PCM

MODULE - 3 - CHEMISTRY

b) Absolute value of internal energy cannot be

MULTIPLE ANSWER CORRECT

determined
c) Absolute value of entropy can be determined

1.

Which one is correct for a cyclic process as

d) Internal energy, energy, enthalpy, and

shown in the figure ?

entropy are intensive properties

5.

Which of the following arrangement will

produce oxygen at anode during electrolysis ?
a) Dilute H2SO4 solution with Cu electrodes
b) Dilute H2SO4 solution with inert electrodes
c) Fused NaOH with inert electrodes
d) Dilute NaCl solution with inert electrodes

6.

2.

a) dU = 0

b) q = w

c) w = 314 kJ

d) w = 31.4 J

Choose te correct Nernst equation for the

following cell :
a) Ecell = E

o
cell

0.0591

log
2

2+
Zn
Pb2+

b) Ecell = E

o
cell

0.0591

log
2

Pb 2+
Zn2+

The poissons ratio for O2 is 1.4. Which of the

following are correct for O2 ?
a) CVM = 5 cal
c) CP =

3.

RJ
J 1

b) CV = 0.156 cal
d) CV =

R
J 1

c) Ecell = E ocell +

Pb 2+
0.0591
log
2
2
Zn2+

d) Ecell = E ocell +

0.0591
log
2

Which is an irreversible process ?

a) Mixing of two gases by diffusion
b) Evaporation of water at 373 K and 1 atm
pressure

Pb2+
Zn2+

c) Dissolution of NaCl in water

7.

d) All of the above

4.

Which of the following statement are correct ?

a) Absolute value of enthalpy cannot be
determined

Select the correct relations :

wE
a) 'S = T u nF
w P
wE
wG 'H
b) nF =
=
w
T
T

P
wE
c) 'S =
u nF
w T P

Space for Rough Work

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