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Sebanyak 1 gram sampel dilarutkan menjadi 100 mL --> dianalisis kadar Cd dengan AAS

No
1
2
3
4
5
6

Standar Cd 5 ppm (mL)


0
0.8
1.6
2.4
3.2
4

H2O (mL)
10
9.2
8.4
7.6
6.8
6
Jumlah
Rata
Sxx =
Sxy =

[Cd] ppm
0
0.4
0.8
1.2
1.6
2
6
1

Abs
0
0.123
0.218
0.318
0.398
0.504
1.561
0.2601667

2.8 Beta =
0.689 Alfa =

Y = 0,246 X + 0,014

A = 0,246 C + 0,014

Sampel
(gram)
1
1
1
1

Cd 10 ppm
(mL)
2
4
6

Volume
(mL)
100
100
100
100

nalisis kadar Cd dengan AAS


XX
0
0.16
0.64
1.44
2.56
4
8.8

XY
0
0.0492
0.1744
0.3816
0.6368
1.008
2.25

0.24607143
0.01409524

(Abs - Y^)
0.014
0.0386
0.0352
0.0368
0.0184
0.026

(Abs - Y^)2
0.000196
0.00148996
0.00123904
0.00135424
0.00033856
0.000676
0.0052938

sd =
Y = 0,246 X + 0,014

0.032538592

LoD =
LoQ =

0.396812103
1.322707011

Abs

[Terukur] mg/L

[Terukur] mg/100 mL

[Teoritis] mg/100 mL

0.234
0.273
0.325
0.373

0.894308943
1.052845528
1.264227642
1.459349593

0.089430894
0.105284553
0.126422764
0.145934959

0.109430894
0.129430894
0.149430894

[Cd] =

0.0920 mg/1 gram sampel


92.024 ppm (mg/kg)

ppm
ppm
Recovery (%)
96.21
97.68
97.66
97.18

Rumus
=

t tabel pada df = (N-1)

1
2
3
4
5

Sampel CRM 1
gram 100 mL
Pengukuran 1
Pengukuran 2
Pengukuran 2
Pengukuran 4
Pengukuran 5

A = 0,246 C + 0,014

Abs

[Cd] ppm (mg/L)

0.234
0.238
0.229
0.232
0.23

0.894308943
0.910569106
0.87398374
0.886178862
0.87804878

[Cd] mg/100 mL
0.089430894
0.091056911
0.087398374
0.088617886
0.087804878
Jumlah
Rata-Rata

[Cd] ppm (mg/kg)


89.43089431
91.05691057
87.39837398
88.61788618
87.80487805
444.3089431
88.86178862

sd =

x-x^

(x-x^)2

0.569106
2.195122
-1.46341
-0.2439
-1.05691

0.32388
4.81856
2.14158
0.05949
1.11706
8.46057

1.454353156

akar N =

2.236067977

t hitung =

-1.75

t tabel =

2.78
95%

Karena t hitung < t tabel maka kedua data tidak berbeda secara signifikans

Rumus

t tabel pada df = (N1 + N2 -2)

Jml
Rata

Metode Baku
87
92
91
88
358
89.5

-2.5
2.5
1.5
-1.5

Sd =
Metode 2
90
87
89
92

6.25
6.25
2.25
2.25
17
2.3805

1
-2
0
3

1
4
0
9

87

-2
445
89 sd =

4
18
2.1213

Sp2 =

Sxx =

1.5

thit = 0.333333
t tabel

2.36

[Cd] ppm (mg/L)

Abs

0.4

0.12

0.8

0.22

1.2

0.35

1.6

0.41

0.504

Sampel
(gram)

Cd 10 ppm (mL)

Volume (mL)

Abs

100

0.234

100

0.273

100

0.325

100

0.373

10.1
10
9.9
0.1

ppm (mg/L)
0.867541766
1.022673031
1.229514718
1.420445505

2.1
2
1.9
0.1

RSd =

A = 0,2514 C + 0,0159

Terukur
mg/100 mL
mg/kg
atau mg/1 g
atau ppm
0.086754177 86.75418
0.102267303 102.2673
0.122951472 122.9515
0.142044551 142.0446

Teoritisnya

0.106754177 95.8
0.126754177
97
0.146754177 96.79
96.53