<<

<<
<<
<<
<<
( 6.5) :1-

< <^]<]<<]<^fj}]

< <u^<I<KV^j]
H2015@M@2014I

<<

< C = 1mol / L ]<i< ( H + + NO3 ) <l]<<< V = 100mL <^ru<e<^<< 1

<^<^j]<<^j}]]< OX / Re d j^n]<_<^J (Cu ) ^v]< m = 19, 2 g <^<j<<H
< <V ( NO3 / NO ) (Cu 2+ / Cu )
< <V<e^]<vj<t]<^j]<<]<^]<_<e<IK]
< < 3Cu( aq ) + 2 NO3( aq) + 8H + = 3Cu 2 + + 2 NO( g ) + 4 H 2O( l )
< <Jl^j<]je]<^]<<gu]<Kh
< <Je^]<vj<t]<^j]<i<q<_<K{q
< <J]<^j]<u<K
0
5
< <V p = 10 pa ]<k< 25 C ]]<q<<kq_<erj]<_<^<K2
< << VM = 24L<erj]<<<^]<]<r]<_<e<K]
< < (VNO ) <l]<_<^<ru<e<]<q]<Kh
< <J ( X ) j]<]
< << (VNO ) <l]<_<^<ru<i<]<]<<K3
< <J]<<e
< < t = 20s <v]<<^j<gu]<^j]<<<IK]
< <J t = 30s v]<<s<]<g]<sjj]<IKh
< <J ( X ) <e<v< (t ) <]<^]<^f<_K4
< <V

VNo (L )

0.6
0

t(S)

10

M (Cu ) = 64 g / mol R = 8,31 j 0 K 1MoL1

Cu = 10, 4msm 2 / mol NO 3 = 7,14msm 2 / mol H = 35msm2 / mol

2+

<<
( 6.5) :2-

<<

< C0 = 2,0.102 mol..L1 <e< I 2 (aq) <]<^m<<j<<^<<V0 = 225ml <^ru<<e<<^

< <J m = 0,5 g <^jj< Zn (s ) <]<<<<H<ne^m<]u<q<<<^_<m
< <V<^<j^<^<^je<t<]<<]<e<p^]<^j]<<f]<^]<vj]<
< < Zn(s) + I 2 (aq) = Zn 2+ (aq) + 2I (aq) <
<<^j<j<<l^<<^j]<s< <]<^]<^<<<vj]<e^j
< <V^j]<l^^]<q<<]
< <<

< < t (10 s)

< < (S .m 1 )
< < x(mmol )

< <0

< <1

< <0 < < 0,18

<<

<<

< <2

< <4

< <6

< <8

< <10

< <12

< <14

< <16

< < 0,26 < < 0,38 < < 0,45 < < 0,49 < < 0,50 < < 0,51 < < 0,52 < < 0,52
<<
<<
<<
<<
<<
<<
<<
<<
<<

< <J]<^]<^<<<vj]<]<e^j<<]^<|]<D1
< <Jp^]<^j]<j<q<_<H^j<]je]<^]<<gu]<D2
< <JD A <<gu]E = Ax <_<e<mJ x <j]<e<s< <]<^]<^f<gj]<D]I3
< <J x = f (t ) <v]<]<<m<e^]<]<_<Ih<
Jj<<m< t1 / 2 <^j]<<<<D]I< 4
< <J t 2 = 1000s << t1 = 400s <jv]<<^j<r]<]<<q<Ih<
< <J^j<r]<]<i<^<<I{q
< <<V<
I = 7 , 70 mS .m 2 .mol

Zn 2

= 10 ,56 mS .m 2 .mol

; M(Zn) = 65,4g.mol

-1

<<<<<<<<<<<<

(7) :3-

238
<u< ( 206
U ) <]]<<c<K1
82 pb ) <j]<^]<<c<i<]<^]<^]< (
238

206

X + y + 82 Pb <<V^j]<^]<< ( ) ( ) <^<^e<^jj<l^i<
< < 92U
<<]<_<e<Jgi]< N u (t ) <{e< t v]< N u (0) <{e< t = 0 v]<< (238U ) ]]<<
< <V<]]<_<<<]f]<<j
< <J Y << X <<<^<e^]<^j]<<^<_<IK]
N
< < t = 4t1/ 2 < N = 0 <fj]<]<<<<]<]<_<ofm]<m<^]<^j]<^<gj]<IKh

16

< <J N Pb (t ) = N u (0)(1 e t ) ]<<^e^u< t <v]<<j]<^]<_<<_<e<IK{q

< < 21H + 13 H
ZA X + 01n <^]<gu<^]<t^j<<t^]<h^<<<]<l^]<u]<<<K2
< <J^]<^<^j^e< Z A <]<<sjj]<m<]<t^]<^i<<K]
< <<e]<^<gu]<]<e]<^<<Kh
<
<
J

J]]j]<n]<]]<sjj]<H MeV <{e<]<<u]]<

E(MeV )
2P + 3n
< <]<^j<^]<]<n<]<^]<~]<I3
< <[ E H<< E2 <<H E1 <l^^]<n<]<^<I]
< <J^j]<]<<]<^] MeV <{e<gu]<<Ih
E1
< <<<vj]<^]<H<^e MeV <ue<<gu_<<I{q
E2
< <]]<^]<<^]<<^<m< 13 H ]<< 1 g <
< <J<< 41,85 GJ <i<]<f]<]u]<<^]<
<<
2
3
H
+
H
3
1
1
< < El ( 1 H ) = 8, 57 MeV <H< El ( ZA X ) = 28, 41MeV <V<l^]
E

A
Z

X + 01n

N A = 6, 023 1023 mol <<<H El ( 1 H ) = 2, 23MeV

2

<<<<<<<<<<<<<<<<<<

1MeV = 1, 6 1013 j

<<
<<