Appendix

634

C8

d Disperse

d Polar

d Polar
LOW

dH
Bonding

d H Bonding
LOW

Molar Volume cc/mole

MPa

Primary Group
0.4493

1.1409

Example Solvent

AcCH3

0.2167

0.6212

AcOH

0.4223

1.0520

Ac

0.7013

0.7661

0.1745

0.1553

0.1740

6.3284

AcCH2

0.6657

0.8019

0.2857

0.2298

0.8808

18.7669

m-Ethyltoluene

AcCl

0.8868

0.0941

0.0927

0.7512

0.4424

24.6543

m-Dichlorobenzene

AcF

0.1966

0.1293

0.6613

0.3718

17.0693

Fluorobenzene

AcNH2

1.6581

1.6493

4.4945

21.2133

Aniline

CN (except as
above)

0.3714

6.3705

0.5239

17.5817

cis-Crotonitrile

CON(CH3)2

0.7347

5.5309

3.2455

55.2907

N,N-Dimethylacetamide

AcNO2

1.3926

4.4640

0.7302

30.5165

Nitrobenzene

6.9757

0.2873
0

28.5986

Toluene

17.5750

Phenol
Naphthalene

Estimation of HSP from Group Contribution Methods

Table C8-5 Primary Groups used in the Stefanis Panayiotou Group Contribution Method (Continued)