l t i n g p o i n t 2 7 4 0 K.
................................................................................
................................................................................
PORIATIOU PROH THE ELEIEYTS
GIBBS
TEMP.
( H ~ - H )/T
: ~ ~
- ( G ~ - H ~ ~ ~ ) C;
/ T
S;
EYTHALPY
PBEE ENERGY
TEflP-
36.40
0.42
24.70
0.000
400
500
600
700
800
900
1000
6.387
10.244
12.890
14.840
16.352
17.573
18.591
43.77
49.49
54.26
58.34
61.94
65.16
68.08
37.38
39.25
41.37
43.50
45.59
47.59
49.49
25.42
25.91
26.33
26.74
27.14
27.55
27.96
.000
.OOO
-000
.OOO
-000
.000
000
1100
1200
1300
1400
1500
16 0 0
1700
1800
19.461
20.221
20.896
21.505
22.061
22.575
23.054
23.503
70.77
73.25
75.58
77.76
79.81
81.77
83.63
85.41
51.31
53.03
54.68
56.26
57.75
59. 19
60.58
61.91
28.37
28.79
29.21
29.63
30.06
30.50
30.93
31.37
.OOO
.000
-000
-000
-000
.OOO
.OOO
.000
0.000
0.000
-000
000
.ooo
.ooo
.ooo
-000
-000
00u
-000
.000
-000
.ooo
.ooo
.boo
-000
.000
.000
-000
.ooo
.ooo
-(G;-H:~~)/T
J/mol-K
J/mol.K
C;
J/mol-K
kJ/mol
kJ/mol
................................................................................
-000
.000
-000
s;
)/T
J/mol.K
kJ/.0l
36.40
0.42
(~:-~:98
FORHATION PRON THE ELEHENTS

GIBBS
ENTBALPY
FREE ENERGY
Log Kf
Log Kf
K
J/mol-K
J/mol-K
J/mol-K
J/mol.K
kJ/mol
................................................................................
298.15
0.000
UNCERTAINTY
144.240
A l p h a c r y s t a l s ( d o u b l e h e x a g o n a l c l o s e p a c k e d ) 2 9 8 . 1 5 t o 1 1 2 8 K.
Beta
c r y s t a l s ( b o d y - c e n t e r e d c u b i c ) 1 1 2 8 t o m e l t i n g p o i n t 1 2 8 9 K.
Liquid
1 2 9 8 t o 1 8 0 0 K.
~ d :
Nb:
FORIOLA YEIGHT
298.15
0.000
UNCERTAINTY
71.09
4.18
71.09
4. 18
27.45
0.000
0.000
0.000
.ooo
.000
.000
-000
.ooo
.ooo
-000
___________________------------------------------------------------------------8ELTING POINT
2740
BOILING POINT
5 0 17
682.004
kJ
................................................................................
UELTI NG POINT
ENTHALPY OF NELTING
4 9 8
26. 368 kJ
E m H A L ~OF
~ HELTING
5. 2 5 1 k J
HOg
1289
IOLAR VOLUIE
1.0828 J / b a r
10.828
cm3
':98
H:
TRANSITIONS I N
BOIL1 NG POINT
3341
7. 1 4 2 kJ
273.040
kJ
7.134
B O L A R YOLOIE
2.0570 J / b a r
20.570
cm3
kJ
REFERENCE S T A T E ELEHENTS
NEAT CAPACITY @OATION

BEAT CAPACITY EQUATIONS
C;
21.778 + 4 . 6 7 0 9 ~ 1 0 - 3 T
(EQUATION VALID PROI
+ 51.793 T-0-5
198
1 8 0 0 K)
1 . 3 0 9 8 ~ 1 0 T-2
~
................................................................................ CONPILGD
REFERENCE
107
107
4- 17-76
___________________-------------------------------------------------------------
107
COIPILED
78
PROPERTIES AT H I G H TEHPERATURES
THERUODY NAUIC PBOPEBTIES OF U I l EBALS
NEON (REFERENCE STATE)

PORUOLA WEIGHT
20.179
=S===S=====_==I===-------=========s===========================s=================
NICKEL (REPERENCE STATE)
m R u u u WEIGHT
58.700
__-----------------------------------------------------------------------------_
__----------------------------.----------Face-centered
NL:
Ne:
I d e a l g a s 298.15
79
t o 1800 K.
C u r i e c r y s t a l s ( m a g n e t i c ) t o C u r i e p o i n t 6 3 1 K.
Nonmagnetic 631 t o melting pornt
1726 K .
Llquid
1726 t o 1 8 0 0 K.
_------------------------------------------------------------------------------___________________------------------------------------------------------------PORIATION FROH THE ELEMENTS

GIBES
(H;-H&~)/T
TE~P.
J/nol-K
-(G;-H;~~)/T
S:
J/mol.K
C;
J/mol-K
J/mol.K
EYTBALPY
kJ/mol
FREE ENERGY
log
rf
TEHP-
( H;-Hzg8)/T
S;
- ( G ~ - H ~ ~ ~ )C; / T
FURHATION FROR THE ELEHENTS

GIBES
ENTHALPY
FREE EYERGY
Log K f
kJ/mol
___________________------------------------------------------------------------298.15
0.000
UNCERTAINTY
146.32
0.02
146.32
0.02
20.79
400
500
600
700
800
900
1000
5.292
8.394
10.460
11.930
13.039
13.900
14.590
152.42
157.06
160.85
164.06
166.83
169.28
171.47
147.13
148.67
150.39
152.13
153.80
155.38
156.88
20.79
20.79
20.79
20.79
20.79
20.79
20.79
1100
1200
1300
1400
1500
1600
1700
1800
15.154
15.620
16.018
16.359
16.655
16.91U
17.139
17.343
173.36
175.26
176.86
178.47
179.85
181.24
182.47
183.69
158.21
159.64
160.84
162. 1 1
163.20
164.33
165.33
166.35
20.79
20.79
20.79
20.79
20-79
20.79
20.79
20.79
0.000
.ooo
-000
.000
.000
.000
-000
-000
-000
.000
-000
-000
000
.000
.000
.000
0.000
0.000
-000
-000
.000
-000
.000
-000
-000
.060
000
000
-000
.000
298.15
0.000
UNCEBTAI NTY
29.87
0.08
29.87
0.08
2b.06
0.000
0.000
0.000
.ooo
.ooo
..
.0 0 0
.000
-000
-000
.000
-000
-000
000
.DO0
-000
-000
.ooo
-000
.000
.000
000
------_---___--_-_--------------------------------------------------------------
~__________________------------------------------------------------------------#ELTI NG
HELTING POINT
24.55
BOILING POXNT
ENTHALPY OF BELTING
0.331
kJ
POI NT
E ~ U R L P OF
Y RELTING
4 9 8
6. 1 9 7 kJ
H:
HOLAR VOLUHE
1726
J/bar
cm3
3187
370.380
kJ
17.472
kJ
4.786
kJ
UOLAH VOLUUZ
kJ
2478.9200
24789.200
BOIL1 NG POINT
T R A N S I IN
~ ~REFERENCE
~ ~ ~
STATE ELEnENTS
___________________------------------------------------------------------------REFEHENCE
107
107
COHPILED
3-11-76
:
C
1 . 5 1 3 5 ~ 1 0 2 - 0.20499 T
298
2 . 5 6 9 7 ~ 1 0 7 T-2
(EQUATION VALID FROR
b31
_______~___~_____~_-------------------------------------------------------------
1.741 1 r 1 0 - * Tz
6 3 1 K)
1126 K )
1.3753~103~ - 0 . s
--80
THER IIOOIIAIIIC PROPERTIES OF IIIUERALS

PROPERTIES AT HIGH TEIIPEBATURES
OXYGEN (REPEEENCE STATE)

...............................................................................
0,:
I d e a l d l a t o a i c g a s 298.15
PORIIULA WEIGHT
31.999
o s # ~ u I I ( REPERENCE STATE)
PORIIULA WEIGHT 1 9 0 . 2 0 0
................................................................................
t o 1 8 0 0 K.
gs:
------------------------------------------------------------------------------(n;-nig8
TEUP.
)/T
-(G;-H&~)/T
S;
C;
K
J/mol.K
J/mol-K
J/mol-K
J/mol.K
kJ/mol
kJ/mol
------------------------------------------------------------------------------
298.15
0.000
UNCERTAINTY
2 0 5 . 15
0.04
205. 1 5
0.04
29.37
400
500
600
700
800
900
1000
7.560
12.176
15.420
17.867
19.799
21.376
22.694
213.87
220.70
226.47
231.48
235.93
239.94
243.58
206.31
208.52
211.05
213.61
216.13
218.56
220.89
30.13
31.16
32.12
32.95
33.67
34.29
34.82
1100
1200
1300
1400
1500
1600
1700
1800
23.818
24.792
25.644
26.399
27.072
27.678
28.226
28.726
246.92
250.01
252.88
255.56
258.08
260.45
262.69
264.82
223.10
225.22
227.24
229.16
231.01
232.77
234. 46
236.09
35.29
35.69
36.05
36.36
36.64
36.89
37.11
37.31
0.000
0-000
( H ; - H ~ ~ ~ ) / TS;
J/mol.K
J/mol.K
298.15
0.000
o~cERTAINTX
32.64
0.06
32.64
0.06
24.71
6.340
10.130
12.718
14.623
16.099
17.288
18.278
39.95
45.60
50.27
54.29
57.82
60.97
63.84
33.61
35.47
37.55
39.67
41.72
43.68
45.56
25.09
25.48
25.86
26.24
26.62
27.00
27.38
.000
-000
-000
-000
000
.000
-000
-000
-000
000
-000
.OOO
-000
.000
000
-000
.OOO
-000
-000
-000
-000
19.123
19.858
20.511
21.096
21.629
22.120
22.575
23.001
66.47
68.90
71.16
73.29
75.30
77.20
79.01
80.74
47.35
49.04
50.65
52.19
53.67
55.08
56-44
57.74
27.76
28.14
28.52
28.90
29.28
29.66
30.05
30.43
.OOO
-000
000
.000
-000
-000
-000
.OOO
-000
-000
-000
.000
-000
-000
-000
-000
-000
-000
.000
000
.000
.OOO
-000
-000
,500
1000
54.35
BOILING POINT
ENTHALPY OF IELTING
0.444
kJ
8.682
H:
3300
31.757
2478.92 00 J/baK
24789.200
cm3
UOLAR VOLUUE
kJ
kJ/mol
0.000
0.000
0.000
BOIL1 NG POINT
5285
kJ
746.080
kJ
kJ
UOLAR VOLUUE
kJ
EMTHALPY OF UELTING
kJ/mol
-------------------------------------------------------------------------------WELT1 NG POI NT
6.816
PORIIATION PROU THE ELEIIEYTS

GIBBS
FREEENERGY
t o g K~
ENTHALPY
J/mol-K
.OOO
.000
.000
000
.000
.OOO
.OOO
000
UELTING POINT
C;
J/mOlsK
--------------------------------------------------------------------------------
-(<-H;~~)/T
__________----------------------------------------------------------------------
0.000
-000
.OOO
.OOO
-000
000
-000
.000
t o 1800 K .
___________----_----------------------------------------------------------------
PORIIATIOY PROII THE ELEIIEUTS

GIBES
EIITHALPY
FREE E I E R G Y
LO^
mnp.
'0298
81

TRAYSITIONS I N
0.8423 J / b a r
8.423
cm3

HEAT CAPACITY E Q U A T I O N
C;
48.318
6.9132~10-4 T
( ~ U A T I O N V A L I D Paou
298
4 . 2 0 6 6 ~ 1 0 2 T-0's
1800 K )
4 . 9 9 2 3 ~ 1 0 5 T-2
C;
23.571 +
3.8083~10-3 T
(EQUATION VAL10 PROU
___________________-----------------------------------------.----...............................................................................
REFERENCE
107
298
1 8 0 0 K)
35
1
~ 07 ~
1 0~7
COUPILED
4-17-76
82
THEBMODYNAUIC
PHOSPHORUS ( REPEBENCE S T A T E )
.------------------------------------------------------...............................................................................
P:
Crystals (red triglinic.
V)
298.15
3 0.974
FOBUULA YElGHT
K t o sublimation p o l n t 7 0 4 K.
LBbD ( ~ E F E B E U C E S T A T E )
...............................................................................
pace-centered
Ideal
600.6
d l a t o m l c g a s 7 0 4 t o 1 8 0 0 K.
( H;-H;~~)/T
J/mol.K
-(G;-H;~~)/T
S;
J/mol-K
J/mol-K
C;
J/mol.K
FURMATION PROM THE ELEMENTS

