M.M. : 210
Blank spaces and blank pages are provided in this booklet for your rough work. No additional sheets will
be provided for rough work.
2.
Using a black ball point pen, darken the bubbles on the upper original sheet. Apply sufficient pressure
so that the impression is created on the bottom sheet.
3.
Write your Name, Registration Number and the name of examination centre and sign with pen in the
boxes provided on the right part of the ORS. Do not write any of this information anywhere else. Darken
the appropriate bubble UNDER each digit of your Registration Number.
4.
The question paper consists of 3 parts (Chemistry, Physics and Mathematics). Each part consists of three
sections.
5.
Section I contains 10 Straight objective type questions. Each question has four choices (A), (B), (C) and
(D) out of which ONLY ONE is correct.
6.
Section II contains 5 Multiple type questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE or MORE are correct.
7.
Section III contains 5 Integer (Subjective) type questions. Each question has an integer answer lying
between 0 and 9.
8.
For each question in Section I, you will be given 3 Marks if you have darkened only the bubble
corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases,
minus ONE (1) marks (NEGATIVE MARKING) will be given.
9.
For each question in Section II, you will be given 4 Marks if you have darkened only the bubbles
corresponding to the correct answers and zero mark if no bubble is darkened. There is NO Negative
Marking.
10.
For each question in Section III, you will be given 4 Marks if you have darkened only the bubble
corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases,
minus one (1) marks (NEGATIVE MARKING) will be given.
VMC/2013
Vidyamandir Classes
PART - I (CHEMISTRY)
70 MARKS
SECTION - I
STRAIGHT OBJECTIVE TYPE
This Section contains 10 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
Only One is Correct :
1.
2.
Two moles of an ideal gas ( = 3/ 2) is made to expand reversibly and adiabatically to four times to its
initial volume. The change in entropy of the system during expansion is :
[R = 2 cal K 1mol1 , ln 2 = 0.7]
1
(A)
5.6cal K 1mol1
(B)
11.2cal K mol1
(C)
(D)
Zero
The initial pressure of 200 mm of Hg changes to 390 mm of Hg after infinite time, where all the reactant
is consumed. If at 10 min, 0.2 g of NaOH was required to react completely with reaction mixture, then
half life of reaction is :
(A)
20 min
(B)
10 min
(C)
5 min
(D)
2.5 min
3.
The rate law for the substitution reaction of 2-bromobutane with OH in polar aprotic solvents at a fixed
temperature has been reported as when the base concentration is 1 M:
Rate = 3.12 105 [substrate] [base] + 0.80 106 [substrate]
The percentage of reaction taking place through SN1 is :
(A)
2.5
(B)
97.5
(C)
5
4.
95
III.
IV.
(A)
5.
(D)
The compounds formed by Mg, Ca, Sr and Ba are predominantly divalent and ionic.
The ionization energy of Be is low and its compounds are ionic.
I, II
(B)
II, III
(C)
II, IV
(D)
I, II, III
When haematite ore is burnt in air with coke along with lime at 200C , the process not only produces
steel but also produces an important compound (A), which is useful in making building materials.
The compound (A) is :
(A)
SiO2
(B)
CaSiO3
(C)
FeO
(D)
Fe2O3
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6.
CO2C2H5
HCl
H2O
CN
COOH
COOH
(A)
(B)
COOH
COOH
COOH
COOH
(C)
7.
8.
(D)
COOH
(D)
CrO5
H SO
X + NH 3
HCN
2 4
X
Y + H 2O
I, II
(C)
I, III
(D)
I, II, III
9.
When AgNO3 is treated with excess of KI, AgI precipitates out, which forms colloidal solution with :
(A)
positive charge
(B)
negative charge
(C)
charge neutralization occurs, not charge acquisition
(D)
first positive, later negative
10.
If you have a saturated solution of CaF2, then which of the following is(are) true :
I.
II.
[Ca 2+ ] = K sp
[Ca 2+ ] = 2[F ]
1/ 3
2+
III.
2[Ca ] = [F ]
(A)
I, II
IV.
(B)
II, III
(C)
K sp
[Ca ] =
4
I, III, IV
(D)
2+
III, IV
VMC/2013
Vidyamandir Classes
SECTION - II
MULTIPLE CORRECT ANSWERS TYPE
This Section contains 5 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which one
or More Choices may be Correct:
11.
