KOLOM DESTILASI III

Fungsi : Memisahkan Gliserin dengan Methanol

Feed Masuk
Komponen
Methanol
H2O
Gliserin
KOH
Total

Masuk (kg/jam)
4.8304
0.061
9.0448
0.1363

Masuk (kmol/jam)
0.1510
0.0034
0.0983
0.0024
0.2551

Xi
0.5918
0.0133
0.3854
0.0095
1.0000

Persamaan Antoine :
Pi = exp (ant A - ant B /( T + ant C))
T=
P=
Komponen
Methanol
H2O
Gliserin
KOH
Total

99.478 C
1.01325 bar
Xi
0.5975
0.0134
0.3891
0.0095
1.0000

ANT A
5.15853
4.6543
3.93737
4.02783

372.478
1
ANT B
1569.6130
1435.2640
1411.5310
5854.9060

Penentuan Distribusi Masing-masing Komponen :

=

Kf
Khk
Kf Ki tiap komponen feed
Khk Ki tiap komponen heavy key

Heavy Key (HK)

(Gliserin)D

Diinginkan distribusi komponen kunci

0.0010

0.0983

(Gliserin)B

0.9990

0.0983

(Gliserin)D

LOG

(Gliserin)B
Light Key (LK)
(H2O)D

Diinginkan distribusi komponen kunci

0.9990

0.0034

(H2O)B

0.0010

0.0034

LOG

(H2O)D
(H2Ol)B

Komponen
Methanol
H2O
Gliserin
KOH
Total

Ki
1.6429
0.9759
0.0138
0.0000
2.6326

Persamaan VAN WINKLE P-345

LOG
=
dimana :

i = (Ki/Khk)
119.4681
70.9626
1.0000
0.0000

m (log id/ib) + b
m

=
b

Persamaan menjadi =

Log (id/ib)I =

Maka

LOG

(Methanol)D

=
=
=

2.0773

(Methanol)B
(Methanol)D

5404.3647

(MethanolB
(Methanol)B

=
5404.3647

LOG

(Methanol)D

0.1510

(H2O)D

1.8510

(H2O)B

(H2O)D

999.0000

(H2O)B
(H2O)B

=
999.0000

LOG

(H2O)D

0.0034

(Gliserin)D

0.0000

(Gliserin)B
(Gliserin)D

0.0010

(Gliserin)B
(Gliserin)B

=
0.0010

LOG

(Gliserin)D

0.0983

(KOH)D

-7.5294

(KOH)B
KOH)D

0.0000

(KOH)B
(KOH)B

=
0.0000

(KOH)D

0.0024

Kondisi Top (Dew Point)

T=
P=
Komponen
Methanol
H2O

102.2650 OC
=
1.01325 bar
kg/jam
n (kmol)
4.8295
0.1509
0.0609390
0.0033855

375.2650
1.0000
YD
0.9774
0.021926

Gliserin
KOH
Total

0.0090448
0.0000

0.00010
0.0000
0.1544

0.0006
0.0000
1.0000

Kondisi Bottom (Bubble Point)

T=
P=
Komponen
Methanol
H2O
Gliserin
KOH
Total

642.7382 OC
=
1.01325 bar
kg/jam
n (kmol)
0.0009
0.0000279
0.000061
0.00000339
9.0358
0.09821
0.1363
0.0024
0.1007

915.7382
1.0000
YD
0.0003
0.0000
0.9755
0.0242
1.0000

Sehingga diperoleh Neraca Massa untuk Kolom Distilasi 3 sebagai berikut :

Komponen

Masuk (kg/jam)

Methanol
H2O
Gliserin
KOH
Total

4.8304
0.061
9.0448
0.1363
14.0725

Nama Kelompok 5:
Aldila Putri Ananta (10-003)
Zalvi Febriantono (10-004)
Widya Wahyuni (10-015)
Astri Ramadani (10-019)
Zul Hendra (11-010)

Produk
n (kmol)
0.1509
0.00339
0.00010
0.0000
0.1544

kunci

kunci

PRA RANCANGAN PABRIK METHYL ESTER

BM
32
18
92
56

Titik Didih
64
100
290
1032

ANT C
-34.8460
-64.8480
-200.5660
-144.1130

Pi (bar)
1.6647
0.9888
0.0139
0.0000

LK
HK

K
atm
Ki=(Pi/Pt)
1.6429
0.9759
0.0138
0.0000

Yi = Ki x Xi
0.9816
0.0131
0.0054
0.0000
1.0000

99.9000 %

kmol

0.00010 kmol

kmol

0.0982 kmol
Total

=
=

-2.9996

99.9000 %
kmol =

0.0034 kmol

0.0609

kmol =

0.0000 kmol

=
Total

0.0001
0.0610

2.9996

Log i
2.0773
1.8510
0.0000
-7.5294

Log id/ib

id/ib

2.9996
-2.9996

999.0000
0.0010

LK
HK

999.0010

(log i)lk
(log id/ib)lk

1.8510
2.9996

(log i)hk
(log id/ib)hk

0.0000
-2.9996

m (log id/ib)lk
0.9255

0.3085
(log i)lk
1.8510
0.9255
(log i - b )
m
log i

0.3085

0.9255

0.9255

3.7327

0.0000279

0.3085

0.1510
+

1.0000

0.0000

0.1509

0.9255

2.9996

0.3085

0.0034
+

1.0000

0.00000339

0.00000339

0.0034

0.9255

-2.9996

0.09821

0.3085

0.0983
+

1.0000

0.09821

0.00010

0.9255

-27.4022

0.00243

0.0000

0.3085

0.0024
+

1.0000

0.00243

ANT A
5.15853
4.6543

ANT B
1569.6130
1435.2640

ANT C
-34.8460
-64.8480

K
atm
O

Pi (bar)
1.1075
0.2112

3.93737
4.02783

1411.5310
5854.9060

-200.5660
-144.1130

1.1924
0.0000

ANT A
5.15853
4.6543
3.93737
4.02783

ANT B
1569.6130
1435.2640
1411.5310
5854.9060

ANT C
-34.8460
-64.8480
-200.5660
-144.1130

Pi bar)
29.2736
19.4437
7.1255
0.0284

K
atm
O

si 3 sebagai berikut :
Keluar
Atas
kg/jam
4.8295
0.0609
0.0090
0.0000
4.8995

Produk Bawah
n (kmol)
kg/jam
0.0000
0.0009
0.0000
0.0001
0.0982
9.0358
0.0024
0.1363
0.1007
9.1730

Titik Didih
64
100
290
1032

kg
kg
kg

0.0090

kg

9.0358
9.0448

kg
kg

kmol

kmol

0.0008936307 kg

4.8295063693 kg

kmol

kmol

kmol

kmol

kmol

kmol

Ki
1.0930
0.2085

0.000061 kg

0.060939 kg

9.0357552 kg

0.0090 kg

0.1363 kg

0.0000 kg

Xi=YD / Ki
0.89429
0.10518

LK
HK

1.1768
0.0000

0.00054
0.00000
1.0000

Ki
28.8908
19.1894
7.0323
0.0281

Xi=YD / Ki
0.00001
0.00000
0.13872
0.86127
1.000000