GIBBS
ENTHALPY
FBEE E N E R G Y
l o g K~
kJ/rnol
rlllp.
22.85
0.08
22-85
(1.08
21.21
0.000
t o melting p o r n t 600.6
K.
Lrquld
t o b o l l l n g p o i n t 2 0 2 1 K.
( H;-H&)/T
kJ/mol
................................................................................
298.15
0.000
UNCEBTAI NTY
c u b r c c r y s t a l s 298.15
207.2 0 0
P0RUUI.A HEIGHT
.........................................................................
................................................................................
TEHP.
83
P B O P E P T I E S AT HIGH TBUPEBATUBES
P B O P E R T I E S O F MINERALS
U.OU0
-(G;-H&)/T
C%
~~~~~~K
~/mol-K
J/mol-K
65.06
0.42
65.06
0.42
26.61
72.99
79.20
84.46
85. 14
66. 12
68.13
70.43
71.06
27. 40
28.33
29.39
29.40
-000
.OOO
-000
.000
-000
.OOO
-000
-000
25.220
93.13
97.14
101.17
104.69
107.80
71.06
73.91
77.07
79.95
82.58
30.58
30.37
30.03
29-68
29.35
-000
-000
.OOO
.000
.000
-000
.OOO
.OOO
-000
.000
.OOO
-000
-000
-000
.000
25.584
25.866
26.090
26.273
26.426
26.557
26.674
26.779
110.58
113.10
115.41
117.53
119.50
121.34
123.07
124.71
85.00
87.23
89.32
91.26
93.07
94.78
96.40
97.93
29.08
28.87
28.71
28.60
28.54
28.52
28.55
28.60
.OOO
.OOO
.000
.000
.000
.OOO
.OOO
-000
-000
.OOO
.OOO
-000
-000
-000
.OOO
-000
.OOO
-000
.OOO
- 000
-000
.000
-000
-000
0.000
6.872
11.070
14.033
14.088
500
600
600.6
SOT
~ R M A T I O UP u o n T H E E L E U E ~ S
GIBBS
ENTHALPY
PBEE ENEBGY
LO^ K~
J/.ol.K
kJ/m01
kJ/mol
0.000
0.000
0.000
.OOO
-000
000
-000
_________-_-_-----_-----------------------------------------------------------
600.6
22.078
23.233
24.105
3
------------------_-------------------------------------------------------------_-____-___~_______------------------------------------------------------------NELTING P O I N T
BOILING P O I N T
~ E L T I N GPOINT
ENTHALPY OF MELTING
kJ
E u T H A ~ ~OP
Y MELTING
~;98
U O L A R VOLUUE
3. 6 0 7 k J
H:
1 . 7
17.200
~ bar
~
cm3
T R A N S I T I O N S I N REFERENCE STATE ELEMENTS
C:
C:
REFERENCE
107
107
BOILING POINT
LO21
4. 7 9 9 k J
EYTHALPY O F VAPORIZATION
177.699
kJ
6.874
MOLAB V O L U U E
1.8267
18.267
J/bar
cm3
kJ
s IN
~ BEFERENCE
~ ~ ~ ~ ~STATE ELEMENTS
CAPACITY E Q U A T I ~ ~ ~
1 . 1 1 6 7 ~ 1 0 5 T-2
( q U A T I O N VALID FROU
600.6
13.743 +
1.5675~10-2 T
( E Q U A T I O t l VALID FROH
1.5920~102 T-0-5
600.6 K )
5-3727x10-3 T
+ 8.3501~102 T-0-5
- 2.4248xlw
( EQUATION VALID FROH
600.60 - 1 8 0 0 K )
107
704 - 1800 K )
+
298
9.1526x10*
T-2
T-2
CO
4 -U1P0I-L7E6D
------------_--------------------------------------~--------~-------~--~-~
COQIPILED
8-18-76
_~___~-____________-------------------------------------------------------------
PROPERTIES AT HIGH TEIPERATURES

84
PALLAOIUI ( REFERENCE STATE)
PORlOLA WEIGHT
...................................................................................
....................
106.400
FoRnuLA YEIGET
140.908
p B A , ~ ~ r n (~REPEREECE
ua
STATE )
ss5============'===============================================================
~ l p h ac r y s t a l s ( d o u b l e h e x a g o n a l c l o s e p a c k e d ) 2 9 8 . 1 5
pt:
pd:
Face-centered
c u b l c c r y s t a l s 298.15
t o melting p o i n t 1 8 2 5 K.
c r y s t a l s (body-centered
P O R M A T I O N Puon T H E E L E I E U T S
GIBBS
TEIP.
( H ; - H ~)/T
~ ~
J/mol.K
-(G;-H;~~)/T
S;
C;
ENTHALPY
J/mol-K
J/mol-K
298.15
0.000
UNCERTAINTY
37.82
0.21
37.82
0.21
25.93
400
500
600
700
800
900
1000
6.710
10.774
13.575
15.647
17.260
18.569
19.665
45.56
51.59
56.61
60.94
64.75
68.17
71.28
38.85
40.82
43.04
45-29
47-49
49.60
51.61
26.73
27.32
27.83
28.32
28.79
29.28
29.79
.000
000
.OOO
-000
.OOO
-000
-000
1100
1200
1300
1400
1500
1600
1700
1800
20.610
21.443
22.193
22.881
23.522
24.127
24.705
25.263
74.15
76.81
79.31
81.67
83.91
86.05
88.11
90.09
53.54
55.37
57.12
58.79
60.39
61.92
63.41
64.83
30.33
30.90
31.51
32.15
32.84
33.57
34.34
35.16
-000
.000
.000
.000
-000
.OOO
.OOO
-000
J/mol-K
FREE EHEBGY
kJ/mol
K
0.000
ENTHALPY OF MELTING
G98
1825
17.560 k J
5.469
kJ
Beta
-(~-H&~)/T
cOp
PORIATION FROI THE ELEIENTS

GIBBS
F R E E E N E P G ~ l o g K~
ENTHALPY
J/.0l.K
J/mol-K
JA0l.K
J/mol-K
kJ/.01
kJ/.0l
............................................................................
298.15
0.000
u@cERTAINTY
73.93
4.18
73.93
4. 1 8
27.44
0.000
0.000
0.000
7.092
11.480
14.670
17.213
19.377
21.307
23.082
82.11
88.58
94.16
99.16
103.77
108.09
112.21
75.02
77.10
79.49
81.95
84.39
86.78
89.13
28.37
29.77
31.50
33.47
35.62
37.88
40.24
.000
-000
-000
-000
000
-000
-000
.OOO
-000
-000
.000
-000
.OOO
.000
-000
24.099
114.85
90.75
41.90
.000
-000
-000
27.183
117.93
90.75
38.45
.0 0 0
.ooo
.000
27.512
28.427
28.463
119.00
122.35
122.73
91.49
93.92
94.26
38.45
38.45
38.45
-000
-000
.000
.000
-000
.000
.000
.000
.000
34.183
34.832
128.45
131.50
94.26
96.67
42.97
42.97
.OOO
.OOO
.ooo
.ooo
35.413
35.917
36.357
36.746
37.092
134.68
137.64
140.42
143.02
145.48
99.27
101.72
104.06
106.27
108.39
42.97
42.97
42.97
42.97
42.97
.OOO
000
.000
-000
.000
-000
.000
.000
.000
-000
.OOO
-000
-000
-000
-000
-000
.000
.000
-000
-000
-000
.ooo
.ooo
................................................................................
................................................................................
BOILING POINT
3237
nEL?IlG POINT
357.510
kJ
t M T B A L ~ OP
~ MLTING
IOLAR VOLUKE
TRANSITIONS I N REFERENCE STATE ELEIEUTS
1204
BOILING POINT
3785
6.887
kJ
ELITHALPY OP VAPOEIZATION
296.780
kJ
7.418
kJ
IOLAR VOLUUE
2.0800
20.800
J/bar
cm3
IN~ R ~E P E~B E N~C E ~STATE

~
~E L E I E N T S
CIPACITY E Q U A T I O N
S;
(R;-H:~~)/T
................................................................................
UELTING POINT
TEnp.
kJ/mol
0.000
t o 1 0 6 8 K.
L i q u i d 1204 t o 1800 K.
Log Kf
................................................................................
0.000
c u b l c ) 1 0 6 8 t o 1 2 0 4 K.
................................................................................
................................................................................
C;
85
THERIOOYNAIIC PROPERTIES OP IINERALS
31.615 1.3625~10-3 T
+
298
2 . 5 4 2 7 ~ 1 0 - 6 Tz
1 8 0 0 K)
95.020
T-0.5
C:
2.9291~10-2 T
+ 3 . 5 0 9 2 ~ 1 0 2 T-0.5
(EQUATION VALID PROM 2 9 8 - 1 0 6 8 K)
1.4325xlOS
T-2
..................................................................
REFERENCE
107
107
107
....................................................................
COIPILED
4-26-76
86
PROPEPTIES AT HIGH TENPERITURES
THERHODYNAIIC PROPERTIES OF IINERALS
PLATINUH ( BEFEBENCE STATE)
.................................................................................
-------------------
FOBUULA YEIGHT
195.090
pLUTONIUN ( REFERENCE STATE)
Face-centered
POBlLlLa YEIGHT
244.002
....................................................................................
pu:
Pt:
87
Alpha c r y s t a l s ( m o n o c l i n i c . s i m p l e ) 298.15 t o 3 9 5 K .
( b o d y - c e n t e r e d m o n o c l i n i c ) 3 9 5 t o 4 8 0 K.
Gamma c r y s t a l s ( f a c e - c e n t e r e d
o r t h o r h o m b i c ) 4 8 0 t o 5 8 8 K.
D e l t a c r y s t a l s ( f a c e - c e n t e r e d c u b i c ) 588 t o
D e l t a prime c r y s t a l s (body-centered t e t r a g o n a l ) 730 t o 753 K.
7 3 0 K.
E p s i l o n c r y s t a l s ( b c c ) 753 t o 9 1 3 K.
L i q u i d 9 1 3 t o 1 8 0 0 K.
--------------------------------------------------------------------------------
SOT
TENP.
-(G;-H;.~)/T
( H ~ - H ' ~ ~ ~ ) / T
C:
EUTHALPY
GIBBS
FBEE E N E R G Y
LO^ K~
J/mol'K
TEIP-
( H ~ - R ; ~ ~ ) / T S;
J/mol-K
-(G;-H;~~)/T
J/mol-K
3/8ol-K
C;
mRIATION PRO8 THE ELEHEYTS

GIBBS
ENTHALPY
PBEE EYEBGI
Log K f
J/mol-K
kJ/mol
k J/mol
................................................................................
298.15
0.000
UNCEBTAINTY
298. 1 5
0.000
UNCEBTAI NTY
51.46
8. 3 7
51.46
8.37
31.97
0.000
0.000
0.000
753
800
900
913
30.299
30.585
31.092
31.162
97.61
99.74
103.89
104.86
67.32
69. 1 6
72.79
73.70
35.15
35.15
35.15
35.15
W0
-000
-000
000
-000
-000
.OOO
-000
.000
-000
.a00
.000
91 3
1000
34.278
34.936
107.98
111.29
73.70
76.35
41.84
41.84
-000
-000
-000
.000
.000
-000
1100
1200
1300
1400
1500
1600
1700
1800
35.564
36.087
36.529
36.909
37.057
37.525
37.779
38.004
115.10
118.91
122.15
125.39
128.17
130.96
133.42
135.89
79.54
82.82
85.62
88.48
91.12
93.43
95.65
97.89
41.84
41.84
41-84
41.84
41.84
41.84
41.84
41.84
-000
-000
000
-000
.000
-000
.000
.000
................................................................................
................................................................................
BELTING POINT
ENTHALPY OF IlELTING
G98
HE
2042
1 9 . 6 4 8 kJ
5. 7 2 4 kJ
BOILING POINT
4100
ENTHILPY OF VAPORIZATION
509.820
kJ
HOLAB VOLUHE
-000
.000
-000
-000
.000
-000
.a00
.OOO
.000
-000
000
-000
.000
.000
................................................................................
IELTI N G POINT
ENTHALPY OF NELTING
.00 0
.0 00
BOIL1 N
G POINT
3503
2.845
kJ
343.670
kJ
6.485
kJ
HOLAB VOLUNE
913
T R A N ~ l ~ lI O
N ~
KEPEREICE
~
STATE ELEHENTS
................................................................................
REFERENCE
1U7
107
................................................................................
CONPILED
5-15-73
THERUOOY MIMIC PROPERTIES O? I I N ERALS
88
RUBIDIUU (REFERENCE STATE)

................................................................................
Rb:
Body-centered
c u b i c 298.15
( H;-H;~~)/T
J/mol-K
5;
~ R U O M WEIGHT
K.
85.468
L i q u i d 312.64
-(G;-H;~~)/T
J/mol-K
J/m01-K
C;
kJ/aol
STATE)
.......................................................................
Re:
FOBMATION PROU THE ELEIEWTS

GIBBS
ENTHALPY
FREE ENERGY
Log K~
J/nol-K
ss~~rUM
(REFERENCE
TmP.
76.78
0. 30
76.78
0.30
31.66
6.000
6.660
0.606
SOT
( H;-H;~~)/T
kJ/mol
?ORUULA WEIGHT
186.207
-(G>H;~~)/T
t o 1 8 6 0 K.
C;
~/mol.K
J / m o l - ti
36.53
0.38
36.53
6.38
25.16
6.516
16.450
13.168
15.183
16.757
18.041
19.121
44.04
49.88
54.76
58.96
62.67
66.01
69.64
37.53
39.43
41.59
43.78
45.91
47.97
49.92
25.92
26.49
27.61
27.53
28.05
28.57
29. 1 0
.OOO
.006
.606
-060
-066
.OOO
-000
.OOO
.OOO
.606
.600
.(I00
-000
-000
.OOO
-000
-006
.60U
-660
-000
.OOO
20.052
20.873
21.609
22.280
22.898
23.473
24.014
24.526
71.84
74.44
76.88
79.18
81.35
83.43
85.41
87.31
51.79
53.57
55.27
56.90
58.45
59.96
61.46
62.78
29.63
30. 17
30.72
31.27
31.83
32.38
32.94
33.51
.006
-000
-000
.OOO
.OOO
-006
.006
-600
.000
.660
-060
-000
.OOO
-060
-006
-606
.600
-066
000
.OOO
.OOO
.600
.666
.600
J/~O:.K
800
1100
95 9
1000
1100
1200
1300
1400
1560
1600
1700
1ROO
J/mol-K
PJRUATION PRO8 THE ELEUENTS

GIBES
ENTHALPY
FREE ENERGY
LO^ K~
298.15
6.066
O ~ I C E R TN
MTY
-------------------------------------------------------------------------------298. 1 5
6.666
UNCERTAINTY
89
t o
I d e a l monatoalc g a s 959 t o 1800 K.
b o i l i n g p o i n t 9 5 9 K.
TEMP.
PROPERTIES AT HIGH TEUPEPATURES
kJ/mol
kJ/nol
6.006
0.606
6.006
-------------------------------------------------------------------------------BELTING POINT
ENTHALPY OP MELTING
'2098
312.64
BOILING POINT
959
2. 192 k J
ENTHALPX OF VAPORIZATION
7 1. 1 9 2 k J
7.489
IOLAR VOLVUE
kJ
MELTING POINT
3453
EMTHALPY OF MELTING
TRANSITIONS I N REFERENCE STATE ELEIENTS
TRANSITIONS I N
BEATCAPACITY EQUATION
C;
41.678 2.8113~10-2 T
+
1.5320110-5 T2
312.64 - 9 5 9 K)
C:
BOILING POINT
5869
33.229
kJ
ENTBALPY OP VAPORIZATION
714.840
kJ
5.355
kJ
IOLAR VOLUUE
0.8860
8.860
J/bar
cm3
R E F E R E N C E STATE E L E I E N T S
21.470 + 5 . 9 7 2 8 ~ 1 6 - 3 T
( E Q U A T I O NV A L I D P a o u
+
56.132 T-0.5
2 9 8 - 1806 K )
1 . 1 9 2 8 ~ 1 0 . T-2
--------------------------------------------------------------------------------
-----------_---_-_--------------------------------------------------------------
REFERENCE
107
35
COMPILED
4-1 0-76
1~0 7 ~
~ 1 0~7
COMPILED
4-17-76
------------------------------------------------------------------------------
90
THERMODYPAMIC PROPEBTIES OF UINERALS
BHODIOM ( REFEREUCE STATE)
FORNULA UEIGHT
................................................................................
................................................................................
Rh:
Face-centered
102.906
91
FoRnuLA W E I G H T
BADON (REFERENCE STATE)
222.000
II===================1=====11=-=====5===============c====================x====
to a e l t i n g p o i n t 2 2 3 3 K.
~n:
I d e a l g a s 298.15
t o 1800 K.
................................................................................
TEMP.
( H;-H;~~)/T
J/aol-K
- ( G ; - H ~ ~ ~ ) / T C;
S;
J/mol-K
J/m0lSK
J/mol.K
31.54
0.21
31.54
0.21
24.95
FORUATION PROM THE ELEMENTS

GIBBS
ENTRALPY
FREE ENERGY
Log K f
kJ/mol
kJ/mol
0.000
0.000
( H : - H ~ ~ ~ ) / T S;
0.000
298.15
0.000
uNCERTAI NTY
5.292
8.392
10.457
11.933
13.040
13.900
14.589
400
500
600
700
BOO
900
1000
BELTING POINT
ENTHALPY OF HELTING
'2098
HE
2233
21.489
4.920
BOILING POINT
3970
RELTING P O I N T
kJ
493.260
kJ
ENTHALPYOF MELTING
kJ
MOLAR VOLUME
-(G;-H;~~)/T
cOp
K~
K
J/mol.K
J/mol-K
J/mol-K
J/mol-K
kJ/mol
k J/mol
................................................................................
................................................................................
298. 1 5
0.000
ONCERTAI NTY
TEMP.
FORUATION FBOl THE ELEHEYTS

GIBES
ENTHALPY
FREE ENERGY
176.23
0.00
176.23
0.00
20.79
182.34
186.98
190.77
193.97
196.75
199.19
201.38
177.05
178.59
180.31
182.04
183.71
185.29
186.79
20.79
20.79
20.79
20.79
20.79
20.79
20.79
202
2.887
0.000
-000
.000
.0 0 0
.0 0 0
.000
.OOO
.OD0
0.000
-000
.OOO
-000
.000
-000
-000
-000
211
kJ
1 6 . 4 0 5 kJ
kJ
MOLAR VOLUME
................................................................................
P
~ 1 0~7 ~
~ 107
BOKLING POINT
TRANSITIONS I N REFERENCE STbTE ELEMENTS
-000
-000
-000
.000
-000
-000
-000
0.000
COUPILED
4-17-76
-----------___-_----------------------------------------------------------------
REFERENCE
107
107
92
THERIOOINABIC PROPERTIES OF lINBBALS
RUTHENIUB (REFERENCE STATE)
PROPERTIES AT HIGH TEHPERATUR ES
PORBULI WEIGHT
101.070
___-__----_---__-__----------========================s==========================
-----------------------------
suLPUR (REFERENCE STATE)
93
FORnULA UEIGHT
32.060
.................................................................................
Ru:
Hexagonal c l o s e packed c r y s t a l s 298.15
t o 1800 K.
5:
------------------------------------------------------------------------------FORIATIOU
TEIP.
(H;-Hiq8)/T
5;
-(<-H;~~)/T
C;
ENTHALPI
Faom T H E ELEIENTS
GIBBS
FREE ENERGI
Log Xi
O r t h o r h o m b i c c r y s t a l s 298.15 t o 368.54
m e l t i n g p o i n t 388.36 K.
L i q u i d 388.36
d i a t o n i c g a s 7 1 6 . 9 t o 1 8 0 0 K.
------------------------------------------------------------------------------TEIIP.
J/mol.K
298.15
0.000
UNCERTAINTY
J/mol.K
J/mol.K
28.53
0.21
28.53
0.21
J/mol'K
kJ/mol
24.05
0.000
K.
n o n o c l i n i c c r y s t a l s 368.54 t o
t o b o i l i n g p o i n t 7 1 6 . 9 K.
Ideal
( H ; - H ~)/T
~ ~
-(<-H;~~)/T
S!
C:
PORIIATION FROn THE ELEBENTS

GIBBS
ENTHALPY
FREE ENERGY
Loq K~
kJ/mol
0.000
0.000
298.15
0.000
UNCERTAINTY
31.80
0.21
31.80
0.21
22.72
0.000
0.000
0.000
-------------------------------------------------------------------------------BELTING POINT
ENTHALPY OF BELTING
2523
24.280
BOIL1 NG POINT
4423
kJ
595.540
kJ
BELTING P O I N T
388.36
ENTHALPYOF BELTING
?RAUSITIONS
BOILING POINT
1.715 k J
4.410
lOLAR VOLUBE
kJ
716.9
K
W
I N REPEEEUCE STATE ELEBEUTS
HEAT CAPACITY EQllATION
REFERENCE
107
107
- l . l 3 2 0 x 1 0 * T-2
(EQUATION VAL10 PBOM
716.9
1 8 0 0 K)
-------_--__-__---__-----------------------------------------------------------R
2~4 7
~ 2 4 7~
COB OIL ED
5-21-76
94
THERBODYNABIC
FORHULA WEIGHT
D I A T O M I C SULFUR
64.120
O C ~ ~ - ~ T O HSULFUR
IC
===============================L=r=================================================
I d e a l d i a t o n i c gas 298.15
S,:
95
P R O P E R T I E S A T H I G H TEBPERATUBES
PROPEBTIES O F HINERALS
256.480
FORBULA Y E I G H T
................................................................
t o 1 8 0 0 K.
I d e a l o c t a t o n i c g a s 298.15
5,:
t o 1800
K.
................................................................................
PORMATION FROM T H E ELEBENTS
TEnp.
J/mol-K
J/mol-K
J/mol-K
298.15
0.000
UNCERTAINTY
228.17
0.05
228.17
0.05
J/molsK
kJ/mol
kJ/mol
J/mol.K
................................................................................
32.46
128.490
0.500
79.453
0.669
( H ; - H ~ ~ )/T
~
S;
-(G~-H;~~)/T
J/nol-K
J/mol*K
FORHATIOY F R O B T H E ELEMENTS
GIBBS
ENTHALPY
FREE ENERGY
l o g K~
C;
J/mol-K
kJ/mol
430. 32
1.67
430. 3 2
1.67
156.0Q
101.253
0.628
kJ/mol
41.290
66.984
84.788
97.859
477.90
515.75
547.44
574.61
436.61
448.77
462.65
476. 7 5
166.86
172.15
175.23
177. 1 8
800
900
1000
101.861
115.763
122.164
598.36
619.44
638.38
490.50
503.68
516.22
1100
1200
1300
1400
1500
1600
1700
1800
127.454
131.897
135.682
138.943
141.783
144.279
146.489
148.459
655.56
671.2'9
685.79
699.23
711.75
723.48
734.51
744.91
528.11
539.39
550. 1 1
560.29
569.97
579.20
588.02
596.45
................................................................................
-13.920
0.117
298.15
0.000
OWCERTAINTY
48.836
0.910
-8.556
0.161
................................
80.585
66.161
54.758
45.738
33.707
24.054
16.344
10.837
-4.402
-2.513
-1.423
-0.809
178.50
179. 42
180.09
-399.186
-395.952
-392.735
-38.015
7.306
51.957
2.482
-0.424
-2.714
180.5kl
180.95
181.23
181.46
181.64
181.78
181.91
182.02
-389.532
-386.31 1
-383.097
-379.923
-376.768
-373. 5 8 9
-370.436
-367.304
96.228
140.285
184.059
227.557
270.791
313.899
356.746
399.428
-U.570
-6. 106
-7.396
-8.490
-9.430
-10.248
-10.962
-11.591
................................
................................................................................
UELTING P O I N T
BOILING POINT
~ ~ L T I N PGO I N T
BOILING POINT
ENTHALPY OF MELTING
kJ
kJ
EN^^^^^^
k~
E N T H A L P Y OF V A P O R I Z A T I O N
k~
kJ
MOLAR VOLUBE
kJ
HOLAR VOLUME
'2098
9.131
T R A N S I T I O N S IN REFERENCE S T A T E E L E H E N T S
SULFUR..
...
HEAT CAPACITY
ORTHO-RON0 368.54,
8. P. 716.9
K.
R.
P.
31.330
T
RON0 388.36,
EQUATION
OF M E L T I N L
A IN
~R E F E B~ E N C E~ S T A T
~ E E L~E B E N T
~S
S U L ~ ~ ~ . . . . . ORTHO-MONO 368. 54.

B. P. 716.9 K.
CAPACITY
REFERENCE
247
247
298
1800 K )
2478.9200
24789.200
J/bar
cm3
P.
M O N O 388.36.
1 . 1 8 9 7 ~ 1 0 - 6 TZ
EQUITION
0'
-2.2639~10' T-2
H.
6.4724~10-3 T
- 1 . 6 2 6 0 ~ 1 0 6 T-2
( EQUATION VALID FROH
247
296
4.1246~102
T-0.5
1800 K )
LOHPILED
8-12-76
------------___---_----------------------------------------------------------

96
ANTIMONY ( REFERENCE STATE)

....................................................................................
PORROLA YEIGHT
121.750
,~ANDIOU (REFERENCE STATE)

................................................................................
--
R h o m b o h e d r a 1 c r y s t a l s 298.15
t o .eltin9
p o i n t 904 K.
-(G;-H;~~)/T
S;
C:
PORMATIOW PROR THE ELERENTS

GIBBS
ENTHALPY
FREE E N E R G Y
~ o K~
g
TEHP.
45.52
0.21
25-26
0.000
PORUATION FROM THE ELEMENTS

GIBBS
EUTHALPY
FREE ENEBGY
l o g K~
- ( G ; - H ~ ~ ~ ) / T C;
J/mol-K
J/mol-K
298.15
0.000
~NCEBTA
NTIY
34.64
0.21
J/mol. K
~/mol.K
k~/mol
kJ/mol
................................................................................
K
J/mol-K
J/moL.K
J/mol-K
J/mol-K
kJ/mol
kJ/mol
................................................................................
45.52
0.21
c u b i c ) 1 6 0 8 t o 1 8 1 2 K.
( H ; - H ~ ~ ~ ) / T5;
298.15
0.000
UNCERTAINTY
................................................................................
................................................................................
( H ; - H ~ ~)/T
~
t o 1 6 0 8 K.
00.956
L l q u i d 904 t o
(body-centered
TEUP.
FORRULA WEIGHT
Alpha c r y s t a l s ( h e x a g o n a l c l o s e p a c k e d ) 298.15
%:
Sb:
97
THERMODYNARIC PROPERTIES OF MINERALS
0.000
0.000
34.64
0.21
25.45
6.000
0.000
0.000
................................................................................
ELTI
NG P O I N T
HELTING POINT
904
BOILING POINT
1860
1812
ENTHALPY O F MELTING
ENTHALPY OF RELTING
19.874
kJ
ENTtlALPY OF VAPOBIZATIOU
86.525
14.096
kJ
5.870
H:
3100
314.1 9 0 kJ
kJ
5.217 k J
'&I3
BOILING POINT
I(
ROLAR VOLURE
SOLAR VOLUHE
kJ
a I N ~REFERENCE
~
~ STATE
~ ELEMENTS
~
~
TRANSITIONS IN REFERENCE STATE ELEHENTS
1 . 2 6 1 7 x 1 0 S T-2
298
- 2 . 4 7 6 0 ~ 1 0 5 T-z
----___
904 K)
___-_______________----------------------------------------------------d--------
REFERENCE
107
107
CORPU~~
u- 13-76
&
~1 0 ~
7
E107
298
1 6 0 8 K)
COUPILED
98
TBERflODYNAUIC P R O P E R T I E S O F U I N E R A L S
SELENIUtl ( REFERENCE S T A T E )
PORnULA WEIGHT
...............................................................................
......................
Se:
C r y s t a l s 298.15
PROPERTIES
78.960
s I L I C O U ( REFERENCE S T A T E )
FoRnuu
28.086
WEIGHT
...............................................................................
t o m e l t i n q p o i n t 494 K.
494 t o b o i l i n g p o u t
Liquid
si:
C r y s t a l s 298.15
1685 t o 1800 K ,
Liquid
................................................................................
................................................................................
(HTO-H;~~
99
HIGH TEUPERATURES
I d e a l d i a t o m i c g a s 957 t o 1 8 0 0 K .
957 K .
TEHP.
AT
)/T
J/aol-K
-(c~-H;~~)/T
S;
J/aol- K
298.15
0.000
UNCERTAINTY
J/mol.K
C;
PORflATION FROB T H E E L E n E N T S
GIBES
ENTHALPY
F R E E ENERGY
L o g Kf
J/mol*K
kJ/mol
kJ/mol
42.27
0.05
42.27
0.05
25.06
0.000
4 00
4 94
6.556
10.446
49.826
55.51
43-27
45.06
26.44
27.30
.0 0 0
494
500
60 0
700
800
900
957
22.906
23.056
25.070
26.339
27.214
27.917
28.305
67.97
68.38
74.79
80.03
84.48
88.43
90.50
45.06
45.32
49.72
53.69
57.27
60.51
62.19
35.95
35.85
34.37
33.54
33.29
33.93
34.78
.OOO
.OOO
-000
000
.000
.0UO
-000
957
1000
84.275
81.481
146.44
147.29
62. 19
65.81
19.27
19.31
-000
.000
1 10 0
1200
1300
1400
1500
1600
1700
1800
75.834
71.136
67.169
63.776
60.843
58.283
56.028
54.031
149.13
150.82
162.39
153.84
155.21
156.49
157.70
158.85
73.30
79.68
85.22
90.06
94-37
98-21
101.67
104.82
19.41
19.52
19.62
19.73
19.83
19.94
20.04
20.15
.000
-000
.OOO
-000
000
.000
-000
.000
0.000
(H;-~:~~)/T
TEUP.
J/mol-K
S;
-(G;-H~~~)/T
F U R n A T I O N FROH THE E L E B E U T S
GlBBS
ENTHALPY
F R E E ENERGY
L o g Kf
C;
J/mol-K
J/mol-K
298.15
0.000
u I C E R T A I NTY
18.81
0.08
18.81
0.08
19.94
400
500
600
700
800
900
1000
5.385
8.880
11.393
13.303
14.815
16.047
17.075
25.01
30. 10
34-47
38.29
41.68
44.73
47.50
19.61
21.22
23.08
24.99
26.87
28.68
30.43
22. 15
23.47
24.40
25.10
25.66
26. 1 3
26.52
.OOO
-000
-000
.000
.000
.OOO
.OOO
-000
-000
.000
.000
.000
-000
.OOO
-000
.OOO
.000
-000
.000
-000
.OOO
1100
1200
1300
1400
1500
1600
1685
17.950
18.705
19.367
19.952
20.475
20.946
21.312
50.04
52.40
54.58
56.62
58.54
60.35
61.81
32.09
33.70
35.21
36. 6 7
38.06
39.40
40.50
26.86
27. 17
27.44
27.68
27.91
28.12
28.28
-000
000
-000
000
000
-006
.000
-000
-000
-000
.OOO
.000
000
-000
-000
.QUO
.OOO
.000
.OOO
-000
-000
1685
1700
1800
51-312
51.085
49.664
91.81
92.03
93.49
40.50
40.95
43.83
25. 52
25.52
25.52
-000
.000
-000
-000
.OOO
.000
-000
-000
.000
J/mol.
kJ/mol
kJ/nol
................................................................................
0.000
-000
................................................................................
0.000
.
.
.
0.000
0.000
................................................................................
___________________------------------------------------------------------------................................................................................
ENTHALPY OF n E L T I NG
~ ' h 8T R A N S I T I O N S IN
BOILING POIYT
957
MELTING P O I N T
6. 1 5 9 k J
53.563
E N T H A L p OF
~
NELTING
5. 5 1 9 k J
8 O L d R VOLUUE
494
UELTING P O I N T
0.67669
T-2
( E U U A T I O N V A L I D FROR
4 . 1 b 7 5 ~ 1 0 - ~T 2
5.H695~10J
T-O.S
298 -
C:
1.1612~10-2 T
2 . 9 5 2 0 ~ 1 0 - 6 TZ
2.6879xlU5
T-Z
( m U A T I L l N VALID F R O n
1.4519~102
T-0.5
9 5 7 - 180U K )
___________________----------------------------------------------REFERENCE
75
30
3553
kJ
ENTHALPY OF V A P O R l Z A T I O N
392.840
kJ
3.217
kJ
NOLAB VOLUNE
1.2056
12.056
J/bar
cm3
- 1.7864~102 T-o.5
2 9 8 - 1685 K )
31-778 +
5. 3878x10- T
( E Q U A T I O N V A L I D FROM
1 . 4 6 5 4 ~1 0 s T-2
----__..........................................................................
494 K )
R
=
BOILING POINT
50.551
BEAT C A P A C I T Y E Q U A T I O N
- 2 . J0L4x10b
Ci
H:
T R A N S 1 I~N ~ R~E F~E R~E N C E S T A T E E L E H E N T S
C i = -4.5189~102
G98
1685
~1 0 7 ~
1~0 7 C
--_.............................................................................
C O U P I L ED
4-10-76
r
100
THERHODYNAHIC P R O P E R T I E S OF HINERALS
. SAIAUUH
FORHULA Y EIGHT
( REFERENCE S T A T E )
................................................................................
.........................
Sm:
298.15
Alpha c r y s t a l s (rbombohedral)
P R O P E R T I E S AT HIGH TEHPEBAFURES
150.400
Tls
t o 1190 K.
c e n t e r e d c u b l c ) 1190 t o m e l t l n g p o r n t
1 3 4 5 K.
H
)/T ~
~ S;~
- ( G - H : ~ ~ ) / TC;
J/mol-K
J/mol-K
J/mol.K
Se:
L l q u l d 1345 t o 1 8 0 0 K.
298.15
0.000
UNCERTAINTY
69.50
2.09
69.50
2.09
29.63
C r y s t a l s 298.15
TEIP.
kJ/mol
0.000
K.
l i q u i d 5 0 5 t o 1 8 0 0 K.
---
P O R I A T I O N F R O I T H E ELEHENTS
G I BBS
ENTHALPY
FREE ENERGY
L o g Kf
J/mol-K
118.690
FORHULA WEIGHT
B e t a c r y s t a l s (body-
-------------------------------------------------------------------------------TEIP.
( REFEREUCE S T A T E )
.................................................................................
( H ~ - H ; ~ ~ ) / T S;
-(G;-H&~)/T
C;
F O R I A T I O N FROB THE ELEHENTS

GIBES
EMTHALPY
FREE ENERGY
L o g Kf
kJ/mol
0.000
0.000
400
500
600
700
800
900
1000
7.900
13.426
17.745
21.176
23.924
26.163
28.038
78.59
86.50
93.66
100.10
105.86
111.05
115.78
70.69
73.07
75.91
78.92
81.94
84.89
87.74
33.20
37.68
40.75
42.58
43.66
44.47
45.36
.000
-000
.OOO
-000
.000
.000
-000
.000
.000
-000
.OOO
-000
-000
U00
-000
-000
-000
.OOO
.OOO
.UOD
000
1100
1190
29.667
30.899
120.16
123.79
90.49
92.89
46.63
48.27
-000
-000
.OOO
.OOO
.OOO
.OOO
1190
1200
1300
1345
33.662
33.772
34.785
35.195
126.55
126.93
130.69
132.39
92.89
93.16
95.90
97.20
46.94
46.94
46.94
46.94
-000
-000
-000
.OOO
000
-000
-000
-000
-000
-000
OCO
.OOO
1345
1400
1500
1600
1700
1800
41.603
41.941
42.493
42.975
43.401
43.778
138.80
140.71
144.18
147.42
150.46
153.33
97.20
98.77
101.69
104.42
107.06
109.55
50.21
50.21
50.21
50.21
50.21
50.21
.OOO
-000
.000
000
.OOO
.OOO
--------------------------------------------------------------------------------
.0 0 0
.000
.000
.000
-000
.000
.000
000
.000
.000
.OOO
.OOO
-------------------------------------------------------------------------------ENTHALPY O F I E L T I N G
G98
B O I L I N G POINT
2064
8.619
166.405
kJ
7.573
kJ
MOLAR VOLUHE
1.9980
19.980
J/bar
1345
NELTING POINT
E~HALPY
OF IELTING
C:
0.23954
5 . 9 1 7 8 ~ 1 0 6 T-2
( E Q U A T L O NV A L I D
mun
7 . 9 0 0 9 ~ 1 0 - 5 TZ
298 -
6.5623~10'
107
107
7.029
ENTHALPY O F VAPORIZATION
6.322
kJ
HOLAR VOLUlE
2876
295.770
kJ
CAPACITY
EQUATIONS
T - O ' ~
1190 K )
_______-___-_-_____------------------------------------------------------------REFERENCE
B O I L 1 SG P O I W
T ~ ~ ~ S I T I O INNS REFERENCE S T A T E ELEHENTS
EQUATIONS
4.0750~102
498
c13
T R A N S I T I O N S I N REFERENCE S T A T E E L E I E N T S
HEAT CAPACITY
505.1
~ L T I N GP O I NT
COBPILED
4-2 7-76
6.0419x10*
T-2
( EQUATION VALID FRO8
298
505. 1 K )
-------------_-----__-----------------------------------------------------------
P
___________________-------------------------------------------------------------
---_
~1 0 7 ~
1 0~ 7
COIPILED
4-10-76
102
S T R O N T I U I ( REPERENCE S T A T E )
. .-. .-. . .-. .. .-. .-.. .. .-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Sr:
P R O P E R T I E S AT
THERBODY NABIC P R O P E R T I E S O F N I N ERALS
TANTALUM ( R E F E R E N C E S T A T E )
..................................................................................
87.620
FORHULA UEIGHT
Gamma c r y s t a l s
Alpha c r y s t a l s (face-centered
c u b i c ) 298.15 t o 8 2 8 K.
L i q u i d 1041 t o
( b o d y - c e n t e r e d c u b i c ) 8 2 8 t o m e l t i n g p o i n t 1 0 4 1 K.
b o i l i n g p o i n t 1 6 5 2 K.
I d e a l m o n a t o m l c g a s 1 6 5 2 t o 1 8 0 0 K.
Ta:
Body-centered
103
HIGH TEBPERATURES
FORBULA YElGHT
180.948
t o 1 8 0 0 K.
________________-__-------------------------------------------------------------__-----------------------------------------------------------------------------FORBATION FROB THE ELEBENTS

GIBBS
TEHP.
( H ; - H ~ ~)/T
~
-(G;-H~~~)/T
S:
C;
ENTHALPY
FREE E N E R G Y
~ o K~
g
TEMP-
(H;-H;~~)/T
J/mol-K
kJ/mol
SOT
-(G;-H~~~)/T
J/mol.K
J/801eK
N E B A T I O N FROB THE E L E n E N T S
GIBBS
FREE ENERGY
L o g Kf
ENTHALPY
C;
J/mol.
kJ/mol
kJ/mol
K
.J/mol. K
J/.0l.
K
J/.0l.K
J/mol-K
kJ/nol
-_-____________-___-------------------------------------------------------------__------------------------------------------------------------------------------
298.15
0.000
UNCERTAINTY
55.40
0.17
55.40
0. 17
29. 18
0.000
0.000
0.000
.0 0 0
.000
.a00
-000
.000
.000
000
.000
.ooo
.ooo
-000
00u
..OOO
000
-000
-000
-000
-000
.000
.ooo
.ooo
.000
35.15
.000
.000
.00u
73.59
76.43
79.06
81.50
83.79
85.94
87.00
35.15
35.15
35.15
35.15
35.15
35.15
35.15
.000
-000
.000
000
.000
W0
-000
.ooo
.000
-000
.000
.000
-000
.ooo
-000
-000
.ooo
.000
.000
000
-000
87.00
90.19
96.54
20.82
20.82
20.82
-000
.000
.000
.DO0
.UU0
.000
400
500
600
700
800
828
7.020
11.468
14.730
17.353
19.620
19.970
63.49
70.01
75.67
80.76
85.50
86.83
56.47
58.54
60.94
63.41
65.88
66.86
28.41
30.12
32.02
34.22
36.82
37.63
-000
.000
-000
-000
000
.000
82 8
900
1000
104 1
21.121
22.444
23.966
24.503
87.98
90.83
94.79
96.44
66.86
68.39
70.82
71.93
37.66
37.66
37.66
37.66
.000
-000
1041
32.381
104.31
71.93
1100
1200
1300
1400
1500
1600
1652
31.529
32.747
32.932
33.089
33.227
33.346
33.403
106.12
109.18
111.99
114.59
117.02
119.29
120.41
1652
1700
1800
116.317
113.621
108.468
203.31
203.81
205.01
298. 1 5
0.000
UNCERTAINTY
41.51
0. 17
41.51
0.17
25.36
0.000
0.000
0.000
___________________-------------------------------------------------------------
_-_________________-------------------------------------------------------------
_______-_________-_-------------------------------------------------------------000
.000
.000
_-___-__-__-_______------------------------------------------------------------nE L T I NG P O I N T
ENTHALPY O F n E L T 1 N G
4 9 8 -
------__-_-_-__-_-_--------------_--------------
BOILING POINT
1652
~ E L T I N GP O I N T
8.101
kJ
136.973
kJ
E N T H A L P Y OF nEI.TING
6.360
kJ
HOLAU VOLUNE
3.3921
33.921
J/bar
ca3
$98
-__-__-____________------------------------------------------------------------107
124
- H;
TRANSITIONS
T R A N S I T I O N S I N REFERENCE STATE E L E n E N T S
REFERENCE
3187
1041
C O ~ P I LED
5-11-76
I N
BOILING POINT
5731
31.631
kJ
743. 130 k J
5.636
kJ
NOLAR VOLUnE
1.0851
10.851
kEFERENCE STATE ELEMENTS
J/bar
cm'
r
104
P R O P E R T I E S AT HIGH
THERMODYIAHIC P R O P E R T I E S OF M I I E B A L S
TERBIUH ( REPEREUCE S T A T E )
PORHULA YEIGHT
158.925
-_____---_=I==iiS==_ES=E=5=====I========================================~=============~=
-- -- - -- A l p h a c r y s t a l s ( h e x a g o n a l c l o s e p a c k e d ) 2 9 8 . 1 5 t o 1 5 6 0 K.
Beta crystals
L r q u r d 1630 t o
( b o d y - c e n t e ~ e d c u b r c ) 1 5 6 0 t o m e l t l n g p o i n t 1 6 3 0 K.
1 8 0 0 K.
Tb:
................................................................................
(H ~ - H ; ~ ~ ) / T
TEMP.
K
J/mol-K
TEnPERATURES
TELLURIUH ( R E F E R E N C E STATE )
.................................................................................
C r y s t a l s 298.15
Te:
t o m e l t l u g p o l n t 7 2 3 K.
SOT
-(G~-H;~~)/T
J/mol. K
EUTHALPY
C:
J/mol.
kJ/mol
P R E E ENERGY
~ o K~
g
Liquld
7 2 3 t o b o ~ l l n gp o r n t
I d e a l d l a t o m l c g a s 1261 t o 1 8 0 0 K.
1 2 6 1 K.
.............................................................................
PORMATION PROH THE ELEHEUTS

GIRBS
J/mol.K
127.600
PORHULA WEIGHT
PORHATION FROH THE ELEHENTS

GIBBS
( ~ ; - ~ ; 9 8 )/T
TEUP-
kJ/mol
- ( G ; - H ; ~ ~) / T
5;
C;
J/mol-K
J/mol-K
J / m o l -K
J/mol.K
298.15
0.000
"NcERTAINTY
49.50
0.42
49.50
0.42
25.70
6.830
11.272
14.602
17.297
17.866
57.37
63.85
69.54
74-69
76.22
50. 54
52.58
54.94
57.39
58.36
42.055
41.631
41.189
40.835
100.41
103.83
108.27
112.23
40.546
40.305
40.177
80.099
78.256
ENTHALPY
FREE ENERGY
kJ/mol
L o g Kf
kJ/mol
___________________----------------------------------------------------------------------------------------------------------------------------------------298.15
0.000
UNCERTAI NTY
73.30
0.84
73.30
0.84
28.91
400
500
600
700
800
900
1000
7.225
11.452
14.428
16.736
18.650
20.311
21.803
81-63
87.97
93.31
98.02
102.30
106.25
109.96
74.40
76.52
78.88
81.28
83.65
85.94
88.16
28. 1 5
28.76
29.90
31.29
32.81
34.41
36.06
11 00
1200
1300
1900
1500
1560
23.175
24.458
25.675
26.843
27.967
28.676
113.48
116.83
120.06
123.17
126.19
128.03
90.31
92.37
94.38
96.33
98.22
99.36
37.73
39-43
41.14
42-86
4'4.60
45.64
1600
16 30
31.791
31.727
131.96
132.58
100. 17
100.86
27.74
27.74
1630
1700
1800
38.349
38.682
39.113
139.21
141.08
143.76
100.86
102.40
104.65
46.48
46.48
46.48
0.000
0.000
0.000
0.000
0.000
0.000
27-95
30. 15
32.36
34. 57
35.07
.000
.OOO
.OOO
-000
.000
.000
.000
-000
.OOO
00 0
.000
.000
.000
.000
.000
58.36
62-20
67.08
71.39
37.66
37.66
37.66
37.66
.000
-000
-000
.OOO
.000
.000
-000
-000
.000
.000
00u
-000
115.82
119.10
120.97
75.27
78.80
80.79
37.66
37.66
37. 6 6
.000
-000
-000
000
-000
00U
.
.
.000
-000
.0U0
160.89
161.46
80.79
83.20
18. 6 6
18.66
.OOO
.OOO
-000
-000
-000
.OOO
................................................................................
___________________------------------------------------------------------------................................................................................
1630
UELTING P O I N T
ENTHALPY OP MELTING
li&8
H:
T R A N S I T I O N S IN
BOILING
10.795
kJ
POINT
9.426
kJ
MOLAR VOLUHE
R E F E R E N C E STATE E L E H E N T S
HEAT CAPACITY EuUATION
C"
--
107
330.890
NELTING P O I N T
723
BOILING P O I N T
17.489
k~
H OF
~ ~H E~L T ~I N G
6 . 121 k J
UOLAR VOLUW
1261
50.341
kJ
2.0476 J / b a r
20.476
cm3
IN ~ R E~F E R~E N C~E S T~A T E~ E L~E N E N T S
CAPACITY E Q U A T I O N
17.894 t
1.7650~10-2 T
(EQUATION VALID PROH
REFERENCE
3496
107
298
5.1149x105 T - ~
- 1560 K)
l9-124 + 2.2061~10-2 T
( E Q U A T I O N VALID FROB
298
723 K )
.................................................................
107
...........................................................................
COHPIL ED
8-06-76
10 6
THEBRODY N A U I C
P R O P E R T I E S AT HIGH
P R O P E H P I E S O F 1 IN E R A L S
THORIUn ( REFERENCE S T A T E )
FORnULA
WEIGHT
TITANIUM
232.038
Alpha c r y s t a l s (face-centered
( body-centered
cublc)
c u b l c ) 298.15
1636 t o a e l t l n y
t o 1 6 3 6 K.
107
(BEPERENCE STATE)
F o a n u L A WEIGHT
47.900
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
.....................................................................................
~ h :
TEMPBBATURES
~ l p h ac r y s t a l s ( h e x a g o n a l c l o s e p a c k e d )
Beta c r ystdls
(body-centered
p o l n t 2028 K.
cublc)
t o 1 1 5 5 K.
298.15
1155 t o m e l t i n g p o i n t 1943
Beta crystals
K.
_________-_______-_-------------------------------------------------------------____---------------------------------------------------------------------------FURUATION
( I I ; - H ~ ~ ~ ) / T S;
TEMP.
J/mol-K
J/mol-K
-(G;-H:~~)/T
C:
J/mol-X
J/mol-K
EUTHALPY
FHOU THE E L E f l E N T S
GIBBS
FREE ENERGY
kJ/mol
TEUP.
o K~
y
tH;-~;98
)/T
)/T
S:
C:
P O R I A T I O N FBOU T H E ELEMENTS
G I BBS
ENTHILPY
F R E E ENERGY
L o g Kf
kJ/mol
___-_______________--------------_---------------------------------------------298. I 5
0.000
UNCERTAINTY
53-39
0.84
5 3 . 39
0.84
27.32
400
500
h00
700
800
900
1000
7.1 I0
11.560
14.727
17.169
19.160
20.849
22.328
61.61
6 8 . 1
73.71
78.61
83.03
87.07
90.83
54.48
56.58
58.98
61.44
63.87
66.22
68. 5 0
28.65
29.92
31.19
32.46
33.73
35.00
3b.27
110 0
1200
1300
1400
1500
1600
1636
21.654
24.864
25.987
L7.04U
28.037
28.990
29.3UU
94.34
97.66
100.82
103.84
106.74
109.53
110.53
70.69
72.80
74.83
76.80
7d.70
HD.54
81.27
37.55
38. 82
40.09
41.37
U2.bU
UJ.92
4U.38
0.000
0.000
U.000
.a00
.000
.000
.000
00 0
.000
.000
.0 0 0
-000
-000
.000
.000
.000
.000
000
.OD0
-----
-000
.000
OUU
-000
.ooo
________-____-_____-------------------------------.---------------------------
I 636
1700
1800
30.997
31.5h2
32.366
112.27
113.95
116.58
4b.02
46.0L
46.lJ2
81.27
82.39
84.21
.000
.000
.000
-000
.0u0
-000
................................................................................
_________________-_-----------------------..-------.-------------.------------
IIELTING P O I N T
ENTHALPY OF UELTING
HE
2028
J O I L LNG P O I N T
lb. 120 k J
5061
ENTHALPY U P V A P U R I Z A l l ! l h
~ . L , I Uk~
~ U L A RV O L U ~ E
T R A N S I T L O N S I N REFEREBCE S T A T E ELEMENT2
ilU.4bU
K
kJ
m L T I NG P O I N T
1943
ENTHALPY O F U E L T I N G
":98
T'"
15.447
H:
B O I L I NG P O I N T
3562
kJ
421.031
kJ
MOLAR VOLUUE
1.0631
10.631
Jbar
4- 8 0 7 k J
~ IN N
R E P E B E~ N C E ~S T A T E~ E L E M
~ E N T S~
ca3
CAPACLTY E Q U A T I O N S
HEAT C A P A C I T Y i:i)::ATl(!hi
c;
21.317 +
:.,!79jx10-.'
T
(EbUATION VALID FBOU
REFERENCE
107
1U 7
+
i'lk
? . r b h ~ :.-0-5
- 1636 K )
'l.LLti9x10J
C;
17.fi8
+
1.1603~10-2 T
( EQUATIOli V A L I D FROU
+
298
1. 1 8 2 6 r 1 0 '
1155 K)
T-O-5
2.2609~105 T-2
17-274 +
1.0368~10-2 T
( E Q U A T I O N V A L I D FROU 1 1 5 5 - 1 8 0 0 K )
--- -- -_.........................................................................
------___
R
1~ 0 7~
107
COMPILED
THERMODYNAMIC P R O P E R T I E S O F R I N E R A L S
P R O P E B T I E S AT
'II
109
HIGH TEHPERATUR E S
T H o L r u a ( REFERENCE S T A T E )
THALLIUN ( REFERENCE STATE)
FORMULA W E I G H T
204.370
PORHULA Y E I G H T
168.934
_
.~ ..
_ . _.~ _~
. . _ _~
- ~ . _ _.- - -_
_ - _ __
_ _ - -_
- - - - -_
- - - - -.
- - - -~
- - - - -_
- - - - -_
- - - - - -_
- - - - -.
-==
_
= - - -~
- - - - -~
- - - - _ _-----------_ _ ~ ~ ~ ~ ~
. ~ ~ ~ ~ ~ - - - - - - - - - - - - - - - - - - - ................................................................................
A l p h a c r y s t a l s ( h e x a g o n a l c l o s e p a c k e d ) 298.15 t o 5 0 7 K.
Beta crystals
( b o d y - c e n t e r e d c u b l c ) 5 0 7 t o m e l t l n g p o l n t 5 7 7 K.
L l q u l d 577 K t o
T1:
H e x a g o n a l c l o s e p a c k e d c r y s t a l s 298. 1 5 t o r e l t i n g p o i n t
Tm:
1 8 1 8 K.
___________________-------_------------------------------------------------------ ..............................................................................
FORMATION FROH T H E ELEflENTS

GIBES
J/mol.K
J/mol-K
J/mol-K
J/mol-K
kJ/m01
FORHATION
TEHP.
kJ/mol
(H;-H&~)/T
J/mol.K
- ( G > H ~ ~ ~ ) / T C;
S;
J/mol-K
J/mol-K
ENTHALPY
J/mol. K
FROM T H E E L E M E N T S
GABBS
F R E E ENERGY
l o g K~
kJ/mol
kJ/mol
______________-____------------------------------------------------------------_____-------------------------------------------------------------------------298.15
0.000
UNCERTAINTY
6.827
11.134
11.188
400
500
107
h4. 18
0.21
64. 18
0.21
26.33
72.05
78.37
78.78
65.22
67.24
67.40
27.44
29. 45
29.66
0.000
0-000
.000
-000
.OOO
0.000
298.15
0.000
U N C E R T A INTY
74.01
0.00
74.01
0.00
27.03
0.000
U.000
0.000
.000
.000
-000
000
-000
.000
______-.___________----------------------------------------------------------
507
57 7
79.54
83.72
12.111
14.582
b7.40
69.12
32.01
32.68
000
.0U0
.OOO
.000
000
.000
_____________._____---------------------------------------------------------
',77
600
700
800
900
1000
21.761
22.063
23.156
23.975
24.611
25.121
90.88
92.04
96.62
100.59
104.09
107.22
69.12
69. 98
73.46
76.61
79.48
82.10
29.71
29.71
29.71
29.71
29.71
29.71
.000
.000
.OOO
.OOO
.OOO
000
.U00
-000
.000
-000
-000
.OOO
1100
1200
130U
1400
1500
1600
1700
1744
25.538
2'5.885
26.179
26.411
26.649
26.841
27.009
27.077
110.05
112.64
115.01
117.22
119.26
121. 18
122.98
123.77
4.51
86.76
88.83
90.79
92.61
94.34
95.97
96.70
29.71
29.71
29.71
29.71
29.71
29.71
29.71
29.71
-000
.000
000
006
000
-000
.000
-000
.000
.OOO
.OOO
00 0
-000
.00U
.OOO
.
.0 0 0
.
..
.0 0 0
.000
.000
.000
.OOO
.OOO
.000
-000
-000
.OOO
-000
.000
-000
000
_._-__-____________----------------------------------------------------------
1744
1800
121.200
118.115
217.90
218.56
96.70
100.44
22.05
22.05
-000
000
.ooo
-000
.000
-000
---_--_---_________--------------------------------------------------------
__________________-------------------------------------------------------------~ L T I N G POI
577
f l E L T I NG P O I N T
1818
LIT
E N r H k ~ ~O
YF MELTING
ENTHALPY O F n E L T I N G
ENTHALPY
6.828
HOLAH VOLUME
OF V A P O R I Z A T I O N
164.151
kJ
1.7210
17.210
cm3
G98
- "0
"298
4. 142 k J
TRANSITIONS I N
kJ
cg
CAPAClTY
BOILING
2220
16.841
kJ
ENTHALPY O F V A P O R I Z A T I O P
190.670
kJ
7.397
kJ
8 O L A B VOLUflE
1.8126
18. 1 2 6
J/bar
POINT
J/bar
TRANSITIONS
IN
cm3
REFERENCE S T A T E ELEMENTS
CAPACITY
NEAT
1744
BOILING POINT
EQUATION
EUOATION
C:
?0.850 2.8925~10-2 T
( EQUATION V A L I D FROn
5.3134x10-5
298 507 K )
t
TZ
5.4964~10'
T-'
38.778 +
3.9669~10-3 T
( E Q U A T I O N V A L I D PBOM
3 . 8 0 9 9 ~ 1 0 2 T-0.5
298 - 1800 K )
8 . 1 1 9 2 ~ 1 0 ~T - 2
----.___
.........................................................................
' E r e ~ ~ ~ ~
1 07 ---_____________._____--------------------------------------------------107
REFERENCE
107
107
CO~PIL~"
4-30-76
___________________-------------------------------------------------------------
COM P I L E D
110
ORANIUN (REFERENCE STATE)

................................................................................
.........................
u:
PROPERTIES AT HIGd
THERHODYNAHIC PROPERTIES OF NINERALS
FORNULA WEIGHT
VANADIUN ( REFERENCE STATE)
238.029
A l p h a c r y s t a l s ( o r t h o r h o m b i c ) 2 9 8 . 1 5 t o 9 4 1 K.
Beta c r y s t a l s ( t e t r a g o o a l )
941 t o 1 0 4 8 K.
Gamna c r y s t a l s ( b o d y - c e n t e r e d c u b i c ) 1 0 4 9 t o m e l t i n g p O l n t
1 4 0 5 K.
L i q u i d 1405 t o 1800 K.
v:
Body-centered
FORNULA WEIGHT
5;
-(G;-H;~~)/T
J/mol-K
J/mol-K
298.15
0.000
UNCERTAINTY
50.29
0.13
J/mol-K
C:
ENTHALPY
J/nol-K
TEHP.
Log K f
FREE ENERGY
kJ/mol
27.68
0.000
1405
ENTHALPY OF NELTING
8.519
BOILING POINT
kJ
mLTINL POINT
464.070
2175
ENTHALPY OF UhLTINL
kJ
32.935 7.7083~10-3 T
298
2 . 8 7 2 1 ~ 1 0 - 5 TZ
- 941 K)
95.207
T-0.5
................................................................................
REFERENCE
107
107
cU~
J/mol-K
kJ/mol
24.89
28.91
0.42
0.000
YOILINL
POINT
20.928
kJ
4.640
kJ
NULA* V I ) L U ~ ~ .
0.000
0.000
CONPILED
4-30-76
j68L
451.893
kJ
0.8350 J / b a r
cm3
H. 354
T R A N ~ I T I o N ,IN REFEHENLt STATE ELEUbkTj
C:
J/mol-K
28.91
0.42
G Y R - B:
TRANSITIONS I N
-(G:-H~~~)/T
--------_-----------------------.---------.----
4407
S;
J/mol.K
298.15
0.000
UNCERTAINTY
0.000
................................................................................
nELTI NG POINT
J/mol-K
FORUATIOI FROU THE ELEflENTS

GIBBS
ENTHALPY
FREE ENERGY
~ o gK~
kJ/mol
................................................................................
kJ/mol
0.000
(H;-H;~~
)/T
................................................................................
50.29
0. 1 3
50.941
t o m e l t l n q p o l n t 2175
c u b l c c r y s t a l s 298.15
FORNATION PROn THE ELENENTS

GIBBS
(H;-H;~~)/T
11 1
................................................................................
................................................................................
TENP.
TEUPERATURES
HEAT CAPACITY LQllATLON
C;
20.403
2.tiOOUxiJ-'T
- 2 . 9 9 4 7 ~ 1 0 s 1-2
( EVdArlON VALID kRON
3 . 9 7 4 7 ~ 1 0 - 6 Pz
29H -
1800 K )
1.1614~102T-a-5
112
THERNODYNANIC PROPERTIES OF NINERALS

PROPERTIES AT HIGH TEIPEBATURES
TUNGSTEN (REPERENCE STATE)
PORNULA Y EIGHT
................................................................................
.................................
Body-centered
U:
183.850
l ~ ~ o( NREFERENCE
STATE)
.................................................................................
--
...............................................................................
( H;-H'~~~)/T
I d e a l g a s 298.15
5;
-(G;-H:~~)/T
C:
PJRNATION FRO8 THE ELEnENTS

GI88S
ENTHALPY
FREE ENERGY
Log K f
131.300
J/mol.K
J/mol-K
J/moL-K
kJ/mol
to
1800 K .
------------------------------------------------------------------------------*
TEMP-
J/mol.K
POBHULA WEIGHT
cubic c r y s t a l s 2 9 8 . 1 5 t o 1 8 0 0 K.
Xe:
TENP.
113
( H % - H ; ~ ~ ) / T S:
-(G;-H:~~)/T
C;
FOBNATION PRO8 THE ELENENTS

GIBES
ENTHALPY
FREE ENERGY
~ o q
K~
k J/mol
................................................................................
298.15
0.000
UNCERTAINTY
32.64
0. 42
32.64
0.42
24.26
0.000
400
500
600
700
800
900
1000
6.295
10.108
12.723
14.646
16.129
17.318
18.301
39.90
45.56
50.26
54.29
57.83
60.99
63.85
33.60
35.45
37.54
39.64
41.70
43.67
45.55
25.09
25.60
25.99
26.34
26.67
26.99
27.31
.OOO
-000
-000
000
-000
.000
-000
1100
1200
1300
1400
1500
1600
1700
1800
19.134
19.854
20.488
21.056
21.569
22.039
22.474
22.879
66.47
68.89
71. 19
73.24
75.23
77.10
78.89
80.59
47.34
49.04
50.65
52. 1 8
53.66
55.06
56.42
57.71
27.62
27.94
28. 26
28.59
28.92
29.26
29.60
29.95
.000
.OOO
-000
000
.UOO
-000
000
-000
0.000
0-000
................................................................................
MELTING POINT
ENTHALPY OF NELTING
~ ; 9 8 - H:
3680
35.397
WILING POINT
5828
kJ
823.913
kJ
4.979 kJ
................................................................................
~
T NG I P O I N T
ENTHALpr OF RELTING
NOLAR VOLUNE
24.843 +
2.2255~10-3 T
(EQUATION VALID PBON
+
3 . 5 0 4 4 ~ 1 0 - 7 Tz
2 9 8 - 1 8 0 0 K)
1 . 1 1 5 3 ~ 1 0 T-'
~
..................................................................
REFERENCE
107
B O I L I NG POINT
ENTHALPY OF VAPOBIZATION
6. 197 k J
NOLAB VOLUNE
165.03
12.636
2u78.9200
24789.200
I ~N REFERENCE
~
~
~
~STATE
~
~ ELENENTS
BEPEBENCE 1 0 7
2. 297 kJ
K
kJ
Jhar
cm3
---___
------_--__-_~_____-------------------------------------------------------
C;
161.36
107
...............................................................................
35
---__...........................................................................
CONPILED
3-11-76
P B O P E B T I E S A T BIGH T E I P E B A T U B E S
114
THERIODY NA8IC
1 15
P R O P E R T I E S OF NINEBALS
r r T E ~ s( ~B E~P E8B E N C E
YTTRIUI (REFERENCE STATE)
FORNULA UElGHT
STATE )
..................................................................................
88.906
173.040
FORNULA H E I G H T
..................................................................................
"pha
c r y s t a l s ( f a c e c e n t e r e d c u b i c ) 298.15 t o 1 0 3 3 K.
Beta crystals
(body-centered
c u b i c ) 1 0 3 3 t o m e l t i n g p o i n t 1 0 9 7 K.
b o i l i n g p o i n t 1 4 6 5 K.
yb:
Y:
A l p h a c r y s t a l s ( h e x a g o n a l c l o s e p a c k e d ) 2911.15 t o 1752 K.
Beta crystals
( b o d y - c e n t e r e d c u b i c ) 1752 t o m e l t l n g p o i n t 1 7 9 9 K.
L l q u l d 1799 t o
b o i l i n g p o i n t 3 6 1 1 K.
______-___________-------------------------------------------------------------F J R U A T I O N PRO8 THE E L E n E N T S

GIBEIS
TE~P.
(H;-H;~~)/T
-(G;-H~~~)/T
S;
C:
ENTHALPY
FREE ENERGY
FORMATION
TE,,D.
( B ~ - H ; ~ ~ ) / T S;
J/mol.K
J/nol-K
J/mol.
J/mol- K
kJ/mol
kJ/moI
_-______________-__------------------------------------------------------------44.43
0.25
44.43
0.25
26.53
0.000
0.000
C:
ENTHALPY
K~
o K~g
J/mol-K
298.15
0.000
UNCERTAINTY
-(G;-H~~~)/T
FBOR THE E L E I E N T S
GIBBS
FREE ENERGY
LO^
0.00o
J/molWK
J/mol-K
J/m01-K
kJ/mol
kJ/.0l
................................................................................
298.15
0.000
59.83
59.83
0.17
0.17
6.900
11.312
13.220
67.79
71.24
77.66
60.89
62.93
64.44
27.61
31.02
34.90
-000
.000
.000
.ooo
00 0
-000
-000
-000
.00o
13.349
1'4.658
16.859
18.574
19.968
21.138
21.487
77.79
79.97
84.60
88.68
92.35
95.68
96.73
64.44
65.31
67. 7 4
70.11
72.38
74.54
75.25
29.68
29.84
30. 3 1
30.85
31.40
31.92
32.05
-000
-000
-000
-000
-000
-000
.000
-000
-000
-000
.ooo
.000
.000
.000
-000
-000
-000
-000
-000
.000
-000
23.180
98.45
75.25
36.11
-000
-000
-000
23.937
100.62
76.69
36.11
.000
-000
-000
30.917
30.928
31.416
31.828
32.182
107.61
107.67
110.87
113.81
116.54
76.69
76.74
79.45
81.98
84.36
36.78
36.78
36.78
36.78
36.78
.ooo
.ooo
-000
000
.0o0
.000
.ooo
.ooo
-000
.o00
u~cERTAINTY
26.72
0.000
0.000
0.000
............................................................................
000
-000
-000
.ooo
-000
................................................................................
__________-________------------------------------------------------------------ilELTING POINT
ENTHALPYOFUELTING
4 9 0 - H:
TRANSITIONS
1799
11.397kJ
5.966
kJ
W I L I N G POINT
3611
ENTIIALPY OF V A P O R I Z A r I U N
3bJ. 3 4 0 kJ
NULAH VOLUiiE
1.50 38 J / b a r
15.038
cm3
I(
~ E L T I u GP O I N T
1097
E N T H a ~ ~OP
Y HELTING
BOILING POINT
1465
7. 6 5 7 k J
ENTHALPY O F V A P O R l Z A T I O N
128.935
6.711
8OLAR VOLUfiE
2.4830
24.830
J/bar
cm3
kJ
r P A N s l T ~I N~ ~REFERENCE
~
STATE ELENENTS
IN R E F E R E N C E S T A T E ELEUENTS
"AT
C A P A C I T Y EQUATIONS
HEAT C A P A C I T Y EUUATION
C:
___________________------------------------------------------------------------REFERENCE
107
107
~ 4~- 2~6 -P7 6I L E D
''
5 - 1 2 0 2 ~ 1 0 2-
0.73984
2. 1 1 9 1 x 1 0 6 T - z
( E Q U A T I O N V A L I D FRO8
298
5.6939~10-*
T2
5.8564~103 T-oes
553 K )
2-7211~10-2 T
- 7 . 9 8 3 8 ~ 1 0 - 6 Tz
+ 4.0139x102
( E Q U A T I O N VALID F R o n
553 - 1033 K )
T-0.5
107
......................................................................
COIPILED
4-30-76
PROPERTIES AT HIGH TENPERATURES
ZINC ( nEPEREUCE STATE)
PORllUlA WEIGHT
..................................................................................
....................
H e x a g o n a l close p a c k e d c r y s t a l s 2 9 8 . 1 5
Zn:
692.7
K.
c r y s t a l s 1136
J/mol-K
J/mol.K
J/aol-K
:
C
PORIATIOH FROI THE ELEHENTS

GIBBS
ENTHALPl
FREE ENERGY
Log K f
J/aol.K
kJ/mol
41.63
0. 1 3
41.63
0.13
25.40
0.000
0.000
0.000
ENTHALPY OF NELTING
498
HE
t o a e l t r n g p o i n t 2 1 2 5 K.
( H~-H:~~)/T
TEMP.
-(G~-H&~)/T
S;
298.15
0.000
UNCERTAINTY
38.99
0. 17
38.99
0.17
BOILING POINT
1178
IIELTING POINT
7.322
kJ
ENTHALPY OF VAPORIZITION
115.353
kJ
ENTHALPI OF HELTING
5.657
kJ
MOLAB VOLUHE
4 9 8
2125
1 6 . 8 9 5 kJ
5.531
kJ
TRINSITIONS I N REFERENCE STATE ELEHENTS
2 . 4 5 8 4 ~ 1 0 5 T-2
298
107
C:
FORIATlON PROM THE ELEIENTS

GIBBS
ENTHALPY
FREE EYERGY
Log K f
25.37
0.000
0.000
0.000
BOILING POINT
4682
582.045
kJ
MOLAR VOLUME
6 9 2 . 6 6 K)
................................................................................
................................................................................
REFERENCE
cubic
_____________--_----------------------------------------------------------------
692.66
Body-centered
................................................................................
................................................................................
NELTIWG POINT
t o 1 1 3 6 K.
91.220
K
J/molmK
J/mOlmK
J/nol. K
J/aol*K
kJ/mol
k J/mol
................................................................................
k J/mol
................................................................................
298.15
0.000
UNCERTAINTY
FORaULA WEIGHT
Hexagonal c l o s e packed c r y s t a l s 298.15
deal m o n a t o m i c g a s 1 1 7 8 t o 1 8 0 0 K.
t o b o i l i n g p o i n t 1 1 7 8 K.
( H ~ - H ~ ~ ~ S~; ) / -T( G > H ; ~ ~ ) / T
Zr:
Liquid
--__-_-_-----------------------------------------------------------------------TENP.
zIRCONIUM (REFEREUCE STATE)
65,380
1 17
35
-------_------_---------------------------------------*-------------------------
COIPIL ED
4-10-76
REPERENCE
107
107
COHPILED
4-13-76
--------------------------------------------------------------------------------
120
THERIODTNAIIC PROPERTIES OP IIINEBALS
AMIONIA ( I D E U
manuu
GAS)
...............................................................................
I d e a l gas 2 9 8 . 1 5
NH,:
WEIGHT
17.030
l ~ ~ ~ ~ H(ARGENTITE)
I T E
PORIULA WEIGHT 2 4 7 . 7 9 6
_izl_l=======l==L===_============================================================
,4r~:
t o 1 8 0 0 K.
.............................................................................
TEIP.
5;
(H:-H;~~)/T
J/molSK
J/mol-K
J/nol. K
J/mol.
kJ/mol
kJ/.0l
-45.940
-16.410
n o n o c l i n i c c r y s t a l s 298.15
t o 452 K .
Cubic c r y s t a l s ( a r g e n t i t e ) 452 t o
................................................................................
PORIATION PBOH THE ELEUENTS

GIBES
ENTHALPY
FREE ENERGY
Log g f
- ( G ~ - H ; ~ ~ ) / T C;
121
PROPEBTIES AT HIGH TEIPERATURES
FOR~ATION PROHGIBES
THE ELEHENTS
Telp.
( H;-H&~)/T
S;
- ( G ~ - H ; ~ ~ ) / T C;
ENTHALPY
FREE ENERGY
LO^
------------------------------------------------------------------------------298.15
0-000
UNCERTAI NTY
192.78
0.08
192.78
0.08
35.63
2.875
0.350
0.350
0.061
-5.984
4.760
15.841
27.155
38.630
50.236
61.887
0.781
-0.497
-1.379
-2.026
-2.522
-2.916
-3.233
73.622
85.377
97.147
108.933
120.719
-3.496
-3.716
-3.903
-4.064
-4.201
132.535
144.307
156.066
-4.327
-4.434
-4.529
400
500
600
700
800
900
1000
9.450
15.628
20.290
24.067
27.272
30.078
32.581
203.67
212.65
220.59
227.79
234.42
240.60
246.41
194.22
197.02
200.30
203.72
207. 1 5
210.52
213.83
38.70
41.98
45.19
48.25
51.14
53.85
56.37
-48.086
-49.905
-51.430
-52.684
-53.698
-54.497
-55.113
1100
1200
1300
1400
1500
1600
1700
1800
34.852
36.932
38.852
40.636
42.293
43.841
45.288
46.641
251.89
257. 10
262.05
266.78
271.30
275.62
279.77
283.75
217.04
220. 1 7
223.20
226. 1 4
229.01
231.78
234.48
237.11
58.72
60.88
62.87
64-68
66.32
67.78
69.07
70.19
-55.56 1
-55.868
-56.052
-56.126
-56.116
-56.031
-55.884
-55.695
................................................................................
................................................................................
WLTING POINT
4 9 8
- HE
BOILING POINT
239.68
RELTING POINT
5.657
23.351
EYTHALPY OP HELTING
10.046
kJ
IOLAR VOLUHE
2478.92
24789.2
TRANSITIONS I N REPEUEYCE STATE ELEIEYTS
29.735
3.9119~10-2 T
2 . 9 2 4 3 ~ 1 0 5 T-2
298
8 . 2 2 7 4 ~ 1 0 - r Tz
1 . 4 3 7 8 ~ 1 0 2 T-0'5
1800 K )
................................................................................
REFERENCE
247
35
215
215
BOILING POINT
kJ
ENTBALPY OP VAPOBIZATION
kJ
cm3
.....
SULFUR.....
J/bar
SILVER
C; =
1061
195.36
ENTHALPY OP HELTING
I . P.
1234 K .
ORTHO-ION0 368.54,
8. P. 7 1 6 . 9 K.
1. P.
MONO 388.36,
K~
--
. --
THERUODYNAUIC P R O P E R T I E S O P I I N E R A L s
CHALCOCITE
........................................
----------------------------------------------.--------=-----------------------O r t h o r h o m b i c c r y s t a l s 298.15
Cu,S:
6 2 3 K.
t o 376 K .
C u b i c c r y s t a l s 623 t o m e l t i n g
159.152
PORUULA WEIGHT
~ e r a y o n a lc r y s t a l s 3 7 6 t o
CUFeSz:
1403 K.
l c r y~ s t a l hs
2 9~8 . 1 5
t o 8 3 0 K.
GI885
(H;-H;~~)/T
J/molsK
S;
-(G;-H;~~)/T
J/mol-K
J/mol-K
EQTHALPY
C:
J/mol-K
PBEEENEBGY
kJ/mol
k J/.0l
-80. 1 1 5
1.255
-86.868
-------------------------------------------------------------------------------298-15
0.000
120.75
2.09
UNCEBTAI NTY
120.75
2.09
76.32
15.219
1.423
0.2119
ST
~
TEIP-
~ B u A T I O N PROU THE E L E I S N T S
GIBBS
( H ~ - H ~ ~ ~ )s298
/ T - ( G ~ - B ~ ~ ~ ) / C;
T
J/.o~.K
~/mol.K
J/mol-R
EYTHALPY
J/mol.K
16.914
139.70
122.80
81.69
-82.216
-88.660
27.151
31.380
44.518
53.347
54.976
149.96
155.98
177.61
195.39
199.05
122.80
124.60
133.09
142.05
144.08
97.28
97.28
97.28
97.28
97.28
UKERTAINTY
623
700
56.316
59.473
200.40
210.29
144.08
150.82
85.02
85.02
800
900
1000
62.655
65.131
67.1 11
221.67
231.63
240.62
159.01
166.49
173.51
85.02
85.02
85.02
26.150
30. 10
42.442
53.952
63.221
54.11
74.42
92.72
71.574
72.769
110.07
115.27
83.089
91.478
95.757
125.59
139.80
1 4 8 . 27
---------
1000
96.076
101.425
148.59
160.10
-----
172.49
172. 49
-88.660
-89.269
-92.269
-95.524
-96.294
12.317
11.657
9.639
8.316
8.07~
-74.784
-74.926
-96.294
-98.904
8.073
7.380
-129.768
-128.693
-127.713
-107.896
-105.138
-1O2.631
7.045
6.102
5.361
--------------------------------------------------------------------------------
1100
12 00
1300
68.770
70.117
71.257
248.74
256. 14
262.92
179.97
186-03
19 1 . 6 7
85.02
85.02
85.02
1400
72.234
269.20
196.96
85.02
--------------------------------
---------
12.317
-78.366
-77.297
-76.675
-75.816
-75.618
------------___--_--------------
---
------------------ ----------------------------------------------------------- -- -----
106.26
109. 1 5
114.53
123.84
---
136.83
141.37
108.73
203.75
244.48
___________________------------------------------------------------------------
-126.775
-125.959
-125.221
-100.1
-97.782
-95.430
4.756
4.256
3.834
1100
107.885
176.54
---
172. 49
-151.146
-92.571
3.454
1200
113.269
191.55
---
172.49
--------------------------------
kJ/mol
___________________----------------------------------------------------------------95.77
--0.00
298.15
0.000
-------------------------------------------------------------------------------376
400
500
600
623
PEEE
kJ/mol
---------_--_--__--------------376
Gamma
c r y s t a l s 9 3 0 t o 1 2 0 0 K-
M R U A T I O N P R O l THE ELEUENTS
830 to 930 K-
Beta crystals
___________________------------------------------------------------------
------------------------------------------------------------------------------TEnP-
123
AT H I G H TBUPXRATfJR ES
m R U U L I WEIGHT
183-513
...................................................................
___________________-----
point
PBOPERTIES
-----
-----
-----
---------------------------------------------------------------------------
-------------------------------------------------------------------------------1403
UELTI N G POINT
ENTHALPY OP RELTING
4 9 8 -
B O I L I N G POINT
kJ
kJ
UOLAR VOLUnE
2.7475
27.475
kJ
________~__________-----------------------------------------------------------
J/bar
MELTING POINT
cm3
T R A N S I T I O N S I N REFERENCE S T A T E ELEMENTS
..... U. P . 1 3 5 7 K.
SULFUR.. ... ORTHO-UONO 368.54,
ENTHALPY O F I E L T I N G
COPPER
B.
P.
716.9
8.
P.
nONU
120
266
kJ
kJ
IOLAR
J/ba
VOLUnE
26
2 19
................................................................................
U.
P.
1 3 5 7 K.
...... C U R I E P. 1 0 4 2 , ALPHA-GAflUA 1184. G M I A - D E L T A

U. P. DELTA 1809 K .
SULFUR.. .. . ORTHO-RON0 368. 54. U- P - NONO 388.36.
................................................................................
115
B O I L 1 NG POINT
TRANSITIONS I N REPERENCE S T A T E E L E I E N T S
388. 36,
K.
COPPER.....
REFERENCE
IRON.
COUPILED
7-24-76
0 . P. 716.9
HEAT CAPACITY 2QUATIONS
C;
-5.8753~10'
( EQUATION
C:
K.
0.37073 T
VALID
1665.
man
+
298
1.2750110*
830 K )
T - O ' ~
1 . 4 7 2 1 ~ 1 0 T~ - ~
1.3575 1
= -1.0180~103 +
( EQUATION V A L I D FBOU
830 - 930 K)
_____~_____________----------------------------------------------------------REFERENCE
209
COnPILED
8 - 4-76
___________________------------------------------------------------------------
THERHODYNAIIC PROPERTIES OF HINERALS
PROPERTIES AT HIGH TEIPERATURES
FORMULA YEIGW
125
501.81,
8 7. 90 7- _-__-___-___---____--------------------------------------------------_
_ _ _ _ _ _ _ _ _ _ _ _ _ . _ - _ _ - - - - - - - - - - -(- - - -YEIGHT
----RO
I LI TE - - - - - - - - - - - - - - - - - - - - - - - -FORHULA
-*
..............................................................
----_=__-===============
Alpha c r y s t a l s 298.15
t o 4 8 5 K.
Beta c r y s t a l s 485 t o 540 K.
Gamma
A l p h a c r y s t a l s 298. 1 5 t o 4 1 1 K .
pe5:
c r y s t a l s 540 t o 1 2 0 0 K .
Gamma c r y s t a l s 5 9 8 t o m e l t i n g p o i n t
--
______________-_--_----------------------------------------------------------S;
TEHP.
(H;-H;,~
)/T
J/mol-K
S298
J/mol-K
-(G;-H;~~)/T
C;
J/molSK
FORBATION FROH THE ELEHENTS

-.
GIBBS
ENTHALPY
FREE ENERGY
Log
J/nol-K
kJ/aol
B e t a c r y s t a l s 411 t o C u r l e p o i n t 5 9 8 K .
1 4 6 8 K.
L i q u i d 1468 t o 1800 K.
--____~_-____--___-__----------------------------------------------------------FORHATION PROH THE ELEHENTS

GIBBS
TEIIP.
( H ; - H ; ~ ~)/T
-(G;-H;~~)/T
1468
1500
1600
74.320
7 4 -2 52
74.057
71.13
71.13
71. 1 3
1700
1800
73.885
73.731
71.13
71.13
S;
C;
EITHALP~
FREE ENERGY
LO^
K~
kJ/mol
_______-__-__-----------------------------------------------------------------298.15
0.000
0.00
-------- UNCERTAINTY
0.00
..............................
MELT1 NG POINT
BOILING POINT
ENTHALPY OF UELTING
kJ
-------- -__-------
G 9 8 - HgO
kJ
HOLAR VOLUBE
IELTI NG POI NT

COPPER
..... fl.
IRON..
..... CURIE
P.
E m H ~ ~OF~ UELTING
Y
1357 K.
P. 1 0 4 2 , ALPHA-GAUHA 1 1 8 4 , GABBA-DELTA
n. P. D E L T A 1 8 0 9 K.
SULFUR..
ORTHO-nONO 368. 54, . !I
P. UONO 388.36,
8. P. 7 1 6 . 9 K .
1665.
...
B
IRON
= -1.3274~102 +
1.0113 T
485
1 . 8 9 7 1 ~ 1 0 t~ 0. 1 1 7 0 3 T
2.475
2.385
2.120
-119.587
- 1 1 8 5 0
-67.515
-58.088
1.890
1.686
--------------------------------
BOIL1 NC POINT
kJ
kJ
kJ
UOLAR VOLUUE
....... CURIE P. 1 0 4 2 , ALPHA-GABBA 1 1 8 4 , GAHHA-DELTA

. P. DELTA 1 8 0 9 K .
.... . IORTHC-HONO
368.54.
11. P. HOMO 3 8 8 . 3 6 ,
1665,
SULFUR
P.
7 16.9
K.
540 K )
C;
C;
-69.562
-68.477
-64.950
~ I N~ REFERENCE
~
~
l STATE
~
~ ELEHENTS
~
8.
C:
32.342
-122.037
-121.525
-119.926
+ 2.61351107
540 - 1200 K )
T-2
51.045 +
9.9579~10-3 T
(EQUATIOU VALID PROE
598
1468 K )
-----__-____________------------------------------------------------------------
-----_-_------------------------------------------------------------------------
REFERENCE
2
7-24-76
---_-_____~_______~-------------------------------------------------------------
209
COIPIL~~
8- 4-76
-------_------------------------------------------------------------------------
~ 39 ~
8~ 2
2 20
COHPILED
--
..
..
THEPUODYUAUIC PPOPERTIES OF UIUERALS
PYRITE
PROPERTIES AT HIGH TEIIPERATURES
PORUULA YYIGHl
1 1 9.967
===l========E=======ii=======Gs~=======z=======s=========================s=~=====
PeS,:
C r y s t a l s 298.15
TE~P.
SO+
(H>H;~~)/T
J/mol-K
t o 1000 K.
pesz:
J/.01.
PORIATIOY PRO8 THE ELEUEUTS

GIBBS
EUTKALPY
FREE ENERGY
LO^ K~
cOp
-(G>H:~~)/T
J/mol.K
~ARCASITE
..................................................................................
J/.Ol.
tJ/mol
k J/rnOl
-171.544
1.674
-160.229
1.715
C r y s t a l s 298.15
PORUULA WEIGHT
11 9.967
t o 7 0 0 K.
--- .............................................................................
TE~P.
(H;-H;~~)/T
S!
-(G;-Hig8)/T
C;
PORIATION PROU THE ELEUENTS

GIBBS
ENTHALPY
FREE ENERGY
Log K f
................................................................................
298.15
0.000
UNCERTAINTY
52.93
0.11
52.93
0.13
62.17
28.072
0.300
................................................................................
BELTING POINT
BOILING POINT
ENTHALPY OF MELTING
kJ
8998
H:
9.632
.....
SULFUR..
...
BOLL ING POINT
ENTHALPY OP HELTING
kJ
~ & n- HP)
k.l
IIOLAB voLune
IRON.......
TRANSITIONS I N REFERENCE STATE ELEUEITS

IRON..
TRANSITIOUS I N REPER ENCE STATE ELEMENTS
MOLAR VOLUIIE
kal
UELTING POINT
CURIE P. 1 0 4 2 , ALPHA-GAIIIIA 1 1 8 4 , GMLIA-DELTA

n. P. D E L T A 1809 K .
O R T H O - M O N O 368.54.
n. P. aoNo 388.36.
B. P. 716.9 K .
1665.
SULPUR
.....
CURIE P. 1042. ALPHA-GARIIA 1 1 8 4 , GABIIA-DELTA

n. P. D E L T A 1809 K .
OBTHO-ION0 368.54,
M. P. NONO 388.36,
8 . P. 716.9 K .
' HEAT CAPACITY EQUATION
C:
= -20.319
REFERENCE
t
5.0299~10-2 T
39
39
80
+
1 . 7 8 7 0 r l O ~ T-0'5
298
1 0 0 0 K)
3 . 2 0 0 2 ~ 1 0 6 T-2
8 . 9 2 4 5 ~ 1 0 ' T-1
(EQUATION VALID FROll
298
7 0 0 K)
1665,
-128
P l O P I l T I S S AT HIGH TBIPERATURES
THERfiODIUAIIIC PROPERTIES OP BIYERALS
PORBULA YBIGHT
HYDROGEU SULFIDE (IDEAL GAS)

................................................................................
HpS:
I d e a l g a s 298.15
129
PORIULA WEIGHT
86.998
34.076
c r y s t a l s 298.15
,,n~:
t o 1800 K.
t o m e l t m g p o r n t 1803 K.
.............................................................................
TEBP.
SOT
(8;-HZg8)/T
J/mol-K
P088ATIOU PROM TBE ELEBEuTs

G I BBS
ENTHALPY
P8EE ENERGY
LO^
- ( G ; - H ~ ~ ~ ) / T C:
J/mol- K
J/.0l.K
J/.01.
kJ/mol
k J/.ol
205.80
0.21
205.80
0.21
34.19
-20.627
0.628
-33.543
0.669
( H : - ~ ; ~ ~ ) / T S;
5.877
0.117
J/mol- K
0.000
UNCERTAINTY
78.20
1.67
12.850
20.608
25.922
29.796
8.850
14.346
18.310
21.401
216.01
224.10
231.05
237.21
207.16
209.75
212.74
215.81
35.48
37.21
39.05
40.85
800
900
1000
23.941
26.100
27.989
242.77
247.88
252.62
218.83
221.78
224.63
1100
1200
1300
1400
1500
1600
1700
1800
29.665
31.174
32.545
33.800
34.952
36.014
36.996
37.903
257.04
261.20
265.12
268.83
272.36
275.71
278.91
281.95
227.37
230.03
232.57
235.03
237.41
239.70
241.91
244.05
-24.698
-27.914
-30.626
-32.896
-37.375
-40. 1 1 8
-42.346
-44. 1 0 0
4.881
4.191
3.687
3.291
42.57
44.20
45.72
-89.515
-89.98b
-90.338
-51.108
-46.230
-41.354
3.337
2.68)
47.12
48.40
49.57
50.62
51.54
52.34
53.03
53.59
-90.588
-90.746
-90.826
-90.845
-90.814
-90.739
-90.636
-90.518
-36.441
-31.508
-26.569
-21.625
-16.695
11.740
-6.821
-1.888
1.730
1.372
1.068
0.807
0.581
0.383
...............................
cOp
J/mol. K
kJ/mol
k J/mol
78.20
1.67
49.96
-213.865
0.837
-218.155
1.004
93.02
104.54
114.11
122.29
80.17
83.93
88.19
92.49
51.07
52.12
52.81
53.23
32.745
35.067
129.41
135.74
96.66
100.67
53.53
53.82
36.963
141.42
104.46
54.19
-278.881
-212.797
11.115
38.552
39.927
41.153
146.61
151.40
155.87
108.06
111.47
114.72
54.71
55.42
56.36
-279.081
-279.265
-279.415
-206.189
-199.543
-192.890
9.791
8.686
7.750
42.279
160.09
117.81
57.58
-296.791
-297.079
-297.143
-171.519
-163.692
-155.845
5.600
5.030
4.523
38.220
0.176
................................
...............................
400
500
600
700
-(G~-H;~~)/T
J/mol- K
J/mol.K
..............................................................................
298.15
0.000
UNCERTAI NTY
TsnP.
I*)RU&TIOU PROU THE ELEBEUTS

GIBES
EIITHALPY
PPEEEYEPGY
L O
0.210
0.055
43.350
164.12
120.77
59.08
44.387
45.419
46.464
167.98
171.74
175.41
123.59
126.32
128.95
60.88
63.01
65.48
-216.151
- 2 1 7.836
-219.289
-220.586
-219.320
-219.870
-220.191
-220.219
28.640
22.970
19.169
16.433
-276.509
-225.623
14.732
-276.535
-219.225
12.724
................................
................................
-281.792
-186. 1 6 8
6.946
................................
-284.251
-179.218
6.241
................................
................................................................................
RELTING POINT
................................................................................
lELTI NG POINT
BOIL1 N
G POINT
ENTHALPY OP UELTIUG
kJ
1803
ENTHALPY OP RELTING
26.108
kJ
BOILING POINT
kJ
lOLAR VOLUUE
kJ
2. 1 4 6 0 J / b a r
21.460
'i98
9.962
H:
kJ
UOLAR VOLUlE
2478.9200
24789.200
J/bar
cm3
TRANSITIONS I N REPEREYCE STATE ELEHEUTS

SULFUR
..... ORTHO-lONO
368.54,
P. 716.9 K .
1. P.
cm3
TRANSITIONS I N REFmERCE STATE ELEBEYTS

RANGANESE..
1 0 1 0 388.36,
SULFUR
8.
.....
ALPHA-BETA 980. BETA-GAlBA 1 3 6 0 . GMlA-DELTA

P. DELTA 1 5 1 7 K.
