Penimbangan 1,7677gram
Larutan
Standar10 g Zr/L
Larutan Standar 2,
4, 6, 8, 10 g Zr/L
Penambahan 30 mL ABM
Penambahan 2 tetes indikator PP
Larutan dengan
spesies anion
[Zr(SO4)3]2-
Pengenceran
menjadi 10 mL
Pemipetan 5 mL
Larutan umpan
[Zr(SO4)3]2Pengaliran ke dalam kolom pemisahan
Larutan eluen
H2SO4 1,2,3,4 M
Pemutaran alat CAC dengan variasi
kecepatan 40, 75, 100 rpm
Pencacahan sampel
selama 300 s
Perbandingan Zr/Compton
sampel
Perbandingan Zr/Compton
larutan standar
Pembuatan persamaan
regresi linier
LAMPIRAN 2
Pembuatan Larutan Standar Zirkonium Oksiklorid
a. Pembuatan Larutan Standar Zirkonium Oksiklorid
Berat ZrOCl2.8H2O yang ditimbang untuk membuat larutan standar
Zirkonium Oksiklorid dengan konsentrasi 10 g Zr/L dalam 50 mL
No
1
10
10
LAMPIRAN 3
Data Standardisasi Eluen H2SO4
a.
= 18,1974M
= 18,2M
No
55
110
165
220
b.
No
Volume (ml)
Konsentrasi (M)
H2SO4
NaOH 1N
H2SO4
1,940
0,970
1,910
0,955
4,748
2,374
4,032
2,016
6,600
3,300
4,310
2,155
7,658
3,829
7,274
3,637
Rata-rata H2SO4
0,9625
2,195
2,7275
3,733
N H2SO4 = 1,940N
N H2SO4 0,970M
LAMPIRAN 4
Pembuatan Larutan Umpan
a.
Pembuatan
Larutan
Induk
Zirkonium Sulfat
Berat zirkonium sulfat yang ditimbang untuk membuat umpan Zirkonium
Sulfat dengan konsentrasi 100 g Zr/L adalah
Berat [Zr(SO4)2].H2O
b.
= 0,05843X + 0,00421
No
0,1
88,5
51,579
1846,05
41,72
0,2
10
88,5
50,930
1878,50
42,45
Keterangan :
W = Jumlah Zr yang terikat oleh resin (mg/g)
C1 = Konsenttrasi Zr awal (g/L)
C2 = Konsentrasi Zr akhir (g/L)
= 1846,05 mg/g
= 1878,5 mg/g
Efektivitas
resin
untuk
menjerap
= 41,72%
= 42,45%
Zr
dapat
ditentukan
dengan
LAMPIRAN 6
Penentuan Kadar Zr dalam Sampel Hasil Proses Adsorpsi
Data analisis penentuan kadar Zr dalam sampel hasil proses adsorpsi
dengan variasi konsentrasi H2SO4 dapat dilihat dari Tabel 14 di bawah ini:
Tabel 14. Data cacah sampel hasil adsorpsi menggunakan CAC
dengan XRF pada kecepatan putar 75 rpm
Area
Area
Kadar
No
Konsentrasi
Kode
Area Zr
Compton Zr/Compton Zr (g/L)
Fraksi
H2SO4
Sampel
1
1M
A1
2499
48176
0.0519
0.8157
2
1M
A2
2746
50919
0.0539
1.1327
1M
A3
2871
48800
0.0588
0.992
1M
A4
2723
32350
0.0842
1.1378
1M
A5
2036
23830
0.0854
0.4609
1M
A6
1600
26215
0.0610
0.7124
1M
A7
1548
25918
0.0597
0.9501
1M
A8
1178
25721
0.0458
0.9725
1M
A9
796
25563
0.0311
1.3902
10
1M
A10
1801
25476
0.0707
1.3685
11
1M
A11
1639
26363
0.0622
0.9348
12
1M
A12
1690
24008
0.0704
0.8509
2M
B1
4873
24463
0.1992
3.3371
2M
B2
4482
24152
0.1856
1.9541
2M
B3
5121
24181
0.2118
3.3752
2M
B4
3650
18699
0.1952
2.0903
2M
B5
4259
21472
0.1984
2.982
2M
B6
4096
21563
0.1900
3.2042
2M
B7
3626
19345
0.1874
3.1359
2M
B8
4459
23293
0.1914
3.1789
2M
B9
4425
24797
0.1784
3.3226
10
2M
B10
