Elsevier US

Job Code:CAPA

Chapter:0capaappC

22-12-2006

5:31 p.m.

Page:834

Trimsize:8.5 in11 in

Heat Capacity of Gas

Cp = A + BT + CT 2 + DT 3 + ET 4
No. Formula
Substance
A
1 C2H3C13 1,1,1-Trichloroethane
18.674
2 C2H3C13 1,1,2-Trichloroethane
28.881
15.730
3 C2H4C12 1,1-Dichloroethane
4 C2H4C12 1,2-Dichloroethane
37.275
5 C4H6
1,3-Butadiene
18.835
46.223
6 C4H8O2 1,4-Dioxane
7 C4H10O 1-Butanol (n-Butanol)
8.157
1-Butene
24.915
8 C4H8
9 C10H20
1-Decene
121.553
10 C9H10
1-Nonane (n-Nonane)
29.687
1-Octene
56.266
11 C8H16
12 C3H8O
1-Propanol (n-Propanol)
31.507
13 C2H4O
Acetaldehyde
34.140
34.850
14 C2H4O2 Acetic acid
15 C4H6O3 Acetic anhydride
9.500
16 C3H6O
Acetone
35.918
7.755
17 C3H4O2 Acrylic acid
Ammonia
33.573
18 NH3
19 C6H7N
Aniline
22.062
Benzene
31.368
20 C6H6
14.368
21 C4H8O2 Butyric acid
22 CS2
Carbon disulfide
20.461
23 CO2
Carbon dioxide
27.437
24 CO
Carbon monoxide
29.556
Carbon tetrachloride
19.816
25 CCl4
Chlorine
27.213
26 Cl2
27 CHCl3
Chloroform
22.487
Cyclohexane
13.783
28 C6H12
29 C6H12O Cyclohexanol
17.124
Cyclopropane
21.172
30 C3H6
26.694
31 CH2Cl2 Dichloromethane
35.979
32 C4H10O Diethyl ether
33 C5H10O Diethyl ketone
49.800
Dimethylamine
30.638
34 C2H7N
Ethane
28.146
35 C2H6
Ethanol
27.091
36 C2H6O
69.848
37 C4H8O2 Ethyl acetate
38 C2H5Cl Ethyl chloride
35.946
Ethylbenzene
20.527
39 C8H10
Ethylene
32.083
40 C2H4
41 C2H6O2 Ethylene glycol
48.218
42 C2H4O
Ethylene oxide
30.827
Fluorine
27.408
43 F2
44 C3H8O3 Glycerol
9.656
Hydrogen
25.399
45 H2
46 HCl
Hydrogen chloride
29.244
47 CHN
Hydrogen cyanide
25.766
48 H2O2
Hydrogen peroxide
36.181
i-Butane (iso-Butane)
6.772
49 C4H10
50 CH4
Methane
34.942
Methanol
40.046
51 CH4O

B
3.3443E01
2.4893E01
2.6124E01
1.4362E01
2.0473E01
5.7263E01
4.1032E01
2.0648E01
2.0974E01
6.6821E01
4.0665E01
2.3082E01
4.0020E02
3.7626E02
3.4425E01
9.3896E02
2.9386E01
1.2581E02
5.7313E01
4.7460E01
3.9591E01
1.2299E01
4.2315E02
6.5807E03
3.3311E01
3.0426E02
1.9823E01
2.0742E01
3.3700E01
6.3106E02
8.3984E02
2.8444E01
2.6897E01
1.0737E01
4.3447E02
1.1055E01
8.2338E02
5.2294E02
5.9578E01
1.4831E02
1.9073E01
7.6041E03
1.2928E02
4.2826E01
2.0178E02
1.2615E03
3.7969E02
8.2657E03
3.1447E01
3.9957E02
3.8287E02