12.
(C)
(Acidic character)
(D)
(Ionisation energy)
E cell = E 0
(B)
(C)
The amount of AgCl(s) precipitated in anodic compartment will increase with the working of the
cell
The concentration of Ag+ is constant in anodic compartment when the cell stops working
(D)
Ag + Ag
E0
Cl AgCl Ag
0.059
1
log
+
1
[Ag ][Cl ]
(A)
{Where [Ag+]a and [Ag+]c is amount Ag+ ion in anodic compartment and in cathodic compartment}
SPACE FOR ROUGH WORK
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NH OH
13.
H SO
H O+
H+
HNO
2
2 4
3
2
P
Q
R
S
O
HCl
35C
(A)
Q is :
(B)
R is :
NH
(C)
S is :
(D)
S is :
O
15.
Consider the following aqueous solutions and assume 100% ionization in electrolytes.
I.
0.1m urea
II.
0.04 m Al2(SO4)3
III.
0.05 m CaCl2 IV.
The correct statement(s) regarding the above solutions is(are) :
(A)
freezing point will be lowest for solution I
(B)
freezing point will be highest for solution IV
(C)
boiling point will be highest for solution II
(D)
vapour pressure will be highest for solution II
Knowing that average kinetic energy of an ideal gas (X) is
directly proportional to absolute temperature, if
T1 = 300K , which statement(s) may describe the other
curves when compared to the dotted curve? (Dotted curve
indicates the graph of gas (X) at temperature T1) [Assume
number of moles is constant]
(A)
Curve A is for heavier gas but at same temperature
(B)
Curve B is for the same gas but at 373 K
(C)
Curve A is for the same gas but at 273 K
(D)
Curve B is for lighter gas but at same temperature
0.005 m NaCl
A
Fraction of molecules
at a given velocity
14.
NH2
T1(X)
Velocity
VMC/2013
Vidyamandir Classes
SECTION - III
SUBJECTIVE TYPE
This Section contains 5 Subjective Questions. Each question has an integer answer between 0 and 99. Fill the
answer bubbles in OMR Sheet appropriately and CAREFULLY. [Please note that an answer 5 should be filled
as 05 in the OMR sheet]
16.
Positronium is a species consisting of an electron bound to a positron. If the radius of its 2nd orbit is
x R o (where R0 is the radius of 1st Bohr orbit of hydrogen). Then the value of x is _____.
18.
One litre of oxygen was added to one litre of a mixture of carbon monoxide and carbon dioxide. When
the whole mixture was burnt, its volume decreased to 1.6 litres finally. What is the mole ratio of carbon
monoxide to the carbon dioxide in the original mixture ?
19.
A mixture containing Salicylic acid, Malonic acid and some inert impurities was dissolved in water and
the solution was made to 1.0 L. 25 mL of this solution required 20.0 mL of 0.1 M NaOH for complete
neutralization. In another experiment, 50 mL of same solution on heating gave 11.2 mL of CO2 at STP.
Calculate the ratio of moles of salicylic acid and malonic acid.
20.
How many of the following compounds are more acidic than benzoic acid ?
o-nitrobenzoic acid
p-methoxybenzoic acid
2, 4, 6-trinitrophenol
o-toluic acid
Salicylic acid
Formic acid
p-toluic acid
VMC/2013
Vidyamandir Classes
PART - II (PHYSICS)
70 MARKS
SECTION - I
STRAIGHT OBJECTIVE TYPE
This Section contains 10 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
Only One is Correct :
21.
The activity of a radioactive element decreases to one-third of the original activity I0 in a period of nine
years. After a further lapse of nine years, its activity will be
(A)
I0
(B)
(2/3)I0
(C)
(I0/9)
(D)
(I0/6)
22.
A long wire bent as shown in fig carries current I. If the radius of the
semicircular portion is a, the magnetic field at the centre C is:
0 I
0 I
(A)
(B)
2 +4
4a
4a
0 I 0 I
0 I
(C)
(D)
+
2 4
4a 4a
4 a
23.
g sin
k
m
(B)
mg sin
k
(C)
3mg sin
k
(D)
None of these
VMC/2013
Vidyamandir Classes
24.
(D)
40 mg/s
25.
