Narayana Sri Chaitanya IIT Academy

12-07-14_Jr. IPLCO(JEE-Main 2011)_WTM-10

Narayana Sri Chaitanya IIT Academy

Sri Sarvani Educational Society

COMMON CENTRAL OFFICE_MADHAPUR_HYD

Jr.IPLCO
Time: 3 hrs

Date: 12-07-14
Max. Marks: 360

JEE-MAIN
2011 Model

KEY & SOLUTIONS

MATHS:
1
7
13
19
25

2
2
4
2
4

2
8
14
20
26

2
4
2
1
3

3
9
15
21
27

2
2
2
2
4

4
10
16
22
28

2
3
2
4
3

5
11
17
23
29

2
2
2
2
2

6
12
18
24
30

3
3
2
3
2

32
38
44
50
56

3
2
4
2
4

33
39
45
51
57

4
4
4
2
4

34
40
46
52
58

1
4
3
3
2

35
41
47
53
59

1
4
2
4
4

36
42
48
54
60

1
2
1
1
2

62
68
74
80
86

2
3
3
3
1

63
69
75
81
87

2
2
2
4
1

64
70
76
82
88

3
3
4
1
1

65
71
77
83
89

1
3
2
4
1

66
72
78
84
90

1
2
1
2
2

PHYSICS:
31
37
43
49
55

2
2
4
3
4

CHEMISTRY:
61
67
73
79
85

2
3
4
2
1

Sec : JR.IPLCO_SOLUTIONS

Page 1

Narayana Sri Chaitanya IIT Academy

12-07-14_Jr. IPLCO(JEE-Main 2011)_WTM-10

MATHEMATICS
01.
02. Q divides P T in ratio 1:3

3a b 3 x y
,

A
4

R is mid point of PT

a b x y
,

2
2

03. Ortho centre (0,0)

Circumcentre =

a a
,
2 2

Centroid =

a a
,
3 3

a
a
,

2 2 2 2

Incentre =
04. Perimeter of PQRS = 12
PQ = 3 area of the square = 9

PQT 12, 2S 12
Perimeter

PQ 3, PT QT

9
2

Sec : JR.IPLCO_SOLUTIONS

Page 2

Narayana Sri Chaitanya IIT Academy

PQT

12-07-14_Jr. IPLCO(JEE-Main 2011)_WTM-10

9
2

Area of the
05. using section formula
06. h = 1

AP 2 BP 2 AB 2
07. If E,F are mid points of AB and AC then BC = 2EF
08. Slopes are equal
09. Conceptual
10. Conceptual
11. Eliminating M

x y
a b
1 1 bx ay xy
p q
x y
12.

13. Circumcentre (0,0) centroid

3 5cos 5sin 4 5sin cos

,

3
3

14.

P ,0 Q 0,
15. Let

x2 y2 x 0
Equation of the circle passing through O,P,R is

x2 y 2
x

x2 y 2
III
y
ly

Sec : JR.IPLCO_SOLUTIONS

Page 3

find orthocenter

Narayana Sri Chaitanya IIT Academy

12-07-14_Jr. IPLCO(JEE-Main 2011)_WTM-10

a
A P,0 B 0, q
16.

use

17. PA = PB

18. Conceptual
19. Conceptual

C ,
20. Let

6 6
,

3
3

x, y

, 3x 6,3 y 6 sub
9x 7 y 4 0
In
21. Conceptual
22. Conceptual
23. Conceptual
24. Conceptual
25. Conceptual
26. Conceptual
27.

Conceptual

x x h, y y k
28.

f1 , f 2 and f 3
29. Under the transformations
Sec : JR.IPLCO_SOLUTIONS

Page 4

Narayana Sri Chaitanya IIT Academy

12-07-14_Jr. IPLCO(JEE-Main 2011)_WTM-10

A 0,0 0,0 0,0 A1 0,0

B 2,0 0, 2 6, 2 B1 2, 4
C 2, 2 2, 2 8, 2 C1 3,5
D 0, 2 2,0 2,0 D1 1,1

A1B1 || D1C1 || B1C1 and A1C1

Clearly

B1D1
is not perpendicular to

parallelogram
30. Conceptual

31.

u sin
R

Or

R
2u cos

d
3
2

S
4
5
d
3
45Pm
V

32.

oo

d 3 2m

Sec : JR.IPLCO_SOLUTIONS

Page 5

A1 B1C1 D1
. Therefore

is

Narayana Sri Chaitanya IIT Academy

Let velocity of spot at

12-07-14_Jr. IPLCO(JEE-Main 2011)_WTM-10

450

in V, then

component velocity perpendicular to line joining

length of the joining

V
d

V
0.1 2
3 3

V 0.3 2 2
V 0.6m / s

2h

2 2
10
v2 B
6.4s; v
15.63 m / s; a
0.45m / s 2
9.8
t
R

33.