OBTUO-NONO 368.54, .!I
P. IIOYO 388.36,
0 . P. 716.9 K.
14101
U.
HEIT CAPACITY EQUATION

C;
c;
26.356
2.6497110-2
1 . 6 5 9 9 ~ 1 0 5 T-2
(EQUATION VALID FBOB
6 . 0 2 4 4 ~ 1 0 - 6 T*
43.559
0.5
1.35291102
1.1688110*
f 2
(EQUATION VALID PBOl

298
247
262
298
2.0865110-5
T'
1.4352110'
T-O.'
1 8 0 0 K)
................................................................................
1 8 0 0 K)
R~PERIUCE
REFEBEUCE
5.7749110-2
262
39
120
2
49
COBPILED
7-26-76
130
9BERMODXBAMC PBOPBBTIES OF MNERALS
MOLIBDLBITB
==--
PROPERTIES AT HIGH TElPERATURES
POBLICJLA WEIGET
160.060
--E~l=j.====x=f================~==r=====u===r=E==s============-=s==s
131
NLLEBITE
FORlULA WEIGHT
90.760
I===============================I=============s==__=L====_==_=_=_==_====__=r=
NiS:
C r y s t a l s 298.15
t o 6 0 0 .K
_-------------------------------------------_------__--_____------------------
__________I_____-_______________-________---------------------------------
IOBMATIOM PROM TBB ELEMEBTS
TEIP.
(H$H;~~)/T
J/mol.K
S;
-(G;-H;~~)/T
C:
J/Mo~-K
J/mol. K
J/nol. K
298.15
0.000
URCEBTAI NTP
66.11
4.18
66.11
4.18
FUBlATION FBOH THE ELEMENTS

GI885
EWTHALPY
F B E E ENERGY
LO^ K~
46.69
kJ/mol
k J/mol
-84.868
4.184
-86.192
4.393
15. 1 0 1
0.770
------------__--_--------------------------------------------------------------~ E L T I N GP O I N T
BOILING POINT
kJ
kJ
kJ
HOLAR YOLUUE
I---__-_-_I___----_________--_____-_--_-_______-___-_---I_-_-______-_----
MELT110 POIBT
BOILING POINT
EMTEALPI OF MELT116
kJ
ENTBALPI OP VAPOBIDATIOU
kJ
ENTHALPY OF U E L T I N G
MOLAB VOLUME
TRAYSITIOBS I S REPEPLICE STATB ELEMENTS

NICKEL
..... CURIE
P.
6 3 1 , H.
P.
1 7 2 6 K.
BEAT CAPACITI IPCJATIOLI
C;
C;
1.0453~10'
4,8122~10-3 T
( EQUATIOB VALID FROB 2 9 8
RBIEBEBCE
61
6.8169~10'
1200 K )
T
0
'
'
6 . 2 9 0 6 ~ 1 0 ~2-+
--i
165
286
~0l~a-P
03-15-79
38.702 + 2 . 6 7 7 8 ~ 1 0 - 2 T
(EQUATION VALID FROn
298
boo K )
--- ----------_----___----------------------------------------------------------REPEREN C E
I 15
80
274
231
................................................................................
---__-_____________________________________________-_________________-----
COHPILED
7-26-76
132
THERUODI IAIIIC PROPERTIES OF IIIU EilALS
GALENA
.................................................................................
PbS:
C r y s t a l s 298.15
PROPERTIES AT HIGH TBBPtEATURES
PORBULI
WEIGHT
239.260
Sn~:
1153 K.
( H;-H&
TE~P.
SOT
)IT
- ( G ~ - H ; ~ ~ ) / T C;
mRBATION FROB THE ELEBENTS

GIBBS
E ~ H A L P Y
F R E E ENERGY
LO^ K~
J/mol-K
298.15
0.000
UNCERTAI NTY
91.38
1.25
J/m01-K
J/mol-K
91.38
1.25
49.50
kJ/m01
k~/mol
-97.709
0.962
-96.075
0.837
t o 8 7 5 K.
150.750
Beta c r y s t a l s 875 t o melting p o i n t
L i q u i d 1 1 5 3 t o 1 3 0 0 K.
------ --------------------------------------------------------------------------mRBAT1ON FROBGIBBS

THE ELEBENTS
TE~P.
.l/mol-K
PoRnuLA W E I G H T
W~~ZENBERGITE
t o melting p o i n t 1385 K.
133
(H:-H;~~)/T
SOT
-(G;-H;~~)/T
C:
E ~ H A L P Y
FREE ENERGY
l o g K~
16.832
0.147
--__-----------___-------------------------------------------~-----------------UELTI NG POINT
BOILING POINT
ENTHALPY OF UELTING
1385
kJ
kJ
4 9 8 -
kJ
nOLAR VOLUME
lELTI NG POINT
1153
EWHALPY OF IELTING
31. 5 8 9 k J
BOILING POINT
kJ
kJ
H:
NOLAB VOLUME
TRANSITIONS I N REPERENCE STATE ELEHENTS

LEAD
....... 8 .
TRANS1 T I O N S I N REPERENCE STATE ELEUENTS

P.
600.6.
8.
P.
2 0 2 1 K.
........
SULFUR .... .
TIN
C:
298 900 K )
-------------------------------------------------------------------------------115
120
P.
505 K
n.
ORTHO-NONO 3 6 8 . 5 4 ,
8. P. 7 1 6 . 9 K.
P.
UONO 3 8 8 . 36,
44.601 +
1.6401110-2 T
( EQUATION VALID PRO8
REPE RE NCE
8.
245
COBPILED
1 44
7-24-76
___-------------_---------------------------------------------------------------
C:
C:
= -1.55931102
+ 0.12193 T
( EQUATION VALID FROB
298
26.722 +
3.0352110-2
T
(mUAT1ON VALID FROn
875
REFERENCE
192
120
3 . 6 0 4 1 ~ 1 0 3 T-0.5
8 7 5 K)
3.5476110*
T-2
1 1 5 3 K)
2 20
COBPILED
7-24-76
---________________-------------------------------------------------------------
~~OPEETIX
OPS RIMEBUS
-----srrraxr
STANNIC SULFIDE
97.440
POBnULA WEIGHT
.........................................................
C r y s t a l s 298.15
SnS,:
135
P l O P E I T I B S A T HIGH TEIIPERATURES
......................................................................
t o 1 0 0 0 K.
298.15
cublc
ZnS:
t o 1 2 0 0 K.
u u r t z l t e 1s t h e s t a b l e P h a s e
Of
ZnS
a b o v e 1 2 9 3 K.
..............................................................................
FOBMATION
TEuP.
- ( 6 - ~ ; 9 ~ ) / ~ C;
J/mol.K
J/nol-K
J/mol.~
ENTHALPY
J/mol.~
.............................................................................
FREE E N E R ~ Log
0.18
TEIIP.
( ~ i - ~ i ~ ~5; ) / -~ ( G ; - H ~ ~ ~ ) / T C;
J/.o~-K
l
kJ/.01
..............................................................................
298.15
0.000
87..45
87.45
70. 12
--UNCERTAINTY
P O B n A T I O N F R O 8 T H E ELEMENTS
PBOH T H E E L E M E ~ s
GIUbS
~ / m o l -K
J/mol - K
J/mol-K
298.15
0.000
58.66
0.13
58.66
0.13
45.76
12.000
19.432
24.618
72.49
83.46
92.67
60.49
64.03
68.05
48.30
49.93
51.11
28.471
100.62
72.15
52.04
31.466
33.867
35.853
107.62
113.87
119.53
76.15
80.00
83.68
52.79
53.42
51.96
37.521
124.70
87. 18
54.43
38.948
40.186
129.45
133.86
90.50
93.67
54.85
55.23
IJUCERT AIYTY
..............................
18-125
29.058
108.36
124.59
90.23
95.53
72.05
73. 5 3
600
700
36.603
42-253
138. 14
1U9.87
101. 54
107.62
75-19
77. 1 4
800
900
1000
46-747
50.500
53-752
160.31
169.79
178.54
113.56
119.29
124.79
79.33
81-74
84.33
EWHALPY
G98
OF MELTING
---
-----
---
........
- -..
8.
P.
-220.819
-192.592
14.371
................................
-276.553
-276.217
-275.827
-194.035
-183.699
-17 3 . 4 3 3
12.669
10.662
9.059
-275.399
-163.226
7.151
-390.047
-388.48Y
-150.953
-13110
6.571
5.268
................................
kJ
ENTHALPY O F V A P O B I Z A T I O N
ENTHALPY OF B E L T 1 NG
kJ
EYTHALPY OF V A P O R I Z A T I O N
kJ
M O L A R VOLURE
kJ
MOLAR VOLUNE
TRANSITIOUS
P.
MONO 388. 36.
K
kJ
2. 3 8 3 0 J / b a r
23.830
cm3
I N R E F E R E N C E S T A T E ELEMENT5
....... n. P. 6 9 2 . 7 , 8. P.
SULFUR ..... ORTHO-nOUO 368.54,
1 1 7 8 K.
ZINC
fl.
16.203
20.709
-212.397
-195.581
17.027
................................
WILING POINT
8.
P.
716.9
U.
P.
nONO
388.369
K.
HEAT C A P A C I T Y E Q U k T I O N
3-8228x10-2
+
d.544lxlO2
2 9 8 - 1000 K )
T-0-5
g . 6 0 1 7 ~ l ~ .~ - 2
................................................................................
192
-200.655
-198.231
-209.378
-211.067
ORTHO-NONO 368.54,
8. P . 716.9 K.
35.477
0.312
___________________-------------------------------------------------------------
5 0 5 K.
(EQUATION VALID P R o n
REFERENCE
-202.496
1.780
RELTING POINT
2.0u2
-206.900
1.700
Cp =
kJ/nol
T R A N b I T I O N S I N REFERENCE S T A T E ELERENTS
TIN
Log K f
................................
-------
................................................................................
B E L T 1 NG P O I NT
kJ/mol
____________-______--------------------------------------------------------
0. 1 8
400
500
GIUBS
PBEEENEBGY
ENTHALPY
120
C:
61.506
t
7.6314~10-4 T
2.6035~10~~-0.5
1 9 8 - 1300 K )
7 . 9 6 3 1 ~ 1 0 ~T - ~
-_-________________----a--------------------------------------------------------
COMPILED
REFERENCE
,208
120
CULlDILED
7-24-76
-___-_-_-__________-------------------------------------------------------------
--
136
THERIODIIAIXC PBOPEBTIES OP IIIEBALS
UURTZITE
PBOPERTIKS AT H I G H TEIPEBATOBES
POBBO LA
_______________
-----------------------------------------------------------------------------------*---------------=========-====-*=--*
C r y s t a l s 298.15
ZnS:
Y EIGHT
137
FOBBULA WEIGHT
97. 440
t o 1300 K.
L1zO1:
( corundum ). c r y s t a l s 298.15
101-962
t o m e l t ~ n g point 2345 K -
___________________----------------------------------------------------------s;
(';-~;g8)/~
J/molSK
J/mol.K
298.15
0-000
UNCERTAINTY
C
:
-(($-H;~~)/T
J/mol-K
P08flATION FROB THE E L E I E ~ s

GIBES
ENTHALPP
F R E E E N E R G Yl o g ( (
J/mol-K
kJ/mol
-194.570
1.500
58.84
0.12
58.84
0.12
45.88
72.78
83.81
93-04
60.68
64.24
68.30
48.71
50. 13
51.08
500
600
12-100
19.570
24-745
700
28.563
100.97
72.41
51.85
800
900
1000
31.519
33-889
35-855
107.94
1111.17
119.81
76.42
80. 28
83.95
52.54
53.20
53.85
1100
37.520
124.97
87.45
54.50
1200
1300
38.962
40.232
129.74
13'4.18
90.78
93.95
55.14
55.79
2g8.15
-197.008
-198.668
-199.991
-208. 425
-264-181
-263.869
-263.495
-181.919
-171.619
161.381
-----------__----__---------
-138.955
-119.127
11.878
g.gbl
BOIL1 UG POINT
ENTHALPY OF HELTING
kJ
~ O L A BV O L U H E
498
8;
R.
P.
692.7,
SULFUR.---.
ORTHO-UONO 168.54,
8 . P. 716.9 K.
8.
41.Y06
7.6193xlO-'T
( @UATION VALID FBON
79.01
-1675.700
1.300
-1582.228
1.320
277.201
0.231
boo
500
22.575
38.372
76.85
99.47
54.27
61-10
96.39
105.95
-1676.304
-1675.984
-1550.162
-1518.654
202.431
158.653
600
700
50.187
59.377
119.38
137.02
69.19
77.64
112.19
116.65
-1675.264
-1674.404
-1487.257
-1455.990
129.478
108.648
800
900
66.756
72.833
152.83
167.13
86.07
94. 30
120.04
122.73
-1673.565
-1672.865
-1424.841
-1393.793
93.033
80.894
looo
77.935
180.18
102.25
124.94
-1693.698
-1361.288
71.107
192.17
109.88
126.79
-1692.719
-1328.080
63.066
1800
6.070
9.378
2.307
94.924
97.277
99.409
101.352
203.28
213.61
223.27
232.34
240.90
249.00
256.68
117.21
124.23
130.96
137.42
143.62
149.59
155.33
128.38
129.77
130.99
132.08
133.07
133.96
134.78
-1691.635
-1690.457
-1689.203
-1687.872
-1686.481
-1685.029
-1683.527
-1294.993
-1261.964
-1229.065
-1196.232
-1163.513
-1130.906
-1098.329
56.370
50.707
45.857
~1.657
37.985
34.749
31.873
4.78,
BELTING POINT
2345
10.016
BOIL1 NG POINT
kJ
ERTH ALPY OP VAPORIZATION
k~
~OLAR
VOLUBE
2.5575
25.575
J/baC
cm3
TB&ISITIONSI N REFERENCE STATE ELEEENTS
1178 K.
P.
................................
___________________-----------------------------------------------------------EllTBALPY OP BELTING
ALUUINOH...
I. P.
9 3 3 K.
P. HUN0 388.36,
8.
C:
50.92
0.10
6.04)
TRANSITIONS IN REFERENCE STATE ELEUENTS

ZINC.......
PORIATION PBOB THE ELEMENTS

GIBES
FREE ENEBG1
LogKf
ElFTHALPY
50.92
0.10
2.294
-------------------------------------------------------------------------------NELTING POINT
C;
0.000
-263.070
-151. 194
7.180
................................
-377.701
-376.095
-(G:-~;~~)/T
S;
J/.O~.K
J/DOI- K
~/.ol- K
J/L0ls K
kJ/mol
kJ / O O ~
___________________---------------------------------------------------------
------------_--____------U 00
(H;-Hq98)/~
HEIT CAPACITY EQ UATIOU
+
298
1.57671102
1300 K )
T-o-s
6.603qX105
T-2
C:
1.5736xlOt + 7.1899~10-* T
(EQUATION VALID PBOB 298
9 . 8 8 0 4 ~ 1 0 2 T-0.'
1800 K)
1.8969~10' T - ~
--------------------------------------------------------------------------------
-----______________-------------------------------------------------------------
REFERENCE
REFERENCE 285
50
208
--------------------
248
2 15
2
50
66
35
159
COMPILED
7-21-76
----_______________-------------------------------------------------------------
ALUNINUI OXIDE ( G A I I A )
FORIULA
WEIGHT
.................................
_
_ ~ _ - _ _ - - - - - _ _ - - - - - - - - - _-- --- --- _- - _
- --- - - - -_ --_ - - -=- --- - - - - - - - - - =
- =-----------
101.962
-----------
A1,0,:
C r y s t a l s 298. 15 t o
(H:-H~~~)/T
J/mol-K
SOT
-(G;-H;~~)/T
cOp
............................
ENTHALPY OF IELTING
94. 140 kJ
4 9 8 - H:
kJ
...
fl.
P.
kJ
noLAR voLunE
J/ba r
32
kJ/mol
48.45
0.21
65.63
-993.054
2.110
-918.400
2.090
48-45
0.21
BOILING POINT
ENTHALPY OF MELTING
kJ
ENTBALPY OF VAPORIZATIOU
kJ
HOLAR VOLUHE
498
ALUIIAUU...
160.900
0.366
8.828
W
1.9535 J / b a r
19.535
cm3
I.
P.
9 3 3 K.
1.5343xlO2 +
1.9681~10-J T
(EQUATION VALID FROM 2 9 8
REFERENCE
kJ/mol
- 9 . 1 ~ 0 6 3 ~ 1 0T2- 0 . 5
- 1800 K)
.............................................................
=
J/mo1. K
HELTING POINT
933 K.
C;
J/nol-K
_____~_____________------------------------------------------------------------K
BOILING POINT

ALUUINUU
J/mol-K
298.15
0.000
UNCERTAINTY
................................................................................
2291
J/mol.K
................................................................................
59.83
6. 2 8
UELTING POINT
59.989
FORIATION FROB THE ELEIENTS

GIBBS
ENTHALPY
FREE ENERGY
logl ( f
J/nol.~
298.15
0.000
UNCERTAINTY
FOBUULA WEIGHT
1800 K.
...............................................................................
TEUP.
8OEHII TE
................................................................................
32
32
C;
60.396 +
1.7573.10-2
T
298
500 K )
................................................................................
REFERENCE
115
120
94
2 16
COIPILED
7-14-77
- -P R O P I P T I E AT HIGH TEMPERATOBES
FOBWLA WEIGHT
GIBBSITE
------------------------------------------..............................................................................
Al(OH),:
C r y s t a l s 298.15
t o 480 K.
( H ; - H ~ ~ ~ ) / TS;
G l b b s l t e d e c o m p o s e s a b o v e 4 8 0 K.
J/mol.K
~ ~ 0 , : C r y s t a l s 298.15
26.467
J/mol- K
C;
FOBMATION PROM THE ELEMENTS

GIBBS
ENTHALPY
FREE ENERGY
log
J/mol-K
kJ/mol
68.44
0. 14
68.44
0.14
91.70
-1293.128
1.192
-115
98.83
72.36
115.10
-1294.070
-1106.856
J/B0lsK
298.15
0.000
UWCERTAI NTY
400
-(G;-H&~)/T
FORMULA WEIGHT
78.00
-----------------------------------------------------------------------------TEUP.
141
kJ/mol
t o m e l t i n g p o r n t 7 2 3 K.
69.618
L l q u d 7 2 3 t o 1 8 0 0 K.
................................................................................
TEnP.
(H;-H;~~)/T
J/mol.K
cOp
-(G;-H;~~)/T
S;
J/molaK
J/nol- K
FORMATION FROM THE ELEHENTS

GIBBS
EUTHALPY
FREE ENERGY
LO^ K~
J/nol- K
kJ/mol
k J/mol
298.15
0.000
uwERTAINTY
53.97
0.03
53.97
0.03
62.68
-1273.500
1.400
-1194.325
1.715
209.242
0.301,
17.475
30.358
40.960
50.006
51.877
74.06
92.27
109.37
125.43
130.48
57.28
61.91
68.41
75.42
78.61
75.28
88.20
99.43
108.88
110.83
-1273.766
-1273.595
-1272.874
-1271.622
-1271.081
-1167.236
-1140.605
-1114.069
-1087.697
-1082.695
152.426
119.159
96.989
81.165
78.240
82.317
87.200
92.294
96.257
160.92
173.00
188.69
202.59
78.61
85.80
96.40
106.33
127.61
127.61
127.61
127.61
-1249.073
-1246.430
-1242.998
-1239.930
-1082.695
-1064.070
-1041.492
-1019.266
78.240
69.477
60.447
53.242
99.381
101.870
103.905
105.616
107.093
108.386
109.529
110.525
215.05
226.31
236.56
246.06
254.84
263.09
270.83
278.15
115.67
124.44
132.66
140.44
147.75
154.70
161 - 3 0
167.62
127.61
127.61
127.61
127.61
127.61
127.61
127.61
127.61
-1237.209
-1234.815
-1232.681
-1230.752
-1228.986
-1227.369
-1225.899
-1224.623
-997.358
-975.680
-954.143
-932.828
-911.562
-890.459
-869.430
-848.466
47.361
42.470
38.338
34.804
31.743
29.071
26.715
24.625
______________-__-_------------------------------------------------------------IUU.54)
1200
1300
1400
1500
1600
1700
1800
----------------------------------------J---------------------------------------
--------------------------------------------------------------------------------
flELTING POINT
&LING
MELTING POI NT
723
BOIL1 NG POINT
ENTHALPY OF nELTING
kJ
ENTHALPY OF nELTING
22.008
kJ
ENTHALPP OF VAPORIZATION
kJ
kJ
MOLIE VOLUlE
9.301
kJ
MOLAB VOLUME
'?98
11.719
H:
POINT
a.
ALUUINUM...
P.
9 3 3 K.
BORON......
-------------------------------------------------------------------------------REFERENCE
95
95
2.7220
27.220
J/bar
cm3

U.
P.
BETA 2 3 0 0 K.
93
C;
2.78451102
1.0123110-2
T
( E Q U A T I O NV A L I D F a o n 2 9 8
REFERENCE
2 ~ 7
35
262
4.53981103
723 K )
T-0.5
35
4.4598110*
T-1
COMPIL ED
6- 2-76
--------------------------------------------------------------------------------
142
PBOPLB~IBS AT HIGH TEUPBBATUBBS
THERIODYUAUIC PROPERTIES OP UI UEBALS
FORMULA YBIGBT
BARIUI OXIDE
FORUULA YELGHT
153.
BBOUBLLITB
.------------------_----u---------------------------=------------------------.......................................
_ _ _ _ ~ - _ ~ ~ ~ _ _ _ - _ - - - - - - - - - - ==__====-------
BaO:
C r y s t a l s 298.15
.............................................................................
TENP-
(H;-H;:~)/T
J/nolSK
J/mol-K
298.15
0.000
UNCERTAINTY
72.07
0.38
S:
-(G;-H;,,)/T
FURUATIOU FROM THE ELEUENTS

GIBBS
ENTHALPY
FREEENEBGY
C:
J/mol-K
J/mol-K
kJ/mol
kJ/mol
47.28
-548.100
2.090
-520.394
2.100
..............................................................................
72.07
0. 3 8
Crystals 298.15
BeO:
---
25.012
--=====E========E==='5r
t o 1 8 0 0 K.
---
m B I A T I O N FROIGIBBS
THB ELEUEUTS
TE~P.
( ~ ; - f l ; ~ )/T
~
C:
-(4-Bqg8)/~
S;
ENTHALPII
PBEE ENERGY
L o g Kt
--
91.17,
0.368
................................................................................
NE LTl NG
POI NT
2286
BOIL1 U
G POINT
58.600
kJ
kJ
9.983
kJ
NOLAR VOLUIE
2681
UELTING POINT
ENTHALPY OF UELTING
ENTHALPY OF I g l T I N G
4 9 8
H:
~ ? 9 8
TRANSlTlOUS I N REFERENCE STATE ELENENTS
65.610
fl:
2.883
BOILING POIIlT
kJ
MOLAR VOLUIE
kJ
kJ
0.8309 J/bar
8.309 cm3
TRANSITIONS I A REPEBENCE STATE ELEIENTS

BARIU I-....
ALPHA-BETA 5 8 2 .
8. P.
2 1 6 9 K.
BETA-GAUUA
768,
I.
P.
GAHnA 1 0 0 2 .
BERYLLIUN..
ALPHA-BETA
1527,
1(.
P.
1560 R.
HEhT CAPACITY EQULTION

HEAT CAPACITY EQOATIOU
C;
57.218 +
5.3703110-3
T
REFERENCE
33
155
33
1 . 6 6 8 1 r l O z T-0.5
298 - 1000 K )
1.66941105
33
58
................................................................................
T-2
COUPILED
5-1 8-76
REFERENCE
32
3L 1
215
215
COIPILED
6- 8 - 7 6
144
THERNODI NAIIC PROPERTIES OF II N ERALs
BERYLLIUN OXIDE ( BETA )
PORNULA WEIGHT
__________---___---------------------------------------------------------=======
.........................................................................
BeO:
C r y s t a l s 298.15
25.012
PROPERTIES AT HIGH TEflPERATuRES

PORBULA WEIGHT
BISNITE
.................................................................................
465.959
t o 1800 K.
B~,o,:
C r y s t a l s 298.15
t o meitin9 polot
1098 K.
-_-______-_------_-------------------------------------------------------------FORNATION FROB THE ELEBENTS
---_____________---~_----------------------------------------------------------FORMATION PRON THE ELENENTS
J/mol.K
J/mol-K
J/mol-K
16.54
0.03
16.54
0.U3
J/nol- K
kJ/mol
kJ/mol
25.56
-601.785
3. 5 0 0
-573.289
3. 5 0 0
__________________-------------------------------------------------------------298. 1 5
0.000
UNCERTAINTY
100.438
0.613
................................................................................
BELTING POINT
2720
BOIL1 NG POINT
kJ
NOLAR VOLURE
J/bar
BELTING POINT
ENTHALPY OF UELTING
59. 1 2 0 W
1098
ENTHALPY OF UELTING
; -~
11:~
kJ
BOILING POINT
kJ
kJ
kJ
MOLAR VOLURE
TRANSITIONS I N SEFERENCE STATE ELENENTS

BEEYLLIOR..
ALPHA-BETA
1527.
N.
P.
1 5 6 0 K.

c i =
- 2 . 6 8 2 2 ~ 1 0 5 T-2
(EQUATION VALID FRON
298
32
32
8 0 0 K)
1 8 0 0 K)
-------------------------------------------------------------------------------REFERENCE
1.0356~102 +
3.336oxi0-2 T
(EQUATION VALID PRON 2 9 8 -
32
COBPIL ED
7-29-76
--------------------------------------------------------------------------------
REFERENCE
115
L62
262
161
COMPILED
5-26-76
--------------------------------------------------------------------------------
THEBMODYYAMIC P W P E B T I E S O P MIYEPALS
CARBON PlONOXIDE
...................................................................................
28.010
FOBMULA WEIGHT
POBBULA WEIGHT
44.010
............................................................................
CABBOY D I O X I D E
I d e a l gas 298: 1 5 t o 1 8 0 0 K.
CO:
I d e a l g a s 298.15
'0,:
................................................................................
t o 1800 K.
______--__-----------------_------------_-_----__---_-____----___________
FORMATION F R O B T H E ELEMENTS
J/mol-K
J/mol-K
J/mol-K
0.000
197.67
0.03
197.67
0.03
J/mol-K
kJ/mol
kJ/mol
29.14
-110.530
0.170
-137.171
0.170
PORBATION
FROB THE ELEMENTS
................................................................................
298.15
UYCERTAI NTY
24,032
0.030
9.975
16.588
21.505
25.371
28.526
31.167
33.416
400
500
600
700
BOO
900
1000
PlELTING P O I N T
68.05
EUTHALPY O F R E L T I I G
0.837
kJ
ENTHALPY OP VAPORIZATLUN
~:gn
8.673
k.J
81.61
MELTING
6.042
kJ
ENTHALPY O F B E L T I N G
J/bar
cm3
$98
2478.9100
24789.200
noLAH v o L u n E
215.31
218.28
221.75
225.37
228.97
232.48
235.89
225.28
234.87
243.26
250.74
257.50
263.65
269.31
POINT
9.364
TBANSITIOWS
41.23
44.65
47.42
49.66
51.49
53.02
54.30
-393.588
-393.685
-393.823
-393.994
-394.184
-394.388
-394.600
-394.660
-394.920
-395.149
-395.359
-395.544
-395.694
-395.830
51.538
41.257
34.401
29.502
25.826
22.966
20.676
BOILING POINT
kJ
ENTHALPY
kJ
kJ
BOLAR VOLUPlE
OF V A P O R I Z A T I O N
I N REFERENCE S T A T E ELEMENTS
C;
- 9.7115~10-5 T
( E Q U A T I O N V A L I D PRON
45.730
- 4.1469~102 T-0-5
298 - 1 8 0 0 K )
6.6270x105
T-2
................................................................................
REPEBENCE
247
35
35
................................................................................
COBPILED
5-24-76
2~ 4 7 ~
3~5
35
96
--__............................................................................
COUPILED
5-24-76
148
THEBBODYYABXC PBOPEBTIES OF NUEBALS
PPOPEBTIES AT HICE TBNPEBATUBES
!
CALCIUN OXIDE
PORBULA WEIGHT
56.079
...............................................................................
CaO:
C r y s t a l s 298.15
(H:-H;~~)/T
t o 1800K.
S;
J/mol.K
C;
FOBBATION FROB TRE ELEBENTS

G I BBS
ENTHALPY
FREE EUEBGY
Log K~
J/aol.K
J/mol-K
298.15
0.000
UNCERTAINTY
38.21
0.13
38.21
0.13
42.12
-635.089
0.879
-603.487
0-900
105.729
0.158
-634.672
-634.105
-633.569
-633.161
-592.746
-582.330
-572.024
-561.803
77.405
60.836
49.799
41.922
-633.672
-633.570
-633.837
-551.540
-541.275
-531.007
36.012
31.415
27.737,
-634.485
-520.70
-642.458
-641.611
-640.855
-640.001
-639.117
-638.201
-509.696
-'498.671
-487.695
-476.786
-465.941
-455.137
22.187
20.037
18.196
16.603
15.211
13.985
-790.750
-441.040
12.799
C r y s t a l s 298.15
( O H ) :
-(G:-H;~~)/T
e0BMULA WEIGHT
--
74.095
...............................................................................
...............................................................................
TEtlP.
poBTLANDITE
J/mol.K
400
500
600
700
11.375
18.684
23.863
27.743
51.31
61.99
71.06
78.92
39.93
43.31
47.20
51.18
46.65
48.98
50.46
51.53
800
900
1000
30.771
33.211
35.235
85.86
92.07
97.70
55.09
58.86
62.47
52.39
53.10
53.73
110b
36.943
102.85
65.91
54.30
1200
1300
1400
1500
1600
1700
38.412
39.695
40.829
41.845
U2.761
43.596
107.60
112.01
116.12
119.99
123.64
127.09
69.19
7 2 3
75.29
78.15
80.88
83.49
54.84
55.34
55.82
56.28
56.73
57.17
1800
44.362
130.37
86.01
57.60
kJ/aol
kJ/.ol
t o 7 0 0 K.
--___________________----------------------------------------------------FOBHATION PROM THE ELEBENTS

GIBBS
TeNp.
- ( G ~ - H ; ~ ~ ) / TcOp
( H ~ - " ~ ~ ) / T S;
J/mol-K
J/nol-K
J/nol-K
298.15
0.U00
UNCERTAI NTY
83.39
0.42
83.39
0.42
EUTHALPY
FREE ENEBGY
J/801sK
kJ/mol
kJ/m01
87.49
-986.085
1.255
-898.408
1.300
~ o gK~
157.398
0.228
...............................
24.726
__-----_--_----_----------------
--------------------------------
-__________________---------------------------------------------------------MELTING POINT
3200
ENTHALPY OF MELTING
BOILING POINT
IELTING POINT
BOILIBG POINT
79.496
kJ
kJ
ENTHALPY OF BELTING
kJ
EUTHALPY OF VAPORIZATION
kJ
6.749
kJ
HOLAR VOLUNE
kJ
BOLAB VOLUBE
ALPHA-BETA 7 2 0 .
CALCIUM....
H.
P.
BETA 1112,
P.
1 7 5 5 K.
CALCIUN
.... ALPHA-BETA
720.
fl.
P.
BETA 1112.
8.
P.
C:
-------------------------------------------------------------------------------33
3.3056
33.056

B.
REFERENCE
14.159
~ ; 9 8- 8;
TRANSITIONS I N REFEREUCE STATE ELEBENTS
33
33
COHPILED
5-18-76
2.1911~10-2 T
1.8667~102
(EQUATION VALID PROM 2 9 8
- - -
REFERENCE
32
32
86
1 . 5 9 9 8 ~ 1 0 3 T-0.5
700 K )
1755 K.
J/bar
cm3
TREBtlODIYAtlIC PBOPEBTIES OF BIYERALS
CERIANITE
.................................................................................
CeO,:
Crystals 298.15
FORMULA WEIGHT
172.119
p m p g ~ ~ AT
~ g HIGH
s
TEBPEBATVBES
CEEIUB SESQUIOXIDE (HEXAGONAL.
FOBBULA WEIGHT
a)
328.238
.................................................................................
t o 1800 K.
Ce,O,:
C r y s t a l s 298.15
t o 1O00 K .
................................................................................
( H ~ - H & ~)IT
TEBP.
J/mol-K
S;
-(G;-H;~~)/T
J/mol- K
C:
FOEBATION FROB THE ELEUENTS

GIBBS
ENTBALPY
FREE ENERGY
L ~ YK f
J/mol- K
J/mol-K
kJ/mol
kJ/mol
62.30
0.08
62.30
0.08
61.63
-1088.680
( H ~ - H ; ~ ~ ) / T 5;
J/mol.K
- ( G ; - H ~ ~ ~ ) / T C:
J/mol-K
J/mol. K
J/mol- K
ENTHALPY
kJ/mol
FREE ENERGY
Log K f
kJ/mol
................................................................................
-1025.380
1.464
TEMP.
K
................................................................................
298. 1 5
0.000
UNCEBTAI NTY
FORBATION FROU GIBES

THE ELENENTS
179.643
2-929
0.513
298.15
0.000
UNCERTAINTY
150.62
4.18
150.62
Y. 1 8
124.37
-1796.200
8.400
-1707.940
8.400
299.225
1.472
400
500
6U0
700
800
900
31.425
51.400
65.525
76.136
84.475
91.267
186.82
216.09
240.90
262.45
281.52
298.66
155.39
164.69
175.38
186.31
197.05
207.39
128.13
134.00
138.11
141.40
144.25
146.84
-1793.79U
-1791.054
-1788.273
-1785.571
-1783.000
-1780.585
-1678.1'48
-1649.544
-1621.5U6
-1593.932
-1566.732
-1539.826
219.145
172.327
141.165
118.941
102.298
89.370
1000
96.942
314.25
217.31
149.27
-1784.337
-1513.197
79.042
................................
................................................................................
NELTING POINT
BOILING POINT
ENTHALPY OF BELTING
kJ
ENTHALPY OF VAPORLZATION
~ ; 9 8-
10.368 k J
BOLAR VOLUHE
2.3853
23.853

CERIUB----.
BETA-GABHA
999,
N.
P.
MELTING POINT
BOILING POINT
ENTHALPY OF UELTING
kJ
kJ
kJ
J/bar
cm3
H;Y~
80.292 + 5 . 6 9 9 4 ~ 1 0 - 3 T
21.464
1 0 7 1 K.
CERIUM
..... BETA-GAUUA
130
279
4.7750
47.750
J/bar
cm3
999,
U.
P.
1071 K.
BEIT CAPACITY EQUATION
298
2 . 0 9 9 0 ~ 1 0 2 T-0.5
- 1800 K )
7 . 2 9 4 1 ~ 1 0 5 T-2
C;
1.306bx10Z + 2.U315x10-2 T
(EQUATION VALID FRON 2 9 8
................................................................................
REFERENCE
BOLAR VOLUUE
kJ
HSAT CAPACITY EQUATION
C:
235
8
CONPILED
6- 2-76
REFERENCE
101
,,,
8
1 . 7 0 5 3 ~ 1 0 6 TWZ
1 0 0 0 K)
235
105
COBPILED
5-18-76
THERIODIYAIIC PBOPERTIIS OF OLNERALS

CERIUM SESQUIOXIDE (HEXAGONAL, 0 )
FOROULA WEIGHT 3 2 8 . 2 3 8
=========================-======================================================
Ce,O,:
C r y s t a l s 298.15
TEBP-
( H ; - H ; ~ )/T
~
t o 1 5 0 0 K.
J/mol-K
J/mol-K
-(G;-H;~~)/T
J/mol-K
C;
FORIATIOU FROB THE ELEOENTS

GIBES
FREE EUERGY
Log
ENTHALPY
J/mol-K
kJ/mol
UNCEHTAI NTY
33.350
54.036
68.578
79.539
88.227
95.389
aoo
900
38.45
68.94
94.69
117.08
136.98
154.96
- ------
134.21
139.15
---
150.88
154.45
-----
BOILING POINT
ENTHALPY OF BELTING
kJ
kJ
MOLAR VOLUME
H:
c r y s t a l s 298.15
FORIATION FROU THE ELEBEUTS

GIBBS
s;
-(G;-H&~)/T
C;
J/mol-K
J/mol- K
J/mol-K
J/mol- K
kJ/nol
k J/mol
298.15
0.000
UNCERTAINTY
52.97
0.34
52.97
0.34
43.32
-237.940
1.255
-214.194
1.297
37.526
0.227
-236.659
-235.611
-234.659
-205.725
-198.111
-190.700
26.865
20.697
16.602
TEUP.
K
---
143.35
147.21
MELTING POINT
~:98
PORODLA WEIGHT
74-933
COBALTOUS OXIDE
=============_==================================================================
( H;-H;~~)/T
ENTHALPY
FREE ENERGY
LO^
K~
kJ/aol
................................................................................
298.15
0.000
0.00
- -- 131.01
---- 400
500
600
700
PROpERTIES AT HIGH TEIPERATUBES
coo:
s; Sz98
400
500
600
13.525
21.456
26.930
67.18
79.03
88.93
53.65
57.57
62.00
51.86
53.99
54.50
700
8 00
900
1000
30.880
33.865
36.222
38.158
97.34
104.66
111.14
117.00
66.46
70.80
74.92
78.84
54.66
54.89
55.29
55.91
-233.867
-233.667
-233.214
-232.949
-183.439
-176.223
-169.062
-161.959
13.688
11.506
9.812
8.460
11 0 0
1200
1300
39.807
41.259
42.572
122.36
127.34
132.01
82.55
86.08
89.44
56.74
57.75
58.94
-232.896
-233.105
-233.644
-154.862
-147.755
-140.629
7.354
6.432
5.651
1400
1500
1600
1700
43.786
44.936
46.035
47.102
136.43
140.63
144.67
148.56
92.64
95.69
98.63
101.46
60.28
61.75
63.33
65.02
-234.606
-236.075
-238.172
-241.004
-133.456
-126.155
-118.772
-111.235
4.979
4.393
3.878
3.418
1800
48.146
152.32
104.17
66.80
-248.550
-104.429
3.030
................................
-------------------------------................................
_____-_______~_____------------------------------------------------------------K
BOILING POINT
ENTHALPY OF BELTING
kJ
kJ
~ z 9 8-
kJ
BELTING POINT
kJ
J/bar
2078
noLAR v o L u n ~

CERIUI
..... BETA-GAflBA

999,
1. P.
1 0 7 1 K..
COaALT
..... ALPHA-BETA
700.
CURIE P.
1394, M.
P.
BETA 1 7 6 8 K.

- 7 . 1 1 2 3 ~ 1 0 5 T-Z
- 1 5 0 0 K)
__-----------------------------------------------------------------------------C;
1.2532~102 +
3.3341~10-2 T
(EQUATION VALID FROU 2 9 8
REFERENCE
202
COIPILED
REFERENCE
129
120
163
COIPILED
6 - 8-76
--THEBIODYliAtlIC PPOPEBTIBS OF ~ I l t E R A L S
ESKOLAITE
Cr,O,:
PBOPBBTIES AT HIGH TEUPEBATUBES
FOHBULA WEIGHT
151.990
C r y s t a l s 298.15
(H;-H;~~)/T
TEMP.
5;
-(G;-H&~)/T
C;
J/mOlsK
J/molsK
J/molsK
J/mol.K
298.15
0.000
UNCEBTAI NTY
81.17
1.25
81.17
1.25
101.34
FORUATION FROn THE ELEBENT5

GIBB5
ENTHALPY
FREE E N E R G Y
LO^ K f
kJ/mol
kJ/mol
CsOH melts a t 5 8 8 K .
t o 100U K.
o v e r t h e r a n y e 298.15
--------------------------------------------------------------------------------
149.913
...............................................................................
-- - - - -- -CsOH:
B e t a c r y s t a l s 298. 1 5 t o m e l t l n y p o r n t 2 6 0 3 K .
FORBULA YEIGHT
CESIUB HYDROXIDE
The h e a t c a p a c i t i e s
t o 1000 K h a v e been e s t i m a t e d .
___________________------------------------------------------------------------FORUATION FROU THE ELEUENTS

GIBBS
TEMP.
(tl;-Hzg8)/T
J/mol-K
-(G;-H;~~)/T
S;
J/mol-K
J/mol-K
C;
ENTHALPY
FREE ENERGY
J/mol-K
kJ/moi
kJ/mol
67.86
-416.726
0.837
-370.690
0.850
Log K f
___________________-------------------------------------------------------------
-113470
-1053.056
184.492
8.370
M.40U
1.472
400
500
600
700
800
900
1000
28.125
45.686
57.953
67.049
74.U97
79.756
84.408
113.45
139.30
161.05
179.79
196.27
210.99
224.30
85.32
93.61
103.10
112.7U
122.17
131.23
139.89
113.64
117.85
120.57
122.60
124.24
125.67
126.97
-1132.992
-1131.195
-1129.398
-1127.690
-1126.126
-1 124.741
-1123.581
-1025.370
-998.680
-972.345
-946.299
-920.506
-894.863
-869.391
133.900
104.332
84.650
70.614
60.103
51.937
45.413
1100
1200
13U0
1400
1500
1600
1700
1800
88.332
91.700
94..635
97.229
99.549
101.642
103.550
105.302
236.45
247.66
258.05
267.76
276.86
285.45
293.58
301.30
148.12
155.96
163.41
170.53
177.31
183.81
190.03
196.00
128.17
129.32
130.42
131.49
132.54
133.57
134.58
135.59
-1122.661
-1122.011
-1121.647
- 1 121.597
-1121.869
-1122.491
-1123.476
-1124.843
-844.020
-818.729
-793.464
-768.239
-742.968
-717.717
-692.397
-667.012
40.079
35.639
31.882
28.663
25.873
23.431
21.275
19.356
298.15
0.000
UNCERTAINTY
98.74
4.18
98.74
4-18
64.944
0.149
___________-_______------------------------------------------------------------K
UELTING POINT
588
BOILING POINT
kJ
ENTHALPY OF MELTING
H
................................................................................
MELTING POINT
2603
ENTHALPY OF BELTING
'0298
H:
-~
4-561
kJ
HOLAR VOLUUE
kJ
H;~
J/bar
H O I L I W P O L NT
kJ
kJ
kJ
HOLAR VOLUHE
CESIUN.....
M.
P.
3U1.55.
B.
P.
9 4 2 K.
2.9090 J / b a r
~ 9 . 0 9 ~cm3

CHROflIUM...
M.
P.
REFERENCE
2 1 3 0 K.
REFERENCE
33
33
33
158
COUPILED
6- 8-76
32
32
32
COMPILED
10-11-74
-- ,,.,
TH~HODII(AU1C PROPEBTIES OF lIllEBALS
TENORITE
..............................................................................
CUO:
C r y s t a l s 298.15
TEHP.
( H ; - H ~ ~)/T~
FORHULA WEIGHT
79.545
S;
J/molSK
298.15
0.000
UNCERTAINTY
42.63
0.21
Cu,O:
- ( G ; - H ~ )IT
~ ~
J/mol.K
C:
J/mol-K
kJ/nol
kJ/mol
42.30
-157.320
1.255
-129.564
1.297
MELTING POINT
EOILILIC POINT
ENTHILPY OF OELTING
kJ
7.100
kJ
..... n.
P.
143.091
1509 K .
FORHATION FROM THE ELEMENTS

GIBES
ENTHALPY
FREE ENERGY
Loq Kf
K
22.699
0.227
HOLAR VOLUnE
J/mol-K
J/aol.K
298.15
0.000
UNCERTAINTY
93.14
1.67
J/mol-K
J/molsK
93.14
1.67
62.59
................................................................................
K
MELTING POINT
1509
ENTHALPY OP MELTING
BOILING POINT
kJ
kJ
OOLAR VOLUHE
kJ
kJ
1.2220
12.220

COPPER
t o melting point
PORIATION PROH THE ELEHENTS

GIBES
FREE ENERGY
LO^ K~
................................................................................
4 9 8
C r y s t a l s 298.15
ENTHALPY
................................................................................
42.63
0.21
FORHULA WEIGHT
CUPRITE
................................................................................
t o 1 4 0 0 K.
J/molaK
P B O ~ E R T I E SAT HIGH TEOPERATURES
J/bar
cm3
TRAISITIONS I N BEPERENCE STATE ELEHENTS

COPPER.....
1 3 5 7 K.
O.
P.
1357 K .
................................................................................
REFERENCE
164
120
263
164
................................................................................
COHPILED
5-28-76
................................................................................
REFERENCE
164
263
263
164
COMPILED
6-15-76
THEBUODYNAUIC PROPEBTIES OF UINEBALS
DYSPIIOSIUU SESQUIOXIDE (CUBIC)
FOBUULA WEIGHT
............................................................................
Dy,O,:
A l p h a c r y s t a l s 298.15
t o 1590 K.
~ ~ ~ = T IA TE HIGH
S
TEUPERATURES
372.998
B e t a c ~ y s t a l s1 5 9 0 t o l8UO K.
FOHMATIOM FROB THE ELEUENTS

GIBBS
ENTHALPY
FREE ENERGY
J/mol-K
J/mol-K
J/mol-K
J/mol-K
kJ/mol
C r y s t a l s 298.15
EK,O,:
------------__--------------------------------------------------------------_---
kJ/aol
FORIULA WEIGHT
p,RsIUu S E S Q ~ I O X I D E( C U B I C )
382.518
..................................................................................
--t o 1 8 0 0 K.
___________________------------------------------------------------------------FORUATION FROU GIBBS

THE ELEUEUTS
TEfip-
( H ~ - H ; )IT
~ ~
J/mol-K
-(G;-H;~~)/T
5;
J/mol.K
J/mol-K
C;
J/nol.K
ENTHALPY
kJ/mol
FREE ENERGY
LO^ K~
kJ/mol
___________-_______------------------+------------------------------------------
298.15
0.000
UNCEBTAINTY
149.79
0.85
149-79
0.85
111.74
-1863.130
-1771.385
310.341
3.930
4.000
0.7U1
400
500
600
700
800
900
1000
30.275
49.402
62.595
72.219
79.576
85.422
90.240
184.64
212.72
236. l b
256.19
273.69
289.27
303.34
154.36
163.32
173.56
183.97
194.11
203.85
213.10
123.67
127.59
129.36
130.53
131.64
132.87
134.28
-1861.284
-1858.919
-1856.459
-1854.051
-1851.763
-1849.641
-1847.705
-1740.298
-1710.314
-1680.836
-1651.758
-1623.007
-1594.545
-1566.315
2 2 7 . 26 1
178.676
140.330
123.256
105.972
92.545
81.816
1100
1200
1300
1400
1500
1590
94.315
97.851
100.985
103.814
106.412
108.592
316.21
328.10
339.20
349-62
359.47
367.91
221.90
230.25
238.21
245.81
253.06
259.32
135.87
137.65
139.58
141.66
143.88
145.97
-1846.014
-1844.606
-1843.528
-1842.843
-1842.596
-1842.373
-1138.245
-1510.316
-1482.518
-1454.791
-1427.081
-1402.142
7J.045
65.743
59.569
54.279
4Y.696
46.064
1590
lb0U
109.051
109.271
368.37
369.28
259.32
260.01
144.23
144.23
-1841.644
-1842.141
-1402.142
-1399.397
46.064
45.332
198.15
0.000
UNCERTAINTY
155.64
0.85
155.64
0.85
118.09
-1897.860
1.920
-1808.879
2.000
316.909
0.350
400
500
600
700
800
900
l0U0
28.250
46.564
59.158
68.476
75.716
81.544
86.376
190.36
217.09
239.35
258.52
275.39
290.49
304.17
162.11
170.53
180.19
190.04
199.67
208.95
217.79
118.77
120.96
123.28
125.43
127.35
129.04
130.55
-1896.848
-1895.178
-1893.505
-1891.841
-1890.211
-1888.649
-1887.171
-1779.486
-1750.348
-1721.536
-1693.013
-1664.703
-1636.613
-1608.691
232.378
182.858
149.874
126.335
108.694
'94.987
84.030
1100
1200
1300
1400
1500
1600
1700
90.455
93.958
97.012
99.700
102.096
104.244
106.186
315.68
328.21
338.90
348.88
358.24
367.05
375.37
226.23
234.25
241.89
249.18
256.14
262.81
269.18
131.89
133.09
134.18
135.16
136.05
136.87
137.63
180U
107.953
383.25
275.30
138.32
-1885.822
-1580.902
75.071
-1884.627
-1553.253
67.611
-1883.606
-1525.664
61.302
-1882.797
-1498161
55.897
-1882.214
-1470.734
51.216
-1881.888
-1443.320
47.120
-1881.844
-1415.900
43.505
--------------------------------1921.861
-1388.377
40.290
---_----------------------------------------------------------------------------
MELTING POINT
BOILING POINT
IELTING
ENTHALPY OF IELTING
kJ
kJ
POINT
ENTHALPY OF MELTING
4 9 8
21.087
B O I L I N G ~N T~
kJ
kJ
kJ
UOLAR VOLUUE
498
4,
20.000
UOLAR VOLUUE
kJ

DYSPhOSIUH.
ALPHA-BETA 1 6 5 7 ,
n.
P.
1 6 8 2 K.

HEAT CAPACITY EUUATION
C;
C;
38.243 +
3.7210~10-2 T
+
2.0124xlb3 T-0.5
2 9 8 - 1 5 9 0 K)
4 . 8 1 3 1 ~ 1 0 . T-2
1.6353~102 + 6.9435~10-5 T
202
235
1.0957~10T
~-om5
1 8 0 0 K)
1 . 5 9 9 2 ~ 1 0 T-2
~
-________________-_------------------------------------------------------------RPFEBENCE
REFERENCE
235
COUPILED
207
235
235
COUPILED
5-19-76
THERBODYUABIC P R O P E R T I E S OF U I Y E R A L S
EUROPIUU O X I D E
FORUULA Y E I G H T
................................................................................
C r y s t a l s 298.15
EuO:
351.918
S====_==E==z=====_=====15=========4LI========================~=======================
t o 1800 K .
FORMULA Y E I C H T
EUROPIUB SESQUIOXIDE ( BONOCLIYIC )
167.959
eu,O,:
B e t a c r y s t a l s 895 t o 1800 K .
t o 8 9 5 K.
___________________------------------------------------------------------------FORUATION FROB THE E L E U E N T S
GIBBS
( H;-H&~
TEMP.
J/m0lsK
J/~ol-K
J/uol-K
J/mol- K
kJ/mol
kJ/mo1
-592.040
8. 3 7 0
-556.082
8.370
62.76
0.85
62.76
0.85
48.74
J/mol- K
S;
-(G;-H;~~)/T
J/mol-K
C;
J/mol. K
J/mol.K
146.44
8.50
146.44
8.50
115.69
EWTHALPY
kJ/mol
FREE ENERGY
~ o gK~
kJ/.0l
-- ..............................................................................
................................................................................
298.15
0.000
UNCERTAINTY
)IT
97.424
1.466
298.15
0.000
UUCERTAI NTY
-1651.420
8.400
-1555.158
8.400
272.458
1.472
-1648.948
-1522.618
198.834
400
500
31.500
51.810
182.68
212.36
151.18
160.55
129.62
135.88
600
700
800
895
66.132
76.740
84.902
90.967
237.46
259.10
278.06
294.00
171.33
182.36
193.16
203.03
139.28
141.34
142.67
143.93
-1642.967
-1639.982
-1637.210
-1635.043
-1460.732
-1430.612
-1400.878
-1372.924
127.169
1b6.754
91.468
80.128
895
900
1000
91.685
91.956
97.482
294.72
295.49
311.00
203.U3
203.53
213.52
146.33
146.41
147.98
-1634.400
-1634.289
-1632.075
-1372.924
-1371.471
-1342.405
80.128
79.598
70.120
-1645.981
-1491.386
155.805
................................
____________----___-------------------------------------------------------------
2247
MELTING P O I N T
ENTHALPY
O F MELTING
G98 TRANSITIONS I N
BOILING POINT
kJ
ENTHALPY OF V A P O R I Z L T F O N
kJ
MOLAR VOLUnE
kJ
................................................................................
H E L T I NG P O I N T
BOILING POINT
EITHALPY O F MELTING
kJ
kJ
G98
REFERENCE S T A T E E L E n E N T S
B O L A R VOLUUE
kJ
T R A N S I T I O N S I N REFERENCE S T A T E ELEUENTS
EUROPIUM...
HEAT CAPACITY
n.
P.
1090,
0.
P.
1868 K .
EQUATION
HEAT C A P A C I T Y E Q U A T I O N S
C;
47.124 + 6 . 9 0 1 3 x l O - '
T
( E Q U A T I O N VALID F R O 8
3.9277x10* T - 2
2 9 8 - 1 8 0 0 K)
C:
................................................................................
REFERENCE
166
235
235
................................................................................
1.4702~102 - 2 . 7 8 ~ 6 ~ 1 0
T -~2
298
8 9 5 K)
1.3223~102 +
1.5752~10-2 T
( E Q U A T I O N V A L I D FROU
895
1 8 0 0 K)
~ ~ ~ P I L E D
5-19-76
C;
REFERENCE
210
28 1
235
57
COMPILED
5-18-76
TBEBIIODIUAMIC PBOPEBTIES OF IIIUEBALS
IbZ
EUROPIUB SESQUIOXIDE (CUBIC )

......................................................................................
Eu,O,:
C r y s t a l s 298.15
FORHULA WEIGHT
351.918
POBIIULA WEIGHT
UUSTITE
..............................................................................
t o 1300 K .
C r y s t a l s 298.15
Fe.,.,O:
t o m e l t l o g p o i n t 1 6 5 2 K.
68.887
L i q u i d 1 6 5 2 t o 1 8 0 0 K.
----A~---------------------------
TEBP-
s; S298
(H;-H&~)/T
J/mol-K
J/mol-K
298.15
0.000
UNCERTAINTY
0.00
- ( G ~ - H ; ~ ~ ) / T C;
J/nol-K
---
J/sol.K
120.49
kJ/mol
---
kJ/mol
L(
ENTHALPY OF PlELTING
kJ
kJ
NOLAR VOLUBE
Hi
---
---
BOIL1 N
G POINT
J/mol-K
J/mol-K
J/mol-K
298.15
0.000
UNCERTAINTY
57.59
0.42
57.59
0.42
BELTING POINT
kJ
ENTHALPY OF BELTING
B.
P.
1090.
B.
P.
1652
'0298
THANSITlONS I N REFERENCE STATE ELEMENTS

EUROPI OM...
ENTHALPY
J/mol-K
48.12
-_-__--____----_-__-------------------------------------------------------------
BELT1 N
G POINT
~ ; 9 8-
FOQEATION FROB THE ELEREITS

GIBES
FREE ENERGY
Loq K f
FORHATION RON THE ELEMENTS

GIBBS
EUTHALPY
FREEENERGY
Logf
31.338
9.464
BOILING POINT
kJ
EWTHALPY OF VAPORIZATION
kJ
kJ
MOLAR VOLUME
TRANSITIONS I N REFERENCE STATE ELEiYENTS
1 6 6 8 K.
IRON.......
CURIE P. 1 0 4 2 , ALPHA-GAMMA
N. P. DELTA 1 8 0 9 K.
1184.
GAiYBA-DELTA
1665.

C;
1.J665x10z +
1.59J6xlU~T
~ 1 . 8 5 9 5 ~ 1 0 6 T-2
2 9 8 - 1 3 5 0 K)
REFERENCE
210
C;
19.296 +
3.0165~10-2 T +
1 . 5 0 0 9 ~ 1 0 3 T-0-5
298 - 1 6 5 2 K )
COPlPILEO
EEPERENCE
44
120
247
2.53338106
T-2
COMPILED
6-11-16
-THKRMODYIAMIC PPOPEBTIKS O? MIIERALS

PERPOUS OXIDE (STOICHIOMETRIC)
..............................................................................
FeO:
C r y s t a l s 298.15
t o 1 6 5 2 K.
P O O P ~ R T I X SAT HIGH TEMPSRATOIKS
FORMULA YEIGHT
71.846
Pep02:
L i q u i d 1 6 5 2 t o 1 8 0 0 K.
FORMULA YEIGHT
HEMATITE
159.692
= = = = = - ~ 5 1 = = = = = _ = _ = _ = _ S = _ = = ~ = = _ _ = P = = = = = 5 = = = = = = = = = = = = = =
Beta c r y s t a l s 950 t o m e l t i n g p o i n t
t o 9 5 0 K.
1 8 9 5 K.
TEMP.
(H;-H:~~)/T
J/801sK
S;
-(G;-H;~$)/T
J/mol.K
298.15
0.000
UNCERTAI NTY
J/mol.K
59.80
1.67
C;
FORMATION PROH THE ELEMENTS

GIBES
FREE ENERGY
Log K f
PORMATION FROM THE ELEHENTS

GIBBS
ENTHALPY
J/mol-K
kJ/mol
kJ/mol
49.92
-272.043
2.092
-251. 156
2.176
59.80
1.67
................................................................................
44.002
0.381
( H ~ - H : )/T
~ ~
TEMP.
1652
ENTHALPY OF MELTING
22.185
~ z 9 8
BOILING POINT
kJ
k .I
~ O L A RV O L U H E
CURIE P. 1 0 4 2 . ALPHA-GAHMA
M. P. DELTA 1 8 0 9 K.
298.15
0.000
UNCERTAINTY
87.40
0.21
4 9 8
247
l o g K~
FREE E U E R G Y
87.40
0.2 1
103.85
-824.640
1.255
-742.683
1.297
130.116
0.227
BOILING POINT
kJ
kJ
15.560
MOLAR VOLUME
kJ
3.0274
30.274
J/bar
cm3
TRANSITIONS I N REPEREYCE STATE ELElENTS

1 1 8 4 , GAHMA-DELTA
IRON.......
1665,
CURIE P. 1 0 4 2 , ALPHA-GAHMA
H. P. DELTA 1 8 0 9 K.
1 1 8 4 . GAHMA-DELTA
1665.
................................................................................
247
1895
nELT1 NG POINT
EUTHALPY OF MELTING
REFERENCE
EYTHALPY
kJ

IRON.......
C;
K
J/aol.K
J/aol-K
J/8ol- K
J/mol. K
kJ/80l
kJ/mol
................................................................................
................................................................................
ClELTING POINT
-(G;-H&~)/T
S;
247
COMPILED
5-24-76
C;
2 . 7 8 2 1 ~ 1 0 * T-1
(EQUATION VALID PROH
+ 0.27267 T
(EQUATION VAL10 PROM
= -1.0957x10J
298
950
9 5 0 K)
3 . 3 9 6 0 1 1 0 * T-0.5
- 1800 K )
1 . 0 2 3 9 ~ 1 0 s T-2
................................................................................
REFERENCE
44
78
78
247
84
COMPILED
6-11-76
--166
THERIOD'IYAIIC PROPERTIES OP EIYERILS
IAGNETITE
FOBBULA WEIGHT
...............................................................................
Pe,O.:
t o 8 4 8 K.
P R O P B ~ T X ~AT
S HIGH TEIPEBATOHES
Beta c r y s t a l s 848 t o m e l t i n g p o i n t
~ ~ ~ 0 C. r y
: s t a l s 298.15
5:
(Bi-n;98)/T
298.15
0.000
UNCERTAINTY
146.14
0.42
150.79
-1115.126
2.092
BOIL1 NG POINT
ENTHALPY OF BELTING
138.072
kJ
ENTBALPY OF VAPORIZATION
24.573
kJ
UOLAR VOLUME
... CURIE
n.
P.
0.374
4.4524
44.524
TRANSITIONS I N REFERENCE STATE ELEflENTS

IRON....
177.398
2.134
1870
POBIATION PBOU THE ELEBENTS

GIBBS
FREE ENERGY
ENTHALPY
----
-1012.566
UELTI NG POINT
~ ; 9 8-
t o 1 8 0 0 K.
FOBnATlON FBOU THE ELEBENTS

GI 8 8 s
ENTnlLPr
PBEe EsEnGY
Log ~f
- ( G ~ - H ; ~ ~ ) / T CE
146.14
0.42
187.438
..................................................................................
--
1 8 7 0 K..
TEnP.
PORHULA YEIGHT
231.539
BELTING POINT
BOILING POINT
lkJ
I' J / b a r
ENTHALPY OF HELTING
kJ
ENTIiALPY OF VAPORIZATION
kJ
cm3
';98
kJ
MOLAR VOLUUE
TRANSITIONS I N REFERENCE STATE ELBUENTS

1 0 4 2 . ALPHA-GAUUA
DELTA 1 8 0 9 K.
1.
1184,
GAUUA-DELTA
1665,
HEAT CAPACITY EQIIATIONS
C:
1 . 4 2 7 3 ~ 1 0 5 T-1
(EQUATION VRLID'FROU
96.813 +
5.2733~10-2 T
( EQUATlON VALID FROU
REFERENCE
4U
79
79
C;
298
848 K )
1.657nxlOL 2.4571~10-3 T 1 . 1 5 8 9 ~ 1 0 3 T-0-5

(EQUATIOU VALID PROU
298 - 1 8 0 0 K )
5 . 1 5 6 3 ~ 1 0 5 T-2
COUPILED
6- 2 - 7 6
5 . 6 4 1 3 ~ 1 0 7 T-2
848 - 1800 K )
84
247
................................................................................
COnPILED
6-11-76
PWpERTIES AT HIGH TEIPEBATURES

GADOLINIOH SESQUIOlIDE ( IONOCLINIC )
FORHULA WEIGHT
362.498
PORIULA YEIGHT 3 6 2 . 4 9 8
GADOLINIUH sEsauroxrDE (CUBIC)
========_=_==_===_===============================================================
..............................................................................
Gd,O,:
C r y s t a l s 298.15
TEIP.
(H;-H:~~)/T
t o 1 8 0 0 K.
SOT
-(G;-H&,~)/T
C:
tid,O,:
C r y s t a l s 298.15
FORIATION FROB THE ELEHENTS

GIBES
FREE ENERGY
Log R~
S9
ENTHALPY
28.025
45.644
57.867
66.927
73.977
79.667
84.399
1100
1200
1300
1400
1500
88.421
91.909
94.982
97.729
100.209
1600
1700
1800
102.475
104.562
106.499
................................................................................
HELTING POINT
BOILING POINT
ENTHALPY OF IELTING
kJ
kJ
kJ
IOLAR VOLUHE
4 9 8
H:
J/mol*K
J/mol-K
J/mol-K
298.15
0.000
UNCERTAINTY
0.00
---
C
:
PORIATION FROB THE ELEBENTS

GIBBS
FREE E N E R G Y
~ o g
ENTHALPY
ALPHA-BETA
1 5 3 3 . 1. P.
_____________~~-~__------------------------------------------------------------flELTING POINT
BOILING POINT
ENTHALPY OF MELTING
kJ
kJ
4 9 8

GADOLINIUH.
-( G ; - H & ~ ) / T
___________________-------------------
298.15
0.000
UNCERTAINTY
400
500
600
700
800
900
1000
s~~~
( H;-H:~~)/T
t o 1500 K .
MOLAR VOLUIE
kJ
TRANSITIONS I N REFERENCE STATE ELEIIENTS
1 5 8 5 K.
GADOLINIUH.
ALPHA-BETA
1533.
B.
P.
1 5 8 5 K.
C;
1.1925xlOZ t
1.3585~10-2 T
1 . 4 3 5 1 ~ 1 0 2 T-0.5
1 8 0 0 K)
4-8446x10.
T-2
-------------------------------------------------------------------------------REFERENCE
210
28 1
235
................................................................................
COIPILED
5-18-76
;.
I
REFERENCE
210
COHPILED
5-18-76
170
TBERMODYNAMIC PBOPEETIES OF MINERALS
GERUANIUB DIOXIDE (QUARTZ TYPE)

-------------__--___---------...............................................................................
GeO,:
PROPERTIES
POBIULA WEIGHT
104.589
C r y s t a l s 298. 1 5 t o 1 3 0 0 K
TEUP.
( H;-H;~~
J/mol-K
5;
-( G ; - H ; ~ ~ )IT
J/nol-K
J/mol-K
C;
kJ/mol
kJ/mol
52.09
-551.030
0.800
-497.074
6.900
55-17
0.27
55-27
0.27
BELTING POINT
BOILING POINT
ENTHALPY O F YELTING
kJ
kJ
UOLAB YOLUBE
4 9 8
GERnANIUfl..
8.
P.
1210.4
*EBP.
120
J/aol-K
HELTING POINT
kJ
t o 1800 K.
S;
J/mol-K
-(G;-H&~)/T
J/mol-K
60.50
0.30
C;
GERBANIUB..
8.
P.
1210.4
FHEE E N E P G Y
kJ/mOl
kJ/mol
44.38
-526.350
0.630
-475.180
0.710
LO^ K~
83.250
0.124
BOILING POINT
kJ
EUTBALPY OF VAPORIZATION
kJ
4 9 8 - H
:
kJ
TRANSITIONS I N EEPERENCE STaTE ELEMENTS
K.
ENTHALPY
J/mol-K
64.50
0.30
ENTBALPY OF BELTING
MOLAR VOLUBE
J/bar
K.
NEAT CAPACITY EQUATION
C:
11 9
( H;-B&~)/T
298.15
0.000
UNCERTAINTY
HEAT LAPACITY L,LJATION
REYERENCE
104.589
FOBBATION PROM THE ELEMENTS

GIBBS
87.086
0.158
2.4440 J/bar
2 4 . 4 4 ~ cm3
G l a s s 298.15
................................................................................
298.15
0.000
UNCERTAINTY
FORBULA YEIGHT
..................................
...............................................................................
___________________-------------------------------------------------------------
FORBATION FROM THE ELEMENTS

GIBBS
ENTUALPY
FREE ENERGY
LO^ K~
J/mol. K
171
GERBANIUB DIOXIDE GLASS
GeO,:
................................................................................
AT H I G H TEMPERATUPES
76.125 +
4.8606~10-3 T
(EQUATION VALID PEON
REFERENCE
lbi
83
COMPILYD
6- 8-76
298
1.08141102 T-0.5
- 1 8 0 0 K)
11 9
--_----------------------------------------------.------------------------------
2.3Y43x101
163
T-2
COBPILED
5-28-76
PROPEBTIES AT H I G H TEHPEBATUBES
THERMODYYAHIC PROPERTIES OF MINERALS
172
FORMULA UEIGHT
HATER
FORMULA WEIGHT
STEAH
18.015
I d e a l g a s 298.15
H,O:
H,O:
L i q u i d 298.15
t o 372.8
K.
I d e a l g a s 372.8
18.015
..................................................................................
t o 1800 K.
t o 1 8 0 0 K.
________-------------------------------------------------------------------2----
(H;-H;~~)/T
TEUP.
-(G;-H;~~)/T
S;
C;
FOBHATION PROH THE ELEHENTS

GIBBS
ENTHALPP
FREE ENERGY
LO^ K~
J / ~ o ~ . K ~ / m o l - ~ ~ / m o l - ~ J/mol-K
298.15
0.000
UNCERTAINTY
69.95
0.08
69.95
0.08
75.19
k~/mol
-285.830
0.042
(H;-H;~)
~/T
TEHP.
S;
-( G T - H ~ ~ ~ ) / TC;
FOBHATION FROH THE ELEHENTS

G I BBS
FREE ENERGY
Log K f
ENTBALPY
K
J/mol-K
J/mol-K
J/mol- K
J/mol- K
kJ/mol
kJ/mol
................................................................................
kJ/mol
-237.141
0.084
298.15
0.000
UNCERTAINTY
41.546
0.015
188.83
0.04
188.83
0.04
33.58
-241.814
0.042
-228.569
0.084
40.044
0.015
................................................................................
flELTING POINT
ENTHALPY OF HELTING
G98 -
273. 1 5 K
BOILING POINT
372.8
40.866
6.008
kJ
13.293
kJ
HOLAB VOLUHE
kJ
HELTING POINT
BOILING POINT
EBTHALPY OF HELTING
kJ
kJ
2 . 2 3 1 6 1 1 0 5 T-2
372.8
HEAT C A P A C I T YEQUATION
1 8 0 0 K)
................................................................................
BEPEBENCE
247
196
35
35
~ ~ ~ P I L E D
8-03-76
~2 4 ~
7
196
~ 35
35
196
COHPILED
8-17-76
-----____---____----------------------------------------------------------------
.~
TnERMODYllAllIC P B O P E R T I E S OF MINERALS
174
HAPNIA
HfO,:
FORBULA HEIGHT
C r y s t a l s 298.15
J/mol-K
210.489
-(G;-H~~~)/T
J/mol-K
J/mol-K
C;
FOBilATION FROB THE ELEnENTS

GABBS
EQTHALPY
TREE E N E R G Y
logK,
J/moA-K
kJ/mol
kJ/mol
298.15
0.000
UNCERTAINTY
59.33
0.42
59.33
0.42
60.25
-11U4.740
1.255
-1088.276
1.297
BOILIYG POINT
ENTHALPY OF BELTING
kJ
~ q 9 8- H:
kJ
NOLA8 VOLUBE
HELTlNG POINT
3173
190.662
0.227
HAPNIUB....
ALPHA-BETA
188
t o 1 0 0 0 K-
___________________-----------_------------------------------------------------FOBNATION FROB THE hLEnENTS

GIBBS
TE~P.
S;
(H;-H;~~)/T
-(G;-H;~~)/T
C;
J/mol- K
J/mol-K
J/mol-K
J/mol-K
298.15
0.000
UNCERTAINTY
70.27
0.34
70.27
0.34
ENTHALPY
44.06
PEEE ENERGY
kJ/mol
kJ/mol
-90.789
0.050
-58.528
0.060
L o g Kf
10.254
0.011
BELTING POINT
BOILING POINT
ENTHALPY OF BELTING
kJ
kJ
BOLAR VOLUnE
9.1 1 3 k J
NERCURY....
8.
P.
6 2 9 K.
95.584 + 2.0947~10-' T
BEFERENCE
216.589
T R A N S I T I O N S I N YEPERENCE STATE ELEBENTS
2 0 1 3 K.
C;
C r y s t a l s 298.15
H ~ O :
';98
TRANSITIONS I N EEPEREYCE STATE ELEMENTS
POBNULA YEIGHT
BONTROYDITE
_____--_____---_-_--------------------------------------------L-----------------
175
___________________-------------------------------------------=========
_______________-___----------------------------------------------------
t o 1 8 0 0 K.
SOT
( H ; - H ; ~ ~)/T
TEnP-
P B O P B R T I E S AT HIGH TEMPERATURES
120
298
5.3496~10~T-0.5
U . 4 2 4 6 ~ 1 0 5 T-2
ci
1 8 0 0 K)
264
CO~PILED
5-26-76
73.566 +
3.0J51x10-3 T
REPEBENcE
247
247
298
5 . 2 5 1 0 ~ 1 0 2 T-0.5
- 1000 K )
258
247
COMPILED
6- 3 - 7 6
---_--_____________-------------------------------------------------_-----------
176
THERIODIPAIIC PPOPEBTIES OP IIBEBALS
HOLlIUl SESQUIOXIOE (CUBIC)
PBOPBPTIllS AT HIGH TEIPEBATUPES
PORBULA WEIGHT
377.859
...................................................................................
Ho,O,:
C r y s t a l s 298.15
C r y s t a l s 298.15
KrO:
t o 1 8 0 0 K.
PORIULA UEIGHT
DIPOTASSIUI IOlOXIOE
..................................................................................
t o 1 8 0 0 K.
D e c o m p o s e s a b o v e 1 1 5 4 K.
94.195
Tabulated data
a r e a m e t a s t a b l e e x t r a p o l a t i o n f o r t e m p e r a t u r e s g r e a t e r t h a n 1 1 5 4 K.
POBlATION PBOl THE ELEIIEWTS

TEBP.
( H ~ - H ; ~ ~ ) / TS:
J/mol-K
J/mol-K
298.15
0.000
UNCERTAI NTY
158.16
0.32
-(G;-H&~)/T
J/mol-K
HELTING POINT
ENTHALPY OF BELTING
'0298
C;
21.004
ENTHALPY
J/mol-K
GIBBS
FREE ENERGY
kJ/nol
158.16
0.32
106.86
-1880.700
4.850
BOILING POINT
log K~
kJ/mol
-1791.373
5.000
313.842
0.876
kJ
ENTHALPI OP VAPORIZATIOU
kJ
BOLAR VOLUFiE
kJ
HOLBIUfl....
ALPHA-BETA
1701.
It.
P.
74.141 + 2 . 2 9 6 6 ~ 1 0 - 2 T
(EQUATION VALID F R 0 l
REFERENCE
207
235
kJ
EMTHALPY OP VAPORIZATION
H:
kJ
lOLbR VOLUME
4.0386
40.380
J/bar
cm3
1 7 4 3 K.
HEAT ChPkCITY EQUATION
HEAT CAPACITY EQUATIOU
C;
kJ
ENTHALPY OP RELTING
G98
TRANSITIONS I N BEFERENCE STATE ELEUENTS
BOILING POINT
MELT1 NG POINT
+
1 . 1 7 3 2 ~ 1 0 3 T-0.5
298 - 1 8 0 0 K )
3 . 7 3 9 9 ~ 1 0 . T-2
235
C:
COBPILED
5-19-76
49.265 + 4 . 6 0 5 9 ~ 1 0 - 2 T
(EQUATION VALID PROl
REFERENCE
247
247
+
298
6.1447xlOZ T - 0 - 5
- 1 8 0 0 K)
1.3249~10.
247
T-2
COIIPLLED
5-24-76
178
THERIODIUAIIC PBOPBBTIES OF UIUERALS
PBOPE~TICS AT HIGH TCHPEPATURBS
POTASSIUU SUPEPOXIDE
PORUULA WEIGHT
71.097
=======================--------===E=_=_=============___=======_===============
KO,:
C r y s t a l s 298.15
pOTASSIUU BIDBOIIDE
POBUULA WEIGHT
56.105
_S==S=========__===IS===========z========~=========*===s===========z==========
Above 7 8 2 K t h e d a t a
C r y s t a l s 298.15
KOH:
Liquid 679 t o b o i l i n g point
tabulated a r e a metastable extrapolation.
................................................................................
TEHP.
(H;-H;~~)/T
J/sol.K
298.15
0.000
UNCEBTAI NTY
S;
-(G;-H;~~)/T
J/mol-K
J/mol-K
122.50
4.18
122.50
4.18
C;
POPUATION FROM THE ELEHEUTS

GIBBS
EUTHALPY
FREE ENERGY
Loy K~
J/mol-K
kJ/mol
kJ/mol
77.53
-284.512
2.092
-240.586
2.800
BOILING POINT
ENTHALPY OF MELTING
kJ
EUTHALPY OF VAPOEIZATION
kJ
kJ
HOLAR VOLUUE
H:
8.
P.
336.4,
8.
P.
C;
-(G;-H;~~)/T
S;
ENTHALPY
FREE EUEBGY
log K~
ENTHALPY OF HELTING
BOILING POINT
1596
8.619
kJ
ENTHALPY OF VAPOBIZATIOU
142.700
kJ
12.163
k.J
679
IELTING POINT
Hi98
H:
UOLAR VOLUUE
TRANSITIONS I U REFERENCE STATE ELEHENTS
TRAYSITIONS I N REFERENCE S T I T E ELEUEUTS

POTASSIUU..
GIBBS
T E ~ ~ .( U ; - H & ~ ) / T
42.150
0.491
HELTl NG POINT
4 9 8
--___________________----------------------------------------------------------PORUATIOU PROM THE ELEHENTS
POTASSIUU..
1 0 3 0 K.
M.
P.
336.4.
8.
P.
1 0 3 0 K.

COMPILED
C;
125.95
- 6 . 5 6 2 6 ~ 1 0 - 3 T - 7 6 9 . 2 5 T-0.5
(EQUATION VALID PBOU 2 9 8
1 5 0 0 K)
REFERENCE
32
204
32
14-3
1 . 7 0 3 3 ~ 1 0 s T-2
32
ConpIL~n
b- 8 - 7 6
t:*
180
TBEBMODIYAlUC PPOPEPTIES 01 IINBBALS
LANTHANDII SESQUIOIIOE
FORMULA YEIGB?
p AT ~
HIGH ~TEIIPEBATOIES
~
~
DILITHIUM I I O ~ O I I D E
===I====_=====E====- __====_=====
325.809
181
FORMULA WEIGHT
29- 8 7 9
-------=====5=55=====5===1===_================
=====================I=_=_============/_j==========J1====5==I==C====EE==I==E.===
La,O,:
LiZO:
C r y s t a l s 2 9 8 - 1 5 t o 1 8 0 0 K.
C r y s t a l s 298.15
t o 1 8 0 0 K.
----------------------
1
ENTHALPY
J/mol-K
J/mol-K
298.15
0.000
UNCERTAINTY
127.32
0.84
J/mol.K
127.32
0.84
GIBBS
FREE ENERGY
PORIATION PROI THE ELEMENTS

GIBBS
TEIP.
Log K f
( H ~ - H ; ~ ~ ) / T S;
J/nol-K
J/mol. K
298.15
0.000
UNCERTAINTY
107.95
1700
4 9 8
ENTHALPY OF MELTING
19.841 k J
ALPHA-BETA 5 5 0 .
BETA-GAIMA
1134.
1. P.
LITHIUM....
1193 K.
142
235
EYTHALPY
kJ/mol
kJ/mol
54.09
-598.730
2.092
-561.985
2.134
37.57
0.08
~ o K~
g
FREE ENERGY
J/mol- K
98.458
0.374
BOILING POINT
kJ
kJ
kJ
MOLAR VOLUME
1.4760
14.760
J/bar
cm3
COMPILED
5-18-76
P.
453.691
8.
P.
1.17481102
+ 5.3302xlO-3 T
( EQOATIOU VALID rsoa
298
REFERENCE
235
.!I
1618 K-
C;
REFERENCE
C;
TRAUSITIONS I NREFERENCE STATE ELEMENTS

LANTHANU!!..
11.401
~ ; 9 8-
MOLAR VOLUME
J/mol.
37.57
0.08
MELTING POINT
ENTHALPY OF RELTING
-(G:-H:~~)/T
J/mol- K
247
247
1.15151103
1800 K )
T-0.5
247
1.51801105
T - ~
COMPILED
5-24-76
162
TBEBMODZYAiYIC PBOPERTIES 0 1 MIIBRALS
LITHIUM HYDBOXIDE
....................
LiOH:
PPOPBPTIBS
FORBULA WEIGHT
23.947
...............................................................
------
C r y s t a l s 298.15
K.
L i q u i d 7 4 4 . 3 t o 1 0 0 0 K.
( ~ g - 0 )/T
; ~ ~ S;
J/mol.K
c:
-( G ; - H ; ~ ~ ) / T
J/mol-K
J/mol-K
42.80
0.21
42.80
kJ/mol
kJ/mol
49.59
-484.926
0.159
-438.941
U-159
...............................................................................
298.15
0.000
UlCEBTAI NTY
0.21
76.901
0.028
................................................................................
MELTING POINT
744.30
BOILING POINT
ENTHALPY OF BELTING
20.878
kJ
~ ; 9 8 - H:
7.414 k J
BOLAR VOLUBE
LITHIUM-..,
I.
P. 4 5 3 . 6 9 9
8.
P.
51.051 + 3 . 3 2 7 1 ~ 1 0 - 2 T
REFERENCE
32
215
t o 1 8 0 0 K.
FORMATION PROM THE ELEMENTS
GIBBS
TEMP.
( H ; - H ~ ~ ~ ) / T S;
J/nol-K
-(G;-H&~)/T
C:
kJ/mol
FREE ENERGY
Log K f
kJ/mol
J/nol-K
J/mol-K
298.15
0.000
UtiCERTAINTY
109.96
0.85
109.96
0.85
96.39
-1878.200
7.530
-1788.849
6.280
313.400
1.100
400
500
600
700
800
900
1000
26.725
43.996
56.398
65.759
73.090
79.000
83.879
140.34
165.54
187.12
205.91
222.51
237.39
250.85
113.61
121.54
130.72
140.15
149.42
158.39
166.97
109.39
116.15
120.38
123.29
125.93
127.09
128.41
-1877.510
-1876.178
-1874.499
-1872.679
-1870.842
-1869.073
-1867.428
-1758.252
-1728.583
-1699.212
-1670.148
-1641.334
-1612.753
-1589.348
229.605
180.585
147.930
124.629
107.169
93.602
82.758
1100
1200
1300
1400
1500
1600
1700
1800
87.978
91.478
94.505
97.150
99.487
101.567
103.431
105.113
263.14
174.45
284.92
294.67
303.79
312.36
320.44
328.08
175.16
182.97
190.41
197.52
204.30
210.79
217.01
222.97
129.50
130.42
131.20
131.88
132.48
133.02
133.49
133.92
-1865.966
-1869.731
-1863.761
-1863.097
-1862.769
-1862.816
-1863.270
-1864.162
J/mol. K
EUTHALPY
- 1556.118
73.894
66.513
60.271
54.923
50.288
46.234
42.657
39.476
-1528.005
-1499.995
-1472.035
-1U44.104
-1416.200
-1388.299
-1360.324
BELTING POINT
BOILING POINT
kJ
ENTHALPY OF BELTING
kJ
J/bar
cn3
4 9 8
17.539 k J
kJ
4.222U
42.220
BOLAR VOLUBE
J/bar
cm3
TRANSITIONS I N REFERENCE STATE ELEBEUTS
1 6 1 8 K.
LUTETIUH...
C:
C r y s t a l s 298.15
................................................................................
1.6440
16.440
TRANSITIONS X K REFERENCE STATE ELEMENTS
397.938
...........................................................
--
FORBATION FROB THE ELEMENTS

GIBBS
ENTHALPY
FREE ENERGY ~ o K~
g
J/aol-K
ORM MU LA YEIGBT
LUTETIUB SESQVIOILDE (CUBIC )

=s=======5==-====__
LU~O.:
......................................................
TEMP.
AT UIGU TEMPERATURES
n.
P.
1936 K.
298
1 . 0 1 1 6 ~ 1 0 * T-2
- 744.30 K )
C;
1 . 4 7 0 5 ~ 1 0 2 - 5 . 3 3 9 3 ~ 1 0 2 T-0.5
- 1 . 7 5 4 8 ~ 1 0 6 T-?
(EQUATION VALID FROB 2 9 8 - 1 8 0 0 K)
-_-_______________~------------------------------------------------------------215
COMPILED
5-19-76
REFERENCE
202
281
235
COBPILED
6 - 8-76
P I O P E ~ T I E S AT HIGH TEIPEBATUPES
PEBICLASE
..............................................................................
lgo:
C r y s t a l s 298.15
POBIULA WEIGHT
40.304
PORlULA WEIGHT
BRUCITE
~ g ( 0 H ) ~ : C r y s t a l s 298.15
t o 1 8 0 0 K.
( H;-H;~~)/T
-------
3;
-(G;-B;~~)/T
C;
PORIATION PROl THE ELElENTS

GIBBS
ENTHALPY
FREE ENERGY
1.09
PORHATION FROl THE ELElENTS

GIBBS
K~
TEMP.
J/Dol.K
-- --- -----
( H;-H;~~)/T
J/.ol-~
298.15
0.000
UICERTAI NTI
3125
ENTHALPY OP IELTIUG
4 9 8
HI;
5.166
BOILING POINT
kJ
EYTHALPY OF VAPORIZATION
kJ
BOLAR VOLUME
J/mol. K
ENTBALPY
J/mol. K
kJ/mol
FREE ENERGY
l o g K~
k J/mol
63.18
0.13
63.18
0.13
77.28
-924.540
0.440
-833.506
0.440
146.027
0.077
21.775
36.612
47.477
55.810
62.442
67.889
88.21
109.59
128.14
144.94
158.98
172.10
66.43
72.98
80.66
88.63
96.54
104.21
91.91
99.30
104.01
107.45
110.22
112.59
-924.416
-923.482
-922.180
-920.691
-919.108
-917.475
-802.310
-771.901
-741.712
-711.766
-682.042
-652.494
104.771
80.640
64.572
53.113
44.533
37.870
BOILING POINT
kJ
ENTHALPY OF lELTING
kJ
kJ
4 9 8
1
11.401
IOLAR VOLUME
kJ
C;
215
J/mol-K
C:
MELTING POINT
261
204
-(G;-H;~~)/T
TRANSITIONS I N REFERENCE STATE ELEIEITS
BEPEBENCE
s;
298.15
0.000
UNCERTAINTY
400
500
600
700
800
900
HELTING POINT
A t a p p r o x i a a t e l y 540 K t h e p a r t i a l
t o 9 0 0 K.
pressure of steam I n equilibrium with b r u c i t e reaches one atmosphere.
----_----------_---------------------------------------------------------------TEap-
58.320
.....................................................................
215
247
COIPILED
7- 1 5 - 7 6
1.0222110~ +
1.5107110-2
(EQLIATION VALID PRO8
REPERENCE
131
214
T
298
2.6172110.
900 K )
T-2
214
102
COMPILED
5-26-76
THEBIODYNAHIC PPOPEBTIES OP IIYERALS
186
UAUGANOSITE
.------------------..............................................................................
Mno:
C r y s t a l s 298.15
TEnP-
( 8 ; ' ~ ; ~ )/T
~
J/molSK
t o meltlng point
5;
FORUULA WEIGHT
70.937
C:
J/nol-K
J/mol.K
59.71
44-10
59.71
0.42
86.937
----fino,:
FORHATION FROM THE ELEHEYTS

GIBES
FREE E N E R G Y
LO^ K~
EUTHALPY
kJ/mol
kJ/mol
-385.220
-362.896
-_--_--------------------------------------------------------------------------298.15
0.000
UNCERTAINTY
PORUULA WEIGBT
PYROLUSITE
................................................................................
2 6 5 4 K.
-( G ; - ~ ; ~ ~ ) / T
J/Mol.K
PBOPEBTIES AT HIGH TEIPEBATUBES
0.42
0.4bU
63.578
0.502
0.088
C r y s t a l s 298.15
t o 8 0 0 U.
FOBHATION
( H ; - H ~ ~ ~ ) / TS ;
TESP.
J/mol-K
J/mol-K
298.15
0.000
UNCERTAINTY
53.05
0.42
-(G;-H;~*)/T
C;
J/aol.K
PRO^ GIBBS
T H E ELEUENTS
FREE ENERGY
ENTHALPY
J/moL-K
kJ/nol
kJ/mol
53.05
0.42
54.02
-520.030
0.837
-465.138
0.879
~ o yK~
________~____~~____-----------------------------------------------------------81.491
----------_---_----------------------------------------------------------------UELTING POINT
2054
BOILING POINT
ENTHALPY OF UELTING
kJ
~ i 9 8- H:
kJ
HOLAR VOLUBE
1.3221
13.221
UELTING POINT
BOIL1 NG POINT
kJ
ENTHALPY UP HELTING
kJ
kJ
kJ
UOLAR VOLUnE
J/bar
clp3
H;Y~
HE
1.6610
16.610
J/bar
cm3
TRANSITIONS I N REFEBEYCE STATE ELEtlENTS

UANGANESE..
ALPHA-BETA 9 8 0 , BETA-GA~IIA 1360.

n. P. D E L T A 1 5 1 7 K.
GBUUA-DELTA
1410.
UANGANESE..
ALPHA-BETA 9 8 0 , BETA-GAUUA
P. DELTA 1517 K.
1 3 6 0 , GAUMA-DELTA
1410.
n.

C:
59.749 t
3 . 6 0 0 0 ~ 1 0 - ~T
(EQUATION VALID FBOM
298
2.8.265~102 T-0-5
- 1800 d )
1.1362110.
T-2
C;
................................................................................
BEFERENCE
242
120
COUPILEO
6 - 8-76
-----------_-------------------------------------------------------------------263
57.665 +
1.3383~10-2 T
+ 2 . 6 6 8 8 ~ 1 0 2 T-0.5
298 8 0 0 K)
2.0526~10T
~-2
-_-____~___~_______-----------------------------------------------------------REFERENCE
168
120
263
COlPILED
6-14-76
w.3
TREBIODYIAIIC PROPERTIES OF IINEBALS
PROPEBTIES AT HIGH TEIPEBATUBES
BIXBY I T E
.................................................................................
POBIULA WEIGHT
157.874
HAOSIAUUITE
Un,O,:
C r y s t a l s 298.15
-------------------------------------------------------------------------------TEIP-
( H ; - H ~ ~ ~ ) / T S;
-(G~-H&~)/T
POBIATIOU PBOI THE ELEIENTS

ENTHALPY
PBEE
GIBES
ENEBGY
~ o K,
g
C:
J/moleK
J/molSK
J/Sol-K
J/mol.K
kJ/mol
298.15
0.000
UNCERTAI NTY
110.46
2.09
110.46
2.09
107.65
-958.970
....................................................................
-----
kJ/mo1
-881.068
2.092
154.360
2.218
0.389
Inlo,:
BOILING POINT
kJ
IOLAR VOLUIE
3.1370
TRAUSITIONS I N BEFEBENCE STATE ELEIEUTS

IANGANESE..
C u b i c c r y s t a l s 1 4 4 5 t o 1 8 0 0 K.
PORIATION FRO8 THE ELEIENTS

GIBBS
TEnP.
( H ~ - H ~ ~ ~ ) 5;/ T
-(G;-H;~~)/T
C;
ENTHALPY
J/mol. K
PBEE ENERGY
kJ/mol
ALPHA-BETA 9 8 0 . BETA-CAIIA
I. P. DELTA 1 5 1 7 K .
31.370
1 3 6 0 , GAIIA-DELTA
kJ
J/bar
J/mol-K
J/mol- K
kJ / a o l
298.15
0.000
UNCERTAINTY
153.97
4.18
153.97
4-10
139.29
-1387.830
1.674
-1282.774
2.092
224.738
0.367
-1386.542
-1384.870
-1383.639
-1382.903
-1382.51 1
-1382.254
-1247.038
-1212.365
-1177.989
-1143.783
-1109.647
-1075.534
162.847
126.655
102.553
85.351
72.453
62.423
___________________-------------------------------------------------------------
400
500
600
700
800
900
39.175
64.484
81.855
94.527
104.367
112.467
199.01
235.98
266.73
293.02
316.15
337.02
159.83
171.50
184.88
198.49
211.78
224.55
162.60
167.73
169.57
171.69
175.03
179.74
1000
119.486
356.26
236.77
185.73
-1388.612
-1041.351
54.395
-1388.073
-1386.984
-1385.241
-1006.659
-972.000
-937.495
47.802
42.310
37.669
1100
1200
1300
125.825
131.743
137.411
374.29
391.41
407.85
248.47
259.67
270.44
192.86
200.99
209.97
1400
142.936
423.67
280.73
219.70
__________-_____--_-------------
_____________-__--_-------------1389.601
-902.821
33.685
-1394.952
-887.166
32.070
-1374.903
-887.166
32.070
145.172
430.45
285.28
224.30
1445
1500
159.047
160.917
444.33
451.79
285.28
290.87
210.04
210.04
1600
1700
1800
163.986
166.695
169.103
465.34
478.06
490.11
301.36
311.37
321.01
210.04
210.04
210.04
UELTING POINT
BOILIUG POINT
EUTHALPY OF I E L T I l G
kJ
kJ
kJ
IOLAB VOLDIE
cm3
1410,
LOy K f
J/mol-K
-1374.893
-867.888
30.223
_____________-___-_-------------1411.227
-1411.429
-1411.678
-832.111
-795.898
-759.758
ENTHALPY OP IELTIUG
4 9 8
kJ
t o 1 4 4 5 K.
228.812
___________________-------------------------------------------------------------
1445
IELTING POINT
FOBIULA WEIGHT
...................................................................................
----
t o 1 3 0 0 K.
27.166
24.455
L2.048
TBANSITIONS I N BEPEBENCE STATE ELEIENTS

IANGANESE..
ALPHA-BETA 9 8 0 , BETA-GAHIA 1 3 6 0 .
I. P. DELTA 1 5 1 7 K -
CAIIA-DELTA
1410.
C;
6 1 . 9 4 3 + 0.10847 T
3.3789110-s
Tz
(EQUATIOU VALID PROI
2 9 8 - 1 3 0 0 K)
BEPEBEUCE
11 5
19 1
120

+
1.4552110.
T-2
C;
263
197
---------------------------------------------------------------4---------------
COIPILED
6-14-76
= -2.40651102
REPEBEUCE
+ 0.17137 T
241
197
+
298
8.52801103 T - 0 ' s
- 1445 K )
1 . 4 6 7 2 ~ 1 0 1 T-2
263
197
COIPILED
6- 8-76
-- THERBODYUABIC PROPERTIES OF MINERALS
BOLYBDENUM DIOXIDE
FORMULA WEIGHT
C r y s t a l s 298.15
Moo,:
127.939
FOBHULA UEIGHT
~~oLYBDITE
143.938
5===_===s======================__=====_=:==============:====i;=;==
t o 1 8 0 0 K.
C r y s t a l s 298.15
loo,:
t o melting point
107U K .
Liquid
1074 t o 1500 K.
................................................................................
TE4P.
(H;-H;~~)/T
5;
-(G;-H;~~)/T
C;

GIBBS
FREE ENERGY
~ o q
K~
FORHATION PROM THE ELEMENTS

GIBBS
BNTUALPY
TEMPJ/mol-K
J/molSK
J/mol-K
298.15
0.000
UNCERTAINTY
50.02
0.30
50.02
J/mol- K
kJ/mol
kJ/mol
55.90
-587.850
-533.053
( H ~ - H ; ~ ~ ) / TS;
J/mol-K
J/mol-K
J/mol-K
298.15
0.000
UYCERTAINTY
77.74
0.42
77.74
0.42
0.30
2.090
0.440
................................................................................
MELTING POINT
BOILING POINT
ENTHALPY OF HELTING
kJ
kJ
MOLAR VOLUME
';98
H:
lELTING POINT
kJ
ENTHALPY OF HELTlNG
J/bar
4 9 8
cm3
P.
................................................................................
247
140
247
247
159
kJ/~ol
LO^
FREE E N E R G Y
K~
kJ/mol
74.68
-745.170
0.418
-668.055
0.460
COHPILED
5-24-76
U8.911
BOILIUG
kJ
ENTHALPY OF VAPOUIZATLON
kJ
I N REFERENCE STATE ELEtlENTS
2890 K.
REFERENCE
1074