6
12
2
(A)
(B)
(C)
(D)
g (2 d )
g (2 d )
g (2 d )
g (2 d )
26.
A ball is thrown with a velocity whose horizontal component is 12 ms 1 from a point 15m above the
ground and 6 m away from a vertical wall 18.75 m high in such a way so as just to clear the wall. At what
time will it reach the ground ( g = 102 )
(A)
2s
(B)
3s
(C)
4s
(D)
5s
VMC/2013
Vidyamandir Classes
27.
60
60 each at A and B with the ceiling of the truck. Find the acceleration
of the truck so that the string between A and P becomes vertical in
equilibrium with respect to the truck.
(A)
2 m/s2
(B)
2.5 m/s2
(C)
5 m/s2
(D)
28.
L
would be equal after a time t equal to Given : R =
:
C
(A)
RC
(B)
RL
(C)
(D)
RCn2
R/L n 2
6 m/s2
L
29.
In an experiment of resonance tube to measure the velocity of sound, first resonance occurs at
l = 10cm from the open end of the tube. End correction of the tube is 1.0cm and the frequency of tuning
fork is 700Hz
I.
Velocity of sound is 308 m/s
II.
Next resonance will occur at l = 32cm from open end of the tube
III.
Radius of resonance tube is 1cm
IV.
Radius of resonance tube is 1.67 cm
(A)
I, II
(B)
I, III
(C)
II, III
(D)
I, II, III
30.
VMC/2013
Vidyamandir Classes
SECTION - II
MULTIPLE CORRECT ANSWERS TYPE
This Section contains 5 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which one
or More Choices may be Correct:
31.
A particle P is projected vertically upwards from level ground with an initial velocity of 100 ms 1 .
One second later another particle Q is projected vertically upwards from the same point with an initial
velocity of 90 ms 1 . Before either of the particle strikes the ground g = 10 ms 2 , which of the
following is(are) the wrong statements ?
(A)
Both particles are rest with respect to each other
(B)
After 3s from launch of P, the distance between the particles is 95 m.
(C)
When the particle P is at the highest position, particle Q is moving upward
(D)
When the particle P is at highest point particle Q will be moving downwards
32.
b
2H
8V
2
S
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33.
(D)
The change in charges on both capacitors is same after the switch is closed
34.
In Bohr model of the hydrogen atom, let R, v and E represent the radius of the orbit, speed of the electron
and the total energy of the electron respectively. Which of the following quantities are directly
proportional to the quantum number n?
(A)
vR
(B)
RE
(C)
v/E
(D)
R/E
35.
VMC/2013
11
Vidyamandir Classes
SECTION - III
SUBJECTIVE TYPE
This Section contains 5 Subjective Questions. Each question has an integer answer between 0 and 99. Fill the
answer bubbles in OMR Sheet appropriately and CAREFULLY. [Please note that an answer 5 should be filled
as 05 in the OMR sheet]
36.
A particle moving in a straight line and its acceleration (a) varies with velocity(v) as a = k ( v ) .
At origin particle has velocity 1m/s and has velocity 36m/s at displacement of 5m. Find the value of K.
32
37.
A silver ball of radius 4.8 cm is suspended by a thread in a vacuum chamber. Ultraviolet light of
wavelength 200 nm is incident on the ball for some time during which a total light energy of 1.0 107 J
falls on the surface. Assuming that on the average, one photon out of ten thousand photons is able to eject
a photoelectron, find the electric potential (in 101V ) at the surface of the ball assuming zero potential
at infinity.
38.
A cube of side l = ( )
39.
40.
A 0.1 kg mass is suspended from a wire of negligible mass. The length of the wire is 1 m and its
cross-sectional area is 4.9 107 m2 . If the mass is pulled a little in the vertically downward direction and
1/ 4
m has one corner at the origin of coordinates and the edges from this corner
extend along the positive x, y and z-axes. Suppose the electric field in this region is given by E = 2 xyi .
The charge inside the cube is b2 nC. Find the value of 1/b.
released, it performs simple harmonic motion of angular frequency 140rads 1 . If the Youngs modulus of
the material of the wire is n 109 Nm 2 , the value of n is_____________.
VMC/2013
12
Vidyamandir Classes
70 MARKS
SECTION - I
STRAIGHT OBJECTIVE TYPE
This Section contains 10 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
Only One is Correct :
41.