V 2 400 2 2
Rc

a
10

34.

gcos45o20m
/s20

20

Rc 80 2m

Sec : JR.IPLCO_SOLUTIONS

Page 6

Narayana Sri Chaitanya IIT Academy

12-07-14_Jr. IPLCO(JEE-Main 2011)_WTM-10

V2
speed
Rc

a comp.of accelration perpendicular to velocity

2

r r
V ,U velocity / v, u speed
Note:

r
r r uu
r
r r
V U at
but V U a t is wrong
v u at t
35. The speed of the block is

2 25cm
0.785 m / s
2.0

The acceleration of the block is

v 2 0.785 m / s
a

2.5 m / s 2
r
0.25
2

Towards the center. The only force in this direction is the normal constant force due to the
slide walls. Thus from Newtons second law, this force is

ma 0.100 kg 2.5 m / s 2 0.25 N

36. conceptual

37.

38.

0
rw2 r

r 2t 2 t

39. Just if starts slipping net reaction by disc on com

Sec : JR.IPLCO_SOLUTIONS

Page 7

Narayana Sri Chaitanya IIT Academy

12-07-14_Jr. IPLCO(JEE-Main 2011)_WTM-10

N 2 f 2 N 1 M 32

40 103 10 1

Fty road

mg

9
0.5
16

mv 2

40.

T cos30o mg
41.

T sin 30o m R R sin 30o w2

2g
2g
3
w

2
3Rw
3 3R

N
42.

1/2

1 1
1

8 3000 16 600
2 60 2
2

200+80 =280

uu
r ur
r
v f vi
a ave
0
T
43.
44. conceptual
45. conceptual
46. conceptual
47. conceptual

48.

dv
v2

dt
R

Sec : JR.IPLCO_SOLUTIONS

Page 8

Narayana Sri Chaitanya IIT Academy

12-07-14_Jr. IPLCO(JEE-Main 2011)_WTM-10

dv V 2

ds R

dv ds

V
R

ln V / Vo

S
R

V Vo e S / R

49. If

is angle between velocity vector and position vector at the required instant, then

2H
1
tan a =
=
=1
R
2cos q
3 2
( 20) 2

u 2 sin 2 q
=15
H=
=
2g
2 10
2

u cos 60sin 45
u
20 1
w=
=
= =
H
4 H 30 3
sin 45
50. Ang.velo about 0=08 rad/s

acc 0.5 0.8

0.32m / s 2

0.5 0.8
Speed =
=0.4 m/s
Sec : JR.IPLCO_SOLUTIONS

Page 9

Narayana Sri Chaitanya IIT Academy

51.

12-07-14_Jr. IPLCO(JEE-Main 2011)_WTM-10

k as 2
1 2
mv as 2 V
2

2a
2as
v
m
m

af

ac

anet

2a
S
m

2as 2
mR

2as
s 2

1 2
m
R

Fnet

1/2

s 2
2as 1 2
R

1/2

mv 2
2
mat mg
r

f
52.

53. conceptual
54. conceptual
55. conceptual

T cosq =mg
56.

T sin q =ml sin qw2

Rd rw2 2T sm
57.

Sec : JR.IPLCO_SOLUTIONS

Page 10

Narayana Sri Chaitanya IIT Academy

R 2 w2
T=

12-07-14_Jr. IPLCO(JEE-Main 2011)_WTM-10

2
2
2
0.25 10
2 0.25

58. Velocity of constant point on rod CD and ring should have same component of

velocity along normal to rod CD.

59.

Rw
wmax = , wmin =0
4R

60. The rate of change of a rotating vector is

times the vector

10 0.99 10
5.823
17

61. molarity of ammonia =

[OH ] K bC 5.823 2 105

[OH ] 0.01079

[H ]

KW
1014

9.268 10 13

[OH ] 0.01079

62.

2 KCN AgNO3 [ Ag (CN ) 2 ] NO3 2 K

Initial conc. 0.1

0.03

Final conc. 0.1-0.06

0.03

0.03

= 0.04

[ Ag (CN )2
Ag 2CN

Initial conc.

