(a)
(b)
(c)
(d)
1
The lid must be opened at intervals
The crucible is quickly covered with the lid //quickly replace 1
the cover/lid of the crucible
(ii)
Empirical formula = RO
(iii)
2 R + O2 2 RO
Chemical formula
Balanced eq
1
1
Total
(a)
(b)
(d)
(i)
(ii)
(iii)
Chlorine
(i)
(ii)
2H+ + 2e H2
1.correct formula of reactant and product
2.correct balancing
2.4 dm3 //0.1 x 24 dm3
1
1
1
(i)
Hydroxide ion
(ii)
(c)
No of mole of R
= (30.64 28.24) / 24
=0.1 mol
No of mole of oxygen= (32.24 30.64) / 16
= 0.1 mol
Total
3
1
2
9
(a) (i)
Copper(II) sulphate
Carbon dioxide
CuCO3 + H2SO4 CuSO4 + H2O + CO2
(ii)
(b
)
Cu(OH)2
(c) (i)
(d
)
1
1
1
(ii)
(i)
1
1
1
(ii)
Green
4
10
(a)
(i)
(ii
)
(b
)
(c)
2W + 3X2 2WX3
Correct formula of products
Balanced equation
(i)
1
1
1
2
1
(ii
)
1
Number of shells and electrons
Charge
(d
)
4
Number of moles of Y = 40 = 0.1 mol
1
Total
3
10
(ii) n =
1.0 x 50
1000
1
1
// 0.05 mol
1
(iii)
H = 168
//
= - 33600 J mol-1
//
-1
- 33.60
0.05 kJ mol
1.68
0.05
(e)
1
1
H = - 33.60 kJ mol1
Fe 2+ + Cu
2
(f)
1
TOTAL
a)
Saponification
1
11
b)
c)
d)i
Hard water
ii
e)
Q : anion of soap react with magnesium ion and calcium ion in hard
water
scum produced
1. Pour 2 cm3 of soap and and detergent into different test tube
2. Add 2 cm3 of hard water into both test tube and shake
1
TOTAL
a)
1
1
1
3
11
Max 5
b)i
1
1
1
1
1
1
1
4
ii
Reaction 1
H2SO4 + 2NH3 ( NH4)SO4
Reaction 2
CO2 + 2NH3 CO(NH2)2 + H2O
1+1
1+1
4
1
1
1
1
1
1
TOTAL
(a)
(i)
Percentage of C in P
= 36
x 100%
44
= 81.81%
5
20
Percentage of C in Q
5
= 36 x 100%
42
= 85.7%
1
1
(ii)
Test I
1.P is saturated hydrocarbon/P has single bond
between carbon atoms
2.do not undergo addition reaction //do not react with
bromin
(b)
1
1
Test II
3.Q is unsaturated hydrocarbon /Q has double bond
between carbon atom
2.correct balancing
46
4. 1 mole of ethanol produce 2 mole of carbon dioxide//
0.05 mole of ethanol produce 0.1 mole of carbon dioxide
5. volume = 0.1 x 24 dm3//2.4 dm3
(c)
(i)
1.R
2.S
3.ethyl butanoate
4.
H H
H O
||
HCCCCOCCH
|
H H
6
(ii)
3.correct balancing
TOTAL
9(a)
20
1
1
1
Reaction Y
Oxidation number of zinc changes/increases from 0 to +2
(i)
(ii)
9 (c)
1+1
1+1
1
1
2
1
1
1
Observation
Galvanometer needle deflects
1+1
redox equation:
Br2 + 2Fe 2+ 2Br - + 2Fe3+
1+1
LAMPIRAN
Functional and labelled diagram
G
Q electrode
P electrode
Bromin water
8
Dilute sulphuric acid
Max
9
10.
(a)
1
1
1
Zinc/ magnesium
Nitric acid//hydrochloric acid//sulphuric acid
Catalyst: copper(II) sulphate
Fill a burette with water , invert into a basin with water, clamp
with retort stand, adjust the meniscus to 50 cm3
50cm3 of 1.0 mol dm-3 nitric acid is poured into a conical flask.
Excess zinc/ magnesium granules are added into the acid
A stopper with delivery tube is immediately connected to collect
the gas released.
(consider diagram if any)
Start the stop watch //the time taken/ to collect 50 cm3 of gas is
recorded.
Step 1 to 5 are repeated by adding copper(II) sulphate in step 2.
The present of catalyst/copper(II) sulphate will increase the rate
of reaction//reduced time taken to collect 50 cm3 of gas.
1
1
1
(c)
1.
2.
3.
4.
5.
6.
7.
1
1
1
10
Max 3
1
1
3
1
1
1
1
1
1
1
Total
Max 9
20