C
3.4963E04
1.7639E04
2.1489E04
1.0378E05
6.2485E05
3.8800E04
2.2645E04
5.9828E05
7.8760E04
9.6492E05
1.5805E04
7.8983E05
1.5634E04
2.8311E04
8.6736E05
1.8730E04
2.0878E04
8.8906E05
4.5651E04
3.1137E04
1.8906E04
1.6184E04
1.9555E05
2.0130E05
5.0511E04
3.3353E05
2.1676E04
5.3682E04
2.8176E04
2.9197E04
8.9712E06
1.2673E06
5.0669E05
1.5824E04
1.8946E04
1.0957E04
3.7159E04
2.0321E04
3.0849E04
2.4774E04
6.6117E08
3.2347E04
7.0701E06
2.6797E04
3.8549E05
1.1210E06
1.2416E05
6.6420E05
1.0271E04
1.9184E04
2.4529E04

(Cpjoule/(mol K), TK)

Tmin
D
E
1.8764E07 4.0744E11 100
5.2632E08 3.5668E12 200
9.5761E08 1.8004E11 200
7.8305E08 2.8872E11 200
1.7148E07 6.0858E11 100
1.1392E07 9.0669E12 298
6.0372E08 6.2802E12 200
1.4166E07 4.7053E11 200
8.6982E07 2.6033E10 150
2.0014E07 8.2200E11 200
3.2277E07 1.0600E10 200
6.3696E09 8.6908E13 100
1.6445E07 4.7248E11 100
3.0767E07 9.2646E11 50
7.6769E08 3.6721E11 200
2.1643E07 6.3174E11 100
7.1591E08 9.0960E12 250
7.1783E08 1.8569E11 100
1.8410E07 2.9867E11 200
8.5237E08 5.0524E12 200
7.6462E09 2.0812E11 298
1.0199E07 2.4444E11 100
3.9968E09 2.9872E13 50
1.2227E08 2.2617E12
60
3.4057E07 8.4249E11 100
1.5961E08 2.7021E12 50
1.1636E07 2.4555E11 100
6.3012E07 1.8988E10 100
4.2713E07 1.3215E10 200
3.2708E07 9.9730E11 100
5.0924E08 1.8726E11 100
1.0128E07 3.4529E11 200
1.5227E07 4.9510E11 200
1.9418E07 5.8509E11 200
1.9082E07 5.3349E11 100
1.5046E07 4.6601E11 100
4.1129E07 1.2369E10 200
2.2795E07 6.9123E11 100
3.5621E08 1.2409E11 200
2.3766E07 6.8274E11 60
1.8834E08 1.2555E11 200
3.2747E07 9.7271E11 50
1.6302E08 5.9789E12 100
3.1794E08 2.7745E11 298
3.1880E08 8.7585E12 250
4.9676E09 2.4963E12 50
3.2240E09 2.2610E12 100
6.9944E08 2.0951E11 100
3.6849E08 2.0429E11 200
1.5303E07 3.9321E11 50
2.1679E07 5.9909E11 100

Tmax
1500
1500
1500
1500
1500
1500
2980
1500
1500
1500
1500
2980
1500
1500
1500
1500
1500
1500
1500
1500
1200
1500
5000
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1200
1500
1500
1500
1500
1500
1500
1500

Elsevier US

Job Code:CAPA

Chapter:0capaappC

22-12-2006

Cp = A + BT + CT 2 + DT 3 + ET 4
No. Formula
Substance
A
B
52 CH3Br
Methyl bromide
2.4374E02
29.146
53 C6H12O
Methyl isobutyl ketone
2.404
5.8495E01
54 CH5N
Methylamine
40.039
1.5108E02
m-Xylene
16.725
5.6424E01
55 C8H10
56 C10H8
Naphthalene
67.099
4.3239E02
57 C4H10
n-Butane
20.056
2.8153E01
58 C10H22
n-Decane
31.780
7.4489E01
59 C7H16
n-Heptane
26.984
5.0387E01
60 C6H14
n-Hexane
25.924
4.1927E01
61 C6H5NO2 Nitrobenzene
-16.202
5.6182E01
62 N2
Nitrogen
29.342
3.5395E03
63 C9H20
n-Nonane
29.687
6.6821E01
64 C8H18
n-Octane
29.053
5.8016E01
65 C5H12
n-Pentane
26.671
3.2324E01
66 O2
Oxygen
29.526
8.8999E03
o-Xylene
0.182
5.1344E01
67 C8H10
68 C6H6O
Phenol
4.408
3.6338E01
p-Xylene
17.360
5.6470E01
69 C8H10
Pyridine
23.262
1.1251E01
70 C5H5N
Styrene
71.201
5.4767E02
71 C8H8
72 SO2
Sulfur dioxide
29.637
3.4735E02
73 C7H8
Toluene
24.097
5.2187E01
74 C4H6O2
Vinyl acetate
27.664
2.3366E01
Water
75 H2O
33.933
8.4186E03
Cp heat capacity of ideal gas, joule/(mol K)
A, B, C, D, and E regression coefficients for chemical compound
T temperature, K
Tmin minimum temperature, K
Tmax maximum temperature, K

