V 2

a) Clculo de

por forma polinmica.

V r=a n 21+ b n1+ c

5.8 = a (0.0555)2 + b (0.0555) + c
6.6 = a (0.1111) 2 + b (0.1111) + c

Para V2 = 1 ml
Para V2 = 2 ml

[1]

12.4 = a (0.0154) + b (0.1666) + 2c

Ecuaciones multiplicadas por coeficiente de a

0.0178 = 9.4879E-6 a + 1.7080E-4 b + 3.0802E-3 c
0.0814 = 1.5208E-4 a + 1.3701E-3 b + 0.012 c
[2]

0.0992 = 1.615E -4 a + 1.5409E-3 b +

0.01508 c
Ecuaciones multiplicadas por coeficiente de b
0.3212 =
0.7332 =
[3]

1.709E-4 a + 3.0802E-3 b + 0.0555 c

1.371E-3 a + 0.0123 b + 0.1111 c
1.0544 =

1.5419E-3 a +

0.0153 b

0.1666 c
[1] y [2]
[1] x (1.615E -4)
3.23E-4 c
[2] x (- 0.0154)
2.32E-4 c
[4]

2.0023E-3 = 2.4871E -6 a + 2.6905E-5 b +

-1.527E-3 = -2.4871E -6 a - 2.3729E-5 b 4.756E-4 =

----

3.176E-6 b +

9.08E-5 c
[1] y [3]
[1] x (1.5419E-3)
3.083E-3 c
[3] x (-0.0154)
2.565E-4 c

0.0191
-0.0162

2.379E -5 a + 2.5688E-5 b +

= -2.379E -5 a - 2.3562E-4 b -

[5]

2.9E-3 =

----

-2.0993E-4 b +

5.183E-4 c

[4] y [5]
[4] x (-2.0993E-4)
[5] x (- 3.176E-6)

-9.9842E-4 =
-9.21E-9
=
-1.0905E-7

-6.667E-10 b - 1.906E-8 c
6.667E-10 b - 1.646E-8 c

---

- 2.0706E-8

c
c

5.26

c en [4]
[4]

4.756E-4
=
3.176E-6 b + 9.08E-5 (5.26)
-2.008E-6 =
3.176E-6 b
b =
-0.6322

b y c en [1]
[1]

12.4 = a (0.0154) + (-0.6322) (0.1666) + 2

(5.26)
1.984 = 0.0154 a
a = 128.89

Vr=a n2 +b n 2+ c
d Vr=2a n 2 dn+ bdn
dVr
=2 a n2 +b=V 2
dn

Clculo de

V 2

Para n = 0.0555

V 2=2 (128.89 )( 0.0555 ) + (0.6322 )

ml
L
V 2=13.67
=0.01367
mol
mol
-

Para n = 0,1111

Para n = 0,1666

Para n = 0,2222

ml
L
V 2=28.01
=0.0 2801
mol
mol

ml
L
V 2=42.31
=0.0 4231
mol
mol

ml
L
V 2=56.64
=0.0 5664
mol
mol

Clculo de

V 1

R= n 1 V 1+ n2 V 2
V

V n 2 V 2
V 1= R
n1
3

5,8 10 L0,0555 mol 0,0 1367 L/ mol

V 1=
= 0,0588L/mol
0,0857 mol

6,6 103 L0,1111 mol 0,02801 L/mol

V 1=
= 0,0407L/mol
0,0857 mol

7,8 103 L0,1666 mol 0,04231 L/ mol

V 1=
= 0,0087L/mol
0,0857 mol

Resultados

nagua,
mol

V1 (Etanol),
ml

V2(Agua),
ml

VReal, ml

1
2

0,0555
0,1111

5
5

1
2

5,8
6,6

V 1 ,

V 2 ,

L/mol
0,0588
0,0407

L/mol
0,0136
0,0280

3
4

0,1666
0,2222

5
5

3
4

7,8
8,7

0,0087
--

0,0423
0,0566