Vidyamandir Classes
05/05/2013 
M.M. : 210 

10:00 AM  01:00 PM 
TEST CODE : ACEG 
TIME : 3.00 Hrs 
Read the following Instructions very carefully before you proceed.
1. Blank spaces and blank pages are provided in this booklet for your rough work. No additional sheets will be provided for rough work.
2. Using a black ball point pen, darken the bubbles on the upper original sheet. Apply sufficient pressure so that the impression is created on the bottom sheet.
3. Write your Name, Registration Number and the name of examination centre and sign with pen in the boxes provided on the right part of the ORS. Do not write any of this information anywhere else. Darken the appropriate bubble UNDER each digit of your Registration Number.
4. The question paper consists of 3 parts (Chemistry, Physics and Mathematics). Each part consists of three sections.
5. Section I contains 10 Straight objective type questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
6. Section II contains 5 Multiple type questions. Each question has four choices (A), (B), (C) and (D) out of which ONE or MORE are correct.
7. Section III contains 5 Integer (Subjective) type questions. Each question has an integer answer lying between 0 and 9.
8. For each question in Section I, you will be given 3 Marks if you have darkened only the bubble corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases, minus ONE (–1) marks (NEGATIVE MARKING) will be given.
9.
For
each question
in Section
II, you
will be given
4 Marks
if
you have darkened only the bubbles
corresponding to the correct answers and zero mark if no bubble is darkened. There is NO Negative
Marking.
10. For each question in Section III, you will be given 4 Marks if you have darkened only the bubble corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases, minus one (–1) marks (NEGATIVE MARKING) will be given.
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PART  I (CHEMISTRY) 
70 MARKS 
SECTION  I STRAIGHT OBJECTIVE TYPE
This Section contains 10 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which Only One is Correct :
1. Two moles of an ideal gas _{(}_{γ} _{=} _{3}_{/} _{2}_{)} is made to expand reversibly and adiabatically to four times to its initial volume. The change in entropy of the system during expansion is :
[R = 2 cal K − 
1 
mol 
− 
1 

1
5.6cal K − 
− 1 

1
2.8 calK − 
− 
1 
, ln 2
=
0.7]
− 1
(B) mol
11.2cal K
− 1
(D) Zero
2. In a vessel of capacity 1 litre at 27°C for the first order decomposition of :
C
2
H Br(g)
5
→ C
2
H
4
(g) + HBr(g) ,
The initial pressure of 200 mm of Hg changes to 390 mm of Hg after infinite time, where all the reactant is consumed. If at 10 min, 0.2 g of NaOH was required to react completely with reaction mixture, then half life of reaction is :
(A) (B)
2.5
97.5
(C)
5
(D)
95
4. Which of the following statements is(are) correct?
I. The ionization energy of Be is lowest in its group and its compounds are predominantly covalent. The compounds of beryllium are covalent due to small size and more polarizing power of Be ^{2}^{+}
II.
.
III.
IV.
(A)
The compounds formed by Mg, Ca, Sr and Ba are predominantly divalent and ionic. The ionization energy of Be is low and its compounds are ionic.
I, II
(B)
II, III
(C)
II, IV
(D)
I, II, III
5. When haematite ore is burnt in air with coke along with lime at 200°C , the process not only produces steel but also produces an important compound (A), which is useful in making building materials. The compound (A) is : (A)
SiO _{2}
(B)
CaSiO _{3}
(C)
FeO
(D)
Fe _{2} O _{3}
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6. Identify the major product in the following reaction.
CN
Which of the following is (are) correct ?
I. Y dissolves is NaOH at 473K to give a salt which on hydrolysis gives X.
10. If you have a saturated solution of CaF _{2} , then which of the following is(are) true :
I. III.
(A)
(B)
II, III
II.
IV.
(C)
[Ca
2
+
]
=
2[F
−
]
[Ca
2
+
]
=
K
sp
4
1/ 3
I, III, IV
(D)
III, IV
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SECTION  II MULTIPLE CORRECT ANSWERS TYPE
This Section contains 5 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which one or More Choices may be Correct:
11. Which of the following order(s) is(are) correct ?
(A)
(B)
(C)
I _{2} < Br _{2} < Cl _{2} < F _{2}
H
2
O < H S
2
<
H Se
2
<
H
2
_{T}_{e}
Na
2
O
<
MgO < Al O
2
3
<
SiO
2
(D) Li < Be < B < C < N
(Bond energy)
(Acidic character)
(Acidic character)
(Ionisation energy)
12. For the cell (at 298 K)
Ag(s)  AgCl(s)  Cl
−
(aq)  AgNO (aq)  Ag(s)
3
Which of following is(are) correct :
(A) E
cell
=
E
0
Ag
+
Ag
−
E
0
Cl
−
AgCl
Ag
0.059
−
1
log
1
[Ag
+
][Cl
−
]
(B) The amount of AgCl(s) precipitated in anodic compartment will increase with the working of the cell
(C) The concentration of Ag ^{+} is constant in anodic compartment when the cell stops working
(D) When the cell emf will be zero, then
{Where [Ag ^{+} ] _{a} and [Ag ^{+} ] _{c} is amount Ag ^{+} ion in anodic compartment and in cathodic compartment}
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NH OH → HCl 2 P SO H 2 → 4 Q H 3 O + → Which of the following choices is(are) correct : 
R HNO 2 H + → → 35 C ° 
S 


