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Author

Rinaldi
Binder
Hang 2011
Hu
Ishida

DepolimerizatNucleogel OA 5gIL cellulose+25g mL H2O


Fermentable sugars
cellulosic convShodex Asahipak GS-220 HQ, MH2P-50 4E precolumn
Catalytic con Bio-Rad Aminex HPX-87H
Hydrolysis of cellulose to produce glucose with solid acid catalysts in 1-butyl-3-methyl-imidazolium ch

tyl-3-methyl-imidazolium chloride ([bmIm][Cl]) with sequential water addition

J. Jacquemin, P. Husson, A. A. H. Padua and V. Majer 2005


H. Rodrigues and J. F. Brennecke, 2006
Wenjing Li, Zhaofu Zhang, Buxing Han,* Suqin Hu, Ye Xie, and Guanying Yang, 2007
Begona Gonzalez, Noelia Calvar, Elena Gomez, Eugenia A. Macedo, and A ngeles Domngue
Alberto Arce a,*, Ana Soto a, Juan Ortega b, Gisela Sabater 2008
Babak Mokhtarani *, Ali Sharifi, Hamid Reza Mortaheb, Mojtaba Mirzaei, Morteza Mafi,Fatemeh Sadegh
Di Wu, Bo Wu,* Yu M. Zhang,* and Hua P. Wang 2010
Yin-hui Gong,, Chong Shen,,, Ying-zhou Lu, Hong Meng, and Chun-xi Li, 2011
U. Domanska M. Krlikowska 2012
Di Wu, Bo Wu,* Yu M. Zhang,* and Hua P. Wang
Nan Nie, Danxing Zheng,* Li Dong, and Yun Li 2012
E. Quijada-Maldonado, S. van der Boogaart, J.H. Lijbers, G.W. Meindersma, A.B. de Haan
Sebastian Fendt, Sasisanker Padmanabhan, Harvey W. Blanch, and John M. Prausnitz*

Density and viscosity of several pure and water-saturated ionic liquids


Temperature and Composition Dependence of the Density and Viscosity of Binary Mixtures of Water +
Effect of Water and Organic Solvents on the Ionic Dissociation of Ionic Liquids
Synthesis and Physical Properties of 1-Ethyl 3-methylpyridinium Ethylsulfate and Its Binary Mixtures w
Mixing properties of tris(2-hydroxyethyl)methylamonium methylsulfate, water,and methanol at 298.15
Density and viscosity of pyridinium-based ionic liquids and their binary mixtures with water at several
Density, Viscosity, Refractive Index and Conductivity of 1-Allyl-3-methylimidazolium Chloride + Water
Computational studies of room temperature ionic liquid-water mixtures (A
Viscosity and Density Measurements for Six Binary Mixtures of Water (Methanol or Ethanol) with an Io
Density and Viscosity of Binary Mixtures of Thiocyanate Ionic Liquids +Water as a Function of Tempera
Density, Viscosity, Refractive Index and Conductivity of 1-Allyl-3-methylimidazolium Chloride + Water
Thermodynamic Properties of the Water + 1(2-Hydroxylethyl)-3-methylimidazolium Chloride System

Experimental densities, dynamic viscosities and surface tensions of the ionic liquids series 1-ethyl-3-m
Viscosities of Acetate or Chloride-Based Ionic Liquids and Some of Their Mixtures with Water or Other

Density and viscosity of several pure and water-saturated ionic liquids


Density and Viscosity of Binary Mixtures of Thiocyanate Ionic Liquids + Water as a Function of Tempe

(1-butyl-3-methylimidazolium hexafluorophosphate, 1-butyl-3-methylimidazolium tetrafluoroborate, 1


1-ethyl-3-methylimidazolium ethylsulfate, 1-ethyl-3-methylimidazolium trifluoroacetate, and 1-ethyl-3
1-n-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]), 1-n-butyl-3-methylimidazolium te
[empy][EtSO4]
tris(2-hydroxyethyl) methylamonium methylsulfate
1-butylpyridinium tetrafluoroborate [BuPy][BF4] and 1-octylpyridinium tetrafluoroborate [OcPy][BF4],
amimCl

1-butyl-3-methylimidazolium dimethylphosphate ([BMIM][DMP]) or 1-ethyl-3-methylimidazolium dime


1-butyl-3-methylimidazolium thiocyanate [BMIM][SCN], or 1-butyl-4-methylpyridinium thiocyanate [BM
amimCl

,
amide and their binary and ternary mixtures with water and ethanol at T = (298.15 to 343.15 K)

1-ethyl-3-methylimidazolium acetate [Emim][Ac], 1-butyl-3-methylimidazolium acetate [Bmim][Ac], a


1-butyl-3-methylimidazolium dicyanamide [Bmim] [N(CN)2]

ethyl-3-methylimidazolium butyltrimethylammonium bis(trifluoromethylsulfonyl)imidebis(trifluoromethylsulfony

um trifluoroacetate ([bmim][CF3CO2])

R][SCN], or 1-butyl-1-methylpiperidinium thiocyanate [BMPIP][SCN]

idebis(trifluoromethylsulfonyl)imide, 1-ethyl-3-methylimidazolium ethylsulfate and

emimAc
H2O

170.21 g/molg
18 g/molg

H2O initial emimAc


10243.5 ppm
1.02435 %

Prausnitz

25 C
Ww

wt %
0.023
0.045
0.084
0.192
0.374
0.556
1

2.3
4.5
8.4
19.2
37.4
55.6
100

viscosity (Pas)
0.122
0.081
0.057
0.032
0.012
0.004
0.000089

Budtova
10-60 en intervalos de 5C

C water (wt%)
1.02435
3
6
7
9
10
12
15
18
20

Froba density
20
25
30
35
40
50
55
60
65

Yo
1.10269
1.09968
1.09664
1.0936
1.09057
1.08452
1.08152
1.07852
1.07554

0.5%wt H2O
Temperature (Cdensity
20.000
29.999
40.000
50.000
60.000
70.001
80.000
90.000

(g/cm3)
1.0999
1.0938
1.0876
1.0817
1.0758
1.0698
1.0640
1.0586

70
75
80
85
90

1.07257
1.0696
1.06665
1.06371
1.06078

100.001

1.0526

YO
25-50-60-70-80-90-100 C
gIL + H2O
wt %
9.9
9.9
9
1

1.02
2.3
1.7
0.51

g necesito H2 g IL aado
mol IL
0.10098
0.05757018
0.2277
0.12672 0.05682569
0.153
0.05197697
0.0051
0.00584513

1.11
1.1
1.09
1.08
1.07
1.06
1.05
1.04
1.03
1.02

Frb
a

1.07

Frb
a

1.06
1.05
1.04
1.03
1.02
10

20

30

40

50

60

70

80

90

100

110

mol H2O
% mol H2O
0.00561
10%
0.01265
22%
0.0085
16%
0.00028333
5%

Frb
a

Frb
a

110

4/25/2013

Cojoconlajeringayagujade10mL8mL.

H2Oinicial:

3964

1KarlFisher

H2Ofinal:

4335.2

2AnlisisViscosidadydensidad

H2Ofinal:

4135.6

H2Oinicial:

4041.9

H2Ofinal:

5107.5

Medidadensidadyviscosidad
T
19.999
20.001
20.000
29.999
29.999
29.999
40.000
40.000
40.000
50.000
50.000
50.000
60.000
60.000
60.000
70.001
70.001
70.001
80.001
79.999
80.001
90.001
90.001
89.999
100.001
100.001
100.001
50.000
49.999
49.999
20.000
19.998
19.999
0.001

Density (g/cm3)
1.0999
1.0999
1.0999
1.0938
1.0938
1.0938
1.0878
1.0877
1.0873
1.0817
1.0817
1.0817
1.0757
1.0758
1.0758
1.0699
1.0698
1.0698
1.064
1.064
1.064
1.0586
1.0586
1.0586
1.0526
1.0526
1.0526
1.082
1.082
1.082
1.1003
1.1003
1.1003

Viscosity (mPas)
174.3000
174.3200
174.3200
93.0140
93.0110
92.9930
55.2490
55.2540
55.2810
35.6310
35.6380
35.6390
24.4960
24.4930
24.4890
17.7110
17.6410
17.6350
13.262
13.263
13.26
10.251
10.249
10.248
8.1973
8.2363
8.236
35.512
35.512
35.51
173.33
173.32
173.3
979.3

ppm

muestra:0,3359g

Elbotedondeserecogenlosresiduosestabaabiertoalaatmsfer

ppm

muestra:0,1448g

Seacablamuestracuandofuimosamedira90C

ppm

0,1124gmuestra

EsteLIemimAc,lometoenlaestufadevaco72ha80C

ppm

0,2011gmuestra

ppm
5/6/2013
Pesoinicial
Pesofinal

177.9074
177.9022

Viscosity (mPas)
174.313
93.006
55.261
35.636
24.493
17.662
13.262
10.249
8.223
35.5113333333
173.317

desviation
0.100%
0.000%
0.000%
0.000%
0.000%
0.000%
0.115%
0.115%
0.000%
0.0005773503
0

desviation
0.000%
0.000%
0.026%
0.000%
0.006%
0.006%
0.000%
0.000%
0.000%
0
0

T
20.000
29.999
40.000
50.000
60.000
70.001
80.000
90.000
100.001
0

Viscosity(mPas)
174.3133
93.0060
55.2613
35.6360
24.4927
17.6623
13.2617
10.2493
8.2232
979.3

Viscosity(mPas)
0.1743133333
0.093006
0.0552613333
0.035636
0.0244926667
0.0176623333
0.0132616667
0.0102493333
0.0082232
0.9793

T
50.000
50.000
50.000
50.000
49.999
49.999
19.999
20.001
20.000
20.000
19.998
19.999

Density (g/cm3)
1.0817
1.0817
1.0817
1.082
1.082
1.082
1.0999
1.0999
1.0999
1.1003
1.1003
1.1003

Viscosity (mPas)
35.6310
35.6380
35.6390
35.512
35.512
35.51
174.3000
174.3200
174.3200
173.33
173.32
173.3

T
Density (g/cm3)
20.000
1.100
29.999
1.094
40.000
1.088
50.000
1.082
60.000
1.076
70.001
1.070
80.000
1.064
90.000
1.059
100.001
1.053
49.9993333333
1.082
19.999
1.100