5:31 p.m.

Trimsize:8.5 in11 in

Page:835

(Cpjoule/(mol K), T K)
Tmin
C
D
E
1.0655E04 1.1324E07 3.3241E11 100
3.7647E04
1.2418E07 1.7051E11 298
2.5012E04 2.3336E07 6.5582E11 100
2.6465E04
1.3381E08 1.5869E11 200
9.1740E04 1.0019E06 3.0896E10 50
1.3143E05 9.4571E08 3.4149E11 200
1.0945E04 2.2668E07 9.3458E11 200
4.4748E05 1.6835E07 6.5183E11 200
1.2491E05 1.55916E07 5.8784E11 200
3.9302E04
1.0043E07 1.2252E12 200
1.0076E05 4.3116E09 2.5935E13 50
9.6492E05 2.0014E07 8.2200E11 200
5.7103E05 1.9548E07 7.6614E11 200
4.2820E05 1.6639E07 5.6036E11 200
3.8083E05 3.2629E08 8.8607E12 50
2.0212E04 2.1615E08 2.3212E11 200
6.0417E05 1.2794E07 5.5287E11 100
2.6293E04
1.1217E08 1.6544E11 200
3.7351E04 4.5402E07 1.4286E10 50
6.4793E04 6.9875E07 2.1232E10 100
9.2903E06 2.9885E08 1.0937E11 100
2.9827E04
6.1220E08 1.2576E12 200
6.2106E05 1.6972E07 5.7917E11 100
2.9906E05 1.7825E08 3.6934E12 100

Tmax
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500
1500

Elsevier US

Job Code:CAPA

Chapter:0capaappC

22-12-2006

5:31 p.m.

Page:836

Trimsize:8.5 in11 in

Heat Capacity of Liquids

No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51

Formula
C2H3Cl3
C2H3Cl3
C2H4Cl2
C2H4Cl2
C4H6
C4H8O2
C4H10O
C4H8
C10H20
C9H20
C8H16
C3H8O
C2H4O
C2H4O2
C4H6O3
C3H6O
C3H4O2
NH3
C6H7N
C6H6
C4H8O2
CS2
CO2
CO
CCl4
Cl2
CHCl3
C6H12
C6H12O
C3H6
CH2Cl2
C4H10O
C5H10O
C2H7N
C2H6
C2H6O
C4H8O2
C2H5Cl
C8H10
C2H4
C2H6O2
C2H4O
F2
C3H8O3
H2
HCl
CHN
H2O2
C4H10
CH4
CH3OH

