COLLIGATIVE PROPERTIES OF
SOLUTION
SIFAT SIFAT KOLIGATIF
LARUTAN
Molality / Kemolalan ( m )
3
4
5
Molarity ( Kemolaran = M )
1.
Molality / Kemolalan ( m )
Dirumuskan :
m=n/p
Keterangan :
m = molality ( molal )
n = moles of solute (mol zat terlarut)
p = mass of solvent (massa pelarut) = kg
Atau
m = g . 1000
Mr . p
Keterangan :
g = mass of solute (massa zat terlarut = gram)
p = mass of solvent (= gram)
Mr = molecular mass of solute ( massa
molekul relative zat terlarut )
Menyatakan perbandingan
mol zat terlarut atau pelarut
terhadap jumlah mol larutan.
Dirumuskan :
Xp =
np
(np + nt)
Xt =
nt
(nt + np)
Keterangan :
Xp = Fraksi mol pelarut
Xt = Fraksi mol zat
terlarut
np = mol pelarut
nt = mol zat terlarut
Dan :
np = p/Mr pelarut
nt = g/Mr zat terlarut
Serta :
Xt + X p = 1
Keterangan :
g = mass of solute (massa zat terlarut = gram)
p = mass of solvent (massa pelarut = gram)
3. Molarity (Kemolaran = M )
Dirumuskan :
M=n/V
M = g . 1000
Mr . V
Keterangan :
M = Molarity ( Kemolaran )
V = Volume larutan ( Lt)
V = Volume larutan ( ml )
Dirumuskan :
% massa =
g
x 100 %
(g+p)
Keterangan :
g = massa zat terlarut ( gram )
p = massa pelarut ( gram )
g + p = massa larutan ( gram )
6. Pengenceran larutan.
V1.M1 = V2.M2
1.
m = g . 1000
Mr . p
m = 10 . 1000
60 . 100
m = 1,67 molal
2.
Jawab :
24% artinya ; g = 24 gram dan p = 76 gram
Mr CH3COOH = 60
m = 24 . 1000
60 . 76
m = 5,26 molal
3.
Jawab :
1 molal artinya ;
% massa =
180
x 100%
(180 + 1000)
= 15,254 %
4.
Xt =
nt
(nt + np)
Xt =
12/60
Xt= 0, 0385
(12/60 + 90/18)