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1.

Reaksi peruraian pestisida fosfonium di dalam sistem tanah oleh penambahan oksidan diam
variasi waktu reaksi:
Waktu(jam)
30
60
90
120
240
480
3000
3600
4800
6000

ln [A] Orde 1
1.6098378325
1.4843281014
0.8329091229
0.6259384309
-1.064210862
-1.8325814637
-36.2760476789
-43.9306386435
-56.933355548
-74.5454729408

Waktu(jam)
30
60
90
120
240
480
3000
3600
4800
6000

1/[A] Orde 1
0.199920032
0.2266545784
0.4347826087
0.5347593583
2.8985507246
6.25
5681818181818180
11990407673860900000
5319148936170210000000000
2.36966824644550E+032

Waktu(jam)
30
60
90
120
240
480
3000
3600
4800
6000

1/[A]
0.0399680192
0.0513722979
0.1890359168
0.2859675713
8.4015963033
39.0625
3.22830578512397E+031
1.43769876185383E+038
2.82933454051607E+049
5.61532759821208E+064

orde reaksi 1:

2. Hidrolisis suatu gula oleh asam lemah memberikan data perubahan konsentras
waktu
0
1
2
3
4
5
6
7
8
9
10

ln [M]
0
-0.2329994616
-0.4660004527
-0.6990002766
-0.9320009943
-1.1649989165
-1.3979985892
-1.6309986844
-1.8640011839
-2.0970028426
-2.3299974006

orde reaksi 1:
waktu
0
1
2
3
4
5
6
7
8
9
10

1/[M]

waktu
0
1
2
3
4
5
6
7
8
9
10

1/[M]

1
1.2623807997
1.5936077207
2.0117405177
2.5395857936
3.2059194096
4.0470919621
5.1089744245
6.4494908127
8.1417312577
10.2779148166

1
1.5936052834
2.5395855675
4.0470999104
6.4494960028
10.2779192608
16.3789533495
26.1016196699
41.5959317431
66.2877878732
105.6355329782

orde reaksi 1:
time(menit)
0
20
40
60
80
100
120
140
160
180
200

ln [C]
0.9162907319
0.0676586485
-0.3856624808
-0.6931471806
-0.9416085399
-1.1394342832
-1.2729656758
-1.4271163556
-1.5606477483
-1.6607312068
-1.7719568419

time(menit)
0
20
40
60
80
100
120
140
160
180
200

1/[C]

time(menit)
0
20
40
60
80
100
120
140
160
180
200

1/[C]

0.4
0.9345794393
1.4705882353
2
2.5641025641
3.125
3.5714285714
4.1666666667
4.7619047619
5.2631578947
5.8823529412

0.16
0.8734387283
2.1626297578
#VALUE!
6.5746219592
9.765625
12.7551020408
17.3611111111
22.6757369615
27.7008310249
34.6020761246

tem tanah oleh penambahan oksidan diamati dengan mengukur sisa pestisida pada

10
0

Sisa dalam tanah (mg/kg)


5.002
4.412
2.3
1.87
0.345
0.16
1.76E-016
8.34E-20
1.88E-025
4.22E-033

-10

f(x) = 1000
R = 0.99

-20
-30
-40
-50
-60
-70
-80

k= 0,012
Sisa dalam tanah (mg/kg)
5.002
4.412
2.3
1.87
0.345
0.16
1.76E-016
8.34E-20
1.88E-025
4.22E-033

[A]
25.020004
19.465744
5.290000
3.496900
0.119025
0.025600
0.000000
0.000000
0.000000
0.000000

25000000000000

20000000000000

15000000000000

10000000000000
f(x) = 20
R = 0.4
5000000000000

Sisa dalam tanah (mg/kg)


5.002
4.412
2.3
1.87
0.345
0.16
1.76E-016
8.34E-20
1.88E-025
4.22E-033

memberikan data perubahan konsentras iversus waktu sebagai berikut:


Kons.(M)
1
0.792154
0.627507
0.497082
0.393765
0.311923
0.247091
0.195734
0.155051
0.122824
0.097296

k= 0,233
Kons.(M)
1
0.792154
0.627507
0.497082
0.393765
0.311923
0.247091
0.195734
0.155051
0.122824
0.097296

[M]
1
0.6275079597
0.393765035
0.2470905147
0.1550508752
0.0972959579
0.0610539623
0.0383117988
0.0240408126
0.015085735
0.0094665116

Kons.(M)
1
0.792154
0.627507
0.497082
0.393765
0.311923
0.247091
0.195734
0.155051
0.122824
0.097296

k= 0,233
conc.
2.5
1.07
0.68
0.5
0.39
0.32
0.28
0.24
0.21
0.19
0.17

conc.
2.5
1.07
0.68
0.5
0.39
0.32
0.28
0.24
0.21
0.19
0.17

[C]
6.25
1.1449
0.4624
s
0.1521
0.1024
0.0784
0.0576
0.0441
0.0361
0.0289

conc.
2.5
1.07
0.68
0.5
0.39
0.32
0.28
0.24
0.21
0.19
0.17

10

ln [A] Orde 1

0
-10

f(x) = - 0.0126939006x + 2.3792354721


1000
2000
3000
4000
5000
R = 0.9989556107

6000

7000

-20
-30
ln [A] Orde 1

-40

Linear (ln [A] Orde 1)

-50
-60
-70
-80

1/[A] Orde 1
250000000000000000000000000000000
200000000000000000000000000000000
1/[A] Orde 1

150000000000000000000000000000000

Linear (1/[A] Orde 1)

100000000000000000000000000000000
f(x) = 20793512439413800000000000000x - 14604966917029200000000000000000
R = 0.4053986444
50000000000000000000000000000000
0
0 2000400060008000

1/[A]
60000000000000000000000000000000000000000000000000000000000000000
50000000000000000000000000000000000000000000000000000000000000000
40000000000000000000000000000000000000000000000000000000000000000

1/[A]
Linear (1/[A] )

30000000000000000000000000000000000000000000000000000000000000000

f(x) = 4927372537291230000000000000000000000000000000000000000000000x - 3460892615478360000000000000000000000000000000000000000000000000


20000000000000000000000000000000000000000000000000000000000000000
R = 0.4053986295
10000000000000000000000000000000000000000000000000000000000000000
0
0 20004000 60008000

ln [M]
0

- 2.15195900274334E-008
0 f(x) = - 20.2329999739x
4
6
8
10
R = 1

-0.5

12
ln [M]

-1

Linear (ln [M])

-1.5
-2
-2.5

1/[M]
12
10
8

1/[M]

f(x) = 0.8743327198x - 0.2227147338


R = 0.908534923

Linear (1/[M])

4
2
0
0

10

12

1/[M]
120
100
80

1/[M]

60

Linear (1/[M])

f(x) = 8.6651084604x - 17.6975848802


R = 0.7386461102

40
20
0
0

10

12

ln [C]
1.5
1
0.5
0
-0.5

ln [C]
f(x) = - 0.0116722948x + 0.270018487
0 R = 0.882345864
50
100
150

Linear (ln [C])


200

250

-1
-1.5
-2

1/[C]
7
6
f(x) = 0.027245767x + 0.3790397591
R = 0.9996392871

1/[C]

Linear (1/[C])

3
2
1
0
0

50

100

150

200

250

1/[C]
40
35
30

f(x) = 0.1681040432x - 4.0197032192


R = 0.9366196636

25
20

1/[C]
Linear (1/[C])

15
10
5
0
0

50

100

150

200

250