Cp = A + BT + CT 2 + DT 3
Substance
A
1,1,1-Trichloroethane
11.142
1,1,2-Trichloroethane
34.934
1,1-Dichloroethane
57.325
1,2-Dichloroethane
26.310
1,3-Butadiene
34.680
1,4-Dioxane
20.729
1-Butanol (n-Butanol)
83.877
1-Butene
74.597
1-Decene
137.962
1-Nonane (n-Nonane)
98.040
1-Octene
119.984
1-Propanol (n-Propanol)
88.080
Acetaldehyde
45.056
Acetic acid
18.944
Acetic anhydride
71.831
Acetone
46.878
Acrylic acid
18.242
Ammonia
182.157
Aniline
63.288
Benzene
31.663
Butyric acid
28.210
Carbon disulfide
39.938
Carbon dioxide
338.956
Carbon monoxide
19.312
Carbon tetrachloride
9.671
Chlorine
127.601
Chloroform
28.296
Cyclohexane
44.417
Cyclohexanol
47.321
Cyclopropane
30.543
Dichloromethane
38.941
Diethyl ether
75.939
Diethyl ketone
26.231
Dimethylamine
36.962
Ethane
38.332
Ethanol
59.342
Ethyl acetate
62.832
Ethyl chloride
60.180
Ethylbenzene
102.11
Ethylene
25.597
Ethylene glycol
75.878
Ethylene oxide
35.720
Fluorine
83.829
Glycerol
132.145
Hydrogen
50.607
Hydrogen chloride
73.993
Hydrogen cyanide
123.155
Hydrogen peroxide
15.248
i-Butane (iso-Butane)
71.791
Methane
0.018
Methanol
40.152

B
1.0501E+00
8.5054E01
5.6014E01
7.7555E01
7.3205E01
1.2913E+00
5.6628E01
3.3434E04
1.1934E+00
1.3538E+00
8.3332E01
4.0224E01
4.4853E01
1.0971E+00
8.8879E01
6.2652E01
1.2106E+00
3.3618E+00
9.8960E01
1.3043E+00
1.1040E+00
2.3565E01
5.2796E+00
2.5072E+00
9.3363E01
6.0215E01
6.5897E01
1.6016E+00
1.9131E+00
5.0198E01
4.9008E01
7.7335E01
1.2822E+00
9.5817E01
4.1006E01
3.6358E01
8.4097E01
3.4553E01
5.5959E01
5.7078E01
6.4182E01
4.2908E01
7.8518E01
8.6007E01
6.1136E+00
1.2946E01
1.7769E+00
6.7693E01
4.8472E01
1.1982E+00
3.1046E01

C
3.0826E03
2.3306E03
1.8136E03
2.2271E03
2.8426E03
3.5408E03
1.7208E03
1.3914E03
3.2863E03
3.8058E03
2.5321E03
1.3032E03
1.6607E03
2.8921E03
2.6534E03
2.0761E03
3.1160E03
1.4398E02
2.3583E03
3.6078E03
2.8523E03
7.2098E04
2.3279E02
2.8970E02
2.6768E03
1.5776E03
2.0353E03
4.4676E03
4.8388E03
2.1040E03
1.6224E03
2.7936E03
3.7449E03
3.5846E03
2.3024E03
1.2164E03
2.6998E03
1.2983E03
1.5609E03
3.3620E03
1.6493E03
1.5473E03
5.2305E03
1.9745E03
3.0930E01
7.8980E05
5.8083E03
1.4948E03
2.0519E03
9.8722E03
1.0291E03

D
T min
3.5983E06 244
2.6455E06 238
2.5617E06 177
2.6107E06 238
4.6035E06 165
3.5408E06 286
2.2780E06 185
3.0241E06
89
3.9390E06 208
4.4991E06 221
3.4745E06 172
1.9677E06 148
2.7000E06 151
2.9275E06 291
3.3501E06 201
2.9583E06 179
3.1409E06 241
2.0371E05 195
2.3296E06 268
3.8243E06 280
2.9528E06 269
1.0443E06 163
3.5980E05 218
1.2745E04
69
3.0425E06 251
5.3099E07 172
2.5901E06 211
4.7582E06 281
4.7281E06 298
3.7444E06 147
2.3069E06 179
4.4383E06 158
4.3816E06 235
5.3990E06 182
5.9347E06
91
1.8030E06 160
3.6631E06 191
2.1963E06 138
2.0149E06 179
8.4120E06 105
1.6937E06 261
2.4070E06 162
4.6617E06
53
1.8068E06 292
4.1480E03 14
2.6409E06 165
6.9129E06 261
1.2018E06 273
4.0634E06 115
3.1670E05
92
1.4598E06 176

