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BURNER (B)

Fungsi

Reaksi

: S + O2

SO2

BURNER

1. Menghitung harga k berdasarkan persamaan Arhennius

k

= Ae-E/Rt

MA MB

D2AB(8RT MA x MB )

0,5

Keterangan :
DAB

= Konstanta Gas

Treaksi

= 847,5 K

= Energi aktifasi pada 298 K

= 1,98 Kcal/KmoloK

= -70.960 Kcal/KmoloK
E847,5
E847,5

= E298 +

CpdT

produk 298
reak tan

847 , 5

298

847 , 5

CpdT

= -70.960 Kcal/KmoloK 278.246,6977 Kcal/KmoloK

= -349.206,6977 Kcal/kmol

= Berat Molekul

DO2 = 3,43 Ao
DS

= 3,47 Ao

Do2-s

D2o2-s

= 1,190 x 10-15 cm2 = 1,9 x 10-17 dm2

Mo2

= Berat Molekul O2

= 32

Ms

= Berat Molekul S

= 32

MO2 MS 32 32

0,0625
MO2 xMS
32 x32

= Ae-E/RT

= D2AB 8RT

MA MB

MAxMB

0,5

e E / RT

= 1,19 x 10-19 m2 (8 x 3,14 x 8.314,47 J.K-1kmol-1 x 847,5 K x 0,0625)0,5 x

e(-349.206,6977 kkal/kmol/1,987 kal/mol K x 847,5 K)
= 1,19 x 10-19 m2 x (11.063.025,92 m2/s2)0,5 x e-207,3695
= 0,028 m3/mol.jam
= 28,1870 m3/kmol.jam
2. Menghitung Design Burner
Data :
Konversi

= 96 %

Tekanan

= 1 atm

Qrate

= 1.449,0377 kmol

Reaksi :
S

Stoikiometri :
S

: 1X

O2

: 2,24 - X

N2

: 8,44

SO2

: X

Total : 11,68 - X

1 X
11,68 X

O2

SO2

O2

2,24 X

11,68 X

yb

r

= kCa x Cb
= kya x yb2

dx

dx
1 X 2,24 X

k 2

11,68 X 11,68 X

Q
V
k 2

11,68 X 2 dX
1 X 2,24 X

Misal :
Y

= 1 - X

= 1 - Y

dX

= -dY

Q
k 2

(10,68 Y ) 2 dY
Y 1,24 Y

Q
k 2

(10,68 Y ) 2 dY
Y 1,24 Y

Q
k 2

(10,68 Y ) 2 dY
Y 1,24 Y

m
m2
1
1
Y !,24 Y
Y 1,24 Y

1,24m1 Ym1 Ym2

Y 1,24 Y

1,24m1 Y (m1 m 2 )
Y 1,24 Y

1,25 m1

114,0624

m1

91,985

m1 + m2

21,36

m2

21,36 m1

m2

= -70,625

= k 2

Q
k 2

(10,68 Y ) 2 dY
Y 1,24 Y

=
V

= -

Allowance

= 10 %

Vactual

= 1,1 x

Perbandingan
L/D

= 3/1
D 2

H
4
= D 2
3D
4

= 3D

4 x11,9085

x3

0 , 33