Geometric Family
2
3
4
5
6
Linear
Trigonal planar
Tetrahedral
Trigonal bipyramidal
Octahedral
Hybridization of Central
Atom
sp
sp2
sp3
sp3d
sp3d2
5.
6.
(moleculesor,insomecases,atoms)inconstant,random,straightline
motion.
Moleculesofagasareseparatedbygreatdistances.Thegasismostly
emptyspace.(Themoleculesaretreatedassocalledpointmasses,as
thoughtheyhavemassbutnovolume.)
Moleculescollideonlyfleetinglywithoneanotherandwiththewallsof
theircontainer,andmostofthetimemoleculesarenotcolliding.
Thereareassumedtobenoforcesbetweenmoleculesexceptverybriefly
duringcollisions.Thatis,eachmoleculeactsindependentlyofalltheothers
andisunaffectedbytheirpresence,exceptduringcollisions.
Individualmoleculesmaygainorloseenergyasaresultofcollisions.Ina
collectionofmoleculesatconstanttemperature,however,thetotalenergy
remainsconstant
7.
8.
a. qualitative
The gas tends to be less ideal at high pressure and low temperature
The gas tends to be more ideal at low pressure and high temperature
Lower molecular weight or the smaller the size of its molecules, the
more ideal its behavior
Monatomic gases display ideal behavior more readily than do diatomic
gases
The weaker the intermolecular forces present, the more likely the gas
will behave ideally
b. quantitative (van der Waals equation)
(P+an2/V2)(Vnb)=nRT,whereaandbcanbelookedupfrom
tables.
Preal<Pideal:becauserealgasesdoexperienceintermolecularforces,
reducingcollisionwiththewallsofthecontainer
Vreal<Videal:realgasesdohavevolumethatreducestheeffective
volumeofthecontainer
Partial pressure, mole fraction
P=Pa+Pb+Pc
The partial pressure of a gas is equal to its mole fraction times the total
pressure
Daltons law relating partial pressure to composition
The total pressure is the sum of the partial pressures of all the constituent
gases.
9.Grahams law of Effusion
Definition of Effusion: The escape of a gas molecule through a very tiny
hole
Rate of effusionof Gas A
molar mass of Gas B
=
Rate of effusionof Gas b
molar mass of Gas A
rms vA
mB
=
rms vB
mA
1.
Phase diagram shows how its phases are determined by temperature and pressure
Normal melting point: draw a horizontal line at 1 atm pressure level, the
temperature at the point where this line crosses the solid-liquid boundary
Normal boiling point: draw a horizontal line at 1 atm pressure level, the
temperature at the point where this line crosses the liquid-gas boundary
Triple point: the temperature and pressure at which all three phases exist
simultaneously in equilibrium
Critical point: end of the liquid-gas boundary. Beyond this point, the substance
display properties of both a liquid and a gas. This substance is called supercritical
fluid, and no amount of increased pressure can force the substance back into its
liquid phase
The phase diagram for water is special: the solid-liquid boundary line is slightly
negatively sloped. At fix temp, when increasing pressure, water will favor the
liquid phase. Others, for example, CO2 will never turn to liquid with increased
pressure.
2.
3.
4.
5.
6.
SOLUTION CHEMISTRY
A. Ions in Solution
1. Anion, cation (common names, formulas, and charges for familiar ions; e.g., NH +,
ammonium; PO 3+, phosphate; SO42-, sulfate)
Ionic substance are strong electrolytes
Not completed dissolved (remain ion-paired to some extent) are weak electrolytes
Covalent compounds are nonelectrolytes
Salt Solubility rules:
o All group 1 and NH + salts are soluble
o All NO3-, ClO4-, and C2H3O2- salts are soluble
o All Ag+, Pb2+/Pb3+, and Hg22+/Hg2+ slats are insoluble, except for their salts
mentioned above.
o Cl2, Br2, and I2 are soluble
o Carbonates (CO3 2-), phosphates (PO4 3-), sulfides oxides (SO4 2-) and
hydroxides (OH-) are insoluble (sulfides of group 2 cations and hydroxides of
Ca2+,Sr2+, and Ba2+ are slightly soluble)
o Sulfates are soluble except for those of calcium, strontium and barium
Phase solubility rules
o Solubility of solid in liquid increase with temperature
o Solubility of gas in liquid decrease with temperature
o Solubility of gas in liquid increase with pressure
2. Hydration, the hydronium ion
4
Liters of solution
moles of solute
molality=
moles of substance S
mole fractionof S=
moles of solution