TRANSITIONS
MOLYBDENUM. H.
J/molSK
ENTHALPY
117.041
0.081
__-______________-_-------------------------------------------------------------
1.9580
19.580
C:
--___________________-----------------------------------------------------------
93.389
2.510
-(G;-H;~~)/T
POI NT
MOLAR VOLUME
kJ
3.0560
JU.560
J/bar
cm3
192
THERIIODIYAIIIC P R O P E R T I E S O P I I I N E R A L S
PORIIULA Y E I G B T
46.005
-----_--------_-_------------------=----------_---__-__=
NITROGEN D I O X I D E
...............................
I d e a l g a s 298.15
NO,:
TEMP.
t o 1 8 0 0 K.
H ~ - H )/TZ ~ ~ S;
J/.0l'K
C;
FORMATION PROM T H E ELEMENTS

GIBES
ENTHALPY
FREE ENERGY
LO^ K~
.J/mo1-K
J/molsK
J/mol.K
kJ/.ol
298.15
0.000
UNCERTAINTY
240.06
0.08
240.06
0.08
36.97
33.095
0.418
51.251
0.460
-8.979
0.081
400
500
600
700
800
900
1000
9.825
16.214
20.948
24.661
27.680
30.200
32.334
251.37
260.68
268.81
276.04
282.56
288.48
293.92
241.54
244.47
247.86
251.38
254.88
258.28
261.59
40.23
43.30
45.86
47.94
49.63
51.00
52.12
32.520
32.165
57.551
63.853
-7.515
-6.671
31.969
31.882
31.874
31.923
32.003
70.209
76.591
82.973
89.378
95.743
-6.112
-5.715
-5.418
-5. 187
-5.001
1100
1200
1300
1400
1500
1600
1700
1800
34.175
35.779
37.188
38.436
39.544
40.537
41.429
42.234
298.93
303.57
307.90
311.95
315.75
319.33
322.71
325.90
264.75
267.79
270.71
273.51
276.21
278.79
281.28
283.67
53.03
53.78
54.39
54.88
55.27
55.58
55.82
56.00
32.110
32.230
32.356
32.485
32.605
102.114
108.483
114.828
121.167
127.495
-4.849
-4.722
-4.614
-4.521
-4.440
32.719
32.824
133.815
140.120
-4.369
-4.305
32.916
146.442
-4.250
kJ/mol
..............................................................................
PORIIATION
(H;-HZ~~)/T
S;
261.90
BOILING POINT
294.25
NELTlNG P O I N T
ENTHALPY O P MELTING
14.652
kJ
ENTHALPY O F V A P O B I Z A T I O N
38.116
kJ
ENTHALPY O P MELTING
10.196
H:
kJ
2478.9200
24789.200
MOLAR VOLUHE
J/bar
cm3
91.607 5.4423~10-3 T
REFERENCE
247
247
ENTHALPY
F R E E ENERGY
L o 9 Kf
BOILING POINT
kJ
ENTHALPY OP V A P O R I Z A T I O N
IIOLAB VOLUIIE
kJ
kJ
2.5880
25.880
J/bar
cm3
T R A N S I T I O N S I N REPEREUCE S T A T E ELEIIENTS
1193
4 9 8
SODIUH.....
C;
C;
................................................................................
U E L T I NG P O I N T
-(G;-H~~~)/T
P R O n THE ELEIIENTS
GIBES
--
................................................................................
4 9 8
C r y s t a l s 298.15
TEMP.
61.979
FORMULA N E I G H T
D I S O D I U I I IIONOXIDE
...........................................
Na20:
-(G;-H&~)/T
193
P R O P E R T I E S AT H I G B TEMPERATURES
II.
P.
370.98.
B.
P.
1 1 7 5 K.
298
1.1O8lxlO3
- 1800 K)
T-0.5
9.9225~105 T - 2
247
................................................................................
C;
COMPILED
5-24-76
7.4857~10-3 T
1.1397~102 +
298
( E Q U A T I O N V A L I D PROM
REFERENCE
247
63
247
8 . 1 3 3 5 ~ 1 0 2 T-O"
1000 K )
183
265
COIIPILED
6-
9-76
194
THEBIODYNABIC PPOPIRTIES OF SIYEPALS
SODIUM HYDROXIDE
195
PROPEPTIES AT HIGH TEBPERATUPES
FORMULA WEIGHT
39.997
PORIULA WEIGHT
NIOBIOH IOWOXIDE
...............................................................................
NaOH:
C r y s t a l s 298.15
t o melting point
5 9 6 K.
108.906
L i q u i d 5 9 6 t o 1 8 0 0 K.
Nbo:
C r g s t a l s 298.15
t o 1 8 0 0 K.
___________________------------------------------------------------------------POBSATION
TE~P.
( H ~ - H ; ~ ~ ) / T S;
- ( G ~ - H ; ~ ~ ) / T C:
EYTHALPY
GIBBS
FBEE ENERGY
Log K~
TEHP.
J/aol-K
J/mol-K
J/mol-K
298.15
0.000
UNCERTAINTY
64.43
0.84
64.43
0.84
'K
J/mol-K
kJ/nol
kJ/aol
59.53
-425.800
0.085
-379.651
0.125
( H ~ - H ~ ~ ~ )S;/ T
J/mol-K
BELTING POINT
ENTHALPY OF HELTING
':98
HE
596
BOILING POINT
6.611
kJ
10.489
kJ
SOLAR VOLUnE
66.514
0.022
kJ
1.8780
18.780
J/bar
cm3
J/ool.K
-(G;-H&~)/T
J/aol-K
C;
EYTBALPP
Fiton T H E E L E H E N T S
GIBBS
FREE E N E R G Y
J/nOlsK
kJ/mol
kJ/mol
~ o K~
g
298.15
0.000
UNCERTAINTY
46.02
8.40
46.02
8.40
41.11
-419.660
12.550
-391.945
12.550
68.667
2.199
400
500
600
700
800
900
1000
10.875
17.694
22.500
26.114
28.966
31.300
33.268
58.55
68.58
77.06
84.42
90.96
96.84
102.21
47.67
50.89
54.56
58.31
61.99
65.54
68.94
44.02
45.82
47.20
48.38
49.46
50.48
51.46
-419.377
-418.979
-418.520
-418.021
-417.488
-416.915
-416.330
-382.515
-373.349
-364.259
-355.259
-346.332
-337.464
-328.670
49.952
39.004
31.712
26.510
22.613
19.586
17.168
1100
1200
1300
1400
1500
l6U0
1700
1800
34.966
36.460
37.795
39.007
40.117
41.145
42.105
U3.009
107.16
111.76
116.07
120.13
123.97
127.62
131.10
134.44
72.19
75.30
78.27
81.12
83.85
86.48
88.99
91.43
52.42
53.36
54.29
55.21
56.12
57.02
57.93
58.83
-415.704
-415.048
-414.359
-413.636
-412.881
-412.090
-411.264
-410.401
-319.927
-311.154
-302.624
-294.062
-285.561
-277.090
-268.677
-260.317
15.192
13.549
12.160
10.972
9.944
9.046
8.255
7.554
__--_________-___~_------------------------------------------------------------2210
MELTING POINT
ENTHALPY OF MELTING
H
-~
H;~
BOILING POINT
kJ
kJ
kJ
nOLAR VOLUME
TRANSITIONS I N BEFERENCE STATE ELEflENTS

TRANSITIONS I N REFEBENCE STATE ELEHENTS

C;
8 8 . 4 4 5 - 5 . 5 1 7 8 ~ 1 0 ' ~T
(EQUATION VALID FRO8
1 5 - 9 9 , T-Oas
596 - 1 8 0 0 K )
t
4 . 3 1 2 5 ~ 1 0 . T-*
-___--------------.--------------------------------------------------~-~--------
REFERENCE
32
32
215
32
................................................................................
~ ~ ~ P I L E D
5-24-76
REPEHENCE
33
33
____-_______-______----------------L--------------------------------------------
3,
COnPlLEC
5-19-76
196
THEBIIODIUAIIIC PBOPZPTIES 01 IIIUEBALS

PBOPEBTIXS AT HIGH TEIIPLBATUBES
NIOBIUII DIOXIDE
...............................................................................
FOBlULA WEIGHT
124.905
FOBMULA WEIGHT
UINIOBIUl PENTOXIDE
265.810
..............................................................................
NbO,:
t o 1 1 5 0 K.
B e t a c r y s t a l s 1 1 5 0 t o 1 8 0 0 K.
C r y s t a l s 298.15
Nb,Os:
TEMP.
(H;-H;~~)/T
S;
-(G;-H;~~)/T
J/.0l-K
J/.0l.K
298.15
0.000
UNCERTAINTY
J/.Ol.K
54.51
0.30
54.51
0.30
C;
FOBIIATION PBOU THE ELEUENTS

GIBBS
ENTHALPY
FREE ENERGY
Log K~
kJ/.0l
J/.0l.K
57.45
-794.960
8.370
t o melting point
1 7 8 5 K.
L i q u i d 1 7 8 5 t o 1 8 0 0 K.
-- ___________________------_---------------------------------------------------FOBlATION PROUGIBBS
THE ELEUEYTS
TEUP.
( H ; - H ; ~ ~ )IT
-(G;-H;~~)/T
S;
C;
ENTHALPY
FREE ENERGY
LO^
K~
kJ/.0l
-739. 194
129.504
8.370
1.466
................................................................................
RELTING POINT
2175
BOILING POINT
ENTHALPY OP MELTING
kJ
ENTHALPY OP VAPOBIZATION
~ 4 9 8-
kJ
BOLAB VOLUlE
kJ
MELTING POINT
1785
BOILING POINT
ENTHALPY OF MELTING
104.265
kJ
kJ
22.288
kJ
"298
TRABSITIONS I N REFERENCE STATE ELElENTS
H:

NIOBIUM....
l.
P. 2 7 4 0 K .
NIOBIUU....
8.
P.
2740 K-

C;
69.650 + 2.8178110-2
T
(EQUATION VALID PROU
REFERENCE
130
.<.n
33
3.55721102 T - 0 - s
298 - 1 1 5 0 K )
33
COUPILED
IIOLAB VOLUME
9.3420
93.420
J/bar
cm3
-THERIODIYAIIC PROPEPTIES OF I I I P R A L S
198
NEODYIIUI SESQUIOXIDE (HEXAGONAL)

..................................................................................
Nd,O,:
t o 1 3 9 5 K.
FORIULA WEIGHT
336.978
PORIULA WEIGHT
BUNSENITE
_______________F____
C r y s t a l s 298.15
NiO:
74.699
-----==-_____
- - - - - = = _ _-----------=_--______-___--------=_-_-_
-------==-__-------=-___-----
a-p
t r a n s i t i o n a t 525 K and
B e t a c r y s t a l s 1 3 9 5 t o 1800 K.
6-7 t r a n s i t i o n a t 5 6 5 K.
TEIP.
( H ; - H ~)/T~ ~
S;
-( G ; - H ; ~ ~ )/T
C;
J/aol*K
J/mol-K
J/molsK
298.15
0.000
UNCERTAINTY
158.57
4.20
158.57
4.20
111.25
400
500
600
700
800
90U
1000
29.575
48.304
61.612
71.706
79.736
86.367
92.000
192.64
220.11
243.47
263.85
282.00
298.41
313.44
163.06
171.81
181.86
192.14
202.26
212.04
221.44
120.22
125.88
130.31
134.16
137.71
141.07
144.33
1100
96.903
327.35
230.45
147.51
FORIIATION FROB THE ELEMENTS

GIBBS
ENTHALPY
FREE ENERGY
LO^ K~
J/mol- K
kJ/nol
PORIATION FRO8GIBBS
THE ELEMENTS
TEIP.
( H ; - H ~ ~ ~ ) / T S;
-(G;-H;~~)/T
-1721.048
1.020
301.522
0.179
-1806.334
-1804.506
-1802.667
-1800.936
-1799.393
-1798.097
-1797.103
-1691.604
-1663.136
-1635.030
-1607.239
-1579.669
-1552.271
-1525.013
220.902
173.727
142.343
119.934
103.142
90.092
79.659
-1796.467
-1497.850
71.127
-1801.924
-1470.322
64.002
----------------------------~-_-
1200
101.251
340.32
239.07
150.65
105.170
108.373
352.50
363.26
247.33
254.89
153.75
156.70
-1815.300
-1815.283
-1455.616
-1415.402
58.488
52.999
1395
1400
1500
1600
1700
1800
109.043
109.200
112.299
115.008
117.399
119.523
363.93
364.47
375.21
385.25
394.69
403.58
254.89
255.27
262.91
270.24
277.29
284.06
155.64
155.64
155.64
155.64
155.64
155.64
-1814.348
-1814.331
-1813.995
-1813.702
-1813.445
-1813.220
-1415402
-1413.973
-1385.400
-1356.830
-1328.291
-1299.734
52.999
52.756
48.244
44.296
40.814
37.717
298.15
37.99
0.17
48.04
-239.743
0.418
-211.581
0.460
37.068
0.081
400
500
12.175
21.212
52.01
64.73
39.83
43.52
52.74
53.22
-239.170
-237.923
-202.044
-192.873
26.384
20.149
600
27.747
75.79
48.04
50.94
700
800
900
1000
31.130
33.786
35.956
37.795
83.71
90.71
96.99
102.71
52.58
56.92
61.03
64.91
51.91
52.87
53.83
54.79
-236.734
-184.009
16.019
................................
-236.535
-236.052
-235.562
-235.099
13.075
10.872
9.161
7.794
-175.222
-166.504
-157.838
-149.219
................................
"298
................................................................................
2257
6.694
- HP)
BOILING POINT
kJ
ENTHALPY OF VAPOHIZATION
kJ
kJ
WLAR VOLURE
1.0970
10.970
J/bar
cm3
HELTING POINT
BOILING POINT
EMTHALPY OF UELTING
kJ
kJ
kJ
HOLAR VOLUNE
NICKEL

P.
l o g K~
37.99
0.17
ENTHALPY OF BELTING
ALPHA-BETA 1 1 2 8 , H.
FREE ENERGY
0.000
u NCERTAINTY
BELTING POINT
NEODYHIUn..
ENTHALPY
K
J/mol-K
J/mol-K
J/mol-K
J/mol-K
kJ/mol
................................................................................
-1807.910
1.000
1300
1395
21.004
C;
kJ/nol
kJ/mol
..... CURIE
P.
631,
M.
P.
1 7 2 6 K.
1289 K.
C;
45.175 +
9.6149~10-3 T
5 6 5 - 1 8 0 0 K)
---________-_-_-~__----_-------------------------------------------------------HEAT CAPACITY EQUATION
REFERENCE
119
~ L O
23
Lb J
COUPILED
6-21-76
----_________-_-___------------------------------------------------------------C;
1.1574~102 + 2.9779~10-2 T 1 . 1 8 8 3 ~ 1 0 s T-2

(EQUATION VALID PROU 2 9 8 - 1 3 9 5 K )
................................................................................
REFERENCE
210
235
235
................................................................................
COHPILED
8 - 1 1-76
200
THPMODIYAMIC P E O P E P T I E S OF l l I I B R A L S
PBOSPHORUS MOIOXIDE
FORIIULA WEIGHT
........................................................................
PO:
I d e a l g a s 298.15
46.973
p.0.:
t o 1800 K.
c r y s t a l s 298.15
(PzOs)2
( C )
T h e free e n e r g y c h a n g e f o r t h e r e a c t i o n
t o 1 0 0 0 K.
= P.O.,
(4) a p p r o a c h e s z e r o a t 6 3 1 K.
______________
( H ; - H ~ ~ ~ ) / T S;
TEMP.
- ( G ~ - H ; ~ ~ ) / T C;
FORHATIOW FROM THE ELEMENTS

GIBBS
ENTHALPY
FREE ENERGY
l o g K~
P O R B A T I O I FROB6 ITBB
B B 5 ELBMBITS
( ~ ; - n ; ~ ~)/T
TEMP.
K
J/.Ol.
----
298.15
0.000
UUCERTAINTX
BELTING POINT
BOILING POINT
ENTHALPY OF HELTIYG
kJ
ENTHALPX OF VAPORIZATION
9.393 k J
MOLAR VOLUHE
-(G-H;~~)/T
J/.OlsK
C:
BBTBALPI
J/mol'K
kJ/.Ol
FREE E Y E R G P
log
kJ/.Ol
115.50
0.40
115.50
0.40
105.86
-1470.000
4.200
-1337.897
4.200
234.396
0.736
31.327
54.936
74.720
92.180
108.089
122.861
136.758
151.46
181.69
216.28
246.59
275.86
304.23
331.80
120.13
129.75
141.56
154.41
167.77
181.37
195.04
125.42
148.01
170.60
153.97
153.97
153-97
153.97
-1469.571
-1467.072
-1462.646
-1456.387
-1619.194
-1607.236
-1593.367
-1292.781
-1248.837
-1205.572
-1163.209
-1166.197
-1110.251
-1055.763
168.820
130.466
104.955
86.800
76.146
64.438
55.147
___________________-_-----_--_-_---_-_------__-_------_----_-_-_--K
MELTIUG P O I I T
BOILING POIllT
kJ
J/bar
';98
TRANSITIONS I N REFERENCE STATE ELEHEUTS

PHOSPHORUS.
J/mol.K
298.15
0.000
UUCBltTA1.IITI
400
500
600
700
800
900
1000
G 9 8
S;
K
_________________________________________________
J/MOl.K
-4
MOLAR VOLUME
kJ
T R A B S I T I O B S X I REPBBBUCB STATE ELEMENTS
s u B L L n e s 7 0 4 K.
PEOSPEOROS.
I/~
SUBLIMES 7 0 4 K-

BEAT C A P A C I T I EQOATION
C;
REFERENCE
32
32
32
COBPILED
5-24-76
35.041 + 0.22594 T
(BQOATIOll VALID PROM
298
6 3 1 K)
--__________-___________________________--_____-______REPBBEBCB
247
215
215
COMPILED
03-15-79
-202
TIiIRNODlYAMIC P I O P P B T I I S O F M I M M U S
PHOSPHOBUS PBUTOXIDE ( D I N E R I C )
PORLIULA WEIGHT
..............................................
(P.O.),:
283.889
97.995
...............................................................................
t o 1 0 0 0 K.
( P Z O S ) Z ( c ) = P.O,O
T h e free e n e r g y c h a n g e f o r t h e r e a c t i o n
H,PO.:
S;
C r y s t a l s 298.15
-(G;-B;~~)/T
cOp
K.
Above 315.5
K the data
t a b u l a t e d are a m e t a s t a b l e e x t r a p o l a t i o n
( g ) a p p r o a c h e s z e r o a t 6 3 1 K.
..............................................................................
( H;-H;~~)/T
POBHULA WEIGHT
OBTHOPHOSPH0BIC ACID ( CRYSTAL )
...................................
C r y s t a l s 289.15
TENP.
203
PBOPEBTIES AT HIGH TENPEBATUBES
____--__-________---------------------------------------------------------------
FORHATIOII PRO8 THE ELEIIEMTS

GIBBS
ENTBALPY
FREB EMEBGI
log
TEBP.
K~
(H
-(G:-H;~~)/T
S;
C;
FORHATION PROn THE ELEHENTS

GIBBS
ENTHALPY
FBEE E N E R G Y
l o g K*
--------------------------------------------------------------------------------
................................................................................
MELTING POIUT
I[
BOILING POIMT
ENTBALPP O P VAPORIZATION
kJ
kJ
8OLAB VOLUME
$98
34.551
HELTING POINT
315.50
BOILING POINT
ENTHALPY 0 P HELTING
13.460
kJ
kJ
kJ
HOLAR VOLUME
~ ; 9 8-
Hi
4.8520
48.520
J/bar
c-n3
TRANSITIONS I N REFEBENCE STATE ELEHENTS

PHOSPHORUS.
SUBLIMES 7 0 4 K.
TRANSITIONS I N REFERENCE S T A T E ELEMENTS
C;
C;
70.082 + 6.45190 T
247
15.756 + 0.30288 T
REFERENCE
- 631 K )
...............................................................................
BEPEREUCE
298 - 1000 K )
--------------------------------------------------------------------------------
215
298
215
32
32
32
COMPILED
5-19-76
-------------------------------------------------------------------------------COMPILED
03-15-79
204
THEPIOOIYAIIC PBOPEPTIES OF IIUSPALS
ORTHOPHOSPHOPIC ACID ( L I Q U I D )
PROPERTIES AT HIGH TEIIPERATUBES
POBIULA WEIGHT
...............................................................................
--__---------------------------------------------------------------------------=
H3P0.:
L i q u i d 298.15
97.995
LITHABGE ( B E D )
................................................................................
pbO:
t o 1 0 0 0 K.
PORUULA WEIGHT
223.199
Massicot (orthorhombic) is the
t o 1 4 0 0 K.
s t a b l e p h a s e a b o v e 7 6 2 K.
S e e t a b l e f o r l e a d monoxide ( r e f e r e n c e s t a t e ) .
--------------------------------TEMP.
( H G - H)IT
~ ~ ~ S;
J/mol.K
-(G;-H;~~)/T
J/nol-K
J/mol.K
C;
FORMATION PBOI THE ELEMENTS

GIBES
ENTHALPY
FREE ENERGY
L~~
J/mol.K
k J/mol
kJ/mal
..............................................................................
298.15
0.000
U NCERTAINTY
150.78
4.20
150.78
4-20
145.05
-1254.200
2.090
-1111.700
2.510
FOBBATION FROU THE ELEHENTS

GIBES
FREE ENERGY
Log K f
ENTHALPY
--
194.766
0.4110
................................................................................
UELTING POINT
315.50
ENTHALPY OF MELTING
4 9 8
tli
BOILING POINT
kJ
kJ
kJ
IOLAR VOLUUE

PHOSPHORUS.
................................................................................
MELTING POIUT
BOILING POINT
ENTHALPY OF IELTING
kJ
kJ
':98
SUBLIHES 7 0 4 K.
IOLAP VOLOIE
kJ
2.3910
13.910
J/bar
ca3
TBANSITIOIS I N BEPEBEUCE STATE ELEMENTS

LEAD
.......
I. P.
600.6.
8.
P.
2 0 2 1 K.
C;
55.239 + 0.30123 T
( E Q U A T I O NV A L I D F a o a
BEPEBEYCE
32
32
298
iooo K )
32
................................................................................
COIPILED
5- 19-76
C;
51.017 + 1 . 0 2 7 2 ~ 1 0 - 2 T
BEPEBEUCE
32
32
298
7 . 3 8 7 2 ~ 1 0 5 T-2
- 1 4 0 0 I)
32
COUPIL ED
6- 7 - 7 6
THEBtlODYUAUIC PBOPERTIES OP UINEBALS
206
nASSICOT (YELLOU)
PbO:
PROPERTIES AT HIGH TEHPEBATUBES
FORaULA WEIGHT
O r t h o r h o n b i c c r y s t a l s 298.15
(reterence state).
Liquid
t o
1 1 7 0 K.
223.199
S e e t a b l e f o r l e a d monoxide
FOBBULA YEIGHT
LEAD MOUOXIDE ( R E P E R E I C E )
223.199
_ ____- _ -__
__
_ -__-_-___-__~__-~~
-_
_ --------- --------- -- =--_=
_
-~
-_--_- _~
-- ---.- __ __ -__-________- ._--_- -- .--_- -_-_- ----------- -- -- - - - - - = = = = = = ~ = = =
PbO:
L i t h a r g e ( r e d ) 298.15
1170 t o 1789 K.
Liquid
t o 7 6 2 K.
M a s s i c o t ( y e l l o w ) 762 t o 1170 K.
1 1 7 0 t o 17.59 K.
................................................................................
TEHP.
5:
( H;-H;~~)/T
-(G;-H&~)/T
FORBATION FHOE THE ELEiYENTS
FORiYATION PROU THE ELEMENTS

GIBMS
EUTHALPY
FREE ENERGY
Log K~
C;
J/mol-K
J/mol-K
J/mol-K
J/nOl.K
kJ/nol
298.15
0.000
UNCERTAINTY
68.70
0.21
68.70
45.77
-218.070
0.630
kJ/m31
................................................................................
0.21
-----
5
0. 100
33.037
0.123
298.15
0.000
UNCERTAINTY
66.32
0.84
h6.3L
17
-219.409
0.830
0.84
-189.202
0.900
33.148
0.158
................................................................................
nELTING POINT
1170
25.522
ENTHALPY OF MELTING
G9tl
BOILING POINT
1789
kJ
ENTHALPY OF VAPORIZATlON
207.233
kJ
kJ
MOLAR VOLUME
1170
UELTING POINT
MOILING POINT
1789
kJ
ENTHALPY OF VAPORIZAZLON
207.233
kJ
TBANSITIONS 1 N HEPERENCE STATE ELEUEHTS

LEAD
....... 8 .
25.522
EHTHALPY OF UELTING
P.
600.6,
8.
P.
2 0 2 1 K.
k
.!
B O L A 8 VULUUE
TRANSITIONS 1 8 PEFERENCE STATE PLEiYENTS

HEAT CAPACITY
C;
EQUATION
LEAD
45.188 t
1.2863~10-2 T
(EQUATION VALID PBOn
2.8Y18n105
298 - 1170 K )
.......
fi.
P.
600.6,
P.
Li.
LO21 K .
T-7
HEAT CAPACITY OUIJATION5
REFERENCE
32
32
32
................................................................................
COUPILED
6 - 7-76
C:
51.017 +
1 . 0 2 7 l r l O ~1
~
(LuUATiON VALID P R u n
I.
LYii
r.7
~ ~ J L X I U ~
76,
P)
- - - - - - - - - - - . - - - - - ---..-----------~
HEPEHENCE
32
115
32
32
COUPLLED
h-29-70
THEBIODIIABIC PBOPEBTIES OF BINEBALS

PLATTNEBITE
_---_----_------------_---_---_------------------===---------------=====--------------------P~o,:
c r y s t a l s 298.15
POBnULA WEIGHT
239.199
-"r
_-----_------_-_--___
209
PBOPLPTIES AT HIGH TEIIPEBATUBES

POBBULA WEIGHT
BIUIUII
................................................................................
685.598
t o 1200 K.
pb.0,:
C r y s t a l s 2 9 8 . 1 5 t o 1 8 0 0 K.
-------------------------------------------------------------------------------TEnP-
(H;-H;~B
J/mol.K
s;
-( G ; - H ; ~ ~ ) / T
J/mol-K
C;
FORBATION FROB THE ELEBENTS

- GIBBS
FREE ENERGY
logK f
FOBIIATION FROB THE ELEBEYTS

GIBES
ENTHALPY
(H~-H;~~)/T
TE~P.
J/mols K
J/mol* K
kJ/mol
J/mol- K
298.15.
0.000
UNCERTAINTY
71.80
0.42
71.80
0.42
61.17
-274.470
2.929
si
- ( G ~ - H ; ~ ~ ) / T C:
ENTHALPI
FREE ENERGY
1.09
K~
kJ/nol
-215.314
3.000
37.722
0.526
J/mol- K
298.15
0.000
UUCERTAINTI
J/mol-K
211.96
6.69
211.96
6.69
J/m0lsK
kJ/mol
kJ/mol
15U.93
-718.686
6.276
-601.358
6.300
105.356
1.104
-------------------------------------------------------------------------------MELTING POINT
ENTHALPY OF BELTING
4 9 8
kJ
10.966
k.l
BOILING POINT
2.5010
~ O L A RV O L U ~ E
25.010
TRANSITIONS I N BEFERENCE STATE ELEBENTS
UELTING POINT
BOILIUG POINT
kJ
ENTHALPY OF BELTING
kJ
kJ
kJ
BOLAB VOLUBE
J/bar
cm3
'0298
30.188
7.6810
76.810
J/bar
cm3
TRANSITIONS I U REPEBENCE STATE ELEBENTS

LEAD
....... a.
P.
600.6,
8.
P.
2 0 2 1 K.

C:
REFERENCE
32
32
32
COMPILED
6- 7 - 7 6
--------------------------------------------------------------------------------
1.7793xlOZ +
3.3260~10-2 T
(EQUATION VALID FROB 2 9 8
REPEBEUCE
32
32
2.9259~10.
1 8 0 0 K)
T-2
32
COBPILED
6- 7 - 7 6
---
210
.-
THERMODIYAMIC PBOPBBTIES
PRASEODYMIUM S E S Q U I O X I D E ( H E X )
...............................................................................
Przo3:
C r y s t a l s 298.15
O F MINERALS
FORMULA WEIGHT
329.814
................................................................................
alpha crystals
-(G;-H:~~)/T
C;
J/mol- K
J/mol-K
J/mol-K
J/mol-K
298.15
0.000
UNCERTAINTY
158.57
4.20
158.57
4.20
120.40
ENTHALPY
GIBBS
FREE E N E R G Y
kJ/nol
-1809.580
6.690
LO^ K~
170-235
..........................................
t o 7 6 0 K.
298.15
B e t a c r y s t a l s 760 t o 1100 K-
FOBMATIOY FROM THE ELEMEYTS

GIBBS
POBUATIOY F u o n T H E ELEMENTS
( H ~ - H ~ ~ ~ ) s/: T
TEMP.
211
~ AZ
l R
~ I Gxt l T
~ I MsP L I A T O P E S
FORMULA WEIGHT
PRASEODIlLIUM OXXDE
=_5====_==_===_=*======fE_5==___
to 1 8 0 0 K .
TEMP-
(H;-H~~~)/T
-(G:-H;~~)/T
S;
C;
EYTHALPY
FREE EYEBGY
L o g Kf
k~/mol
-1721.015
6.700
301.518
1.174
................................................................................
MELTING POINT
BOILING POINT
ENTHALPY OF MELTING
kJ
EUTHALPY OF VAPOBIZATILJN
kJ
MOLAR VOLUnE
4 9 8
nELTING P O I N T
BOILING POINT
kJ
ENTHALPY OF MELTING
kJ
EYTHALPY OF VAPOBIZATIOY
kJ
kJ
MOLAR VOLUME
4 9 8
THANSITIONS I N REFERENCE STATE ELEMEYTS

PRASEODYIIUM ALPHA-BETA
1068.
M.
P.
H:
2.4600
24.600
J/bar
cm3
TRAYSITIONS I N REFERENCE STATE E L E l E l T S

1 2 0 4 K.
PRASEODYMIUM ALPHA-BETA
1068.
1. P.
1 2 0 4 K.
760 K)
HEAT CAPACITY
EQUATION
C;
BEPERENCE
200
28 1
235
COUPILED
6-14-76
C:
51.577 t
4.7918~10-2 T
(EQUATIOU VALID PROM
298
49.403 t
4.9701~10-2 T
(EQUATION VALID PRon
760 - 1100 K )
................................................................................
REFERENCE
200
281
281
COMPILED
5-18-76
SULFUR DIOXIDE
..............................................................................
SO,:
I d e a l g a s 298.15
TEnp-
( H ; - H ~)/T
~ ~
J/molSK
POPMULA WEIGHT
t o 1800 K.
S;
-( G : - H ~ ~ ~ ) / T
J/nol.K
C;
J/mol- K
~ / m o l -I(
248-22
0.06
248.22
0.06
39.87
293.86
300.10
305.78
264.21
267.87
271.37
52.30
53.48
54.44
PORflATIOY PROM THE ELEMENTS

GIBBS
EuTHfiPY
FREE E Y E N G Y
L~~
k
l
k J/mol
-Kt
------------------------------------------------------_-----------------------298.15
O-000
UUCERTAINTT
-296.810
0.200
52.589
-300.170
POPMULA WEIGHT
64.059
0.251
0.0114
80.058
...............................................................................
SOLPUB
TRIOIIDB
50,:
I d e a l g a s 298.15
t o 1800 K -
-TEMP.
(H;-H;g8)/~
0.000
256.76
0.84
UNCERTAINTI
ENTHALPI
J / ~ o ~ . K ~1.0l.K
J/nol.K j/.ol-K
--298.15
COP
-(G;-B&~)/T
S;
~OJJMJ,TIGYFROB THE ELEMEYTS

GIBBS
256.76
0.84
50.66
FREE ENERGY
l o g 'f
kJ/.ol
kJ/mol
-395-722
0.711
65-006
0.139
-371-046
0.795
-.
--_-----------------------------
BOO
900
1000
29.654
32.233
34.412
BELTING POINT
197.64
ENTHALPY OF BELTING
~ g 9 e
7.401
10.548
H:
-362.267
-362.212
-362.111
BOILING POINT
kJ
k.l
noLAR voLunE
P.
24.937
2478.9200
24789.200
BELTING POINT
BOILIYG POINT
kJ
EITHALPY OF VAPORIZATION
kJ
ENTHALPY OP BELTING
kJ
MOLAR VOLUBE
kJ
J/bar
cm3
$98
:H
2478.9200
24789.200
J/bar
cm3
TRAUSITIONS I N REFERENCE STATE ELEMENTS
.... ORTHO-MONO
8.
19.825
17.195
15.092
263.08
TBANSITIONS I N REFERENCE STATE ELEBENTS

SULFUR.
-303.629
-296.262
-288.927
368.54.
716.9 K.
P.
H.
MONO 388.36.
SULFOR...-.
ORTHO-MOM0 368.54.
8. P. 716.9 K.
M.
P.
HOMO 388.36.

C;
8 6 . 2 1 9 - 4 . 3 0 7 3 ~ 1 0 - ~T
REFERENCE
247
35
298
8.8646~10~
T-O-s
1 8 0 0 K)
5 . 5 7 6 9 ~ 1 0 5 T-*
C;
35
COMPILED
5-24-76
1 . 2 7 6 0 ~ 1 0 2 - 7 . 8 1 4 0 ~ 1 0 - 3 T 4 6.12381105
1 8 0 0 K)
REPEEENCE
247
247
TZ
247
1.4073x103
T-O"
COBPILEO
5-24-76
---
THEBUODYIAIIZC P R O P E R T I E S O F H I U E B A L S
SCAUDIUH SESQUIOXIDE
--___--___
P P O P L I T I E S AT H I G H T E I I P E 8 A T U R E S
137.910
POBUULA WEIGHT
----------_----_--E=---------=~=======*~-T====--===========================
Sc,O,:
C r y s t a l s 298.15
TEHP.
( H ; - H ~ ~ ~ ) / T 5;
t o 1800
I.
si0:
-(G;-B;~~)/T
C:
PORHULA
S I L I C O N U0110XIDE
YEIGUT
44.085
.............................................................................
t o 1 8 0 0 K.
Ideal gas 298.15
FORHATION PROU THE E L E U X l T S

GIBBS
F R E E ENERGY
EUTHALPY
PORHATIOU P R O 8 T H E ELEHEUTS
GIBES
F R E E ENERGY
L o g K~
EYTHALPY
kJ/mol
298.15
0.000
76.99
0. 42
UNCEBTAIBTY
76.99
0.62
96.98
-1908.820
-1819.371
318.748
2.510
2.520
0.441
K
J/nol.K
J/nol-K
J/n01-K
J/mol-K
kJ/mol
___________________------------------------------------------------------------
298.15
0.000
211.57
0.84
UNCERTAINTY
211.57
0.84
29.90
-100.416
8.368
-127.305
8.500
22.304
1.489
________________7__-------------------------------------------------------------
HELTING P O I N T
BOILIBG POINT
EUTHALPY
kJ
ENTHALPY OF Y A P O B I Z I T I O N
~ l 9 8-
OF BELTING
MI:
13.975 k J
3.5910
35.910
MOLAR YOLUUE
T B A U S I T I O N S 11 REPEBEUCE S T A T E ELEUEUTS
SCANDXUU...
ALPHA-BETA
1 6 0 8 , U.
P.
HELTING P O I N T
BOILING POINT
kJ
ENTHALPY O F HELTING
kJ
EUTHALPY
kJ
J/bar
cm3
4 9 8
k J
UOLAB YOLUUE
1.9455xl0z
8.711
2478.9200
24789.200
J/bar
cn3
T R A N S I T I O N S I N BEPERENCE S T A T E ELEUENTS
1 8 1 1 K.
SILICON....
C; =
OF VAPORIZATIOU
K.
P.
, 6 8 5 K.
1.2212~10-2 T 1 . 7 5 2 7 ~ 1 0 3 T-0.5
298 - 1800 K )
4.2670~10s T-2
C;
( E Q U A T I O N V A L I D FROU
- 1.O84Or10-3 T
( E Q U A T I O N V A L 1 0 FROU
50.373
298
4 . 0 9 0 0 ~ 1 0 T~- 0 . 5
- 1800 K )
3.4095~105 T - ~
................................................................................
REFERENCE
203
181
264
162
................................................................................
COHPILED
6-
9-76
REFERENCE
247
247
247
COKPILED
5-24-76
THEPMODIIAMIC PBOPEBTIES OP EIIBPALS

QUABTZ
......................................................................
SiO.:
POBMULA WEIGHT
60.085
----=========
A l p h a q u a r t z 2 9 8 - 1 5 t o 8 4 4 K.
(tl;-Hig8)/~
J/mol-K
S;
J/mol-K
298.15
0.000
DNCEBTAINTY
J/m0lsK
41-46
0.20
PROPERTIES AT HIGH TEEPEBATUPES
siOZ:
41.46
0.20
C;
FOBEATION FBOl THE ELEEENTS

GIBES
ENTHALPY
FREE ENEBGY
Log tif
J/mol*K
kJ/mol
kJ/mol
44.59
-910.700
1.000
-856.288
1.100
TeaP.
A l p h a c r i s t o b a l i t e 298.15
(H;-H:~~)/T
BOILING POINT
lELTING POINT
ENTHALPY OP BELTING
kJ
kJ
EYTHALPY OF BELTING
6.916
H:
kJ
HOLAB VOLUlE
.... H.
P.
C;
1685 K.
44.603 t 3 . 7 7 5 4 ~ 1 0 - 2 T
(EQUATION VAL10 FRon
58.928 +
1.0031~10-2 T
(EQUATION VALID PBOB
REFERENCE
247
35
278
t o 5 2 3 K.
-(G;-H&~)/T
C:
B e t a c r i s t o b a l i t e 5 2 3 t o 1 8 0 0 K.
FOBlATION FROl THE ELEMENTS

GIBES
ENTHALPY
FREE ENEBGY
LOq Kf
1996
BOILIPG POINT
8.159
kJ
kJ
7.040
kJ
BOLAR VOLUEE
TRANSITIONS I N BEFEREICE STATE E L E l E l T S
....
SILICON
C;
SOT
- 4
4 9 8
TRANSITIONS I N BEFEBENCE STATE ELElENTS

SILICON
60.085
150.019
0.193
HELTING POINT
4 9 8
POBIULA WEIGHT
CBISTOBALITE
................................................................................
B e t a q u a r t z 8 4 4 t o 1 8 0 0 K.
M t a q u a r t z i s m e t a s t a b l e a b o v e 1 1 4 0 K.
TEBP.
.!I
P.
1 6 8 5 K.
298
844
1 . 0 0 1 8 r 1 0 b T-2
- 844 K)
1 8 0 0 K)
35
284
COHPILED
7-16-76
t
2 . 5 4 8 0 T + 7 . 1 6 8 0 x 1 0 + T-0.5
(EQUATION VALID FBOl 2 9 8
5 2 3 K)
C;
= -4.1596~101
C;
72.753 t
1.3004110-~ T
(EQUATION VALID ?POM
R$FERENCE
247
172
247
278
523
6 . 2 8 5 9 ~ 1 0 7 T-2
4 . 1 3 2 0 ~ 1 0 * T-2
1 8 0 0 I)
247
COMPILED
6- 8-76
218
THEIIIIODINAIIIC PROPERTIES OF BIYEBALS
TBIDYBITE
FORBULA WEIGHT
~LO,:
Alpha t r i d y m i t e 298.15
TEBP.
)/"I'
S;
t o 390 K .
-(G;-H;~~)/T
J/mol-K
J/nol-K
J/mol-K
298.15
0.000
UNCERTAINTY
43.93
0.42
43.93
0.42
60.085
B e t a t r l d y m i t e 3 9 0 t o 1800 K.
FORMATION PROU THE ELEBEUTS

GIBBS
FREE ENERGY
LO^ K f
ENTHALPY
C;
J/nol. K
kJ/mol
kJ/nol
44-60
-907.488
-853.812
149.585
2.427
0.425
2.385
390
11.640
57.15
45-52
54.15
-907.593
-837.302
112.145
390
400
500
600
700
800
900
1000
12.069
13.275
22.468
29.155
34.253
38.281
41.556
44.290
57.57
59.01
72.21
83.61
93.60
102.48
110.46
117.72
45.52
45.73
49.74
54.45
59.35
64.20
b8-90
73.43
56.41
56.97
61.17
63-84
65.73
67.18
68.35
69.35
-907.426
-837.302
112.145
-907.356
-906.782
-906.083
-905.330
-904.554
-903.768
-902.967
-835.408
-817.487
-799.685
-782.011
-764.450
-746.979
-729.607
109.094
85.403
69.619
58.355
49.914
43.354
38.111
P R O ~ E B T I B SAT BIGH TEnPGPATUBES

COESITE
==_======_====_=====---
......................................................
Si0.z
t o 1 8 0 0 K.
C r y s t a l s 298.15
FORBULA WEIGHT
60.085
FORBATION FHOB THE ELEMENTS

GIBBS
TEnp.
( H ~ - H )/T
; ~ ~ S;
-( G;-H!&,~)/T
C;
EUTHALPY
FREE E N E R G Y
LO^
K~
K
J/nol-K
J/mol-K
J/mol. K
J/#Ol. K
kJ/nol
kJ/mol
___-_______________------------------------------------------------------------
298.15
0.000
UNCERTAIUTY
40.38
0.42
40.38
0.42
45.40
-905.584
2.092
-850.850
1.134
149.066
0.374
400
500
600
700
800
900
1000
12.475
21.102
27.708
32.946
37.190
40.689
43.611
54.72
67-11
78.17
88.09
97.02
105.10
112.47
42.24
46.01
50.46
55.14
59.83
64.41
68.86
52.54
58.45
62.76
65.79
67.89
69.36
70.40
-905.772
-905.561
-905.047
-904.341
-903.523
-902.644
-901.742
-832.108
-813.716
-795.385
-777.165
-759.051
-141.031
-723.132
108.663
85.009
69.245
57.993
49.561
43.009
37.773
1100
1200
1300
1400
1500
1600
46.083
48.202
50.041
51.657
53.106
54.419
119.22
125.44
131.21
136.60
141.66
146.44
73.14
77.24
81.17
84-94
88.55
92.02
71.18
71.81
72.40
73.01
73.70
74.52
-900.638
-899.938
-899.045
-898.155
-897.246
-896.313
-705.324
-687.574
-669.920
-652.343
-634.806
-617.337
33.493
29.929
26.918
24.339
22.106
20.154
1700
1800
55.629
56.764
150.99
155.34
95.36
98.58
75.49
76.66
-945.844
-944.512
-599.503
-579.166
18.421
16.807
-------------------------------------------------------------------------------BELTING POINT
BOIL1 NG POI UT
ENTHALPY OF UELTING
kJ
kJ
kJ
(OLAR
"298
HE
il.
P.
BOILING POINT
ENTHALPY OF BELTING
kJ
EUTHALPY OF VAPOBIZATION
kJ
VOLUBE
~ f 9 8 H;

SILICON....
UELTING POINT
BOLAR VOLUBE
kJ
1 6 8 5 K.
SILICON
.... n.
P.
1 6 8 5 K.

HEAT CBPACITY EQUATION
C
:
74.904 + 3 . 0 9 9 9 ~ 1 0 - ~T
1 . 3 6 6 9 ~ 1 0 2 T-0-5
390 - 1 8 0 0 K)
1.1740~106
T-2
--_--__------------------------------------------------------------------------REFERENCE
172
285
1Q 8
COBPILED
6-28-76
REFERENCE
2 . 6 0 3 6 ~ 1 0 ' T-2
(EQUATION VALID FBOB
285
101
298
1 8 0 0 K)
101
COBPILED
7-16-76
220
THERIODINAMIC PROPERTIES OF HIYEPALS
P B O P ~ P Z I E S AT HIGR TElPEPATUBES
STISHOVITE
FORIULA WEIGHT
60.085
.............................
.................................................................
__=------__--_
---------__
sio,:
C r y s t a l s 298.15
SILICA GLASS
...................................................................................
SF
( H ~ - H ~ ~ ~ ) / T -(G;-H;~~)/T
J/mol-K
60.085
t o 1800 K.
SiO.:
TEIIP.
FORBULA WEIGHT
J/mol- K
J/mol-K
C:
PORMTIOU PROM THE ELEIEUTS

GIBBS
EUTHALPY
FREE ENERGY
Log Kf
J/mol- K
kJ/mol
kJ/mol
-861.318
-802.827
G l a s s 298.15
t o 1 8 0 0 K.
PORnATION FROB THE ELEBENTS

GIHBS
TEIP.
(~;-H;~~)/T
- ( G ; - H ~ ~ ~ ~ ) / T C;
S;
ENTHALPX
FREEENERGY
log
xf
................................................................................
298.15
0.000
UNCERTAINTY
27.78
0.42
27.78
0.42
42.97
400
500
600
700
800
900
1000
12.425
21.270
27.958
33.170
37.335
40.744
43.574
42-03
54.66
65.84
75.77
84.65
92-65
99.93
29.60
33.39
37.88
42.60
47.32
51.91
56.36
53.47
59.40
63.12
65.58
67.30
68.57
69.56
-861.526
-861.211
-860.631
-859.918
-859.141
-858- 328
-857.513
-782.786
-763.141
-743.571
-724.118
-704.773
-685.510
-666.363
1100
1200
1300
1400
1500
1600
45.976
48.045
49.855
51.464
52.913
54.240
60.62
64.72
68.64
72.39
75.99
79.45
70.40
71.18
71.95
72.77
73.66
74.66
-856.689
-855.860
-855.021
-854.159
-853.270
-852.333
-647.293
-628.280
-609.360
-590.497
-571.690
-552.957
106.60
112.76
118.49
123.85
128.90
133.69
2.092
MELTING POINT
8 0 1 1 1 1 6 POINT
ENTHALPY OF BELTING
kJ
ENTHALPI Oq VAPORLZATION
kJ
MOLAR VOLUIE
~0298-
Hi
140.653
2.134
0.374
102.222
79.725
64.734
54.035
46.017
39.786
34.807
30.738
27.348
24.484
22.032
19.908
18.052
kJ
TRAUSITIOUS LU REFERENCE STATE ELEIENTS

SILICON....
I.
P.
___________________________________--__-_--------------------K
IELTING POINT
BOILING POINT
ENTHALPY OF BELTING
kJ
EUTHALPY OF VAPOBIZATIOU
kJ
MOLAR VOLUME
TBAISITIONS I N REFERENCE STATE ELEIEYTS
1 6 8 5 K.
SILIcOu
298
285
101
P.
1 6 8 5 K.
74.639
7.2594110-3
T
+ 5.5704110- T2
298
1 5 0 0 K)
3.1140110*
T-Z
1 8 0 0 K)
................................................................................
REFERENCE
.... n.
C:
-2.83391105
T-*
kJ
101
REZERENCE
COBPILED
7-16-76
52
240
285
27 8
148
284
COBPILED
6 - 8-76
THEBEODXYAEIC PBOPEBTIES OF EIYBBALS
222
SAIIARlUH SESPUIOXIDE (HOYOCLIUIC)

.-.. .-. .-. . .-. .-. .-.-. .-. .-.. .-. .-. .-.. .-. .-.. .-. .-. .-.. .-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Sm,O,:
t o 1 1 9 5 K.
PORHULA WEIGHT
348.798
B e t a c r y s t a l s 1 1 9 5 t o 1 8 0 0 K.
r
1
PPOPEBTIES
AT HIGH TEEPBBATURES
POBHULA YEIGHT
SAHARIUE SESQOIOXXDE ( CUBIC )
----
348.798
_-_=____E_====-=====I====_======----
sn20.:
C r y s t a l s 298.15
t o 1 1 0 0 K.
---TEnP-
(n$-~;y8)/~
J/.0l.K
298.15
0.000
UYCEBTAIUTY
S;
-(G~-H;~~)/T
J/.0l.K
J/.0l.K
151.04
4-20
151.04
4.26
C;
FOBEATIOU PBOH THE ELEHEUTS

GIBBS
EUTHALPI
FREE ENEBGY
l o g Kf
J/mol-K
kJ/.ol
kJ/.0l
113.36
-1822.970
2.010
-1796.690
2.020
SOT
TEHp.
( H$-H;~~)/T
s~~~
- ( G $ - H ~ ~ ~ ) / T C:
POBEATIOU PROH THE ELEHEYTS

GIBBS
FREE E U E B G Y
LO^
ENTHALPY
314.774
0.354
................................................................................
-------_---_----------------------------------------------------------------
MELT1 NG P O I I T
BOILING POINT
BELTING POINT
BOILIUG POINT
EUTHALPY OF MELTING
kJ
kJ
EYTHALPY OF HELTIUG
EYTHALPX OF VAPORIZATIOU
kJ
kJ
H O L A ~VOLUIE
kJ
BOLA8 VOLUBE
- Hi
':98
21.004
4 9 8
H:
TBANSITIONs I l l BEPEBEUCE STATE ELEIlEYTS
TBAYSITIOUS I U REFBBEUCE STATE ELEHEUTS
SAHABIUH...
ALPHA-BETA
1190.
H.
HEAT CAPACITX EQUATIOBS
C;
C;
1 . 2 8 4 1 ~ 1 0 2 + 2.0545110-2
(EQUATIOY VALID FROB
T
298
1.8827r10*
1 1 9 5 K)
T-2
1.2365~10-2 T
1.3702~102 +
(EQUATIOU VALID FBOH 2 9 8
~EPEBENCE 193
BEFEREUCE
210
235
235
COHPILED
5-18-76
P.
1 3 4 5 K.
2.5189rlO*
1100 K )
T-2
COHPILED
9-28-76
THEBIODIYAMIC PROPERTIES OP MIYEBALS

CISSITEBITE
FORMULA UEIGHT
150.689
*====I============----_=================
===X===5====I===========e=E=L-==El
Sno,:
C r y s t a l s 298.15
TEUP.
t o a e l t i n g p o l n t 1903 K.
SOT
(tl;-nZg8)/~
-(G;-H;~~)/T
C:
FOBIATION FRO1 THE ELEMENTS

ENTHALPY
F R E GE I EBBS
NERGY
LO^ K~
_ _ _ _ _
kJ/mol
kJ/eol
52-59
-580.740
-519.902
91.085
0.628
0.753
0.132
J/eolSK
J/mol. K
298- 15
0.000
UNCERTAINTY
52-30
1.25
52-30
69.57
84-54
54.52
59.07
64-03
69.82
-------------_------------------------------1.25
U00
500
15.050
25.468
600
700
800
900
1000
33.185
39.144
43.912
47.844
51.160
97.62
109.16
119.48
128.81
137.35
64.43
70.02
75.57
80.97
86.19
1100
1200
1300
1400
1500
54.018
56.524
58.753
60.764
62.589
145.22
152.53
159.38
165.81
171.90
91.20
96.01
100.63
105.05
109.31
HELTIYG POINT
1903
ENTHALPY OF HELTING
498
-580.585
-579.910
-499.109
-478.820
65.177
50.022
73.50
76.18
78.34
80.18
81-83
.. H.
P.
-585.837
-584.465
-582.914
-581.225
-579.426
-457.383
-436.079
-414.986
-394.088
-373.396
39.819
32.541
27.096
22.872
19.504
83.36
84.81
86.19
87.53
88.84
-577.519
-575.508
-573.393
-571.170
-568.852
-352.888
-332.544
-312.392
-292.388
-272.557
16.757
14.475
12.552
10.909
9.491
BOILING POIYT
kJ
REPEBENCE
11 5
GIBBS
TEIp.
120
( H:-H;98)/~
s;
-(G:-H;~~)/T
C;
EYTBALPI
PPEE E Y E R G I
kJ
MOLAR VOLUME
298.15
0.000
UYCEBTAI YTI
55.52
0.42
2.1550
21.550
2938
RELTIYG POIIT
kJ
EYTBALPY OF UELTIYG
J/bar
G98
ca3
55.52
0.42
45.41
-590.490
0.920
-560.353
0.930
BOILIYG POIYT
-4
75.300
kJ
EYTHALPI OF VAPORIZATIOI
kJ
8.673 kJ
MOLAR VOLOIE
2.0686
20.686
TBAYSITIOYS I Y PEFEPEYCE STATE ELEMEYTS

STBOYTIUI..
ALPHA-GAIIA 828,
11.
P.
GMIA 1041.
1.5122110'
T-0"
1800 K)
B.
P.
1652 K.
2.7805110S
HEAT CAPACITI EQUATION
298
mg K~
K
~ / a o l .K
J/sol- K
J/mol- K
J/eol- K
kJ/mol
kJ/mol
____________________________-------------_--------------------------_----
5 0 5 K.
72.158 +
1.1726110-2
T
(EQUATIOY VALID FBOU
t o 1800 K.
_____________________________________________________-_-WBIATIOU FPOI THE ELEMEYSS
BEAT CAPACITY EQUATIOY
C;
C r y s t a l s 298.15
103.619
98.172
0.163
---------_-----_----------------
TRAYSITIONS I N REFERENCE SThTE ELEHEYTS

TIM......
STBOYTIOM OXIDE
?ORllULA YEICBF
LIPS=II*====IIICIP*P===P-===-=P===-=~Y--=s=====Y=======l.*=-*=T=i.-I==siZ-.:
S~O:
J/mol- K
J/mol-K
2.0502110.
T-2
1500 K)
C:
262
COIPILED
55.667 + 5.4617110-1
T
(EQUATIOY VALID FBOM
298
T-2
Jce3
/bar
226
THERllODXYAM~PPOPEPTIES 0 1 IIIPEPALS
DITAUTALOII PEUTOXIDE (BETA)
PsOpLBTIlS AT BICE TMPBPATUBBS
POBIIULA UEIGHT
Ta,O,:
C r y s t a l s 298.15
TEMP-
441.893
-------------
........................................................
t o 1800 K .
(H;-H;~~)/T
Tb,03:
-(G%H;~~)/T
C;
POBIIATION FRO8 THE ELEIIEYTS

GIBES
EYTHALPY
FREE EUERGY
L o g K~
J/mOlaK
J/molsK
J/mol-K
298.15
0.000
UNCERTAINTY
143.13
1.26
143.13
1.26
135.03
-2045.976
4.184
-1910.984
4.200
334.798
0.736
400
500
60 0
700
800
900
1000
36.425
59.960
76.878
89.760
99.987
108.378
115.435
185.06
219.41
248.84
274.58
297.48
318.15
337.00
148.63
159.45
171.96
184.82
197.49
209.77
221.57
149.51
158.20
164.48
169.45
173.63
177.29
180.58
-2044.204
-2041.680
-2038.723
-2035.483
-2032.029
-2028.397
-2024.610
-1865.110
-1820.620
-1776.682
-1733.265
-1690.313
-1647.805
-1605.720
1100
1200
1300
1400
1500
1600
1700
1800
121.496
126.792
131.483
135.693
139.505
142.992
146.207
149.191
354.36
370.45
385.48
399.59
412.90
425.50
437.48
448.90
232.86
243.66
254.00
263.90
273.39
282.51
291.27
299.71
183.61
186.44
189.12
191.67
194.12
196.49
198.79
201.03
-2020.684
-2016.633
-2012.458
-2008.171
-2003.778
-1999.284
-1994.692
-1990.012
-1564.030
-1522.671
-1481.694
-1441.017
-1400.658
-1360.620
-1320.838
-1201.334
POEIIOLA WEIGHT 365.849

TEBBIUll SBSQUXOXIDE (CUBIC)
===5======___===__==ID=S=~-~===========~I=E1===L?===========~=============
J/m01-K
kJ/mol
kJ/m01
C r y s t a l s 298.15
t o l a 0 0 K.
FOBIIATIOY ?Boll GIBBS

THE ELEIIEUTS
TEfip-
(H;-II;~~)/T
J/mol.K
- ( G ; - B ~ ~ ~ ) / TC;
S;
J/mol- K
EYTHALPI
kJ/mol
PEEE ENEBGI
LO^
J/mol- K
J/mol- K
298.15
0.000
uUCEBTAINTY
156.90
4.20
156.90
4.20
127.27
-1865.230
8.370
-1776.553
8.400
311.246
1.472
243.559
190.200
154.675
129.338
110.367
95.637
83.875
400
500
600
700
800
900
1000
30.725
49.850
63.168
73.073
80.819
87.122
92.405
192.31
220.48
244.13
264.55
282.58
298.77
313.52
161.58
170.63
180.96
191.48
201.76
211.65
221.12
124.12
128.21
131.19
133.79
136.27
138.75
141.25
-1863.256
-1860.889
-1858.521
-1856.269
-1854.173
-1852.237
-1850.472
-1746.554
-1717.634
-1689.204
-1661.172
-1633.441
-1605.961
-1578.702
228.078
179.441
147.059
123.959
106.653
93.208
82.463
74.270
66.280
59.535
53.765
48.775
44.420
40.585
37.184
11 00
1200
1300
1400
1500
96.961
100.972
104.567
107.836
110.855
327.10
339.73
351.55
362.69
373.25
230.14
238.76
246.98
254.85
262.39
143.80
146.39
149.04
151.72
154.45
-1848.857
-1847.389
-1846.054
-1844.857
-1843.761
-1551.593
-1524.655
-1497.797
-1471.071
-1444.386
73.679
66.367
60.183
54.887
50.298
1600
113.666
383.31
269.64
157.21
1700
1800
116.310
118.816
392.92
402.15
276.61
283.33
160.01
162.84
-1851.521
-1417.465
46.276
................................
-1871 .000
-1869.729
-1389.430
-1361.053
42.692
39.497
IIELTIUG POINT
2058
BOILIYG POINT
BELTING POINT
BOILIBG POINT
ENTHALPY OF BELTING
120.100
kJ
kJ
ENTHALPY OF IIELTING
kJ
kJ
23.041
kJ
HOLAR VOLUBE
kJ
IOLAR VOLUUE
498
5.3170 J / b a r
53.170
cn3
498
- HE
TRANSITIONS I N REFERENCE STATE ELEIIEUTS
TRAISITIOUS I N BEPEBEUCE STATE ELEMENTS
C;
1.8972~102 + 1.6639~10-2 T
(EQUATION VALID PROU 298
BEPEREUCE
33
189
33
7.73771102
1800 K)
T-0.5
33
K~
kJ/.0l
1 . 1 0 9 0 ~ 1 0 6 T-Z
CONPILED
6- 2-76
REFERENCE
200
28 1
235
COHPILED
8-18-76
-p
TERBIUM OXIDE
POPEULA YEIGHT
- -
................................................................
TbO,.,,.:
c r y s t a l s 298.15
TEnP.
( ~;-8;g8)/~
J/eol*K
--==
t o 1000 K.
S;
-(G;-B;~~)/T
C;
J/mol- K
J/mol. K
80.75
4.20
80.75
57.37
4.20
POPIATION F P O I THE ELEIENTS

GIBBS
ENTHALPI
?BEE E l E P G I
L o g K~
kJ/mol
kJ/mol
-953.950
4.180
-938.980
4.200
BOILIYG POINT
ENTHALPY OF RELTING
kJ
kJ
kJ
EOLAB VOLUEE
J/bar
TRAUSITIONS I N PEPERENCE STATE ELEIENTS

TERBIUE..
..ALPHA-BETA
1560.
1. P.
53.269
2.6629~10-2
C r y s t a l s 290.15
t o
9 0 0 K.
?OPIATION
TEIP.
(H;-R;~~)/T
S;
-(4-8:98)/~
C;
EYTHUPI
?ROE THE ELEIENTS

G I BBS
?BEE ENEPGY
L o g Kf
IIELTING POINT
BOILING P O I l T
EYTUALPY OF E E L T I l G
kJ
EYTHALPY OF V I P O R I Z I T I O N
kJ
EOLAR VOLOIE
J/bar
'0298
BOO
kJ
TBAYSITIOYS I N BEFBBEUCE STATE ELEEEYTS
1 6 3 0 K.
TERBIUE....ALP8A-BETA
HEBT CAPACITY EQUATION
C;
229
r .Z
~ ~HIGH
s TSIIPEUAT O I E S
164.506
0.736
IELTIUG POINT
4 9 8
T S P B I ( I l l OXIDE
FOPIDLA WEIGHT 1 8 7 . 9 1 6
=~L==0~~~=E=======LI-'P==-=1I-=====l~===--=sLC13C=.2======s5ii====~=============
~bo,-.~,:
J/mol- K
298.15
0.000
UNCERTAINTY
186.348
1560.
I- P.
1 6 3 0 K.
HEAT CAPACITI EQUATIOY
2 9 8 - 1 0 0 0 K)
................................................................................
REFERENCE
200
281
235
COEPILED
8-18-76
C8O-I1P8I-L7E6D
PPOPBPTIBS AT HIGH TLIPEPATUPES

THORXAUITE
FOBHULA YEIGHT
....................................
Tho,:
264.037
-----------===5_===_=23======_1=====_====_===========
C r y s t a l s 298.15
~ I T A t i 1 0 1OXIDE
t o 1200 K.
T~O:
TEMPK
(nG-H0298)~
-(G;H;~~)/T
S;
J/mol-K
J/mol-K
298.15
0.000
OYCEBTAINTI
65.23
0.21
C;
J/~ol-K
J/mol-K
kJ/mol
65.23
0.21
61-76
-1226.410
3493
ENTHALPY OP MELTING
~ i 9 8- 8;
10.562
~1
204.765
3.510
0.615
80ILIUG POI YT
POBMATIOU PROM THE ELEMENTS

GIBBS
K.
kJ/.Ol
-1168.775
~ ~ n p .( M ~ - H ; ~ ~ ) / T 5;
EYTHALPI OF VAPOBIZATION
kJ
MOLAR VOLUHE
kJ
2.6373
ALPHA-BETA
1636.
1. P.
C;
EUTHALPY
FREE EUEBCY
l o g Kf
-----------------2023
HELTIYG POINT
J/bar
EUTHALPY OF ?!ELTING
26.373

THOBIUM....
-(G;-B;~~)/T
kJ
63.899
B e t a c r y s t a l s 1 2 6 5 to 1 8 0 0 K.
t o 1 2 6 5 K.
POBMATIOU PPOR THE ELEMEUTS

GIBBS
EUTBALPY
FREE
ENERGY
Lo.
3.510
MELTING POINT
FOPRULA YEIGHT
-=P==___=_=__==~==_~===~==-================Si=====l======
_I==_===_-_=-------
4 1 . 8 0 0 kJ
BOILIYG POINT
kJ
cm3
'0295
BETA 2 0 2 8 K.
MOLAR VOLUIIE
kJ
TBANSITlONS I N BEPEHElCE STATE ELEMENTS

TITANIUH...
ALPHA-BETA
1 1 5 5 , fl.
P.
1 9 4 3 K.
HEAT CAPACITY EUUATIOU
C;
71..373 + 7 . 5 5 6 3 ~ 1 0 - 3 T
EEPERENCE
260
240
215
298
1.0529~10.
T-I
HEAr I A P A L LTY EQUATIONS
1200 K )
215
COlPILED
-.
._
_ .
REPI:I:EHCE
--------------------
___.__
176
J3
33
COMPILED
8-11-76
232
TEIP.
C r y s t a l s 298.15
( H ; - H : ~ ~)/T
J/mol.K
298.15
0.000
UICEBTAINTI
MBIULA YEIGRT
- ( G ; - E ~ ~ ~ ) / T C;
J/mol-K
J/mOl.
50.29
0.17
2103
ENTHALPY OF IELTING
~ ; s e-
8.669
50.29
ALPHA-BETA
J/mol- K
kJ/mol
kJ/aol
55.10
-944.750
-889.446
1.260
BOILIUG POINT
kJ
ENTHALPX OP VAPOBIZATION
k.l
noLAR voLunE
1.8820
18.820
1. P.
63.079 t
1.1307110-2
T
(EQUATION VAL10 FRO1
FORHATION FROB THE ELEHENTS

GIBBS
( H ; - H ~ ~ ~ ) / Ts t
-(G;-H&~)/T
C;
ENTHALPY
LO^ K~
FREE ENERGY
0.180
NELTING POINT
BOILING POINT
EYTHALPY OF nELTINC
kJ
EITHALPY OP VAPORIZATION
kJ
kJ
J/bar
cm3
Hi98
kJ
IOLAR VOLUIE
H;
2.0520
20.520
J/bar
cm3
TBANSITIOBS I N REPERENCE STATE ELEIEUTS
1 9 4 3 K.
TITAUIUU.
t o 1300 K .
155.828
1.030
79.899
I _ _ _ _ _ - = --_
- -_- _
- -_- =
_ _ - _....................................................................
_
FORIATION ?ROB THE ELEIEYTS

ENTHALPX
F R EGIBBS
E EUEBGI
LO^ K~
0.17
1155.
FORMULA WEIGHT
__ _ _ _
ANATASE
~ i o ~ C
: r y s t a l s 298.15
TRANSITIONS I N REPERENCE STATE ELBIENTS

TITANIUI...
79.899
S;
IELTING POINT
C;
PROPERTIES A T l i l t i n r s a r m r r & u r r =
RUTILE
====E===========E~===========
Tio,:
TUBBIODIIAIIC P R O P I P T I I S O? IIllEBALS
.. hLPHA-BETA
1 1 5 5 , U.
P.
1 9 4 3 K-
298
5.6160 T-O.5
- 1800 K )
9.86261105
T-2
C;
43.961
+ 1.3738110-2
T + 6.2937110'
1300 K )
(EQUATION VALID PBOI! 2 9 8
~EFERENcJ!
176
33
T-0.3
2.5953110*
33
T-2
COIPILED
6-14-76
-..-
TRERIODINAIIC PROPEETIES OF MINERALS
DITITAUIUM TBIOXIDE
Tl,O,:
133
P P O P ~ P T I ~ SAT H I 6 8 TEMPERATUPLS
FOBIULA WEIGHT
A l p h a c r y s t a l s 298. 15 t o 4 7 0 K.
143.798
B e t a c r y s t a l s 4 7 0 t o 1 8 0 0 K.
FOR8ULA WEIGHT
223.697
T~~TITANIUM
PEYTOXIDE (ALPBA)
Tilo.:
B e t a c r l s t a l s 4 5 0 t o 1 8 0 0 K.
t o 4 5 0 K.
................................................................................
( H ~ - H ; )/T
~ ~
TE~P.
-( G ; - H ; ~ ~ ) / T
S;
C;
J/mol- K
J/mol-K
J/aol-K
PORIIATION FROM TBE ELEMENTS

GIBBS
FORIATION PRO8 THE ELEHENTS

GIBBS
ENTHALPY
FREE
ENERGY
Log K,
J/aol. K
TEIp.
( H ; - H ~ ~ ~ ) / T S;
-(G;-H;~~)/T
C:
ENTBALPY
PBEE E N E R G Y
LO^ K~
kJ/mol
kJ/mol
298.15
0.000
UNCERTAI NTY
8ELTING POINT
2115
EUTBALPY OF 8ELTIBG
G98
77.25
0.21
H:
104.600
14.088
77.25
0.21
95.81
-1520.884
8.368
-1433.903
8.370
251.215
1.466
BOILLUG POINT
kJ
MELTING POINT
2050
BOILIYG POINT
kJ
ENTHALPI OF HELTIYG
172.000
kJ
EYTBALPY OF VAPOBIZATION
kJ
MOLAR VOLUME
EYTHALPY OP YAPORIZATIUN
kJ
MOLAR VOLU8E
kJ
3.1430
31.430
TRANSITIONS I N RMEREYCE STATE ELElENTS
J/bar
cm3
H;gn
H:
5.2690
52.690
J/bar
ca3

TITANIU8...
ALPHA-BETA
1155.
C.
P.
1943 KTITANIUM...
ALPHA-BETA
1155.
8.
P-
1 9 4 3 K-
HEAT CAPACITY EYUATION

C;
1 - 4 8 6 1 ~ 1 0+~ 3 . L 8 6 1 ~ 1 0 - 3 T 27.0~6
(EQUATION VALID FRO8 4 7 U - I d 0 0 K )
REFEREUCE
33
176
33
Y C . 5
Q.bd81r10L
T-z
C; =
J3
CunpILED
2.2034~102 1 . 0 5 0 7 ~ 1 0 7 T-'
450
(EQUATIOU VALID PBOM
REFERENCE
176
33
1 8 0 0 K)
33
COMPILED
8-17-76
-- -
rmJ=aoDrTXMtC
TETRATITANIU8 HEPTOXIDE
---------.....................................
T1.0,:
C r y s t a l s 298.15
-.PROPEBTIES
PROPERTIES OF MINERALS
PORlULA WEIGHT
........................................
J/mO1-K
298-15
O.OoO
UUCERTUUTy
a00
500
C;
J/mol-K
J/mol-K
198-74
198.74
12.00
12.00
57*65U
96-214
124-345
145-864
265.05
320-86
600
700
u49-21
483-14
looO
162-929
176-844
188-435
'loo
198-272
"0
13"
1400
15"
1600
1700
1800
~ l p h ac r y s t a l s 298.15
513-99
207-40
224-65
244.80
265.66
286.28
306.30
325-56
240.78
258.73
270.54
279.02
285.48
290.61
294.82
542-26
343.99
298.36
411-52
568-35
592.58
615-20
636-U0
656-37
675-22
693-10
206-742
214.125
220-629
226-413
231-594
236.271
240-516
208.49
361-61
378-46
394.57
409.99
42u-78
438.95
452.58
301.38
304.01
306.33
308.39
310.24
311.91
313.94
kJ/mol
~
GIBBS
-3402.516
-3398.949
-3394-675
-3390.109
-3385.465
-3380.869
-3376.418
-3148.030
411.092
-308U.~14
322.270
- 3 0 2 2 . ~ ~ 263-122
~
-2960-687
f20.930
-2ggg-653
189.32g
-2839.168
164.782
- 2 ~ 7 9 . ~145.173
~ ~
-3372.161
-3384.347
-3378.715
-3373.389
-3368.349
-3363.622
-3359.215
-3355.142
aOO
30.125
500
6oo
48.830
78.642
8U.U33
89.135
129.150
-2719.729
--_---__
~/mol-K
~/.ol-K
kJ/mol
139.75
112.88
0.85
0.85
-1888.660
0.850
-1794.446
0.850
314'381
0.149
174.29
201.87
22~.g5
244.76
262.09
277.49
291.34
194.16
153.OU
163.15
173.42
183.45
193.06
202.20
121.43
125.43
127.73
129.23
130.30
131.13
131.80
-1886.596
-1884.107
-1881.666
-1879.363
-1877.2'8
-1875.307
-1873.558
-1762-492
-1731-767
-1701.525
-1671.687
-1C42-162
-1612.885
230-159
180.917
148.132
124.743
-1583.828
82.731
303.93
315.47
326.12
336.02
345.26
353-93
210.89
219.13
226.95
231.40
241.49
248.25
132.37
132.87
133.32
133-73
134.12
134.49
-1871.993
-1870.600
-1869-366
-1868.287
-1867.351
-1866.553
-1554-9U0
-1526-170
-1u97-514
-1468.979
-1440.481
73.838
66-433
60.171
54.809
50-162
-1412.049
46.099
93.039
96.337
- 2 6 ~ 9 . ~ ~ ~
-2599.843
-2540.137
94.774
-2480.769
86.388
99.165
101.621
03.774
105.682
1400
1500
1600
- 2 ~ 2 1 . ~ 79.064
~ ~
-2363-0g2
72.609
-2304.572
66.877
Log
EUTHALPY
139.75
J/.o~.K
61.803
,I.336
900
100o
- ( G ; - H ~ ~ ~ ) / T C:
S;
_ J/mol.K
____---- o.OOo
562.936
1.100
-3213.166
6.280
(H;-H;98),T
TEIIP-
-340q.520
6.280
eta c r y s t a l s 1680 t o 1800 K -
t o 1680 K -
~ O R M A T I O YPROM THE ELEMENTS
PORflATIONPRO8 T H E ELE~ENTs
GIBRS
E N ~ R G y Log
ENTHALPy
J/rnol-K
385-867
f g ~ SESQUIOXIDE
~ ~ ~ n
t o 1800 K.
';
(x;-n;98vr
237
F O R M U L A WEIGHT
303.596
T,zO,:
"-
AT H I G H TEMPERATURES
k~/mol
93-610
-------------------------------------------------------------------------------BELTING POINT
1950
ENTHALPY OF EELTING
226.000
k~
~ z 9 8-
WILING POIUT
HELTIUG POIUT
EYTHALPY 0 1 V A P O B I Z A T I O N
kJ
EITBALPY OF MELTING
BOLA8 VOLOlE
TITAulu~--.
UPHA-BETA 1155, 8.
p.
TBAYSITIONSI U
l g q j KTHULIUM...
HEIT CAPACITY EQUATIOU
c;
5-2682110-.
T
(EQoATIOU VALID FROB 298
3-6004x102
BEPEBEUCE
33
33
1.973911()3
1800 I)
BOILING POIIT
kJ
E N T ~ A L P XOF VAPOBIZATIOU
20.878 kJ
TRANSITIOuSI N REFERENCE STATE ELEMENTS
T-O-s
3.3236r10.
T-z
COMPILED
kJ
4.3420
43.420
MOLAH VOLU8E
J/bar
cm3
.. M -
P- 1818 K -
BEAT CAPACITI EQUATIOM
C;
___
33
- 1.6528110. Tm2
- 1600 K ,
_------________________________---_---------------------------
1.3063x10z + 2.8191110-3 T
(EQUATI01 VALID PROM 298
REPEREUCE 207
235
235
.............................................................................
COllPIZED
5-19-76
238
THERIODYUAUIC PROPERTIES OP UINERALS
URANIUITE
FORUULA WEIGHT
...............................................................................
270.028
P ~ P E R T I E SAT HIGH TEIPERATUBES

PORUULA WEIGHT
TRIOXIDE ( GAIHA)
,IRANIUH
--------_-----__--_----_----_-___--__-_-____--------------------------------a
286.027
__======C==_========L====_=_I================~====~=================================
-UO.:
C r y s t a l s 298.15
t o 1 8 0 0 K.
T - ~ ~ , :
C r y s t a l s 298.15 t o
900 K .
_________-_______-_-------------( H ; - H ; ~ ~ )/T
TEUP.
J/mol.K
S;
-(G;-H&~)/T
J/mol-K
J/nolaK
77.03
0.24
77.03
0.24
C;
FORBATIOI
FORBATIOU PEOH THE ELEUENTS

GIBBS
ENTHALPY
FREE ENERGY
Loy K~
J/mol-K
kJ/nol
EUTHALPY
PBon T H E E L E U E N T S
GIBES
FREE ENERGY
Log K f
kJ/mol
_-----_--_--------_----------------------------------------------------------298.15
0.000
UNCEBTAINTY
EXTHALPY OF MELTING
63.60
-1084.910
1.000
-1031.770
1.000
--
180.763
0.175
ENTHALPY OF VAPOIIIZATION
~ ; 9 8 - H:
kJ
UOLAE VOLUHE
ALPHA-BETA 9 4 1 ,
BETA-GABHA
58.454 +
1.6057110-2
T
(EQUATION VAL10 FROB
REPBBENCE
77
60
110
215
+
298
I!
BOILING POINT
ENTHALPY OF IEI.TING
kc
EUTBALPi OY VAPORIZATIOU
k -1
POLAR J k i i . U 5 B
...
1048.
....
1 4 0 5 K.
1. 9.
URAUIU~
3 . 6 8 8 9 ~ 1 0 2 T-0.5
- 1800 K )
1 - b 6 7 2 x 1 0 6 T-2
u1
215
................................................................................
COBPILED
7-21-76
ALPHA
HL;A
HEAT CAPACITY EdUATiON
94:.
"A
b 2 ~ n1043.
~
8.
kJ
3.5560
35.560
TRANSITIONS I N KEPE#PNIE <TATF Z i EI%F\:',
C;
..
IIELTING POINT
';98
TKAUSITIOUS I N REFERENCE STATE ELEIIENTS

URANIUH....
_ - _ _ _ _ _ _ _ _ _-.__
_
P.
1 4 0 5 K.
J/bar
cm'
--------_-_-__-____-----TEIP-
( H ; - H ~)IT~ ~
J/mol.K
S;
-( G ; - H ; ~ ~ ) / T
2g8-15
0-000
UNCERTAINTY
J/mol. K
J/nol-K
J/mOl'K
39-01
0.85
c;
39-01
0.85
PORIATION PROR THE ELEIENTS

G I BBS
ENTHALPY
P E E E R G
LO,
kj/mol
kJ/mol
45.50
-431.790
-qoq_2lg
6.280
BELTING POINT
2063
H H g 8 , T
K~
s;
';98
54.400
kJ
kJ
IOLAR VOLOIE
1.0260
10.260
ENEPG'
Kf
"9
1.100
kJ
J/bar
EWTHALPI OP BELTING
'0298
TRANSITIONS I N PEFEEENCE STATE ELEnENTS
ENTHALPY
70.81~
BELTIWG POINT
ENTHALPY OP NELTING
FOBIATIOI FRO1 TBE ELEIIEMTS

GIBES
- ( - H ~ ~ ) TC:
----------_----________
BOILING POINT
6.280
_________-___-_--
cm3
-4
8OlLIUG POINT
kJ
EMTHALPI OF VAPORIZATION
kJ
BOLAR V O L U I E
kJ
2.9850
29.850
J/bar
cm3
TRAYSITIONS I N REPEBEUCE STATE ELENENTS

VANADIUI...
I - P.
2175 K .

C:
55.932 +
- 2 5 x 0 T
REFERENCE
115
191
298
S . ~ ~ S I X I O TZ- 0 . 5
l.807gxlo,
T-r
Ci =
1800 K )
33
33
COIPILED
6- 2-76
5 7 . 9 8 9 + 4.1200110-2
T
BEPEREMCE
__
38
33
298
1 . 3 5 1 0 ~ 1 0 ~T-0.9
- 1 8 0 0 K)
3 . 8 7 1 8 ~ 1 0 T-'
~
33
COlPILED
6-21-76
2UZ
TBERIODIIAIIC PPOPEBfIES
O F NIYEBALS
P P O p E I r I E S AT HIGH TBNPERATURES
DIVA WADI U I TETBOXIDE

D L ~ ~ # ~ D PENTOXIDE
I U I
V,O.:
C r y s t a l s 298.15
FOBNATION P B o n T H E ELENENTS
( H ; - H ~ )/T
~ ~
C r y s t a l s 298.15
S;
-(G;-B;~~)/T
ENTBALPY
C;
GIBBS
FREE ENERGY
_----_________
J/mol-K
J/molSK
J/aol-K
298.15
0.000
UNCERTAINTY
103.52
2.09
103.52
2.09
------------------- ---------- ---- --
J/aol-K
kJ/mol
115.40
_ _ _-- . _
-1427.162
6.276
____
_.
__
L i q u i d 9 4 3 t o 1 8 0 0 K.
______________-----------____-_-__---__-__---------------------FOBNATIOY FROB THE ELENEYTS

GIBHS
( H > H ~ ~ ~ ) / T S:
-(G;-B:~~)/T
C;
ENTHALPY
FREE EUERGI
l o g K*
kJ/mol
- 1 3 18.457
6.500
230.989
1.139
.__
BELTING P O I N T
1818
B O I L 1 NG P O I HT
ENTHALPY O F BELTING
112.068
kJ
18.100
kJ
BOLA@ VOLUnb
4 9 8 -
L o g K~
+Enp.
181.880
t o 1 6 0 0 K.
v,O,:
TEHP-
FORNULA YEIGBT
T R A N S I T I O N S I N REPEREYCE STATE ELEBENP5
I.
VANADIUH...
P.
2 1 7 5 K.
HELTXUG POINT
943
BOILING P O I N T
EUTHALPY O F BELTING
64.520
kJ
21.506
kJ
HOLAB VOLUHE
kJ
HEAT CAPACITY EQUATIOY

TRANSITIONS
C;
2.0206~102 1 . 1 3 4 3 ~ 1 0 - ~T
1 . 2 2 7 0 ~ 1 0 ' T-0.5
1600 K )
In
REFERENCE STATE ELEBENTS
9 . 6 2 5 4 ~ 1 0 s T-2
-------------------------------~-~-....__..I_.~~.__~..__-~._~_~~-____~_I~._~__~__~~_~~_~~~
BEFERENCE
38
33
li
COBPILED
C;
1.3449~102 t 4.9532~10-2 T
9 4 3 K)
_____-_____________----------------------------------------C O B P I L E D
REFERENCE
837
710
710
6-
7-76
- .-
244
O PROPERTIES
D ~ ~ ~
Or
~ ~
alIEPALS
~
TUUGSTEY DIOXIDE
Pol~fluLAW ~ I G H T 215.gy9
C r y s t a l s 298.15
( H;-H:~~)/T
J/mOl-
S;
J/mol-K
J/mol- K
50.53
0.29
50-53
0.29
298.15
0.000
UNCEBTAINTI
~ O R I U L A WEIGHT
POR8ATIOY FROB THE ELBIBITS

GIBES
EYTBALPI
C:
J/mol.
7
-589.690
0.880
crlstals
o.-tho=ho.bic
cI,stals
(monocllnic)
1050 K.
Tetragonal
crlstbis 1050 t o = e l t r n g point 1745 K -
298.15
t o 5 9 3 K.
_______________-__---____----
_________
- ( G ~ H ; ~ ~ ) / TC;
I;
,gap.
k ~y.01
231-848
T ~ n ~ ~ TTRIOXIDE
E N
t o l e O OK.
------ --
TEIP-
245
P H ) ~ ~ ~ I AT
E SBIGB TIIIPEnATfJRES
FORIATIOU PRO8 THE ELEIEITS

GIBBS
----
ETHALP
FREE EnERG1
LOg 'f
H B 9 8 T
kJ/.ol
---------__-__
----__
-533.858
0.960
93 . ~ 3 ~
0.16~
--------------
K
1745
IELTIYG POINT
BYTHALPI OF BELTING
OELTING POINT
BOILIYG POINT
IOLAR VOLUIE
kJ
1997
1.9920 J / b a r

TUNGSTEN...
I.
P.
80298
73.429
kJ
12.339
kJ
BOILIYG POINT
kJ
EYTBALPX OF VAPORIZATION
llOLAR VOLUIE
3.1610
31.610
J/bar
cm3
TRANSITIONS I N REFERENCE STATE ELtlIGYTS

19.920
cm3
TUNGSTEN...
I- P.
3680 K -
3 6 8 0 K.
HEAT CAPACITI EQUATIOMS

HEAT CAPACZTY EQUATIOS
C:
2.7572xlO2
+
REFERENCE
0.12311
2 . 4 6 1 6 ~ 1 0 6 T-2
140
298
3 . 9 6 8 5 ~ 1 0 - 5 Tz
3 - 7 0 3 8 x l 0 = T-0-5
1800 K)
--__________-_-__-------------
.............................................................
247
247
COIPILED
REFERENCE
140
247
247
COllPILED
8-12-76
247
THEWIODIIAIIIC P ~ O P E R T I E S OF IIIEEUS
L-O
PpgpsRTIES AT MIGH TEBPERATU8ES

PORIULA WEIGHT
" P l ' B I O I SESPOIOXIDE (CUBIC)

PORUULA YEIGHT
A l p l a ~ r ~ s t a 298.15
l s
t o 1330 K.
225.81
.eta
1330 to
18.0
K.
("-H:~~
)/T
t o 1365 K.
B e t a c r Y S t a U 13.5
______-------
-.
FORflATION PROl THE ELEBEUTS

GIBBS
A L P
FREEEMERGI
LogKI
~ i -)/T ~ C;i ~ ~
-(
S;
~ l ~ h~ .~ y s t . 298.15
1 ~
IbrO,:
------------TEIP.
394.078
~ T T E R B I U SESPOIOXIDE
I
(CUBIC)
SOT
(H:-H;~~)/T
to l a o 0 K -
PORUATIOU FRO8 THE ELEHEUTS

G I BBS
FREE ENERGY
LO9 K f
- ( G : - H ~ ~ ~ ~ ) / TC;
ENTHALPY
UMCEPTAINTI
400
500
600
700
800
900
1000
4.20
27.650
45-256
57.652
66-881
74-047
9 - 8 0
84*537
4.20
2.260
156-71
i78-31
197-35
213-94
2 - 7 5
242-15
103-26
11 1 - 4 5
120-86
130-47
139-89
148.95
157.61
112.95
117.97
121.09
123.31
125.05
126.52
127.81
-1904.246
-1902.782
-1901_211
-1899.151
-1898.156
-1896.745
-1895.432
-1786.448
-1757.172
-1728.186
-1699.472
-1670.992
-16
14.512
-1642.657
165-86
17-3-71
181.20
183-38
128.99
130.10
131.15
131.46
- 1894.221
-1893.114
-1892.109
-1586.470
-1558.536
-1130.709
7 ~ ~ 3
67.04~
61 -505
-1523.247
59.825
1100
1200
1300
1330
88-526
91-946
95-742
254-39
265-66
276- 12
279.12
1330
96.378
279-76
183.38
131.66
1400
1500
1700
98-143
100-378
12-333
104.058
286-51
295-59
304-09
312-07
8
195.21
201.76
208.01
131.66
131.66
131.66
131.66
1800
105-591
319.59
214.00
131.66
94-922
-1891.675
233.21
783.571
1(0.411
126.81~
log.los
84-33,,
95.338
EUTHALPX OP IELTISG
-1890.864
-1890.373
-1889-671
-1EB9.168
-1888.858
-1521.247
-1503.007
-1475.356
7 5 2
-1420.194
5 9 . ~ 5
56.078
51.377
47.264
43-637
-1921.256
-1392.308
40.404
...............................
BOILING POINT
kJ
HOLAR VOLUHE
TBANSITIONS I N REPIRENCB STATE ELEIEMTS

I!Pl"l'IUl--..
ALPHA-BETA
HEAT CAPACITY EQUAZIOUS
1752, I. p.
WELTING POINT
K
ENTHALPY OF BELTING
ElTHALPY OF VAPORIZATION
16.665 k J
-----I----__----_____
--- ----_-- ----------_----------------- ----------------------------------------nELTING POINT
kJ
4.4880
44.880
19.623
BOILING POINT
kJ
k~
MOLAR V O L U ~ E
J/bar
'0298
cm3
TRANSITIONS I N BEPERENCE STATE ELEHENTS

YTTERBIUB..
1799 K.
ALPHA-BETA 1033.
H.
P.
1097. 8.
kJ
4.2760
42.760
J/bar
cin3
P- 1465 K.
HEkT CAPACITY EQUATIONS
C;
1.3614~102 - 2.0174~10-3
T
298
(EQUATLOU VALID PROl
1.9928x106
K)
-- 1 3 6 5
T-2
COBPILED
------------ - _-_________________--+--------------------------------------------235
REFERENCE
210
264
REFERENCE
207
235
8-11-76
P W P ~ ~ T I SA
ST H I G H TEMPERATURES
2 1 IICI TE
PORUULA WEIGH?
81.379
........................................................................
BADDELEYITB
ZnO:
=to,:
C r y s t a l s 298.15
t o 1800 K.
---------------------------------------------_____
("-H&b."
5:
J/801mK
J/molsK
J/#ol.K
__-
POBUATIOY PBOU THE ELElEYTS

GIBBS
T L P
P B E E E U ~ G ~~
J/#ol.K
kJ/.ol
FOBMULA WEIGHT
n o n o c l i n i c c r y s t a l s 298.15
t o 1478 K.
123.219
T e t r a g o n a l c r y s t a l s 1478 t o
1800 K.
__----
F O B M A T I O B Puon T H E B L E ~ E N T S
GIBES
0
~
TEnp.
( H ~ - H ~ ~ ~ S;) / T - ( G ; - H ; ~ ~ ) / T
C;
EYTHALPP
FREE EUEBGY
l o g K~
-------------_-------------------------_---_--______________________
--------298.15
0-000
43.64
43.64
40.62
-350.460
56.146
UYCEBTAIUTY
0.40
0.40
0.270
kJ/80l
-320.477
0.300
0.053
3123
UELTIYG POIYT
EUTBALPY OP MELTIUG
-4
~998
6.933
kJ
EYTHALPI OF VAPORIZATION
kJ
MOLAR VOLUME
kJ
EUTBALPI OP MELTIUG
1.4338 J / b a r
14.338
TRANSITIOUS III REFERENCE STATE ELEMENTS
87.027
BOILING POIYT
kJ
EYTHALPI 0 1 VAPORIZATION
8.749 kJ
MOLAR VOLUME
cm3
TRANSITIOUS I N BEPEBENCE STATE ELEMENTS
ZINC.......
M.
P.
692.7.
6.
P.
1178 K.
ZIRCONIUM..
ALPHA-BETA
1136. M.
P.
2125 K -
HEAT CAPACITr EQUATIOY

C;
----------- -----------------------_-------------------------------------------BEPEBEUCE
11 5
120
-.
215
41
215
COMPILED
7-29-76
-----------------------------------------------------
90.700
4.3877110'
T-0.9
(EQUATION VALID PROM 298
BEPEHEUCE
43
264
8.1334~109
1478 K)
T-2
264
104
COMPILBD
6- 8-76
250
THEPLIODIIAIIC PBOPEBTIES OF MINERALS
TIALITE
.............................................................................
Al,TiO,:
TEIP-
c r y s t a l s 298.15
(H;-H;~~)/T
J/molsK
J/nol-K
298.15
0.000
UNCEBTAINTY
109.62
0.84
109.62
C;
POBBATION PBOI THE ELEIENTS

GIHHS
FREEENERGY
LogKF
ENTHALPY
J/mol-K
kJ/mol
136.40
-- -
---
BOILING POINT
ENTHALPY OP BELTING
kJ
kJ
IOLAB VOLUBE
H:
I.
P.
TITANIUH...
ALPHA-BETA
21
POBIATION PBOI THE ELEIENTS

G I BBS
TEIP.
120
(H:-H;~~)/T
-(G~-H&~)/T
S:
C;
FBEE E N E R G Y
ENTHALPY
~ o gK~
BELTING POINT
1510
BOILING POINT
EITHALPY OF MELTING
108.240
kJ
EMTHALPI OF VAPOBIZATIOU
kJ
25.422
kJ
IOLAB VOLUIE
kJ
4.8750
48.750
J/bar
cm3
G98
1155.
H.
P.
8;
TBANSITIOYS I I PEFBBENCE STATE ELEIENTS
9 3 3 K1 9 4 3 K.
2 . 1 1 1 0 ~ 1 0 ~t
1 . 4 6 0 9 ~ 1 0 - 2 T - 6 . 6 1 0 1 ~ 1 0 2 T-0.5
(EQUATION VALID FRO8 2 9 8 - 1 8 0 0 K )
BEPEBENCE
---
CALCIUI....
ALPHA-BETA 7 2 0 .
1. P.
BETA 1112.
IBOU.......
CUBIE P. 1 0 4 2 , ALPHA-GAMMA
I. P. DELTA 1 8 0 9 K.
1184.
8.
P.
1 7 5 5 K.
GALIIA-DELTA 1 6 6 5 .
C:
C r r s t a l s 298.15

ALUHINUI...
CALCIUI FEEBITE
POBIULA HEIGHT 2 1 5 . 7 7 2
1======1=5=_=-==__=============e~===========================================
0.84
kJ/mol
BELTING POINT
4 9 8
181.861
CaFe.0.:
-(G;-H;~~)/T
J/mol-K
PORBULA WEIGHT
t o 1800 K .
S;
251
PWPEBTIES AT HIGH TEIPEBATUBES
3 . 6 2 4 8 ~ 1 0 * T-2
COBPILED
C;
95.884 + 4.6664110-2
T
(EQUATION VALID PBOI
BEFEBENCE
183
214
+
1.40971103
T-0's
298 - 1510 K )
3 . 3 6 0 0 ~ 1 0 6 T-2
214
COBPILED
8 - 2-76
252
THERMODINAUIC PROPERTIES OF UIIJERALS
DICALCIUU FERRITE
------------------..........................................................................
Ca,Pe,O,:
C r y s t a l s 298.15
253
PORUULA WEIGHT
271.851
Alpha c r y s t a l s ( o r t h o r h o m b i c ) 298.15
1530 t o 1 8 0 0 K.
CaTiO,:
FORMULA YEIGHT
PEROVSKITE
................................................................................
t o 1 5 3 0 K.
135.978
Beta c r y s t a l s (cubic)
___________________------------------------------------------------------------PORUATIOU PROU THE ELEUENTS
( H;-H;~$
TEIP.
)IT
- ( G ~ - H ; ~ ~ ) / T C;
S!
FORUATION PROM THE ELEMENTS

GIBBS
ENTHALPY
FREE ENERGY
LO^ K~
FREE ENERGY
TEIP-
K
298.15
0.000
UNCERTAINTY
UELTING POINT
1750
BOILING POINT
ENTHALPY OP MELTING
151.080
kJ
31.648
L.J
~ O L A R VOLUUE
';go
J/mol.K
J/mol-K
298.15
0.000
UNCERTAINTY
93.64
0.42
K
kJ
UELTING POINT
2188
ENTHALPY OF BELTING

CALCIUU....
ALPHA-BETA
720.
1. P.
BETA 1 1 1 2 ,
IRON-----..
CURIE P. 1 0 4 2 . ALPHA-GAMMA
I. P. DELTA 1 8 0 9 K.
1184.
8.
P.
1 7 5 5 K.
GAMMA-DELTA
2 . 2 2 2 8 ~ 1 0 2 + 9 . 7 2 8 1 ~ 1 0 - ~T
(EQUATION VALID FROU 2 9 8
5 . 4 1 9 5 ~ 1 0 2 T-0.s
1 7 5 0 K)
5.6610110.
T-2
----------------------------------------------------------------------------REFERENCE
183
214
214
BOILING POIRT
kJ
kJ
UOLAR VOLOUE
kJ
TRANSITIOUS I N REFERENCE STATE ELEUEUTS
1665,
C
:
CALCIUM....
ALPHA-BETA 7 2 0 , I.
TITAUIUU...
ALPHA-BETA
1155,
P.
BETA 1 1 1 2 .
1. P.
8.
1 7 5 5 K.
P.
1 9 4 3 K.
C;
1 2 . 4 9 6 + 4.5156110-2
T
(EQUATION VALID PROU
COUPILED
8- 2 - 7 6
REFERENCE
177
120
+
298
2 . 4 6 2 0 1 1 0 3 T-0.5
1530 K)
6.3018110*
214
T-'
COUPILED
7-17-76
-THERBODIIAIIC PBOPEBTIES 0 1 IIYEBALS

PEBOVSKITE
PBOPEBTIES AT HIGH TEMPERATURES

135.978
FORBULA YEIGBT
_--------_----_----------------------------------------------------------------................................................................................
COBALT SPINEL
FOBMULA YEIGHT
240.797
_==-------=_==_=====---~~-~---==;_5=======1======c==z===;======3
CaTiO,:
Alpha c r y s t a l s ( o r t h o r h o m b i c ) 298.15
t o 1 5 3 0 K.
Beta c r y s t a l s ( c u b i c )
co,O,:
1 5 3 0 t o 1 8 0 0 K.
................................................................................
TEBP.
(H;-H;~~)/T
S;
-(G:-H;~~)/T
C;
FORBATION FROM THE OXIDES

GIBBS
EUTHALPY
FBEE ENERGY
Log K f
C r y s t a l s 198.15
--- _______________-__----------------------------------------------------------FOBilATION FRO8 THE ELEMENTS

-
J/nol-K
J/mol.K
J/mol.K
J/mol. K
kJ/mol
97.65
-80.791
~~
-~
GIBBS
TELIp-
t o 1 0 0 0 K.
(~:-H;~~)/T
S;
COP
-(G;-H;~~)/T
ENTHALPY
FREE ENEBGY
~ o K~
g
kJ/mol
--_--_-----------------------------_-------------------------------------------298.15
0.000
UNCERTAINTY
93.64
0.42
93.64
0.42
0.760
-82.323
14.423
0.810
-------------------------------------------------------------------------------MELTING POINT
2188
ENTHALPY OF BELTING
4 9 8
BOILING POINT
kJ
kJ
kJ
BOLAR VOLUBE
3.3626
33.626
J/bar
cm3
BELTING POINT
BOILING POINT
ENTHALPY OF BELTING
kJ
ENTHALYY OP VAPOBIZATION
kJ
';98
kJ
3.9770 J / b a r
39.770
cm3
UOLAH VOLUNE
TRAUSITIONS I N BEPEBENCE STATE OXIDES

COBALT
..... ALPHA-BETA
700,
CURIE P.
1394.
B.
P.
BETA 1 7 6 8 K.

C;
12.496
4.5156~10-2 T
REFERENCE
177
120
+
298
2 . 4 6 2 0 ~ 1 0 3 T-0.5
- 1 5 3 0 K)
6.3018~106 ~ - z
214
COBPILED
7-17-76
REFEBENCE
129
263
263
COBPILED
8- 4-76
256
THPZMODIYAMIC PROPERTIES OF MIYEBALS
CHROIETE
PWPXBTIXS AT HIGH TEMPLBATOBBS
POBIULA WEIGHT
----
223.837
.............................................................................
Crystals 2 9 8 . 1 5
PeCc,O,;
t o 1 8 0 0 K.
FeTiO.:
( H ; - H ~ ~ ~ ) / T S;
TEIP.
-(G;-B&~)/T
C:
POBIATIOUPBOI THE ELEMENTS

G I 88s
FREE ENEEGY
l o g K*
TEIP.
(H;-H;~~)/T
S;
298.15
0.000
UNCERTAINTY
MELTING POINT
BOILING POINT
ENTHALPY OP nELTIYG
kJ
EUTHALPY OP VAPORIZATION
kJ
105.86
1.25
NELTIUG POINT
1640
ENTHALPP OF MELTILlG
~ q 9 8-
kJ
CUBIE P. 1 0 4 2 , ALPHA-GAllA
fl. P. OELTA 1 8 0 9 K.
fl. P. 2 1 3 0 K .
- HE
~"28
1 1 8 4 , GAllA-DELTA
1665,
IBOU.......
HEAT CAPACITT EQUATION
REFERENCE
174
120
298
99.50
-1236.622
1.590
-1159.170
1.632
1 8 0 0 K)
COMPILED
7-17-76
203.083
0.286
BOILING POINT
kJ
EUTHLLPI OF YAPOBIZATIOU
kJ
kJ
MOLAB VOLUIE
CUBIE P. 1 0 4 2 . ALPBA-GAlMA 1 1 8 4 , GAIIA-DELTA

I. P. DELTA 1 8 0 9 K .
ALPHA-BETA I 155. n. P. 1 9 4 3 K.
4 . 8 7 6 9 ~ 1 0 5 T-2
90.667
105.86
1.25
TBAUSITIOUS I U BEPEEEYCE STATE ELEIENTS
TITAUIOI...
C:
POBlATIOU PBOI THE ELEMEYTS

GIBES
EUTHALPI
PBEE EUEBGY
Lo9 K f
IOLAB VOLUIE
TRANSITIONS I N BEPEBEYCE STATE ELElENTS
CHRO!IIUN...
-(G;-B:~~)/T
L i q u i d 1 6 4 0 t o 1 8 0 0 K.
K
J/Yo~.K
J/bol*K
J/bOlmK
J/bOl' K
kJ/mOl
kJ/b0l
................................................................................
298.15
0.000
UNCEBTAIUTY
IRON.......
t o a e l t i n g p o i n t 1 6 4 0 K.
ENTHALPY
J/mol-K
C r y s t a l s 298.15
1665.
PROPERTIES
T B E R B O D I N A I I C PROPERTIES OF BIUEBALS
1LUENITE
259
AT HIGH TEIPEBATUUES
T~TANO~~AGN*TI*~
FORUULA HEIGHT
PORUULA UEIGBT
151.745
.. . .. . ..... . . .. . .. . .. . . .. . .. . .. . . .. . .. . .. . . .. . .. . ..... . . .. . .. . .. . . .. . .. . .. . . .. - - - - - - - - - - - - - - - - - - - - - - ................................................................................
PeTiO,:
c r y s t a l s 298.15
L i q u i d 1 6 4 0 t o 1 8 0 0 K.
pea~io,:
C r y s t a l s 298.15
t o 1 8 0 0 K.
--( H ~ - H ; ~ ~ ) / T S;
TEUP.
J/mol-K
-(G;-H'&~)/T
J/!dol-K
J/mol-K
ci
FORBATION FROU THE OXIDES

GIBBS
ENTHALPY
FREE E N E R G Y
LO^ Kf
J/mol-K
kJ/mol
223.592
FUBMATIOI FBOB THE ELEUENTS

GIBBS
T E ~ ~ .( a ; - n i g e ) / ~
S;
-(G~-H;~~)/T
C;
FREE ENERGY
ENTHALPY
LO^ K*
kJ/mol
................................................................................
298.15
0.000
UNCEBTAINTY
105.86
1. 2 5
105.86
1.25
99.50
-19.829
1.300
-18.568
2.340
3.253
................................................................................
MELTING POINT
1640
ENTHALPY OF UELTING
90.667
BOILING POINT
UELTING P O I N T
BOILING POINT
kJ
kJ
ENTHALPY OF MELTING
kJ
ENTHALPP OF VAPOBIZATION
kJ
kJ
UULAR VOLUME
~:98 -
kJ
MOLAR VOLUfib
FEO
........ M .
P.
H298
T P A N S I T I U N S I N BEFEBEYCE STATE OXIDES
'0
THANSITIONS I N REFEBENCE STATE ELEUENTS
1 6 5 0 K.
IRON
.......
TITANIUM...
HEAT CAPACITY
C;
EQUATION
+
i.'iihbrl0J
298 - l b 4 U K )
1-0.5
5 . 1 0 5 7 ~ 1 ~ T6- 2
C:
_ _ _ _ _ - - - -------------177
GAUnA-DELTA
1665,
-2.9895
+
b.504YrlO-? T
(EUUATIIIN VALIU FEOM
REFERENCE
CURIE P. 1 0 4 2 , ALPHA-GABMA 1 1 8 4 ,
fi. P. DELTA 1 8 0 9 K.
ALPHA-BETA 1 1 5 5 , tl. P. 1 9 4 3 K.
___
_
_
-.
-_
-_
__ _ _ - _ . -
1 2 I)
122
COMPILED
7-11-76
1.U257x10Z +
0.14252 T
+
( EQUArION VALID FRON
298
5.L707r103
1800 K )
T-0.5
--
9 . 1 4 4 5 x 1 0 6 T-2
260
P . O P I R Z I B S AZ HIGH TBIPBPATUBES
T H ~ I I O D I I A I I I C PPOPBPTIES O? I I Y I B A L S
===s========5====E==============-=E====c======11===I================
PSBUDOBROOKITE
FOBBULA WEIGHT
L I r s l U I ALUIIMATZ (ALPHA)
IORIULA WEIGHT
65.921
====S.E==DIE=========-======-----PP==========--x=E============================
Pe,TiO,:
hAl0,:
C r y s t a l s 298.15
239.591
t o 1 8 0 0 .K
C r y s t a l s 298.15
---------_------_-------------------__--_
TEBP.
S;
(H;-H;~~)/T
J/mol-K
~~~~~~K
-(G;-H;~~)P
C;
J/S0lmK
POBIATIOU F R O I THE ELEBEYTS