T max
491
542
471
505
383
528
507
378
555
536
510
483
415
533
512
457
617
385
629
506
565
497
274
120
501
396
483
498
563
358
459
420
505
394
275
465
471
414
555
254
581
422
137
651
32
308
411
694
367
172
461

Cp at 25 C
145.56
151.46
131.00
128.77
122.26
153.23
160.12
130.74
306.05
282.60
235.43
144.32
102.72
128.66
189.75
127.53
123.05
80.16
210.44
137.87
182.09
73.79

130.72
74.23
112.49
162.07
218.25
92.42
101.98
175.81
191.76
147.08

107.40
170.66
106.00
183.60

165.52
89.90

260.94

98.37
73.52
85.55
141.61

79.93

Elsevier US

Job Code:CAPA

Chapter:0capaappC

22-12-2006

Cp = A + BT + CT 2 + DT 3
No. Formula
Substance
A
B
52 CH3Br
Methyl bromide
25.042 4.9312E01
Methyl chloride
11.381 6.2328E01
53 CH3Cl
54 C6H12O
Methyl isobutyl ketone
96.184 8.5227E01
55 CH5N
Methylamine
13.565 9.0836E01
m-Xylene
70.916 8.0450E01
56 C8H10
57 C10H8
Naphthalene
30.842 1.5362E+00
n-Butane
62.873 5.8913E01
58 C4H10
59 C10H22
n-Decane
79.741 1.6926E+00
n-Heptane
101.121 9.7739E01
60 C7H16
61 C6H14
n-Hexane
78.848 8.8729E01
62 C6H5NO2 Nitrobenzene
51.773 9.1277E01
63 N2
Nitrogen
76.452 3.5226E01
64 C9H20
n-Nonane
98.040 1.3538E+00
n-Octane
82.736 1.3043E+00
65 C8H18
66 C5H12
n-Pentane
80.641 6.2195E01
67 O2
Oxygen
46.432 3.9506E01
o-Xylene
56.460 9.4926E01
68 C8H10
69 C6H6O
Phenol
38.622 1.0983E+00
p-Xylene
11.035 1.5158E+00
70 C8H10
71 C5H5N
Pyridine
37.150 6.9497E01
Styrene
66.737 8.4051E01
72 C8H8
73 SO2
Sulfur dioxide
203.445 1.0537E+00
74 C7H8
Toluene
83.703 5.1666E01
75 C4H6O2
Vinyl acetate
63.910 7.0656E01
Water
76 H2O
92.053 3.9953E02
C p heat capacity of liquid, J/(mol K)
A, B, C, and D regression coefficients for chemical compound
T temperature, K
T min minimum temperature, K
T max maximum temperature, K

C
1.7627E03
2.4353E03
2.5379E03
3.4881E03
2.1885E03
3.2492E03
2.3588E03
4.5287E03
3.0712E03
2.9482E03
2.1098E03
2.6690E03
3.8058E03
3.8254E03
2.2682E03
7.0522E03
2.4902E03
2.4897E03
3.9039E03
1.8749E03
2.1615E03
2.6113E03
1.4910E03
2.2832E03
2.1103E04

5:31 p.m.

D
T min
2.5993E06 181
3.8333E06 176
3.3066E06 190
5.2770E06 181
2.5061E06 226
2.6568E06 354
4.2257E06 136
4.9769E06 244
4.1844E06 184
4.1999E06 179
2.0093E06 280
5.0057E05
64
4.4991E06 221
4.6459E06 217
3.7423E06 144
3.9897E05
54
2.6838E06 249
2.2802E06 315
3.9193E06 287
2.1188E06 233
2.3324E06 244
1.0697E06 198
1.9725E06 179
3.1788E06 181
5.3469E07 273

Page:837

T max
420
375
514
3887
555
674
383
557
486
457
647
120
536
512
423
147
567
625
555
558
583
409
533
472
615

C p at 25 C
85.16
82.33
212.42
114.19
182.66

140.84
313.73
230.42
192.63
189.62

282.60
254.71
163.64

189.25

197.75
133.85
187.00
93.06
157.49
155.86
75.55

Trimsize:8.5 in11 in