H2O
3964

5107.5

desviation
0.000%

0.058%

0.100%

0.100%

siduosestabaabiertoalaatmsfera,

mosamedira90C

estufadevaco72ha80C
g
g

>

incertidumbresubidabajada
T
20
50

viscosity (m Pas)

desviation
1.155%
1.136%
1.721%
0.436%
0.351%
4.225%
0.153%
0.153%
2.243%
0.0011547005
0.0152752523

esmuchomsqueloinicial
4668.2
ppm

density
-0.04%
-0.03%

viscosity
0.58%
0.35%

Viscosity emimAc
1.2
1
0.8
0.6
0.4

Density (g/cm3)
1.0817

desviation
0.000%

Viscosity
(mPas)
0.2
35.636
0
0.000

20.000

desviation
0.436%
40.000
60.000
80.000
Temperature (C)

1.0820

0.000%

35.511

0.115%

1.0999

0.000%

174.313

1.155%

1.1003

0.000%

173.317

1.528%

100.000

120.000

mAc

100.000

120.000

KF

Sample

H2O ppm
0.0772
7330
0.0793
7109
0.0701
7389.3

T (C)
viscosity mPas
density g/cm3
24.999
127.37
1.0983
25
127.38
1.0983
24.999
127.37
1.0983
29.999
94.373
1.0953
29.998
94.376
1.0952
30
94.388
1.0952
39.999
55.94
1.0892
40
55.93
1.0982
40
55.927
1.0982
50
35.983
1.0831
50
35.977
1.0831
50
35.972
1.0831
60
24.663
1.0772
59.998
24.658
1.0771
60
24.655
1.0771
70
17.776
1.0712
70.001
17.775
1.0712
70.001
17.772
1.0712
80
13.343
1.0653
80
13.339
1.0653
80.001
13.337
1.0653
89.999
10.349
1.0595
90.001
10.346
1.0595
89.999
10.342
1.0595
99.999
8.2502
1.0538
100.001
8.2467
1.0538
79.999
13.308
1.0653
79.999
13.304
1.0653
79.999
13.3
1.0653
59.997
24.505
1.0771
59.999
24.494
1.0772
60
24.484
1.0772
49.999
35.61
1.0831
49.999
35.596
1.0832
49.999
35.583
1.0832
30
92.43
1.0953
29.999
92.351
1.0953
30
92.335
1.0953

H2O

0.72761

Promedio
Temperature
24.999
29.999
40.000
50.000
59.999
70.001
80.000
90.000
100.000
79.999
59.999
49.999
30.000
24.9993333

Subida

Bajada

25
30
50
60
80

Incertidumbre subida bajad


T
0.0000%
0.0022%
0.0020%
0.0011%
0.0017%

25
24.999
24.999

124.06
124.03
123.99

1.0983
1.0983
1.0983

wt %

Promedio
desviacion
density (g/c viscosity (m Temperaturedensity (g/c
127.3733
1.098 0.00057735
0.0057735
94.379
1.095
0.001 0.00793725
55.932
1.095 0.00057735 0.00680686
35.977
1.083
0 0.00550757
24.659
1.077
0.0011547 0.00404145
17.774
1.071 0.00057735 0.00208167
13.340
1.065 0.00057735 0.00305505
10.346
1.060
0.0011547 0.00351188
8.248
1.054 0.00141421 0.00247487
13.304
1.065
0
0.004
24.494
1.077
0 0.00989949
35.596
1.083
0 0.01350309
92.372
1.095 0.00057735 0.05086256
124.026667
1.0983 0.00057735 0.03511885

rtidumbre subida bajada


density
viscosity
0.0000%
2.6983%
0.0061%
-2.1265%
-0.0062%
1.0590%
-0.0031%
0.6664%
0.0000%
0.2674%

visosity (mPas)
0
5.7735E-005
0.00519615
0
5.7735E-005
0
0
0
0
0
7.0711E-005
5.7735E-005
0
0

25/06/2014 Maana
KF
Sample (g)

Water (ppm)
0.0443
0.0229
0.0196
0.0184
0.0118

7843
12558.9
11489.8
12669.7
15121.2

Temperature (C)
density (g/cm3)
viscosity (mPas)
24.999
1.0981
123.72
25.001
1.0981
123.68
25.001
1.0981
123.67
24.999
1.0981
123.59
25.001
1.0981
123.19
25.001
1.0981
123.18
25.001
1.0981
123.17
50.000
50.000
50.001
50.000
50.001

1.083
1.083
1.083
1.083
1.083

35.23
35.23
35.223
35.216
35.217

80.001
80.001
79.999
79.999

1.0652
1.0652
1.0652
1.0652

13.163
13.164
13.165
13.164

99.999
100.000
100.000

1.0538
1.0538
1.0538

8.1481
8.1457
8.1445

0.0129
0.0148
0.0089
0.0205
0.0194
0.0679

Water (ppm)
33134.2
15875
22020.4
13712.1
13470.7
12502.8

KF
Sample (g)

25/06/2014 Tarde

Incertidumbre 1%
KF

Sample (g)
0.1142
0.0815
0.0117
0.1717

Water (ppm)
11025.2
9402.7
9102.5
8880.4

Temperature (C)
density (g/cm3)
viscosity (mPas)
25.000
1.0984
120.260
25.000
1.0984
119.85
25.001
1.0984
119.71
24.999
1.0984
119.62
50.000
1.0833
34.513
50.000
1.0833
34.491
50.000
1.0833
34.474
60.001
1.0773
23.737
60.000
1.0772
23.724
60.001
1.0772
23.714
70.001
1.0713
17.156
69.999
1.0713
17.148
70.001
1.0713
17.143
79.999
1.0654
12.903
80.001
1.0654
12.898
80.000
1.0654
12.894
90.001
1.0596
10.025
90.000
1.0594
10.183
90.000
1.0595
10.187
90.000
1.0595
10.186
100.000
1.0538
8.1288
99.999
1.0538
8.1281
100.001
1.0538
8.1273
79.999
1.0653
13.113
80.001
1.0653
13.112
79.998
1.0653
13.112
49.998
1.0853
35.091
49.999
1.0832
35.092
49.998
1.0832
35.09
25.000
1.0983
120.13
24.998
1.0983
120.22
25.001
1.0983
120.63

Subida

Bajada

KF al terminar
Sample mass
0.136
0.144
0.00969
0.1152
0.1029

emimAc:H2O 1%wt
Temperature (C)
25.000
50.000
60.001
70.000
80.000
90.000
100.000
79.999
49.998
25.000

Promedio
desviacion
density (g/cm3) viscosity (mPas) Temperature (C)
1.0984
119.860
0.0008164966
1.0833
34.493
0
1.0772
23.725
0.0005773503
1.0713
17.149
0.0011547005
1.0654
12.898
0.001
1.0595
10.145
0.0005
1.0538
8.128
0.001
1.0653
13.112
0.0015275252
1.0839
35.091
0.0005773503
1.0983
120.327
0.0015275252
Prausnitz
25 C
wt %

Ww
0.023
0.045
0.084
0.192
0.374
0.556
1

2.3
4.5
8.4
19.2
37.4
55.6
100

viscosity (Pas)
0.122
0.081
0.057
0.032
0.012
0.004
0.000089

25 C
Ww

KF al terminar
Water `ppm
15288.5
12467.2
10455.6
9563.8
10243.5

H2O

1.0087633333

desviacion
density (g/cm3)
0
0
0.000057735
0
0
8.16496581E-005
0
0
0.0012124356
0

visosity (mPas)
0.28296054
0.01955335
0.01153256
0.00655744
0.00450925
0.08018468
0.00075056
0.00057735
0.001
0.26652079

25 C
wt %
viscosity (Pas)
1.0087633333

%wt

Desviacion subida bajada


T (C)
25
50
80

0.001%
0.003%
0.001%

Desviacion subida bajada


density (g/cm3)
viscosity (mPas)
0.009%
-0.389%
-0.055%
-1.735%
0.009%
-1.659%

KF

Sample (g) Agua ppm


0.0588
11575.4
0.072
11133.5
0.0659
11552

Temperature (density (g/cm viscosity (mPas)


25
1.0982
121.75
24.999
1.0983
121.56
25.001
1.0983
121.42
30.001
1.0952
90.217
29.999
1.0952
90.181
30
1.0952
90.13
29.999
1.0952
90.078
40
1.0892
53.748
39.998
1.0891
53.712
40
1.0891
53.659
40
1.0891
53.625
50.001
1.0831
34.698
50.001
1.0831
34.673
50.001
1.0831
34.651
60.002
1.0771
23.865
60
1.0771
23.853
59.999
1.0771
23.844
70.001
1.0712
17.256
70.001
1.0711
17.249
70.001
1.0711
17.243
80.001
1.0653
12.987
80.001
1.0652
12.983
80.001
1.0652
12.983
79.998
1.0652
12.979
90
1.0594
10.1
90
1.0594
10.097
90
1.0594
10.094
100.002
1.0537
8.0718
100.002
1.0537
8.069
79.998
1.0652
12.952
79.999
1.0652
12.95
80
1.0652
12.948
59.996
1.077
23.684
59.998
1.0771
23.679
49.998
1.083
34.281
49.999
1.0831
34.275
50
1.0831
34.269
29.999
1.0952
87.817

Promedio
Temperature
25.000
30.000
40.000
50.001
60.000
70.001
80.000
90.000
100.002
79.999
59.997
49.999
29.999
24.9995

Subida

Bajada

25
30
50
60
80

Incertidumbre subida bajada


T
0.0020%
-0.0025%
0.0040%
0.0056%
0.0016%

29.999
29.999
25
24.999

1.0952
1.0952
1.0982
1.0982

87.9
87.837
117.53
117.53

H2O

1.14203 %wt

Promedio
desviacion
density (g/c viscosity (m Temperaturedensity (g/c
1.0983
121.577
0.001 5.7735E-005
1.095
90.152 0.00057735
0
1.089
53.6860
0.001 5.7735E-005
1.083
34.6740
0
0
1.0771
23.854 0.00152753
0
1.0711
17.249
0 5.7735E-005
1.0652
12.983
0.0015
0.00005
1.0594
10.097
0
0
1.054
8.070
0
0
1.065
12.950
0.001
0
1.077
23.682 0.00141421 7.0711E-005
1.083
34.275
0.001 5.7735E-005
1.095
87.851
0
0
1.0982
117.53 0.00070711
0

rtidumbre subida bajada


density
viscosity
0.0061%
3.4431%
0.0000%
-2.5514%
0.0031%
1.1507%
0.0046%
0.7231%
0.0023%
0.2542%

visosity (mPas)
0.16563011
0.05150081
0.05468089
0.02351595
0.01053565
0.00650641
0.00326599
0.003
0.0019799
0.002
0.00353553
0.006
0.04331666
0

