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  • Aromatic Chemistry Reactions Map

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    ElectrodeIrresistible
    18 tayangan1 halaman
    1) The document maps out aromatic reactions starting from benzene and shows how benzene can be reacted to form various substituted benzenes and aromatic compounds through substitution, oxidation, reduction, hydrolysis, acylation, and other reactions. 2) Key reactions shown include bromination and nitration of benzene, hydrolysis of bromobenzene to form phenol, oxidation of phenol to form benzoic acid, and reduction of benzonitrile to form phenylamine. 3) The map provides examples of substitution reactions to form chlorobenzene, fluorobenzene, iodobenzene, nitrobenzene, and other substituted benzenes, as well as coupling reactions to

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    organic chemistry interconversion helper

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    1) The document maps out aromatic reactions starting from benzene and shows how benzene can be reacted to form various substituted benzenes and aromatic compounds through substitution, oxidation, reduction, hydrolysis, acylation, and other reactions. 2) Key reactions shown include bromination and nitration of benzene, hydrolysis of bromobenzene to form phenol, oxidation of phenol to form benzoic acid, and reduction of benzonitrile to form phenylamine. 3) The map provides examples of substitution reactions to form chlorobenzene, fluorobenzene, iodobenzene, nitrobenzene, and other substituted benzenes, as well as coupling reactions to

    Hak Cipta:

    © All Rights Reserved
    Unduh sebagai PDF, TXT atau baca online dari Scribd
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    18 tayangan1 halaman

    Aromatic Chemistry Reactions Map

    Diunggah oleh

    ElectrodeIrresistible
    1) The document maps out aromatic reactions starting from benzene and shows how benzene can be reacted to form various substituted benzenes and aromatic compounds through substitution, oxidation, reduction, hydrolysis, acylation, and other reactions. 2) Key reactions shown include bromination and nitration of benzene, hydrolysis of bromobenzene to form phenol, oxidation of phenol to form benzoic acid, and reduction of benzonitrile to form phenylamine. 3) The map provides examples of substitution reactions to form chlorobenzene, fluorobenzene, iodobenzene, nitrobenzene, and other substituted benzenes, as well as coupling reactions to

    Hak Cipta:

    © All Rights Reserved
    Unduh sebagai PDF, TXT atau baca online dari Scribd
    Tandai sebagai konten tidak pantas
    dari 1

    A R O M AT I C R E AC T I O N S M A P

    BENZENE

    KI (aq), room temp.


    Br

    Br2 & FeBr3 cat., room temperature

    BROMOBENZENE
    HBF4 - filter off solid, dry & heat

    N
    N+

    HBr, CuBr cat., room temperature


    OH

    Powdered Zn, heat

    BENZENEDIAZONIUM

    H2O, 160C

    PHENOL

    HCl, CuCl cat., room temp.

    Cl

    NaOH with Cu salt cat., 200 atm & 350C, then HCl

    CHLOROBENZENE

    HNO3, H2SO 4 cat., 55C

    REACTIONS KEY
    SUBSTITUTION

    NO2

    NITROBENZENE
    HCl, reflux, Sn; NaOH

    OXIDATION
    REDUCTION
    HYDROLYSIS

    KMnO4, H2SO4, heat

    ALKYLBENZENE

    BENZONITRILE

    BENZOYL CHLORIDE

    COR

    SOCl2, heat

    PHENYLKETONE

    H 2O

    CHO

    COOH

    BENZOIC ACID

    Air

    NH2

    PHENYLAMINE

    CO, HCl & AlCl3 cat, CuCl


    RCOCl, AlCl3 cat., reflux 60C
    Diazotisation: NaNO2 (aq), dilute HCl, temp. 0-5C

    2014 COMPOUND INTEREST - WWW.COMPOUNDCHEM.COM

    CN

    COCl

    ACYLATION
    OTHER

    CuCN, polar solvent, reflux (also for Ar-Br)

    0.1M H2SO 4, H2O


    KNH2, NH3, -33C; then dilute acid

    Na & RI, dry ether

    Cl2 & AlCl3 cat., room temperature

    Chloroalkane, AlCl3 cat., room temperature

    Cold H3PO2 (aq)

    C6H5R, NaOH, <10C

    AZOBENZENE

    Coupling reaction

    FLUOROBENZENE

    IODOBENZENE

    KCN & copper powder

    H2SO 4 cat., H2O, heat

    H2SO 4, heat under reflux

    PHENYLSULFONIC ACID

    I2 & conc. HNO3, reflux

    BENZALDEHYDE

    SnCl2 (ether), HCl, 20C, then boil with H2O

    SO3H

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