4659
36875
0.1263
3.2687
11
2M
B11
4480
22242
0.2014
3.5524
12
2M
B12
4290
36237
0.1184
3.104
3M
C1
9582
25670
0.3733
6.3164
3M
C2
9180
27077
0.3390
6.5313
3M
C3
9341
26558
0.3517
6.3629
3M
C4
9559
26430
0.3617
6.2257
3M
C5
9147
37667
0.2428
6.327
3M
C6
9204
25772
0.3571
6.1355
3M
C7
9313
37799
0.2464
4.1447
3M
C8
9240
25475
0.3627
6.0401
3M
C9
9380
25087
0.3739
4.084
10
3M
C10
9336
25371
0.3680
6.1178
11
3M
C11
9627
25604
0.3760
5.9475
12
3M
C12
9818
25446
0.3858
5.7303
4M
D1
5116
25767
0.1985
3.326
4M
D2
4889
26585
0.1839
3.4317
4M
D3
4817
25823
0.1865
3.3828
4M
D4
5350
38938
0.1374
3.5258
4M
D5
5416
26539
0.2041
3.4816
4M
D6
5113
26530
0.1927
3.3698
4M
D7
5282
25655
0.2059
3.4516
4M
D8
5386
26782
0.2011
3.2263
4M
D9
5458
26286
0.2076
3.4206
10
4M
D10
5507
26196
0.2102
2.2794
11
4M
D11
5260
26057
0.2019
3.1205
12
4M
D12
5510
26914
0.2047
3.0753
Kecepatn
Putar
40 rpm
Kode
Sampel
A1
Luas
Area Zr
1851
Luas Area
Compton
29703
Luas Area
Zr/Compton
0.0623
Kadar Zr
(g/L)
0.9945
40 rpm
A2
2367
30980
0.0764
1.2356
40 rpm
A3
1743
24723
0.0705
1.1345
40 rpm
A4
1931
26313
0.0734
1.1839
40 rpm
A5
1913
25736
0.0743
1.2001
40 rpm
A6
1936
25921
0.0747
1.2062
40 rpm
A7
2096
26089
0.0803
1.3029
40 rpm
A8
1774
25915
0.0685
1.0995
40 rpm
A9
2746
33043
0.0831
1.3502
10
40 rpm
A10
2068
26539
0.0779
1.2616
11
40 rpm
A11
2151
28580
0.0753
1.2160
12
40 rpm
A12
2060
25585
0.0805
1.3059
75 rpm
A1
2499
48176
0.0519
0.8157
75 rpm
A2
2746
50919
0.0539
1.1327
75 rpm
A3
2871
48800
0.0588
0.992
75 rpm
A4
2723
32350
0.0842
1.1378
75 rpm
A5
2036
23830
0.0854
0.4609
75 rpm
A6
1600
26215
0.0610
0.7124
75 rpm
A7
1548
25918
0.0597
0.9501
75 rpm
A8
1178
25721
0.0458
0.9725
75 rpm
A9
796
25563
0.0311
1.3902
10
75 rpm
A10
1801
25476
0.0707
1.3685
11
75 rpm
A11
1639
26363
0.0622
0.9348
12
75 rpm
A12
1690
24008
0.0704
0.8509
100 rpm
A1
1008
45217
0.0223
0.3095
100 rpm
A2
1049
45997
0.0228
0.3183
100 rpm
A3
639
46812
0.0137
0.1616
100 rpm
A4
747
45299
0.0165
0.2102
100 rpm
A5
780
46496
0.0168
0.2151
100 rpm
A6
1434
46791
0.0306
0.4525
100 rpm
A7
981
46175
0.0212
0.2915
100 rpm
A8
1734
46335
0.0374
0.5684
100 rpm
A9
1262
48786
0.0259
0.3707
10
100 rpm
A10
1270
47232
0.0269
0.3881
11
100 rpm
A11
975
48131
0.0203
0.2746
12
100 rpm
A12
1373
49189
0.0279
0.4057
LAMPIRAN 7
X-RAY CRITICAL ABSORPTION AND EMISSON ENERGIES CHART
Besarnya energi yang digunakan untuk menentukan kadar Zr dengan XRF
dapat dilihat pada Tabel 16 di bawah ini:
Tabel 16. Data X-Ray Critical Absorption And Emisson Energies Chart
Nama
Hydrogen
Helium
Lithium
Berylium
Boron
Carbon
Nitrogen
Oxygen
Fluorin
Neon
Sodium
Magnesium
Aluminium
Silicon
Phosphorus
Sulphur
Chlorine
Argon
Simbol
H
He
Li