0.03

At equilibrium 0.03 a
Sec : JR.IPLCO_SOLUTIONS

0
a

0.09
0.04 + a
Page 11

0
0.03

Narayana Sri Chaitanya IIT Academy

12-07-14_Jr. IPLCO(JEE-Main 2011)_WTM-10

KC

[ Ag ][CN ]2
4 1019

[ Ag (CN ) 2 ]

4 10

19

a (0.04)2

0.03

a is negligible when compared to 0.03

a 7.5 1018 M

63.

pH and pOH of pure water decreases with increase the temperature.

4 log10 5 log

64.

salt

HINT:

6 log10 5 log

salt 0.05

0.5

salt

salt 5

0.5

Now two buffers mixed in equal proportion.

0.05 V 5.0 V / 2V
New conc. of NaH in mixed buffer

New conc. of HA in mix buffer

log10 5 log
pH =

5.05
5.70
2 0.5

H In

KIn
HIn

HIn
In H

65.

red

blue

HINT:

0.5 V 0.5V
0.5
2V

9 10 5 H

Change in

105

H 8 105

Sec : JR.IPLCO_SOLUTIONS

3 105 H

3 105 H

Page 12

0.25 / 0.75
0.75 / 0.25

5.05
M
2

Narayana Sri Chaitanya IIT Academy

12-07-14_Jr. IPLCO(JEE-Main 2011)_WTM-10

66. Conceptual
67. conceptual

68.

69.

70.

HINT:

CONCEPTUAL

Sec : JR.IPLCO_SOLUTIONS

Page 13

Narayana Sri Chaitanya IIT Academy

71.

12-07-14_Jr. IPLCO(JEE-Main 2011)_WTM-10

HINT:

Greater the value of dissociation constant Ka, more is the acidic strength.

72.

HINT:

percentage of hyoholysis = 0.0001 x 100 = 0.01

73.

HINT:

= 4.74 + log 4
= 4.74 + 0.6
= 5.34
pH of buffer solution remains same after dilution.

74.

HINT:
= 7.01

75.

HINT: Buffer solution containing

and

76. HINT :Phenolphthalein is an acid-base indicator and KMnO4(vs) oxalic acid is a redox
reaction and KMnO4 is a self indicator

CaCl2 0.2 M Cl
77.

HINT: 0.01M

Sec : JR.IPLCO_SOLUTIONS

Page 14

Narayana Sri Chaitanya IIT Academy

12-07-14_Jr. IPLCO(JEE-Main 2011)_WTM-10

NaCl 0.01M Cl
0.01 M

AgNO3 0.05M Ag
0.05 M

Ag

Ksp const
Cl

S1 Ksp

S2 Ksp / 0.02 50 Ksp

S3 Ksp / 0.01 100 Ksp

S4 Ksp / 0.05 20 Ksp

78.

CONCEPTUAL
Ksp Zn

79.

HINT:

1021
S 2
1019
0.01

H S 2
Ka1.Ka2
H 2S

1020 H
80.
81.
82.
83.

H
0.1
10 19 / 0.1

pH 1

CONCEPTUAL
CONCEPTUAL
CONCEPTUAL

HINT: At equivalent point

M aVa M bVb
2
2
Va 2.5
15
5

Sec : JR.IPLCO_SOLUTIONS

Page 15

Narayana Sri Chaitanya IIT Academy

12-07-14_Jr. IPLCO(JEE-Main 2011)_WTM-10

Va 7.5

salt

84.

1
0.1M C
10

HCOOH 0.2M . ....1

HINT:

HCOONA HCOO Na
1
0
0
1 0.75
0.75
0.75

PH pK a log

A
HCOOH

pH pK a log

0.75
0.25

85.

CONCEPTUAL

86.

CONCEPTUAL

NO2 H 2O

87.

C 1 n

HNO2 OH
Ch

HINT:

Kh

Ch

OH Ch

Kw
2.36 10 5
Kpc

OH 0.04 2.36 10 5

PH 8
K sp
88.

HINT: When I.P. >

89.

conceptual

90. HINT:

precipitation takes place

is not dependent on concentration in this case

Sec : JR.IPLCO_SOLUTIONS

Page 16

Narayana Sri Chaitanya IIT Academy

Sec : JR.IPLCO_SOLUTIONS

12-07-14_Jr. IPLCO(JEE-Main 2011)_WTM-10

Page 17