22.33.

The folowing problem and itssolution were given in a textbook:

How much heat in kJ is required to vaporize 1.00 kg of saturated liquid water at
100C and 101.3 kPa? The solulion is
n = l.00kg
ae=Q+W+Eflow
aU=Q+w=Q-pav
Q = aH = (lkg)(2256.91cJIkg) = 2256.9kJ
Is this salution correet?
a) Jika evaporasi terjadi dalam keadaan terbuka, sistem unsteady state volume tetap:
U = Q + W - H
W=0
U = Q - H
Data :
liquid = 419.5 kJ/kg
vapor = 2506 kJ/kg
liquid = 419.5 kJ/kg
vapor = 2675.6 kJ/kg
Asumsikan hanya 1 kg air di dalam sistem t = inisial. di t = final, 0 kg air di dalam
sistem.
Ufinal = 0
Uinisial = (1 kg)x(419.5 kJ/kg) = 419.5 kJ
Hkeluar = (1 kg)x(2675.6 kJ/kg) = 2675.6 kJ
Hmasuk = 0
-419.5 = Q (2675.6-0)
Q = 2256.1 kJ
b) Jika evaporasi terjadi dalam sistem terbuka steady state, m masuk adalah kg dan min
1 = mkeluar.
Prosesnya adalah isotermal.
W=0
U = 0
OUT
IN
Q = H = [ (min 1)liquid + (1)vapor] m1Hmasuk
Hmasuk = liquid
Q = (1)(2675.6 419.5) = 2256.1 kJ
Jawaban di atas adalah benar tapi menandai dari persamaan di atas U = Q - V
hampir sama ke sistem, tidak membuka salah satu dalam bejana bertekanan.
Kesimpulannya adalah baik tapi prosedurnya kurang memadai.

23.8.

The vapor pressure of phenylhydrazine has been found to be (from 25C to 240C):
2366.4
7.9046Log p* =
T+230
where p. is in atm and T is in C. What is the heat of vaporizadon of phenylhydrazine
in Btu/lb mol at 200' F?
Use the Clausius-Clapeyron equation.
Penyelesaian:
200 F 660 R = 366.7 K

v
dp
=
dT T (V g V t )

T 2=320

T 1=302

ln

dT
1
=
2
T
T

T2
T1

v 1
0.2111 v 1
1
1
=

p 35
R T1 T2
R 308 320

-1.5554 ln p35
p *35 = 0.1310

417.7 78
0.1218x 10 -3

1 gmol 8.314 J
K
= g
= 0.4771
(gmol)(K)