Be
B
C
N
O
F
Ne
Na
Mg
Al
Si
P
S
Cl
Ar
K1
K2
K1
0,
0,
0,
0,
0,
0,
0,
0,
1,
1,
1,487
1,740
2,015
2,308
2,622
2,957
052
110
185
282
392
523
677
851
041
254
1,486
1,739
2,014
2,306
2,621
2,955
1,067
1,297
1,553
1,832
2,136
2,464
2,815
3,192
L
K2
-
L1
-
L
L2
-
L1
-
L2
-
Potassium
Calcium
Scandium
Titanium
Vanadium
Chromium
Manganese
Iron
Cobalt
Nickel
Copper
Zinc
Galium
Germanium
Arsenic
Selenium
Bromine
Krypton
Rubidium
Strontium
Yttrium
Zirconium
Niobium
Molybdenum
Technetium
Ruthenium
Rhodium
Polladium
Silver
Cadmium
Indium
Tin
Antimony
Tellurium
Iodine
Xenon
Cesium
Barium
Lanthanum
Cerium
Praseodymium
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Kr
Rb
Sr
Y
Zr
Nb
Mo
Tc
Ru
Ro
Pd
Ag
Cd
In
Sn
Sb
Te
I
Xe
Cs
Ba
La
Ce
Pr
3,313
3,691
4,090
4,510
4,952
5,414
5,898
6,403
6,390
7,477
8,047
8,638
9,251
9,885
10,543
11,221
11,923
12,648
13,394
14,164
14,957
15,774
16,614
17,478
18,410
19,278
20,214
21,175
22,162
23,172
24,207
25,270
26,357
27,471
28,610
29,802
30,970
32,191
33,440
34,717
36,023
3,310
3,688
4,085
4,504
4,944
5,405
5,887
6,390
6,915
7,460
8,027
8,615
9,234
9,854
10,507
11,181
11,877
12,597
13,335
14,097
14,882
15,690
16,520
17,373
18,328
19,149
20,072
21,018
21,998
22,982
24,000
25,042
26,109
27,200
28,315
29,485
30,623
31,815
33,033
34,276
35,548
3.589
4,012
4,460
4,931
5,427
4,946
6,490
7,057
7,649
8,264
8,904
9,571
10,263
10,981
11,725
12,495
13,290
14,112
14,960
15,834
16,736
17,666
18,621
19,607
20,585
21,655
22,721
23,816
24,942
26,093
27,274
28,483
29,723
30,993
32,292
33,644
34,884
36,376
37,799
39,255
40,746
8,328
8,976
9,657
10,365
11,100
11,863
12,651
13,465
14,513
15,184
16,083
17,011
17,969
18,951
19,964
21,012
22,072
23,169
24,297
25,454
26,641
27,859
29,106
30,387
31,698
33,016
34,446
35,819
37,255
38,728
40,231
41,772
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
1,
1,
1,
1,
1,
1,
1,
1,694
1,806
1,922
2,042
2,166
2,293
2,424
2,558
2,696
2,838
2,934
3,133
3,287
3,444
3,605
3,769
3,937
4,111
4,286
4,467
4,651
4,840
5,034
341
395
452
510
571
636
704
775
849
928
009
090
186
282
379
480
587
1,692
1,805
1,920
2,040
2,163
2,290
2,420
2,554
2,962
2,833
2,78
3,127
3,279
3,435
3,595
3,758
3,936
4,099
4,272
4,451
4,635
4,823
5,014
0,344
0,399
0,458
0,519
0,581
0,647
0,717
0,790
0,866
0,948
1,032
1,122
1,216
1,317
1,419
1,526
1,638
1,752
1,872
1,996
2,124
2,257
2,395
2,538
2,683
2,834
2,990
3,151
3,316
3,487
3,662
3,843
4,029
4,220
4,422
4,620
4,828
4,043
5,262
5,439
2,219
2,367
2,518
2,674
2,836
3,001
3,172
3,348
3,528
3,713
3,904
4,100
4,301
4,507
4,720
4,936
5,156
5,384
5,613
5,850
Neodymium
Promethium
Samarium
Europium
Gadelinium
Terbium
Dysprosium
Holmium
Erpium
Thulium
Ytterbium
Lutecium