_{O} 
R is : 
O
NH 2
O
O



_{O} 
S is : 
OH
14. Consider the following aqueous solutions and assume 100% ionization in electrolytes.
I.
0.1m urea
II.
0.04 m Al _{2} (SO _{4} ) _{3}
III.
0.05 m CaCl _{2}
IV.
0.005 m NaCl
The correct statement(s) regarding the above solutions is(are) :
(A) freezing point will be lowest for solution I
(B) freezing point will be highest for solution IV
(C) boiling point will be highest for solution II
(D) vapour pressure will be highest for solution II
(D) Curve B is for lighter gas but at same temperature
SPACE FOR ROUGH WORK
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SECTION  III SUBJECTIVE TYPE
This Section contains 5 Subjective Questions. Each question has an integer answer between 0 and 99. Fill the
answer bubbles in OMR Sheet appropriately and CAREFULLY. [Please note that an answer ‘5’ should be filled
as ‘05’ in the OMR sheet]
The cell reaction :
16. Zn
+
2Fe
3
+
2Fe
2
+
+
Zn
2
+
works at 25°C with
E
cell
= 1.2 V and at
45°C
with the
E
cell
= 1.70 V. Assuming
∆
r ^{S} ^{Θ}
to be constant in this temperature range, calculate
∆
r ^{S} ^{Θ}
in kJ/K.
[Assume
1F ≡10
5
coulombs].
17. Positronium is a species consisting of an electron bound to a positron. If the radius of its 2 ^{n}^{d} orbit is
x R
o
(where R _{0} is the radius of 1 ^{s}^{t} Bohr orbit of hydrogen). Then the value of x is _____.
18. One litre of oxygen was added to one litre of a mixture of carbon monoxide and carbon dioxide. When the whole mixture was burnt, its volume decreased to 1.6 litres finally. What is the mole ratio of carbon monoxide to the carbon dioxide in the original mixture ?
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PART  II (PHYSICS) 
70 MARKS 
SECTION  I STRAIGHT OBJECTIVE TYPE
This Section contains 10 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
Only One is Correct :
21. The activity of a radioactive element decreases to onethird of the original activity I _{0} in a period of nine years. After a further lapse of nine years, its activity will be
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24. As shown in figure AB is a rod of length 30 cm and area of cross section 1.0 cm ^{2} and thermal conductivity 336 W/mK. The end A and B are maintained at temperature _{2}_{0}_{°}_{C} _{a}_{n}_{d} _{4}_{0}_{°}_{C} , respectively. A point C of this rod is connected to a box, containing ice at _{0}_{°}_{C} , through a highly conducting wire of negligible heat capacity. The rate at which ice melts in the box is (assume latent heat of fusion for ice L _{f} = 80 cal/g
(A)
84 mg/s
(B)
84 g/s
(C)
20 mg/s
25. A spherical body of density ρ is floating halfimmersed in a liquid of density d. If _{σ} is the surface tension then diameter of the body is
^{(}^{A}^{)}
(B)
(C)
(D)
26. A ball is thrown with a velocity whose horizontal component is
12 ms
− 1
from a point 15m above the
ground and 6 m away from a vertical wall 18.75 m high in such a way so as just to clear the wall. At what
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27. A block is suspended from the roof of a truck by mean of a light pulley P and a light string with its ends fixed to the ceiling of the truck at points A and B. When the truck is at rest, the string make angles
_{6}_{0} ^{} each at A and B with the ceiling of the truck. Find the acceleration
of the truck so that the string between A and P becomes vertical in
equilibrium with respect to the truck.
(A)
2 m/s ^{2}
(B)
2.5 m/s ^{2}
(C)
5 m/s ^{2}
(D)
6 m/s ^{2}
28. In the circuit switch S is closed at time t = 0, the current through C and L would be equal after a time t equal to
(A) RC
(C) RC n2
29. In an experiment of resonance tube to measure the velocity of sound, first resonance occurs at l = 10cm from the open end of the tube. End correction of the tube is 1.0cm and the frequency of tuning fork is 700Hz
I. Velocity of sound is 308 m/s
