Lithium
Sodium
Potassium
Rubidium
Caesium
Francium
Trends in alkali
metals:
Soft
Low density
Low melting and boiling points
Good conductors
Shiny
4Li + O2 2Li20
Sodium
4Na + O2 2Na2O
Potassium
4K + O2 2K2O
Lithium:
Fizzes
Floats around slowly across the surface of the water
Sodium:
Potassium:
2K + 2H2O 2KOH + H2
Alkali metals react vigorously with chlorine. They burn brightly forming chlorides.
Lithium:
2Li +
Cl2
2LiCl
(Lithium Chloride)
Sodium:
2K + Cl2 2KCl
Uses of alkali metals:
Lithium
Used for batteries
Alloys
Submarines
Sodium
Street lights
Table salts
Cleaning products
Potassium
Explosives and fireworks
Food preservatives
Fertilisers
All alkali metals react in a similar way because all alkali metals have the same valency. Alkali
metals are very reactive because they only have one electron in their outer shell.
Why does reactivity in alkali metals increase down the group?
As you go down the group, the number of shells in one atom of the element increase, which
means that the outer shell gets further away from the nucleus and is shielded by more
electrons. Therefore the outer shell can be easily lost as the forces are weak.
Alkali metals form ionic compounds. The metal ion has a charge of +1.
Halogens are the most reactive elements in the periodic table. They react with metals to form
halides.
Fluorine
(Halogen) + (metal)
reacts
with
metals to form fluoride (F-)
Chlorine reacts with metals to form chloride (Cl-)
Bromine reacts with metals to form bromide (Br-)
Iodine reacts with metals to form iodide (I-)
(metal halide)
Fluorine:
(Halogen) + (iron)
(iron halide)
(Halogen) + (hydrogen)
(hydrogen halide)
Fluorine:
Atoms of each element gets larger down the group, as the number of shells
increase
This means that the outer shell gets further away from the nucleus and is
shielded by more electron shells
The further the outer shell is from the nucleus, the harder it is to attract another
electron, to have a complete outer shell.
Displacement of halogens
If a halogen is added to a solution of a compound containing a less reactive halogen, it
will react with the compound and form a new one. A halogen will displace a less
reactive halogen from a solution of its halide
Fluorine + sodium chloride sodium fluoride + chlorine
F2 (aq) + 2NaCl (aq) 2NaF (aq) + Cl2 (aq) (as F is more reactive
than C)
Uses of halogens:
Fluorine:
In polymers
Toothpaste (to prevent tooth decay)
Chlorine:
Antiseptic, disinfectant
Bleach
Bromine:
Insecticides
Fire extinguisher
Drugs
Iodine:
Non-metals
Colourless gases
Monoatomic
Unreactive
Odourless
They are unreactive because they already have a full outer shell, so they have no need to gain
or lose electrons.
Trends in the group:
Group 7
Group 0
Reactivity
Increases down
the group
Reactivity
decreases down
the group
Unreactive
Melting and
boiling points
Density
Decrease down
the group
Increases down
the group
Softness
increases down
Increases down
the group
Increases down
the group
Colour gets
darker down the
Increases down
the group
Increases down
the group
The atoms
increase in size
Transition
metals
Generally
decreases
across a period,
except for zinc
No fixed pattern
No fixed pattern
the group
group