42.
43.
44.
An ellipse
1 1 1 1 1 1 1 1
Sum of the series 1 + + + ......
2 4 3 6 8 5 10 12
1
1
(A)
(B)
(C)
log4
log 2
log 2
2
3
(D)
(D)
log2
( 4r + 1)! is :
r =0
(A)
45.
( )
f i2 + f (i )
(B)
f (1) + f ( i )
(C)
f (1) f ( i )
(D)
None of these
A triangle has 2 of its sides along axes, its third side touches the circle x 2 + y 2 2ax 2ay + a 2 = 0 .
If the locus of the circumcentre of the triangle passes through the point (38, 37) then the value of
(a2 2a) equal :
(A)
2800
(B)
2810
(C)
2812
(D)
2820
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1x
46.
47.
f (1 + x )
Let f : R R be such that f (1) = 3 and f (1) = 6 the lim
x0
f (1)
1/2
2
(A)
1
(B)
e
(C)
e
{0, 1}
{0, 1}
(B)
(C)
{0, 1, 1}
(D)
None of these
5 2
(D)
None of these
4
4
If the focal distance of an end of the minor axis of any ellipse (referred to its axes as the axes of x and y)
is k and the distance between the foci is 2h then its equation is :
x2
(A)
k2
x2
(C)
50.
e3
Let r = a b sin x + b c cos y + 2 c a where a , b , c are three non-coplanar vectors. If r is
perpendicular to a + b + c , then minimum value of x 2 + y 2 , is :
(A)
49.
(D)
(A)
48.
equals :
If
k2
(B)
+
+
y2
k 2 + h2
y2
k 2 h2
(C)
=1
(B)
=1
(D)
lim
(A)
f ( x)
sin ( sin x )
0
x2
k2
x2
k2
y2
h2 k 2
y2
h2
=1
=1
f ( ) = f ( ) = 0 and
3
, then
f =
4
2
2
is equal to :
(B)
(C)
(D)
None of these
VMC/2013
14
Vidyamandir Classes
SECTION - II
MULTIPLE CORRECT ANSWERS TYPE
This Section contains 5 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which one
or More Choices may be Correct:
19
51.
sin x
1 + x8 dx
10
(A)
52.
xk
xk + 2
If then y k
yk + 2
zk
zk +2
(A)
53.
k = 3
None of these
xk +3
1 1 1
y k + 3 = ( x y )( y z )( z x ) + +
x y z
zk +3
(B)
k = 1
(C)
k3 + 3 = 24
(D)
k2 + 2k + 1 = 0
An ellipse intersects the hyperbola 2x2 2y2 = 1 orthogonally. The eccentricity of the ellipse is reciprocal
of that of the hyperbola, if the axes of the ellipse are along the coordinate axes, then :
(A)
(B)
(C)
(D)
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54.
Let = e
2
11
, = 6 , = 7 , = 2 , then :
(C)
) 12
( ) ( ) ( ) . . . . . . ( ) ( ) = 0
( i ) ( i ) ( i ) . . . . . .( i ) = i (where i = 1 )
(D)
None of these
(A)
(B)
55.
Re + 2 + 3 + 4 + 5 =
2
10
10
VMC/2013
16
Vidyamandir Classes
SECTION - III
SUBJECTIVE TYPE
This Section contains 5 Subjective Questions. Each question has an integer answer between 0 and 99. Fill the
answer bubbles in OMR Sheet appropriately and CAREFULLY. [Please note that an answer 5 should be filled
as 05 in the OMR sheet]
56.
Let 0.8 the probability that a man aged 90 years will die in a year. If p is the probability that out of 4 men
A1, A1, A3, A4 each aged 90, A1 will die in a year and will be the first to die, find [10p], where [ ]
denotes greatest integer x .
2
57.
If :
58.
59.
ABCD is a trapezium such that AB and CD are parallel and CB is perpendicular to them. If ADB = ,
51AB
BC = 45m CD = 30 and tan = 1/5 then
, is equal to_________.
117
2 + 3 1 + 3
Let p 4 + q 3 + r 2 + s + t = + 1
2 4 be an identity in , where p, q, r, s and t are
3 + 4 3
constants. Then the value of t is ____________.
60.
x| is a find value of
a +2
VMC/2013
17