II. Next resonance will occur at l = 32cm from open end of the tube
statement1
(B) Statement1 is True, Statement2 is True; Statement2 is not a correct explanation for Statement2.
(C) Statement1 is True, Statement2 is false.
(D) Statement1 is False, Statement2 is true.
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SECTION  II MULTIPLE CORRECT ANSWERS TYPE
This Section contains 5 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which one
or More Choices may be Correct:
31. A particle P is projected vertically upwards from level ground with an initial velocity of
100ms ^{−}
1
.
One second later another particle Q is projected vertically upwards from the same point with an initial
velocity of
90 ms
− 1
.
Before either of
the particle strikes the ground _{(}
g
=
10 ms
−
2
which
of
the
following is(are) the wrong statements ?
(A) Both particles are rest with respect to each other
(B) After 3s from launch of P, the distance between the particles is 95 m.
(C) When the particle P is at the highest position, particle Q is moving upward
(D) When the particle P is at highest point particle Q will be moving downwards
32. In the circuit shown in figure, circuit is closed at time t = 0. At time t = ln (2) second.
(A) Rate of energy supplied by the battery is 16 J/s
(B) Rate of heat dissipated across resistance is 8 J/s
a
b
(C) Rate of heat dissipated across resistance is 16 J/s
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33. In the adjoining circuit,
(A) The steady state potential of a w.r.t. respect b when s is open is 18V
(B) The final potential of b with respect to ground when switch is closed is zero volts
(C) The change in charge of capacitor c _{1} after switch is closed is _{−}_{3}_{6}_{µ}_{c}
(D) The change in charges on both capacitors is same after the switch is closed
34. In Bohr model of the hydrogen atom, let R, v and E represent the radius of the orbit, speed of the electron and the total energy of the electron respectively. Which of the following quantities are directly
35.
proportional to the quantum number n?
(A)
vR
(B)
RE
(C)
v/E
(D)
R/E
Suppose a nucleus X undergoes
_{α} − decay
225
95
X → Y + _{α} . The emitted _{α} _{−} _{p}_{a}_{r}_{t}_{i}_{c}_{l}_{e} is found to move
along a helical path in a uniform magnetic field B = 5T. Radius and pitch traced by theα _{}_{p}_{a}_{r}_{t}_{i}_{c}_{l}_{e} are
R = 5cm and P =
_{7}_{.}_{5}_{π}_{c}_{m}
respectively. [Given: m(Y) = 221.003 U, m(α ) = 4.003 U, m(n) = 1.009U,
m(p) = 1.008U, I U = 931 MeV/c ^{2}
=
1.6
×
10
− 27
kg
]
(A) Speed of the _{α} _{}_{p}_{a}_{r}_{t}_{i}_{c}_{l}_{e} after the decay is 1.5 × 10 ^{7} m/s approx.
(B) Speed of the _{α} _{}_{p}_{a}_{r}_{t}_{i}_{c}_{l}_{e} after the decay is 2.5 × 10 ^{7} m/s approx.
(C) Total energy released in the process is 4.7 MeV approx.
(D) Total energy released in the process is 13.05 MeV approx.
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SECTION  III SUBJECTIVE TYPE
This Section contains 5 Subjective Questions. Each question has an integer answer between 0 and 99. Fill the
answer bubbles in OMR Sheet appropriately and CAREFULLY. [Please note that an answer ‘5’ should be filled
as ‘05’ in the OMR sheet]
36. A particle moving in a straight line and its acceleration (a) varies with velocity(v) as
a = k
v
) 3 2
.
At origin particle has velocity 1m/s and has velocity 36m/s at displacement of 5m. Find the value of ‘K’.
37. A silver ball of radius 4.8 cm is suspended by a thread in a vacuum chamber. Ultraviolet light of wavelength 200 nm is incident on the ball for some time during which a total light energy of
1.0
×
10
−
7
J
falls on the surface. Assuming that on the average, one photon out of ten thousand photons is able to eject
a photoelectron, find the electric potential (in
× 10
−
1
V ) at the surface of the ball assuming zero potential
at infinity. 