GIBBS
EUTHALPI
FREE EUEBGI
L o g Kf
J/D0lsK
kJ/.ol
156.48
1-25
156.48
1.25
(H;-H;~~)/T
1883
MELTING POINT
BELTING POINT
BOIL1 NG POI I T
ENTHALPY OP BELTING
kJ
EUTHALPP OP VAPOBIZATIOU
kJ
ENTBALPY OP IELTIUG
4 9 8
kJ
-(G:-H~~~)/T
S;
C;
EYTHALPI
FREE EYEBGY
L o g Kf
---
---
---
164.26
TEIP.
kJ/mol
------------------------------L------_--------------------I--____----_______
298.15
0.000
UUCEPTAI NTY
POBIATIOU PBOB THE ELEIEUTS

GISBS
IOLAB VOLUBE
87.900
BOILING POIUT
kJ
EYTHALPY OP VAPOBIZATIOU
kJ
NOLAP VOLUIE
kJ
2.5210
25.210
J/bar
cm3
TBANSITIOUS I U BEPEBEUCE STATE ELEIBUTS
TRANSITIOYS I N REFERENCE STATE ELEBENTS

IROU..
..... CURIE
TITANIUM.
..
P. 1 0 4 2 . ALPHA-GABBA 1 1 8 4 .
B. P. DELTA 1 8 0 9 K.
ALPHA-BETA 1 1 5 5 . B. P. 1 9 4 3 K.
GAIBA-DELTA
1665,

C;
C;
2.1356110'
t
1.6245110-2
(EQUATIOU VALID PBOB
T
298
4.7946110'
1 8 0 0 K)
T-0-5
2.3447110b
T-2
95.382 + 1.1387110-2
T
(EQUATIOU VALID PRO1
REFEBEUCE
REPEBEUCE
21
120
COlPILED
8 - 2-76
--------------------------------------------------------------------------------
32
32
298
7 5 . 3 9 2 T-0.5
- 1800 K )
2 . 3 6 4 7 ~ 1 0 6 T-*
32
COlPILED
5-19-76
26 2
THERRODXIAIIIC P R O P E R T I E S O F # I N E R A L S
SPINEL
...........................................................................
C r y s t a l s 298.15
gA10.:
POB#ULA
142.267
YEIGBT
FOBMULA WEIGHT
t o 1 8 0 0 K.
aqcr20,:
Crystals 2 9 8 . 1 5
t o 1 8 0 0 K.
-FOBHATION PRO# T H E E L E # E N T S
EUTHALPY
GIBBS
F R E E ENERGY
(H;H~~~)/T
298.15
0.000
80.63
0.42
UNCERTAINTY
80.63
0.42
192.295
...............................................................................
115.94
-2299.320
-2174.860
381.028
0.750
0.760
0.133
J/mol-K
298.15
S;
J/mol-K
0.000
UNCERTAINTY
-(G;-H&,~)/T
J/mol-K
C:
FOBBATION PROM THE E L E B B I T S