6/26/2014
Muestra inicial
9.9961 g IL+H2O
Solucin inicia 10087.6333 ppm
Quiero 2.3 %wt +- 23000ppm
ma Water nec 0.12795008

gIL + H2O
wt %
9.9961
9.9961

1.02
2.3

Aad por pes0.1218 g H2O from Sigma Aldrich que me dej


Despus de 3h en el ultrasonidos analic KF
KF al empezar
Sample mass Water `ppm
0.087
2228.5
0.097
21438.3
0.0831
21174.6

Temperature (density (g/cm viscosity (mPas)


25.001
1.0992
102.33 se vacio la conexin, tuve que aadir mucha muestra, no es
24.999
1.0992
102.86
25.001
1.0992
103.28
emimAc
H2O

170.21 g/molg
18 g/molg

7/1/2014
KF
g IL + H2O
ppm H2O
wt %
g H2O
5.6299
11420.3
1.14203 0.06429515
terico
6.1005 15588.0906 1.55880906 0.09509515
Degas 70 min
6.1
14616.425
1.4616425 0.08916019
0.089
0.16558756

Temperaturedensity (g/c viscosity (mPas)


25
1.0986
110.59
24.999
1.0986
110.18
24.999
1.0986
110.05
29.999
1.0956
82.454
29.999
1.0956
82.378
30.001
1.0956
82.315
29.999
1.0956
82.233
40
1.0896
49.749
40
1.0895
49.728

40
50.001
50
50
60.001
60.001
59.999
70
70
70
80.001
80
79.998
90
90.001
89.999
100.001
79.996
79.999
79.998
59.998
59.999
50
49.998
29.999
30
25.001
24.998

1.0895
1.0836
1.0835
1.0835
1.0776
1.0775
1.0775
1.0716
1.0716
1.0716
1.0657
1.0657
1.0657
1.0599
1.0599
1.0598
1.0541
1.0656
1.0657
1.0657
1.0775
1.0775
1.0835
1.0835
1.0956
1.0957
1.0987
1.0987

49.696
32.466
32.448
32.426
22.5
22.486
22.481
16.364
16.358
16.351
12.371
12.367
12.364
9.6531
9.6504
9.648
7.733
12.335
12.333
12.331
22.312
22.309
32.05
32.045
80.183
80.175
106.4
106.41

g necesito H2O
g IL aado
0.10196022
0.2299103 0.12795008

218 g H2O from Sigma Aldrich que me dej Jos Juan

n, tuve que aadir mucha muestra, no es normal. Segn Geraldine haba burbujas, y para eliminarlas el Anton

g H2O aado

mol IL (1)
0.03269846
0.03528233
0.03531426

mol H2O (2)


0.003571953
0.005283064
0.004953344

100 X2
10.923916981
14.973682839
14.026470742

Temperature
24.999
30.000
40.000
50.000
60.000
70.000
80.000
90.000

Promedio
density (g/cm3viscosity (m
1.0986
110.273
1.096
82.345
1.090
49.7243
1.084
32.4467
1.0775
22.489
1.072
16.358
1.066
12.367
1.060
9.651

osity (mPas)

Subida

Subida

100.001
79.998
59.999
49.999
29.9995
24.9995

Bajada

25
30
50
60
80

1.054
1.066
1.078
1.084
1.09565
1.0987

7.733
12.333
22.311
32.048
80.179
106.405

Incertidumbre subida bajada


T
density
viscosity
-0.0007%
-0.0091%
3.6355%
0.0000%
0.0046%
-2.6304%
0.0027%
0.0031%
1.2302%
0.0031%
0.0031%
0.7937%
0.0025%
0.0031%
0.2776%

para eliminarlas el Anton Paar succiona muestra

Temperature
0.00057735
0.001
0
0.00057735
0.001154701
0
0.001527525
0.001

desviacion
density (g/c
0
0
5.7735E-005
0.02003331
5.7735E-005
0
0
5.7735E-005

visosity (mPas)
0.2818392
0.09383319
0.02668957
5.7735E-005
0.00984886
0.00650641
0.00351188
0.00255147

0.001527525 5.7735E-005
0.002
0.000707107
0 0.00212132
0.001414214
0 0.00353553
0.000707107 7.0711E-005 0.00565685
0.00212132
0 0.00707107

0.1023
0.0656
0.0725
0.0805
0.0763

14806.5
14976.8
15159.1
15244.7
14916.2
1.502066

Temperatureviscosity (m density (g/cm3)


25.001
113.79
1.0988
25
113.76
1.0988
24.998
113.71
1.0988
30
85.02
1.0958
30
84.953
1.0958
30.001
84.908
1.0958
40
51.14
1.0898
39.999
51.093
1.0897
40
51.071
1.0897
50
33.271
1.0837
50
33.236
1.0837
50
33.22
1.0837
60.001
22.996
1.0777
59.999
22.987
1.0777
60.002
22.975
1.0777
70
16.692
1.0718
70.002
16.687
1.0717
70.001
16.8
1.0717
80
12.601
1.0659
80
12.596
1.0658
79.998
12.592
1.0658
90.001
9.8185
1.06
89.99
9.8161
1.06
90.001
9.8138
1.06
100.001
7.8595
1.0543
99.999
7.8566
1.0543
79.997
12.563
1.0658
79.999
12.562
1.0659
80.001
12.559
1.0659
59.997
22.821
1.0777
59.999
22.817
1.0777
59.999
22.816
1.0777

0.0835
0.0851
0.0842

16763.9
16791
16616.2
1.67237

Promed
Temperature (C)
25.000
30.000
40.000
50.000
60.001
70.001
79.999
89.997
100.000
79.999
59.998
50.000
30.000
24.9993333333

Subida

Bajada

25
30
50
60
80

Incertidumbre subida bajada


T
0.0013%
-0.0022%
0.0007%
0.0039%
0.0004%

49.999
49.999
50.001
29.998
30
30.001
25
24.999
24.999

32.878
32.874
32.874
83.019
83.011
83.007
110.51
110.5
110.49

1.0837
1.0837
1.0837
1.0958
1.0958
1.0958
1.0988
1.0989
1.0988

Promedio
desviacion
viscosity (mPas) density (g/cm3) Temperature (C) visosity (mPas)
113.8
1.099
0.15%
4.04%
84.960
1.096
0.06%
5.64%
51.101
1.090
0.06%
3.52%
33.242
1.084
0.00%
2.61%
22.986
1.078
0.15%
1.05%
16.726
1.072
0.10%
6.38%
12.596
1.066
0.12%
0.45%
9.816
1.060
0.64%
0.24%
7.858
1.054
0.14%
0.21%
12.561
1.066
0.20%
0.21%
22.818
1.078
0.12%
0.26%
32.875
1.084
0.12%
0.23%
83.012
1.096
0.15%
0.61%
110.5
1.0988333333
0.06%
1.00%

bre subida bajada


viscosity

density
2.9442%
-2.2928%
1.1040%
0.7309%
0.2779%

-0.0030%
0.0000%
0.0000%
0.0000%
-0.0031%

cion
density (g/cm3)
0.00%
0.00%
0.01%
0.00%
0.00%
0.01%
0.01%
0.00%
0.00%
0.01%
0.00%
0.00%
0.00%
0.01%

H2O: 1.725 wt%


Temperature (C) density (g/cm3) viscosity (mPas)
24.999
1.0987
108.78
50.001
1.0836
32.469
60
1.0776
22.548
70.001
1.0716
16.425
79.999
1.0657
12.438
89.999
1.0599
9.7243
100.001
1.0542
7.8058
80
1.0657
12.436
49.997
1.0835
32.475
24.998
1.0987
108.78

Sample g

Water ppm
0.0777
0.0838

H2O

1.72515 wt%

17121
17382

Incertidumbre subida bajada

25
60
80

rtidumbre subida bajada

Density
viscosity
0.004%
0.000%
0.000%
0.007%
0.009%
-0.027%
-0.001%
0.000%
0.016%

7/4/2014
H2O
0.70995 %Wt
Temperatureviscosity (m density (g/cm3)
24.999
126.98
1.0982
30.001
93.819
1.0952
40.001
55.524
1.0891
50.002
35.698
1.0831
60.002
24.455
1.0772
70.001
17.631
1.0712
79.999
13.24
1.0654
89.999
10.277
1.0595
100
8.1965
1.0538
79.997
13.162
1.0653
59.999
24.113
1.0772
50
34.967
1.0832
29.996
89.961
1.0954
24.998
120.62
1.0984

25
30
50
60
80

Incertidumbre
Temperature
0.004%
0.017%
0.004%
0.005%
0.003%

KF

Incertidumbre
viscosity (m density (g/cm3)
5.273%
-0.018%
4.112%
-0.018%
2.091%
-0.009%
1.418%
0.000%
0.593%
0.009%

Sample g
Water ppm
0.1098
7212.2
0.1083
7026.6
0.1125
6896.5
0.0551
7262.7
7099.5
0.0742
0.0921
0.1082
0.087
0.0991
0.025

10285.2
10094.9
9060.3
8247.2
8168.2
7503.5
8893.21667

7/7/2014

LI mezclado 60 min degas


Sample g
Water ppm
0.053
11148.6
0.0641
11137.3
0.063
10866.8
0.0662
10812.5
0.0698
10939.4
H2O
1.08729 %wt
Temperatureviscosity (m density (g/cm3)
25
120.25
1.0983
30.001
89.512
1.0954
40
53.481
1.0893
49.999
34.585
1.0834
59.999
23.807
1.0774
70.002
17.22
1.0715
80
12.968
1.0656
89.999
10.092
1.0598
100
8.0681
1.0541
79.999
12.95
1.0656
59.997
23.693
1.0774
49.999
34.317
1.0834
29.999
88.05
1.0955
24.998
117.86
1.0986

KF final
Sample g
Water ppm
0.1076
13600
0.0428
13989.3
0.1003
13730.2
H2O
1.37731667 % wt

Incertidumbre
Temperatureviscosity (m density (g/cm3)
0.008%
2.028%
-0.027%
0.007%
1.633%
-0.009%
0.000%
0.781%
0.557%
0.003%
0.481%
0.000%
0.001%
0.139%
0.000%