Hafnium
Tantalum
Tungsten
Rhenium
Osmium
Iridiuum
Pltanium
Gold
Merkury
Thallium
Lead
Bismuth
Polonium
Astatine
Radon
Francium
Radium
Actinium
Therium
Protactinium
Uranium
Neptunium
Plutonium
Americium
Curium
Berkelium
Caliternium
Einstennium
Fermium
Nd
Pm
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
Lu
Hf
Ta
W
Re
Os
Ir
Pt
Au
Hg
Tl
Pb
Bi
Po
At
Rn
Fr
Ra
Ac
Th
Pa
U
Np
Pu
Am
Cm
Bk
Cf
Es
Fm
37,359
38,649
40,124
41,529
42,983
44,470
45,985
47,528
49,099
50,730
52,360
54,063
55,757
57,524
59,310
61,131
62,991
64,886
66,820
68,794
70,821
72,860
74,957
77,097
79,296
81,525
83,800
86,119
88,485
90,894
93,334
95,851
98,428
101,005
103,653
106,351
109,098
111,896
114,745
117,646
120,598
36,845
38,160
39,523
40,877
42,280
43,737
45,193
46,686
48,205
49,762
51,326
52,959
54,579
56,270
57,973
59,707
61,477
63,278
65,111
66,980
68,890
70,820
72,794
74,805
76,868
78,956
81,080
83,243
85,446
87,681
89,942
92,271
94,648
97,023
99,457
101,932
104,448
107,023
109,603
112,244
114,926
42,269
43,945
45,400
47,027
48,718
50,391
52,178
53,934
55,690
57,576
59,352
61,282
63,209
65,210
67,233
69,298
71,404
73,549
75,736
77,968
80,258
82,558
84,922
87,335
89,809
82,319
94,877
97,483
100,136
102,846
105,592
108,408
111,289
114,181
117,146
120,163
123,235
126,362
129,544
132,781
136,075
43,293
44,955
46,553
48,241
49,961
51,737
53,491
55,292
57,088
58,969
60,959
62,946
64,936
66,999
69,090
71,220
73,393
75,605
77,866
80,165
82,526
84,904
87,343
89,833
92,386
94,976
97,616
100,305
103,048
105,838
108,671
111,575
114,549
117,533
120,592
123,706
126,875
130,101
133,383
136,724
140,122
5,230
5,431
5,636
5,846
6,059
6,275
6,495
6,720
6,948
7,181
7,414
7,654
7,898
8,145
8,396
8,651
8,910
9,173
9,441
9,711
9,987
10,266
10,549
10,836
11,128
11,424
11,724
12,029
12,338
12,650
12,966
13,291
13,613
13,945
14,279
14,618
14,961
15,309
15,661
16,018
16,379
5,208
5,408
5,609
5,816
6,027
6,241
6,457
6,680
6,904
7,135
7,367
7,604
7,843
8,087
8,333
8,584
8,840
9,098
9,360
9,625
9,896
10,170
10,448
10,729
11,014
11,304
11,597
11,894
12,194
12,499
12,808
13,120
13,438
13,758
14,882
14,411
14,743
15,079
15,420
15,764
16,113
5,722
5,956
5,206
6,456
6,714
6,979
7,249
7,528
7,810
8,103
8,401
8,708
9,021
9,341
9,670
10,008
10,354
10,706
11,069
11,439
11,823
12,210
12,611
13,021
13,441
13,873
14,316
14,770
15,233
15,712
16,200
16,700
17,218
17,740
18,278
18,829
19,393
19,971
20,562
21,166
21,785
6,090
6,336
6,587
6,842
7,102
7,368
7,638
7,912
8,188
8,472
8,758
9,048
9,346
9,649
9,959
10,273
10,596
10,918
11,249
11,582
11,923
12,268
12,620
12,977
13,338
13,705
14,077
14,459
14,839
15,227
15,620
16,022
16,425
16,837
17,254
17,677
18,106
18,540
18,980
19,426
19,879