TP ON CNG NGHIP CAO SU VN

CNG TY TNHH MTV CAO SU LC NINH

CNG HA X HI CH NGHA VIT NAM

S : .........../BC-CSLN

c lp - T do - Hnh phc
Bnh Phc, ngy. thng ..nm 2011

BO CO
V vic thc hin nh ng khng s dng
acid sulfuric cho m skim.
1. Thng tin chung v cng ngh sn xut m skim ti Cng ty TNHH MTV cao su Lc
Ninh:
Cng ty TNHH MTV cao su lc ninh trc thuc tp on cng nghip cao su Vit
Nam c tr s ti th trn lc ninh huyn lc ninh tnh bnh phc.
Cng ty qun l 08 nng trng v 01 X nghip c kh ch bin Lc Hip, 01 X
nghip xy lp v 01 Trung tm y t.
Hot ng sn xut kinh doanh chnh ca cng ty:
- Trng, chm sc, khai thc, ch bin v tiu th sn phm cao su.
- Lm dch v cho vic pht trin cao su Tiu in.
- Nhp khu my mc, vt t, thit b ch bin cao su.
- u t xy dng c s h tng khu cng nghip v dn c.
X nghip c kh ch bin Lc Hip (ti x Lc Hip) c u t xy dng vo nm
2002 ban u bao gm 02 dy chuyn ch bin m cm SVR 10, 20 v dy chuyn ch bin
m ly tm HA, LA. Hin nay, c thm dy chuyn ch bin m cm SVR3L, 5 (c di di
t nh my khu vc Lc Ninh).
Trong qu trnh hot ng sn xut kinh doanh Cng ty khng ngng tm ti, hc hi
thay i cng ngh ch bin em li hiu qu sn xut nh: nng cao nng sut sn phm,
gim chi ph ch bin, ci thin mi trng lm vic ca cng nhn bn cnh cng tc
qun l mi trng nh my lun c cng ty ch trng.
Ring i vi dy chuyn ch bin m ly tm, ngoi sn phm chnh l latex c
DRC60% th cn c phn sn phm ph l m skim m vic nh ng m skim rt kh t
KT\D\Trinh\Nm2011\BCKHAC- Bo co nh ng m skim.doc

c do hm lng cao su thp (4-7%), kh khn gia tng khi cc ht cao su c trong m
skim l cc loi ht nh nht c trong m nc v lng NH3 cn li trong m skim tng
i ln. Nu x l khng tt s gy nh hng ln n mi trng lm vic ca cng nhn
do mi hi ca m v nh hng n hiu qu hot ng ca h thng x l nc thi.
Nm 2002 di s hng dn ca ng Pierre Michel ng dng cng ngh ca Php
trong vic ch bin m ly tm cng nh nh ng m skim. Cng ngh ban u c nh
my s dng cho vic nh ng m skim nh sau:
M skim

H cha

Thp kh
nh ng hai dng
chy

M skim

Acid sulfuric
Mng nh ng

Quy trnh ch bin:

M skim sau khi ra khi my ly tm c cha trong h m skim c bm ln thp
kh v i qua h thng thp kh, m skim i qua mng phn phi xung mng nh ng.
Ly 50 ml mu gi phng kim phm kim tra pH v NH3 pha dung dch acid sulfuric 10%
tin hnh nh ng m. M c nh ng theo phng php hai dng chy (01 dng
chy m skim v 01 dng chy ca acid sulfuric ) trn u 02 dung dch
Mi mng cha 20.000 22.000 lt hn hp. lng dung dch sulfuric dng cho 1
mng khong 1.000 1.2000 l acid sulfuric 10%.
Cho 50% lng dung dch acid sulfuric cn nh ng vo mng trong ngy u
nh ng.
Sau 48 gi cho thm 50% lng dung dch sulfuric cn li vo mng v v cho cng
nhn trn u m v acid bng dng c co.
Thi gian ng t ca m t 3-5 ngy.

KT\D\Trinh\Nm2011\BCKHAC- Bo co nh ng m skim.doc

Tuy nhin thc t sn xut khi nh ng m skim li gy ra nhng cn tr nht l v

mi trng lao ng ca cng nhn khi phi lm vic trong mi trng c hi, nng
nhc.v d lng ho cht cn li trong serum khi m ng t gy kh khn cho hot ng
x l nc thi nh hng ln n mi trng xung quanh.
Nm 2006- 2007 hn ch cho vic tip xc gia cng nhn vi acid sulfuric cng
nh trnh gy nguy him khi cng nhn di chuyn trn thnh mng nh ng trn u
acid v m skim. T , Cng ty t nghin cu ch to mi my quy m t hnh
khuy trn m skim v acid trong mng nh ng. My c tc 80 vng trn pht, cng
xut 2 HP, my t di chuyn qua li trn mng nh ng.
M skim

H cha

M skim

Thp kh
nh ng hai dng
chy

Acid sulfuric
Mng nh ng

My quy m
t hnh

Quy trnh ch bin:

Sau khi m t thp kh v acid chy song song vo y mng, s cho my t vn hnh v
khuy trn lm hp cht v m c khuch tn u trong mng trong thi gian k2 gi.
Trong thi gian khuy trn nh tc c khuy cao hn lao ng th cng nn gp phn lm
bay hi thm d lng NH3 cn li, to iu kin lng acid trung ho NH3, do kh
nng ng t m c tt hn.