Vial sin tapa


LI 11000 ppm

10.0097
4.195 g --> g H2O
H2O
1.08729 %wt
g H2O
0.04561182

LI 7000ppm

1.415 g --> g H2O


H2O
0.70995 %wt
g H2O
0.01004579

masa total

g IL+ H2O
g H2O
% water
5.61 0.05565761
1.0

gIL + H2O
wt %
5.61
5.61

g necesito H2 g IL aado
2.3
0.12903
1.0 0.05565761 0.07337239

KF inicial
Sample
H2O ppm
0.0624
23724.3
0.0969
23621.7
0.077
23705.3
H2O
2.36837667 % wt
Temperatureviscosity (m density (g/cm3)
25.001
101.58
1.0996
30
76.585
1.0966
40
46.729
1.0905
50
30.775
1.0845
60.001
21.472
1.0785
70.002
15.693
1.0726
79.999
11.909
1.0667
90
9.3188
1.0608
100.002
7.4792
1.0551
79.998
11.867
1.0667
59.999
21.307
1.0785
50
30.437
1.0845
29.999
74.867
1.0966
25
98.737
1.0997

25
30
50
60
80

2.03104339

KF final
Sample
H2O ppm
0.0828
24151.6
0.0904
24165.5
0.0367
24207.2
H2O final

2.41747667 % wt

Incertidumbre
Temperatureviscosity (m density (g/cm3)
0.004%
2.879%
-0.009%
0.003%
2.243%
0.000%
0.000%
1.110%
0.556%
0.003%
0.774%
0.000%
0.001%
0.354%
0.000%

% agua

Vial sin tapa


LI 24174ppm

LI 7000ppm

masa total

10.0097
3.8736 g --> g H2O
H2O
2.41747667 %wt
g H2O
0.09364338
1.5195 g --> g H2O
H2O
0.70995 %wt
g H2O
0.01078769
g IL+ H2O
g H2O
% water
5.3931 0.10443107
1.9

gIL + H2O
5.3931
5.3931
90 min sonicador

KF
Sample
0.042
0.0509
0.0519
H2O
Temperature
25.001
30
39.999
50
60
69.999
80.001
90.001
100.001
79.997
59.998
49.998
29.999
24.999

wt %

g necesito H2 g IL aado
1.9 0.10443107
3.5
0.1887585 0.08432743

KF final
Sample
Water ppm
0.0436
36412.5
0.0325
35358.6
0.0505
36652.4
0.0744
39667.6
0.0675
39729.2
0.073
38924.8
0.0415
38035.5
0.0364
39193.6
0.0709
38685.8
3.80733333

min sonicador

Water ppm
35850.2
35856.6
35534
3.57469333 %wt
viscosity (m density (g/cm3)
88.615
1.1004
67.467
1.0974
41.806
1.0914
27.849
1.0854
19.617
1.0795
14.436
1.0735
11.022
1.0677
8.6661
1.0618
6.984
1.056
10.982
1.0676
19.436
1.0795
27.476
1.0855
65.409
1.0976
82.288
1.1006

25
30
50
60
80

Incertidumbre
Temperatureviscosity (m
0.008%
7.689%
0.003%
3.050%
0.004%
1.358%
0.003%
0.931%
0.005%
0.364%

6.11031343 % agua

rtidumbre
density (g/cm3)
-0.018%
-0.018%
0.547%
0.000%
0.009%

Vial sin tapa


LI ppm

LI 7000ppm

masa total

10.0097
2.435 g --> g H2O
H2O
3.80733333 %wt
g H2O
0.09270857
3.13861 g --> g H2O
H2O
0.72627 %wt
g H2O
0.02279478
g IL+ H2O
g H2O
% water
5.57361 0.11550335
2.1

gIL + H2O
5.57361
5.57361
90 min sonicador

KF inicial
Sample
0.1172
0.0558
0.0534
0.0685
0.0978
0.0688
H2O
Temperature
25
30.001
40.001
50.001
60.001
70
80.001
89.998
100
79.998
59.997
49.999
29.999
24.999

wt %

g necesito H2 g IL aado
2.1 0.11550335
5.0
0.2786805 0.16317715

min sonicador

Water ppm
54844.6
56577.5
55218.1
54354.9
53237.8
53441.2
5.461235 %wt
viscosity (m density (g/cm3)
75.531
1.1018
58.318
1.0989
36.927
1.0928
24.966
1.0868
17.767
1.0808
13.185
1.0748
10.127
1.0689
7.9979
1.0629
6.4675
1.0571
10.091
1.0688
17.629
1.0807
24.69
1.0868
57.111
1.0988
73.709
1.1018

Sample
0.1116
0.1132
0.0741
0.1162

25
30
50
60
80

KF final
Water ppm
58319.4
54043.2
54244.9
54390.3
5.524945

Incertidumbre
Temperatureviscosity (m
0.004%
2.472%
0.007%
2.070%
0.004%
1.118%
0.007%
0.783%
0.004%
0.357%

#DIV/0! % agua

rtidumbre
density (g/cm3)
0.000%
0.009%
0.564%
0.009%
0.009%

0.0461
0.0449
0.0378
0.0471
0.0428
H2O ini
Temperature (C)
25
30
40
50.001
60.002
70.001
80.002
90.002
100.003
90
79.998
69.999
60
49.998
40
29.998
25

8469.3
8350
8255.2
8140.6
8408.9
0.83248 % wt
viscosity (mPas) density (g/cm3)
123.48
1.0983
91.71
1.0953
54.599
1.0892
35.24
1.0832
24.208
1.0772
17.48
1.0713
13.137
1.0654
10.203
1.0596
8.1386
1.0539
10.19
1.0595
13.106
1.0654
17.414
1.0713
24.077
1.0772
34.965
1.0832
54.006
1.0893
90.316
1.0954
121.18
1.0984

25
30
40
50
60
70
80
90

Temperature (C) viscosity (mPas) density (g/cm3)


100.000%
100.000%
100.000%
16.667%
-32.134%
-0.283%
25.005%
-65.417%
-0.569%
20.002%
-53.252%
-0.563%
0.003%
0.541%
0.000%
-0.003%
-0.378%
0.000%
-0.005%
-0.236%
0.000%
-0.002%
-0.127%
-0.009%

0.0446
0.0443
0.045
0.0522
0.0627
H2O out

8850.9
9112.4
9417.3
8647.5
8730.7
0.895176 % wt

A H2O

7.0037624 %

H2Ofinal:

0.51075

wt%

H2O final: 0.51075 wt%


Promedio
Temperature (C)
density (g/cm3)
viscosity (mPas)
Temperature (C)
25
1.0964
142.77375
Ecuacion recta
20.000
1.0999
174.313
0.100%
29.999
1.0938
93.006
0.000%
40.000
1.0876
55.261
0.000%
50.000
1.0817
35.636
0.000%
60.000
1.0758
24.493
0.000%
70.001
1.0698
17.662
0.000%
80.000
1.0640
13.262
0.115%
90.000
1.0586
10.249
0.115%
100.001
1.0526
8.223
0.000%
49.999
1.0820
35.511
0.058%
19.999
1.1003
173.317
0.000%

desviacion
density (g/cm3)
0.000%
0.000%
0.026%
0.000%
0.006%
0.006%
0.000%
0.000%
0.000%
0.000%
0.000%

H2O
1.00876333
%wt
Promedio
desviacion
Temperature (C)
density (g/cm3)
viscosity (mPas)
Temperature (C)
25.000
1.0984
119.860
0.082%
50.000
1.0833
34.493
0.000%
60.001
1.0772
23.725
0.058%
70.000
1.0713
17.149
0.115%
80.000
1.0654
12.898
0.100%
90.000
1.0595
10.145
0.050%
100.000
1.0538
8.128
0.100%
79.999
1.0653
13.112
0.153%
49.998
1.0839
35.091
0.058%
25.000
1.0983
120.327
0.153%

density (g/cm3)
0.000%
0.000%
0.006%
0.000%
0.000%
0.008%
0.000%
0.000%
0.121%
0.000%

H2O
1.72515
wt%
Temperature (C)
density (g/cm3)
viscosity (mPas)
24.999
1.0987
108.78
50.001
1.0836
32.469
60
1.0776
22.548
70.001
1.0716
16.425
79.999
1.0657
12.438
89.999
1.0599
9.7243
100.001
1.0542
7.8058
80
1.0657
12.436

H2O
Temperature (C)
25
29.99975
39.9995
50.001
60.0003333333
70.001
80.00025
90

49.997
24.998

1.0835
1.0987

32.475
108.78

100.002
79.999
59.997
49.999
29.999
24.9995

H2O
0.72761
wt %
Temperature (C)
density (g/cm3)
viscosity (mPas)
24.999
127.373
1.098
29.999
94.379
1.095

H2O
Temperature (C)
24.9993
29.9995

40.000
55.932
1.095
50.000
35.977
1.083
59.999
24.659
1.077
70.001
17.774
1.071
80.000
13.340
1.065
90.000
10.346
1.060
100.000
8.248
1.054
79.999
13.304
1.0653
59.99866667 24.49433333 1.077166667
49.999
35.59633333 1.083166667
29.99966667
92.372
1.0953
24.99933333 124.0266667
1.0983

40.0000
50.0003
60.0003
70.0000
79.9997
90.0000
100.0010
79.9977
59.9985
49.9990
29.9995
24.9995

H2O
1.502066
wt %
Temperature viscosity
(C)
(mPas)
density (g/cm3)
24.99966667 113.7533333
1.0988
30.00033333 84.96033333
1.0958
39.99966667 51.10133333 1.089733333
50
33.24233333
1.0837
60.00066667
22.986
1.0777
70.001
16.72633333 1.071733333
79.99933333 12.59633333 1.065833333
89.99733333 9.816133333
1.06
100
7.85805
1.0543
79.999
12.56133333 1.065866667
59.99833333
22.818
1.0777
49.99966667 32.87533333
1.0837
29.99966667 83.01233333
1.0958

H2O
Temperature (C)
24.999
30.001
40.001
50.002
60.002
70.001
79.999
89.999
100
79.997
59.999
50
29.996

24.99933333

110.5

1.098833333

24.998

H2O
1.08729
%wt
Temperature viscosity
(C)
(mPas)
density (g/cm3)
25
120.25
1.0983
30.001
89.512
1.0954
40
53.481
1.0893
49.999
34.585
1.0834
59.999
23.807
1.0774
70.002
17.22
1.0715
80
12.968
1.0656
89.999
10.092
1.0598
100
8.0681
1.0541
79.999
12.95
1.0656
59.997
23.693
1.0774
49.999
34.317
1.0834
29.999
88.05
1.0955
24.998
117.86
1.0986