A cube of side 
( 
π 
) 
1 / 4
m has one corner at the origin of coordinates and the edges from this corner
_{}
extend along the positive x, y and zaxes. Suppose the electric field in this region is given by _{E} _{=}_{2}_{x}_{y}_{i} .
The charge inside the cube is b ^{2} nC. Find the value of 1/b.
39. A sound source P revolving in a circle with speed 20 m/s (as shown in
the figure), emits sound of frequency 510 Hz. If the bandwidth of the
frequency observed at a stationary point O (which is far away from the
sound source) is found to be 8K. Find the value of K (assuming the
velocity of sound is 320 m/s).
40. A 0.1 kg mass is suspended from a wire of negligible mass. The length of the wire is 1 m and its crosssectional area is
4.9
×
10
−
7
2
m . If the mass is pulled a little in the vertically downward direction and
released, it performs simple harmonic motion of angular frequency
140rads ^{−}
1 . If the Young’s modulus of
the material of the wire is
n
×
10
9
Nm
−
2
, the value of n is
_____________.
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PART  III (MATHEMATICS) 
70 MARKS 
SECTION  I STRAIGHT OBJECTIVE TYPE
This Section contains 10 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
Only One is Correct :
41. If the points z, –iz and 1 are collinear then z lies on :
(A) 
A straight line 

Sum of the series 



− 

1 

(A) 
2 
log 2 

(A) 

(C) 
BA ^{T} = I _{n} 

(A) 
f 
( 
i 
2 
)+ f 
( ) i 

(a ^{2} – 2a) equal : 

(A) 
2800 
(B)
A circle
1
1
−
2 4
+
1
3
1
−
6
1
−
8
(B)
1
3
log 2
B is an idempotent matrix
+
5
−
1
(C)
1
−
An ellipse 

1 



+ 
∞ 

12 
...... 

log4 

AB = I _{n} 

None of these 
(D) 
A pair of st. lines 
(D) 
π – log2 
42. 1
10
(C)
43. Suppose A is an Idempotent Matrix, and B = I – A, where I is an identity matrix, then :
(B)
(D)
44. If f _{(}_{x}_{)} = x sin x , then
None of these
45. A triangle has 2 of its sides along axes, its third side touches the circle
− 2ax − 2ay + a
2
= 0 .
If the locus of the circumcentre of the triangle passes through the point (38, –37) then the value of
(B)
2810
(C)
2812
(D)
2820
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46. Let f : R→ R be such that f (1) = 3 and f ’ (1) = 6 the
(A)
1
(B)
e ^{1}^{/}^{2}
(C)
lim
x → 0
f
(
1 +
x
)
f
( 1 )
1 x
e ^{2}
equals :
(D)
e ^{3}
47. If _{f} _{(}_{x}_{)} _{=} _{}_{1}_{−} _{x} _{} , then the points where
sin
− 1
(A)
{0,
1}
(B)
_{{}_{0}_{,} _{−}_{1}_{}}
(
f  x
)
is nondifferentiable, are :
(C)
_{{}_{0}_{,}_{1}_{,} _{−}_{1}_{}}
(D)
None of these
48. r
Let
=
a
× b
sin x +
b
× c
cos y + 2
c
× a
where
a ,
b ,
c
are three noncoplanar vectors. If _{r}
perpendicular to _{a}
_{+} _{b} _{+} _{c}
, then minimum value of
2
x + y
2
, is :
(A)
π
2
(B)
2
π
4
(C)
5 π
2
4
(D) None of these
is
49. If the focal distance of an end of the minor axis of any ellipse (referred to its axes as the axes of x and y) is k and the distance between the foci is 2h then its equation is :
(A)
2
2
x
y
k
2
k
2
+
h
2
+
= 1
(B)
2
2
x
y
k
h
2
−
k
2
2 +
= 1
(C)
2
2
x
y
k
2
k
2
−
h
2
+
= 1
(D)
2
x
2 +
k
2
y
h
2
= 1
f
be
(
x
)
π
2
3 π
2
4
,
50. If
_{f} _{(}_{x}_{)} _{=} _{0}
lim
= −
then
x
→−π sin sin x
(A)
0
(
)
None of these
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SECTION  II MULTIPLE CORRECT ANSWERS TYPE
This Section contains 5 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which one
or More Choices may be Correct:
19 
∫ 
sin x 