KT\D\Trinh\Nm2011\BCKHAC- Bo co nh ng m skim.doc

Hnh 1 My quy m t hnh

Cui nm 2007, sau khi nm thng tin v tnh hnh nh ng m skim ti cng ty Trang
Latex, Thi Lan. Cng ty tin hnh xy dng h thng kh NH3 spillway loi b hon
ton vic s dng acid sulfuric trong nh ng m skim.
H cha m skim

Mng spillway

Thp kh NH3

Mng nh ng

Bi tn tr

Quy trnh ch bin:

Trn nguyn l lng NH3 bay hi khi dng m skim, nh hng bi nhng yu t
chnh nh sau: mt thong bay hi, tc gi, nhit tip xc. Da vo nhng yu t trn
Cng ty thit k mt mng kh NH3 (mng spillway), pha trn c mi che c ph
nilong trong sut, cch ni lm vic chnh ca cng nhn 100m, mng c chiu di 300m,
b rng lm vic ca mng l 0.08m, dc 0.5%, mng c ch to bng inox phng,
dy 1.5mm.
KT\D\Trinh\Nm2011\BCKHAC- Bo co nh ng m skim.doc

Dng m skim sau khi ra khi my ly tm theo mng dn chy trn xung h m. Sau
s c bm ln mng spillway cho chy trn t nhin trong ton b mng theo
dc c thit k, dy ca dng chy c iu chnh t 3-5mm, lng NH3 s c
bc hi khi dng m skim do mt thong rng v lp cht lng mng. Do v tr mng kh
nm l thin nn tn dng c nng lng mt tri gia nhit cho dng chy m skim v
gi t nhin ngoi tri s lm cho qu trnh bay hi ca kh NH3 c nhanh hn.

Hnh 2- H thng spillway.

M skim sau khi ra khi mng li c bm ln thp kh NH3
Ti nh my b tr hai thp kh NH3 kch thc rng 1m di 1.8m cao 9m. Khung thp lm
bng thp, cc mng lm bng inox c b tr sao cho dng chy skim trong mng chy
ziczac (gm 32 mng) pha sau mi thp c b tr bn qut thi.

KT\D\Trinh\Nm2011\BCKHAC- Bo co nh ng m skim.doc

Hnh 3- Thp kh NH3

Mng nh ng m:
M skim sau khi chy qua thp kh theo ng ng chy xung mng ng t, mng c
kch thc di 22m x rng 1m x cao 1m. Khi b tr ct mng m thng cha li mt phn
serum trong mng sau mi cho m skim mi chy vo (nc serum cn li trong
mng s cha mt lng vi khun c li cho vic ng t m skim mi) v do Cng ty
khng s dng acid sulfuric cho vic nh ng, m skim sau khi chy vo mng s c
ng t hon ton t nhin trong vng 4-5 ngy.

KT\D\Trinh\Nm2011\BCKHAC- Bo co nh ng m skim.doc

Hnh 4- Mng m skim ng t.

M sau khi ng t c ct thnh tng khi mang ra bi tn tr cho n khi xut hng.

Hnh 5- Bi tn tr m skim.
2. Hiu qu t c v mt k thut:
So snh 02 ch tiu pH v NH3 khi nh ng m skim bng acid v khi m ng t t
nhin sau khi qua h thng kh NH3:
V tr ly mu

NH3

pH

Trc thp kh NH3

0.58

10.41

Sau thp kh NH3

0.22

9.67

(Theo kt qu phn tch mu ngy 13/12/200 ca phng kim nghim cht lng Cng ty).
V tr ly mu

NH3

pH

Trc mng spillway

0.54

10.32

Sau mng spillway

0.27

9.79

Sau thp kh NH3

0.14

9.44

(Theo kt qu phn tch mu ngy 07/10/2011 ca phng kim nghim cht lng Cng ty).

KT\D\Trinh\Nm2011\BCKHAC- Bo co nh ng m skim.doc

3. Hiu qu v mt kinh t:
Bng so snh chi ph nh ng m skim
Ni dung

nh ng bng acid
nh ng khng s
sulfuric
dng acid sulfuric
Chi ph ho cht
120 kg H2SO4 / tn m skim 0
x 5.750 VN = 690.000
VN
Chi ph in vn hnh h 145 Kw/tn sn phm x 211 Kw/ tn m skim x
thng
1.043 VN = 151.000 VN 1.043 VN = 320.000
VN
Chi ph nhn cng
2.2 cng/tn m skim x 2.2 cng/ tn m skim x
154.000 VN = 338.800 154.000 VN = 338.800
VN
VN
Tng cng
1.179.800 VN
658.800 VN
4. Hiu qu v mt mi trng:
- Do v tr lp t mng spillway xa ni lm vic ca cng nhn nn trong qu
trnh bay hi NH3 khng lm nh hng khi cng nhn lm vic trong nh my.
- Khng s dng acid sulfuric nh ng m skim trnh vic tip xc ho cht c
hi vi cng nhn cng nh lng ho cht d tha trong qu trnh nh ng thi ra nc
thi. Bng chng l h thng mi che khu vc nh ng sau 9 nm hin vn cn c tip
tc s dng.
- Gim ch tiu tng nit v ch tiu NH3 (tnh theo Nit) trong nc thi y l hai
ch tiu thng rt kh x l h thp trong qu trnh hot ng ca h thng x l nc thi.
- Qu trnh nh ng m skim xy ra tt hn khi nh ng m bng ho cht,
lng m cn li trong dung dch serum thi vo h thng x l nc thi rt t, tng hiu
qu hot ng ca h thng x l nc thi.
- Thi gian ng m skim nhanh gim thiu mi hi trong mi trng.

Ni nhn:

TNG GIM C

- Tp on cng nghip cao su Vit Nam.

- Lu : VT, P.KT.

KT\D\Trinh\Nm2011\BCKHAC- Bo co nh ng m skim.doc