H2O
Temperature (C)
25.001
30
40
50
60.001
70.002
79.999
90
100.002
79.998
59.999
50
29.999
25

H2O
3.57469333
%wt
Temperature viscosity
(C)
(mPas)
density (g/cm3)
25.001
88.615
1.1004
30
67.467
1.0974
39.999
41.806
1.0914
50
27.849
1.0854
60
19.617
1.0795
69.999
14.436
1.0735
80.001
11.022
1.0677
90.001
8.6661
1.0618
100.001
6.984
1.056
79.997
10.982
1.0676
59.998
19.436
1.0795
49.998
27.476
1.0855
29.999
65.409
1.0976
24.999
82.288
1.1006

H2O
Temperature (C)
25
30.001
40.001
50.001
60.001
70
80.001
89.998
100
79.998
59.997
49.999
29.999
24.999

H2O ini
0.83248
% wt
Temperature viscosity
(C)
(mPas)
density (g/cm3)

25
30
40
50.001
60.002
70.001
80.002
90.002
100.003
90
79.998
69.999
60
49.998
40
29.998
25

123.48
91.71
54.599
35.24
24.208
17.48
13.137
10.203
8.1386
10.19
13.106
17.414
24.077
34.965
54.006
90.316
121.18

1.0983
1.0953
1.0892
1.0832
1.0772
1.0713
1.0654
1.0596
1.0539
1.0595
1.0654
1.0713
1.0772
1.0832
1.0893
1.0954
1.0984

200.000
1.1200

on

1.1000

visosity (mPas)
1.155%
1.136%
1.721%
0.436%
0.351%
4.225%
0.153%
0.153%
2.243%
0.115%
1.528%

1.0800
1.0600

180.000

f(x) = 1.61439202384488E-005x^4 - 0.0047484962x


160.000
R = 0.9993242822
f(x) = - 0.0005897683x + 1.1113639847140.000
R = 0.9997745261
120.000

1.0400
1.0200
0.000

170.21
18

g/molg

100.000
g/molg
80.000

50.000

100.000

150.00060.000
40.000
20.000
0.000
0.000 20.000 40.000 60.000 80.000

visosity (mPas)
28.296%
1.955%
1.153%
0.656%
0.451%
8.018%
0.075%
0.058%
0.100%
26.652%

1.14203
density (g/cm3)
1.0982666667
1.0952
1.089125
1.0831
1.0771
1.0711333333
1.065225
1.0594

emimAc
H2O

%wt
viscosity (mPas)
121.5766666667
90.1515
53.686
34.674
23.854
17.2493333333
12.983
10.097

g IL + H2O
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

water %wt
0.40419
0.51075
0.70995
0.8893216667

0.728
0.842
0.913
1.009
1.08729
1.3773166667

1.142
1.133
1.462
1.945
1.502066
1.67237
1.72515
1.72515
2.3683766667
2.4174766667
3.5746933333
3.8073333333
5.461235
5.524945
0.83248
0.895176
2.8
2.8

1.0537
1.0652
1.07705
1.0830666667
1.0952
1.0982

8.0704
12.95
23.6815
34.275
87.8513333333
117.53

1.4616425
density (g/cm3)
1.0986
1.0956

wt %
viscosity (mPas)
110.2733
82.3450

1.0895
1.0835
1.0775
1.0716
1.0657
1.0599
1.0541
1.0657
1.0775
1.0835
1.0957
1.0987

49.7243
32.4467
22.4890
16.3577
12.3673
9.6505
7.7330
12.3330
22.3105
32.0475
80.1790
106.4050

0.70995
viscosity (mPas)
126.98
93.819
55.524
35.698
24.455
17.631
13.24
10.277
8.1965
13.162
24.113
34.967
89.961

%Wt
density (g/cm3)
1.0982
1.0952
1.0891
1.0831
1.0772
1.0712
1.0654
1.0595
1.0538
1.0653
1.0772
1.0832
1.0954

wt %
X H2O in
X H2O out
X H2O media
Devest

Ecuacin

298.15
303.15
313.15
323.15
333.15
343.15
353.15
363.15
373.15
353.15
333.15
323.15
303.15
298.15

25
30
40
50
60
70
80
90
100
80
60
50
30
25
25
30
50
60
80

1.0984

2.3683766667
viscosity (mPas)
101.58
76.585
46.729
30.775
21.472
15.693
11.909
9.3188
7.4792
11.867
21.307
30.437
74.867
98.737

% wt
density (g/cm3)
1.0996
1.0966
1.0905
1.0845
1.0785
1.0726
1.0667
1.0608
1.0551
1.0667
1.0785
1.0845
1.0966
1.0997

100

160.000

140.000

Viscosity/mPas

120.62

120.000

100.000

80.000

60.000

40.000

5.461235
viscosity (mPas)
75.531
58.318
36.927
24.966
17.767
13.185
10.127
7.9979
6.4675
10.091
17.629
24.69
57.111
73.709

%wt
density (g/cm3)
1.1018
1.0989
1.0928
1.0868
1.0808
1.0748
1.0689
1.0629
1.0571
1.0688
1.0807
1.0868
1.0988
1.1018

20.000

0.000
0.0000

wt in %
wt out %

X H2O in
X H2O out
X H2O media
Devest
25
30
40
50
60
70
80
90
100
80
60
50
30
no medido, obtenido por la ecuacin
25
50

Vm (cm3/mol)

1.100

1.080

1.060

1.040

1.020

1.000
0.020

0.04

1.020

1.000
0.020

0.04

157.4
157.35
157.3
157.25
157.2
157.15
157.1
157.05
157
156.95
156.9
0.020

0.040

1439202384488E-005x^4 - 0.0047484962x^3 + 0.5215940617x^2 - 25.9155864888x + 518.5755516402


93242822

00 20.000 40.000 60.000 80.000 100.000 120.000

g H2O
0.0040419
0.0051075
0.0070995
0.008893217
0.0072761
0.00842075
0.009128533
0.010087633
0.0108729
0.013773167
0.0114203
0.011327025
0.014616575
0.0194485
0.01502066
0.0167237
0.0172515
0.0172515
0.023683767
0.024174767
0.035746933
0.038073333
0.05461235
0.05524945
0.0083248
0.00895176
0.028
0.028

mol IL
0.005851349
0.005845088
0.005833385
0.005822847
0.005832348
0.005825623
0.005821464
0.00581583
0.005811216
0.005794177
0.005808
0.005808548
0.005789222
0.005760834
0.005786848
0.005776842
0.005773741
0.005773741
0.005735951
0.005733066
0.005665079
0.005651411
0.005554243
0.0055505
0.005826186
0.005822503
0.005710593
0.005710593

mol H2O
mol H2O/(mol IL+H2O) %
0.00022455 0.036957494 3.695749434
0.00028375 0.046297517 4.629751685
0.000394417 0.063331601 6.33316013
0.000494068 0.078213436 7.821343592
0.000404228 0.064815664 6.481566366
0.000467819 0.074334431 7.433443086
0.000507141 0.080134678 8.013467806
0.000560424 0.087892373 8.789237338
0.00060405 0.094158214 9.415821361
0.000765176 0.116654182 11.66541819
0.000634461 0.098481169 9.84811687
0.000629279 0.097747134 9.774713408
0.000812032 0.123011778 12.30117775
0.001080472 0.157933622 15.79336224
0.000834481 0.126029252 12.60292518
0.000929094 0.138548051 13.85480512
0.000958417 0.142363961 14.23639607
0.000958417 0.142363961 14.23639607
0.001315765 0.186587894 18.65878936
0.001343043 0.189799591 18.97995908
0.001985941 0.259565503 25.95655029
0.002115185 0.272343912 27.23439116
0.003034019 0.353275132 35.32751322
0.003069414 0.356084068 35.60840681
0.000462489 0.073543133 7.354313303
0.00049732 0.078692077 7.869207697
0.001555556 0.214082548 21.40825483
0.001555556 0.214082548 21.40825483

9.811415139

13.22886515
14.23639607
18.81937422
26.59547072
35.46796001
7.6117605
21.40825483

Viscosity mPas
0.404
0.70995
0.511
0.889321667

0.037
0.046

0.728
0.842
0.065
0.074

0.83248
0.895176

0.913
1.009
0.080
0.088

0.0416
0.0

0.063331601
0.078213436
0.0708
0.0

0.0696
0.0

0.073543133
0.078692077
0.0761
0.0

142.77375
93.006
55.261
35.636
24.493
17.662
13.262
10.249
8.223
13.262
24.493
35.574
93.006
142.77375

126.98
93.819
55.524
35.698
24.455
17.631
13.24
10.277
8.1965
13.162
24.113
34.967
89.961
120.62

127.373
94.379
55.932
35.977
24.659
17.774
13.340
10.346
8.248
13.304
24.494
35.596
92.372
124.03

123.48
91.71
54.599
35.24
24.208
17.48
13.137
10.203
8.1386
13.106
24.077
34.965
90.316
121.18

119.860

142.77375

123.80
4.497
91.890
2.728
35.333
0.517
24.284
0.242
13.201
0.055

125.70
2.366
93.376
1.419
35.787
0.269
24.577
0.116
13.322
0.025

122.33
1.626
91.013
0.986
35.103
0.194
24.143
0.093
13.122
0.022

120.09
0.330

93.006
35.605
0.044
48.985
13.262

0.0840
0.0

34.493
23.725
17.149
12.898
10.145
8.128
13.112
35.091
120.33

34.792
0.423

13.005
0.151

1.08729
1.377316667
0.094158214
0.116654182
0.1054
0.0
120.25
89.512
53.481
34.585
23.807
17.22
12.968
10.092
8.0681
12.95
23.693
34.317
88.05
117.86
119.06
1.690
88.781
1.034
34.451
0.190
23.750
0.081
12.959
0.013

8.2232

8.1965

8.24845

8.1386

8.128066667

8.0681

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000
0.0000

5.0000

10.0000

15.0000

20.0000
%molH2O

Density (g/cm3)
0.404
0.511

0.70995
0.889321667

0.728
0.842

0.83248
0.895176

0.913
1.009

1.08729
1.377316667

20

0.037
0.046

0.063
0.078

0.065
0.074

0.074
0.079

0.080
0.088

0.094
0.117

0.042
0.0

0.07077252
0.01052305
1.0982
1.0952
1.0891
1.0831
1.0772
1.0712
1.0654
1.0595
1.0538
1.0653
1.0772
1.0832
1.0954
1.0984