GIBBS
ENTHALPY
FREE ENERGY
~ o K~
g
J/mol-K
kJ/aol
kJ/mol
106.02
0.84
106.02
0.84
126.78
-1783.640
8.370
-1669.079
8.400
292.417
1.472
-1783.163
-1781.786
-1760.051
-1778.236
-1776.495
-1774.932
-1629.971
-1591.836
-1553.995
-1516.464
-1479.199
-1442.112
212.853
166.299
135.288
113.160
96.582
83.698
400
500
600
700
800
900
35.325
59.018
76.242
89.350
99.690
108.078
146.63
180.91
210.49
236.38
259.35
279.99
111.30
121.89
134.25
147.03
159.66
171.91
147.92
158.75
165.51
170.22
173.76
176.58
1000
115.051
298.72
183.67
178.90
-1782.554
-1404.44U
73.361
1100
1200
1300
120.949
126.019
130-435
315.86
331.68
346.36
194.91
205.66
215.92
180.89
162.64
184.20
-1781.414
-1780.499
-1779.835
-1366.692
-1319.035
-1291.438
64.899
57.852
51.891
1400
1500
l66U
1700
1800
134.329
137.791
140.899
143.712
146.274
360.06
372.92
385.02
396.46
407.31
225.73
235.13
244.12
252.75
261.04
185.62
186.92
188.13
189.27
190.35
-1906.419
-1905.172
-1904.263
-1903.711
-1903.544
-1250.281
-1203.472
-1156.727
-1110.033
- 1 0 6 3 . 376
46.649
41.909
37.763
34.107
30.859
................................
--------------------------------
--_--_-______--~_-_------------------------------------------------------------2408
MELTING P O I N T
15.410
BOILING POINT
kJ
ENTHALPY O P V A P O R I Z A T I O N
kJ
HOLAR VOLURE
lELTING POINT
BOILING
kJ
ENTHALPY O F H E L T I N G
kJ
ENTHALPY
kJ
ROLAR VOLUUE
T B A N S I T L O N S I N REPEBENCE S T A T E E L E R E N T S
T R A N S I T I O N S I N HEPERENCE S T A T E E L E 5 E N T S
HEAT C A F A C I T Y EQUATION
C;
2.2291~10~
+
6.1267~10-3 T 1.5512xl0J
298 - 1800 K )
T-0.5
1 . 6 8 5 7 ~ 1 0 6 T-2
1.961UxlOz
( E Q U A T I O N VALID FBOH
POLNT
OF VAPOKIZATLON
5 . 3 9 7 7 ~ 1 0 - 3 T - 6.1688110Z
298 - 1 8 0 0 K )
T-0.5
kJ
3 . 1 2 6 0 x l U ~ T-2
( E Q U A T I O N V A L I D FBON
................................................................................
REFERENCE
22
214
237
31
................................................................................
COMPILED
8-
2-76
REFERENCE
-- _ _ _ _
174
________
214
214
COMPILED
7-17-76
PPOPEETIES AT HIGH TIIPEEATOPES

PICBOCHPOIITE
POBIULA WEIGHT
192.295
~~AGIESIOPEBBITE
265
FOBIULA WEIGHT
======0==================Z=P==_=n=5=C===r=LFI=======E==j===5===X==_=======*=
199.997
...................................................................................
c r y s t a l s 298.15
Alpha C r y s t a l s 298.15
figpeZO,:
t o 1800 K.
B e t a c r y s t a l s 6 6 5 t o 1230 K -
t o 665 K .
Gamma c r y s t a l s 1230 t o 1800 K.
TEIP-
(H;-8Sg8)/~
S;
PORIATION FROI THE OXIDES

GIBES
ENTHALPY
FREE ENERGY
Log
-(G;-H&~)/T
C;
J/mol- K
kJ/mol
-47.450
-46.827
8.370
8.400
J/mol-K
J/mol-K
J/mol- K
298.15
0.000
ONCEBTAINTY
106.02
0.84
106.02
0.84
126.78
400
500
600
700
800
900
1000
35.325
59.018
76.242
89.350
99.690
108.078
115.051
146.63
180.91
210.49
236.38
259.35
279.99
298.72
111.30
121.89
134.25
147.03
159.66
171.91
183.67
147.92
158.75
165.51
170.22
173.76
176.58
178.90
-48.620
-49.312
-49.666
-49.812
-49.841
-49.810
-49.744
1100
1200
1300
1400
1500
1600
1700
1800
120.949
126.019
130.435
134.329
137.791
140.899
143.712
196.274
315.86
331.68
346.36
360.06
372.92
385.02
396.46
407.31
194.91
205.66
215.92
225.73
235.13
244.12
252.75
261.04
180.89
182.64
184.20
185.62
186.92
188.13
189.27
190.35
-49.664
-49.577
-49.487
-49.390
-49.283
-49.162
-49.016
-48.842
kJ/.01
*
*
*
8.204
6.071
4.792
3.930
3.311
2.847
2.486
2.197
-41.282*
*
*
POBIATION FBOI THE ELEMENTS

G I BBS
TEIp.
( H ; - H ~ ~ ~ ) / TS;
-46.492
-45.872
-45.142
-44.373
-43.601
-42.826
-42.054
-40.529
-39.776
-39.016
-38.303
-37.578
-36.844
-36.152
--
1.960
*
*
*
1.764
1.598
1.456
1.334
1.227
1.132
1.049
J/mol-K
-(G;-H;~~)/T
ENTHALPY
FREE ENERGY
l o 9 K~
J/mol-K
kJ/mol
kJ/.Ol
123.85
0.84
123.85
0.84
143.72
-1428.420
1.841
-1317.004
1.883
230.735
0.330
J/mol.K
298.15
0.000
UNCEBTAINTY
C;
J/nol.K
400
500
600
665
39.350
66.022
86.428
97.601
169.11
207.59
241.91
262.55
129.76
141.57
155.48
164.95
164.30
180.83
196.01
205.88
-1426.641
-1423.820
-1420.197
-1418.140
-1279.171
-1242.595
-1206.670
-1185.187
167.043
129.814
105.050
93.095
665
700
800
900
97.601
102.857
113.470
121.867
262.55
272.03
297.10
319.36
164.59
169.17
183.63
197.49
186.68
187.13
188.40
189.68
-1418.140
-1416.079
-1414.267
-1413.500
-1185.187
-1170.817
-1135.915
-1101.103
93.095
87.368
74.168
63.907
1000
128.711
339.41
210.70
190.95
-1423.296
-1065.610
55.662
BOILING POINT
kJ
ENTBALPX OF VAPOBIZATION
kJ
kJ
IOLAB VOLUIE
................................
................................................................................
HELTING POINT
BOILING POINT
EUTHALPY OF UELTING
kJ
kJ
BOLAR VOLUME
498
kJ
4.3560
43.560
TRANSITIONS IN REFERENCE STATE OXIDES
J/bar
co3
UELTIUG POINT
EUTHALPY OF IELTING
G98
TBAYSITIONS 11 BEPEBENCE STATE ELEIENTS

C;
1.96141102
+
5.3977110-1
(EQUATIOU VALIO PROM
T
298
6 . 1 6 8 8 ~ 1 0 2 T-0.5
1800 K )
3.1260110.
I. P.
IRON.......
CUHIE P. 1042. ALPHA-GMIA

I. P. DELTA 1809 K.
T-2
922.
8.
P.
1361 K.
BAGYESIUI..
1184, GAIIA-DELTA
................................................................................
BEPEBENCE
174
214
214
COIPILED
C:
7-17-76
C:
1.7820110.
+ 1.2752~10-2 T
(EQUATION VALIO PPOfl 6 6 5
1 2 3 0 K)
1 . 0 6 6 2 ~ 1 0 2 + 5.7158110-1
T
(EQUATION VALID FRO1 1230
1 8 0 0 K)
1665,
THERUODYNAUIC PROPERTIES OF UINERALI
Zbb
P m P E B T I E S AT HIGH TEUPERATUBES
FORdULA WEIGHT
GEIKELITE
267
120.203
FOQUULA WEIGHT
---------------------------------------.----------_=_----_====_==
--------....................................................
------
UgTlO,:
C r y s t a l s 298.15
b4Ti~C
3r:y s t a l s 2 9 8 . 1 5
t o 1800 K.
120.203
t o 1 8 0 0 K.
_________
TEUP.
( H;-H;~~)/T
J/mol.K
-(G;-H;~~)/T
S;
C:
J/nol-K
J/mol-K
J/mul.K
298.15
0.000
UNCERTAINTY
74.56
(1.42
74.56
0.42
91.76
400
500
60U
700
800
900
15.725
42.910
55.255
64.564
71.877
77.822
104.13
129.02
15u.34
168.89
185.33
200.09
78.40
86.11
95.09
104.33
113.45
122.27
107.77
114.78
118.89
121.83
124.26
126.47
1000
82.793
213.52
130.73
128..56
1100
87.046
225.87
138.82
130.60
1200
I300
90.759
94.055
237.32
248.02
146.56
153.97
132.60
134.59
1400
1500
1600
1700
1800
97.021
Y9.721
102.206
104.510
106-663
258.06
267.55
276.55
285.12
293.31
161.04
167.83
174.34
180.61
186.65
136.56
138.50
140.43
142.33
144.10
PORdATION FRON THE ELEBENTs

GIBBS
ENTHALPY
FREE ENERGY
logKf
kJ/nol
kJ/mol
-1572.765
1.590
-1484.371
260.057
1.630
0.285
-1572.218
-1571.022
-1569.645
-1568.273
-1566.961
-1565.748
-1454.218
-1424.857
-1395.750
-1366.876
-1338.103
-1.j09.662
1901
ENTHALPY OF BELTING
H
~- B~ ;
13.556
S;
-(G;-H;~~)/T
J / ~ O ~ . K
~/ool-K
-1151.260
59.418
-1575.283
-1573.590
-1221.961
-1192.599
53.191
47.919
-1698.814
-1695.847
-1692.8L7
-1689.756
-1686.633
-1159.744
-1121.347
-1U83.139
-1045.142
-1U07.313
43.271
39.0Uq
35.361
31.113
29.232
--------------------------------
kJ
ENTIIALPY OF VAPURlZATION
UOLAR VOLUME
J/molSK
kJ/nol
74.56
0.42
74.56
0.42
91-76
25.725
104.13
78.40
107.77
06-11
95.09
104.33
113.45
121.27
130.73
114-78
118.89
121.83
124.26
126.47
128.56
-26.285
-25.826
-25.345
-14.888
-24.460
87.046
90.759
94.055
97.021
99.721
215.87
237.32
248.02
258.06
267.55
138.82
146.56
153.97
161.04
167.83
130.60
132.60
134.59
136.56
138.50
1600
1700
102.206
104.510
276.55
285.12
174.34
180.61
140.43
142.33
1800
196.663
293.31
l8b.65
144.20
kJ/mol
*
*
-24.055
-23.646
-23.233
-21.798
-22.329
-21.815
-21.250
-20.622
-19.924
-19.152
-25.729
0.960
4.508
-25.481
-25.331
-15.279
-25.301
-25.404
*
*
3.327
2.64b
2.201
1.888
1.659
-25.540
-25.716
*
*
*
*
*
*
*
-25.950
-26.218
-26.528
-26.855
-27.250
-27.662
-28.118
-28.638
*
*
1.482
1.343
1.232
1.141
1.066
1.002
*
*
0.949
0.903
0.864
U.831
*
*
___________________-----------------------------------------------------------HELTING POINT
kJ
FOBMATION FROd THE OXIDES

GIBBS
FREE ENERGY
L ~ Y
~t
ENTHALPY
298.15
0.000
O~~~RTAINTY
189.90~
148.850
121.511
101.998
87.376
76.011
-1572.416
J/moleK
C;
-26.525
0.920
-_----____-_-_____--------------
BOILING POINT
(H;-H;98)/~
42.910
129.02
55.255
150.34
64.564
168.89
71.877
185.33
77.822
200.09
----------___.__---------------82.793
213.52
-1573.568
-1280.508
66.887
................................................................................
MELTING POINT
TEHP.
1903
ENTHALPY OF BELTING
13.556
BOILING POINT
kJ
kJ
dOLAR VOLUBE
kJ
J.0860
30.860
TRANSITIONS I N BEELHENCE STATE ELEdENTS

MAGNESIUH..
U.
TITANIUN...
ALPHA-BETA
P.
922,
8.
P.
1155.
61.635
1 3 6 1 K.
U.
P.
1 9 4 3 K.
HEAT C A P A C I T Y E Q U A T I O N
3 . 7 6 7 j ~ l U - ~T
- 4 . 3 4 4 4 ~ 1 0 6 T-2
(EQUATION VALID FHOU
XEPEBENCE
17 1
cm3
THANSITIONS I N REFERENCE STATE OXIDES
HEAT CAPACITY EUUArlON
C;
J/bar
1L(1
3.5882~10-'
Tz
1.1759x10J
T-0-5
C;
61.635
3.767jr10-L
3 . 5 8 8 2 ~ 1 0 - * TZ
1 . 1 7 5 9 ~ 1 0 T-Oo5
~
-4.3U44x106 T - ~
298 - 1800 K )
298 - 1 8 0 0 K)
-__~__-~__~___~____---------------------------------------------------------2 1 'L
REPERENCE 177
120
-____~~_________~~_
214
COMPILED
7-17-76
268
THERMODYYAMIC PROPERTIES O F M I Y E P U S
ZINC TITANIUB S P I N E L
--------_-_---_--------------------====-----_---_____---___-_---------------.....................................
FORMULA WEIGHT
242.658
BBOBARGIPITE
---
*=========_ED======----
Zn,TiO.:
TEBP.
C r y s t a l s 298.15
(H;-H;~~)/T
5;
J/mol*K
J/mol-K
298.15
0.000
UNCERTAINTY
143.09
0.28
t o 1 8 0 0 K.
-(G;-H;~~)/T
C:
J/mol'K
FORMATION FROE THE ELEMENTS

GIBBS
ENTHALPI
FREE EUERGY
L o g K~
J/mol-K
kJ/mol
kJ/mol
-1647.660
2.510
143.09
0.28
133.58
BELTING POINT
BOILIUG POINT
ENTHALPY OF MELTING
kJ
kJ
-1534.035
2.510
kJ
BOLAB VOLOlE
11
I
~gsr:
TEap.
C r y s t a l s 298.15
(H;-H;~~)/T
FOBBULA UEIGHT
187.772
...............................................
t o m e l t l u g p o i n t 7 0 3 K.
-(G;-H'&~)/T
S;
C:
Liquid 7 0 3 t o 1 0 0 0 K .
FORBATION FROB THE ELEBENTS

GIBHS
EYTHALPY
PHEE E N E R G Y
l o g K~
268.758
0.440
MELTING POINT
~ 0 2 9 8-
269
p m p ~ B T 1 E sAT HIGH TEMPERATUBES
4.5580
45.580
703
EUTAALPY OF BELTIUG
9.163
J/bar
cm3
B O I L 1 UG P O I YT
kJ
ENTHALPY OP VAPOBIZATIOY
kJ
kJ
EOLAR VOLUMB
TRANSITIONS I N REFERENCE STATE ELEEENTS

TBAYSITIOUS I U BEPEBEYCE STATE ELElENTS
ZINC.......
I. P.
692.7.
TITAUIUB...
ALPHA-BETA 1 1 5 5 ,
8.
P.
1 1 7 8 K.
SILVER...
1. P.
.. B.
P.
1 2 3 4 K.
8.
P.
3 3 2 K.
1 9 4 3 K.
8ROMIYII....
C;
2.61291102
- 5.1374110-3
REFERENCE
21
264
T
298
2.0949110a
1 8 0 0 K)
T-0's
264
4.3165110S
T-2
COMPILED
8- 2-76
HEAT C I P A C I T I EQUATIOY
C;
3 3 . 1 6 9 + 6.4434110-2
T
(EQUATIOY VALID FROM
REPEPEYCE
1 15
120
215
298
7 0 3 K)
215
COMPILED
6- 2 - 7 6
27 0
THERBODYYABIC PROPERTIES OF MINERALS
PROPERTIES AT HIGH TEHPEBATUBES
POTASSIUB BBOHSDE
PORHULA WEIGHT
llY.00i
.....................................................................
KBr:
C r y s t a l s 298.15
)/T
TE8P.
J/moL-K
t o melting polnt
S;
1 0 0 7 K.
- ( G ; - H ~ ~ ~ ) / T C;
J/mol-K
J/mol.K
J/mol-K
5~~0NTIUH
BROBIDE
SCB~Z:
FOR8ATION FROB THE ELEHEUTS

GIBBS
ENTHALPY
PEEL ENERGY
Log K~
kJ/mol
FORL4ULA WEIGHT
-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
C r y s t a l s 298.15
to
9 0 0 K.
-Tenp.
247.428
FOBMATION FBOH GIBE5

T H E ELElIEN'rb
(H;-H;~~)/T
S;
TC;
ENTHALPY
FREE ENERGY
~ o g
K~
kJ/mol
-_-_---.-----------------------------------------------------------------------
298.15
0.000
UNCERTAINTY
95.90
0.20
95.90
0.20
52.30
-393.460
-380.061
0.180
6b.585
0.180
0.032
...............................
400
400
600
700
800
900
1000
13.550
21.710
27.333
31.594
35.075
38.089
40.8L1
111.54
123.65
133.76
142.57
150.50
157.83
164.71
8ELTlNG POINT
1007
ENTHALPY OF UELTING
25.500
~ ; g n - H:
97.99
101.94
106.43
110.98
115.42
119.74
123.89
53.87
54.79
56.21~
58.21
60.75
63.74
67.09
-410.879
-410.401
-409.751
-408.897
-407.80b
-406.45U
-404.813
48.569
37.843
30.703
25.611
21.802
18.84tj
16.493
-371.930
-362.236
-352.668
-343.218
-333.904
-324.750
-315.746
BOILING POINT
1671
kJ
149.200
kJ
k .J
BOLA#V O L U ~ E
4.3280
4J.280
J/bar
co3
-__________________------------------
lELTIBG POINT
BOILING P O I NT
EUTHALPY O F nELTING
kJ
ENTHALPY OF VAPORLZATION
kJ
kJ
HOLAH VOLUMt
17.628
TRANSITIONS I N BEFERENCE STATE ELEnENTS

TRANSITIONS I N HEYEHENCE 5TATE ELEEENTS
dEAT CAPACITY EQUATION
c~
43.924 +
5.8546~10-2 T +
1.71731103
(EQUATION VALID FRO8 2 9 8 - 1 0 0 0 K )
T-0-5
1 . 8 3 9 1 ~ 1 0 6 T-2
L;
................................................................................
REFERENCE
247
173
215
215
~ ~ ~ P I L E D
6-29-76
+ 0.11349 T
(EQUATION VALID FRO'!
= -1.2l17~102
j.:OlixlOJ
29ti YIJO K)
T-U.5
4.4156~106T - ~
27 2
T~EBIODYUAIIIC
PBOPEBTIES OP IINBBALS
pWPEnT1C.S AT RIGB TBLIPCPATuEIS
TITAYIUII TBIBRoIIDE
.......................................................
TiBr,:
C r y s t a l s 298.15
to 1200 K.
crystals
AgC1:
9
J/m0lsK
s:
J/mOl*K
g
J/mol-K
PORIATION PROII THE ELEIENTs

GIBBS
EMTHALPY PREE E N E B G ~
J/mol-K
-595.380
8.370
,f
l
kW.01
99.990
298-15
0.000
UNCERTAINTY
176-44
3.35
176.44
3.35
101.71
-570.732
400
500
600
700
800
900
1000
25-750
42-452
55.590
66-630
76-189
84-600
206-15
230-48
252-55
273.02
291.11
309-99
180.40
188.03
196.96
206.39
215.92
225.39
103.80
115.17
127.27
138.23
147.71
155.81
-639.619
-636.924
-633.157
-628.359
-622.655
-616.183
-553.109
-537.779
-511.080
-491.104
-471.876
-453.404
92.072
326.77
234.70
162.68
-609.082
-435.692
1100
98-764
342.56
243.80
168.51
-601. 459
-418.726
1g.884
I2O0
104.788
357-44
252.65
173.46
-597.458
-402.309
17.511
8-450
...............................
BOILING POINT
ENTBALPI OP BELTIYG
kJ
EITHALPY OP VAPOBIZATION
kJ
IIOLAB VOLUIE
ALPHA-BETA 1 1 5 5 , I. P.
kJ
6.7800 J / b a r
67.800
cm3

TITANIUII...
72.229
55.555
44.49,
36.6,,.,
30.810
26.315
3.97491102 - 2.6092110-2 T
(EQUATIOI VALID PBOB 298
141
247
S;
600
7oo
) C:
l i q u i d 728 to 1000 K -
PoBUATION PBOI THE ELLIEITS

GIBBS
PBBE E Y E R G y
loqKf
EYTHALPI
kJ/mol
kJ/mol
50.79
-127.070
0.085
-109-819
0.085
19-240
0.015
98.30
102.40
107.13
111.97
114.04
56.65
59.70
61.70
63.21
63.81
-125.938
-124.502
-122-900
-121.208
-120.678
-104-086
-98-787
-93-789
-89-071
-88-257
13-592
10*320
114.04
118.42
129.84
134.93
66.94
66.94
66.94
66.94
-107-791
-106.373
-104.40@
-106.706
-88- 257
-85-939
-83.482
-85-460
6.333
5.b11
~/mol.K
J/mol-K
J/.ol-K
000
96.23
0.20
96.23
0.20
13.775
22.678
29.025
33.806
34.932
112.08
125.08
136.15
115.78
148.97
52.634
53.921
55.368
52.392
166.67
172.34
180.20
187.27
728
BOILIIG POIIT
EITHALPY OP IELTIYG
12.887
kJ
EYTflALPI OF VAPOBIZATIOU
12.033
H:
kJ
2.5727
25.727
IOLAB VOLUIE
kJ
4.845
4-U64
MELT1NG POINT
"298
6-647
6-333
J/bar
cm3
TBANSITIONS I N REFEREYCE STATE ELEIIBITS

SILVEB.....
I. P.
1234 K.
HEAT CAPACITY EQUATIOI
6.91691103
T-O.5
1.001UxlO7
T-2
C;
1200 K )
................................................................................
BEPEREYCE
5oo
1 9 4 3 K.
BEAT CAPACITY EQUATION
C;
t o m e l t i n g p o i n t 728 K-
J/.o~.K
______________________
1.480
1*3-321
.................................................
298.15
(H;-~z98)/~
..............................
IIELTING POINT
498
TIUP.
POPIULA UEI6ET
=*===-
273
247
................................................................................
COBPILED
6- 2-76
59.955 + 7.6201110-3 T
(EQQATIOM
VALID rnon
BE~EBEYCX115
120
215
298
1.0167110* T-2
728 K )
21 5
COIIPILCD
7- 1-76
274
THERNODYYANIC P B O P E R T I E S O F f l I U E B A L S
HY D B O P H I L I T E
PBOPEBTIES AT H I G H T E E P E B A T U B E S
110.986
FORflULA WEIGHT
LAW B E N C I T E
FORHULA WEIGHT
126.753
_---_--__--_--____-___----~-----.--.--.--.--~-----.-.-.-----------------------_-------_--_-----_-------------------------------------------------------------...................................................................................
~~c1,:
C r y s t a l s 198.15
CaCl,:
t o meltlng p o i n t
C r y s t a l s 298.15
L l q u i d 950 t o b o i l i n g p o i n t
1 0 5 5 K.
1 3 4 7 K.
--------------
-------- TEHP.
( H ! - H ~ ~ ~ ) / T S;
J/nol-K
--..............................................................................
_-_--_-_.-_-___-_____--____
-(c!-H;~~)/T
J/mol-K
.l/mul-K
FOBNATION PEON T H E E L E H E N T S
PORHATIOU PROM T H E E L E n E N T S
GIBBS
ENTHALPY
FEEX ENERGY
LO^ K f
C;
J/mol-K
kJ/mol
kJ/mol
J/mol-K
J/mol-K
J/mol- K
J/mol- K
kJ/mol
kJ/mol
117.95
0.42
76.32
-341.650
0.420
-302.172
0.420
-_____-______-_____-----------.-------------------.-----------------------------
298.15
0.000
UNCERTAINTY
104.60
1.25
104.60
1.25
72.59
do0
YOU
1000
180.72
190.34
199.05
l31.911
i31.94
30.85
t12.0b
53-37
48.774
5i.400
1~.434
1kj.61
-----------
1U55
MELTING P O I N T
ENTHALPY
OF i l t L I l N G
CALClUn
-748.06J
0.750
131.058
0.131
2 8 . i b d k.!
H E A T CAPACITY
ALPHA-BETA
720,
RELTING P O I N T
95U
1347
kJ
ENTHALPY O F NELTING
43.012
kJ
ENTHALPY OF V A P O E I Z A T l U N
124.tlUY
kJ
16.272
kJ
BOLAR VOLUNE
OF VAL'!JHLIATLIIN
noLA~c v ; ~ ~ o r . r .
5.0750
'>0. 1 5 0
J/bar
cm3
H.
Y.
BETA 1111.
HP)
~ -S
T R A U S I T l O N S I N REFERENCE S T A T E ELEMENTS
B.
P.
1755 K .
IRON.......
Z,UATION
115
169
C U R I E P . 1 0 4 2 . ALPHA-GAHMA
8. P. DELTA 1 8 0 9 K.
1184.
GAflnA-DELTA
1665.
214
52.939
0.074
ENI'HALPY
C;
REFEHENCE
117.95
0.42
3 U i ~ i h GV U l U l
IN L i . . i t . K E H i . t I T A I t E L E n Z N T I
....
298.15
0.000
U N C E R T A INTP
.--.
x,!
TRANSITION:,
-795.800
0.650
214
CO~PILED
6-14-76
t
8.9510~10-2 T
+
( E Q U A T I O N V A L I D FEOR
298 -
= -1.123lrlOz
3 . 7 8 9 7 ~ 1 0 3 T-0.5
950 K )
5 . 1 1 4 5 ~ 1 0 6 T-Z
IOLYSITE
FOPMULA WEIGHT
162,206
BTDBOGEU CELOBIDE
==================**=l=~=s=======l*=r====-===~==5================S========I
==-
PeC1,:
C r y s t a l s 298.15
HC~:
I d e a l g a s 298.15
t o 1 8 0 0 K.
TEMP-
(~;-H;gg
)/T
J/nol-K
298.15
0.000
UNCERTAINTY
5;
-(G;-H;~~)/T
J/nol-K
J/nol.K
142.26
0.42
C;
PORIATION POOH THE ELEIEYTS

GIBES
ENTHALPI
FREE EUEBGY
log
Kf
kJ/nol
kJ/mol
-399.240
0.420
-333.754
1-420
J/DOl'K
142.26
0.42
94.93
--
577
BOILIUG POINT
605
ENTBALPI OP MELTING
43.095
kJ
EHTHALPY OF VAPORIZATION
21.882
L J
19.707
kJ
IOLAB VOLUIE
PORIATIOM FBOI THE ELElEYTS

GIBBS
FREE EYEPGI
Log K t
BUTHIIPI
58.473
0.239
UELTING POINT
'0298
1 1 8 4 , GAIIA-DELTA
8.640
BOILIYG POINT
kJ
kJ
kJ
MOLAR VOLUIE
1665.
I
T-2
298
H:
TPAUSITIOUS I N EEFEBENCE STATE ELEMEUTS
CURIE P. 1 0 4 2 . ALPHA-GAIIA
I. P. DELTA 1 8 0 9 K .
1.2368110'
- 2.55641102
(EQUATION VALID FBOI
ENTEALPY OF MELTING
C;
BELTING POINT
~0298
TRAUSITIONS 1 8 REFERENCE STATE ELEIEUTS

IBON.......
36.461
L i q u i d 577 t o b o i l i n g p o i n t
I d e a l g a s ( d i n e r ) 6 0 5 t o 7 0 0 K.
6 0 5 K.
FOOIULA WEIGHT
P--===_===*=n_=_--------==*====~=-=====================================
HEAT CAPACITX EQUATIOU
577 K )
-------~-----------------------------------------------------------------------REFERENCE
169
215
215
147
~ ~ ~ P I L E D
7-24-76
REPBRENCE
247
215
215
COMPILED
6- 2 - 7 6
278
TBEBBODIIAIIIC PROPERTIES OF BIIERALS
SYLVITE
-------
.................................
KC1:
C r y s t a l s 298.15
-----=
PPOPERTIES AT HIGH TEBPERATUBSS
FORMULA WEIGHT
..............................................
74.551
Liquid 1043 t o f i c t i v e b o i l l n g
C r y s t a l s 298.15
UgC1,:
S;
J/mol-K
J/mol-K
298.15
0.000
UNCERTAINTY
82.59
0.20
BELTING POINT
-(G;-H;~~)/T
J/mOl-K
C;
26.284
GIBBS
FREE SNEBGY
ENTHALPY
J/mol-K
kJ/mol
kJ/mol
51.29
-436.470
0.140
-408.554
0.140
82-59
0.20
1043
ENTHALPY OF BELTING
TEIP.
P.
336.4.
8.
BOILING POINT
1750
kJ
155.394
kJ
P.
MOLAR VOLUME
1 0 3 0 K.
REFERENCE
24.516 t 4 . 8 5 2 2 ~ 1 0 - z T t
1.J710x103
(EQUATION VALID FROB 2 9 8 - 1 0 4 3 K )
247
173
215
J/mol-K
S;
-( G ; - H ; ~ ~ ) / I
C;
J/mol-K
J/nol. K
kJ/nol
k J/mol
J/m01-K
ENTHALPY
PBEE E N E R G Y
~ o K~
g
298.15
0.000
UNCERTAINTY
89.62
0.84
89.62
0.84
71.04
-641.320
0.460
-591.785
0.544
103.679
0.095
400
500
600
700
800
900
18.750
30.394
38.508
44.529
49.205
52.967
111.22
128.39
142.80
155.23
166.17
175.96
92.47
98.00
104.29
110.70
116.97
122.99
75.64
78.17
79.93
81.33
82.53
83.63
-639.951
-638.495
-637.004
-635.515
-634.042
-632.598
-575.067
-559.015
-543.254
-527.749
-512.458
-497.354
75.096
58.400
47.295
39.381
33.460
28.866
987
55.798
184.01
128.21
84.52
-640.229
-483.881
25.608
-597.134
-596.844
-483.881
-482.356
25.608
25.196
-594.610
-592.389
-590.174
-471.025
-459.876
-448.928
22.367
20.018
18.038
-714.928
-711.544
-708.167
-704.798
-434.507
-414.633
-394.956
-375.491
16.212
14.439
12-894
11.537
987
1000
99.461
99.370
227.67
228.82
128.21
129.45
92.47
92.47
1100
1200
1300
98.743
98.219
97.777
237.65
145.68
253.09
138.91
147.46
155.31
92.47
92.47
92.47
1400
1500
1600
1700
97.398
97.069
96.781
96.527
259.91
266.31
272.29
277.90
162.51
169.24
175.51
181.37
92.47
92.47
92.47
92.47
ENTHALPY OF MELTING
43.095
~ ; g a - H:
13.770 k.l
--------------------------------
------------_-------------------
kJ
156.230 kJ
MOLAR VOLUBE
TBANSITIONS I N REFERENCE STATE ELEMENTS
Cp =
( H ; - A ; ~ ~ )/T
71.577
0.025

N.
L i q u i d 987 t o b o i l i n g p o i n t
FORHATION FROB THE ELEMENTS

GIBHS
Log K~
11.368 k J
POTASSIUM..
1 7 1 0 K,
(H;-H;~~)/T
95.211
...............................................................................
p o i n t 1 7 5 0 K.
TEMP-
P o a a u L a WEIGHT
CHLOBOIAGUBSITE
n.
IAGNESIUM..
P.
9 2 2 , 8.
P.
1 3 6 1 K.

T-0.5
1 . 6 0 5 4 ~ 1 0 6 T-2
2 15
................................................................................
C;
COBPILED
5-28-76
= 76.903
8.4955~10-3 T
298
7 . 4 6 3 1 x 1 0 S T-'
9 8 7 K)
................................................................................
REFEBENCE
169
120
247
214
247
................................................................................
COBPILED
6 - 9-76
P ~ O P ~ ~ IU
S SBIOB TLIPERATUPES
lnC1.:
C r y s t a l s 298.15
Beta c r y s t a l s 457.7 t o m e l t i n g p o i n t
Alpha c r y s t a l s 298.15 t o 457.7 K.
Decomposition t e m p e r a t u r e (from d i f f e r e n t i a l t h e r m a l a n a l y s i s )
793.2 K.
is 611.4 K.
uH.Cl:
L i q u i d 9 2 3 t o 1400 K.
----_-------_--------------------_----------------____--________-________
TEnP.
( B ; - H ; ~ ~ ~ ) / T S:
J/.0l'K
J/.01.
-(G;-B;~~)/?
K
J/.0l.K
FOPIATIOP ?PO8 2 8 1 ILEIEITS

GIBBS
?BEE EUEBGI
log
EYTHALPY
C:
.J/.ol.
kJ/mol
kW.01
POEIIATIOI FROB THE ELEILYTS

GIBBS
xi
T~np.
( B ~ - H ; ~ ~ ) / TS;
J/mol-K
-(G;-H;~~)/T
J/mol-K
J/mol-K
C;
J/mol-K
EYTBALPY
kJ/mol
~ o g
K~
FREE BNERGI
kJ/.01
C____________I________--____--__-----__--------_--_--_--------------------
298.15
0.000
UUCEBTAIITX
118.24
0.21
118.24
0.21
73.01
-481.290
0.837
-440.488
0.879
77.172
0.154
400
500
600
700
800
900
923
19.175
31.068
39.357
45.529
50.352
54.267
55.167
140.35
157.88
172.61
185.33
196.56
206.64
109.60
121.17
126.81
133.25
139.80
146.21
152.37
154.44
77.25
79.80
81.73
83.37
84.85
86.24
88.56
-479.930
-478.557
-477.211
-475.898
-474.610
-473.332
-P72.767
-426.762
-413.622
-400.765
-388.124
-375.674
-363.388
-361.187
55.730
43.211
34.890
28.962
24.529
21.091
20.440
923
95.828
250.26
154.44
94.56
-457.696
-361.187
20.440
1000
95.730
257.19
161.46
94.56
-436.085
-354.396
18.512
298.15
0.000
UUCEBZAIUTY
95.02
0. 40
95.02
0.40
86.65
-315.190
0.290
-203.776
0.290
35.701
0.051
24.172
34.470
122.80
137.06
98.63
102.59
102.97
110.65
-314.694
-313.810
-165.748
-145.435
21.645
16.598
400
457.7
___________________--------------------------7------------_-------------------
457.7
500
600
43.099
46.920
55.117
145.69
153.49
170.98
102.59
106.57
115.86
86.03
90.50
101.67
-309.860
-310.002
-309.556
-115.435
-129.015
-92.837
16.598
13.478
8.082
700
62.563
187.49
124.92
112.80
-308.062
-56.822
4.240
BOILIIG POIUZ
kJ
EUTHALPY OF VAPOBILATIOU
kJ
kJ
IOLAB VOLUIE
IELTIUG POINT
793.20
EUTHALPY OF IIELTIUG
'0298
EUTHALPI OF IELTIYG
G98
37.530
kJ
EUTBALPY OF VAPORIZATIOY
15.071 kJ
A;
kJ
HE
22.698
3.5060
35.060
J/bar
cm3
TBIUSITIOUS I Y REPEBEYCE STATE ELElENTS
IOLAB VOLUIE
TBAUSITIOUS I U BEPEBEYCE STATE ELEIEUTS

IAIGAYESE..
ALPHA-BETA 980, BETA-GAIIA 1360.

n. P. DELTA 1517 K.
GAIIIA-DELTA 1 4 1 0 ,
BEPEBENCE
BEAT CAPACITY EQUATIOU
298
923 K )
247
215
215
COIPILKD
7-24-76
THEBBODYUABIC PBOPEBTIES OF UINERALS
282
HALITE
. .. .-. .-. .-.-. .-. .-. .-.. .-. . .. .-. .-. .-. .-.-. .-. .-. . .. .-. .-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
NaC1:
C r y s t a l s 298.15
b o i l ~ n yp o i n t
t o melting point
1073.8
PBOPEBTIES AT HIGH TELIPEPATUBES
FOBBULA YEIGHT
K.
L i q u i d 1073.8
58.443
5;
C r y s t a l s 298.15
~iC1,:
-(G;-H&~)/T
ENTHALPY
C:
FOBBULA UEIGHT
129.606
GIBBS
PBEE E N E R G Y
LO^
1 3 0 3 K.
t o melting point
--
FORHATION PROii THE ELEHENTS

(H;-H;~~)/T
NICKEL CHLORIDE
..................................................................................
to fictive
1 7 9 1 K.
................................................................................
TEHP.
FORBATION FROU THE ELEnENTS
GIBBS
If
-,- - ................................................................................
298.15
0.000
UNCERTAIUTY
BELTING POINT
72.12
0.21
50.51
0.21
-411.260
0.110
-384.212
0.110
67.313
0.019
BOILING POINT
1791
28.158
kJ
164.787
kJ
10.611
kJ
NOLA8 VOLUHE
1073.8
ENTBALPY OF NELTING
72.12
__~_~____~_________-------------------------------------------------------BELTING POINT
ENTHALPY OF BELTING
4 9 8
TRANSITIOBS I N REPEXENCE STATE ELEUENTS
H:
C;
45. 151 +
1.7974~10-Z T
298
1073.8
:
C
K)
215
....- CURIE
REPEBENCE
- 1791 K)
................................................................
247
BOILING POINT
77.280
kJ
14.385
kJ
BOLAR VOLUME
kJ
3.6700
36.700
J/bar
cm3
P.
631,
6.
P.
1 7 2 6 K.
72.008 3.2228~10-3 T
(EQUATION VALID FBOB 1 0 7 3 . 8
REFERENCE

NICKEL
C:
1303
215
---------------COHPILED
50.781 t
5.7481110-2
T +
(EQUATION VALID FBOB 2 9 8
40
263
2.6078x103
1 3 0 3 K)
T-0.5
263
4 . 0 6 3 7 ~ 1 0 6 T-2
COBPILED
6- 2 - 7 6
THERI(0DINABIC PROPERTIES 0 1 ~ I E B A L S
PROPERTIES AT HIGH TEBPEBATOBES
COTUIlITE
--------------
- - - - - - - - - - - - - - = = = = = = = T = = = = ~ = = = = S = _ = = = = _ _ = = = _ S ~ = l = = = = _ _ _----------===_ - -FOBBOLA
---
PbClZ:
C r y s t a l s 298.15
WEIGHT 278.1 0 6
-===========
TiC1.:
L i q u i d 7 6 8 t o 1 0 0 0 K.
""-
s:
8
J/mol-K
J/mol.K
J/mol.K
)C;
POBBATIOI FROB THE ELEBENTS

GIBBS
ENTHALPY
FREE ENERGX
Log K+
J/mol.K
kJ/mol
kJ/mol
135.98
2.09
HELTING POINT
135.98
2.09
73.15
-359.400
0.293
-314.033
0.711
768
55.017
0.125
BOILIIG POINT
ENTBALPY OF BELTING
23.849
kJ
EITHALPI OF VAPORIZATION
~ k - n800
16.941
kJ
noLAn voLunE
154.259
The f r e e energy f o r t h e r e a c t i o n TiC13 ( c )
( g ) a p p r o a c h e s z e r o a t 1104- 1 K.
--
FOBIATIOU FROB THE ELEBENTS

GIBBS
T ~ ~ p .( H : - ~ ; ~ ~ ) / T
298.15
0.000
UUCERTAINTY
t o 1 2 0 0 K.
C r y s t a l s 298.15
= TiC1,
-----------------------------------------------------------------------------
FORMULA WEIGHT
TITANIUB TPICHLOPIDE
..............................................................................
J/mol.K
--- _____
-(G;-H;~~)/T
S;
J/mol.K
J/mol. K
ENTEALPI
C;
J/.Ol-
kJ/#ol
FREE ENERGY
log
______I_______---
298.15
0-000
uUCERTAI NTY
139.75
1.26
139.75
1.26
97.16
-721.740
4.180
-654.507
5.020
1 1 04..867697
UELTIIG POIUT
BOILING POIYT
EIITHALPY OF HELTIUG
kJ
EITHALPI OP VAPOEIZATIOU
kJ
kJ
BOLAR VOLUBE
80298
K~
kJ/.Ol
fl:
5.7300
57.300
J/bar
cm3

TRANSITIOllS I Y BEPEBEYCE STATE ELEIIEITS
LEAD.......
8.
P.
600.6,
8.
P.
2 0 2 1 K.
TITAIIUI...
C;
115
120
215
1 1 5 5 1 1. P-
1 9 4 3 K-
BEAT CAPACITY EQOATIOI
1.22871102
8.5847~102 T-0-s
REFERENCE
ALPHA-BETA
768 K )
247
215
---------------------------------_--_-_-__-_-----------------2----~-----------
COBPILED
6- 9-76
REFERENCE
141
247
247
COlPZLED
6- 2-76
THEPMODYUAMIC PBOPERTIES OF M I Y B B A L S
~ B O ~ E B T I E SAT HIGH TEIIPEBATUBES
UBANIUM TBICHLOBIDE
FORnULA YEIGHT
URANIUM TETRACHLORIDE
.............................................................................
UCl,:
C r y s t a l s 298.15
t o 1000 K .
UCA,:
( H ~ - H ; )/T
~ ~
TEBP.
S;
-(G;-H&~)/T
C:
J/mol- K
J/mol- K
FORllATION FROB THE ELEBENTs

GIBBS
EUTHALPY
PBEE ENERGY
L~~
C r y s t a l s 298.15
J/mo1-K
kJ/mol
to
700 K -
--
POBIATION
(H;-H;98)/T
-(G;-H;~~)/T
S;
C;
EYTHALPY
,J/nol-K
158.95
158.95
0.40
101.73
-891.190
0.40
4.000
FREE ENERGY
Log K t
kJ/mol
J/mOr.K
J/mol.K
J/MOl-K
kJ/mol
I_-__--_------__----------------------------------------------------------------
298.15
0.000
UNCERTAINTY
PROMG ITBHBES E L E B E N T S
K~
TEUP.
J/mol-K
379.841
-823.820
144.330
5.000
0.876
kJ/mol
_____~_-_____-_._-_---.----------------------
~ ~ 8 . 1 5 0.000
UNCERTAINTY
1Yb.60
0.50
196.60
0.50
119.89
-1018.390
3.000
-928.850
3.000
162.731
0.526
-----_--------_----------------------------------------------------------------BELTING POINT
BOILING POINT
ENTHALPY OF MELTING
kJ
G98
~1:
k .J
uoLAR VoLunE
6.2040
62.040
TRAYSITIONS I Y REFERENCE STATE ELEMENTS
BELTING POINT
BOILING POINT
kJ
kJ
J/bar
HOLYH
kJ
BOLAR VOLUME
co3
HE
kJ
1.7600
77.600
J/bar
cm3
TRAN5ITIONS I N REFERENCE STATE ELEBEUTS

URANIUB....
ALPHA-BETA 9 4 1 ,
BETA-GAMnA
1048,
8.
1 4 0 5 K.
P.
ALPHA-BETA 9 4 1 ,
URANIUU....
BETA-GABMA
1048.
U.
P-
1405 K -
4 . 6 9 4 8 ~ 1 0 6 T-2

C;
= - 1 . 7 5 2 9 ~ 1 0 ~t
0.13399 T
REFERENCE
70
70
5 . 4 5 6 5 ~ 1 0 1 T-0.5
2 9 8 - 1 0 0 0 K)
7 . 5 0 3 6 ~ 1 0 . T-2
C;
80.231 +
0.12983 T +
1 . 6 9 8 7 ~ 1 0 3 T-0-5
298 7 0 0 K)
____~______________------------------------------------------------------89
COUPILED
REPEREYCE
70
70
89
233
COIIPILED
6-17-76
288
THEBMODINAMIC PROPERTIES 0 1 H I H E R U S
VANAOIUII DICHLORIOE
-------
FORMULA
WEIGHT
...............................................................................
VC1,:
121.847
C r y s t a l s 298.15 t o 1300 K.
PORlOLA WEIGHT
VANADIUH TRICHLOBIDE
157.300
-_====
vcl,:
C r y s t a l s 298.15
to
9 0 0 K.
________I_______--_-----_-------------
( H ; - H ~)IT~ ~
TEIIP.
J/rn0l.K
298.15
0.000
UNCERTAINTY
S;
FORMATION PBOU THE ELEIIENTS

GIBBS
ENTHALPY
FREE ENERGY
LO^ K~
- ( G ; - H ~ ~ ~ ) / T C:
J/aol.K
J/.01-
97.07
1.26
97.07
1.26
.7/.ol-
kJ/.0l
72.20
-405.681
71.074
8.500
8.500
1.489
BOILING POINT
ENTHALPY OF BELTING
kJ
t .I
BOLA8 voLunE
H:
TEMP.
(H;-U;~~)/T
REFERENCE
125
120
FREE EIEBGY
Log
BOILING POINT
kJ
ENTHALPY OF MELTING
kJ
ENTHALPr OF VAPORIZATION
kJ
kJ
MOLAR VOLOME
J/bar
Kf
TRAUSITIONS I N REFERENCE STATE ELEIIENTS
66.755 +
1.3045~10-2 T
(EQUATIOU VALID PBOII
EYTHALPI
IIELTI NG POINT
VANADIUM...
- ( ~ ; - t l f ~ ~ ) / ~C;
C:
S:
k J/.ol
-451.870
UELTING POINT
'i98
FOBMATION FBOM THE ELEIIEUTS

GIBES
I.
P.
2175 K.
+
1.2465~10. T-0-s
2 9 8 - 1 3 0 0 K)
5 . 0 3 4 8 ~ 1 0 5 T-2
264
C;
COMPILED
148.86
- 1 . 3 3 0 1 ~ 1 0 - 2 T - 8 . 9 3 2 6 ~ 1 0 2 T-0.5
(EQUATION VALID FBOII 2 9 8
9 0 0 K)
REFERENCE
125
120
261)
COUPILED
6-29-76
ALUBINUB T E I P L U O B I D E
O BBU
LA
WEIGHT
83 . 97 7- - - - - - - - - - - - - - - - - - - - - - - - - - - - - . - - - -F----..................................................................................
Alp,:
t o 7 2 8 K.
B e t a c r y s t a l s 728 t o
1nu0 K.
PBOPEBTIES
~LUOBITE
................................................................................
C r y s t a l s 1 298.15
sT
ENTHALPY
F R E L I?NERL;Y
FOtlUATiON PROU T B E ELEUENTS

GIBMS
hgK f
TEB~.
66.48
0.42
66-48
c r y s t a l s I1 1 4 2 4 t o
~ l q u ~1 6d9 1 t o 1 8 0 0 K -
i;lllBs
..,
298.15
0.000
UNCEBTAIITY
1 6 9 1 K.
___________________-_-_------------------------------_---__----------
P O R B A T L O N FROR T f l E L L E U E N T s
t o t r a n s i t i o n p o i n t 1424 K.
K.
melting p o l n t
TEUP.
78.077
FOBBULA W E I G H T
The
CaF,:
dissociation t e m p e r a t u r e is 1 5 4 9
AT H I G H T E I P E B A T U B E S
75.13
-1'510.4UU
1. 300
0.42
- ...
(fi;-~;~~)/T
J/mol.K
-1431.076
1. 300
250.720
0. 228
---
-(G;-H;~~)/T
S;
J/mol.K
298.15
0.000
U N C E R T A IN T I
J/lol-K
C:
EUThALPY
kJ/mol
J/mol. K
Log K f
F R E E ENERGY
kiJ/ mol
___--_-----_--_-----
68.87
0.34
68.87
0.34
68.59
-1229.260
U . 42(,
-1176.920
u.420
20h.192
(1.014
-1227.845
-1226.375
-1224.961
-1223.625
-1159.245
-1142.270
-1125.583
-1109.126
151.383
119.333
97.991
82.764
400
500
60U
700
18.300
29.710
37.678
43.673
89-94
106.75
12u.88
133.15
71.64
77.04
83.20
89.48
74.09
76.50
78.54
80.80
800
900
1000
48.474
52.522
56.068
144.11
154.10
163.37
95.64
101.58
107.30
83.42
86.39
89.68
-1223.080
-1221.729
-1220.513
-1092.768
-1076.550
-1060.493
71.351
62.482
55.395
1200
1300
1400
1424
62.268
65.094
67.807
68.402
180.36
1 . 2
195.92
198.05
118.09
123.19
128.11
129.65
97.02
101.01
105. 17
105.19
-1225.326
-1222.144
-12ld.570
1 2 1 7.706
-1028.083
-1011.765
-995.722
-99L.219
44.751
40.653
J7.151
J b . 396
1424
1500
1600
lb91
71.722
74.363
77.456
80.057
201.37
207.44
215.43
222.42
129.65
133.08
137.98
142.36
122.88
123.68
124.73
125.68
--1112.978
-1208.715
-1203.106
-11d4.042
1691
1700
97.624
97.635
139.99
240.50
142.36
142.86
100.00
100.00
-1150.336
-1lbl.hiO
___---____
-----_
................................
. .__-_
I _ - _ - - - _ _ _ _ _ _ _ - _ - _ - - _ _
36.396
34.135
31.510
29.414
-992.219
-980.240
-965.194
-952.223
__.--_______-
- ----- -------- ----- --------
_ ----------
. .
UELTING P O I N T
I I O I L i S G 5t': h ?
ENTHALPY
k.1
Eii:irAiP':
kJ
ROLAh
O F MELTING
- 1%;
iit
CLr~.!?if.A;iit'.
k .l
P;I; I : ?
'
fl.
P.
' =.A
)<,.
i;,,,
T L I A N S I T I O N S I N REFERENCE S T A T E ELEUEN'i,;
A L U U I N U fi.
. ..
~:,'t~d~
___ --------.
___-__-___
RELTING P O I N T
ENTHALPY O F U E L T I N G
1691
29.706
-~ H:~
-951.223
-950.h73
_--_
29.41U
29.211
- - - - - ..-
BOILING POINT
kJ
ENTHALPY
k ,I
kJ
UOLAR V O i U X E
O P VAYORIZATLON
LC"'
T H A N S I T I O N S I N BEPBBEUCE S T A T E ELEPIENTS
9 l j K.
CALCIUH
.... A L P H A - B E T A
1 2 0 , I. P.
BETA 1112.
R.
P.
1755 K.
HEAT C A P A C I T Y E Q U A T I b N
d
c,
C:
u . I ~ ~ $ Y
T
(EQUATION VALIU PRUn
298 -
10.932 +
Q.YJ37~10-' T
(EQUATION VALID FBOn
7211 -
= - 1 . ~ 6 1 5 ~ 1 0 2+
4. I > . ~ ~ ~ IT u- 0,. 5
7,!8
--------
51
18 1
247
215
_ - - _ _ __
C:
lblru li,
~
SEPEHENCE
; ,'
.,.+9'.j,!Mkii,$
K)
. . .- ..- -
24 i
l.llU&'iLED
115
11-11-16
. ~ ..
-------
' -
24.692 + 5 . 8 0 9 5 ~ 1 0 - 2 T
t
1.Y70brlOJ
( E Q U A T I O N V A L I D FBOM
298 - 1 4 2 4 K )
T ~ v . 5
i.ti.l7lb<lG.
T-2
THERIIODIIAKXC PROPERTIES 0 ) ~ I I X R A L S
292
SELLAITE
.....................................................
----
POBlULA WEIGHT
................................
IgP,:
L i q u i d 1536 t o 1800 K.
C r y s t a l s 298.15
62.301
?ORlULA WEIGHT
41 - 9 8 8
=SIXL==S=T-E===~i.====li==-==E=I====.===PIL-======I=S==.==3=========11=5====s==iC=
C r y s t a l s 298.15
yaF:
------___
TEIP.
(H;-H:~~)/T
J/mol.K
-(G;-H&~)/T
S;
J/aOl.K
298.15
0.000
UNCERTAI NTY
J/mol-K
57.25
0.42
57.25
0.42
C;
FORMATIOB PROM THE ELEIENrS

GIBES
EBTHALPl
FREE ENERGI.
IDg
J/aol-K
61.59
kJ/mol
-1124.200
kJ/.ol
--
-1071.064
1.200
rf
187.647
1.200
0.210
L i q u i d 1269 t o 1800 K.
FOBMATIOY PROI THE ELEMENTS

GIBES
~ ~ l p (H;-H;~~)/T
.
- ( G ~ - H ~ ~ ~ )C
/ ;T
S:
J/aol.
BNTUALPY
PREE ENERGY
LO9 K f
kJ/.Ol
J/aol-R
J/aol-K
J/aol*K
kJ/aol
298.15
0.000
~yCERTAINT1
51.30
0.08
51.30
0.08
46.85
-576.550
0.670
-546.319
0.670
95.713
0.117
400
500
600
700
800
900
1000
12.350
19.980
25.292
29.287
32.481
35.167
37.507
65.54
76.80
86.25
94.45
101.77
108.44
114.61
53.19
56.82
60.96
65.16
69.29
73.27
77.10
49.72
51.18
52.53
54.02
55.71
57.58
59.63
-578.927
-578.665
-578.236
-577.641
-576.877
-575.930
-574.818
-535.833
-525.087
-514.411
-503.805
-493.309
-482.919
-472.648
69.973
5U.856
UU.784
37.595
32.210
28.028
24.689
1100
39.616
120.40
80.78
61.81
-573.526
-462.487
21.962
-669.452
-450.400
19.605
1200
1269
41.562
43.067
125.87
129.83
84.31
86.76
64.12
65.77
-667.412
-437.699
18.017
1269
1300
1400
1500
1600
1700
1800
69.179
69.165
69.121
69.077
69.042
69.011
68.983
155.94
157.51
162.58
167.31
171.73
175.88
179.80
86.76
88.35
93.46
98.23
102.69
106.87
110.82
68.51
68.51
68.51
68.51
68.51
68.51
68.51
-634.275
-633.385
-630.513
-627.660
-624.810
-621.970
-619.139
-437.699
-433.078
-417.764
-402.676
-387.770
-373.039
-358.488
18.017
17.401
15.587
14.022
12.659
11.462
10.403
................................................................................
BELT1 NG POINT
1536
ENTHALPY OP MELTING
~2098 -
58.158
BOILING POINT
2630
IELTIUG POINT
kJ
ENTHALPY OF VAPOBIZATIOI
240.162
kJ
ENTHALPY OF MELTING
MOLAR VOLUME
1.9610 J / b a r
19.610 c a 3
9.983 k J
TRANSITIONS I N REFERENCE STATE ELEIEITS

HAGNESIUH..
n.
P.
922,
8.
P.
72.887 t 9.1200110-3 T
REPEBENCE
175
247
BOILIYG POINT
33.137
kJ
kJ
8.485
kJ
lOLA8 VOLUME
8:
1.4984 J / b a r
14.984
cm3
TBAYSITIONS I U BEPEBEUCE STATE ELEIENTS

SODIUM
1361 K.
..... I.
P.
370.98,
8.
P.
1175 K.
298
9.54151101 T-O-5
1 2 6 9 K)
C;
498
1269
298
1.2460110b 1-1
1 5 3 6 K)
C:
215
COMPXLED
6- 9-76
+ 3.3468110-2 T
(EQUATION VALID FROl
= -2,6123
REFERENCE
181
21 5
1.40231106
215
T-2
COMPILED
6- 9-76
CRYOLITE
PORUULA WEIGHT
.....................................................
..............................
Na,AlP,:
C r y s t a l s 298.15
t o 1 5 0 0 K.
J/mol.K
298.15
0.000
UNCERTAINTY
S:
= NaAlP,
+ 2vap.
- ( G ~ - H ; ~ ~ ) / T C:
EYTHALPY
J/mol*K
J/mol.K
kJ/nOl
238.45
1.67
238.45
215.72
-3309.544
-3144.915
550.978
4.180
4.300
0.753
t o m e l t i n g p o i n t 1330 K -
--
FORMATION FROB THE ELEUENTS

GIBBS
BELilNG YOINT
BOILING POINT
ENTHALPY OF NELTING
111.755
kJ
EYTHALPY OF VAPOBIZATION
38.100
kJ
UOLAR VOLUME
EN'I'YhiPY OF 8Ei"Ibiti
kJ
7.0810
70.810
J/ba~
cm3
H ; -~ H;;~
0.15471 T
REFERENCE
18 1
247
838
1285 K )
247
COMPILED
8-1 1 - 7 6
'42.803
22.552
hLYuA-dETA '141,
HEAT LAPACiTY t, I A - I O N
1..j3jlx10z
BOILING POINT
kJ
ENTUALPY OF VAPORIZATION
kJ
n0LAR VOLUHE
tlETA-GABMA
1 0 4 8 , 1. P.
kJ
4.6880
46.880
THANslTIONS IN REYEUENCE STATE ELEMENTS

LiXANIJn....
1330
C:
314.023
k~/mol
1285
H:
2 95
~
~ o gKf
J/molmK
1.67
C r y s t a l s 298.15
UP.:
GIBBS
FREE ENERGY
BELTING POINT
FORUULA L'EIGHT
................................................................................
tIOLgS
~ - B I G pHTEUPIPAZUBES
~
209.942
FORUATION FRO4 THE ELEMENTS

(H;-H;~~)/T
C r y o l i t e d i s s o f i a t e s a b o v e 1279 K
p r e s u m a b l y by t h e r e a c t i o n Ua,AlF.
TEMP.
1405 K -
J/bar
cm3
..~
,-
297
PBOPERTIIS AT HIGH TEnPEBATUnlS

IODARGrRITI
PORIULA WEIGHT
234.772
PORIULA
..............................................................................
WEIGHT
454.399
______=======_====I====S===E==P==X====__======s====================
ZLC======L-----
AgI:
H e x a g o n a l c r y s t a l s 298.15
t o 9 2 3 K.
Crystals 1298.15,to
H411:
C u b i c c r r e t a l s 4 2 3 t o 8 3 1 K.
4 0 3 K.
c r y s t a l s 11 4 0 3 t o m e l t i n g p o i n t 5 2 3 K -
L i q u i d 5 2 3 t o 6 2 7 K.
TEIP.
(H:-H:~~)/T
J/mol.K
S;
- ( G ; - R ~ ~ ~ ) / T C;
298.15
0.000
UNCERTAI NTI
115.98
1.67
115.48
FOBBATION PROM THE ELENBITS

GIBBS
ENTHALPY
n,
J/mol*K
J/mol-K
FOBIATION PPOI THE ELEIEUTS

P R EGIBBS
E ENE~GI
___________________---------------_----_-------_--------------------
..-
J/mol*K
kJ/mol
kJ/aol
56.82
-61.840
-66.254
1.67
1.674
11.607
1.757
0.308
TEap.
( H ~ - H ; ~ ~ ) / T S;
-(G;-H;~~)/T
C:
EYTHALPY
FREE ENEBGY
Log K f
J/mol- K
J/mol- K
J/mol- K
J/mol. K
kJ/mOl
kJ/mol
___________________-----_----_------_----_-------------_---------_---298.15
0.000
181.33
6.28
181.33
6.28
20.334
204.77
184.44
-105.437
1.674
-102.203
2.552
17.906
0.447
_____________-______---_--400
82.01
-121.977
-100.475
13.121
____________________-----38.108
229.77
191.66
84.12
-161.813
-91.682
9.578
79.775
282.42
202.64
102.09
-139.467
-79.817
6.949
___________________--------___________--__________________-------_
IELTING POINT
831
K
ENTHALPY OP IELTING
G98
kJ
kJ
IOLAB VOLUME
a.
IODINE.....
B.
P.
P.
kJ
4.1301
41.301
TRANSITIONS I N BEFERENCE STATE ELEIENTS

SILVER.....
24.351
1 15
BOILING POINT
EYTHALPY OF IELTING
18.828
kJ
kJ
MOLAR VOLUIE
'0298
H;
cm3
TBAUSITIOUS I U REFERENCE STATE ELEMENTS

