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760

T-x-y Diagram at Pt (mmHg)

Component 1
Heptane

Antoine Equation Constants

1.00
0.90

BP (degree C)
A
B
C

x-y Diagram Heptane and Octane


98.5

0.80
Vapor
Pressure (mmHg) at temp (degree C) Vapor Pressure of Component 1
98.4
760
0.70
105
940
110
1050
0.60
115
1200
0.50
120
1350
125.6
1540
0.40
0.30
0.20
0.10
0.00
0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

Component 2
Octane

Octane

126

Vapor Pressure of Component 2


333
417
484
561
650
760

0.70

0.80

0.90

1.00

xa
1.00
0.66
0.49
0.31
0.16
0.00

ya
1.00
0.81
0.67
0.49
0.28
0.00

xb
0.00
0.34
0.51
0.69
0.84
1.00

yb
0.00
0.19
0.33
0.51
0.72
1.00

x
0
135
125
115

y
0
0.2
0.4
0.6
0.8
1

0.2
0.4
0.6
0.8
1

105

y=-4/6x+0.834
0.5
0.50
T-x-y0.48
Diagram
0.51(1 atm)
0.46
0.53
0.44
0.54
0.42
0.55
0.4
0.57
0.2
0.70
0
0.83

for Heptane

95
85
Temperature (C )
75
65
55
45
35
0.00

0.10

0.20

0.30

0.40

0.50
x,y

0.60

m) for Heptane and Octane

0.50

x,y

0.60

0.70

0.80

0.90

1.00