8 
dx 

10 
^{1} 
+ x 


(B) 
less than 10 ^{–}^{6} 
(C) 

k 
k 
+ 
2 
k 
+ 
3 

x 
x 
x 

k 
k 
+ 
2 
k 
+ 
3 
= ( x 
)( 
)( 
) 

1 
1 


y 
y 
y 
− 
y 
y 
− 
z 
z 
− 
x 
+ 

k 
k 
+ 
2 
k 
+ 
3 
x 
y 

z 
z 
z 


(B) 
k = –1 
(C) 
more than 10 ^{–}^{7} (D) 
None of these 

1 


+ 


z 

k ^{3} + 3 = –24 
(D) 
k ^{2} + 
2k + 1 = 0 
53. An ellipse intersects the hyperbola 2x ^{2} –2y ^{2} = 1 orthogonally. The eccentricity of the ellipse is reciprocal of that of the hyperbola, if the axes of the ellipse are along the coordinate axes, then :
(A) Equation of ellipse is x ^{2} + 2y ^{2} = 2
(B)
The foci of ellipse are (±1, 0)
foci of ellipse are (±
(C) Equation of ellipse is x ^{2} + 2y ^{2} = 4
, 0)
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54.
55.
Let
α
=
i
e
2
π
11
,
λ
=
α
6
,
µ
=
α
7
,
β
=
α
2
, then :
(A)
Re
2
λ + λ
3
+ λ
4
+ λ
5
+ λ
1
= −
2
(B)
_{(}
µ − β
_{)}
2
µ − β
3
µ − β
.
.
.
.
.
.
9
µ − β
10
µ − β
(C)
_{(}
i − β
2
i − β
3
i − β
.
.
.
.
.
.
10
i − β
(D) None of these
_{=} _{i}
(where _{i} _{=}
Given a function ‘g’ which has a derivative g′(0) = 2 and
then:
g
x + y
= e
y
g
x
+ e
x
g
y
(A)
(C)
g(x) is increasing for all
_{x} _{∈}_{[}_{−}_{1}_{,} _{∞}_{)}
g′′(x)> 0 ∀ x
(B)
(D)
Range
of g(x) is
lim
g
(
x
)
=
x →
0
x
1
−
2
e
,
∞
for all x and y,
SPACE FOR ROUGH WORK
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SECTION  III SUBJECTIVE TYPE
This Section contains 5 Subjective Questions. Each question has an integer answer between 0 and 99. Fill the
answer bubbles in OMR Sheet appropriately and CAREFULLY. [Please note that an answer ‘5’ should be filled
as ‘05’ in the OMR sheet]
56. Let 0.8 the probability that a man aged 90 years will die in a year. If p is the probability that out of 4 men A _{1} , A _{1} , A _{3} , A _{4} each aged 90, A _{1} will die in a year and will be the first to die, find [10p], where [ ]
57.
denotes greatest integer _{≤} _{x} .
If :
π
2
(
)
sinθ log
(
sinθ
)
d θ
0
=
log
A
3
e
then A equals:
58. ABCD is a trapezium such that AB and CD are parallel and CB is perpendicular to them. If ∠ADB = θ,
51AB 117 
, is equal to 


λ − 
1 
λ 
+ 3 
− 2 
λ 
λ 
− 4 

+ 
4 
3 
λ 
BC = 45m CD = 30 and tanθ = 1/5 then
Let
p
4
λ
+
q
3
λ
+
r
+
s
λ
+
t
=
2
λ
+
λ
+
_________.
59.
1 be an identity in
_{λ} , where p, q, r, s and t are
constants. Then the value of t is ____________.
60. If the largest integer satisfying the equation  4 + log _{1}_{/}_{7} x = 2 +  2 +
x is a find value of _{(}
a + 2
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