HEBCUBI....
8.
P.
6 2 9 K.
IODINE...--
8.
P.
386.75,
1 2 3 4 K.
386.75.
6.
P.
4 5 8 K.
1.0083~10-2 T
BEFEREYCE
523
J/bai.
C;
IELTING POIUT
120
263
298
627
59.166
kJ
BOILIUG POlllT
'
423 K )
263
COIPILED
8.
P.
4 5 8 K.
7.1840
71.840
J/bar
cm3
- - --
- ----
T
A-
WITHERITE
..................................................................
BaCO,:
POBnULA WEIGHT
197.349
299
POBlULA HEIGHT
197-349
====____-~_==~============_==E===S__===_===============================-=
O r t h o r h o m b ~ c c r y s t a l s 298.15
1241 K -
H I G H TEIPEBATOBES
~~~~~~~~~l
crystals1079 to
t o 1079 K.
uKthorho.~lc
BaCO,:
C u b l c c r y s t a l s 1241 t o 1 6 0 0 K .
1 2 4 1 K.
crystals
298.15
t o 1079 K.
T e t r a g o n a l c r y s t a l s 1079
C u b l c c r y s t a l s 1241 t o 1 6 0 0 K -
___________________----------------------------------------------------------(H;-H;~~)/T
TEIP.
J/mol-K
S;
-(G;-H;~~)/T
J/moleK
J/mol-K
POBBATION PROM THE E L E ~ E N T s

GIBES
ENTHALPY
FREE E N E R G Y
L~~ K f
C;
J/mol-K
kJ/nol
TeaP.
(H;_"98)/~
J/*o~.K
kJ/nol
------------------------------------------------------------------------------298.15
0.000
UNCEBTAINTY
112.13
2.09
112.13
2.09
85-35
-1210.850
2.230
-1132.210
1 9 8 . 3 ~ ~
-1210.011
-1209.55U
-1105.461
-1079.381
-1209.498
-1208.319
-1053.335
-1027.417
91.701
76.b67
2.240
0.392
400
500
23.575
39.400
139.25
lb2.13
115.68
122.73
98.U2
106.59
600
700
51.173
60-506
182.17
200.12
131.00
139.61
113.36
119.57
800
900
1000
68.264
74.956
80.885
216.48
lJ1.60
245.74
148.22
156.64
164.85
125.54
131.38
137. 1 5
-1207.305
-1205.493
-1203.282
-1001.631
-976.011
-950.629
65.400
56.646
49.656
1079
85.640
256.91
171.27
141.68
-1209.054
-930.172
45.030
101.917
273.19
171.27
154.81
-1191.491
-930.171
45.030
276.02
289.49
2YS.01
173.09
182.24
l8b.28
154.81
154.61
154.81
-1190.616
-1186.910
-1185.454
-924.964
-900.986
-891.519
43.923
39.219
37.525
_______-___________----------------
---------------------------------------.
297.53
304.4Y
316.28
327.24
337.50
186.28
191.07
199.60
207.74
115.54
158.98
158.98
158.98
158.98
158.98
-118L.328
-1179.876
-117'1.7~~
-1171.549
-1167.411
-891.519
-877.427
- 5 4 5
- 8 3 1 5 1
-808.986
nELT1NG POINT
BOILING POINT
EUTHALPY OF MELTIN6
kJ
ENTHALPX OF YAPORIZAl l ~ t i
kJ
BOLAR VOLUNE
~:98
- HP)
37.525
35.256
31.876
28.956
1b.qll
4.5810
..... ALPHA ~ I ; T A5dL.

n.
F.
BRA-GANNA
FORHATION PROI THE OXIDES

GIBBS
FREE ENERGY
ENTHALPY
J/molSK
kJ/mol
85.35
-269.240
2.09
kJ/mol
38.096
-199.799
-182.656
-165.711
*
*
26.091
19.082
14.426
-148.987
-132.473
-1l6.2Ul
-100.172
-87.766
11-117
8.649
6.744
5.232
4.249
-217-4ub
0.770
0.780
*
*
*
139.25
162.13
182.17
115.68
122.73
131.00
98.42
106.59
113.36
-268.760
-267.891
-266.745
60.506
68.264
74.956
80.885
85.640
20u.12
216.48
231.60
245.74
256.91
139.61
148.22
156.64
164.85
171.27
119.57
125.54
131.38
137.15
141.68
-265.328
-263.618
-261.580
-259.193
-256.515
1079
101.917
273.19
171.27
154.81
-238.953
110"
,200
102.926
107.250
108.734
276.02
289.49
295.01
173.09
182.24
186.28
154.81
154.81
154.81
-238.100
-234.038
-232.460
1241
111.254
297.53
186.28
158.98
-229.333
1
1400
1500
1600
113.ULL
116.679
119.495
121.963
304.49
316.28
327.24
337.50
191.07
199.60
207.74
215.54
158.98
158.98
158.98
158.98
-226.872 *
-222.700*
-218.668 *
-214.757 *
BELTING POINT
BOILING POINT
ENTHALPY OF HELTIYG
kJ
ENTHALPI OP VAPORILATION
kJ
HOLAR VOLUBE
*
*
*
*
-87.766
-84.701
-70.933
-65.740
*
*
*
*
4.249
4.022
3.087
2.767
*
*
*
*
1241
___~_____~__~~-~-__-----------------------_--------------------------------
-65.740
-57.623 *
-4~-712*
-32.188 *
-19.893
2.767
2.315
1-670
1-121
0.649
kJ
4.5810
45.810
J/bdL
cm3
TRANSITIONS I N REFERENCE STATE OXIDES

168,
n. u . ~ n n n n ~ u o i .
2 1 6 9 K.
HEAT CAPACITY E ~ U A T I U N ~
ci
112-13
2.09
J/bar
TfiAtiSITION5 I k REPEBENCZ JTATE E L E ~ E N T ~

EARIUN
112.13
C;
23.575
39.400
51.173
-----------_-_--__--------------
102.926
107.250
108.734
111.254
113.412
116-619
119.495
121.963
u~cEBTAIUTY
-----------_----___-------------
1079
~ / m o l - ~ ~/mol-K
0-000
1 4 4 . ~ 5 ~
112.763
1100
1200
1241
1241
1300
1400
1500
1600
298.15
-(G;-H&~)/T
S;
81.d01 t
5.b484x10-2
T
(hYUAT1Ob YALlD FROB
HEAT CAPALITY EQUATIONS
298
3.3107~10a T - J
- 1079 K )
C;
81.001 +
5.6484~10-2 T
(EQUATION VALID PBOB
298
3.3107~10~
T-'
- 1 0 7 9 K)
___ ________________
-------------------------------------.--...
REPEBENLE
155
llb
CUMPI-ED
BEFEBENCE
155
120
COBPIL E D
6-26-76
.,
302
P R O P E B T L E S AT H I G H
CALCITE
FORlULA UEIGHT
100
================================================================-==========
CaCO,:
c r y s t a l s 298.15
CaCOJ:
..............................................................................
TE~P.
( B;-H;~~)/T
J/mol-K
298-15
0*000
UNCERTAINTY
400
500
600
700
23.175
-(G;-H;~~)/T
S;
J/nol-K
J/DOl-K
91-71
0.20
C:
91-71
0.10
so-18o
118-36
140.88
160.43
95-18
102. 1 3
110.25
97.00
104.54
109.87
59-021
177-70
118.68
114.16
38-750
800
900
1000
66.150
72-089
77-170
1100
1200
193-19
207-27
-1207.370
1.339
-1128.84~
-1206.301
-1204.822
-1~03.276
-1101.155
-1076.292
-1050.723
143.927
I 12.440
-1201.791
-1025.427
76.519
1-381
81-610
232.23
150-62
117.54
-1197.837
-925.510
43.94
85-563
243-45
157-89
130-52
-1,?04.162
-900.161
39.1a3
720,
U.
8NTHALPY OF VAPORLZATION
P.
6.
p.
115
J/mol.K
3.6934
36.934
91.~1
0. L O
83.~7
-178.771
1.000
-130.985
1.040
22-y47
-114-781 *
- 9 9 - 0 4 ~*
-t33-55U*
1q.984
10.347
7-L7J
-b8-26J
5-0y4
-51.152
-38-224
-23-4b1
118.j6
140.88
160.43
95-18
102. 1 J
110.25
97.00
104.54
109.87
-178.041
-177-OJ2
-175.889
59.021
117.70
66.150
19J.19
~ ~ - 0 8 9 207.27
77.170
220.22
118.68
127.04
135.18
143.05
114.16
117.88
121.28
124.48
-174.6J6
-173.289
-171.831
-170-252
~ ~ 2 . 2 3 150.62
143.45
151.89
127.54
130.51
6
-166-677
81.610
85.56~
kJ/mol
---------------------------------------
20
U.
kJ/nol
Kf
*
**
*
3-470
L-218
*
*
O.qL1
-OeL4j
_ _ _.
_
_.
_
.. _ _ .
MELTING POINT
BOJLIBG PIJINT
kJ
ENTHALPY OF nELTING
kJ
BNTHAi.PY OF YAPOllIZATIO8
xJ
HOLAR YU:.[lflb:
J/bar
cm3
kJ
I . b y 34 J / b a r
rm3
jh.YJ4
REFERENCE STATE O X L D 5 2
1 7 5 5 K.
HEAT CAPdClTY EQUATION
99-715 +
2.6920~10-2 T
(EQUATION VALID FRO#
REFERENCE
J/mol-K
91-71
L3-175
38-750
50.180
TRANSLTIONS I N
BETA 1112,
- ( G ; - H ~ ~ ~ ) / TC;
POBUATION PROH THE OXIDES

GlBBS
ENTH~LPY
FREE ENERGY
L"q
C:
O.OOO
298UNCERTAINTY
......................
BOILING POINT
NOLAR YOLUHE
S;
...............................
TRANSITIONS I N BEPEBENCE STATE ELEnENTs

ALPHA-BETA
65.309
56.599
49-639
................................................................................
CALCIUN.---
................................
120-22
kJ
91.47y
-1000.238
-975.195
-950.299
kJ
0.242
-1201.145
-1199.789
-1198.689
ENTHALPY OF MELTING
(,,;-H;98),T
J / ~ ~ ~ . K j,,.ol-K
117.88
1L1.18
124.48
t o 1406 K -
L _ _ _ _ _ _ _ _ _ ~ _ _ _ ~ - . _ _ _ _ _ ~ _ . . _ _ ~ ~ _ _ _ _ _ ~ _ _ _ . . _
127.04
135-18
143.05
MELTING POINT
TEBP-
Kf
rJ/mol
83-47
303
___________________------------------------------------------------------------
k'ORBATION PBOH THE ELEBENTs

GIBBS
ENTHALPY
FREE E N E R G Y
L~~
j/mol.~
TEMPERATURES
POR,YULA WEIGHT
10U.U89
=======================-------~---------_ _ _ _ - _ _ _ _ _ _ _ - _ _ _ _ = = = = = = = I _ = = = = ; = = = = = = = = = = = = L = = : = = = =
t . ~1 4 0 0 K.
C r y s t a l s 298.15
..--
THEB~ODIUA~IC
PBOPEETIES O F ~ I H ~ A L S
14 3
- 2.15761106
298 - 1200 K )
T-Z
C;
__214
................................................................................
COUPILED
7-27-76
99.711, +
2 . b y ~ l r x l U - ~T
( E U ~ A ~ I VUA N
L I D YHOK
____ _ _ _ _ _ _ _
PEPEBENCb
______
L9d
2 . 1 5 7 6 ~ 1 ( ; ' T-.'
- 1LUV n )
----
11 5
.:1 4
24 I
__-
---- - -
CUnPILED
I-27-7b
304
305
p m p m ~ x gAT
~ RIGE T ~ B p x ~ A T O R ~ S
TRE~8ODYNA8IC PPOPERTIEs, OF ~ I N E R ~ S
?ORBULA YRIGRT
DOLOBITE
FOPHULA YEIGBT
184-@03
184.yqj
----------I
Ca89(COz)~:
C r y s t a l s 298.15
t o 1000 K.
Caug(C~,)t:
c r y s t a l s 298.15
t o 1000 K -
___C_______________
___I___II-_____--------------------------------------
FORBATION Pi108 T B E ELEUENTS
T~up.
( ~ ; - H ; ~ ~ ) / T S;
- ( G ; - H ~ ~ ~C;) ~
J/8Ol-K
J/mol'K
298-15
O.OoO
UNCERTAINTY
J/aol-K
155.18
0.29
155.18
0.29
157.53
43-600
73-520
96.110
14-003
205-32
248-35
286-43
320-53
161-72
174-83
190.32
206.53
183.53
201.88
215.65
226.64
128-685
141-103
351-42
379-73
222.74
138-63
236.07
244.72
looO
151-888
405.96
254.07
llOo
161.481
430-48
269-00
400
500
600
700
UELTING POINT
ENTHALPI OF UELTIYG
kJ
- HE
'"28
25.983
kJ
GIBBS
FREE
ENERGY
ENTHALPY
J/aol-K
ALPBA-BETA
nAGNESIU8..
8.
P.
720.
9 2 2 , B,
P.
n.
378-71
0.29
-2323.420
-2321.333
-2318.730
-2315.875
-2106.176
-2052.098
-1998.480
-1945.344
275.040
214.382
173.984
145. 164
-2313.615
-2310.455
-1892.522
-1840.054
123.570
1o ~ . ~
253.14
-2316.263
-1787.193
93.354
261.33
-2312.986
-1734.441
82.362
...............................
BOILING POINT
ENTKALPX OF VAPORIZATION
kJ
6.4340
64.340
p.
5-'788x10z
t
REFERENCE
0 - 16759 T
2.8400110*
T-2
(EQUATION VALID FPOII
151
244
155.18
157.53
0.29
0.29
-300-881
1.120
43.600
73-520
96.110
114.003
205.32
248.35
286.43
320.53
161.72
174.83
190.32
206.53
183.53
201.88
215.65
226.64
1000
128.685
141.103
151.888
351.42
379.73
405.96
222.74
238.63
254.07
236.07
244.72
253.14
-300-071
-298-556 *
-296.484
-293-963
-291-056
-287-758
-284-034*
llOo
161.481
430.48
269.00
261.33
-279-822
goo
kJ/.ol
-200.249
1.130
-165-963
-132-591
-99.594
-66-973
-2-831
EUTHALPI OF BELTING
kJ
ENTRALPY OF VAPORIZATION
kJ
8OLAR YOLUaE
25.983
21-673
13-852
59-614
BOILING POINT
8:
-2-900
28-566*
35.081
4.99B
2.2b8
0-168
-1-492
-34-735
UELTING POINT
80298
kJ
6.4340
64.340
J/bar
ca3
TRANSITIONS I U REFERENCE STATE OXIDES
1755 K.
1361 K.
BEAT CAPACITX EQUATIOU
C:
155.18
O.OOO
700
J/bar
cm3
kJ/'ol
J/.olmK
500
~,,
C;
J / ~ o ~ - K
298.15
...............................
B E T A 1112, B.
P.
-(G;-~;g8)/T
S;
_____________
-2161.672
1.670
8OLAB VOLUlE
("-8"8)8)/T
J / a o l . ~J/.ol-K
-2324.480
1.460
I N REFERENCE STlTE ELEIEITS

CALCIUfi----
IEaP-
L~~
l
kJ/mo1
POPIATION FROB THE OXIDES

GIBBS
EYE'GT
log'f
EIITHALPY
298
7.7076110~.
1100
12
6.547g1703
T-o.s
x)
225
COBPILED
REFERENCE
2.8400110* T-'
151
244
298
1100 5 )
225
COBPILBD
8- 2-76
306
THERIIODYNAMIC PROPERTIES O F H I N E R B L S
~~
307
AT n I G n TE~PEBATUPES
PB,-,PE~TIES
MAGNESITE
PURUULA YEIGHT
84.314
-----------------------------.-------------------------------------------_-===_===========_=_=========================-
ngco,:
C r y s t a l s 298.15
~ o R ~ U L YEIGHT
A
t o 1000 K.
c r y s t a l s 298.15
figcox:
s;
( H;-H;~~)/T
J/mol-K
298-15
0-UOu
UNCERTAINTY
400
500
b00
700
800
- ( G ~ - H ; ~ ~ ) / TC:
J/mol-K
J/nol- K
65-09
0.14
FOt(flATLUN FROM THE ELEMENTS

GIBBS
ENTMALPY
FBEE ENERGY
L~~
,J/mol. K
65.LI9
0.14
76.09
YUO
21.400
3h-206
47.463
56.500
b4.Ub7
70.611
8'1.67
11U-Y4
12Y-t)J
146.8Y
162-51
176-99
ho.i7
74.1J
iJi.37
9 0 . 19
YU.44
106. 38
9i.51
Y9.92
107.J~
IlJ.Y6
12U.ub
lirj.a9
1000
7b-42h
190.54
114. i ?
1( 1 . 5 ~
._-_
- I I I 1.28"
1.339
Kf
UliiLING I'UIN:
ENTHALPY UP f4ELTING
kJ
EN'TllALPf O f
1-381
0 . 2 ~ ~
_ _ _ _ _-_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
K
kJ
Vbi'OklZArIDN
8Ul.ktI V u i l l h t
n.
P.
922,
8.
p.
2.8016
28.018
0-000
298. I s
U
21.400
47-463
56-500
64.067
70.b11
76.qL6
kJ/mol
76.09
-118.280
1.300
90.57
99.92
107.38
113.96
420.06
125.89
131.54
-117-810
-116.976
-115.850
-114.434
-112.711
-110.660
-108.24'J
0.14
68-27
14.73
82-37
90.39
98.44
106.38
114.11
kJ/.01
J/mOl-K
T0.14
Y
ENTHALPY
65.09
89-67
110.94
129.83
146.89
162.51
176.99
ly0..5~
36.206
ci
J/mol-K
65-09
-65-914
1.340
-48-077
-30-736
-13.592
3.j4j
20.050
*
*
*
36-529
s2-767
11-547
*
*
*
*
*
h-278
3-211
1-183
-0-250
-1-'09
-La756
------------ -- _--_________-_-__-_----------------------------------------------K
BELTING POINT
ENTHALPY OF UELTING
11.631
TRANSITIONS I N
BOILING POINT
KJ
ENTHALPYOF VIPOBIZATION
kJ
BOLAR VOLUHE
kJ
2.8018
28.018
J/bar
cm3
REFEREUCE STATE OXIDES
1 , 6 1 K.
298
1 . 8 ~ ~ 0 ~ 1 T0- 6
2
- 1u00 K )
C;
95
LLO
81.119 +
5 . 2 2 5 4 ~ 1 ~ - 2T
( E Q U A T I O NV A L ~ DF R O B
1.8320~10~
T-'
298 - 1000 K )
................................................................................
................................................................................
115
-(Gq-~0298)/~
H E A T CAPACITY EQUATION
81.119 +
5.2254xlO-2 T
(EQUATION VALID P B u n
REFERENCE
___---
J/bar
cm3
C:
s;
(H;-B;98),T
J,,nol.~~ / m o l - K
- 1 ~ 2 9 . q a ~ 180-361
TXAHSITIONS I N BEFEBENCE STATE ELENENTS

MAGNESIUU..
TeaP-
l
kJ/mol
.. _ .__
t a 1000 K-
pOBMATIOI PEON THE OXIDES

GIBBS
- l l y
-100U.ti85
13b.70j
-1111.9bi
- ~ I L . Y Y ~ 101.648
-1119.70~
q
u2.29b
-1 U l Y O
-917.8b6
68.492
-11ii7.uij
-8yu.652
58.154
-1 105.J99
-!jb3.668
-- __---.-- 1 112.036
8jh-156
43.676
BELTING POINT
l l . b i 1 k~
84-314
CUnPILED
7-29-76
REFERENCE
11 5
95
220
COMPILED
7-29-76
_-_-______-__-_____-------------------------------------------------------------
308
THEBMODYUAMIC PROPERTIES OF ~ I I E R U ~
RHODOCHROSITE
..............................................................................
FoPMVLA WEIGHT
114.947
~TROUTIAIITE
FORMULA WEIGHT
147.629
Is5==========X_===========--====5=-5===5===1=5===E============*=-======
UnCO,:
C r y s t a l s 298.15
t o 7 0 0 K.
-----__
TEflp-
(H>H:~~)/T
J/molmK
298.15
0.000
ONCEETAINTI
-5;
- G - H ~ / T
J/mol-K
J/mol-K
100-00
2.10
UELTING POINT
O r t h o r h o m b i c c r y s t a l s 298.15
grco,:
C:
FOBMATION PROM THE ELEUEUTS

GIBES
EUTHILPl
FREE EIERGY
LO.
J/mol-K
kJ/mol
75.52
-889.270
100.00
2.10
--

GIBES
FREE EIERGY
EUTHALPI
r-
kJ/mol
. -816.047
1.213
H e x a g o n a l c r y s t a l s 1197 t o
t o 1 1 9 7 K.
142.9b9
1.381
0.242
BOILING POINT
ENTHALPY OF MELTING
kJ
~ ; 9 8 - H:
kJ
MOLAR VOLUUE
3.1073
31.073
UELTING POIBT
BOILIIG POIUT
kJ
ENTHALPI OF MELTIIG
EITHALPT OF VAPOEIZATIOB
kJ
MOLAR VOLUME
J/bar
~ ; 9 8-
cm3
kJ
3.9010
39.010
J/bar
cm3
TBARSITIOYS ILI REFEREICE STATE ELBllEIITS

IIANGANESE..
ALPHA-BETA 9 8 0 ,
BETA-GAUUA
1360,
GAIIIIA-DELTA
1410,
n. P. DELTA 1 5 1 7 K.
STROITIUM..
C;
1 . 2 3 3 9 x 1 0 Z - 2.9399.10-3
(EQUATION VALID PROII
REFERENCE
168
214
220
T
298
4.1777xlUb
7 0 0 K)
T-2
COMPILED
I.
P.
GAMMA 1 0 4 1 , 8.
P.
1 6 5 2 K.
BEAT CAPACITT EQUATION
c>
220
68
ALPHA-GAIIUA 828,
REPEREICE
81.596 + 0 . 1 0 7 5 4 T + 3 . 1 6 7 7 ~ 1 0 . T-0.5
(EQUATIOU VALID FBOM 2 9 8 - 1 1 9 7 K )
155
120
1.39141109
T-3
COMPILED
6-29-76
-.
311
TREPIIODIUAEIC PROPERTIES O? ~ I ~ E R A L S
P P O P B ~ I ~ I B AT
S HXGE TELIPEBATUBES
STROUTIAUITE
FORMULA WEIGHT
261.350
____s_==_========L==_5=4===========
E=_====l=========__==5=5sE======E=----
SrCO,:
o r t h o r h o n b i c c r y s t a l s 298.15 t o 1 1 9 7 K .
Hexagonal c r y s t a l s 1197 t o
1500 K .
TEUP-
( H;-H;~~)/T
-( G ; - H ; ~ ~ ) / T
S;
C;
J/mOl'K
J/mol-K
298.15
0.000
UNCERTAINTY
97.07
J/mol-K
97-07
1.67
POREATION PROM THE ELEUENTS
FORMATION PRO8 THE O X I D E S

GIBBS
PBEE ENERGY
LO^ K *
G I BBS
EUTRALPY
T,M,
K
C r y s t a l s 298.15
Ba( NO.)=:
J/mol.K
kJ/mol
81.42
-234.680
1.67
(G-tI8)/T
1.110
-182.917
----
J/mol-K
J/mol-K
kJ/mol
kJ/aol
___________________------------------------_--_-------
0.000
213.80
0.84
151.38
-992.070
2.100
-796.579
2.500
139.558
0-438
400
41.700
70.272
261.76
302.86
220.06
232.59
174-97
193.70
-990.496
-987.983
-729.996
-665.149
95.328
69.488
600
700
92.275
110.357
339.70
373.40
247.42
263.04
210.70
226.90
-984.858
-600.898
52.309
800
125.914
404.73
278.82
242.67
298.15
1.120
---_____-_-___-------
BOILING POINT
tlELTIYG POINT
ENTHALPY OF BELTING
kJ
kJ
UOLAR VOLUME
ENTHALPY OF MELTING
3.9010
39.010
J/Dar
cm3
0.10754
3.1677~10'
T-0-5
1.3914rlUq
T-1
C;
298 - 1 1 9 7 K )
-------------------------------------------------------------------------------155
120
-474-459
30.979
BOILING POINT
kJ
ENTHALPY OF VBPORIZATION
kJ
nOLAB VOLUME
kJ
8.0580
80.580
J/bar
ca3
ALPHA-BETA 5 8 2 ,
8. P. 2 1 6 9 K.
BETA-GAUUA 7 6 8 .
U.
P.
G A H f i A 1002.
(EQUATION VALID PBOH
REFERENCE
-973.561
TRANSITIONS I N HEPEREUCE STATE ELEUENTS

BARIUM.....
81.596
865
-979.605
-537.259
40-091
____________-__-___----------
kJ
TRANSITIONS I N HEPEREUCE STATE OXIDES
LO9 Kf
213.80
0.84
FREE EMERGY
J/mOl-K
UELTING POINT
,-;
ENTHALPl
J/nol-K
32.045
--------------------------------------------------------------------------------
G98 -
C:
kJ/mol
COMPILED
1 . 2 5 5 4 ~ 1 0 2 t 0.14967 T
( E Q U A T I O NV A L I D F a o n
298
1.bb97xlU6 T - ~
- 8 0 0 K)
---------- _________-_______-_-------------------------------------------------COnPILED
214
REFERENCE
238
214
6-28-76
---313
PBDPEBTIES AT BIGH TXIIPEBATURES

CALCIUM IITBATE
FOBMULA QBIGHT
169.090
FOBIULA YEIGBT
c a ( YO,),:
c r y s t a l s 298.15
to
O r t h o c h o m h l ~c ~ y s t a l s298.15
,.yo,:
-------------_-_-_--_--__--_-__________
....................................
TEMP-
( H:-H;~~)/T
J/mol.K
SG
298.15
0.000
UNCEBTAI NTI
~/mol-K
193.30
0.40
193.30
0.40
m e l t l n g p o i n t 610 K.
FORIATIOY FROM THE ELEIEYTS

GIBBS
-(G;-H;~~)/T
J/mol-K
101.103
800 K.
J/mol*~
k~/mol
149.37
-938.390
1.510
1-760
--130.168
0.308
Bhombohedral z r y s t a l s 401 t o
6 1 0 t o 700 K -
___----TEIp.
kJ/.ol
-792.985
-quid
t o 401
1
K.
POBIATIOY FBOI THE ELEIEYTS

GIBBS
)IT
S:
-(G:-H;~~)/T
J/mol-K
J/mol-K
J/mol-K
298.15
0.000
UUCEBTAI
NTI
133.09
0.67
26.045
26.293
163.09
163.38
( H:-H:~~
___-----
C;
EUTHALPY
F R E E ENERGY
J/mol-K
kJ/mol
kJ/mol
133.09
0.67
96.27
-494-460
0.420
-394.544
0.420
137.04
137.09
108.41
108.53
~ o g
K~
69.123
0-074
_______-___-___-----------------495.591
-495.458
-360.141
-359.970
47.030
46.891
___C__________-____---------___-_-----__---__--------------------------*-----
IELTIUG POIUT
ENTHALPY OF IELTIUG
498
-4
BOILIYG POIYT
kJ
EYTHALPY OP VAPOBIZATIOU
kJ
MOLAR VOLUIE
6.6090
TBAUSITLOUS I N BEPEBEMCE STATE ELEIEYTS

CALCIUM....
ALPHA-BETA 720.
1. P.
BETA 1112.
66.090
8.
P.
40.901
56.736
67.362
68.384
177.99
204.68
226.64
228.73
137.09
147.94
159.28
160.35
120.50
120.50
120.50
120.50
-489.521
-486.815
-484.043
-483.799
-321.970
-328.061
-296.576
-293.450
46.891
34.172
25.819
25.128
84.935
89.734
245.28
262.08
160.35
172.35
123.43
123.43
-473.703
-471.048
-293.450
-267.000
25.128
19.914
BOILIYG POINT
IELTIUG POINT
610
kJ
J/har
EUTHALPY OF IELTING
1 0 - 0 9 6 kJ
cm3
498
K
kJ
EYTHALPY OP VAPOBIZATIOY
MOLAR VOLUIE
kJ
4.8040
48.040
J/bar
cm3
TBAllSITIOYS I U EEFEBEMCE STATE ELEIEYTS
1 7 5 5 K.
POTASSIUM..
I. P.
336.4.
8.
P.
1030 K -
BEFEBEYCE
115
120
745
BEPEBENCE
238
214
214
COIPILED
215
COMPILED
7-2q-76
314
THERHODYNAHIC PROPERTIES OF HBNERALS

IIAGNESIUB NITRATE
FORUULA UEIGHT
148.315
~H!JOBIA-NITER
FORMULA YE1
-.....................................................................
ny(NO,),:
C r y s t a l s 298.15
t o
600 K.
HH~NO,:
(H;-H;~~)/T
J/mol-K
298.15
0.000
UNCERTAINTY
-(G;-H&~)/T
J/mol- K
J/mol- K
J/mol-K
kJ/mol
kJ/mol
164.01
1.60
164.01
1.60
141.92
-790.650
1.300
-589.181
1.420
UELTING POINT
ENTHALPY OF MELTING
4 9 8
C;
BOILING POINT
kJ
kJ
MOLAR VOLUIIE
K.
GIBES
- ( G ~ - B ; ~ ~ ) / T C:
S;
ENTHALPY
27.292
(EQUATION VALlD PROU
REFERENCE
238
214
l.tJ949r10*
298 -
Log K f
442.80
BOILING POINT
ENTHALPY OF HELTING
5.439
kJ
kJ
MOLAR V O L U ~ E
6.2930
62.930
- H;
J/bar
co3
T-2
600 K )
211)
kJ
kJ
4.6490
46.490
COMPILED
J/bar
cm3
.
58.417
FHEE ENERGY
103.222
0.249
It
K.
C;
398.4
- -- - - - - - - - - -
MELTING POINT
357.4,
PORilATION PROM THE ELEnENTS

GIdBS
ENTHALPY
FREE ENERGY
LO^ K c
5;
u n d e r g o e s p h a s e c h a n g e s a t 305.3.
melts a t 4 4 2 . 8
................................................................................
TEnP-
Ammonia-niter
REFERENCE
115
262
262
COMPILED
THEHMODYUAMIC PBOPERTIES 01 W U Z R A L S
31 6
SODA NITER
PoBflULh WEIGHT
84.995
FORMULA WEIGRT
.............................................................................
NaNO,:
a l p h a c r y s t a l s 298.15
L i q u i d 583.2
t o 549.2
( H ~ - H :)/T
~ ~
K.
B e t a c r y s t a l s 549.2
t o 583.2
K.
t o 7 0 0 K.
~/mol-K
298- 1 5
0-000
UNCERTAINTY
S;
~/m01-K
-(G~-H&,~)/T
EUTHALPP
~ / m o l . ~ ~ / m o l - ~
116-52
0.68
116.52
0.68
211.630
..........................................................
P O B U A T I O N r a o u T H E ELEUENTs
TERP-
317
PPOPSRTIE~ AX RIGA TBRPBRATOPIS
93-05
GIBBS
FREE
ENERGY
k~/mol
k~/mol
-468.020
0.420
-367.153
0.420
UELTING POINT
583.20
BOILING POINT
ENTHALPP OF MELTIIG
15.447
kJ
ENTHALPP OF VAPORIZATION
kJ
MOLAB VOLUME
---
1I
LO,
sr( NO,
crystals 2 9 8 . 1 5
)2:
9 0 0 K.
to
FORMATIOI PROM THE ELEMENTS

GIBBS
TEMP.
( H ~ - H :)/T
~ ~
SOT
-(G~-H;~~)/T
cOp
PREB EYEBGY
EUTAALPY
~ o K~
g
--
64.324
0.074
K
kJ
~:98
H:
3.7600
37.600
TRANSITIOUS X U REFERENCE STATE ELEUEUTS
J/bar
.cm3
MELTIIG POINT
BOILIUG P O I I T
ENTHALPI OF MELTIIG
kJ
EUTHALPI OF VAPORIZATIOI
kJ
kJ
MOLAB VOLUllE
G98
28.677
7.0930
70.930
J/bar
cm3
TRAISITIOUS I U BEPEREBCE STATE ELEMENTS

REFERENCE
1 15
120
215
215
STBOUTJOM..
ALPHA-GAIMA 8 2 8 ,
1. P.
GAMMA 1 0 4 1 .
8.
P.
1 6 5 2 K.
2.57571107
COUPILED
C
:
1.33891103
0.37901 T
(EQOATIOU V I L I D FBOM
298
2.3582110'
T-0's
P-2
900 1()
-________________________-____I____-----______-
PEFEBXICE
250
214
214
COMPILED
5-28-76
THERMODXUAIIC PEOPEBTIES OP M I ~ E B A L S
318
P P O P E ~ T I E S AT HIGH TEIPEPATUPES
ALUIIUUM SULFATE
A~,(so.),:
c r y s t a l s 298.15
to
1 1 0 0 K.
~ ~ 5 0 , : C r y s t a l s 298.15
................................................................................
TEBp-
si
J/nOl-K
- G - H ~ / T
J/aol.K
298.15
0.000
UNCERTAINTY
239.31
1.20
BELTING POINT
ENTHALPY OF RELTIUG
4 9 8
J/mol.K
4,
259.41
kJ/aol
-7440.840
1.800
K~
233.398
t o 1 3 0 0 K.
_____-_-----
FORBATIOU FROB THE ELEMENTS

GIBBS
EUTHALPY
FREE E G Y
LO,
J/aol-K
239.32
1.20
FORMULA WEIGHT
BPRITE
-................................................................................
-
TEBp.
( H ; - H : ~ ~)IT
FOBMATIOY PROM THE ELEIEUIS

GIBBS
S;
-( G!-H&~)/T
C:
ENTBALPY
FREE E N E R G Y
l o g K~
kJ/mol
-3099.852
1.880
BOILING POINT
kJ
kJ
BOLAR VOLUnE
543.084
0.329
__~_______
BELTING POIUT
BOILIUG POINT
kJ
ENTHALPY OP HELTlNG
kJ
EUTHALPY OF VAPOKIZATIOU
kJ
MLAR VOLUBE
J/bar
'0298
H
:
kJ

TRANSITIONS Ill REFERENCE STATE ELEMENTS
ALUnINUI...
SULFUR.....
B.
P.
9 3 3 K.
BARIUB.....
ORTHO-nONO 3 6 8 . 5 4 ,
P. 7 1 6 . 9 K.
n.
P.
nONU 3 8 8 . 3 6 ,
....-
SULFUR
8.
C:
2 . 8 7 6 9 ~ 1 0 2 + 0.15871 T
239
262
GAMBA 1 0 0 2 .
BEAT CAPACITY EQUATIOU
298
2 . 0 0 3 7 ~ 1 0 * T-3
- 850 K )
C;
................................................................................
REFERENCE
ALPHA-BETA 5 8 2 , BETA-GAMMA 768. B. P.

8. P. 2 1 6 9 K .
OBTHG-MOHO 368.54,
n. P. nouo 388.36.
8. P. 716.9 K.
262
COMPILEO
1.4120~102 3 . 5 0 6 6 ~ 1 0 6 T-2
(EQUATION VALID FROM 298
1300 K )
___________________-------------------------------------------------------COlPILED
BEPEREBCE
1 15
120
214
7-29-76
- ...
320
THEP1ODINA1IC PPOPEPT,IES 0 1 ~ I N E B A L S
AIUYDPITB
POPHULA WEIGHT
..............................................................................
CaSO.:
136.130
J/.oleK
298-15
o-ooo
UUCEBTAIUT?
400
500
600
700
C r y s t a l s 298.15
5:
-(~;-fl:~~)/T
J/nol- K
J/.o~- K
J/.ol.K
106-69
1.67
106.69
1.67
99.66
26*750
q4-450
57.920
68-949
137-47
163-16
ins-97
206-78
110.72
118.71
128-05
137.83
110.26
120.30
130.21
140.04
78-449
226.12
244.33
261.66
147.67
157.41
166.98
149.84
159.62
169.39
..1434. 110
4.226
k~/mol
12gSgg8
104.951
87.066
500
700
-1491.651
-1488.282
-1484.470
-1133.629
-1089.009
-10uq.846
74.019
b3.205
54.577
8oo
227.12g
---------------_______-------
278.26
176.34
179.15
- 1480.207
- 100 1.097
lO8-759
115.299
l2l-600
294-27
309.77
324-85
185.51
194.47
203.25
188.90
198.65
208.39
-1482.418
-1475.005
-1466.695
-957.125
-913.692
-870.782
28.033
- Hi
BOILING POINT
kj
kJ
ALPBA-BETA 720. I. P.
CALCIUI....
BETA 1112, B.
P.
120
214
282.84
0.85
275.01
37~.45
445.2g
511.83
572.27
294.27
317.15
344.15
372.48
319.69
351.28
379.15
405.58
628.11
400.98
431.35
-2576-930
2.930
-2249-555
3.010
394*114
0.527
-2583-862
-2586-067
-2585.415
-2582.307
-2136.699
-224-444
-1912-270
-1800*298
279-025
211-493
166*479
134.340
-2741.246
-1705-547
111-361
36.711
32.489
____________________________________-__-------------------K
MELTING POINT
EUTBALPY OF HELTIYG
J/bar
cn3
I1
1755 K.
214
282.8u
0.85
~ 7 . ~ ) ~
115
k~/mol
41.663
4.5900
45.940
TBAnSITIOuS I N BEPmEUCE STATE ELEIENTS
kJ/.ol
J/.o~.K
______
IOLAB VOLUHE
~/mol-K
___________-_e------
-1244.262
-1105.527
-1166.775
101-917
EUTHALPY OF 1ELTIUG
~NCEBTAINTY
-1437.948
-1438.205
-1437.601
'loo
1723
o.OoO
298. 15
0.733
76. 175
128.144
167.683
199.790
1200
l o
IELTIYG POINT
J/.o~.K
_______________________-______________-------------------
-----------__-_____------------1136.727
-1282.908
167.531
94.683
86.922
C;
y0~1~~1O
YPOI
l l THE ELEaEnS
GIBBS
ENTHALPy
FEEE EIEBGr
Log 'f
( 8;-H;98
J/.ol.K
------_____
-1321.696
231.557
'4.184
800 K -
-(G;-H:~~)/T
S;
rEnP.
k~/.~l
to
C____I____________________________--------------------------------
POBIATION PBOI THE ELE~ENTs

GIBBS
EUT~ALPY R E E
N
800
900
1000
BE?EBEICE
399-867
C r y s t a l s 298.15 t o 1400 K.
-------___
'q98
p o ~ 1 o L A YEIGHT
p ~ p s I CSOLPATE
pe,(~~.),:
I(
321
p m p ~ ~ A~T ~BIGB
g sT ~ ~ P ~ B A T o B X S
COIPILED
7-27-76
TBANSITIOUS IN
IEON.......
SULFUR.....
BOILING POINT
kJ
E ~ T H A L P I OP VAPOBIZATXO~
kJ
IOLAB VOLUIE
kJ
13.0770 J / b a r
130.770
cm3
BEFLBEICE STATE ELEaaYTS

CURIE P. 1042. ALPHA-GAIIA 1184. GABIA-OXLTA
I. P. DELTA 1809 K.
ONTHO-ION0 368.54. 1. P. HOBO 388.36.
B. 9 . 716.9 K.
1665.
C;
2 . 3 3 5 9 ~ 1 0 2 + 0.24933 T
(EQUATION VALID PBOn
BEYEBEICE
212
212
298
8.723011Om T-3
800 K )
14
COIPILED
6-28-76
--------------------------------------_-______________________________________
_____________-_____________________-___-----------------
P W P B P T I E S AT H I G H T B M P ~ n l T U n B S
K,sO,:
O r t h ~ r h o m b i cc r y s t a l s ( a l p h a )
298.15
(beta) 8 5 6 t o melting p o i n t 1342 K.
t o 856 K.
Hexagonal c r y s t a l s
l i q u i d 1342 t o 1700 K.
_-__--_------_-----__------------_---------------_--------_-----_--_____
--m R N A T I O Y PBOM T E E BLEMEIBIPTS
--
PORMATIOU FROM T E E ELBMEUTS

GIBES
TBnp.
--
(ii;-noZg8)/~
J/mol.
S:
-(G;-B&~)/T
J/mol-K
EYTBALPI
C:
J/mol- K
J/mol.
FREE ENERGY
1.09
K~
kJ/.Ol
tJ/mol
________L_______________----------------------_------------------_--
298.15
0.000
u#CBOTAI U T I
204.60
1.26
204.60
1.26
192.97
-2470.150
1.300
-2239.790
1.380
392.404
0.242
400
500
600
700
54.525
92.070
120.073
142.010
267.25
321.22
368.60
410.76
212.73
229.15
248.53
268.75
230.89
252.19
267.34
279.58
-2477.813
-2479.424
-2479.034
-2477.202
-2159.839
-2080.032
-1000.262
-1920.570
282.047
217.300
174.139
143.315
800
900
159.885
174.922
448.80
483.56
288.92
308.6Y
290.27
300.06
-2583.688
-2577.590
-1852.324
-1761.151
120.945
102.21 5
1000
187.901
515.66
327.76
309.30
-2581.667
-1670.019
87.233
................................
HELTIUG P O I N T
BOILING POINT
EUTHALPY O F I I E L T I N G
kJ
kJ
kJ
HOLAR VOLUBE
----I----------I-----_------------__---_--
MELTXU6 P O I U T
1342
37.907
E U T B A L P I O F FIELTIUG
~2098
BOILIRG POINT
kJ
E Y T E A L P I OF V A P O R I Z A I I O I
tJ
498
kJ
800
N O L A 8 VOLUHE
T R A N S I T I O N S I11 B E P E R E N C B S T A T E ELEMENTS
T R A U S I T I O N S I N RBFEBBUCB S T A T E ELEIIENTS
POTASSIUM..
H.
P.
336.4,
ALUMINUM...
H.
P.
933 K-
RBAT C A P A C I T I IWUATIOUS
C;
120.37 +
9.9579110-2
r
( B Q U A T I O N V A L I D FROM
= -8.4452~102
0.68449 2
( B Q U A T I O Y V A L I D PBOM
1.7824110"
- 856 K )
T-2
3.4994~10.
1342 K )
f2
298
+
856
C;
239
215
215
............................................................................
COIIPILBD
6-28-76
1030 K.
8.
2.3700~102 + 7.8284~10-2 T
( E Q U A T I O N V A L I D PROM 298
REFERENCE
............................................................................
PBPBPINCB
P.
ORTUO-MONO 368.54,
8. P. 716.9 K.
SULPUR.....
C:
8.
265
26 5
P.
HONO 388.36,
5 . 9 8 8 4 ~ 1 0 6 T-2
1000 K )
265
COIIPILED
6-28-16
--.-.--.
.
324
THEPIIODIIAIIIC PPOPEITIm, OP ~ I ~ E P ~ L S
ALUIITE
.......................................
FOPIIULA SSIGBT
=
0 . :
K z A I H1
pmp~n1.3
~ r p 3 t a l . s 298.15
828.40~
HIOl fEIIPSSATORES
325
POPIIULA SEIGUT
y y ~ ~ I I S SULFATE
E
150-996
wZLIy~-'"L-=YI~-~Y-Y=*==~=-~=~=~~=Ly-=-=====--=====-=-=========
Enso.:
t o 700 K.
C r y s t a l s 298.15
t o 1000 K.
_____________________-_________________------------------------(Cfl;98)/~
J/.ol.K
29B-15
0-000
UYCEBTAIYTI
400
500
600
700
S:
-(G;-H&~)/T
J/.ol.
J/MOl.K
216-150
367.720
481-010
569-996
C;
EYTBUPI
~/.ol- K
656.05
3.77
656.05
3.77
745.17
904.24
1121.21
1312.01
1482.08
688.09
753.49
831.00
912.08
925.89
1014.91~
1077.37
1129.36
GI BBS
E
?OHIATIOI ?POI THE ELEMSYTS

GIBES
Log
--_
_--
----_
_--
-__
-__
IELTIYG POIYT
BOILIUG POIYT
EYTHALPI OF IELTIUG
kJ
EYTBALPI OF VAPOBIZATIOU
kJ
IOLAB VOLOIE
I.
P.
336.4,
bLOII1UI...
8.
P.
933 K.
B.
P.
OBTHO-IOYO 368.54.
B. P. 716.9 K.
8.5901110'
+ 0.41235 T
(EQUATIOY VALID F W I
BEPEBEYCE
121
120
~/mol-K
J/mol-K
C;
J/80l.K
EYTBALPI
FREBEMeRGI
LogKf
k~/mol
kJ/.ol
__________________4__-______---------------------------------
112.13
0.85
112.13
0.85
100.50
-1065.250
1.050
-957-326
1.300
167.720
0.228
28.175
47.368
61.620
72.754
144.50
172.17
(96.38
217.88
116.32
124.80
134.76
145.13
118.66
129.00
136.45
142.52
-1067.444
-1068.017
-1067.759
-1066.914
-920.119
-883.166
-846.259
-809.388
120.156
92.264
73.674
60.398
81.815
89.433
237.27
254.97
155.46
165.54
147.87
152.79
-1120.316
-778.230
-735.572
50.813
42.692
96.002
271.31
175.31
157.45
-693-261
36.212
-----
---
-1117.466
................................
-1116.615
IELTIYG POIYT
BOILIYG POIUT
kJ
BETBALPI OF IIELTIYG
kJ
EYTHALPI OF VAPOBIZATIOU
'0298
- 8i
4,3620
43.620
WLhB VOLUME
k3
J/bac
cm3
TPAUSITIOYS ItI BEFBBEIICE STATE ELBllEYTS
1030 K.
I. P.
-(G;-H;~~)/T
S:
298.15
0.000
OUCEOTAIYTY
IAYGAYESE..
SOLPUB.....
SOLPUB.....
C;
(H;-H;~~)/T
J/.~L.K
TBAYSITIOYS I N BEFEBEUCE STATE ELElEUTS

POTASSIUI..
TsEP.
_________________
~ k lJ / a o l
ALPHA-BETA 980, BETA-GAEIA 1360. GAIIEA-DELTA

I. P. DELTA 1517 K.
OBTBO-I080 368.54, I. P. 1 0 1 0 388.36.
B. P. 716.9 K.
1410.
IOU0 388.36.
298
C;
6 . 2 7 5 6 ~ 1 0 * T-3
700 K )
COIIPIL ED
6-29-76
1.2028~10* + 3.9993~10-* T
(EQUATIOY VALID FBOI 298
BEFEBEUCE
242
263
2 . 8 1 8 1 ~ 1 0 * T-2
1000 K)
263
COIIPILED
6- 8-76
TB~JWJDIMABICPSOPXOTIES
326
m r r p t g s AT
01 ll"PALS
- d ~ e rTBLIPBBATUlES
JL
LIASCAGYITB
POOBULA WEIGHT 132. l j l
=D=========================-=======P==E=L~S~=iC~===~~-==L==I==============I~
(aHo)zsoa:
C r y s t a l s 298.15
pOPBULA PEIGBT
115-104
t o 600 K .
___________________
('iH;98)/~
~/.ol-n
298.15
0-000
ONCEBTAI NTY
400
500
51-350
87-048
115*488
S:
J/lOl.K
:
C
J/mol-~
ENTHALPY
kJlmol
J/.o~-K
220-08
1.25
220.08
1.25
187.49
279-15
330-31
377.22
227.80
203.26
261.73
215.88
243.76
271.64
POBMATION PRO# THE ELEMENTS

GIBES
GIBES
FREE E N E B G ~
-(G:-"~~)/T
J/lol.K
kJ/.o1
-1180.850
1.255
- g o ~ . ~157.971
~ ~
1-339
0.235
-1185.821
-1187.521
-1186.375
-805.519
-710.150
-614.781
j/mol-K
105.190
74.189
53.522
---
177.40
--_
---
---
80.670
102.192
125.093
88-53
126.64
170-24
197.12
223.63
255.57
-------
-------
---
kJ
E U T H A L P YO F BELTING
kJ
MOLAR VOLUME
---
-----
417
BOILING POINT
14.310
id
ENTHALPY OF VAPOHIZATIO8
kJ
kJ
BOLAR VOLUlE
6.5070
65.070
J/bar
TRANSITIONSI N REPEBEUCE STATE ELgMENTS
... OBTBO-H0N0
8.
1 . 0 4 3 8 ~ 1 0 ~+ 0.27876 T
(EQUATION VALID PROM 298
---
cn3
SULFUR..
_____________-------------------
---
J/bar
---
46-86
ENTHALPY OF MELTING
C;
--
40.792
MELTING POINT
TRANSITIONS Ib' REFERENCE STATE ELBBENTS
---
142.88
BOILING POINT
7.4680
74.680
log
~ f
kJ/mol
---
H;
= B E~E EYERGr
~
0.00
MELTING POINT
kJ/mol
QUCBBTAIUT~
500
600
~ ; 9 8
C;
J / ~ o ~ - K~ / . o l - K
P.
716.9
368. 54,
M-
P-
388-369
K.
C:
600 K )
63.922 + 0.31941 T
(EQUATION
VALID FROB
417
600 K)
_______-___________------------------------------------------------------------REFERENCE
121
239
120
262
262
COBPILED
REFERENCE
239
COBPILEO
6-28-76
-------
-----nxaIt
- v r . r r r r o ~ ~ g
TXIIPIIlATU1.S
SLY
POBIULA YEIGHT
TEE B l P D I T l
Orthorho.bic
crlstals ( v ) 298.15 t o 4 5 0 K.
~~.h~~h~.bi~
(111) 450 t o 514 K.
H e x a g o n a l c r y s t a l s ( I ) 514 t o 1155 K.
1155 t o 1800 K.
BazSO.:
c r y s t a l s 298.15
pbSO.:
t o 1100 K-
....................................................................
9
TEMP-
c;
g
J/.Ol-K
J/.Ol*K
J/.ol-K
~ O P ~ A T I O PHOB
B
THE E L E l E N T S
~ ' O B ~ ~ A T I O BFROB T H E ELEUEITS

GIBBS
B
A
Y
n.E
EBalry
Log
J/mol.K
kJ/.ol
127.28
-1387.790
0.420
...................................................................
298-15
0.000
OBCEBTAIITI
149-58
6.08
303- 258
m s a u L A YBIGHT
112.031
*s-=s*=====-==-=*=====--
.......................................
149-58
0.08
GIBBS
kf
kJ/.Ol
-1269.985
222.q97
0.420
0.071
--------------------___________
400
450
36.807
49.929
191-96
210- 10
155-16
160- 17
146.82
162.80
-1395.113
-1395.497
-1229.048
-1208.123
1 6 0 . ~ ~ ~
1qo.235
450
500
514
56-809
68.032
70-981
216-98
234.89
239-66
160.17
166-86
168.68
164.77
173.30
176.40
-1392.401
-1392.077
-1392.002
-1208.123
-1187.782
-1182.022
1 4 0 . ~ ~ ~
124.08~
120.1~~
514
600
700
84-651
96.290
107.514
253.34
279-30
306.23
168-68
183-01
198.72
163.78
170.78
178.92
-1380.976
-1384.277
-1382.534
-1182.022
-1148.353
-1109.125
800
YOO
116-949
125- 189
132.600
330-66
353- 16
374-15
213.71
227-97
241.55
187.06
195.20
203.34
-1434.556
-1429.852
-1424.453
-1075.797
-1031.172
-987.159
70.2~3
5 9 . ~ 4 ~
51.5~4
f100
1155
139.402
143-392
393-91
404-12
254.51
211.48
-11118.395
-943.707
4 0 . 8 ~ ~
1200
1300
lU0O
l5O0
1600
I7O0
le00
165-lU0
167.527
169-543
171.267
172-750
17'+.035
175- 1 5 5
431.72
447.42
461-93
475.41
487.99
499-79
516.89
266-58
279.89
292.39
304.14
315.24
325.76
335.74
----------------------------------___---___________________________
.........................................................
-000
148.57
0.29
109.31
0.29
179.65
204.82
227. 18
152.70
160.67
169.91
108.70
117.60
128.27
2U7.81
179.59
139.77
95.119
267.25
285.82
303.73
189.34
199.03
208.61
103.065
321.12
218.05
298-,5
148.~7
O n c ~ ~ T I AT I1
26.950
Uq.154
57.267
qoo
500
8oo
*-----___--_________
77.911
86.789
120.12~
9gS97)
82.76q
...............................
1100
-919-940
1.088
-813-026
1.046
-922.60'
-929.147
-924-675
-776-138
-739.286
-702-287
151.72
163.93
176.30
-981.9''
-977-749
-972.4b8
-632-308
-588'781
-545-834
1'286
31-172
28-512
188.78
-965-983
-503.494
23-909
142*439
0-183
___________-------------------101-354
77-233
61*190
______________-----------------928.962
-664.443
49.582
___________-------------------
'
260-72
215.96
-1414.289
-919.498
41.584
..........................................................................
1155
163-931
424.65
260.72
196.55
-1390.566
-919.498
41.584
................................
1155
MELTING POINT
23.723
ENTHALPI O I BELTING
4 9 8
-4
196.37
195.98
-1583.206
-1576,781
-896.335
-839.366
39.617
33.726
195.58
195.19
194.80
194.40
194.01
-1570.476
-1564,269
-1558.155
-1552.133
-1546.206
-702.895
-726.849
-671.219
-615.987
-561.093
L9.210
25.311
21.993
18.927
16.283
BOILING POINT
k j
kJ
BOLAP VOLUBE
_____________________________________-_-__-_------------K
1ELTING POIBT
ENTHALPI OF I E L T I B G
498
B O I L I I G POIBT
E I T H A L P I OI VAPOBIZATIO11
MLAP YOLOBE
-4
kJ
20.062
kJ
4.7950
47.950
~ n a r
cm3
T B A l l S I T I O U S I11 P S P g P I I C B STATE Z L E l E Y T S
LEAD
T R A N S I T I O B S I N BEPEBEBCE STATE ELEBEBTS
.......
SULFUR.
I.
P.
600.61
8.
P.
.... OBTBO-llOIO
368.54.
B. P. 716.9 K.
2021 K.
L(.
P-
(LOB0 388.36.
HEAT C A P A C I T I E p O A T I O l
BEAT CAPACITY EQOATIOBS
C;
C:
1 . 2 1 9 3 ~ 1 0 z t 8.1413110-2 T
( EQUATION VALID P P O l 514
46.827 + 0.12775 T + 1.7241110* T-a

1100 K )
(EQUATXOB VALID I P O I I 298
_________-_______________________--___-________--___
COBPILED
26 2
1155 K )
BEFEPEBCB
C:
2.0110110~
3.9406~10-3 T
(BQUATIOB VALID P R O l 1155
- 1800 K )
------------------------------------_--_----------------_-------_________
BXPEBEUCE
42
215
215
CONPILED
1 15
262
7-27-76
..--
InX~~UDIIiA~X
PU
C OPEPtIlS B
ZINKOSITE
C r y s t a l s 298.15
161.438
FOPIIIILA ~ B 1 6 f m 1 2 1 - 9 5 3
-------------
====_i_________
(~:-~",8)/~
J/mol-K
298.15
UNCEBTAI NTY
J/molSK
J/mol.K
110.46
1.25
104.13
110-46
1.25
400
500
600
26-375
42-712
700
140-90
16'4-9Y
114.52
122.27
55.022
1e6-21
131.19
121.41
65.259
205.71
140-45
132.09
74-312
BOO
900
1000
g
J/nol-K
224.08
2u1-64
258-59
82-633
104.85
111.90
149-77
159-01
168.13
143.38
155.02
166.90
-982.820
0.837
l
kJ/mol
0-962
-988.579
-756.123
6seeL7
-717.266
53.523
-1049.874
-1046.723
-1042.517
-683.036
-637.307
-592.033
4q.598
36.g8~
3 0 . ~
BOIL1 NG POINT
kJ
ENTHALPY OF V A P O R I Z A T ~ O ~
kJ
~ 9 9 8-
kJ
MOLAR VOLUHE
4.1570
41.570

8.
P.
692.7.
8.
P.
8.
P.
368.54,
716.9 K.
P.
J/.ol.K
o.Ooo
k J / 101
kJ/.ol
90.79
0.21
90.79
0.21
93.18
-1716.400
2.092
-16o5-B75
2.134
281.344
0.374
120.71
146.87
170.02
190.88
210.61
94.69
102.55
111.90
121.72
131- 6 0
110.97
122.97
131.01
140.52
156.82
-1716.857
-1716.242
-1715.104
-1713.577
-1796.663
-1568.013
204.763
159.928
130.054
J/bar
-1493.878
-1457.132
-1442'815
94.207
_______________________________-___-----------------------------IELTIUG P O I M
EmAALPY OF MELTING
cm3
1 1 7 8 K.
8.
~/aol-K
~ R & ~ A T Il O
BO
I l TEB BLBMBYTS
GIBES
FBgB LuEB6T
log
BII?FIALP~
...............................
ENTHALPY OP BELTING
..-.ORTHO-HOMO
J/.ol.~ ~/.ol-K
26.025
44.324
58.320
6g.161
79.005
------------------- ------------
SULPUR.
C:
ONCEBTAII~Y
108.797
83.027
-996.002
-(G;-"~~)/T
298.
0.16y
-833.141
-794.747
8 0 0 K-
________________________________-_____-_-------------------
................................
-985.596
-987.518
to
~i
I/'
( 8;_E:98
152.689
-871.530
c r y s t a l s 298.15
________________________________________--_-------------
PORflATION PBOl TBE B L E ~ E u T s

GIBES
ENTH~LPY
FREE E N E ~ ~ ,
Kf
HELTING POINT
ZINC.......
=*-=_n=_E==-===-=-=
to 1 0 0 0 R.
A1p~I:
331
p ~ ~ p l u a xA Ts 8168 TBMPEBATOBSS
PORnULA WEIGHT
...............................................................................
ZnSO.:
14.761
TBAUSITIOLIS
HOBO 388.36,
In
BOIL1 NG P O I l T
EBTEALPT 0 1 PAPOBIZITI08
kJ
MOLAR VOLOME
kJ
4.6580
46.580
J/bar
c13
BEPBBBPlCB STATE BLEBENTS
ALUMIlOU...
I. P.
9 3 3 K.
PAOSPAOBDS.
SUBLIMES 7 0 4
K.

C;
40.186 + 0.12432 T + 2 . 3 8 9 2 1 1 0 * T-2

(EQllATION VALID FROB 2 9 8
1 0 0 0 K)
REFERENCE
115
27 1
262
3
................................................................................
COHPILED
7-29-76
1 . 6 4 5 4 ~ 1 0 5 T-'
(BQUATIOI VALID PROM
298
8 3 0 K)
_-________________-__________-_____________________
COMPILBD
REPEREUCE
151
262
262
03-15-79
_-_______________________________________-______
--
mramrmx
maarc r x o t ' B R X X S O
WBITLOCIITI
N)IIBOU WBIGET
31 0.183
-===-=P-==-IY-=====-======~===*=I==5====*==~1P==-T==-===*===-
Ca,(PO.),:
Rhombohedra1 c r y s t a l s 298.15
t o 1373 K.
I o m o c l i n i c c r y s t a l s 1373
t o 1600 K.
Bhombohedral c r y s t a l s 298.15
t o 1373 K.
B o n o c l i n i s c r y s t a l s 1373
t o 1600 K.
______--___-_____-_-_______
c ~ > n ; )/T
~ ~ s:
TEOP.
c:
A)BIATIOI FBOB TEE BLBllBlTs

GIBES
EITBALPX
FEBB EIBBGI
LO^
FOBILTIOY FBOB THE OXIDES

GIBES
Teap.
J/mol-K
J/mol-K
J/mol-K
J/mol-K
kJ/mol
(A;-"~~~,/T
-(G;-E;~~)/T
S;
C;
FREE ENERGY
BYTEALPI
l o g K~
kJ/mol
________________--I____---__-_
298.15
0.000
UNCEBTAINTI
235.98
0.84
235.98
0.84
227.82
-4085.925
2.100
-3860.760
2.200
676.394
- < - -
0.84
uYCBBTAINTT
40 0
500
600
700
62.075
102.738
133.072
157.386
307.46
366.59
418.95
465.17
245.38
263.85
285.38
307.78
255.19
275.25
294.10
312.39
800
900
1000
177.887
195.822
211.940
508.06
548.00
585.60
330.17
352. 18
373.66
330.37
348.17
365.87
-4085.591
-4084.165
-4081.949
-4079.141
-3783.851
-3708.572
-3633.634
-3559.161
494.122
387.434
316.337
265.589
-4248.877
-4242.604
-4236.054
-3529.180
-3439.542
-3350.664
230.433
199.627
175.021
0.84
___-----__--_-----________
----_-_-------___-------__--_-_--__--_*___-_____l__-_-______________________
RELTI N
G POIIT
BOLL1 BG POINT
BELTING POIYT
BOILIUG POIIT
ENTEALPI O P BELTIN6
kJ
BNTEALPI OF VAPORIZATIOI
EYTEALPI OF IBLTIIG
ENTEALPI OF VLPOBIZATIOI
kJ
SOLAR VOLOlE
kJ
BOLAP VOLUBE
';98
A;
'0298
TRAISITIOIS I N BBFIBBICE STATE ELEHENTS

CALCIOI....
ALPBA-BETA
720.
H.
P.
BETA 1 1 1 2 , 0.
kJ
9.7620
97.620
J/bar
cm3
TBAYSITLOYS IY BBFltDBICC STATB OXIDES

P.
1755 K.
I. P. 8 4 2 K.
P,O,.......
PEOSPBOPOS. SOBLIIES 704 K.
BEAT CAPLCIZI BQOATIOP
EXAT CAPACITI EQUATIOI
C:
...........................................................................
BElBEBICl
1 15
214
214
1 . 9 2 8 5 ~ 1 0 2 + 0.17419 T
(EQOATIOM VALID FROB
-298 1-. 1 713367~3 1K0)* T-z
_____________________C___________________
COBPILBD
BE?SPIICE
115
214
214
COBPILLD
7-27-76
03-15-79
_
_
_
_
_
_
_
_
_
_
_
_
-----------------------_
_
__
__
_
-_
_
_
_
-.
--?~BPnODYUAJIIC P P O P S ~ ~ ~ I O
X FS J I U ~ P A L S
331)
RIDBOXIAPATITB
.-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ?OPIULA
335
~AT mHIGB
~ TEIIPEPATaPES
m
FOBIULA @ B I 6 B T
502.321;
m16ET
t o 1 5 0 0 K.
C ~ g S t a l S298.15
POo)aOB:
c r y s t a l s 298.15
Ca~pI-,~):
500.313
to 1600 K -
------------------------------------___________-_________________________
_________________-__________________--___-____---------TEHp-
s:
J/.olaK
c;
J/lOl.K
J/mOl.
J/mol-
ENTHALPY
GIBBS
PEES SNEBGI
rBIIP.
L~~ Ef
(E:-8;98)/~
- ( G ~ - H ~ ~ ~ ) /C;T
S;
F O R I A T I O I PRO5 TBB E L E n l n T S
GIBBS
SUTBALPI
FBEE B u E B G I
log Kf
k.l/mol
kJ / m o l
k w.01
j/.ol.K
J/mOl. K
J/*Ol*K
J/.ol.K
IrJ/'O1
----------------------------------_____________-_______________________
___________________------------__-_____-__-___----------------298-15
600
700
o-ooo
390-37
1.67
390.37
1.67
385.10
106-900
178- 1 4 2
229-773
269- 1 8 9
513-31
6 16-52
705-43
783-35
406.41
438.38
475-66
514- 16
446.35
477.23
497.55
513.28
300-561
UNCERTAINTY
-6669.259
5.000
-6286.093
-6667.545
-6663.244
-6658.313
-6653.651
- 6 1 5 5 . ~ ~ ~ 803.807
-6027.762
629. 719
-5901.106
513.739
-5775.324
430.9~~
298. 15
1101.302
5- OOo
0.876
~ 387.86
~ ~
400
102.725
170.858
220.715
259.059
500
600
7oo
387.86
1.67
U S B P T A IIT?
375.93
-6819.860
5.000
-6455.778
5.000
1131-033
0.876
426.53
458.27
480.52
496.94
-6818.464
-6814.827
-6810.383
-6806.063
-6331.506
-6210,
-6089.647
-5969'908
826-813
648.776
530. 153
445. 482
1.67
506.04
604-86
690.49
765- 85
403.31
434.00
469.77
506. 7 9
...............................
-------------_I____---------
800
900
1000
326.389
348.259
852-78
915.55
972-97
552- 2 2
589. 1 6
624.71
526.80
539. 1 5
550.89
'loo
367-201
1026-01
658-81
562.29
1200
1300
1400
1500
383-926
398.936
412-593
425.167
1075- 42
1121-76
1165-49
1206.97
691a 49
722.82
752-90
781-80
573.50
584.61
595. 6 7
606.72
-6909.611
-6902.718
-6897.107
-5716.202
-5567.379
-5419.322
373. 231
323.123
283.078
-6892.774
-5271.788
-6924.440
-6911.624
-6897.959
-6883.402
-5121.478
-4971.763
-4823.090
-4675.360
looO
289.611
1
6
1
335.482
833.07
893.67
948.80
543.46
579.06
613.32
509.49
519.30
527.09
250.338
lloo
353.196
999.39
6 4 6 . 14
533. 3 5
222. 933
199.769
179.952
162.811
120~
1300
1400
1500
368.427
381.665
393.271
403.535
412.661
1045.97
1089.23
1129.56
1167.31
1202.78
677.54
707.57
736.29
763.78
790.12
538.40
542 - 4 9
545.79
548.45
550.55
9oo
...............................
1600
...........................................................................
MELT1 NG POINT
BOILING POIflT
BNTKALPI OP l l g l T I N G
kJ
kJ
HOLAB VOLUHE
~ z 9 8- H:
64.245
720.
ALPHA-BETA
PHOSPHORUS.
SUBLIUES 7 0 4 K.
11.
P.
BETA 1 1 1 2 .
52
120
-5631.760
386'329
335.
294. 174
-7048.036
-5490.009
260'700
-7081.464
-7071.045
-7060.490
-7049.820
-7039.109
-5345- 348
-5201. l o 4
-5057.699
-4914.979
-4773.056
232.678
984
188-706
171.155
155'825
-5773-932
...............................
__________________________________-____-____-___---IELTIRC POIUT
BOILING POIUT
ENTHALPY OF HSLTIUG
kJ
ENTHALPI OF VAPORIZATIOU
kJ
kJ
BOLA0 VOLUIE
';98
63.471
15.7560
157.560
J/bar
cm3
TUANSITIONS I N BKPSRENCB STATE ELEMENTS

B.
P.
1 7 5 5 K.
REPEBEUCE
-5916.800
TRAWSITIONS I N REPXEENCE STATE E L E n E l T S

CALCIUU-...
-7062.361
-7055.955
-7051.144
720,
CALCIUM.,..
ALPBA-8EfA
PBOSPAOBUS.
SUBLIIBS 704 K-
1.
P.
BETA 1 1 1 2 , B.
P.
1 7 5 5 K.
HEAT CAPACITY BQUA.10.
___________________------------------------------------------------------2 19
150
COBPILED
03-15-79
REPBREUCB
52
120
2 14
COMPILED
03-15-79
D I C B S I U I UPAIATE
FOPIULA I E I G H T
567.837
====================================SE=T=========0================XEX=====I~
Cs.UO.:
C r y s t a l s 298.15
( H : - H ~ ~ )/T
~
J/mOl.K
298.15
0.000
UUCEBTAIUTI
348.006
t o 1 1 0 0 K.
----------------------------------------________
TEIP-
FOPIULA UEIGBT
D ~ S O D I U IUBAUATB ( U P R A )
S:
-( G ~ - H : )/T
~ ~
C;
J/mol. K
J/Dol. K
J/mOl.K
219.66
0.42
219.66
0.42
PORIATIOY P R O I THE ELEIEUTS

GIBBS
EIITHUPI
FREE
EIEPGr
L~~
152.76
-1920.000
3.500
to 1 1 0 0 K-
--
FOBIATIOS P B O I THE ELEIEUTS

GIBBS
K,
5;
+Eap.
k J/mol
kJ/mol
C r y s t a l s 298.15
,azOO.:
-(G~-E;~~)/T
C;
EUTBALPI
PBEB EUBPGY
Log K f
--
-1797.300
3-800
314.881
0.666
-_----------------------------------------------------------------------------IELTIUG P O I I T
E I T H A L P I OF IELTIUG
':98
B O I L I I G POIUT
Hi
30.815
kJ
EITBALPY OF VAPOBIZATIOU
kJ
MOLAR VOLUIE
kJ
8.5400
85.400
TSAUSITIOUS I U PEPEREICE STATE ELEIEUTS
BOILING P O I I T
IELTIRG POINT
EITHALPI OF VAPOBIZATIOI
EITHALPI OF I E L T I I G
J/bar
MOLAR VOLUIE
cm3
T R A I S I T I O I S I Y PEFEBEIICE STATE ELEIIEYTS
CESIUI.....
I. P.
URAUIUI-...
ALPHA-BETA
301.55.
B.
P.
9 4 2 K.
SODIOI
941.
BETA-GAIIA
1048.
8.
P.
1 4 0 5 K.
.....
URAUIUI....
I. P.
370.98.
8.
ALPHA-BETA 9 4 1 ,
1 1 7 5 K.
P.
BETA-GAIIA
1048.
I. P.
1 4 0 5 K.

co
PBPERBYCE
64
193
185
COIPILBD
1.58461102
+ 2.7434110-2
( E Q U A T I O I VALID FROM
RBFEBEUCE
64
195
298
-+
8 4 . 1 2 3 T-0'5
1 1 6 5 K)
2.2082110.
89
184
T-2
COIPILBD
5-19-76
P3 39
PBOPgnTILS AT BIG# TBHPlBA?URES

TRISODIUH U R A N I U H OXIDE
FORHULA WEIGHT
370.996
FORHULA WEIGHT
KIIUITE
162.047
-FCI5=========F========~===L==lnsrl=============~===================================
Na,UO,:
C r y s t a l s 298.15
t o 1200 K .
C r y s t a l s 298.15 t o 1 8 0 0 K.
--
TEHP.
( H ~ - H )/T
; ~ ~ S;
-(~;-H;~~)/T
FORHATION PBOH THE ELEHENTs

ENTHALPY
FREE
ENERGY
Loq K *
GIBBS
C:
_----...........................................................................
PORIt.TIOY FROH THE ELEIEYTS
GIBBS
( H;-~&8
TEnP.
)IT
J/mol-K
-(G;-H&)/T
S;
J/mol.K
C;
J/mol-K
ENTHALPY
J/aolsK
kJ/aol
l o g K~
FREE EYEBGY
kJ/mol
---- ............................................................................
K
298.15
0.000
OICERTAINTI
83.76
0.34
83.76
0.34
121.70
-2591.730
1.900
-2441.276
1.920
427.703
0.336
400
500
600
700
800
900
34.825
59.438
77.995
92.476
104.096
113.656
123.76
158.92
190.03
217.66
242.42
264.80
88.94
99.48
712.04
125. 18
138.32
151.14
149.24
165.27
175.60
182.71
187.94
192.11
-2592.612
-2592.009
-2590.697
-2589.084
-2587.414
-2585.835
-2389.682
-2339.004
-2288.516
-2238.279
-2188.275
-2138.464
312.062
244.355
199.234
167.023
142.880
124.114
1000
121.680
285.23
163.55
195.72
-2605.752
-2087.312
109.030
1100
1200
1300
1400
1500
128.566
134.589
139.959
144.836
149.345
304.05
321.52
337.88
353.31
367.97
175.48
186.93
197.92
208.47
218.63
199. 1 3
202.59
206.26
210.28
214.76
-2603.794
-2601.638
-2599.246
-2596.584
-2593.592
-2035.566
-1983.993
-1932.606
- 1881.451
-1830.465
--_-___-__--___-___------------96.661
86.361
77.653
70- 1 9 8
63.743
-------------------------------------------------------------------------------IELTI NG POINT
BOILIN6 POINT
kJ
EUTHALPY OF VAPORIZATIOU
kJ
IOLAB VOLUIE
K
ENTHALPY OF HELTIPG
'0298
31.109
H:
kJ
J/bar
TRANSITIONS I N BEFEREUCE STATE ELEHEUTS

SODIUM
..... I.
P.
370.98.
8.
ALPHA-BETA 941.
UBANIUI....
P.
BELTING POINT
BOILING POIUT
ENTHALPY OF MELTING
kJ
498
1175 K .
BETA-GABBA
................................................................................
16.041 W
H:
kJ
4.409U
44.090
IOLA8 VOLUHE
J/bar
cm3

1048, I. P.
1405 K.
ALUMINUH...
M.
P.
9 3 3 K.
SILICON....
B.
P.
1685 K.
HEAT CAPACITY EVUATIOU

C;
1.1152xlOZ + 5 . 3 8 9 4 ~ 1 0 - 2 T r
1.6100x10J
298
1212.70 K)
BEFEBENCE
62
194
T-0.5
4 . 2 5 1 0 ~ 1 0 r T-z
C:
89
COIPILED
4.3612~102
0.13576 T
298
4.7236110-5
- 1500 K)
TZ
4 . 8 0 2 7 ~ 1 0 3 T-0'5
___________________----------------------------------------------------------REFEREYCE
205
120
99
98
COHPILED
7- 8-76
--
340
TnmfiODrIAmC PPOPEIT~LS 0 1 IlxIg,ALS
341
p ~ O p ~ r I gATs EIGB TEEPEPATOPES

KIAIITE
?OPIIOLA UEI6ET
162.0~)
~ O P I O L A YEIGBT
162-047
C r y e a l s 298.15 t o 1800
C rly:s t a l s 298.15
uLltSi~
................................................................
t o 1800 K -
---------_____
FOBMATIOB FPOU TEE OIIDgS
VT
E ~ T B A ~ ~ GIBBS
~
EgEnGy
c~
A ) B ~ ~ A T I Or u
I Io n TIE ELBEEITS
GIBBS
Log
TBaP.
(Wq-B;g8)fl
............................................................................
298-15
0-000
UYCEBTAIUTI
400
500
600
700
83.76
0.34
123-76
158.92
190.03
217.66
242.42
34-825
59-U38
77-995
92-476
l04-096
63-76
0.34
121.70
88.94
99-48
112.04
125. 18
138.32
149.24
165.27
175.60
182.71
187.94
looO
113.656
721.680
264.80
285.23
151.14
163.55
'loo
1200
1300
1400
lSo0
128.566
134-589
139-959
144.836
lU9.345
304.05
321.52
337.88
353.31
367.97
175.48
186.93
197.92
208.47
218.63
-5.330
0.960
-2.760
0.970
5;
*
*
-1.860
-0.955
-0.040
0.887
1.854
298.15
4
............................
192.11
1g5.72
-6.7'0
-6-552
1g9.13
2 0 2 . ~ ~
206.26
210.28
21q.76
-6.343
-6-066
-5-681
-5-140
-4.399
*
*
*
2.902
3.958
4.986
6.017
7.007
7.964
8.861
FREE EIEBGr
J/.o~.K
kJ/.ol
kJ/mol
93.22
0.42
122.70
-2587.525
2.100
-2439-892
2. 100
427.458
0.366
312.005
244.409
J/.OI-K
'f
o.qs4
O.oOo
93-22
0.42
OICEPTAIITy
-5.460
-5-485
-5.536
-5-728
-6-138
- ( G ~ - ~ ~ C;
~ ~ ) EUTHALPI
~ T
~/.ol.K
J/.ol.K
0.24~
0 . 1 ~ ~
0 . 0 ~ ~
-0.06~
-0.12~
34.900
59. 384
77.800
92. 157
103.675
113.133
133.31
168.35
199.29
226.77
251.37
273.60
98-41
108.97
121 - 4 9
134.61
147.69
160.47
148.98
164.49
174.61
181.61
186.74
190.73
-2588.377
-2587.831
-2586.609
-2585.102
-2583.546
-2582- 100
-2389.267
-2339-541
-2289.98'1
-2240.6'4
-2191-567
-2142.649
looo
121.063
293.87
172.81
194.06
-2602- 164
-2092.364
lloo
127.835
133.723
138.928
143.607
147.871
151.826
312.51
329.78
345.90
361.04
375.36
388.99
184.67
196.06
206.97
217.43
227.49
237.16
197.05
199.93
202.86
205.96
209.33
213.03
-2600.393
-2598.472
-2596-362
-2594-Og9
-2591.597
-2588-828
-2041-471
-1990-739
-1940-168
96.9Y1
86-654
77.957
-1889*788
70.509
7oo
8oo
-0.168
-0.207
-0.237
-0.262
-0.282
-0.297
-0.309
1200
1500
1600
199.360
167.201
143.094
124*356
-1839-555
-1789-522
64-059
58*422
................................................................................
HELTING POINT
ENTHALPY OF IELTING
G98
11;
16.041
BOILING POIBT
kJ
EITBALPI OF VAPOBIZATIOS
kJ
MOLAR VOLUIE
4.4090
SiO,
.......
ALPHA
44.090
BOILIIIG POINT
kJ
J/bar
EUTHALPI OF IELTIIG
kJ
EITBALPI OF VAPOBIZATIO8
cm3
498
kJ
EOLAB VOLOllE
BETA TRANSITION 844 K .
4.36121102
0.13576 T
205
120
17.096
5.1530
51.530
J/bar
cm3
ALOIIIOE...
I. P.
9 3 3 K.
SILICOI....
I. P.
1685 K.
BEAT CAPACITY BQOATIOI
4.7236110-.
- 4 . 4 1 9 9 ~ 1 0 ' T-0.'
Tz
...............................................................................
Tz
- 4.80271103 T-0-5
- 1500 K )
................................................................................
REFEBENCE
-4
kJ
TRAISITIOIS II REFEREICE STATE ELEmWS
C:
HELTISG POINT
C;
298
99
COlPILED
4.0843xlOZ
0.11050 T
(EQOATIOI VAL10 ?POI!
REFBPBUCE
205
120
298
3.5897110-9
1600 K )
285
267
COIPILBD
10-12-77
THIRLIODIIAEIC PPOPIRTICS 0 1 II1IEUAL.S

AIDALOSITE
========-_
........................................................................
A S i O :
C r y s t a l s 298.15
343
PROpInTIBS AT UXGH T c f l P ~ R ~ O ~ I S
?ORLIOLA WEIGHT
162.047
SILLILIABITC
FORIOLA YBIGHT
162.047
t o 1 8 0 0 K.
S i O :
C r y s t a l s 298.15
t o 1 8 0 0 K.
---------------------------------------------------------------------------
----_
TXBP.
81
s;
-(GI-H;~~)/T
C;
PORIATION PRO1 THE OXIOBS.

GIBBS
ENTHALPY
FRBB
ENERGY
L ~ JK,
J/mol-K
J/mol-K
J/mol.K
298.15
0.000
UNCEHTAINTI
93.22
93.22
122.70
0.42
0.42
kJ/nol
-(G~-H&~)/T
S;
(H ; - ~ ; ~ ~
J/mol-K
C;
FOXIATION FROB THE ELEBBBTS

GIBBS
ENTHALPY
FREE E B E R G Y
l o g K~
kJ/mol
-----------------------------------------------------------------------------1.125
---
-1.376
1.260
0.241
1-260
0.221
...............................................................................
BELTING POINT
ENTHALPY OF IELTING
4 9 8
H:
BOILING POINT
kJ
17.096 k J
IOLAH VOLUBE
5.1530
51.530
TRANSITIONS I N HEFEBENCE STATE OXIDES

SiO,.
...... ALPHA -
___________________-------------------------------------------------------K
BOILING POINT
BELTING POINT
kJ
ENTHALPY OF IELTING
J/bar
17.414
kJ
IOLAR VOLUBE
cm3
THANSITIONS I N REFERENCE STATE ELEBENTS
BETA TRANSITION 8 4 4 K.
kLUIIINUI...
I.
P.
9 3 3 K.
SILICON....
H.
P-
1 6 8 5 K.

BEAT CIPACITY EQ UATION
C;
4.0843~102 0.11050 T
(EQUATION VALID FBOI
+
298
3 . 5 8 9 7 ~ 1 0 - 5 ~2
4 . 4 1 9 9 ~ 1 0 3 T-o-s
C;
1600 K )
................................................................................
REFERENCE
205
120
285
267
1.6442xlOZ + 3 . 3 5 9 4 ~ 1 0 - 2 T
(EQUATION VALID FHOI 2 9 8
--
4.6078~10'
1500 K )
T-I
................................................................................
COlPILED
10-12-77
--------------------------------------------------------------------------------
REFERENCE
205
120
31
7 h7
COBPILED
7- 8-76
SILLIIIAUITl
11,SiO~:
POBIIULA YIIGRT
C r y s t a l s 298.15
162.047
t o 1 8 0 0 K.
C r y s t a l s 298.15
~~1+0,.2Si02:
PORIATIOY PBOl THE ELEIIEYTS

GIBBS
-------------------------------------------------_-----------------------------UELTIIG POIUT
BOIL1 IG POINT
EUTHALPI OF IELTING
kJ
EPTHALPI OF VAPORIZATIOU
kJ
BOLAU VOLqlE
'2098
17.414
4.9900
49.900
TRAllSITIOlS I U REPEHEICE STATE OXIDES

S i O z.......
ALPHA
kJ
J/bar
___________________-----------------------------------------------------------K
IELTIYG P O I UT
EUTHALPI OP BELTING
cm3
';98
BETA TBAUSITIOI 8 4 4 K.
H:
In
TUAUSITIOUS
ALUIIIUUI...
SILICOY.
- 4 . 6 0 7 8 ~ 1 0 . T-2
- 1500 K )
-------------------------------------------------------------------------------C;
1.6442~102 +
3.3594110-?
(EQUATION VALID PPOI
REFEREUCE
205
120
2133
267
---------------------------------------------------------------------
COIPILED
7- 8-76
-----------
BOIL1 UG POINT
EUTHALPI OF VAPOBIZATIOI
kJ
BOLA8 VOLUIIE
kJ
13.4550
134.550
J/bar
cm3
REPEBEYCE STATE ELEIEUTS

I. P.
... I.
P.
933 K1 6 8 5 K.
HEAT CAPACITY EQUATIOI
298
31
-- 16.57571103
- 3 . 4 5 4 1 ~ 1 0 * T-a
800 K )
_____________________________-___--_____------_-------_-_----C;
7.5455~10z
2.9426~10-'
T
(EQUATIOU VALID F a 0 1 2 9 8
REFEREICE
213
99
9.2,
T-O-*
99
267
COIIPILID
7- 9-76
e-
TBERIODIUAHIC PBOPEBTIES OF B I N E B A L S
PBOPEBRES
347
A T BIGB TEMPERATURES
LAUNITE
=>..............................................................................
3b1~0,-2Si0,:
C r y s t a l s 298.15
S:
J/mol-K
-(G;-H;~~,/T
J/mol-K
298.15
0.000
UNCERTAINTY
J/mol.K
269.57
4.18
269. 57
4. 18
C;
to 9 7 0 K.
c r y s t a l s ( b r e d l g r t e ) 9 7 0 t o 1 7 1 0 K.
a'
___________________-------------------------------------------------------------
ORBATION FROB THE O X I D E S

F R EGIBBS
EENERGY
LO^ Ks
FORBATION ROI THE ELEIENTS

GIBBS
ENTHALPY
J/mol-K
326. 10
TEnp.
kJ/mol
38.079
1.470
172.244
a c r y s t a l s 1710 t o 1800 K.
...............................................................................
9
C r y s t a l s 298.15
carsiO,:
FORHULA HEIGHT
kJ/mo1
27.974
-4.901
1.490
)IT
( H;-H'&~
S;
-(G;-H;~~)/T
C:
ENTHALPY
J/mol-K
~ o gK~
FREE E N E R G Y
J/mol-K
J/mol-K
J/mol-K
298.15
0.000
UNCEBTAINTY
127.61
0.84
127.61
0.84
128.60
-2305.980
3.220
kJ/mol
-2191.264
3.225
kJ/nol
383.902
0.565
400
500
600
700
35.025
58.216
75.240
88.406
167 9
201.56
230.77
256.57
132.89
143.34
155.53
168.16
145.21
156. 16
164.18
170.38
-2305.914
-2304.116
-2302.520
-2300.900
-2152.126
-2113.956
-2076.056
-2038.456
181.040
220.844
180.737
152.112
800
900
970
98.975
107.700
112.967
279.65
300.55
314.08
180.67
192.85
201.12
175.35
179.45
181.92
-2300.892
-2299.472
-2298.787
-2000.884
-1963.450
-1937.335
130.645
113.956
104.326
970
1000
113.040
115.048
314.16
319.64
201.12
204.59
179.28
180.66
-2298.716
-2298.667
-1937.335
-1926.167
104.326
100.613
1100
121.354
337.21
215.86
185.28
-2298.502
-1888.940
89.699
1200
1300
1400
1500
1600
126.837
131.663
135.950
139.791
143.257
353.50
368.67
382.87
396.23
408.83
226.66
237.01
246.92
256.44
265.57
189.89
194.50
199.11
203.72
208.33
-2312.099
-2309.705
-2306.393
-2302.973
-2299.460
-1850.445
-1812.053
-1773.904
-1735.986
-1698.307
80.548
72.809
66.185
60.453
55.444
--- .............................................................................
_-____---____-___---------------
___________________-------------------------------------------------------------
................................
................................................................................
BELT1 NG POINT
2133
BOIL1 N
G POINT
kJ
K
ENTHALPY OF HELTING
4 9 8
kJ
SiOp
.......
ALPHA
nELTI NG POINT
kJ
13.4550 J / b a r
SOLAR VOLOnE
................................................................................
134.550
cm3
BETA TRANSITIOU 8U4 K .
ENTHALPY OF HELTING
G9n
HO~
BOILING POINT
kJ
kJ
HOLAR VOLUHE
5.1600
51.600
J/bar
cm3
C:
2403
CALCIUII....
ALPHA-BETA 7 2 0 ,
SILICON....
fl.
1. P.
BETA 1 1 1 2 .
8
.
P.
1755 K-
P. 1 6 8 5 K 4
7 . 5 4 5 5 ~ 1 0 -~ 2 . 9 4 2 6 ~ 1 0 - 2 T - 6 . 5 7 5 7 ~ 1 0 1 T - 0 . 5
3.4541~106 ~ - z
BEAT CAPACITY EaUATION
................................................................................
REFEZIENCE
213
99
99
213
................................................................................
267
COHPILED
7- 9-76
C;
134.557
+ 0.046108 T
................................................................................
REFERENCE
45
120
126
................................................................................
COBPILEO
7- 9-76
TEBBllOLITlAllIC PBOPEPTIBS O? E I I E B I L S
LABNITE
PROPEPTIES
FORIOLA tlGIGHT
------
172.299
C r y s t a l s 298.15
crystals (bredigite)
a'
9 7 0 t o 1 7 1 0 K.
C r y s t a l s 298.15
~-~siO.:
a crystals 1 7 1 0 t o 1 8 0 0 K.
( H;-H;~~)/T
J/mol.K
1[
5;
-(G;-R:~~)/T
J/mol.K
C;
FOPIATION PPOH THE OXIDES

GIBBS
ENTHALPI
PPEE ENEBGI
J/mol- K
J/mol.K
kJ/mol
127.61
0.84
128.60
-125.102
rf
172.24'4
....................................................................................
I
t o 9 7 0 K.
--___------------------------------------------------------------------------__
TEIIP.
POBNULA WEIGHT
CALCIUN OLIVINE
------====3===P===3==============s==========rs;L_s~=lii=~s===P===s===-===~=~==~~~~
Ca,SiO.:
A T HIGH TENPEBATUBES
C a l c l u m o l i r l n e i s t h e s t a b l e form of
t o 1 1 2 0 K.
d i c a l c i u o s i l i c a t e below 1120 K-
___________I_______~-----------
PORIATION FROn THE ELEIEHTS

GIBBS
TEnP-
( H ; - H ; ~ ~ )/T
-(G;-H;~~)/T
5;
C;
ERTHALPY
FREE ENERGY
LO^ K~
-----------------_-------------------------------------------------------------298.15
0.000
UNCERTAINTY
127.61
0.84
kJ/.ol
-128.002
0.960
22.425
0.970
--________--______------------------------------------------------------
--------------------------------------------------------------------------------
HELTING POINT
BOILI NG POINT
HELTI NG POINT
ENTHALPI OF HELTING
kJ
kJ
kJ
BOLAB VOLUHE
2403
ENTHALPY OF IELTING
4 9 8
8:
BOIL1 YG P O I I T
kJ
HOLAP VOLUME
TRANSITIOYS I N REPEBENCE STATE OXIDES

SiO
,....... ALPHl -
kJ
CALCIOI....
ALPHA-BETA
720,
f4.
P.
BETA 1 1 1 2 .
8.
P.
1 7 5 5 K.
BETA TBAlSITIOU 8 4 4 K.

:
C
C;
2 . 4 8 7 1 ~ 1 0 -~ 8.3145~10- T
(EQUATION VALID PBOE 2 9 8
134.557
+ 0.046108 T
(EQUATION VALID FNOH
2.0521x10J
970
T-0'.
9 . 0 7 7 4 ~ 1 0 * T-2
K)
REPEBENCE
970
1710 K )
45
120
93
229
COHPILED
7- 9-76
350
T H E R n O D ~NANIC
PROPEBTIES
0 1 nxYIR,LS
351
~ A~T BTI G H J T E~N P Es R A T U ~ E S
CALCIUN O L I V I N E
---------------- ------------_____-_------------------PORNULA
ca2S10':
298.15
crystals
t o 1 1 2 0 K.
d l c a l c r u m silicate b e l o r
c a l c ~ u molirlne
is the
HEIGHT
stable
FORNULA Y E I G H T
172.2q4
274.206
....................................................................
f o r m of
c r y s t a l s 298.15
Ca,Al,Slo,:
1 1 2 0 R.
t o melting point
'ati3
K.
___________________----------------------------____________-_---------------8
S;
-(G;H;~~)/T.
ENTIIALP~
J/nol.
J/mol-~
kJ/mol
J/mol*K
J/mol.K
298'15
400
500
600
700
MOO
0'000
120-50
0.84
lboeo5
191.74
34-350
56-820
900
73"202
2L0-99
85-911
96.241
245-98
268-48
104-944
112.483
1000
1200
125-70
135-92
147.79
160-07
172-24
L89-03
308-03
184-09
195-55
126.80
141.67
151.21
158.78
165.44
171.60
177.48
183.18
-135.742
1.000
-136.132
-136.704
-137.348
-138.011
-138.663
*
*
*
*
kJ/mol
23.918
-136.522
1.020
-136.740
-136.829
-136-784
-136.646
-136.407
325-75
342-41
206.59
2 1 7 - 22
a
+
17.856
1 4 .294
11.908
POINT
K
W
ENTHALPY O F R E L T I N G
4 9 8
kJ
H:
UPHA
-137.848
-136.658
206.40
-4007.570
2.820
-3808-705
2.900
667-272
0.508
122.688
144-259
1~5-09
3 30.07
377.87
420.01,
2 1 8 . 34
275.32
255. 18
275.78
236.74
255.46
268.58
278.35
-40U7.948
-4006.908
-4005.317
-4003-661
-3740-651
-3673-938
-3607-478
-3541-319
383-815
314-0h0
L64*258
lh1.514
,75-689
457.72
491.77
196.21
316.08
285.96
292.06
-4003.721
-4002- 587
-3475- l n 2
-3409-174
2Lb.907
197.864
187.5~b
522.84
335-21
297.06
-4023- 652
-3341.722
174-554
197.733
551.32
351. 59
301 - 2 3
-4023.617
-3273-549
155.449
-40 18- 1 0 3
-4034-9b8
-4031.696
-4028.312
-4024-833
-324-088
-3134-719
-3065- 6 1 4
13y-471
125-955
114-380
-2996.714
104-355
-135.506
-135.337
800
6.435
5.891
a
+
1200
130U
1400
1500
1600
L06.5V~
114.183
210.964
226.997
232.409
577.66
602.20
625.10
646.59
666.83
371.17
404.14
419.59
434.42
304.75
307.76
310.35
312.59
314.55
170U
237.29:
685.95
448.66
316. 26
lHOO
2 4 1 .TIL
704.07
462.35
317.76
jHH.02
488-481
____________--------------------_____________----_-------------
__~__________----_--------------
-L928-071
95-592
-_______________--_-------------
-4071.779
-2859-212
87-853
_______-__~___------------------4374. 866
-2781-240
80-710
____-_____________-------------------------------------------------------------1863
BOILING POINT
kJ
kJ
NOLAB VOLUHE
RELTING P O I N T
B O I L 1 UG P O I N T
kJ
HOLAR VOLUHE
BETA TRANSITION
209.80
1.64
ENTHALPY OF B E L T I N G
5.9110 J/bar
5 9 . 1 1 ~ cm3
T R A N S I T I O N S I N REFERENCE S T A T E OXIDES
S1Oz--..---
209.80
1.64
O.OOO
56.750
94.752
700
................................................................................
FELTING
298.15
UNCEBTAINTY
------------__-____--------~--139. 192 + - 1 3 6 . 0 ~ *
~
7.M98
-138.696 * - 1 3 5 . 7 6 ~
7.092
188.76
194.26
ENTBALPY
( H;-H;98
100U
ll9.lb5
125-194
'loo
120.50
0. ti4
TEBP.
,J/mol.K J / ~ ~ ~ - JK / ~ o ~ - K ~ / m o l - K
kJ/aol
_______---------_~_________________--------------------------------------
k~/mol
.............................................................................
UNCERTAINTY
- ( G ; - H ~ ~ ~ ) / T C;
5;
Kf
T H E ELEUENTS
GIBBS
FREE ENERGY
~ O R ~ A T I O FBOU
N
PROM T H E O X I D E S
Gl8BS
P~~~
FORHATION
kJ
9.0240 J / b a r
90.240
cm3
T R A N S I T I O N S IN R E F E R E N C E S T A T E ELEHENTS
8 4 4 K.
720.
CALCIUH....
ALPHA-BETA
ALUUINU~...
n.
P.
PI.
P- 1 6 8 5 K -
SILICON...
B.
P.
BETA 1 1 1 2 9 0 -
P-
1755 K -
9 3 3 K.
HEAT C A P A C I T Y E Q U A T I O N
ci =
1-3257*102
(EQUATION
5.2510~10-2 T
298
VALID PROn
- - 1.90~9~10r,
T-Z
c:
1200 K )
45
120
4.0c,73x10~
7.0986~10-3 T
298
................................................................................
REFERENCE
93
229
................................................................................
3.1744~10T
~-'"
180 K ,
1.1883x10b
T-2
................................................................................
CONPILED
7- 9-76
REFFBENCE
206
27 3
93
11
COMPILED
7-
9-76
268
_____-_______-__-__-----------------------------------------------------------
-THERflODINAflIC PROPERTIES o p B I N E R A L S
352
GEHLENITE
PoRnuu. YEIGHT
................................................................................
CazAlzSlOr:
(';-':98)/~
J/mol'K
s:
J/eOl-K
C:
J/mol- K
k~
~
kJ/mol
............................................................................
298.15
O-OOo
UNCERTAINTY
400
500
209.80
1. 6 4
275.09
330-07
377-87
420.04
209.80
1.64
21B.34
235-32
255.18
275.78
206.40
236.74
255.46
268.58
278.35
-151.452
-152.174
-153.018
-153.982
28.595
*
*
21.852
17.888
-167.336
-171.229
-174.954
-178.545
600
700
56-750
94.752
122-688
144.259
161-514
457-72
296.21
285.96
-155. 100 r
-181.971
900
loo'
175.689
187-586
491-77
522-80
316-08
335.21
292.06
297.06
-156.322
-156.778
-185.257
-188.438
'loo
I2O0
I3O0
1400
1500
lboO
1700
"0
lY7-'33
206-508
214.183
220.964
226-Y97
232.409
237.292
241-722
551-32
577-68
602-20
625.30
646-59
666.83
685.95
704.07
353.59
371. 17
388.02
404.14
419.59
434.42
448-66
462.35
301.23
304.75
307.76
310.35
312.59
314.55
316.26
317.76
-157.196
-157.615
-158.060
-158.542
-159.117
-159.765
-160.513
-161.373
-191.594
-194.682
-197.761
-200.809
-203.818
-1~6.756
-279.676
-212.547
+
+
+
r
r
r
+
+
3 53
450-455
t o 120 R -
~ R I A T I O I I PROM TIIB BLEllBI3TS

GIBBS
SOT
cB:-B;98)n
TEap.
-(6;-8Tq8
13.323
)/T
C:
+
+
+
+
7.946
7.492
7.098
6.750
6.40~
6.168
................................................................................
92.225
155. 598
7oo
202.645
238.877
Boo
267. b21
900
291.056
looO
lloo
1200
361.51
452.65
532.42
602.72
6.100
6.000
269.28
329.78
363.84
389.55
425.66
4".
31
463.18
665.31
721-66
397.69
430.60
473.91
482.89
-,to- baa
773.00
462.32
491 - 7 1
327. 5 7 7
820.32
492.74
501.53
3q2.5q7
86q.44
521.89
513.15
- 297.05
-6157.534
-6036. 219
-5915. 468
-5795.383
804.095
'02
514.989
432.458
-6632.988
-6630.058
-5675. 525
-5555'984
370-576
322'462
-6649.649
-5435.229
283.909
............................
_-__________-_____------------
252' 336
___________________---------6648- 281
-5313.882
-6668.283
-5190.716
BOILING POINT
................................................................................
ENTHALPY OF flELTING
kJ
kJ
IIELTING POINT
BOILING POlUT
G98 -
kJ
NOLAB VOLUHE
ENTHALPY OF flELTIN6
kJ
ENTHALPX 0 1 VAPORIZATIOB
kJ
flOLAR VOLUME
1863
47.047
1.069
-6643.817
-6641.469
-6637.887
-6634.129
HFLTING POINT
log
'f
kJ/mO1
kJ/.ol
0.51
0.51
500
J/.0l0K
~/mol-K
9.B,,3
9.0g8
BuBRGP
BUTBALPY
...................................................................
_____-----298. $ 5
O.ooO
255.50
255.50
330.10
-6643.140
-6281.359
1100'472
ONCEBTAI
................................
*
m B f l u l l YBI6UZ
J/mol.~
J/.o~.K
-163.215~
3. 1 7 0
-15v.qg2r
3.090
_____________________________________--___-_----------------
PORfikTION PROM THE O X I D E S

G I BBS
ENTHALPY
FREE ErERGy
Log R f
J/nol. K
p AT
~ HI6B
~ ~ T
C a l ~ l ~ i sCrrstals
~ , z : 298.15
..............................................................................
274.206
C r y s t a l s 298. 1 5 t o m e l t r n g polot 1 8 6 3 K.
TEnP.
225'947
ti
W
12.5300
125.300
J/bar
cm3
TRANSITIOIS I N EEPEREACE STATE ELEnBNTS

CILCIUM....
&LPtlA-BETA 7 2 0 .
N.
P.
BETA 1 1 1 2 ,
0. P.
1 7 5 5 R-
HEAT CAPACIT? BQUATION
................................................................................
REFERENCE
206
27 3
93
268
11
................................................................................
COUPILED
7- 9 - 7 6
7.4426110*
T-2
(EQUATIOU VALID PROM
298
1200 R )
............................................................................
REFERENCE
152
283
286
88
COMPILED
03-15-79
3%
TBIBM)DTIAflIC PPOPIIBTIIS 0 1 BIIEBAL~
GBOSSOL.8
......................................................
c r ~ s t a l s298.15 t o 1 2 0 0 K .
Ca,Al,Sl,O,,:
ca3LIq(SiO.)~:
C r y s t a l s 298.15
to i n c o n g r u e n t m e l t i n g p o i n t 1 8 4 8 K .
------------------------------_---------_-------_-__--__-________________
FORBATIOI
TEUP-
(9
S;
J/mol*K
J/aol-K
298.15
0.000
UREBTNTI
IT
~
c;
EnnALpr
J/mol- K
J/aol-K
kJ/mol
255.50
0.51
255.50
0.51
330.10
-330.073
7.320
361-51
452.65
532.42
602.71
665.31
269.28
297.05
329.78
363.84
397.69
389.55
425.66
448.31
463.18
473.91
-330.953
-331.550
-332.225
-333.384
-335.272
*
*
POBBATION FROB THE ELEUEUTS

GIBBS
moa
T H E OXIDES
GIBBS
PURE EEERGI
LO,
,f
TEnp.
( R > " ~ ~ ~ ) / T S;
- ( G ~ - B ; ~ ~ ) / TC:
ENTHALPY
FREE EUEBGY
l o g K~
k J/mol
------------------------------------------------------------------------------400
500
600
700
800
92.225
155.598
202.645
238.877
267.621
*
*
*
-319.806
7.560
56.029
-316.153
-112.390
-308.483
-304.453
-300. I99
*
*
41.285
32.635
26.856
22.719
19.601
*
*
------I_-----_-_-_-------------
900
1000
291.056
310.680
721.66
773.00
430.60
462.32
482.89
491.71
-337.703
-377. 934
*
*
-295.647
-290.474
1100
1200
327.577
342.547
820.32
864.44
492.74
521.89
501. 53
513.15
-337.911
-337.463
-286.279
-281.119
n e L r 1 ~ 0 POIET
BOILING POINT
ENTHALPI OF lELTING
17.159
15.199
13.594
12.257
................................................................................
BELTING POINT
BOILING POINT
ENTHALPY OF RELTING
kJ
kJ
n0LAR VOLUHE
ENTBALP'I O F VAPORIZATIOCI
498
k~
47.047
noLlR VOLUBE
800
K
kJ
1u.440U
104.400
J/bar
ciu3
TRANSITIOIS I N REFERENCE STATE ELEUENTS

TRANSITIONS I N BBPBREIlCB STATE OXIDES
SiO,.....
CALCIUU
.. UPHA -
HEAT CAPACITI BPUATIom
1-5293x10'
0.69900
7.4426rlOb T-2
(BQ'JA'fIou VALID P e o n
152
PI.
P.
BETA 1 1 1 2 , 8. P.
1755 K.
P.
9 2 2 , 8 . P.
.... n.
P.
1685 K.
283
1361 K .
HEAT CAPACITY EQUATIOA
2 . 5 3 0 0 ~ 1 0 - r ~z
1.8943x10.
T-o.,
Ci=
6.5076x102 - 0. 18169 T
( EQUATION
V A L I L Faon
+
298
7 . 0 3 5 7 ~ 1 0 - ~T2
- 1600 K )
6-05L9~10'
T-O.'
___-___________-_-_------------------------------------------------------------298
1200 g)
REFERENCE
----------------------------------------____________
RE?EBBNCE
720.
UAGNESIU~.. U .
SILICON
C;
.... ALPHA-BETA
BETA TRANSITION 8 4 4 K .
286
88
COUPILBD
206
27 3
179
116
COUPILED
7-
9-76
_____-____-______---------------------------------------------------------------
- -TBEBIIODIIABIC PROPERTIES O? UIISnALS
Ca,lg( S i o . ) ~ :
C r l s t a l s 298.15
............................
TEflp-
S;
t o i n c o n g r n e n t m e l t i n g p o i n t 1 8 4 8 K.
................................................
-(G>H:~~)/T
C:
C r y s t a l s 298.15
ca.l9SizO,:
---_
PORIATIOI FROl THE OXIDES

GIBBS
EUTHALPI
FREE ENERGY
~ o xf
g
...............................................................................
rOBlATIOY FBOl THE BLEIIEUTS
GIBBS
TEnP.
( H;-H&~
s;
)/T
UELTLNG POINT
BOILING POIUT
ENTHALPY OF IELTING
kJ
ENTHALPI OP VAPORIZATION
kJ
a o L a a voLunE
G98
H:
... ALPHA -
SiO,....
1727
104.400
kJ
kJ
kJ
lOLAR VOLOlS
kJ
ALPHA-BETA
720.
IAGYESIUI..
I. P.
922,
8.
SILICOU....
8.
1 6 8 5 K.
P.
~ o K~
g
BOILING POIUT
THANSITIOYS I N REFERENCE STATE ELEMENTS

CALCIOI....
FREE ENEBGI
EITHALPY
4 9 8
cm3
A:
C;
10.4400 J/bar
TRANSITIONS I N REFERENCE STATE OIIDES
-(G;-E&~)/I'
ENTHALPI OF I t L T I N G
................................................................................
UE LTI NG POINT
P.
1. P.
BETA 1 1 1 2 . 8.
9.2810
92.810
P.
J/bar
cm3
1 7 5 5 1-
1361 K -

HEAT CAPACITY IQUITION
C;
Tz
- 6.05291103 T-0-S
- 1600 K )
................................................................................
C;
6.5076110z
0.18169 T
(EQUATION VALID FROl
REFERENCE
206
273
4.45111102
5.1463110-2
(EQOATIOU VALID FROB
T
298
2.1857110-5
1700 K )
T'
3.79371103
T-0"
7.0357110-5
298
179
116
................................................................................
BEPEEENCE
COUPILBD
7- 9-76
206
273
178
116
COlPILED
7- 9-76
AICCBMANI T I
IOBMUL1 WEIGHT
272.633
TITIBITE ( SPHENE)
.............................................................................
Ca,BgSi.O,:
C r y s t a l s 298.15
C r y s t a l s 298.15
caTiSi0~:
POPMULA WEIGHT 196.063

-====*==========================================
t o m e l t l n g poxnt
--
( H;-H:,~
TEMP.
SF
)/T
J/mol-K
J/mol-K
298.15
0.000
UNCERTAI NTY
209.33
2.09
J/mol.K
C:
209.33
2.09
J/mol-K
212.00
POBBATIOU FROB THE ELEMENTS

GIBBS
ENTHALPI
FREE EYERGY
Log K f
FOBMATIOH P80M THE OXIDES

GIBBS
EUTHALPY
PHEE EYERGY
LO^ K,
kJ/mol
kJ/mol
-183.452
0.920
-190.323
0.930
...............................................................................
L i q u l d 1 6 7 0 t o 1800 K .
1 6 7 0 K.
33-34,,
-------------------------------------------------------------------------------RELTING POINT
1727
ENTHALPY OF BELTING
H ; ~ S-
BOIL1 N
G POIBT
kJ
kJ
k.J
UOLAR VOLUME
9.2810
92.810

SiO
,.......
ALPHA
J/bar
cm3
NELTING POINT
1670
BOILING POINT
ENTHALPY OF MELTING
123.805
kJ
$98
kJ
kJ
5.5650
55.650
MOLAR VOLUBE
J/bar
cm3
TBANJITlONS 1 4 kEYERENCE STATE ELEBENTS
BETA TBANSITION 8 4 4 K.
CALCiUn
....
ALPHA-BETA 7 2 0 ,
TITANIV .IP
ALPHA-BETA 1155.
a. P.
U.
P.
BETA 1 1 1 2 ,
8.
P.
1 7 5 5 K.
1943 K.
C:
4 . 4 5 1 1 ~ 1 0 ~5. 1 4 6 3 ~ 1 0 - T
~ +
2 . 1 8 5 7 ~ 1 0 - 5 Tz
(EQUATIOB VALID FROB 2 9 8 - 1 7 0 0 K)
3 . 7 9 3 7 ~ 1 0 3 T-0-5
-------------------------------------------------------------------------------REFERENCE
206
273
178
.
COlPILED
HEAT C A P A L I T P E'JllATION
C;
1. / b 7 ? x l U 2 +
2.3851~10-2 T 3.9905~106
(EQUATION VALID PRO!!
2 9 8 - 1670 K )
116
7- 9-76
-------------------------------------------------------------------------------REFERENCE
1i i
120
T-2
93
253
COBPILED
7- 9-76
--
ramuuuraarc P I O ? ~ I ~ ~ B $ ~ I A L S
TITAIIITI! ( SPAEIE )
POIIIULA WXIGET
C ~ T ~ S ~ O S :c r y s t a l s 298.15
H P - H ; ~)/T~
J/~o~.K
S;
- ( G ; - H ~ )/T
~~
C;
I(.
J/mol-K
J/mol.K
kJ/mol
129.20
0.84
129.20
0.84
139.00
-110.861
-110.634
1.520
1.540
38.600
64.382
83.077
97.313
108.585
173.59
210.92
243.09
271.25
296.28
134-99
146.54
160.01
173.94
187.69
161.33
172.69
179.96
185.28
189.58
900
1000
117.789
125.510
318.82
339.36
201.03
213.85
193.27
196.59
-112.551
-112.493
-169.698
-109.383
6.367
5.714
1100
1200
1300
1400
1500
1600
1670
132.114
137.865
142.952
107.507
151.635
155.410
157.779
358.24
375.74
392.07
407.39
421.84
435.52
444.98
226.13
237.88
249.12
259.88
270.21
280.11
287.20
199.67
202.58
205.38
208.09
210.73
213.33
215.13
-112.414
-112.322
-112.221
-112.111
-112.014
-111.913
-111.955
-169.071
-108.771
-168.477
-168.206
-107.935
-107.640
-107.993
5.179
4.735
4.359
4.037
3.759
3.514
3.378
1670
1700
1800
231.914
232.754
235.350
519.11
523.89
539.82
287.26
291.14
300.47
279.50
279.50
279.50
11.850
13.746
-107.993
-109.945
20.067
-117.327
-110.531
-110.431
-110.314
-110.181
-109.983
*
8
L i q u i d 1490 t o 1800 K .
TEnp.
SOT
( H;-B;~~)/T
-(G;-"~~)/T
ENTHALPI
C;
FREE E U E P G I
LO^ K~
-1379.375
2.470
241.662
0.432
~-
1 9 . 3 ~ ~
4 00
500
6 00
700
800
-110.951
-110.951
-111.052
-111.343
-111.863
t o m e l t i n g p o i n t 1490 K .
203.778
PORIATIOM FROM THE ELEIEBTS

GIBBS
kJ/mo1
---------------------------------------------------------------------------
C r y s t a l s 298.15
FesSiO.:
--
PORIATIOI FPOI THE OXIDES

GIBBS
EITHALPX
FREE
EPEUGI
L~
J/mol-K
298.15
0.000
UICEBZAINTY
POPMULA WEIGHT
...............................................................................
--
I
L i q u i d 1676 t o 1860
------------------------------------------------------------------------TEIP.
PAYALITE
196.063
298.15
0.000
uNCERTAINTY
148.32
1. 67
148.32
1.67
132.90
-1479.360
2.410
14.436
11.537
9 . 6 ~
8.222
7.181
--------_---------_----------
*
*
*
-------------------------------------------------------------------------------*
3.378
3.378
3.405
-------------------------------------------------------------------------------NELTING POINT
1670
BOILING POINT
ENTHALPY OF NELTING
123.805
kJ
kJ
ROLAB YOLURE
SiOz.......
ALPHA
55.650
J/bar
498
BOILING POUT
kJ
MOLAR VOLUIE
kJ
4.6390
46.390
J/bar
cm3
.... CURIE
P. 1042, ALPHA-GABBA
H. P. DELTA 1809 K .
S I L I C O N .... n. P. 1685 K.
BETA TRAIlSITION 844 K .
1.7673110z + 2.3852110-2
(EQU&TION VALID ?POI
92.173
cm3
IRON...
C;
1490
MLTING POINT
EUTHALPY OF BELTING
5.5650
_______-___________----------------------------------_------------------------K
1184, GAIMA-DELTA 16659

T
298
3.9905110.
T-2
C:
1670 K)
1.7276~102
3.4055110-3
T + 2.2411110-3
298 - 1490 K )
Tz
3.6299110.
T-2
----------------------------------------------------------<---------------------
RIFEBEICE
132
120
93
COIPILED
BEPEPENCE
190
251
120
93
127
COEPILED
8-27-76
PAIALI TE
FORNULA WEIGHT
203.778
---------------------------------- _---___---_-______~----------------------------_----------------------------==-------------------------------------------Pe,SiO.:
C r y s t a l s 298.15
t o melting point
1 4 9 0 K.
1800 K.
YORNULA UEIGHT
YORSTERITE
C r y s t a l s 298.15
Ng,SiO,:
140.694
.......................................................
mRNATIOU PEON THE ELEMENTS
FORnATIOY FRO# THE OXIDES
TEBP.
(H;-H;~~)/T
-(G;-H;~~)/T
S;
C;
GIBRS
FREE
ENERGY
ENTHALPY
GlBBS
~ o K,
g
( H;-H&~
J/mol-K
J/mol-K
J/mol-K
J/mol.K
kJ/mol
148.32
1.67
148. 3 2
132.90
1490
92.173
3.640
- H:
$98
ENTHALPY OF VAPORIZATIUN
J/mol.K
95. 19
0.84
J/mol.K
95. 1 9
0.84
2163
BELTING POINT
kJ
ENTHALPY OF NELTING
H O L A R VOLUnE
kJ
J/mol.K
298.15
0.000
UNCERTAINTY
117.90
kJ/mol
kJ/mol
- 2 1 7 01. .337205
- 2 0 5 11.345
.325
3 5 90.236
.385
___________________-----------------------------------------------------K
WILING POINT
kJ
J/mol-K
-20.775
1.67
~ o K~
g
FREE E N E R G Y
EYTUALPY
___________________---------------------+---------------------------------------
-24.574
................................................................................
MELTING POINT
- ( G ; - R ~ ~ ~ ) / T C;
S;
kJ/mol
...............................................................................
298.15
0.000
UNCERTAINTY
)/T
4 9 8
17.276
HOg
BOILING POINT
kJ
kJ
HOLAR VOLUNE
kJ
4.3790
43.790
J/har
cm3
Feu
........ 8 .
Slop.
......
TRANSITIONS I N REPPSENCE STATE ELEISNTS

P.
ALPHA
1650
K.
MGUEsIUn..
I. P.
922.
8.
SILICON...-
B.
1685 K-
P.
1361 K -
B E T A TRANSITION tlU4 K .
P.
HEAT CAPACITY EQUATIOG

C;
1.7L76x102
3.4055110-~
(EQUATIOP VALID FRON
REFERENCE
190
25 1
120
298
2 ~ 2 4 1 1 x 1 0 - 5T Z
3 . 6 2 9 9 ~ 1 0 6 T-2
C;
1490 K )
2.2798~102 + 3.4139~10-3 T
( EQUATIOU VALID PRON 2 9 8
1 . 7 4 4 6 ~ 1 0 3 T-0.5
1 8 0 0 K)
8 . 9 3 9 7 ~ 1 0 T~ - ~
___________________----------------------------------------------------93
127
COBPILED
REFERENCE
190
120
19238
CONPILED
7-13-76
................................................................................
~ n a 8 a o ~ ~ u r nP In C
oPaarras
20-
mii is
PORSTERITE
FORMULA WEIGHT
...............................................................................
----------------_--------------------------------------------------------------=
ng,sio,:
C r y s t a l s 298.15
140.694
FOXMULA WEIGHT
pIBOPE
--
__===-
403.130
---f===--_-----========_===__=======E========5==liYI=X===
l
C r y s t a l s 298.15
t o 1200 K.
------------------------------------------------------------------------------( H : - H ; ~ ~ ) ~s
TEflP-
J/nol-K
J/mol.K
-(G:-H;~~)/T
J/molsK
c:
PORHATION FROM THE OXIDES

GIBBS
FREE ENERn
Log
EMTHALPY
J/mol-K
k~/mol
k J/Mol
-56.690
-56.645
0.610
0.660
__----
1081ATXOU FXOM TEE ELEHBBTS

61BBS
,f
..............................................................................
298.15
0.000
UNCERTAINTY
95.19
0.84
95.19
0.84
117.90
400
500
600
700
800
32.600
54.618
70.915
83.583
93.785
1 3 2 . 68
164.47
192.24
216.83
238.88
100.08
109.85
121 - 3 3
133.25
145. 1 0
136.53
148.09
156.32
162.61
167.63
900
1000
102.233
109.365
258.87
277.16
156.64
167.79
171.80
175.33
1100
1200
1300
1400
1500
1600
1700
1800
115.505
120.859
125.587
129.800
133.594
137.031
140.165
143.042
294.01
309.65
324.25
337.93
350.80
362.97
374.51
385.48
178.51
188.79
198.66
208.13
217.21
225.94
234.34
242.44
178. 39
181.09
183.50
185.68
187.66
189.48
191.16
192.73
BOIL1 YG POINT
kJ
BXLTI NG POINT
2163
ENTHALPY OP MELTING
4 9 8
8:
17. 276 k J
-56.880
-57.079
-57.322
-57.637
-58.070
..... ALPHA
-56.612
-56.509
-56.380
-56. 1 9 4
-55.974
*
*
*.
*
*
..............................
-58.560 *
-55.663 *
-58.240 *
-55.360
-57.810
-57.296
-56.709
-56.060
-55.337
-54.554
-53.704
-52.783
MOLAR VOLUME
*
*
-55.094
-54.873
-54.706
-54.563
-54.482
-54.443
*
*
*
**
-54.452
-54.546
4.3790
43.790

SiO,..
9.924
7.393
5.903
4.908
4.193
3.655
3.231
2.892
2.616
2.389
2.198
2.036
1.897
1.777
1.673
1.583
................................................................................
UELTING POINT
BOILING POINT
kJ
J/bar
ENTRALPY OF f9BLTIIG
kJ
ENTHLLPI OF VAPORIZATION
kJ
MOLAB VOLULLB
cm3
G98
X
W
J/bar
11.3270
113.270
cn3
TRANSITIOWS I N REFERENCE STATE ELEMENTS
E.
HAGBESIUH..
H.
P.
922,
ALUMINUU...
M.
P.
933 K -
SILICON....
E.
P.
1 6 8 5 K-
P.
1361
K.
REAT CAPACITY EQUATION
................................................................................
REPEREUCE
190
120
93
128
................................................................................
C:
COMPILtD
7-13-76
8.0258xlOz - 9 . 5 7 9 5 ~ 1 0 - 2 T
(EQUATIOM VALID FROM 2 9 8
REFEREBCE
252
285
252
7 . 2 8 7 3 ~ 1 0 3 T-0.5
1 2 0 0 K)
31
2.3522x10e
T-2
COHPILED
03-15-79
366
A U C PPOPSITIES
O? U I ~ I P A L S
PIPOPE
p p o p ~ A
~T ~HIGH
~ ~TEMPEBATOBES
s
FOPllVLA WXIGBT
POBlULA WEIGHT
403.130
MgaAl~si~O,,:
t o 1 2 0 0 K.
c r y s t a l s 298.15
...........................................................................
(~;.;,~)n
S:
J/.0l.K
C;
..............................................................
298.15
0-000
UNCEBTAI 1TY
260.76
10.00
260.76
10.00
325.50
-72- 350
4.950
91-250
153.722
199.935
235.469
263.571
365.63
455.57
534.09
603.22
664.67
274.38
301.85
334.16
367.75
401.10
385.20
419.38
441.07
455.29
464.62
-72.270
-72.254*
900
1000
286.267
304.885
719.77
769.54
433.50
464.66
470.55
473.99
1100
1200
320.341
333.287
814.80
856.19
494.46
522.90
475.54
475.63
400
500
600
700
800
J/.0l-K
POBMATIOB PPO8 TBB OXIDES

GIBBS
EDHALPY
?BEE Z B E m
L O
kJ/aol
J/.01.
J/.0l.
-72.609
-73.619
-75.530
ENTBALPY OF HELTIUG
4 9 8
-4
*
*
*
12.918
-74.226 *
-74.714*
9.693
7.806
-75.177
-75.529
-75.706
*
*
*
6.545
5.635
4.942
-75.183
3.928
-74.737
-74.114
3.548
3.227
.......
ALPHA
-79.223
-80.630
-82.584
kl
EBTBALPY OF VAPOPIZATIOM
k .J
MOLAR VOLUME
TEMP.
( H ~ - H ; ~ ~ ) / TS;
- ( G ~ - H ; ~ ~ ) / T C:
J/mol-K
J/mol-K
J/nol. K
298.15
0.000
UNCERTAINTY
407.20
3.80
407.20
3.80
J/mol- K
EUTHALPY
FREEENERGY
kJ/mol
kJ/mol
-9161.524
5.850
- 8 6 5 15..191020
LogKf
--..............................................................................
452.30
IIELTING POINT
BOILING POINT
ENTHALPY OF MELTING
kJ
kJ
UOLAR VOLUBE
W
11.3270
113.270
1 5 1 51.034
.645
Jbar
ca3
23.3220 J / b a r
233.220
ca3
4 9 8 TRANSITIONS I N REFERENCE STATE ELEIEUTS
BETA TBANSITIOB 8 4 4 K.
- 7.2873x103
- 2. 3 5 2 2 x 1 0 6
- 1200 K )
................................................................................
252
8 - 0 2 5 8 ~ 1 0 ~ 9.5795~10-2 T
(EQUATIOB VALID PROM 2 9 8
BEPEEBUCE
-~______-__________----------------------------------------------------------K
BOIL1 YG P O I l T
HEAT CAPACITY WIUATIOB
C; =
t o 1700 K -
--------------_-_-___-_--_____
-78.260
* -75.543 *
4.385
TBAYSITIOBS I B RBFEBEBCB STATE O I I D B S

SiOz
---------_-___
-73.732
5.950
C r y s t a l s 298.15
( ~ l s i o . ) :
---___________________--------------------------------------------------------pOBBATIOII PBOM THE ELEMEUTS
k J/.0l
.............................................................................
5 L T I N G PDIYT
584.957
CORDIERITE
................................................................................
--
-=========-i===I=======r====r==========~~
285
252
31
...............................................................................
T-2
COBPILED
03-15-79
REFERENCE
206
273
31
COIPILED
7-13-76
THEBIODYNAMIC PNOPBBTIBS OP IINBNALS

COBDIENITB
POBMULA WEIGHT
~ Ils
p AT
~ HIGH
n
TMPX8ATUBES
584.957
...................................................................................
?OBIIOLA WEIGHT
TEPHBOITB
201.960
JI_=_=_=====522====11-*=2=====*5==1i====*====*===P====L=5E*=pl===*ZI*s=-======
l g 2 A l , ( AlSi,O,.
TENP.
):
C r y s t a l s 298.15
t o 1700 K .
-(G:-H:~~)/T
J/mol-K
J/mol-K
C r y s t a l s 298.15
PORNATION PEON THE OXIDES

GIBBS
ENTHALPY
FREE
ENERGY
log^^
--
FOBIATIOU PROM THE ELEMElTS

GIBBS
(H;-~;~~)/T
~/mol-K
J/IOO~-K
k~/mol
407.20
3. 80
407.20
452.30
-53.644
1.450
3-80
st
cDp
-(G;-H;~~)/T
FREE RWBBGI
EITHALPI
log
rf
kJ/mol
-66.824
1.470
J/mol.K
J/aol.K
K
298.15
0.000
ONCERTAINTI
L i q u i d 1 6 2 0 to 1 8 0 0 K.
t o n e l t i n g p o i n t 1 6 2 0 K.
J/mol. K
J/.ol.
kJ/nol
kJ/nol
LL___________________------------------------------------------
11.707
298.15
0.000
OBCSBTAI NTI
163.20
4.20
163.20
4.20
129.87
-1728.070
3.180
-1629.695
3.430
285.517
0.601
................................................................................
MELTING POINT
BOILIHG POINT
ENTHALPI OF MELTING
kJ
kJ
kJ
MOLAE VOLUNE
498
H:
23.3220
233.220
TRANSITIONS I N REPEEENCE STATE OXIDES

SiO,.
ENTIIUPI
J/bar
cm3
82098
OF MELTIWG
89.663
88
kJ
kJ
EITtlALPl OF VAPORIZATIOW
kJ
IOLAE VOLUIE
4.8610
48.610
J/bar
cm3
TBAISITIONS I U BEFEBEWCB STATE ELEIEUTS
...... ALPHA -
BETA TRAUSITION 8 4 4 K.
MAIGAIESE..
SILICON
ALPHA-BETA 9 8 0 , BETA-GAMMA
.!I
P. DELTA 1 5 1 7 K.
P. 1 6 8 5 K.
1 3 6 0 . GAMMA-DELTA
14109
.... n.

HEAT CAPACITI EQOATIOI
C;
8.2134110~ + 4.3339~10-2 T
(EQOATIOU VALID PROM 2 9 8
5.00031103
T-0-5
8 . 2 1 1 2 ~ 1 0 . T-2
- 1 7 0 0 K)
................................................................................
BEPEBENCE
206
273
31
COl PIL ED
4.6026110*
T-2
(EPOATIOU VALID PROM
- 1620 K )
..............................................................................
REPEREICE
160
120
298
93
111
COIPILED
7-15-76
TRERMODIlllIC PPOPEPTIBS 01 I I I B P A L S
TEPHROITE
FORMULA YEIGRT
=========c===========---------
..............................................................
In,Sio.:
C r y s t a l s 298.15
201.960
(~;-~;98)/~
s:
-(~:-';98)/~
J/ool.K
J/mOlmK
J/nol.K
C:
kJ/mol
129.87
-46.930
zro.
POBIATIOB PROM TBE OXIDES

GIBBS
ENTHALPY
FREE
ENERGY
L~~
J/aol-K
Zrsio,:
L i q u i d 1 6 2 0 t o 1 8 0 0 K.
................................................................................
TEBp-
ZIRCOll
POBIULA WEIGHT 183.304
_j=====51_1~_===IDI=nE=ir=E==5=TI===========5=~==1===============l=====E=====
and
t2 9 8 . 1 5
sio.
t o~1 8 0 0 K .
~
R o t e z i r c o~
n d = o = P o s e~
s
t o
a t a p p r o x i n a t e l y 1 9 4 9 K-
__________--__-__-_---_-___________________--------------------------------PORIATION PROM THE ELEIENTS

GIBBS
K=
L
TEnP.
- ( G ~ - H ; ~ ~ ) / T C;
S:
EYTHALPY
FREE EYBRGY
l o g K~
kJ/mol
-------------------------------------------------------------~-----------------298.15
0.000
UNCERTAINTY
163.20
4.20
IELTIUG POIWT
163.20
4.20
1620
ENTHALPY OF BELTING
89.b63
2.000
-47.615
___________________---------------------------------------------------------K
WILING POINT
kJ
8.352
2.020
ENTHALPY O P VAPORIZATION
kJ
498
-4
kJ
....... ALPHA
ENTHALPY OF IELTING
ROLA h VOLUflE
$98
TRARSITIONS I N REFERENCE STATE OXIDES

SiO,
BELTING POINT
BOIL1 NG POINT
kJ
ERTBALPY OF VAPORIZATION
1 4 . 9 0 3 kJ
IOLAE VOLOBE
kJ
3.9260
39.260
3/bar
.!a3
ZIRCONIUII..
ALPHA-BETA
SILICON....
I.
P-
1 1 3 6 , 1. P.
2 1 2 5 K.
1 6 8 5 K-

C;
5 . 1 ~ 5 2 ~ 1 -0 ~ 0 . 1 8 2 7 3
+
4 . 6 0 2 6 ~ 1 0 6 T-2
+
298
~.2058ri0-~
Tr
6.6404~103
r-0-5
1620 K )
--------------------------------------------------------------------------------
8
7
1
0 T
9
5 ( E Q U A T I O RV A L I D PRon 2 9 8
2 . 2 6 7 8 ~ 1 0 3 T-0.5
1600 K )
160
120
1 . 4 9 6 0 1 1 0 ~ T-'
~____________-_-__----___________________--------------------------------COIPILED
264
120
REFERENCE
115
234
93
COIPILED
111
7-1 5-76
-----------------------------------------------.-------------------------------REFERENCE
7-13-76
372
T H E P l O D I U A ~ CPROPEPTIES 01 IIIUEPALS
ZIRCON
1OPIOLA NEIGHT
T e t r a g o n a l c r j s t a l s 298.15
ZrO+ a n d SiO,
t o 1 8 0 0 K.
p o ~ n 0 L AYEIGUT 116.164
~
5=5======fD==~~~-ii~-yl;.==-IP=====~==5=s===x5=f========~~==='s=====s====~~==
OLLASTOIITl
183.30,
========E==================-====Is-=========P=====Z========E-E===========Z-=~
ZrSiO.:
373
p P O p n ~ g ~AT EIGH T E l P E ~ U ' o ~ ~ S
note zircon decoaposes to
C r y s t a l s 298.15
CaSiO.:
a t a p p r o x i m a t e l y 1 9 4 9 K.
P a e u d o w o l l a s t o n i t e is t h e s t a b l e p h a s e
t o 1 4 0 0 K.
a b o v e 1 3 9 8 K.
---
---------------_--_--_---_____-______
TEIP.
( H ; - H ~)/T
~ ~
J/aol. K
S;
-(G:-H;~~)/T
C;
J/mol .K
JAo1.K
J/moL. I[
POPIATIOU PPOI THE OXID=

EUTHALPX
?PEEGIBBS
EJIERGI
Log
kJ/mol
kJ/mol
--
r,
---_
-_-__---_------------_---__--________
298.15
0.000
UNCERTAIYTI
84.03
1.25
84.03
1.25
98.60
-22.140
2.010
-19.812
2.050
3.471
..............................................................................
................................................................................
K
BELTING POINT
EUTHALPY OF I E L T I l G
4 9 8
BOILING POIBT
14.903 k J
IOLAR VOLOUE
kJ
3.9260
39.260
IELTI UG POI I T
BOILING POIUT
EUTBALPX OF UELTIUG
kJ
EPTIIALPX OF VAPORIZATION
kJ
I O U 8 VOLOll
':98
J D ~ C.
HOo
CALCIUII....
ZrO,.......
SiO,..
....
lONOCLXUIC TO TETRAGONAL CEISTAL 1 4 7 8 K.
..... ALPHA -
SILICOU
2.3695110z
1.7879~10-2 T
................................................................................
115
1 6 8 5 K.
BETA TBAISITION 8 4 4 K.
REFERENCE
ALPHA-BFTA 720,
I. P.
120
264
COIIPILSD
234
7- 13-76
----------------------------------_-____-________________________________------
I.
P.
BETA 1 1 1 2 .
B.
3.9930
39.930
TRAISITIOUS I N REFERENCE STATE ELEUENTS
cm3
P-
1 7 5 5 K-
K,
J/bar
cm3
374
TRERIIODIIAIIIC PROPERTIES OF IIIIERALS
WOLLASTOII TE
..........................
CaSiOx:
PORIIULA WEIGHT