0.070
0.0
1.0983
1.0952
1.0952
1.0831
1.0771
1.0712
1.0653
1.0595
1.0538
1.0653
1.0772
1.0832
1.0953
1.0983

0.076117605
0.003640853
1.0983
1.0953
1.0892
1.0832
1.0772
1.0713
1.0654
1.0596
1.0539
1.0654
1.0772
1.0832
1.0954
1.0984

0.084
0.0
1.0984

1.0983

0.105
0.0
1.0983
1.0954
1.0893
1.0834
1.0774
1.0715
1.0656
1.0598
1.0541
1.0656
1.0774
1.0834
1.0955
1.0986

1.083
0

1.084
0.000424264

1.083
0

1.0938
1.0876
1.0817
1.0758
1.0698
1.0640
1.0586
1.0526
1.0640
1.0758
1.0817
1.0938
1.0983
1.082

1.083
1.083
7.0711E-005 4.7140E-005

1.0833
1.0772
1.0713
1.0654
1.0595
1.0538
1.0653
1.0839

157.3541647 157.1435166 157.1459346 157.1362629 157.0782577 157.1072549

ChartTitle

0.040

0.060

0.080

0.100

0.120

20

020

0.040

0.060

0.080

0.100

0.120

ChartTitle

0.040

0.060

0.080

0.100

0.120

0.140

1.1100
1.1000
1.0900
1.0800

d 0.
wt%

1.0700
1.1100

d1

1.0600
1.1000

1.0500

1.0900

1.0400

1.0800

1.0700

1.0300
20.000

40.000

1.0600

60.000

80.000

1.0500

160.000

1.0400

140.000

1.0300

1.0200
0.200

120.000
0.400

0.600

100.000

80.000
60.000

0.800

1.000

100.000
80.000
60.000
40.000

Prausnitz

20.000
0.000
0.020
1.142
1.133
0.098
0.098

1.462
1.945
0.123
0.158

1.502
1.672
0.126
0.139

1.725
1.725
0.142
0.142

0.0981
0.00

0.1405
0

0.1323
0.0

0.1424
0.0

121.5766667
90.152
53.686
34.674
23.854
17.249
12.983
10.097
8.070
12.950
23.682
34.275
87.851
117.53

110.2733
82.345
49.724
32.447
22.489
16.358
12.367
9.651
7.733
12.3330
22.3105
32.0475
80.1790
106.41

113.7533333
84.960
51.101
33.242
22.986
16.726
12.596
9.816
7.858
12.56133333
22.818
32.87533333
83.01233333
110.50

108.780

119.55
2.861
89.001
1.626
34.475
0.282
23.768
0.122
12.967
0.023

108.34
2.735
81.262
1.532
32.247
0.282
22.400
0.126
12.350
0.024

112.13
2.300
83.986
1.377
33.059
0.260
22.902
0.119
12.579
0.025

108.78
0.000

32.469
22.548
16.425
12.438
9.724
7.806
12.436
32.475
108.78

32.472
0.004

12.437
0.001

0.040

2.368376667 3.574693333
2.417476667 3.807333333
0.186587894 0.259565503
0.189799591 0.272343912
0.1882
0.2660
0.0
0.0
101.58
76.585
46.729
30.775
21.472
15.693
11.909
9.3188
7.4792
11.867
21.307
30.437
74.867
98.737

88.615
67.467
41.806
27.849
19.617
14.436
11.022
8.6661
6.984
10.982
19.436
27.476
65.409
82.288

100.16
2.010
75.726
1.215
30.606
0.239
21.390
0.117
11.888
0.030

85.45
4.474
66.438
1.455
27.663
0.264
19.527
0.128
11.002
0.028

0.060

8.0704

20.0000
%molH2O

ensity (g/cm3)
1.142
1.133

7.733

7.85805

7.8058

7.4792

6.984

25C
30C
50C
60C
80C

25.0000

1.462
1.945

30.0000

1.502
1.672

1.725
1.725

35.0000

2.368376667 3.574693333
2.417476667 3.807333333

40.0000

0.098
0.098

0.123
0.158

0.126
0.139

0.142
0.142

0.098
0.00
1.0983
1.0952
1.0891
1.0831
1.0771
1.0711
1.0652
1.0594
1.0537
1.0652
1.0771
1.0831
1.0952
1.0982

0.140
0
1.0986
1.0956
1.0895
1.0835
1.0775
1.0716
1.0657
1.0599
1.0541
1.0657
1.0775
1.0835
1.0957
1.0987

0.132
0.0
1.0988
1.0958
1.089733333
1.0837
1.0777
1.071733333
1.065833333
1.06
1.0543
1.065866667
1.0777
1.0837
1.0958
1.098833333

0.142
0.0
1.0987

1.084
0

1.084
7.0711E-005

1.083
1.084
2.3570E-005 2.3570E-005

157.1531892 157.0903386 157.063763

0.187
0.190

0.18819374 0.26595471
0.00227101 0.0090357
1.0996
1.1004
1.0966
1.0974
1.0905
1.0914
1.0845
1.0854
1.0785
1.0795
1.0726
1.0735
1.0667
1.0677
1.0608
1.0618
1.0551
1.056
1.0667
1.0676
1.0785
1.0795
1.0845
1.0855
1.0966
1.0976
1.0997
1.1006

1.0836
1.0776
1.0716
1.0657
1.0599
1.0542
1.0657
1.0835
1.0987

157.085506

50C

0.120

0.140

0.160

0.260
0.272

1.085
0

0.120

0.140

50C

0.140

0.160

0.160

00

200.000
180.000
160.000
140.000
120.000
d 0.51
wt%

100.000

80.000

d 1 wt%

60.000
40.000
25 C

20.000
80.000

100.000

30 C

0.000
20.000

40 C

40.000

50 C

60.000

60 C
70 C
80 C
90 C
100
C

1.000

1.200

1.400

1.600

1.800

2.000

040

140
120

0.060

0.080

0.100

100
0.120

5.461235
5.524945

80

74.62
1.288
57.715
0.853
24.828
0.195
17.698
0.098
10.109
0.025

Ww
0.023
0.045
0.084
0.192
0.374
0.556
1

0.140

0.160

60

0.353275132
0.356084068
0.3547
0.0
75.531
58.318
36.927
24.966
17.767
13.185
10.127
7.9979
6.4675
10.091
17.629
24.69
57.111
73.709

25 C
wt %
2.3
4.5
8.4
19.2
37.4
55.6
100

Budtova
10-60 en intervalos de 5C
40
20
0
0.000

160

160.000
140
140.000
120.000
120
100.000
100
80.000

0.050

C water (wt%)
0.150
0.200
0
3
6
7
9
10
12
15
18
20

0.100

0.250

60.000

2
C

3
C

5
C

80
40.000
20.000
60
0.000
0.0000 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000
40

Yo
0.5%wt H2O
Temperature (C)
density (g/cm3)
20.000
1.0999
29.999
1.0938

20

0
20

30

40

50

1.11
1.1
1.09
1.08

60

1.07
1.06

70

20

1.1
1.09

6.4675

20

Froba density
20
25
30
35
40
50
55
60
65
70
75
80
85
90

25C
30C
50C
60C
80C

40.0000

5.461235
5.524945

1.10269
1.09968
1.09664
1.0936
1.09057
1.08452
1.08152
1.07852
1.07554
1.07257
1.0696
1.06665
1.06371
1.06078

3040.000

50.000
60.000
70.001
80.000
90.000
100.001

40 1.0876

1.0817
1.0758
1.0698
1.0640
1.0586
1.0526

50

1.08

60

70

1.07
1.06
1.05
1.04
1.03
1.02
10

20

0.353
0.356
0.3546796
0.00198622
1.1018
1.0989
1.0928
1.0868
1.0808
1.0748
1.0689
1.0629
1.0571
1.0688
1.0807
1.0868
1.0988
1.1018

00

n 0.51 wt%
n 1 wt%
n 1.7%wt

25 C
30 C
40 C
50 C

60.000

60 C

80.000

100.000

70 C
80 C
90 C
100
C

000

Row 63
Linear
(Row 63)
Row 64

Row 63
Linear
(Row 63)
Row 64

25 C
viscosity (Pas)
0.122
0.081
0.057
0.032
0.012
0.004
0.000089

0.160

25 C

0.180

0.200

30 C
40 C
50 C
60 C
70 C
80 C
90 C
100
C

ter (wt%)
0.150

160.000
0.200

0.250

0.300

0.350

0.400

140.000
120.000
100.000

25
C

3.696
6.33
6.482
8.013
9.415
9.848
12.30
1
12.60
3
14.23
6
18.65
9
25.95
6

80.000

30
C

60.000

50
C

40.000
20.000

3000 0.3500 0.4000

0.000
0.000

0.100

1.11
1.1
1.09
1.08

60

1.07
1.06

70

80

90

100

110

0.200

0.300

1.1
1.09
1.08

60

70

80

90

100

110

1.07
1.06
1.05
1.04
1.03
1.02
10

20

30

40

50

60

70

80

90

100

110

200

160
140
120
100
50 C wt %
initial

80
60
40
20
0
0.200 0.400 0.600 0.800 1.000 1.200 1.400 1.600 1.800 2.000 2.200

0.300

0.400

wt %

x
mol H2O/mol IL
0.001
0.001
0.001
0.0013
0.002
0.003
0.004

kgm-3
T =298.15
1.0982
1.0983
1.0983
1.0988
1.0996
1.1004
1.1018

x
mol H2O/mol IL
T
0.001
0.001
0.001
0.001
0.002
0.003
0.004

kgm-3
=323.15
1.0831
1.0831
1.0834
1.0837
1.0845
1.0854
1.0868

mPas

x
mol H2O/mol IL

126.98
121.58
120.25
113.75
101.58
88.615
75.531

0.001
0.001
0.001
0.001
0.002
0.003
0.004

mPas

x
mol H2O/mol IL

35.698
34.674
34.585
33.242
30.775
27.849
24.966

kgm-3
mPas
T =353.15
0.001
1.0654
13.24
0.001
1.065225
12.983
0.001
1.0656
12.968
0.001 1.06583333 12.59633333
0.002
1.0667
11.909
0.003
1.0677
11.022
0.004
1.0689
10.127

