I.

Pengolahan data

Run ke-

1
2
3
4
5
6
7
8
9
10
11
12

A
60

90

120

150

180

0.329754

0.326058

0.318759

0.313364

0.308035

0.316953

0.302771

0.29243

0.283997

0.267606

0.304518

0.294136

0.280669

0.266001

0.248721

0.29243

0.272459

0.245652

0.220404

0.185752

0.318759

0.309804

0.304518

0.294136

0.29073

0.304518

0.29073

0.277366

0.262807

0.248721

0.29073

0.264401

0.242604

0.220404

0.197911

0.295849

0.258061

0.235077

0.203426

0.175224

0.018634

0.018634

0.018634

0.014125

0.019542

0.078834

0.044793

0.018634

0.016825

0.015923

0.154902

0.129596

0.095826

0.065502

0.030584

0.20204

0.179142

0.149967

0.115771

0.08302

1) Grafik A terhadap t

Kurva A vs t (Run 1-4)

0.35
0.3
Run 3

Absorbansi

0.25

Run 1

0.2

Run 2
y 1 = -0.0002x + 0.3416
R = 0.9929

0.15
0.1

y 2 = -0.0004x + 0.3397
R = 0.9891

0.05

y 3 = -0.0005x + 0.3347
R = 0.9918
y 4 = -0.0009x + 0.3495
R = 0.9914

Run 4
Linear (Run 3)
Linear (Run 1)
Linear (Run 2)
Linear (Run 4)

0
0

50

100

150

200

t (menit)

Kurva A vs t (Run 5-8)

0.35
0.3
Run 5

Absorbansi

0.25

Run 6
0.2

Run 7

0.15

y 5 = -0.0002x + 0.3323
R = 0.9812

0.1

y 6 = -0.0005x + 0.3326
R = 0.9998

0.05

Run 8
y 7 = -0.0008x + 0.3351
R = 0.9988
y 8 = -0.001x + 0.3519
R = 0.9956

Linear (Run 5)
Linear (Run 6)
Linear (Run 7)
Linear (Run 8)

0
0

50

100
t (menit)

150

200

Kurva A vs t (Run 9-12)

0.25

y 11 = -0.001x + 0.2204
R = 0.9975

Absorbansi

0.2
0.15

y 12 = -0.001x + 0.2666
R = 0.9945
Run 9

y 9 = -9E-06x + 0.019
R = 0.0391

Run 10
Run 11

y 10 = -0.0005x + 0.0965
R = 0.7938

0.1

Run 12
Linear (Run 9)
Linear (Run 10)

0.05

Linear (Run 11)

Linear (Run 12)

0
0

50

100

150

200

t (menit)

2) Grafik A terhadap t Penentuan Orde Reaksi

r (lajureaksi) diperoleh dari masing-masing kemiringan grafik A terhadap t.
[M] =
Aseton (Run 1-4)
Run ke-

ln r

[Aseton]

ln [Aseton]

0,0002

-8,51719

0.2

-1.60944

0,0004

-7,82404

0.4

-0.91629

0,0005

-7,60090

0.6

-0.51083

0,0009

-7,01311

0.8

-0.22314

Aseton
0
-8

-6

-4

y = 0.9479x + 6.521
R = 0.9604

ln[Aseton]'

-10

-2

-0.2 0
-0.4
-0.6
-0.8
-1
-1.2

Series1
Linear (Series1)

-1.4
-1.6
ln r

-1.8

y = 0.9479x + 6.521
dimana m = orde reaksi untuk Aseton (x) = 0.9479 1
HCl (Run 5-8)
Run ke-

ln r

[HCl]

ln [HCl]

0,0002

-8.51719

0.066667

-2.70805

0,0005

-7.60090

0.133333

-2.0149

0,0008

-7.13089

0.2

-1.60944

0,0010

-6.90775

0.266667

-1.32176

6
7
8

HCl
0
-10

-8

-6

-4

-2

0
-0.5

ln[HCl]'

-1
y = 0.8397x + 4.417
R = 0.9922

-1.5
-2

Series1
Linear (Series1)

-2.5
-3

ln r

y = 0.8397x + 4.417
dimana m = orde reaksi untuk HCl (y) = 0.8397 1
I2 (Run 9-12)
Run ke9
10
11
12

ln r

[ I2]

ln [ I2]

0.000009

-11.6183

0.002

-7.31322

0.0005

-7.6009

0.00267

-6.62007

0.001

-6.9077

0.003

-6.21461

0.001

-6.9077

0.00367

-5.92693

I2
0
-15

-10

-5

-1

-2
ln [I2]'

-3
y = 0.2481x - 4.47
R = 0.8724

-4

Series1

-5

Linear (Series1)

-6
-7
-8

ln r

y = 0.2481x - 4.47
dimana m = orde reaksi untuk I2 (z) = 0.2481 0

3) PenentuanNilai K
r = k [Aseton]x[HCl]y[I2]z

dengan, x = 1,y = 1 dan z = 0

Run ke-

[Aseton]x

[HCl]y

[I2]z

0.0002

3M

1 M

0,01 M

0.0004

3M

1M

0,01 M

0.0005

3M

1M

0,01 M

0.0009

3M

1M

0,01 M

0.0002

3M

1M

0,01 M

3M

1M

0,01 M

3M

1M

0,01 M

3M

1M

0,01 M

3M

1M

0,01 M

3M

1M

0,01 M

3M

1M

0,01 M

6
7
8
9
10
11

0.0005
0.0008
0.0010
0.000009
0.0005
0.001

k
6.66667E-05
0.000133333
0.000166667
0.0003
6.66667E-05
0.000166667
0.000266667
0.000333333
0.000003
0.000166667
0.000333333

12

3M

0.001

1M

0,01 M

k rata-rata

Sehingga diperoleh laju reaksi iodinasi aseton dengan katalis asam dalah
r = 0.000195[Aseton]1[HCl]1[I2]0

0.000333333
0.000195
-1 -1
M s