.......................
.................................
C r y s t a l s 298.15
t o 1 4 0 0 K.
116.164
J/mol-K
S;
J/mol.K
- ( G T D - H ~ ~ ~ ) / T C;
J/mOl-K
GIBBS
FREE
ENERGI
EITHALPY
J/mol.K
kJ/mol
--
82.01
0.84
82.01
0.84
85.27
-89.431
0.540
"I
-----_
-90.128
................................................................................
FORIATIOI PROU THE ELEUEUTS

GIBBS
l o o r-
kJ/mol
.........................................................................
298.15
0.000
UNCERTAINTI
C r y s t a l s 298.15
CaSiO,:
FORUATION PRO8 TBE OXIDES

( ~ ; - ~ ; g a )/T
116.1 6 4
P s e u d o r o l l a s t o n i t e is t h e s t a b l e p h a s e
a b o v e 1 3 9 8 K.
TEap-
PORIULA WEIGHT
K E U WIIOLLASTO~ITE
..............................................................................
15.790
(B;-H;98
TEnp.
)IT
J/mol-K
J/mol.K
298.15
0.000
UNCERTAINTY
0.860
-(G;-B;~~)/T
S;
J/mol.K
87.45
0.84
C:
J/mol-K
87.45
0.84
86.48
ENTHALPY
FREE ENERG1
Lo4 Kf
kJ/.01
kJ/mOl
-1628.650
2.594
-1544.955
2.636
270.671
0.462
................................................................................
MELTING POINT
BOIL1 NG POINT
ENTBALPY OF IELTING
kJ
4 9 8
kJ
UOLAR VOLUME
3.9930
39.930

SiO
,....... ALPBA -
kJ
................................................................................
BELTING POINT
1817
BOILING POINT
J/bar
cm3
ENTHALPY OF UELTING
G98
27.405
800
kJ
kJ
MOLAR VOLUIE
kJ
4.0080
40.080
J/bar
cm3
TRANSITIOUS I N REPmENCE STATE ELEUENTS
.... ALPHA-BETA 7 2 0 ,
SILICON .... n. P. 1 6 8 5 K.
CALCIUI
C;
1. 1 1 2 5 x 1 0 2 +
1.4373~10-2 T +
16.936 T - 0 - 5
(EQUATION VALID FNOI 2 9 8
1 4 0 0 K)
REFERENCE
240
2 . 7 7 7 9 ~ 1 0 . T-2
254
P.
BETA 1 1 1 2 1 B.
P.
1755 K-
HEAT CAF'ACITY EQUATION
C;
120
I.
COB PIL ED
1.0710x102 + 1 . 7 4 8 1 ~ 1 0 - 2 T
(EQUATION VALID FROI 2 9 8
2 . 2 9 6 5 ~ 1 0 ~T - 2
1 7 0 0 K)
................................................................................
REFERENCE
115
120
116
COUPILED
8-27-76
--
-.
377
p p g p ~ ~ AT
s s 8x68 TEIPSRATOBBS
PSEOWUOLLASTOUITS
CaSiO,:
FORIOLA YIIGBT
C r y s t a l s 298.15
116.164
----------------------------------------------------------------- --------_-___
9
PORIIATIOU FRO8 TBE O n D E s

GIBBS
FREE EUEaGl
Log
K
J/mol-K
~/mol.K
J/mol.K
J/mol-K
kJ/mol
kJ/mol
-----------------_-----------------------------------------------------------
298.15
0.000
URCEBTAIYTI
87.45
0.84
87.45
0.84
PORIATIOB P B O I TBB BLEIEEPS

GIBBS
SMTBALPY
86.48
-82.861
-85.180
(H;-A;g8
TB~P.
)/T
-(G-H;~~)/T
S;
C;
BNTHALPY
PBEE EIEBGY
L o g Kf
14.923
...............................................................................
HELTIIG POINT
1817
BOILIYG P O U T
kJ
EUTBALPX OF VAPOBIZATIOY
K
EYTHALPY OF MELTING
27.405
___________________-----------___________--_-__---------------6
HBLTIYG P O I BT
BOILIUG P O I I T
EYTHALPI OF VAPOBIZATION
kJ
IOLAB VOLUIE
W
G98
kJ
8;
IRJLAR VOLOIE
4.0980
40.080
TBAYSITIOYS II BEPQIEUCE STATE OXIDES
J/bar
cm3
EWHALPY OF I E L T I N G
'2098
8;
kJ
6.3500 J/bar
63.500
cm3
TRABSITIOYS I Y REPEHENCE STATE ELEIEYTS

CALCIOB
.... ALPHA-BETA
720,
1. P.
BETA 1 1 1 2 .
B.
P.
1 7 5 5 K.

SILICON..,.
C;
1.0710xlOZ
1.7481~10-2 T
(EQUATIOY VALID FROB
298
2 . 2 9 6 5 ~ 1 0 * T-2
I. P -
1 6 8 5 K.
HEAT CAPACITY EQOATIOY
1700 K)
.............................................................................
PEFEPEYCE
115
120
116
COIPILED
__________________________________________-_____-_
COIPILBD
286
REPEBEICB
285
88
88
03-15-79
378
THEE (IODTlIAQC
Ca-A1
PIROIBIIE
CaA1,SiO.:
PROPBRTIES OF I I I l B R I I J
'FORMULA WEIGHT
C r y s t a l s 298.15
218.126
t o 1 7 0 0 K.
p ~ o p ~ B T 1 EAsT HIGH TEMPERATURES

FORMUU WEIGHT
DIOPSIDE
................................................................................
C r y s t a l s 298.15
CaMg(SiO,),:
21 6 . 5 5 3
_____--_-_____-__--___--_-__-__------_--___--_____________________________
___________________-----------------------------------------------------------PORMATIOI PROM THE OXIDES
GIBES
PRBE EUBRGX
TEMP.
WRHATION PROM THE ELEHENTS

GIBBS
( H ; - H ; ~ ~ )IT
TEMP.
- ( G ; - H ~ ~ ~ ) / T C:
S;
~ o K~
g
FREE ENERGY
ENTHALPY
K
J/mol-K
J/mol-K
J/mol- K
J/mol- K
kJ/mol
kJ/mol
___________________---------------------------------_~---------------------298.15
0.000
UNCERTAINTY
143.09
0.84
143.09
0.84
166.52
-3210.760
9.120
-3036.554
9.160
531.994
1.605
___________________-------------------_--------------------------------------BOILING
HELTING POINT
1664.50 K
__--__--__-----___-_-_-__---___-___-___________-______-__-____________________
UELTIM; P O I I T
BOILIUG POXUT
ENTHUPY OF MELTIUG
kJ
ENTHALPX OF VAPORIZAl'ION
~ q 9 8
kJ
ENTHALPY OF HELTING
kJ
4 9 8
IIOLAR VOLUME
......
ALPHA
BETA TRAUSITIOl 8 4 4 K.
2.3240~102 + 2 . 1 8 4 5 ~ 1 0 - ~ T
(EQOATIOI VALID PROM 2 9 8
285
H.
P.
BETA 1 1 1 2 .
CALCIUM....
ALPHA-BETA 7 2 0 ,
MAGNESIUM..
n . P. 9 2 2 . B. P . 1 3 6 1 K.
SILICON....
M.
C;
7 . 2 7 8 8 ~ 1 0 6 T-2
1 6 0 0 K)
P.
B-
P. 1 7 5 5 K.
1 6 8 5 K.
1.9182~102 + 8.3079~10-2 T
298
( EQUATION VALID PROM
88
2 . 1 7 1 8 ~ 1 0 - 5 Tz
1 6 0 0 K)
4.2795x10*
T-2
__________--__-____-----------------------------------------------------------REFERENCE
REPEREICE
J/bac
cm3
HEAT CAPbCITY EQUATION
BEAT CAPACITY EQOATIOI
C;
6.6090
66.090
MOLAR VOLUME
kJ
TBAIISITIONS I l l R E l l R E I C E STATE OXIDES

SiO,.
kJ
ENTUALPY OF VAPORIZATION
7 7 - 4 0 4 kJ
POINT
286
88
115
120
148
178
COMPILED
10-29-76
COMPILED
03-15-79
__------_-------------_--__---____-_
THERIODTUAIIC PROPRRTIBS OF IIUBRALS

DIOPSIDE
pROpEBTIBS AT BIGB TEMPERATURES
PORIOLA WEIGHT
...............................................
.......................................
........................................
C a I X SiO,),:
C r y s t a l s 298.15
216.553
(cs;98)fl
J/mol.K
298.15
0.000
UNCERTAINTY
S:
c:
-(G;B:~~)/T
J/aol.K
J/aoleK
143.09
0.84
143.09
0.84
166.52
kJ/mol
-152.781
c r y s t a l s 298.15
LiAlSi~0.:
--
PORIIATION PBOI THE OXIDES

GIBBS
EUTHALPY
FREE ENERGY
log^,
J/mol. K
kJ/nol
186.090
..............................................................................
..............................................................................
TEIP.
FOBIIDLA WEIGHT
e-SPODUUBUE
-151.295
8.850
t o 1 2 0 0 K.
___________________---------d--------------------------
POBIATION FROMGXBBS
THE ELEIENTS
TEIP.
SOT
(H:-H;~~)/T
-(G~-H&)/T
C;
EBTHALPP
FREE ENERGY
Log K f
--
26.506
8.900
...............................................................................
IELTING POINT
ENTHALPY OF BELTING
~2098
1664.50
BOIL1 NG POINT
77.404
kJ
IW
IOLAB VOLUIE
6.6090
66.090

SiO*..
..... ALPHA - BETA THAlLSITIOU 844
BELTING POINT
BOX L I NG POIUT
ENTHALPI OF IELTING
kJ
EYTHUPY OF VAPORIZATION
kJ
J/bar
HZ98
kJ
IOLAR VOLUIB
cm3
8;
5.8370
58.370
J/bar
ca3
TRAUSITIONS I N PEFEREllCE STATE ELEIEUTS
K.
LITHIUM
SILICOU....
....
I. P.
453.69,
I. P.
1 6 8 5 K.
8 . P.
1 6 1 8 K.

C:
REFEREUCE
115
120
148
178
COIPILED
10-29-76
4.2117~102
2.4005~10-2 T
(EQOATIOY VALID FRO1 2 9 8
4 . 7 7 6 1 ~ 1 0 3 T-0''
1 2 0 0 K)
1.9100x10.
T-2
___________________________C____________--______________-___-__--____--__----
REPBREUCE
211
211
93
15
COMPILBD
9-13-76
-.382
TRERlODTNAlIC PROPERTIES OP l I N B R A L S
p s ~ p ~ n T I EAT
s HIGH TElPEBATUBES
LlAlSi206:
C r y s t a l s 298.15
t o 1 2 0 0 K.
( B O T - H ; ~ ~)/T
S;
-(G:-H;~~)/T
_______________-___------------------------------------------------------------PORIATION FROU THE ELEMENTS

GI805
TEnp.
J/mol.K
J/mol-K
298.15
0.000
UNCERTAINTY
J/~ol-K
J/noleK
129.30
158.90
129.30
0.80
kJ/mol
.
-94.885
0.80
ENTHALPY OF UELTING
2.300
-95.520
8z98
UOLAR YOLUlE
5.8370
58.370
TRANSITIOUS I N REFERENCE STATE OXIDES

SiOz
C;
FREE ENERGY
ENTHALPY
l o g K~
16.735
................................................................................
kJ
-(G;-H;~~)/T
S;
2.31 5
BOILING POIUT
kJ
(E;-H;~~)/T
kJ/mol
................................................................................
UELTING POINT
C r y s t a l s 298.15 t o 1700 K -
PORIATION PROU THE OXIDES

GIBES
ENTHALPY
FREE E N E R G Y
LO^ K~
C;
186.090
...........................................................................
~iAlSi~0.:
-------------------------------------------------------------------------------TEIP.
PORIULA UEIGHT
p-SPODUlENE
MELT1 NG POINT
BOILING POINT
kJ
ENTHALPY O F UELTING
kJ
ENTHALPY O P YAPORIZATIOI
kJ
HOLAR VOLUME
J/bar
cm3
~ ; 9 8
HO~
K
kJ
7.8250
78.256
J/bar
cm3
TRANSITIOUS I N REFERENCE STATE ELEMENTS
.-.---ALPHA -
C;
4 . 2 1 1 7 ~ 1 0 ~ 2.4005~10-2 T
(EQUATION VALID F R O l 2 9 8
HEAT CLPLCITP EQUATION
4 . 7 7 6 1 ~ 1 0 3 T-0.5
1200 K )
1.9100rlUb
T-2
-------------------------------------------------------------------------------REFEREICE
211
211
93
15
................................................................................
COlPILED
9-13-76
C;
3.628lr102
3.6841~10-3 T
Puon 2 9 8
(EQUATION VALID
3 . 4 3 4 6 ~ 1 0 3 T-"'5
1700 K )
................................................................................
REFERENCE
21 1
211
93
15
COUPILED
9- 8-76
38 4
THERBODINABIC PNOPERTIES OF BINERALS
0-S PODUnENE
................................................................
LiAlSiz06:
C r y s t a l s 298.15
(~;-H;g8
)/T
J/nol.K
S:
PORBULA
YEIGHl' 186.09
-=======-======
t o 1700 K.
-(G:-H:~~)/T
J/mol-K
J/mol-K
154.40
1.20
600
700
800
45.125
75.894
98.942
117.036
131.726
900
1000
143.956
154.347
C:
PORMATIOY FROB THE OXIDES

GIBES
ENTEALPI
FREE E B E R G Y
LO,
J/mol-K
kJ/mol
154.40
1.20
162.80
-66.685
2.300
206.28
250.61
289.62
324.38
355.69
161.15
174.72
190.68
207.34
223.96
189.61
207.37
220.38
230.42
238.43
-66.205
-66.016
-66.055
-66.378
-67.053
384.17
410.27
240.21
255.92
245.01
250.51
-67.960
-67.328
...........................................................................kJ/.0l
298.15
0.000
UNCERTAINTY
400
5 00
a-eucryptite
LiAlSiO,:
--
1300 t o 1600 K.
?ORBATION FROMGIBBS
THE ELEIIEITS
TEMP.
( H ~ - H )IT
; ~ ~ S;
13.105
-77.661
-80.556
-83.456
-86.339
-89.153
10.141
8.416
7.265
6-41)
5.821
*
*
-91.851
-94.533
0-eucryptite
t o 1 3 0 0 K.
J/mol.K
'
-(<-B;~~)/T
J/mOl.K
J/mol.K
C;
J/mol*K
ENTHALPY
kJ/m0l
FREE EIIERGI
log
~4
kJ/nol
--............................................................................
-74.804
2.320
298.15
*
................................
*
*
298.15
0.000
ONCERTAINTY
103.80
0.80
103.80
0.80
113.30
32.025
140.59
108.57
136.03
400
-2123.300
1.980
-2009.174
1.990
352.000
0.348
-2123.903
-1970.047
257.263
................................
5.331
4-9-38
................................................................................
BELT1 NG POIlT
BOIL1 UG POINT
ENTHALPY OP BELTING
kJ
MOLAR VOLUME
'2098
H:
7.8250
78.250
SiO,
....... ALPHA -
HELTING POINT
BOILING POXMT
ENTHALPY OP MELTING
kJ
ENTHALPY OF VAPORIZATIOY
kJ
kJ
JhaS
ca3
498
kJ
MOLAR VOLUME
5.3630
53.630
J/bar
cm3
TBABSITIONS I N REPERElCE STATE ELElENTS
BETA TRAUSITION 844 K.
LITHIOM
HEAT CAPACITY EQUATIOM
....
I. P.
453.69,
ALUMINUM...
I(.
P.
9 3 3 K.
SILICON....
8.
P.
1685 K -
6.
P.
1618 K -
REPEREYCE
211
211
93
C:
2.4697110z
2 . 0 5 7 7 ~ 1 0 3 T-0-5
( EaUATION VALID FROM 2 9 8
- 1.2895xl0*
1300 K)
C;
89.943 + 7.9203110-2
T
(EQUATION VAL10 FROB 1300
1600 K )
T-2
COMPILED
REFERENCE
21 1
211
93
15
COMPILED
9- 8-76
386
TBERUODIUAIUC PROPERTIES OF llIPlRALS
EUCRIPTITE
FOPUULA WEIGHT
126.006
==========I=====================================================================
LiAlSiO,:
a E u c r y p t i t e 298.15
t o 1 3 0 0 K.
B u c r y p t i t e 1 3 0 0 t o 1 6 0 0 K.
p p o p ~ ~ m AT
l S HIGH TEUPEBATURES
CLINOEUSTATITE
FOBUULA UBIGHT
................................................................
BgSiO,:
C r y s t a l s 298.15
100.389
..............................................................................
TEIIP.
( A ~ - H ; ~ ~ ) / TS;
- ( G ; - H ~ ~ ~ ) / T C;
PORIATION FROB THE OXIDES

GIBBS
EUTBALPY
FREE ENERGY
Log K~
TEMP.
103.80
0.80
103.80
0.80
113.30
-75.385
2.105
-80.779
2.115
14.152
298.15
0.000
UUCEOTAINTI
BOILING POINT
ENTAALPY OP RELTING
kJ
kJ
4 9 8 - H;
kJ
UOLAR VOLUUE
'
2 . 4 6 9 7 ~ 1 0 2 - 2 . 0 5 7 7 ~ 1 0 3 T-0-5
- 1.2895x10b
(EQUATION VALID FROB 2 9 8 - 1 3 0 0 K)
211
255.942
0.215
kJ
12. 1 1 3 k J
a;
BOLA8 VOLUME
TRANSITIOUS I N REFERENCE STATE ELEBEIITS

BAGNESIUU..
T-2
93
15
COBPIL ED
9- 8-76
8.
P.
922.
8.
9.
1 6 8 5 K.
....
8.
P.
1 3 6 1 K.
C;
................................................................................
211
-1460.883
1.225
~ ; 9 8-
2.0556~102 1.2796~10-2 T
REFERENCE
REFERENCE
-1547.750
1.21 5
BOIL1 N
G POINT
61.505
82.09
ENTHALPY OF BELTING
SILICON
C;
67.86
0.42
1830
IIELTING POINT

ALPHA
67.86
0.42
................................................................................
UELTING POINT
,.......
C;
K
J/mol-K
J/mol.K
J/mol-K
J/mol.K
kJ/mol
................................................................................
................................................................................
SiO
-(G;-H&~)/T
S;
kJ/.Ol
K
J/mol-K
J/mol-K
J/mol-K
J/mol. K
kJ/mol
k J/mol
...............................................................................
298.15
0.000
UNCERTAINTI
(~;-E;~~)/T
PORBATIOU FROM THE ELEBENTS

.,
GIBBS
EWTHALPY
FREE ENERGY
l o g K*
1 15
120
2 . 2 9 7 7 ~ 1 0 3 T-0.5
1600 K )
1.1926x10*
T-2
COIIPILED
8-26-76
CLIIOEUSTATITE
?OBlNlLA WEIGHT
100.389
BBOWIITE
ngsio,:
C r y s t a l s 298.15
( H;-H!&
TEIP.
)/T
S;
J/mol-K
J/mol-K
298.15
0.000
UUCEBTAINTY
67.86
0.42
-(G;-B;~~)/T
J/mol.K
C;
PORIATIOI PBOI TBE OXIDES

GIBBS
ENTEALPI
PBEE EBEBGI
Log
82.09
kJ/mol
kJ/mol
-35.560
0.630
-35.399
1830
ENTHALPY OF IELTING
4 9 8
61.505
kJ
ENTHILPl OF VAPORIZATIOY
12. 1 1 3 k J
IOLAB VOLUIE
...... A L P H A
J/baK
J/mol-K
102.50
2.10
1564
IELTIIG P O I I T
ENTEALPI OF MELTING
- 4
J/mol.K
EUTEALPI
C;
J/mol.K
102.50
2.10
86.44
kJ/mol
-1319.350
1.310
PBEEEIEBGI
kJ/.0l
-1243.081
1.440
217.784
0.252
BOILIUG POINT
kJ
EITHALPX OP VAPORIZATIO~
kJ
kJ
IOLAB VOLOIE
3.5166
35.160
J/bar
cm3
T R A # S I T I O I S I N BEPEEENCE STATE ELENENTS
cs3
IAMGANESE..
-(G;-H;~~)/T
J/mol-K
kJ
3.1470
31.470
S;
298.15
0.000
UNCEBTAIUTY
4 9 8
H:
TBAASITIONS I I REFERENCE STATE O X I D E S

SiO,.
(~;-H;~~)/T
6.202
0.650
BOILING POINT
TEap.
I ( ~
--
131.022
POBIIATIOI PBOI THE ELEIIEUTS

GIBBS
................................................................................
IE LTI NG POINT
C r y s t a l s 298.15
InSiO.:
J/mol.K
67.86
0.42
?OBIULA YEIGBT
_-=====----------____=___=yl===*IE====E===*====E=E=I~=E==ii=========I=P*=LD-==
--
.............................................................................
BETA TRAUSITIOU 8 4 4 K.
SILICOU....
ALPHA-BETA 9 8 0 . BETA-GAIIA
I. P. DELTA 1 5 1 7 K.
I. P. 1 6 8 5 K-
1360.
GIIIIIA-DELTA
l 4 lo *

8EAT CAPACITY EQUATION
C:
2 . 0 5 5 6 ~ 1 0 ~1.2796110-2 T
(EQoATIow V A L I D PBOI
298
..................................................................
REPEBENCE
1 15
120
- 3 . 0 4 0 7 1 1 0 ~ T-'
- 1 5 0 0 K)
______________________________________--_--------------------CpO
2 . 2 9 7 7 ~ 1 0 3 T-0-S
1600 K)
93
................................................................2 5 4
1 . 1 9 2 6 ~ 1 0 * T-z
----
---
1.g1q5x10-z
T
99.043 +
(EQOATIOU V A L I D PBOII
BEPEREICB
COIPILED
8-26-76
115
24 1
285
2 , 7 4 4 7 ~ 1 0 2 T-0''
298
19
2 73
COIPILBD
7-13-76
3po
T H E P ~ I O D I U ~ I C PBOPEPTIES 0 1 ~ ~ I N E R A L S
BBODONITE
FORMULA YEIGHT
-----------_-_---_-_=====I==l=============z===Z======
RnSiOl:
C r y s t a l s 298.15
JADEITE
FORMULA WEIGHT 2 0 2 . 1 4 0
__=======E==E==========S-EE==s------========-========Z========5=============1
--
131.021
t o m e l t r n g p o r n t 1 5 6 4 K.
aAl(Si0):
C r y s t a l s 298.15
t o 1 3 0 0 K.
___________________-------4----------------------------------------------
TEIIP.
5;
(H;-H:~~)/T
J/.0l.K
J/.0l.K
- ( G ; - H ~ ~ ~ ) / T C;
J/.0l.K
J/.0l.K
kJ/.0l
............................................................................kJ/.01
298.15
0.000
UNCEBTAINTI
102.50
2.10
UELTING POINT
1564
ENTHALPI OF BELTING
Riga
H:
102.50
2.10
86.44
-23.430
0.710
....... ALPBA -
-23.897
)IT
-(G;-H;~~)/T
S;
C;
EIITHALPI
LO^
FREE E N E R G Y
K~
0.960
BOILING POINT
kJ
kJ
ROLAR YOLOUE
3.5160
35.160
---_____________-__-------------------------------------------------------------
J/bar
cm3
RELTING POINT
BOILING POINT
ENTHALPY OF RELTING
kJ
kJ
MOLAR VOLURE
G9n
HO~
kJ
6.0400
60.400
J/bar
cm3
TRANSITIONS I N BEPEBENCE STATE ELEMENTS
+
2.7447~102
2 9 8 - 1 5 0 0 K)
T-0-5
3 . 0 4 0 7 ~ 1 0 b T-2
285
93
127
SILICON....
COUPILED
7-13-76
----------------------------------------------------------------~---------------
I
;
M.
P.
1 6 8 5 K.
C:
................................................................................
115
24 1
(H;-"g8
99.043 +
1.9145~10-2 T
REFEBENCE
Teap.
~
----
C;
4.187

Si02
FOBRATION PROR THE ELEREIiTS

GIBBS
FOERATION PBOR THE OXIDES

GIBBS
ENTHALPI
FREEENERGY
L
3.0113xlOz +
1.0143~10-2 T - 2.0551~103
( EQUATION VALID FROM
2 9 8 - 1300 K )
T-0.5
2 . 1 3 9 3 ~ 1 0 6 T-2
---__~_~_____-_____--------------------------------------------------_-------REFERENCE
115
120
97
1u9
COnPILED
7-13-76
rn
TUUR-IITC
PBOPIRTBS OF m
JADEITE
9
FOBJIOLA WEIGHT
202.140
---------=====r==I===E=0======I=S==============a===============================-m
- -----Mall( Sio,),:
C r y s t a l s 298.15
TREIOLITE
................................................................................
FOBIULA WEIGHT
t o 1300 K .
-----__----___---__-------_-_-------------------_----___-___________________
___________
--PORIATION FBOM THE OXIDES
TEIP.
(H;-H;~~)/T
S:
-(G$H;~~)/T
EUTHALPT
GIBES
FREE EWEBGI
Log It
133.47
1.25
133.47
1.25
159.95
-162.740
2.380
-159.000
-------__
27.856
298.15
0.000
ONCERTAI NTY
BOILING POINT
ENTHALPY OF MELTING
kJ
&I
kJ
IOLAB VOLUIE
- HZ
...... ALPHA
3.0113~102 +
1.0143~10-2 T
(EQUATION VALID PBOI 298
EEFEBEWCE
115
120
548.90
1.25
548.90
1 .25
655.63
-12355.080
17.320
-1 1627.910
17.360
2037.170
3.041
BOILING POIWT
ENTHALPY OF MELTING
kJ
ENTIIALPX OP VAPORIZATION
kJ
kJ
MOLAR VOLUME
- 2 . 0 5 5 1 ~ 1 0 3 T-0-5 - 2 . 2 3 9 3 ~ 1 0 6 T-2
- 1300 K)
................................................................................
=
l o g K~
FREE E N E R G Y
97.646
27.2920
272.920
Jbar
cm3
TRANSITIOWS I N BEPEBENCE STATE ELEIEITS
C:
EUTHALPY
IELTI N
G POI W
T
498
TRAWSITIONS I N REFERENCE STATE OXIDES
Sio,.
COP
-(G;-H;~~)/T
POBMATION FROI THE ELEMENTS

GIBES
K
J/mol-K
J/mol-K
J/mol. K
J/mol. K
kJ/mol
kJ/m01
................................................................................
2.400
IELTING POINT
$98
SOT
( H ; - H ; ~ )/T
~
TEIP.
-.--298.15
0.000
UNCEBTAI WTI
81 2.374
97
149
................................................................................
COIPILSD
7-13-76
CALCIUI....
ALPHA-BETA
720.
IAGNESIUM..
I. P.
922.
8.
SILICON....
I. P.
1685 K.
I. P.
BETA 1 1 1 2 , 8 - P.
P.
1361 K.
1755 K-
C:
6.13101103
4.1890
+ 5 . 1 3 8 5 ~ 1 0 7 T-2
(BQUATIOW VALID PROM
298
1.7568110-~
T*
8.5656110*
T-O''
1100 K)
.............................................................................
REPEBglCE
151
228
270
COllPILSD
7-13-76
___--________________________-__---_------__------____----------
TREIOLITE
POBHULA WEIGHT 812.374
...................................................................................
CarHgs[Si.o,,l(OH),:
C r y s t a l s 298.15
AUOBTRTTI
IOBUQLA HI16HT
t o 1100 K.
Crystals 298.15
CaAlnSisO.:
----
TEHp-
J/mol.K
s:
(rF-~;98)/T
J/nol.K
C;
J/.ol.K
PORIATION FROH THE OXIDES

GIBES
ENTHALPr
FREEERERGr
Log K~
J/.Ol-K
kJ/a01
UNCERTAINTY
1.25
1.25
15.200
LlELTING POINT
BOILING POINT
ENTHALPY OF HELTING
kJ
kJ
IOLAR VOLUIE
G98
97.646
SiO,
---..
..
___^_______________---_-----_---__-----__---_---_--_---------_--_--------------
POBBATIOII ?BOB TUB B L B M l T S

6IBBS
TEIP.
( H ~ - H ~ ~ ~ )S;/ T - ( G > H : ~ ~ ) / T
C;
J/mol.~
J/mol- K
J/mol- K
199.30
199.30
0.30
0.30
85.410
~/mol-K
BUl'KALPI
PRBB EUBBGX
k~/mol
L o g Kf
kJ/.0l
_____________________________________________-_____--_
298.15
0.000
OUCBBTU NTY
15.200
27.2920
272.920
TBAWSITIONS I N REFERENCE STATE OXIDES
t o m l t i n g p o i n t 1 8 3 0 K.
kJ/mol
................................................................................
298.15
0.000
548.90
548.90
655.63
- 5 0 6 . 0 2 2 * -487.511 *
278.211
=5D~E=2-===~~1==liL=~El~i==~~===5~~==~=PI====ii~ji====-?*=====~Ol==============
211 - 4 0
-4229.100
3.125
-4003.326
3.145
701.369
0.551
__________________________________-________________
K
kJ
EUPBALPT OF IELTIWG
EBLTIWG POINT
1830
81.000
J/bar
33.333
BOIL186 POIUT
kJ
BUTRALPY OF VAPOBIXATIOU
kJ
IOLAR YOL UllE
cm3
TRAUSITIONS I U REFERENCE STATE ELEMENTS

ALPHA
CALCIOH
....
ALPHA-BETA
720.
H.
P.
BETA 1 1 1 2 .
8.
P.
1 7 5 5 K.

HEAT CAPACITY EQQATIOU
+ 5 . 1 3 8 5 ~ 1 0 7 T-2
(EQUATION VALID PNOH
REFERENCE
151
228
298
1 1 0 0 K)
270
................................................................................
COMPILED
7- 13-76
1.4085xlor T-2
(BQUATIOU VALID FROB
298
1 8 0 0 K)
_-_______________________-_______-__________________
COIPUBD
BEPEREUCB
152
56
227
286
93
03-15-79
- ..
396
WE~M)DIUIIIC PPOPEJ~IIISo r IIUII~ALS
AIOPZBITE
108EOLA RKIGBT
...........................................................................
CaAlzSizOa:
e r s t a l s 298.15
p
278.2
t o B e l t i n g point1 8 3 0 K.
397
p A~
T BIGB
~ ~T I R~P E~B w a n B
I O R L ~ L A S I I I G ~ T 278.211
=====_X======Y==_-=IC_55==5====1========I-==~===-~==~*=========~=======
CaAlzSizO.
GLASS
ca&l,Si20.:
G l a s s 298. 1 5 t o 1500 K -
------------------------------_________________________________
--------_____
___________________------_____________________----------TEm-
s;
J/.olmK
J/.Ol-K
J/aol-K
FORBATIOI FBOl TEE OXIDES

GIBBS
EmnALPY
FREE
Log
~ C;
~/mol.~
(H;-~g8
c;
-(G;-H;~~)/T
S;
POBtlATIOB FBOI THE BLEREYTS

GIBBS
WTHALPY
FREE E I E ~ l ~o g ~ K f
k~/.~l
kJ/.0l
kJ/mol
K
J/.ol.~ J/.o~.K
~/mol-K
J/moleK
kJ/mol
---------------------------------------________________________________________
___________________------------------------------------------------------298-15
0.000
UNCEBTAIUTY
199.30
0.30
199.30
0.30
211.40
-96.911
3.430
-105.035
3.450
18.402
298.15
0.000
UNCERTAINTI
237.30
2.50
237.30
2.50
210.60
-4157.300
3.300
-3942.856
3.320
690.775
0.581
--------------------------------------------__----___-_______________________
IELTING POINT
1830
K
BOILING POINT
___________________-----------------------------------------------------. K
K
ENl'HALPX OF BELTIIG
82098
800
81.000
33.333
kJ
ENTAALPY OF VAPORIZATION
noun
VOLURE
TRAISITIONS I N BLFERENCE STATE OXIDES

Si02
....... ALPHA - BEFA TBANSITION
8 4 4 K.
1830
IELTING POINT
BOILING POINT
kJ
lOLAR VOLUME
W
ENTHALPI OF MELTING
10.0790 J / b a r
100.790
cm3
33.154

CALCIUII....
ALPHA-BETA 7 2 0 ,
H.
P.
BETA 1 1 1 2 ,
8- P.
1 7 5 5 K.
BEAT CAPACITY EQUATIOI

BEAT CAPACITY EQ UATION
1.~08sxio. r-a
(EQUATIOI VALID ?ROR
298
1800 K )
C;
3.7517~102 t 3.1970~10-2 T
(BQUATIOB VALID Fnon 2 9 8
2.45941103
1500 K )
T-0's
2 . 8 1 4 7 ~ 1 0 6 T-2
___________________------------------------------------------------------REFEBBICE
152
c.6.
227
286
148
CORPILED
03-15-79
.TAIPIODYUAMC P R O P I P T I I S 0 1 IIINIBALS
BICPOCLIN E
........................................
PORBUU WEIGHT
278.333
~ B O P E S T I E SAT RIGH TEIPIPATUPIS
--
RIGA SA~IDIHE
FOPIIULA WEIGHT
278.333
I=I===5E=======--=5=E==-2====C=======~=5==E=~=I===========E=========I===5=====
K S i O :
C r y s t a l s 298.15
t o 1 4 0 0 K.
K A S i O
)/T
TEMP.
J/mol.
298.15
0.000
UNCE8TAINTI
S;
-(G;-A:~~)/T
J/mol.K
C:
PORHATION FROB THE OXIDES

GIBBS
FREE
ENEBGI
LO^ K~
___________________--------------------------------_-------------------------A-
FOBBATION FROB THE ELEBEUTS

GIBES
ENTBALPI
J/mol - K
J/mol-K
kJ/mol
kJ/mol
214.20
0.41
202.40
- 2 1 6 . 154
-221.308
214-20
0.41
C r y s t a l s 298.15
1.970
TEMP.
( H ~ T - H : )IT
~~
-(G;-H;~~)/T
S;
C;
ENTHALPI
FREE E Y E R G I
log
llf
38.772
2.000
-------_---------------------_----
BELTING POINT
BOILING POINT
ENTHALPY OF BELTING
kJ
ENTHALPI OF VAPORIZATIOU
kJ
BOLAR VOLUBE
4 9 8
33.989
BELTING POINT
kJ
EWTHALPY OP BELTING
TBANSITIOUS I N REFERENCE STATE OXIDES
BOILING POIUT
61.500
kJ
EIITHALPI OF VAPORIZATION
33.989
kJ
HOLA8 VOLOBE
1473
10.8720 J / b a r
108.720
....... DECOMPOSES ABOVE 1 1 5 4 K.

SiO,.. ..... ALPHA - BETA TBAUSITION 8 4 4
cm3
TRAUSITIONS I N PEFEREUCE STATE ELCHENTS
KtO.
POTASSIUM..
0.
P.
SILICON....
I. P.
336.4,
8.
P.
1 0 3 0 K.
K.
1 6 8 5 K.
REPEREUCE
4.7642110.
T-Z
90
115
187
123
298
1400 K )
93
269
COIPILED
10- 5-76
REFERENCE
90
.c
187
93
COMPILED
10- 5-76
H I G H SAUIDIRE
POPlULA WEIGUT
---____
-----------=-------il=~==========j=I==_=_=====j=____===_========I===05LTE====~~I
----------KAlSiO:
C r f s t a l s 298.15
KAlSi.08:
.........................................................................
/
181.-
S;
J/mol-K
278.333
-(~;H;~~)/T
J/aol.K
J/mol-K
C;
G l a s s 298.15
to 1 3 0 0 K.
------
POPIATIOU PRO1 THE OXIDES

GIBBS
EUTHALPP
FREE EUERGI
LO.
J/mol-K
kJ/mol
kJ/mol
204-50
-208.024
1.970
-218.754
2.000
FOPMTIOU PRO8GIBBS
THE ELBIEMTS
( H ~ - ),TU ~ s;
~ ~
Tsap.
-(I$-H;~~)/T
C;
EYTHALPX
FREE EUERGI
LO^ %
-------------------------------------------------------------------------------298- 1 5
0.000
UUCEBTAI NTI
232.90
0.48
232.90
0.48
38.325
................................................................................
IELTING POINT
1473
EUTHALPI OP UELTIUG
498
BOILIUG POIUT
61.500
kJ
33.989
kJ
~ O L A BV O L U I E
________________________________--------_--_-----_--------------K
1473
IELTING POIUT
W
EUTHALPP OP IELTIIG
8;
10.9050 J / b a r
109.050
cm3
TBAUSITIOUS I N REFERENCE STATE OXIDES

KPO.
--..... DECOHPOSES ABOVE
SiO,
--.....ALPHA -
498
-4
34.884
WILIYG POIUT
kJ
EUTHALPP OP VAPOBIZATIOU
MOLAR VOLUME
kJ
TRAUSITIOIS I U REFEREUCE STATE ELEIEYTS
11 54 K.
BETA TEAUSITIOU 844 K .
POTASSIUU..
I.
ALUIIUUI...
I. P.
9 3 3 K.
SILICON....
n.
1 6 8 5 K.
P.
P.
336.4.
B.
P.
1 0 3 0 K.
HEAT CAPACITX EQUATIOU
................................................................................
REPEBEUCE
90
115
187
93
+
COIPILED
3 . 5 2 7 7 ~ 1 0 . T-2
(EQUATIOU VALID PROI
298
1 3 0 0 K)
W
11.6500
116.500
J/;~K
cm
K A l ~ i ~ 0 . GLASS
?OPIOLA SEIGBT
-----==============l;=====I====ZI=='=====S=EP=EZ;IS=EE===I================I--
278.333
-5====
KAlSi.0.:
G l a s s 298.15
t o 1 3 0 0 K.
LOW
KAlSiO,:
---
g
K
~ / m o l . ~
J/DO~.K
............................
298.15
0.000
ONCEBTAI NTI
c
J/mol-K
FORIIATIOU F R O I THE OXIDES

GIBBS
EMTHALPI
FREE
EtIER,
LO^ K*
~ / m o l - ~
k~/mol
261-60
1.78
209.40
-163.204
1.970
t o 8 1 0 K.
f l i g b k a l i o p h i l l i t e 8 1 0 t o 1 8 0 0 K.
__________________________________________-_____C_--___--__---_---_-----------
t O B I A T I O I ?ROI THE ELEIBllTS

GIBBS
TEIP.
(Hi-H~ge)/T
S;
-(G-H;~~)/TC;
ELTBALPI
FREEBUERGI
L o g l(f
k~/mol
..................................................
261.60
1.78
k a l i o p h i l l i t e 298.15
-182.491
--
31.972
2.000
KELTING POINT
1473
_______________________________________________r-----------------------
BOILING P O M T
K
RNTHALPY OP BELTING
34.884
kJ
kJ
IOLAH VOLOIE
-......DECOIPOSES ABOVE 1 1 5 4 K.
S i O z . ...... ALPHA - BETA TRANSITION 8 4 4
80ILItIG P O I l T
ENTHALPI OF 8 E L T I l G
kJ
E H T f l U P I 0 1 VAPOBIZATIOM
kJ
IOLAB VOLOIE
G 9 8
TRAYSITIONS I N REFERENCE STATE OXIDES
IELTIllG POIllT
kJ
5.9890
59.890
J/bar
cm3
TBAMSITIONS I N REPEREBCE STATE ELEIEMTS
KzO.
HEAT CAPACITY
POTASSIUI..
I. P.
ALOEILIIOI...
I.
SILICOM....
I. P.
336.4,
B.
P.
1 0 3 0 K-
K.
EP UATION
P.
\-
9 3 3 K1 6 8 5 K-

C;
6.8469~10'
+
0. 1 4 8 1 4 T
3 . 3 0 4 9 ~ 1 0 - g T2
8 . 1 8 1 9 ~ 1 0 3 T-0..
3 . 5 2 7 7 ~ 1 0 . T-2
( m U A T I O N VALID PROM
298 - 1 3 0 0 K)
................................................................................
REFEHEUCE
152
56
2 27
93
COIPILED
_______-___________________--_-__-__________-_-___-----_COIPILED
93
BBPBBBlCE
201
120
15
7-15-76
T R ~ I O D I I I I I I CPROPEPTIES 0 1 I I I 1 P A I s
406
UALIOPnILLITE
.................................
.....................................
plOpEBTILS AT H I G H TElPEBATOBES
POPEOLA WEIGHT
158.169
KAlSiO.:
TEMP-
L o r k a l i o p h i l l i t e 298.15
SOT
( H;-H;~~)/T
J/.ol.K
J/lol-K
298.15
0.000
ONCEBTAI NTI
ENTHALPY OF RELTING
~;98
- ( G ; - H ~ ~)/T~
C;
J/nol.K
kJ/mol
133.26
1.25
119.79
-191.784
1.605
BOILIBG POINT
kJ
ENTHALPX OP VAPOBIZATIOu
kJ
EOLAB VOLUME
...-.-. DECORPOSES
SiO,
.......
ALPHA
kJ/mol
-197.529
t o 9 5 5 K.
Cubic c r y s t a l s 955 t o 1800 K.
FORRATION PROE THE ELEEEUTS

GIBBS
(H;-~;~~)/T
TEMP.
SOT
COP
-(G!-H;~~)/T
ENTHALP~
FREE E N E R G Y
log
34.606
1.620
5.9890
59.890

K20.
KA1Si20.:
POBIATION PBOE THE OXIDES

GIBBS
1BEE
ENEBCI
LO^ K.
ENT8lLPX
218.248
_===EE==I_P=_=I==I*===-I=P--I5=I===E=D-===================-=====================
n i g h k a l i o p h i l l i t e 8 1 0 t o 1 8 0 0 K.
J/molSK
133.26
1.25
RELTING POINT
t o 8 1 0 K.
POBEULA WEIGHT
LEOCITE
-I===============pl
MELTING POINT
BOILING POINT
ENTHALPY OP EELTING
kJ
EUTHALPY OP VAPORIZATION
kJ
kJ
ROLAR VOLUEE
J/bar
cm3
TBANSITIOYS I N REFERENCE STATE ELElENTS

ABOVE 1 1 5 4 K.
POTASSIUM,.
8 . P.
SILICON....
U.
336.4,
8 . P.
1 0 3 0 K.
BETA TRANSITION 844 K.
P.
1 6 8 5 K.
C;
1 . 8 8 8 8 ~ 1 0 2 + 5.5187~10-2 T
(EQUATION VALID PBOl 2 9 8
REFERENCE
201
120
1 . 4 7 8 7 ~ 1 0 3 T-0.5
8 1 0 K)
C;
93
CORPILEO
1.9647x102 + 2 . 7 6 6 6 ~ 1 0 - 2 T +
1 . 2 2 6 1 ~ 1 0 7 T-'
(EQUATION VALID PROU 9 5 5 - 1 8 0 0 K)
___________________---------------------------------------------_-----------COBPILED
REFERENCE
201
93
r 9"
93
15
7-1576
LEOCITE
POPIIOLA WEIGHT
218.248
KAlSi.0.:
FORIIOLb WEIGBT
202- 1 4 0
DEBIDBATED AUALCITE
...............................................................................
t o 9 5 5 K.
C u b i c c r y s t a l s 9 5 5 t o 1 8 0 0 K.
...............................................................
-----------____
POBIATIOY PBOI TEE OXIDES
C r y s t a l s 298.15
NaAlSi.0.:
t o 1 0 0 0 K.
___________________--------FJBIATIOW PBOl THE ELEIEWS

--_______----GIBES
s;
J/mol.K
~/lol.K
H T
J/m01-K
C;
J/mol.K
E"UALP.'
kJ/mol
F a E EUEBGx
Log I.1
kJ/.0L
K
_________-___--_-__-------.....................................................
------298.15
0.000
UYCEBTAIYTY
45.475
76.940
101.078
120.269
136.032
1~9.344
400
500
600
700
BOO
ann
UELTING POINT
BOILING POMT
-4
~ i g 8
kJ
EYTBALPX OF VAPOBIZATIOY
LJ
nomu
190.13
213.52
229.19
241.22
251.30
260.26
--------------------------------_______________-___--__-----
EUTHALPI OF IELTIYG
kJ
EETHALPI OP VAPOBIZATIOM
G e
IOLAB
!Oo
voLone
J/bar
TBAlSITIONS I N BEFEBEICE STLTE BLEIEITS

SODXUI
K.
HEAT CAPACITY EQUATXOMS
1.4842r102 + 0 - 13425 T
( EQuATIoY VALID PBOI
179.79
193.48
209.73
226.81
243.93
260.75
BOILIUG POI17
..... I.
ALOIIIYun...
225.27
270.42
310.81
347.08
379.96
410.09
K,O..
C;
164.40
BELTIIG POINT
voLonE
TBAYSITIOYS I N REPBBEUCE STATE OXIDES
...... DECOIPOSES ABOVE 1 1 54 K.

SiO, ....... ALPHA - BETA TRAYSITION 844
175.40
1.70
______________________-----4-------------_-----------------------
K
ENTHALPY OP IELTIBG
175.40
1.70
.!I
P.
8.
P.
1 1 7 5 K.
P - 9 3 3 K.
I. P.
SILLCOU....
370.98.
1 6 8 5 K.
HEAT CAPACITY BQOATIOY
2 . 1 6 4 5 ~ 1 0 . T-2
298 - 955 K )
,-- -
_____________________________________--_-------_--_-__
COIPILED
BBPEBEYCE
REFEREICE
201
93
93
120
------..........................................................................
15
COIPILED
7-15-76
20 1
136
7-15-76
- 41 0
TBEBIIODY NANIC PBOPEBTIES OP BIN EBALS
LOW ALBITE
FORMULA WEIGHT
262.225
---------------------------==--------------------------------------------------...........................
...................................................
A l S O :
C r y s t a l s 298. 1 5 t o 1 4 0 0
(n;-niq8
)/T
S;
J/mol-K
J/mol-K
298.15
0.000
UNCERTAINTY
207.40
0.40
LOW ALBITE
FOBNULA WEIGHT
262.225
n.
TEUP.
411
ppOpLSTIES AT BIG8 TENPEPATUBES
PORMATION PEON THE ELEMENTS

GIBBS
ENTHALPY
FREE ENERGY
LO^ K~
- ( G ; - H ~ ~ ~ ) / T C;
J/mol.K
J/mol-K
kJ/mol
kJ/mol
.............................................................................
207.40
0.40
205.10
-3935.120
3.415
-3711.722
3.435
--
650.281
0.602
---
POBNATIOU FROM THE OXIDES

GIBBS
TENp.
S;
(Hg-H;98)/~
J/mol.K
- ( G ; - H ~ ~ ~ ) / T C;
J/mol-K
J/mol-K
207.40
0.40
207.40
0.40
ENTHALPY
J/mol-K
PREEENEBGY
kJ/mol
BOIL1 N
G POINT
ENTHALPI OP MELTING
kJ
kJ
NOLAB VOLUNE
4 9 8
4,
33.452
10.0070
100.070
298.15
0.000
UNCERTAI NT Y
205.10
- 1 5 72.. 7 61 00 5
-163.699
2.125
TRANSITIOIS I N REFERENCE STATE ELEMEMTS

SODIUU-
....
8.
P.
370.98,
ALUUINUU...
n.
P.
933 K-
SILICON....
U.
P-
1 6 8 5 K.
B.
P.
5.8394x102
+
0.092852
1 . 6 7 8 0 ~ 1 0 6 T-2
(EQIIATION VALID FROM
BOILIYG P O U T
ENTHALPY OP NELTING
kJ
kJ
POLAR voLuue
28.680
4 9 8
33.452
10.0070
100.070
J/bar
cm3
TRANSITIONS I U REPWEUCE STATE OXIDES
1175 K.
Na,O
SiO.
....... I.
.......
P.
ALPHA
1 1 9 3 K.
BETA TRANSXTIOU 8 4 4
K.
HEAT CkPACITl EQUATIOU
C;
NELTIIG POINT
J/bar
___________________-------------------------------------------------------------
................................................................................
NELTING POINT
kJ/mol
298
2.2722~10-5
1500 K)
TI
6 . 4 2 4 2 ~ 1 0 1 T-0-5
___________________----------------------------------------------------------COUPILED
EEPEBBYCE
115
90
187
123
93
10- 5-76
___________________---------------------------------------------------------
412
THIRIODINAIIC
PBOPLPTIXS
or
IIIN~RALS
ARALBITE
FOBIULA WEIGHT
..............................................................................
NaAlSi,O,:
262.225
C r y s t a l s 2 9 8 . 1 5 t o 1 4 0 0 K.
C r y s t a l s 298.15
NaAlSi,O.:
( H ~ - R )IT
; ~ ~
TEIP.
K
s;
-(G:-B;~~)/T
J/mol-K
J/.0l.K
C:
kJ/mo1
262.225
t o 1400 K.
FOBHATION PBOU THE OXIDES

GIBBS
PORIATION PBOI THE ELEOEWS

GIBBS
ENTHALPY
FREE
ENERGY
10s
J/.0l.K
J/.Ol.K
PORIULA WEIGHT
ARALBITE
................................................................................
TERP.
SOT
(H;-H;~~)/T
-(G;-H;~~)/T
cOp
ENTBALPY
FREE ENEBGP
~ o K~
g
kJ/mo1
J/mol-K
J/mol-K
J/mol-K
J/mol- K
kJ/m01
kJ/mol
--_------_------------------------------__________________________________________-----------------------------------------------------------K
--_298.15
0.000
226.40
226.40
204.80
-3924.240
-3706.507
649.367
UNCERTAINTY
0.40
0.40
3.640
3-660
0.641
---------------_----------------------------_---------------------------------WLTING POINT
1391
ENTHALPY OF IELTIUG
G98
BOIL1 NG POINT
59. 280 kJ
33. 4 2 3 IrJ
aoLAn 1oLunE
10.0430
100.430
TRANSITIONS I N REFERENCE STATE BLEIEMTS
298.15
0.000
ONCERTAINTY
226.40
0.40
204.80
- 1 4 62.. 8 8
0
450
- 1 5 82.470
.484
27.766
___________________----------------------------------------------------------K
mLTING POINT
kJ
ENTHALPY OF IELTING
J h a r
226.40
0.40
1391
BOILI NG POINT
UOLAB VOLUIE
cm3
TRANSITIONS I N EBFERENCE STATE OXIDES
SODIUI.....
I. P.
370.98.
ALUUINUI...
I. P.
9 3 3 K.
I. P.
1 6 8 5 K.
SILICON
....
8.
P.
1 1 7 5 K.
6.7137110~
+
REFEPEMCE
0.14671
3.1740110* 1 2
(EQUATION VALID PROR
90
76
187
a.
Sio,.......
ALPHA
P.
1 1 9 3 K.
C;
Na,o.......
298
3.6586~10-.
Tz
7.97361103
T-0-S
1400 K )
___________________----------_----------------------_---------------COIPILEO
93
93
100
CW P I L ED
10- 5-76
HEPERENCE
90
76
4 - 7
100
10-
5-76
a1 4
--
YaAlSi,O,
GLASS
p.0pSRTIIS
FORMULA WEIGHT
UaAlSi,O,:
G l a s s 298.15
GLASS
..............................................................................
(H:-H;~~)/T
J/.0l.K
S:
UaAlSi,O.:
J/.ol-K
J/.Ol.
J/.01.
EUTBALPY
kJ/.Ol
kJ/.o1
-3875.460
-3665.330
642.153
3.720
0.652
_------------_----------------------------------------------------------------298.15
0.000
UNCERTAI NTY
251.90
1-50
llE LTI N
G POI IT
251.90
1391
ENTRALPY OP IELTIUG
~ 0 2 9 8- A;
209.90
1.50
3.700
BOILING POIUT
kJ
34. 257 k J
noLau voLunE
11.0086
110.086
TRAUSITIOUS I N REPEREUCE STATE ELElEUTS
I. P.
SODIUI.....
370.98,
8.
P.
TEIP.
(H;-A&~)/T
J/mol-K
298.15
0.000
UUCEBTAINTY
400
500
600
700
58.325
98.416
128.448
151.887
ann
770.782
kJ
ENTHALPY OF IELTING
HZ98
REFEREUCE
152
227
J/mol'K
kJ/mOl
FREE ENERGY
Log
I(f
kJ/.0l
251.90
1 .50
251.90
1.50
209.90
-98.100
2.510
-117.307
2.530
20.552
318.96
376.60
427.35
472.42
512.87
260.63
278.18
298.90
320.53
342.09
246.01
269.92
286.29
298.18
307.62
-98.090
-123.882
16.177
-130.315
-136.696
-142.995
13.614
11.901
10.670
1391
34.257
H:
Na+O.......
-98.210
-98.590
-99.437
-100.885
*
*
-1U9.129
9.737
BOILING POINT
kJ
kJ
IOLAB VOLUIE
kJ
11 .a086 J / b a r
110.086
cm3
I.
,.......
P.
ALPHA
1 1 9 3 K.
BETA TRAUSITIOU 844 K -
5.2796110*
T-+
(EQUATIOY VALID FOOl
J/nOl-K
TRAUSITIOYS I Y BEPEREUCE STATE OXIDES
1175 K.
SiO
- ( G ~ - B ~ ~ ~ C): / ~ ! EUTHALPY
S;
IELTING POINT
cm3
t o 1200 K.
J/mol.K
Jbar
262.225
PORIATION FROl THE OXIDES

GI BBS
PORIATIOU FRO8 THE BLBMEUTS

GIBES
FREE
EUERGY
Log K~
- G - H ~ ) / T C:
G l a s s 298.15
FORMULA WEIGHT
YaAlsi,o,
t o 1200 K.
--
AT HIGH TEMPERATDOES
262.225
................................................................................
--
--
ZHEOMODY UAILIC POOPERTIIS OF MI# IPALS
+
298
1200 K)
5.2796110.
T-2
(EQUATIOA VALID PBOI
298
1200 K)
___________________------------------------------------------------------------93
269
................................................................................
COMPILED
10-19-76
REFERENCE
152
227
93
269
COIPILED
10-19-76
?ORUOLA WEIGHT
NEPHBLINE
FORIULA WEIGHT
-_-_----------_--_--------------------------------------...............................................................................
NaAlSiO,:
C r y s t a l s 298.15
1 5 2 1 K.
t o 1 5 2 1 K.
..............................................................................
~:-~;98
)n
J/IUol'K
@ t r a n s i t i o n a t 4 6 7 K.
s:
J/mOl.K
___________________------------------------------------------------------------PORIATIOY PROU THE OXIDES
H/
C:
PORUATION PROU THE E L E 8 E m S

GIBBS
EDHALPI
FREE ENERGY
Log
kJ/mol
J/mOl.K
J/mOl.K
kJ/mol
_-_----__--------_----------------------------------------------------------298.15
0.000
UNCERTAINTY
124.35
1.25
124.35
115.81
---
-2092.110
-1977.498
346.449
2.420
2.450
0.429
1.25
ENTHALPY OP UELTING
kJ
k.J
noL.Au voLuuE
5.4160
54.160

SODIUI
..... I.
P.
370.98.
8.
P.
kJ/L0l
P.
J/bar
cm3
115
-142.052
24.887
BOILING POINT
ENTHALPY OP MELTING
kJ
ERTHALPY OP VAPORIZATION
k~
ROLAR VOLUUE
4 9 8
kJ
5.4160
54.160
J/bar
cm3
Ra,O
....... 8 . P. 1 1 9 3 K.
....... ALPHA - BETA TRANSITION
8 4 4 K.
1 6 8 5 K.
172.00
+
0.00552 T
(EQOATION VALID PRO8 1 1 8 0
REFERENCE
-136.150
___________________------------------------------------------------------------COUPILED
93
REPERBNCE
115.81
TRANSITIONS III BEPEBENCE STATE OXIDES
1175 K.
C;
124.35
1.25
UELTING POINT
SiO,
8.
124.35
1.25
___________________-----------------------------------------------------------K
SILICON....
GIBBS
PBEE EYERGI
EBTBALPY
298.15
0.000
UNCERT AIRTY
---------------_---------------------------------------------------------------MELTING POINT
K
BOILING POINT
. K
G9e
C a r n e g i e i t e is t h e s t a b l e p h a s e above
NaAlSiO.:
C a r n e g i e i t e is t h e s t a b l e p h a s e above
............................................................................
142.055
NLPR~INJI
142.05
120
1525 K )
93
COIPIL ED
2 29
4-15-76
--------------------------------------------------------------------------------
115
120
2 29
4-15-76
-----
el8
--
P P o P a n T I as O P IIIIEPALS
THIIBODI.LIUC
MUSCOVITE
-----=
-----
POPMULA YEIGHT
POPMOLA HEIGHT
P=====E~===-~====-=-e=========II=P~
---_
IT
9
J/moloK
J/mol.K
/
J/mol.K
c;
kjlnol
326.10
-5976.740
3.235
........................................................................... kJ/.0l
298*15
O.OOO
OUCEBTUNTI
306.40
0.61
306.40
0.61
c r y s t a l s 298.15
t o 1500 K -
...............................................................................
TEnp.
(R;-H~9B)n
298.15
.219
0.576
O.OOO
306.u0
0.61
OIICEPTAINTI
---------------------------------------------------------------_----------------
-(G;-"~~)/T
S;
J/mol.K
J/.o~. K
-----
-5600.671
3.290
K A ~ ~ [ A ~ ~ ~ = ~ , . ]k:
( O H
PROM THE OXIDES

GIBBS
PORUATION
POBIATION PROM THE E L E ~ ~ E N T S

GIBBS
KWTHALPI
~
EN ERG^
Lo,
J/.o~.K
C;
EIlTHALPY
FREE EuEBGx
~ / m o l -K
J/mol-K
k3/901
306.40
0.61
326.10
-263-674
2.525
-260-280
2.550
BOILING POINT
MELTING POIIIT
BOILING POINT
ENTHALPY OP MELTING
kJ
kJ
ENTHALPY OF MELTING
kJ
ENTHALPI OP VAPORIZATION
kJ
MOLAR VOLOME
1 4 . 0 7 1 0 J/bar
140.710
TRANSITIOUS I U BEPEBENCE STATE ELEIENTS

POTASSIUM..
M.
ALUIINUI...
I . P.
SILICON
.... I.
P.
P.
336.4,
B.
P.
cn3
~ ; 9 8
-4
49.443 k J
kJ
14.0710
140.710
IOLAB VOLUME
J/bar
cm3
DEWMPOSES ABOVE 1 1 5 4 K.
....... ALPHA - BETA TRANSITION

H20 ........ B. P. 3 7 3 . 1 5 K.
Si0.
1 6 8 5 K.
K,O........
9 3 3 K.
9.1767~102
8. 1 1 1 0 x 1 0 - 2 T
45*600
TRAIISITIOIIS I N BEFERENCE STATE OXIDES
1 0 3 0 K.
C;
___________________------------------------------------------------------------K
49.443
'f
kJ/mO1
MELTING POINT
~ 2 0 9 8-
398-311
r~*I--===__*----=L====ylCII===--i.~==E===5====--====~=~==~=====i.LD===Y=E
!lOSCOlIT~
398.311
8 4 4 K.
1.0348x)O'
T-0-5
2.8341xlU*
T-2
1 0 0 0 K)
-------------------------------------------_------_-------_-------------------_REFERENCE
152
199
2 26
277
93
COIPILED
12
10-22-76
--------------------------------------------------------------------------------
REPEREUCE
152
199
226
277
93
12
COMPILED
10-22-76
___________________---------_---_-----_--_-----_-_------------------------
----
-------"
. ..
PLUOBPBLOGOPITE
--------------...............................................................................
g A1SiO)P:
TBtnnODIIAIIIC PBOPllTIBS 0 1 UIIBBALS
C r y s t a l s 298.15
i S i*S'IIjIlinsm~
~
Liquid 1670 t o
C r y s t a l s 298.15 t o 1100 K.
I~,S~,~,,,(OE)~:
1800 K.
--
OBIX XI LA WEIGHT 379.268
421.244
FORMULA WEIGHT
___________________------------------------------------------------------------( H ; - H ~ ~ ~ ) / TS:
TERP.
J/.olSK
- ( ~ - H ; ~ ~ ) / T C;
J/mol-K
J/mOlsK
298.15
O-OoO
UNCERTAINTY
336-3~
2.10
POBMATION FROM TEE E L E ~ E N T S

GIBBS
ENTBALPY
FREE E N E R G Y
logK+.
J/.ol.~
336.30
2.10
342.40
-6392.880
3.660
l
kJ/mol
FBOM THE ELEllENTS

GLBBS
FREE ENERGY l o g f'
WBHATIOB
TEnP.
-(G;-~z98)/~
S;
( B;-H;98
C;
ENTBALPY
J/.o~.K
J/.o~. K
~/mol.K
J/mol*K
kJ/mol
kJ/aO1
................................................................................
K
-6053.067
3-800
1 060.477
0.666
298.15
o.oOo
UUCEBTAINTY
260.83
0.63
260.83
0.63
321.70
-5915.900
4.330
- 5 5 3 64.350
-048
969.897
0-762
_----_-------___-_-------------------------------------------------------------NELTING POINT
1670
BOILING POINT
ENTHALPY OP UELTING
308.779
kJ
kJ
lOLAR VOLOIE
~2098-
U.
P.
336.4,
B.
P.
RELTING POINT
BOILING POINT
EUTEALPY OF UELTIUG
498
TRANSITIONS I N REPWENCE STATE ELEUENTS

POTASSIUH..
___________________----------------------------------------------------------K
46.886
kJ
kJ
13.6250 J / b a r
136.250
cn3
IOLAR VOLUIE
TRANSITIONS I N BEIIIEENCE STATE ELEIENTS
1030 K .
8 - P.
IAGNESIUH..
9 2 2 , 8.
P.
1 3 6 1 K.

C:
4.9287~10~
+
4.9103~10-2 T
BEPEBENCE
118
118
1.56881103
1 6 7 0 K)
T-0-5
93
6.59871106
T-2
COMPILED
257
118
8-26-76
----_----_----_-----------------------------------------------------------------
BEFBREUCE
4.02111107 T - 2
151
,
228
298
800 K)
93
11
COMPILED
8-26-76
t o 8 0 0 K.
C r y s t a l s 298.15
A1zSi,o,~o~)2:
-------------------------------_--_____________________________-----____________-__-_________-______________-_--_------------_
?OP~A?IOM ?ROE TUX OIIDBS
FOPMATIOM ?Doll TUB BLBIIEITS
(B;-E;~~)/T
TIUP.
-(~%E;~~)/T
S;
C;
XUTUALPY
*DIEGIUBS
EMXPOI
6IBBS
lop^,
J/mol.K
J/mol-K
J/mol-K
J/mOl- K
kJ/mol
kJ/Dol
K
__________________________-_____-___________--___
-5265.884
922.565
-5639.800
293.70
239 -40
0.40
298.15
0.000
UUCERTAIUTY
239.40
0.40
'
3.960
3.950
0.694
--------------_--_---_-_________-___-___________________________-___________
UELTIUG POIUT
BOILIUG POIItT
K
...............................................................................
K
EYTBALPY OF UELTIUG
4 9 8
46.886
8;
kJ
IUTBALPY OF VAPOUIZATIOM
kJ
UOLAB VOLUUE
-..... ALPBA - BBTA TBAPSITIOU
H20........
8. P.
373.15
13.6250
136.250
TBAYSITIOUS I U BEPBUEUCE STATE OXIDBS

SiOz.
844 K.
HBLTING PORlT
BOILING POMT
ENTHALPY OF IELTIRG
kJ
BUTHALPY OP VAPOBIZATIOU
kJ
MOLAR VOLUBE
J/bar
cm3
4 9 8
42.695
HOg
12.7820
127.820
J/bar
ca3
TRAUSITIONS IY REPEBBUCE STATE ELBHEUTS
K.
BEAT CAPACITY BQUATIOU
ALULIINULI...
H.
P.
9 3 3 K-
SILICON....
M-
P-
1 6 8 5 K-
HEAT CAPACITY BaUATIOY
C;
7.4675~102
5.3543~10-2 T
( BpUATIOn VALID PROM 2 9 8
1.9855110-s
TZ
7 . 5 7 7 7 ~ 1 0 3 T-0''
- 800 K )
................................................................................
BEFEREUCE
152
2 26
q
10
286
152
COIPILEU
03-15-79
AltSi,Ol
doah:
C r y s t a l s 298.15
t o 800
x.
crystals 298.15
~g,si,o~(on).:
t o 900 K-
___________________--------------_----------------_-------------------------
'"'-9
K
J/nol-K
J/mOlaK
298.15
0.000
ONCERTAI NTI
239.40
0.40
g
J/nolm K
J/.ol.K
kJ/mol
...........................................................................
239.40
0.40
FORHATION FRO# THE ELEIEUTS

GIBBS
PORMATION PROM FITE OXIDES

A
,BE GIBES
XNERGr
L o g Kw
293.70
-35.470
1.325
kJ/mol
-21.363
TEIP.
MXLTIIG
Pomr
.....................
BOILIIG P O I l T
-(G;-H;~~)/T
C:
ENTHALPI
PREBENERGI
kJ/.Ol
Log Kf
-4034.024
3.500
706.747
0.613
K
J/nol-K
J/mol-K
J/mol-K
J/mol-K
kJ/nol
___________________---_------_--------_----------_-----_------_----_--
3.743
298.15
0.000
UNCERTAINTY
1.350
.......................................................
( H ~ - H ; ~ ~ ) / T S;
221.30
0.80
221.,30
0.80
273.70
-4361.660
3.480
IELTING POINT
BOILING P O I l T
ENTHALPl OP MELTING
kJ
ENTUALPI OF VAPORIZATIOU
IOLAP VOLUME
4 9 8
10.8500
108.500
J/bar
cn3
TRAISITIOIS I N REFERENCE STATE ELEMEITS

125.900
T P A I S I T I O I S I1 REPXEElCE STATB OXIDES

Sioz-......
ALPHA
- BQA
TRAUSITIOI 8 4 4 K.
E.O....
B.
373.15
K.
P.
ci3
MAGIIESIUII..
SILICON..
I.
P.
922.
B.
.. I.
P.
1 6 8 5 K.
P.
1 3 6 1 K.
HEAT CAPACITI EQOATION

HEAT CAPACITI gPUATIOM
C;
.........................
BEFXRENCE
152
...................................................
226
139
......................................................
286
8.99601102 - 0.14476 T
(EQUATSON VALID PROM
REFERENCE
COMPILED
152
..........................
03-15-79
128
128
298
1.093211W
T-0:.
4.49991106
T-,
9 0 0 K)
93
128
COMPIL
ED
9- 3-76
PORBULA YEIGRT
277.113
...........................................................................
-------------------------------------------------------------------------------TEIP.
SOT
(H~-Hig8)/T
-(G;-,-B;~~)/T
C;
FORIATION PROM THE OXIDES

GIBBS
FREE ENERGY
Log K f
EUTBALPT
K
J/mol-K
J/nols K
J/mol. K
J/mol- K
kJ/mol
k J/mol
______-------------------------------------------------------------------------
298.15
0.000
UNCERTAXNTI
273.70
EELTING POINT
BOILING POINT
ENTHALPY OF BELTING
kJ
BUTBALPY OF VAPORIZATIOU
kJ
ROLAR VOLUIE
H:
-164. 130
2.710
-139.578
2.750
221.30
0.80
4 9 8
221.30
0.80
24.454
TRANSITIOYS I N REFERENCE STATE OXIDES

SiO,..
..... ALPHA -
B R A TBAUSITIOU 844 K.
C;
8.9960110z
0.19476 T
298
1.0932r10* T-0-5
- 900 K )
4.499911P
T-2
-------------------------------------------------------------------------------REFERENCE
128
128
93
COBPILED
128
9- 3-76
-_-------_--------_-------------------------------------------------------------
PIIIBIICSS
1.
2.
3.
'.
Adami. L. H., a n d K e l l e y , K. K.,

1963, H e a t s
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Adami, L. H.,
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1964,
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Ada.j.9
L-
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6-
B a i n , B1 4 7 p.
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Jr.,,
H a u s e n * L- D.9 a n d L e w i s , E. A.,
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19.
Ben=, B.,
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T h e r m o d y n a m i c s of
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"-9
1971,
~h~ h e a t
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Barany, R.,
1963, H e a t s o f f o r m a t i o n o f g e h l e n i t e a n d t a l c :
Bur. N i n e s R e p t . I n v . 6 2 5 1 , 9 p.
1955a, nigh-temperature
aluminum, i r o n , a n d zinc:
3.
P. B., Huber, E. J., Jr., H o l l e y , C. E., Jr., a n d

Krikorian,
N.
H..
1971,
E n t h a l p i e s of f o r m a t i o n o f c e r i u m d i o x i d e , c e r i u m
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J o u r . Chem.
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B.,
aluminates
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JOUK-
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Phys-
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Chemistry * v-
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~6.
~ ~ i nlg , E. ~ G., , a n d Conway,
KC.9
1 g S 4 * Heats Of
of n i c k e l and c o b a l t o x i d e s ( M i 0 a n d COO) by combustion
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Am. Chem. Soc. JOUE.,
V - 769 P - 3835-3837calorimetry:
~
i 1.~
J.,
k ,
and
Holley,
formation
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Baker,
of
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titanateso
22.
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Andon* B- J tetragonal
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garton,
p.~.,
Jr.,
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B.
J.,
1977,
Ore
mineral
stabilities,
i n Barnes,
8. L.,
Geochemistry of hydrothermal o r e
New
I
o
r
k
,
J
o
h
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W
i
l
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y
,
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p
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energies
ot
of a n h y d r o u s c a r b o n a t e s o f b a r i u m , s t r o n t i u m ,
lead:
M i n e s B e p t . I ~ V . 6822, 7 p.
and H i l l s ,
K.
germanium d l o x i d e :
'
18.
21.
II-9
MOTES
of
H-.
U- S - Bur.
5-
of
U.
AID
~ r g o n n e , IL.,
C.
B.,
Jr.9
1976,
The
enthalpy
monoxide: [ a b s . I: c a l o r i m e t r y C o n f e r e n c e *
s e p t . 1976, p r o g r a m of meeting,
p- 49-
25.
B r o d a l e , G.,
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The h e a t o f
h y d r a t i o n of
sodium s u l f a t e .
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Am.
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sodium s u l f a t e decahydrate:
2042-2044.
26.
Brooks, A. A * , 1953, A t h e r m o d y n a m i c s t u d y o f t h e equilibrium

+ HzS(g) = cuZs(,)
+ ~ ~ ( g ) AI.
:
Chem.
Sot- Jour.9
v.
2Cu(s)
p-
759
2464-2467-
calcium
S.
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27.
Burnham,
C.
W.,
Rolloway,
J.
8..
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Y.
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Thermodynamic p r o p e r t i e s o f
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G e o l . s o c . A m e r i c a , Spec. P a p e r
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28.
Cassell,
S.
B.,
1973, w r i t t e n commun.,
A u g u s t 1973.
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Barany,
U. S.
muscovite:
29.
Chang, S. S., a n d B e s t u l , A. B., 1971,

Heat c a p a c i t i e s o f
monoclinic,
a n d v i t r e o u s a r s e n i o u s o x i d e f r o m 5 t o 360 K:
Chem. P h y s i c s , v. 5 5 , p. 933-946.
13.
Barany, R.,
1965, H e a t s of f o r m a t i o n o f g o e t h i t e , f e r r o u s
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U. S.
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Bur. N i n e s Bept. I n v . 6618, 1 0 p.
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14.
Barany, R.,
a n d Adami, L. R..
1965, H e a t s o f f o r m a t i o n o f a n h y d r o u s
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C h a r l u , T. V.,
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f o r m a t i o n a t 9 7 0 K of compounds i n t h e s y s t e m ng0-a1,03-Si0,
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A c t a , v. 3 9 , p. 1487-1497.
32.
C h a s e , I. U.,
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33.
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McDonald,
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34.
C h i s h o l m , B. C., a n d S t o u t , J. W.,
1 9 6 2 , Heat c a p a c i t y a n d e n t r o p y
T h e r m a l anomaly a s s o c i a t e d
o f CoC1, a n d ~ n c l , f r o m 1 1 0 t o 3000 K.
J o u r . Chem. P h y s i c s , V w i t h a n t i f e r r o m a g n e t i c o r d e r i n g i n CoC.1,:
36, p. 972-979.
15.
Barany,
R.,
1964. H e a t a n d f r e e e n e r g y of
Bur. M i n e s B e p t . I n v . 6356, 6 p.
B.,
a n d Adami,
I. H.,
formation
1966, H e a t s o f
of
formation
of
s u l f a t e and f i v e potassium- and lithium-aluminum s i l i c a t e s :

Bur. M i n e s B e p t . I n v . 6 8 7 3 , 1 8 p.
lithiu.
U.
5.
16.
B a r a n y , R.,
and K e l l e y , K. K.,
1961,
Heats and f r e e e n e r g i e s
U.
formation o f g i b b s i t e , k a o l i n i t e , h a l l o y s i t e , and d i c k i t e :
Bur. n i n e s Bept. I n v . 5825, 1 3 p.
of
S.
17.
Barton,
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B.,
Jr.,
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1..
1960,
Thermodynamic
p r o p e r t i e s o f some s y n t h a t i c z i n c a n d c o p p e r a i n e r a l s :
~ m .Jour.
S c i . , v. 258-A,
( B r a d l e y volume),
p.
21-34.
Barton,
written
commun.,
May 5,
1967,
has a l s o determined t h e f r e e e w r g y of
farmation of b i s m u t h i n i t e and h i s value has been adopted f o r t h e s e
tables.
cubic,
Jour.
and
1975
THERnODTYAMIC
PROPERTIES
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480 K and magnesite,
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NOTES
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6
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B e a t s o f f o r m a t i o n of c r y s t a l l i n e c a l c i u m
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AIID
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~ ~ P~. ec.,k Neuvonen,

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"
--
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REPEB~ICBS AID
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1963b. L o u - t e m p e r a t u r e h e a t c a p a c i t y
U. S. Bur. n i n e s B e p t . I n v .
a n d e n t r o p y a t 298.15OK o f m u s c o v i t e :
6281, 4 p.
E.
,-,,
P.,
Jr.,
w r i t t e n communication,
September,
1959.
INDEX
281 .
..
Yestrum. E F
Jr., a n d Gronvold. P.,
1963 Chemical thermodynamics
of t h e a c t l n l d e e l e m e n t c h a l c o g e n i d e s . P r o c e e d l n q s
of
the
5 ympos~um on
Thermod ynamlcs o f Nuclear ls t e r i a l s : Vienna. Aust
Internat
Atomic Energy Agency P r o c . Ser., p 3.36
282
283
..
Westrum. E F . , J r . , E s s e n e . E J.,
and P e r k i n s .
D.,
111. 1979.
Thermophysical
properties
grossular.
of
the
garnet.
(Ca3A12S13O I Z ) : J o u r . Chem Thermo..
v
1 1 . p 57-66
S
285 .
..
f l a r g r a v e . J L . , Feder. 8 . M
and Huhbard.
u I.,
1963.
F l u o r i n e bomb c a l o r i m e t r y
V
The h e a t s of f o r m a t i o n of
s l l i c o n t e t r a f l u o r i d e and s i l i c a :
J o u r Phys Chemistry.
v.
67.
p 815.821
Vise.
. S.,
. .
.
Heat c o n t e n t f o r corundum was o b t a i n e d from a l e a s t s q u a r e s f l t t o .

t h e d a t a o f D i t m a r s and Douglas ( 5 0 ) , F r e d r i c k s o n a n d Chasanov
(60)
Furukawa. and o t h e r s
(66)
Ginnings
and
Corruccini
(70)
Krupka
and o t h e r s ( 1 5 2 )
and O e t t i n g ( 182) F o r c o e s i t e
and s t i s h o v i t e . t h e h e a t c o n t e n t was assumed t o be t h e same a s
t h a t of q u a r t z (JANAF. 247) a f t e r t h e h e a t of t h e a - p t r a n s r t i o n
was s u b t r a c t e d
The h e a t c o n t e n t u a s f u r t h e r constrained t o f i t
t h e h e a t c a p a c i t y v a l u e s g i v e n by Holm. Kleppa. and Yestrum ( 1 0 1 )
The e n t r o p y of t r i d y m i t r i s an a v e r a g e o f t h a t g i v e n by Anderson.
C. T.,
A m . Chem
Sw . J o u r . , v. 58. p.568
( 1936)
and a v a l u e
0 . F.,
and
c a l c u l a t e d from t h e r q u i L i b r i u m c u r v e i n T u t t l e .
Uashington.
Geophys
Lab
Ann
England. 3 L., C a r n e g i e I n s t
Rept . 1952-53. p 6 1 . T h e e n t r o p i e s of p h l o g o p i t e . mon t i c e l l i t e .
and p y r o p e a r e e s t i m a t e s
The
entropy
of
rhodonite
was
corrected
for
magnetic
contribution
below 50 K
High
temperature heat content
of
tremollte
was
estimated
The
of f o r m a t i o n of a n d a l u s i t e i s from Anderson. P.A. M.,
enthalpy
Newton. R.C.,
and Kleppa. 0.J., Am . J o u r S c l . ,
277.
p
285
(1977)
The e n t r o p y of pyrope i s from t h e work o f K o l e s n i k . Yu N . , Nogteva.
V V., and Paukov. I Ye.,
1977. Geokhimiya. p 5 3 3
The . h i g h
t e m p e r a t u r e h e a t c a p a c i t i e s of Ca-A1 p y r o x e n e a r e e s t i m a t e s
.. .
..
.
.
.
..
The e n t h a l p y of f o r m a t i o n o f m o l y b d e n i t e a t 298.15 K i s from O ' H a r e .

P.A.G.,
Benn. E., Cheng. F Yu., and Kuzmycz. G ( 1 9 7 0 J o u r Chem
Thermodynamics. p 797) The e n t h a l p y of f o r m a t i o n o f p y r o p h y l l i t e
a t 298.15 K i s from Krupka. K.M., Robie. R.A., and Hemingway. B.S.
(1979 h e r M i n e r a l . , p 8 6 ) and from Hemingway. B.S., Robie. R.A.
and K i t t r i c k . J.A. ( 1 9 7 8 Geochim Cosmochim A c t a . p 1 5 3 3 )
The p n t h a l p y o f f o r m a t i o n o f a n o r t h i t e i s b a s e d upon t h e h e a t o f
s o l u t i o n o f s y n t h e t i c a n o r t h i t e from Kracek ( r e f e r e n c e 148) r a t h e r
t h a n t h e h e a t o f s o l u t i o n f o r a n o r t h i t e r e p o r t e d by B a r a n y
( r e f e r e n c e 9 ) The sample u s e d by Barany c o n t a i n e d 2 p e r c e n t by
w e i g h t of i m p u r i t i e s The c o r r e c t i o n s made by Barany were p r o b a b l y
i n e r r o r f o r t h e t i t a n i u m impurity ( s e e r e f e r e n c e 122) and f o r t h e
sodium f e l d s p a r i m p u r i t y ( s e e K r a c e k . F.C.
and Neuvonen. K.J.,
1952. h e r J o u r S c i . , Bowen Volume) by -8.4 k J / m o l .
a g r e a t e r s t a b i l i t y f o r a n o r t h i t e t h a n t h a t o b t a i n e d fromi n tdhi ec adt iant ga
o f Kracek and from t h e r e c e n t d a t a of C h a r l u . T.V.,
Newtcn. R.C.
a n d Kleppa. O . J . (1978 Geochim Cosmochim A c t a . p 367)
.
.
The e n t h a l p y o f f o r m a t i o n o f g r o s s u l a r . Ca-A1 p y r o x e n e . and g l a s s

o f a n o r t h i t e c o m p o s i t i o n a r e b a s e d upon t h e e n t h a l p y of f o r m a t i o n
choosen f o r a n o r t h i t e
........................ 17
................... 12. 31
A l u m i n u m i o n ................... 1 2
A l u m i n u m o x i d e ......... 18.137. 1 3 8
A l u m i n u m s u l f a t e ........... 25. 3 1 8
A l u m i n u m t r i f l u o r i d e ....... 24. 2 9 0
A l u n i t e .................... 26. 3 2 4
A m m o n i a .................... 16. 1 2 0
A m m o n i a - n i t e r .............. 25. 3 1 5
A m m o n i u m b i s u l f a t e ......... 26. 3 2 7
A m m o n i u m i o n ................... 16
A n a l b i t e ............... 29.412. 4 1 3
A n a l c i m e ....................... 2 9
A n a t a s e .................... 22. 2 3 3
A n d a l u s i t e ............. 27.341. 3 4 2
A n g l e s i t e .................. 26. 3 2 9
A n h y d r i t e .................. 25. 3 2 0
A n o r t h i t e .............. 28.395. 3 9 6
A n t i m o n y ................... 15. 9 6
-Aluminum
(argentite)
Altaite
Westrum. E F., J r . , and Gronvold.

F.,
1970. Manganese d i s u l f i d e
( hauerite)
and manganese d i t e l l u r i d e
Thermal p r o p e r t i e s f r oa 5
t o 3500K and a n t i f e r r o m a g n e t i c t r a n s i t i o n s :
J o u r Chem
Physicsc
52. p . 3820.3826
28U .
Page
...... 16.121
~ k e r m a n i t e ............. 27.357. 3 5 8
+ l a b a n d i t e ................. 17. 1 2 9
pcanthite
447
NAMES
OF
Page
............... 23.269
B r o m e l l i t e ................. 18.143
B r o m i d e i n n .................... 1 2
R r o m i n e .................... 12. 3 9
B r u c i t e .................... 20. 1 8 5
B u n s e n i t e .................. 20. 1 9 9
Bromargyrite
.............. 24.300. 301

................... 26. 3 2 2
A r g o n ...................... 12. 3 2
A r s e n i c .................... 12. 3 3
A r s e n o l i t e ..................... 1 8
A r t i n i t e ....................... 2 5
A z u r i t e ........................ 2 5
Aragonite
Arcanite
......... 28.377. 3 7 8
.................... 12. 4 3
i o n .................... 12
................ 24.302. 3 0 3
.................... 12. 4 2
f e r r i t e ............ 23. 2 5 1
i o n .................... 1 2
n i t r a t e ............ 25. 3 1 2
......... 27.349. 3 5 0
olivine
Ca-A1 pyroxene
Cadmium
Cadmium
Calcite
Calcium
Calcium
Calcium
Calcium
Calcium
.............. 18.148
........................ 2 3
C a r b o n ..................... 12. 4 0
C a r b o n d i o x i d e ............. 18. 1 4 7
C a r b o n m o n o x i d e ............ 18. 1 4 6
C a r b o n a t e i o n .................. 18
........ 18
Carbonic acid (aqueous)
C a s s i t e r i t e ................ 21. 2 2 4
C e l e s t i t e ...................... 2 6
C e r i a n i t e .................. 18. 1 5 0
C e r i u m ..................... 1 2 4 4
Calcium oxide
Calomel
~addeleyite
.................... 12
..... 18.151. 1 5 2
Cerium sesquioxide
c e r u s s i t e ...................... 2 5
.
c e s i u m ..................... 1 3 4 8
Barite
Cesium hydroxide
................ 22. 2 4 9
..................... 25. 3 1 9
B a r i u m ..................... 12. 3 6
B a r i u m i o n ..................... 1 2
B a r i u m o x i d e ............... 1.8. 1 4 2
B e r l i n i t e .................. 26. 3 3 1
B e r y l l i u m .................. 12. 3 7
B e r y l l i u m i o n .................. 1 2
B e r y l l i u m o x i d e ........ 18.143. 1 4 4
B i a n c h i t e ...................... 2 6
B i c a r b o n a t e i o n ................ 1 8
B i s m i t e .................... 18. 1 4 5
B i s m u t h .................... 12. 3 8
B i s m u t h i n i t e ................... 16
B i s u l f i d e i o n .................. 1 7
B i x b y i t e ................... 20. 1 8 8
B o e h m i t e ................... 18.139
B o r a x .......................... 2 6
B o r i c o x i d e ................ 18. 1 4 1
B o r n i t e .................... 17. 1 2 4
B o r o n ...................... 12. 35
B r o c h a n t i t e .................... 2 6
Cerium ions
Cesium ion
........... 19. 1 5 5
.....................
I3
................... 2 6
................. 17.122
Chalcanthite
Chalcacite
.................. 2 5
............... 17. 1 2 3
.............. 23. 2 7 3
Chlorargyrite
C h l o r i d e i o n ................... 1 2
C h l o r i n e ................... 1 2 . 4 5
............ 24.279
Chloromagnesite
C h r o m i t e ................... 23. 2 5 6
C h r o m i u m ................... 1 3 . 4 7
C h r o m i u m i o n ................... 1 3
Chalcocyanite
Chalcopyrite
Chrysoberyl
....................2 2
............. 29.425. 4 2 6
C i n n a b a r ....................... 1 7
c l a u d e t i t e ..................... 1 8
C l a u s t h a l i t e ................... 1 7
Chrysotile
Cobalt
.........
..................... 1 3 . 4 6
i o n s .................... 1 3
Clc~oonstatite
Cobalt
28.387. 3 8 8
Page
Page
................. 25
Page
..................... I3
Cobaltous
Ferric sulfate ............. 26.321
Coccinite .................. 24. 2 9 7 Ferroselite .................... 17
Coesite
21.219
Ferrous ion .................... I3
Cohenite ................... 16. 119
Ferrous oxide .............. 19. 164
Cooperite ...................... 1 7
Fluorapatite ............... 27. 335
Copper ..................... 13. 49
Fluoride ion ................... I3
Cordierite ............. 28.367. 3 6 8 Fluorine ................... 13. 5 3
Corundum ................... 18. 137 Fluorite ................... 24. 291
Cotunnite .................. 24. 2 8 4 Fluorphlogopite ............ 29.420
Covellite ...................... 17 Forsterite ............. 28.363. 3 6 4
Cristobalite ............... 21. 2 1 7 Frohbergite .................... 1 7
Cryolite ................... 24. 2 9 4
Cupric ion ..................... 13 Gadolinium ................. 13. 56
Cuprite .................... 19. 157 Gadolinium sesquioxide . 19.168. 169
Cuprous ion .................... 13 Galena ..................... 17. 132
CaA12Si208 glass ....... 28.397. 3 9 8 Gallium .................... 13. 55
Gallium sesquioxide ........ 19. 167
Dawsonite ...................... 25
Gehlenite .............. 27.351. 3 5 2
Dehydrated analcite ........ 29. 4 0 9 Geikelite .............. 23.266. 2 6 7
Diamond .................... 12. 41 Germanium .................. 13. 5 7
Diaspore ....................... 18 Germanium dioxide .......... 19. 170
Dicalcium ferrite .......... 23. 2 5 2 Germanium dioxide glass .... 19. 171
Dicesium monoxide .............. 19 Gibbsite ................... 18. 1 4 0
Dicesium uranate ........... 27. 3 3 6 Goethite ....................... I9
Dickite ........................ 29 Gold ....................... 12. 3 4
Dilithium monoxide ......... 20. 181 Gosiarite ...................... 2 6 .
Diniobium pentoxide ........ 20. 197 Greenockite .................... 16
Diopside ............... 28.379. 3 8 0 Grossular .............. 27.353. 3 5 4
Dlpataasium monoxide ....... 19. 177 Gypsum ......................... 25
Dirhenium heptoxide ............. 21
Disodium monoxide .......... 20. 193 Hafnia ..................... 19. 174
Disadium uranate ........... 27. 337 Hafnium .................... 13. 6 0
Ditantalum pentoxide ....... 21. 2 2 6 Halite ..................... 24.282 .
Dititanium triaxide ........ 22. 2 3 4 Halloysite ..................... 29
Divanadium pentoxide ....... 22. 2 4 3 Hauerite ....................... 17
Divanadium tetroxide ....... 22.242
Hausmannite ................ 20. 189
Dolomite ................ 24.304. 3 0 5 Heazlewoodite .................. 17
Dysprosium ................. 13. 5 0 Helium ..................... 13. 59
Dysprosium sesquioxide ..... 19. 1 5 8 Hematite ................... 19. 165
Hercynite ...................... 23
Epsomite ....................... 26
Herzenbergite .............. 17. 133
Erbium ..................... 13. 51
Hexagonal anorthite ............ 2 8
Erbium sesquioxide ......... 19. 159
High sanidine .......... 28.401. 4 0 2
Eskolaite .................. 18.154
Holmium .................... 14. 6 2
Eucryptite ............. 28.385. 3 8 6 Holmium sesquioxide ........ 19. 1 7 6
Europium ................... 13. 5 2 Huebnerite ..................... 2 7
Europium oxide ............. 19. 1 6 0 Huntite ........................ 25
Europium sesquioxide ... 19.161. 1 6 2 Hydrogen ................... 13. 5 8
Hydrogen chloride .......... 23. 2 7 7
Fayalite ............... 27.361. 3 6 2 Hydrogen ion ................... 13
Derberite ...................... 2 7 Hydrogen sulfide ........... 17. 1 2 8
.............. 23. 2 5 5
oxide ............ 18. 153
Cobalt spinel
Ferric ion
x.
?..:
.a*.................
'.
~~dromagnesite
Hydrophilite
Hydroxide ion
............... 23. 2 7 4
.................. 19
Hydraxyapatite ............. 26. 3 3 4
Marcesite
................. 26. 326

................... 21. 206
Mascagnite
Massicot
delanterite .................... 26
......................... 29 Mercuric ion ................... 13
Ilmenite ............... 23.257. 2 5 8 Mercurous i o n .................. 1 3
Indium ..................... 14.. 6 4 ~ e r c u r y .................... 13 . 61
Iodargyrite ................ 24. 296 Merwinite .............. 27.355. 356
Iodide ion ..................... 14 Metacinnabar ................... 17
16.118
Iodine ..................... 14. 6 3 Methane ....................
Nicrocline
.............
28.399.
400
Iridium .................... 14. 6 5
Iron ....................... 13. 5 4 Millerite .................. 17. 131
Minium ..................... 21. 209
Jadeite ................ 28.391. 392 Mirabilite ..................... 26
Molybdenite ................ 17. 130
Kaliophillite .......... 28.405. 406 Molybdenum ................. 14. 73
Kaolinite ...................... 29 Molybdenum dioxide ......... 20. 190
Karelianite ................ 22. 241 Molybdite .................. 20. 191
KA1Si308 glass ........ 28.403. 4 0 4 Molysite ................... 23.276
Krypton .................... 14. 6 7 Monohydrocalcite ............... 24
1.
/ ..
.. X y a n i t e ................ 27.339. 3 4 0 Monteponite .................... 18
Monticellite ................... 27 ..................
Lanthanum
14. 6 8 Montroydite ................ 19. 175
Lanthanum sesquioxide ...... 20. 1 8 0 Uorenosite ..................... 26
Larnite (bredigite) ..... 27.347. 3 4 8 Mullite ................ 27.345. 346
Lawrencite ................. 23. 275 M u s c a v i ~ e .............. 29.418. 419
Lavsonite ...................... 27
\.
Lead ....................... 15. 8 3 Neodymium .................. 14. 7 7
Lead ion ....................... 15 Neodymium sesquiaxide ...... 20.198
Lead monoxide .............. 21. 2 0 7 Neon ....................... 14. 7 8
Leonhardite ....................28 Nepheline .............. 29.416. 4 1 7
Leucite ................ 29.407. 4 0 8 Nesquehonite ................... 25
Litharge ................... 20. 205 Nickel ..................... 14 . 79
ithi hi^^ .................... 14. 6 9 Nickel chloride ............ 24. 283
Lithium aluminate .......... 23. 261 Nickelous ion .................. 14
....................
~ ~
14. 7 6
Lithium hydroxide .......... 20. 182 ~ i o b i
Lithium ion .................... 14 Niobium dioxide ............ 20. 196
Low albite ............. 29.410. 6 1 1 Niobium monoxide ........... 20. 195
Lutetium ................... 14. 7 0 Niter ...................... 25. 313
Lutetium sesquioxide ....... 20. 183 Nitrate ion .................... 2 0
Nitrobarite ................ 25. 311
Magnesioferrite ............ 23. 2 6 5 Nitrogen ................... 14 . 7 4
Magnesite .............. 25.306. 3 0 7 Nitrogen dioxide ........... 20.192
Magnesium .................. 14. 71 NaA1Si308 glass ....... 29.414. 4 1 5
Maguesium ion .................. 14
Magnesium nitrate .......... 25. 3 1 4 Oldhamite ...................... 16
Magnetite .................. 19. 166 Orpiment ....................... 16
Malachite ...................... 25 Orthophosphoric acid ... 20.203. 2 0 4
Manganese .................. 14. 72 Osmium ..................... 14. 81
Manganese ion .................. 14 Otavite ........................ 25
Manganese sulfate .......... 26. 325 Oxygen ..................... 14 . 8 0
Illite
'I
................ 20. 186

.................. 17. 127
Manganosite
INDEX
Page
.................. 1 5 . 8 4
.................. 2 0 . 1 8 4
Perovskite ............. 2 3 . 2 5 3 . 2 5 4
Phenacite ...................... 2 7
Phlogopite ..................... 2 9
Phosphate i o n .................. 2 0
Phosphorus ................. 1 4 . 8 2
Palladium
Periclase
........ 2 0 . 2 0 0
... 2 0 . 2 0 1 . 2 0 2
Picrochromite .......... 2 3 . 2 6 3 . 2 6 4
Platinum ................... 1 5 . 8 6
Plattnerite ................ 2 1 . 2 0 8
Plutonium .................. 1 5 . 8 7
Portlandite ................ 1 8 . 1 4 9
Potassium .................. 1 4 . 6 6
Potassium aluminum s u l f a t e . 2 6 . 3 2 3
Potassium bromide .......... 2 3 . 2 7 0
Potassium hydroxide ........ 1 9 . 1 7 9
Potassium ion .................. 1 4
Potassium superoxide ....... 1 9 . 1 7 8
Powellite ...................... 2 7
Praseodymium ............... 1 5 . 8 5
Praseodymium oxide ......... 21. 2 1 1
Praseodymium sesquioxide .... 2 1 . 2 1 0
Pseudobrookite ............. 2 3 . 2 6 0
Pseudowollastonite ..... 2 8 . 3 7 5 . 3 7 6
Pyrite ..................... 1 7 . 1 2 6
Pyralusite ................. 2 0 . 1 8 7
Pyrope ................. 2 8 . 3 6 5 . 3 6 6
Pyrophyllite ........... 2 9 . 4 2 3 . 4 2 4
Pyrrhotite ..................... 1 7
Phosphorus monoxide
Phosphorus pentoxide
Quartz
..................... 2 1 . 2 1 6
...................... 1 5 . 9 1
........................ 1 6
Retgersite ..................... 2 6
Rhenium .................... 1 5 . 8 9
Rhenium dioxide ................ 2 1
Rhenium trioxide ............... 2 1
Rhodium .................... 1 5 . 9 0
R h o d o c h r ~ s i t e .............. 2 5 . 3 0 8
Rhodonite .............. 2 8 . 3 8 9 . 3 9 0
Rubidium ................... 1 5 . 8 8
Rubidium ion ................... 1 5
Ruthenium .................. 1 5 . 9 2
Rutile ..................... 2 2 . 2 3 2
Radon
Realgar
................ 2 4 . 2 8 1
................... 1 5 . 1 0 0
sesquioxide ... 2 1 . 2 2 2 . 2 2 3
Salammoniac
Samarium
Samarium
Page
...................
..................
Scandium ...................
Scandium sesquioxide .......
214
Scheelite ......................
Selenium ...................
Selenium ion ...................
Sellaite ...................
Siderite .......................
Silica glass ...............
Silicic acid (aqueous) .........
Silicon ....................
Silicon monoxide ...........
Sillimanite ............
Silver .....................
Silver ion .....................
Smithsonite ....................
Sanmartinite
Scacchite
27
24.280
15.
97
21.
27
15.
98
15
24.292
25
21. 2 2 1
15.
Terbium
................. 2 5 . 3 1 6
..................... 1 4 . 7 5
Sodium hydroxide ........... 2 0 . 194
Sodium i o n ..................... 14
Sphalerite ................. 1 7 . 1 3 5
Spinel ..................... 2 3 . 2 6 2
Spodumene .............. 2 8 . 3 8 1.384
Stannic sulfide ............ 1 7 . 1 3 4
Steam ...................... 1 9 . 1 7 3
Stibnite ....................... 1 7
Stishovite ................. 2 1 . 2 2 0
Stolrite ....................... 2 7
Strengite ...................... 2 7
Strontianite ........... 2 5 . 3 0 9 . 3 1 0
Strontium .................. 1 5 . 1 0 2
Strontium bromide .......... 2 3 . 2 7 1
Strontium ion .................. 1 5
Strontium nitrate .......... 2 5 . 3 1 7
Strontium oxide ............ 2 1 . 2 2 5
Sulfate ion .................... 2 1
Sulfide ion .................... 1 5
S u l f i t e ion .................... 2 1
Sulfur ................. 1 5 . 9 3 - 9 5
S u l f u r dioxide ............. 2 1 . 2 1 2
Sulfur trioxide ............ 2 1 . 2 1 3
Sulfuric acid .................. 2 6
Sylvite .................... 2 4 . 2 7 8
Szomolnokite ................... 2 6
Soda niter
Sodium
...............,... 2 9 . 4 2 1 . 4 2 2
................... 1 5 . 1 0 3
Tellurite ...................... 2 2
Tellurium .................. 1 5 . 1 0 5
Tenorite ................... 1 9 . 1 5 6
Tephraite .............. 2 8 . 3 6 9 . 3 7 0 -.
22.228.
....
229
Uranium trichloride
Uranium trioxide
22.227
22.236
................... 1 6 . 1 0 8
Thenardite ................. 2 6 . 3 2 8
Tharianite ................. 2 2 . 2 3 0
Thorium .................... 1 6 . 1 0 6
Thulium .................... 1 6 . 1 0 9
Thulium sesquioxide ........ 2 2 . 2 3 7
.................... 2 2 . 2 5 0
........................ 1 5 . 1 0 1
Titanite (sphene) ...... 2 7 . 3 5 9 . 3 6 0
Titanium ................... 1 6 . 1 0 7
Titanium oxide ............. 2 2 . 2 3 1
Titanium tribromide ........ 2 3 . 2 7 2
Titanium trichloride ....... 2 4 . 2 8 5
Titanomagnetite ............ 2 3 . 2 5 9
Tremolite
451
NAMES
Page
15. 1 0 4
Thallium
Tin
30
....................
oxide ..........
sesquioxide ........
Tetratitanium heptoxide
Tialite
12
Tantalum
Terbium
21
25
Talc
Terbium
99
21. 2 1 5
27.343. 3 8 4
12.
OF
.............. 2 8 . 3 9 3 .
394
...................... 2 3
Tridymite .................. 2 1 . 2 1 8
Trisodium uranium oxide .... 2 7 . 3 3 8
Trititanium pentoxide ...... 2 2 . 2 3 5
Troilite ................... 1 7 . 1 2 5
Tungsten ................... 1 6 . 1 1 2
Tungsten dioxide ........... 2 2 . 2 4 4
Tungsten trioxide .......... 2 2 . 2 4 5
Tungstenite .................... 1 7
Uraninite .................. 2 2 . 2 3 8
Uranium .................... 1 6 . 1 1 0
Uranium ions ................... 1 6
Uranium tetrachloride ...... 2 4 . 2 8 7
Uranium tetrafluoride ...... 2 4 . 2 9 5
Valentinite
........
Page
24. 2 8 6
........... 2 2 . 2 3 9
.................... 2 1
................... 1 6 . 1 1 1
Vanadium dichloride ........ 2 4 . 2 8 8
Vanadium monoxide .......... 2 2 . 2 4 0
Vanadium trichlaride ....... 2 4 . 2 8 9
Vaterite ....................... 2 4
Villiaumite ................ 2 4 . 2 9 3
Vanadium
Water
...................... 1 9 . 1 7 2
............ 2 6 . 3 3 2 . 3 3 3
...................... 2 8 .............. 2 4 . 2 9 8 . 2 9 9
Wollastonite ........... 2 8 . 3 7 3 . 3 7 4
W u l f e n i t e ...................... 2 7
Wurtzite ................... 1 8 . 1 3 6
Wustite .................... 1 9 . 1 6 3
Whitlockite
Willemite
Witherite
Trevorite
Xenon
...................... 1 6 . 1 1 3
Ytterbium
.................. 1 6 . 1 1 5
...... 2 2 . 2 4 7
.................... 1 6 . 1 1 4
Ytterbium sesquioxide
Yttrium
Yttrium sesquioxide
........
22. 246
....................... 1 6 . 1 1 6
....................... 1 6
Z i n c t i t a n i u m spinel ....... 2 3 . 2 6 8
Z i n c i t e .................... 2 2 . 2 4 8
Zinkosite .................. 2 6 . 3 3 0
Zircon ................. 2 8 . 3 7 1 . 3 7 2
Zirconium .................. 1 6 . 1 1 7
Zinc
Zinc ion
'a!
Page
......................... 13 . 4 7
~ r + + ........................... 13
C r 2 0 3 ...................... 18. 154
C s ......................... 13. 4 8
C S + ............................ 13
C s O H ....................... 19. 155
C s 2 0 ........................... 19
C s 2 U 0 4 ..................... 27. 3 3 6
C u ......................... 13. 4 9
............................ 13
cU++ ........................... 13
C u F e S 2 ..................... 17. 123
c u o ........................ 19. 156
C u S ............................ 17
.c U S o 4 .......................... 25
..................... 26
CuS04.5H20
C U ~ ( C O ~ ) ( O H )..................
~
25
C u 2 0 ....................... 19. 157
C u 2 s ....................... 17. 122
C U ~ ( O H ) ~ ( C O .................
~)~
25
C U ~ S O ~ ( O H....................
)~
26
Page
Cr
CU+
.................. 29
A 1 2 S i 4 0 1 0 ( O H ) 2 ......... 29.423. 4 2 4
A 1 2 T i 0 5 .................... 22. 2 5 0
(A17Mg)(Si14A12)040(OH)
........ 29
Ar ......................... 12. 32
As ......................... 12. 3 3
A12Si205(OH)4
. . .
......................... 27
........................ 18. 148
*
C a S ............................ 16
C a S 0 4 ...................... 25. 3 2 0
C a S 0 4 * 2 H 2 0 ..................... 25
CaSiO, ................. 28.37 3.376+
CaMo04
CaO
Cu5FeS4
.................... 17. 1 2 4
................... 23.252
.......................... 12. 3 5 C a 2 M g S i 2 0 9 ............. 27.357. 358
Ba ......................... 12. 36 C a 2 M g 5 ( S i 0 22)(OH)2 .... 28.393. 3 9 4
~ a + + ........................... 12 C a 2 S i 0 4 ................ 27.34 7-350
Ba(N03)2 ................... 25. 311 C a 3 ( P 0 4 ) 2 .............. 26.332. 3 3 3
B a C 0 3 .................. 24.298. 2 9 9 - C a 3 A 1 2 S i 3 0 1 2 ........... 27.353.354.C
BaO ........................ 18. 142 C a 3 ~ g ' ( ~ i 0 4 ) 2........... 27.355. 356
B a S 0 4 ...................... 25. 319 Ca5(P04)3F ................. 27.335
Be ......................... 12. 37 Ca5(P04)30H ................ 26. 3 3 4
~ e + + ........................... 12 Cd ......................... 12. 4 3
B e A 1 2 0 4 ........................ 22 Cd++ ........................... 1 2
B e 0 .................... 18.143. 144 CdCO, .......................... 25
B e 2 S i 0 4 ........................ 27 C d O ............................ 18
Bi ......................... 12. 3 8 CdS ............................ 16
~ i + + + .......................... 1 2 Ce ......................... 12. 4 4
B i 2 0 3 ...................... 18. 145 ~ e + + + .......................... 12
B i 2 S 3 .......................... 16 Ce++++ ......................... 12
Ca2Fe205
............................. 13
......................... 13. 5 4
e++ ........................... 13
~ e + + + .......................... 13
Fe.877S ........................ 17
F e .9 4 7 0 .................... 19. 1 6 3
................... 27
Fe(P04).2H20
F e A 1 2 0 4 ........................ 23
F e C 0 3 ..........................25
F e C 1 2 ...................... 23.275
F e C 1 3 ...................... 23. 2 7 6
F e C r 2 0 4 .................... 23. 2 5 6
F e O ........................ 19. 164
FeO(0H) ........................ 19
FeS ........................ 17. 125
..................... 26
FeS04.7H20
F e S O .H 2 0 ...................... 26
F e S e 2 .......................... 17
F e S 2 ................... 17.126. 127
F e T e 2 .......................... 17
F-
Fe
Page
................. 23.257.258
F e W 0 4 .......................... 27
Fe2(S04)3 .................. 26. 321
F e 2 0 3 ...................... 19. 165
F e 2 S i 0 4 ................ 27.361. 3 6 2
F e 2 T I 0 4 .................... 23. 259
F e 2 T i 0 5 .................... 23. 2 6 0
F e 3 C ....................... 16. 119
F e 3 0 4 ...................... 19. 166
F 2 ......................... 13. 5 3
FeTi03
............................. 13
.......................... 18
H C 1 ........................ 23.277
HS- ............................ 17
H e ......................... 13. 59
H f ......................... 13. 6 0
H f 0 2 ....................... 19. 174
Hg ......................... 13. 6 1
H g + + ........................... 13
H g C l ........................... 23
H g 1 2 ....................... 24.297
HgO ........................ 19. 175
H g S ............................ 17
n g 2 + + .......................... 13
......................... 14. 6 2
H o 2 0 3 ...................... 19. 176
H z ......................... 13. 5 8
H 2 0 .................... 19.172. 1 7 3
n2s ........................ 17. 128
n 2 s 0 4 .......................... 26
H 3 P 0 4 .................. 20.203. 2 0 4
H 4 S i 0 4 ......................... 21
H+
nco3-
HO
Page
Page
.... 29.418. 419

........................ 23.270
24. 278
KMg3(A1Si3Ol0)F2
........... 29. 420
KMg3(A1Si3010)(OH)2
-........... 29
KN03 ....................... 25. 313
KOH ........................ 19. 179
KO2 ........................ 19. 178
Kr ......................... 14 . 6 7
K2A16(OH)12(S04)4
.......... 26. 324
K20 ........................19. 177
K2S04 ...................... 26. 322
....................... 20. 187

MnS ........................ 17. 129
MnS04 ...................... 26. 325
MnSi03 ................. 28.389. 390
MnS2 ........................... 17
Mnw04 .......................... 27
nn203 ...................... 20. 188
Mn2Si04 ................ 28.369. 370
Mn3O4 ...................... 20. 189
Mo ......................... 14. 73
MOO2
20. 190
Moo3 ....................... 20. 191
...................... 20. 180

Li ......................... 14. 69
~ i +............................ 14
LiA102 ..................... 23. 261
LiA1SiO4 ............... 28.385. 386
LiA1Si206 .............. 28.38 1.384
LiOH ....................... 20. 182
Li20 ....................... 20. 181
Lu ......................... 14. 70
Lu203 ...................... 20. 183
*
........................
16. 120
NH4
........................... 16
NH4C1
24. 281
NH4HS04 .................... 26. 327
(NH4)2S04 .................. 26. 326
NH4N03 ..................... 25. 315
NO2- .........................20. 192
KA12(A1Si3010)(OH)2
KBr
KC1 e.......................
La203
Mn02
Page
........................ 20. 199

NiS ........................ 17. 131
NiS04.6H20
..................... 26
NiS04.7H
0
26
Ni3S2 .......................... 17
N 2 ......................... 14. 74
NiO
k....................
Page
......................... 15. 96
Sb203 .......................... 21
Sb2S3 .......................... 17
Sc ......................... 15. 97
Sc203 ...................... 21. 214
Se ......................... 15. 9 8
-Se
........................... 15
Sb
o......................
NH3+
e.....................
NO3
e..........................
20
......................... 14. 75
~ a +............................14
NaA1(S103)2 ............ 28.391. 392
NaA1C03(0H)2 ................... 25
NaAtSi04 ............... 29.416. 417
NaA1S1206 .................. 29. 409
NaA1SI2O6.H20
.................. 29
Na
.............. 29.41 0-415

....................... 24. 282
........................ 24. 293
NaN03 ...................... 25. 316
NaOH ....................... 20. 194
Na2B4O7.10H20
.................. 26
Na20 ....................... 20. 193
Na2S04 ..................... 26. 328
NaZS04*10H20 ................... 26
Na2U04 ..................... 27. 337
Na A1F6 .................... 24.29.4
Na3U04 ..................... 27. 338
Nb ......................... 14. 76
NbO ........................ 20. 195
Nb02 ....................... 20. 196
Nb205 ...................... 20. 197
Nd ......................... 14. 77
Nd203 ...................... 20. 198
Ne ......................... 14. 78
Ni ......................... 14. 79
~ i + + ........................... 14
NiCl? ...................... 24. 283
NaAlSi308
NaCl
NaF
PbC03
.......................... 25
...................... 24. 284

PbMo04 .........................27
PbO .................... 20.20 5-207
Pb02 ....................... 21. 208
PbS ........................ 17. 132
PbS04 ...................... 26. 329
PbSe ........................... 17
PbTe ........................... 17
PbW04 .......................... 27
Pb3O4 ...................... 21. 209
'Pd ......................... 15. 84
Pr ......................... 15. 85
Pr01.833 ................... 21.211
Pr203 ...................... 21. 210
Pt ......................... 15. 86
PtS ............................ 17
Pu ......................... 15. 87
P205 ................... 20.201. 202
PbC12
......................... 15. 102

........................... 15
Sr(N03)2 ................... 25. 317
SrBr2 ...................... 23. 271
srC03 .................. 25.309. 310
SrO ........................ 21. 225
SrS04 ..........................26
Sr
srf+
Page
.......................
.....
..........................
VC12 .......................
.......................
vo .........................
.......................
.......................
.......................
..........................
........................
........................
............................
.........................
U02
U03
V
22.238
i,..................
22. 239
16. 1 1 1
24. 2 8 8
VC13
24.289
22.240
V203
22. 2 4 1
V204
22. 2 1 2
V205
22. 2 4 3
16. 1 1 2
W02
22. 244
~0~
22. 2 4 5
Us2
17
Xe
Page
..........................
.........................
........-.....-.....-.
.......................
.........................
~ n + +...........................
..........................
........................
................
......................
.....................
.....................
........................
....................
.........................
.......................
Y
16. 114
Yb
16. 115
Yb203
Y203
22.247
22. 246
Zn
16. 116
ZnO
17.
18.135. 136
26. 3 3 0
ZnS04.6H20
26
ZnS04-7H20
26
Zn2Si04
28
Zn2Ti04
23. 2 6 8
Zr
16. 117
Zr02
22. 249
ZrSi04
?>
25
22. 2 4 8
ZnS
ZnSOd
16. 1 1 3
16
ZnC03
.................
28.371.
372
U.S. Government Printing Office: 197%281-359/75

THERMODYNAMIC MINERALS

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THERMODYNAMIC MINERALS

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*

A summary of the thermodynamic datafor minerals

Reprinted with corrections 1979

UNITED STATES DEPARTMENT OF THE INTERIOR

CECIL D. ANDRUS, Secretary

Library of Congress Cataloging in Publication Data

For sale by Superintendent of Documents, U.S. Governn~entPrinting Office

Stock Number 024-001-03065-9

The purpose of these tables of thermodynamic properties is to present

R E F E R E N C E STATES AND TRANSITIONS

THERMODYNAMIC PROPERTIES O F MINERALS

constants, a n d conversion factors

REFERENCL.: STATES AND TRANSITIONS

Also, for an ideal gas,

Thus, for a gaseous phase, C;, (H+-H",,,)/T, and AH",re independent of

R E F E R E N C E STATES AND TRANSITIONS

and because the enthalpies of formation of most multiple-oxide phases are

THERMODYNAMIC PROPERTIES OF MINEBALS

ingless result ensues. If a reaction involves both multiple-oxide phases

tabulating the thermodynamic properties of aqueous ions has been given

Having chosen what we believe are the currently "best available"

(GI - H",,)/T = ( H I - H",&/T - S;

rounding off again tends to obscure small differences of major importance

COBALT ( REFEREICE STATE)

CHPOllUl ( RETEBEYCE STATE)

APGON (RETXRZlCE STATE)

OrSPROSIUII (REFERENCE STATE)

BROIINE (IDEAL GAS)

IRON ( REFERENCE STATE)

CARBON (REFERENCE STATE)

13.591 262 262

cIDOLINIUl (REIEPENCE STATE)

~ ~ f 0 Log, Kf~ R~ e f e~r e n c e s

TRERMODT NAnIC PROPERTIES OF NINERALS

IODINE (REFERENCE STATE)

INDIUI ( REPERENCE STATE)

LEAD ( REPEIEUCE STATE)

pLATI1UM (REPERENCE STATE)

POTASSIIIfl (PEFERENCE STATE)

RUBIDIUM (REPEREICE STATE)

NITROGEN ( REFERENCE STATE)

SODIUM (REFERENCE STATE)

NICKEL (REFERENCE STATE)

OXYGEN ( REPEREUCE STATE)

OShIUs ( REPERENCE STATE)

RUTHENIUM ( BEFERENCE STATE)

SULWR (REPEREICE STATE)

RADON ( R,??ERENCE STAT,?)

AmI1*O*T ( REFERENCE STATE)

s,?LE*IUII ( REFERENCE STATE)

RRODIUR (REFERENCE STATE)

7.989 263 263

TITANIUU (REFERENCE STATE)

THALLIUI (REFERENCE STATE)

VANAOIUU (REFERENCE STATE)

xewou (REFERENCE STATE)

U ~ D R O G E USULFIDE ( roeu GAS)

ZIUC (ItEFEREUCE STATE)

URHANE (IDEAL GAS)

108 109 115

OXIDES AND HYDROXIDES

OXIDES AND BYOROXIDES

AmI1OT ( REFERENCE STATE)