x
mol H2O/mol IL

kgm-3
T =303.15
1.0952
1.0952
1.0954
1.0958
1.0966
1.0974
1.0989

T
0.001
0.001
0.001
0.001
0.002
0.003
0.004
x
mol H2O/mol IL
T
0.001
0.001
0.001
0.001
0.002
0.003
0.004

kgm-3
=333.15
1.0772
1.0771
1.0774
1.0777
1.0785
1.0795
1.0808

kgm-3
=363.15
1.0595
1.0594
1.0598
1.06
1.0608
1.0618
1.0629

303.15

mPas

x
mol H2O/mol IL

93.819
90.1515
89.512
84.960
76.585
67.467
58.318

0.001
0.001
0.001
0.0013
0.002
0.003
0.004

mPas

x
mol H2O/mol IL

03.15

33.15

kgm-3
T= 313.15 K
1.0952
1.089125
1.0893
1.0897
1.0905
1.0914
1.0928

T
0.001
0.001
0.001
0.001
0.002
0.003
0.004

24.455
23.854
23.807
22.986
21.472
19.617
17.767

mPas

x
mol H2O/mol IL

63.15

T
0.001
0.001
0.001
0.001
0.002
0.003
0.004

10.277
10.097
10.092
9.81613333
9.3188
8.6661
7.9979
T

mPas

kgm-3
=373.15
1.0538
1.0537
1.0541
1.0543
1.0551
1.056
1.0571

mPas

0.1
0.1
0.1
0.1
0.1
0.1

XIL

55.524
53.686
53.481
51.101
46.729
41.806
36.927

kgm-3
=343.15
1.0712
1.0711
1.0715
1.0717
1.0726
1.0735
1.0748

P
298.15
303.15
323.15
333.15
353.15
373.15

mPas

promedio

17.631
17.249
17.220
16.726
15.693
14.436
13.185

8.1965
8.0704
8.0681
7.85805
7.4792
6.984
6.4675
Densidad agua
997.05
995.65
988.03
983.2
971.79
0.58967

104.92
125.82
209.42
251.25
335.05
2675.8

0.3672
0.43673
0.70377
0.83125
1.0755
7.361

373.15
0.0416
0.0702
0.0761
0.1018
0.1323
0.1405
0.1882
0.2660
0.3547

8.2232
8.2225
8.1386
8.0693
7.8581
7.7330
7.4792
6.9840
6.4675

0.0416
0.0702
0.0761
0.1018
0.1323
0.1405
0.1882
0.2660
0.3547

1.0526
1.0538
1.0539
1.0539
1.0543
1.0542
1.0551
1.0560
1.0571

0.0416
0.0702
0.0761
0.1018
0.1323
0.1405
0.1882
0.2660
0.3547

0.0129217
0.01518276
0.02029754
0.03449284
0.0344755
0.07210631
0.1384664
0.24414867

0.0416
0.0702
0.0761
0.1018
0.1323
0.1405
0.1882
0.2660
0.3547

7.8808887
7.64619782
7.60370926
7.40207171
7.18366916
7.13692461
6.81566136
6.36577232
5.92930969

353.15

T/K
323.15

333.15
viscosity
13.2616667 24.4926667 35.5736667
13.2330
24.3037
35.2817
13.106
24.077
34.965
12.9500
23.6873
34.2960
12.561
22.818
32.875
12.333
22.311
32.048
11.867
21.307
30.437
10.982
19.436
27.476
10.091
17.629
24.690
density
1.064 1.07576667
1.0817
1.0653
1.0772
1.0832
1.0654
1.0772
1.0832
1.0654
1.0772
1.0832
1.0659
1.0777
1.0837
1.0657
1.0775
1.0835
1.0667
1.0785
1.0845
1.0676
1.0795
1.0855
1.0688
1.0807
1.0868
Excess molar volume
148.20463 46963.0081 169507.198
0.01369903 0.01460225 0.01512133
0.01600088 0.01602518 0.01658616
0.02139127 0.02179692 0.02266578
0.03706209 0.03754901 0.03841685
0.03514493 0.03575393 0.03672094
0.07620265 0.07546483 0.07645606
0.1434647 0.14552875 0.1465007
0.25481468 0.25617604 0.2618997
excess viscosity
12.7096166 23.473098 34.0928237
12.333057 22.7871864 33.0978186
12.2640693 22.6599831 32.9122146
11.9438724 22.082248 32.0836997
11.5999448 21.4741042 31.2246332
11.5292169 21.3586505 31.0718678
11.0283715 20.4828226 29.8456137
10.3409521 19.323571 28.2662951
9.68259482
18.24002
26.8166273

303.15
93.006
91.1665
90.316
87.9507
83.012
80.179
74.867
65.409
57.111
1.0938
1.0954
1.0954
1.0954
1.0958
1.0957
1.0966
1.0976
1.0988
2314.75253
0.01545257
0.01730133
0.02240804
0.03757236
0.03690957
0.07477598
0.14328289
0.25115089
89.1343922
86.6085018
86.1313624
84.0561248
82.0244104
81.7430394
78.9164991
75.6101686
72.7498934

298.15
142.77375
122.3233
121.18
117.6950
110.50
106.41
98.737
82.288
73.709
1.0983
1.0984
1.0984
1.0984
1.0988
1.0987
1.0997
1.1006
1.1018
0.91308373
0.91691461
0.91489437
0.89503745
0.88512565
0.87569333
0.87844326
0.87823912
0.9059504
136.830435
134.189859
133.549819
130.797086
128.155854
127.826752
124.192064
120.888869
116.630671

0.0708
0.0696

13.162
13.304

24.113
24.494

34.967
35.596

0.1054
0.0981

12.950
12.950

23.693
23.682

34.317
34.275

0.0708
0.0696

1.0653
1.0653

1.0772
1.0772

1.0832
1.0832

0.1054
0.0981

1.0656
1.0652

1.0774
1.0771

1.0834
1.0831

emimAc
H2O

170.21
18

g/molg
g/molg

0.3
0.25
0.2
0.15
0.1
0.05
0
0.0000 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000

89.961
92.372

120.62
124.03

88.050
87.851

117.86
117.53

1.0954
1.0953

1.0984
1.0983

1.0955
1.0952

1.0986
1.0982

.1500 0.2000 0.2500 0.3000 0.3500 0.4000

[amim][Cl]
H2O

X IL (%)
100.0000
50.8319
32.3370
22.4487
21.1044
18.6711
16.1616
13.6948
11.4280
9.1376
7.8572
6.6464
5.5355
4.4424
3.3936
2.9730
2.5652
2.1561

158.63 g/molg
18
Wue ta al 2010, 298.15 K
XIL
density (g/cm3)
mPas
1
1.1660 821.0000
0.508319
1.1328 48.0000
0.32337
1.1278 18.0000
0.224487
1.1089
8.5184
0.211044
1.1102
7.9004
0.186711
1.1058
7.4412
0.161616
1.1000
5.9742
0.136948
1.0920
4.8056
0.11428
1.0841
3.8670
0.091376
1.0730
3.1181
0.078572
1.0618
2.4752
0.066464
1.0542
2.1658
0.055355
1.0468
1.8997
0.044424
1.0400
1.6769
0.033936
1.0292
1.4726
0.02973
1.0260
1.3941
0.025652
1.0240
1.3222
0.021561
1.0218
1.2521

T fusion

55
masa inicial de IL (g)

mol IL
0.04412784
0.04412784
0.04412784
0.04412784
0.04412784
0.04412784
0.04412784
0.04412784
0.04412784
0.04412784
0.04412784
0.04412784
0.04412784
0.04412784
0.04412784
0.04412784
0.04412784
0.04412784

C
a inicial de IL (g)

mol H2O
0
0.04268348
0.09233455
0.15244409
0.16496526
0.19221519
0.22891347
0.27809552
0.3420101
0.43879814
0.51749518
0.61980819
0.75305118
0.94920559
1.25619761
1.44015889
1.67612183
2.00252327

mas IL

mass H2O
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7

0
0.7683026
1.66202191
2.74399368
2.96937464
3.45987345
4.12044241
5.00571927
6.15618186
7.8983665
9.31491333
11.1565474
13.5549212
17.0857007
22.611557
25.92286
30.170193
36.0454188

%wt
0
9.89022495
19.187459
28.160873
29.7849639
33.0775842
37.0528641
41.6944554
46.7930736
53.0149832
57.0944702
61.4464147
65.9448949
70.9371129
76.3605811
78.7381777
81.167706
83.7381069

[HOEtMIM][Cl
H2O

162.61 g/molg
18

25-50

X [HOEtMIM]X H2O
mol IL+mol H2O
mol H2O
0.0122
0.9878
1
0.9878
0.0453
0.9547
1
0.9547
0.0997
0.9003
1
0.9003
0.2054
0.7946
1
0.7946
0.3071
0.6929
1
0.6929

5C

g IL
1.983842
7.366233
16.212217
33.400094
49.937531

g H2O
17.7804
17.1846
16.2054
14.3028
12.4722

wt H2O
8.96260892 896.260892
2.33288847
0.99957951
0.42822634
0.24975604

B. Mokhtarani et al. / J. Chem. Thermodynamics 41 (2009) 323329


283.15
0.11
0.263
0.391
0.414
0.549
0.637
0.724
0.856

210.64
84.04
44.91
41.27
22.77
15.85
10.78
5.53

1.2196
1.2131
1.2062
1.2047
1.1944
1.1849
1.1717
1.1358

1.24
1.22
1.2
1.18
1.16
1.14
1.12
1.1
1.08
0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

250

200

150

100

50

0
0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.5

0.6

0.7

0.8

0.9

compuesto puro ????


wt in %
0.40419
0.70995
0.72761
0.83248
1.08729
wt out %
0.51075 0.88932167
0.842075
0.895176 1.37731667
X H2O in
0.036957494
0.0633316 0.06481566 0.07354313 0.09415821
X H2O out
0.046297517 0.07821344 0.07433443 0.07869208 0.11665418
X H2O media 0.041627506
0.071
0.070
0.076
0.084

XIL

0.958372494
353.15
1.064
333.15 1.075766667
323.15
1.0817
303.15
1.0938
298.15
1.0983

0.929
0.930
1.0653
1.0653
1.0772 1.07716667
1.0832 1.08316667
1.0954
1.0953
1.0984
1.0983

0.924
1.0654
1.0772
1.0832
1.0954
1.0984

0.929
1.0910
1.0800
1.0830
1.0890
1.0905

0.924
1.0903
1.0802
1.0831
1.0890
1.0905

EXPERIMENTAL
0.916
1.0656
1.0774
1.0834
1.0955
1.0986

CALCULADO
353.15
333.15
323.15
303.15
298.15

0.930
0.00066598
7.9054E-006
2.8496E-008
3.9226E-005
6.0114E-005

0.924
0.00062212
8.7464E-006
6.7559E-009
4.0468E-005
6.2114E-005

Excess volume molar


0.92922748 0.93042495
353.15 0.18139985 0.18163361
333.15
0.195632 0.19133458
323.15 0.20248036 0.19824203
303.15 0.21121096 0.19828354
298.15 0.01311069
0

0.92388239
0.19421174
0.19450669
0.20131565
0.20999603
0.01303528

353.15
333.15
323.15
303.15
298.15

XIL

0.929
0.00065908
7.8954E-006
3.2755E-008
4.0484E-005
0.00006175

0.930
1.0911
1.0800
1.0830
1.0890
1.0905

0.916
1.0893
1.0804
1.0833
1.0890
1.0905

MNIMOS CUADRADOS
0.916
0.00056259
8.9649E-006
1.5455E-008
4.1748E-005
6.5942E-005

0.91598647
0.22001803
0.21971206
0.22616604
0.2211937
0.03876456

wt in %
wt out %
X H2O in
X H2O out
X H2O media

X IL
353.15
333.15
323.15
303.15
298.15

0.710
0.889
0.063
0.078
0.071

0.728
0.842
0.065
0.074
0.070

0.832
0.895
0.074
0.079
0.076

0.9929005 0.9927239
13.162
13.304
24.113 24.4943333
34.967 35.5963333
89.961
92.372
120.62 124.026667

0.9916752
13.106
24.077
34.965
90.316
121.18

1.087
1.377
0.094
0.117
0.105

1.142
1.133
0.098
0.098
0.098

Experimental
0.9891271 0.9885797
12.95
12.95
23.693
23.6815
34.317
34.275
88.05 87.8513333
117.86
117.53

Calculado

X IL
353.15
333.15
323.15
303.15
298.15

X IL
353.15
333.15
323.15
303.15
298.15

calculado
X IL
353.15
333.15
323.15
303.15

0.993
13.9604
26.7345
44.0073
100.3241
118.9390

0.993
13.7993
26.4967
43.7330
99.9808
118.5792

0.992
12.8774
25.1173
42.1362
97.9718
116.4720

0.989
10.8841
21.9983
38.4819
93.3022
111.5601

0.989
10.5015
21.3713
37.7386
92.3382
110.5433

0.993
0.64
6.87
81.73
107.39
2.83

0.993
0.25
4.01
66.21
57.89
29.67

0.992
0.05
1.08
51.43
58.61
22.17

0.989
4.27
2.87
17.35
27.59
39.69

0.989
6.00
5.34
12.00
20.13
48.81

0.9929005

0.9927239

0.9916752

0.9891271

0.9885797

298.15

1.14203
1.4616575
1.502066
1.1327025
1.94485
1.67237
0.09848117 0.12301178 0.12602925
0.09774713 0.15793362 0.13854805
0.105
0.098
0.140

2.36837667 3.57469333
5.461235
2.41747667 3.80733333
5.524945
0.18658789
0.2595655 0.35327513
0.18979959 0.27234391 0.35608407
0.132
0.142
0.188

EXPERIMENTAL
0.895
0.902
0.860
1.0652 1.06566667 1.06586667
1.07705
1.0775
1.0777
1.08306667
1.0835
1.0837
1.0952
1.09565
1.0958
1.0982
1.0987 1.09883333

CALCULADO
0.895
1.0860
1.0811
1.0838
1.0890
1.0903

0.868
1.0667
1.0785
1.0845
1.0966
1.0997

0.858
1.0676
1.0795
1.0855
1.0976
1.1006

0.812
1.0688
1.0807
1.0868
1.0988
1.1018

0.858
1.0791
1.0826
1.0847
1.0889
1.0900

0.812
1.0690
1.0844
1.0858
1.0886
1.0893

0.902
1.0872
1.0809
1.0836
1.0890
1.0904

0.860
1.0794
1.0825
1.0846
1.0889
1.0900

0.868
1.0811
1.0822
1.0844
1.0890
1.0901

MNIMOS CUADRADOS
0.895
0.902
0.00043465 0.00046537
1.6618E-005 1.1317E-005
4.7973E-007 7.5516E-009
3.8133E-005 4.3792E-005
6.1761E-005 6.8992E-005

0.860
0.00018429
2.2999E-005
8.8450E-007
4.7196E-005
7.7985E-005

0.868
0.00020721
1.3445E-005
4.6428E-009
5.8339E-005
9.2266E-005

0.8595273
0.24080584
0.24396949
0.24960819
0.24412122
0.0646533

0.86771135
0.35135019
0.3479483
0.35251857
0.34477218
0.17119583

0.8945938
0.16122019
0.16865394
0.17762805
0.17795395
-0.01262434

0.90188585
0.22564327
0.22955321
0.23576178
0.23697286
0.05088579

0.858
0.812
0.00013115 5.0985E-008
9.4368E-006 1.3421E-005
6.5848E-007 1.0446E-006
7.5313E-005
0.0001039
0.00011278
0.0001559

0.85763604
0.46263704
0.46929306
0.47242735
0.46205074
0.27775727

0.81180626
0.58323104
0.58634698
0.59944754
0.57484519
0.39965179

1.462
1.945
0.123
0.158
0.140

1.502
1.672
0.126
0.139
0.132

2.368
2.417
0.187
0.190
0.188

3.575
3.807
0.260
0.272
0.266

5.461
5.525
0.353
0.356
0.355

rimental

14
12

f(x) = 652.502027
R = 0.991838196

10
8

0.9853834 0.9849793
12.333 12.5613333
22.3105
22.818
32.0475 32.8753333
80.179 83.0123333
106.405
110.5

0.9763162
11.867
21.307
30.437
74.867
98.737

0.9642531 0.9453877
10.982
10.091
19.436
17.629
27.476
24.69
65.409
57.111
82.288
73.709

0.985
8.5893
18.0138
33.6930
86.9858
104.8786

0.985
8.3868
17.6262
33.2174
86.3427
104.1955

0.976
6.1573
11.3121
24.9547
74.3706
91.3351

0.964
9.7812
8.8670
19.6059
63.4753
79.1077

0.945
31.1503
19.8558
25.6087
59.9151
73.2418

0.985
14.01
18.46
2.71
46.33
2.33

0.985
17.43
26.95
0.12
11.09
39.75

0.976
32.60
99.90
30.06
0.25
54.79

0.964
1.44
111.70
61.94
3.74
10.11

0.945
443.49
4.96
0.84
7.86
0.22

0.98538343 0.98497934 0.97631623 0.96425307 0.94538765

6
4
2
0
0.94

0.95

Chart Title
1.07
1.069
f(x)
= - 2346.5883333453x^5 + 10122.2739345779x^4 - 17449.8577829223x^3 + 15027.7271504691x^2 - 6465.3210787683x + 1112.7547681597
1.068
R = 0.8760111333
1.067
1.066
1.065
1.064
1.063
1.062
1.061
1.06
0.600

0.650

0.700

a0
a1
a2
a3
b0
b1
b2
b3

0.750

0.800

3.67398704
-5.27972414
1.2412678
1.37768606
-0.00404237
0.00129619
0.01416141
-0.0111882

mnimos cua 0.0054046

emimAc
H2O

170.21
18

g/molg
g/molg

0.850

0.900

0.950

Chart Title
14
12

f(x) = 652.5020274968x^2 - 1198.2761749532x + 559.7477167801


R = 0.9918381969

10
8
6
4
2
0
0.94

0.95

a0
a1
a2
b0
b1
b2
c0
c1
c2

0.96

203.433269
4335.94129
-0.00452214
46.5370858
-148.254291
38.0925241
0.07212778
-0.03609849
38.1087969

0.97

0.98

mnimos cuad

0.99

1717.95

7683x + 1112.7547681597

%wt
X H2O medi
Devest
X IL
298.15
303.15
323.15
333.15
353.15

0.7922
0.0702
0.0086

0.8638
0.0761
0.0036

1.1848
0.1018
0.0082

1.5872
0.1323
0.0089

0.9298
124.7500
3.4318
92.6328
2.0736
35.5597
0.3932
24.4303
0.1790
13.2614
0.0402

0.9239
122.330
1.626
91.013
0.986
35.103
0.194
24.143
0.093
13.122
0.022

0.8982
119.3042
2.2757
88.8912
1.3301
34.4628
0.2358
23.7589
0.1013
12.9628
0.0180

0.8677
112.127
2.300
83.986
1.377
33.059
0.260
22.902
0.119
12.579
0.025

Viscosity / mPas

140.0000
120.0000
100.0000
80.0000

298.15 K
Polynomial
(298.15 K)
303.15 K
323.15 K
333.15 K
353.15 K

60.0000
40.0000
20.0000
0.0000
0.5000

0.6000

0.7000

X H2O (%

0.0000
0.5000

0.6000

0.7000

X H2O (%

1.7033
0.1405
0.0247

2.3929
0.1882
0.0023

3.6910
0.2660
0.0090

5.4931
0.3547
0.0020

0.8595
108.339
2.735
81.262
1.532
32.247
0.282
22.400
0.126
12.350
0.024

0.8118
100.159
2.010
75.726
1.215
30.606
0.239
21.390
0.117
11.888
0.030

0.7340
85.452
4.474
66.438
1.455
27.663
0.264
19.527
0.128
11.002
0.028

0.6453
74.620
1.288
57.715
0.853
24.828
0.195
17.698
0.098
10.109
0.025

0.7000

X H2O (%)

0.8000

0.9000

1.0000

0.7000

X H2O (%)

0.8000

0.9000

1.0000

0.7996
0.0708
0.0105
123.800
4.497
91.890
2.728
35.333
0.517
24.284
0.242
13.201
0.055

1.0000

0.7848
0.0696
0.0067
125.700
2.366
93.376
1.419
35.787
0.269
24.577
0.116
13.322
0.025

1.2323
0.1054
0.0159
119.055
1.690
88.781
1.034
34.451
0.190
23.750
0.081
12.959
0.013

1.1374
0.0981
0.0005
119.553
2.861
89.001
1.626
34.475
0.282
23.768
0.122
12.967
0.023

1.0000

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