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7/7/2015

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Question1.
20mLof2%w/wH2SO 4solutionhavingdensity1.5g/mLismixedwith100mLofwater.Molarityoffinalsolutionis:
[A]
[B]
[C]
[D]

Question2.
Whichofthefollowingsetofquantumnumberswouldcorrespondtomaximumnumberofelectrons?
[A]
[B]
[C]
[D]

n=3,l=2
n=4,l=1,m=0
n=2
n=5,l=3

Question3.
Whichofthefollowingstatementiscorrect?
[A]
[B]
[C]
[D]

Duringcovalentbonding,only
giveshapetomolecule
Effectivenssof
dependsuponsidewaysoverlapofcombiningatomicorbitals.
remaininaplaneperpendiculartotheplaneof
px andpy orbitalsoftwocombiningatomscanmake

Question4.
100gsampleofchalk(CaCO 3)wasdissolvedin500mLof0.1MHClsolution.Afterthereactionandonboiling,50mLofreaction
mixturerequired30mLof0.1MNaOHforcompleteneutralisation.
Thepercentageofpurityofsampleofchalkis:
[A]
[B]
[C]
[D]

1
5
20
10

Question5.
TheratiooftotalnumberoflonepairsinentireXeF2moleculetonumberof
[A]
[B]
[C]
[D]

inCH2(CN) 2is:

3/4
3/2
9/4
3

Question6.
ThreemonoproticacidsHA,HBandHCwhenseparatelyneutralisedwithaqueoussolutionofNaOHreleased12.3Kcal,7.6Kcaland
11.8Kcalofenergyrespectively.Itsuggeststhattheir
[A]
[B]
[C]
[D]

ispositiveandorderof

isHB>HC>HA

HBistheweakestacidamongthethreegivenacids
forallcasesarenegative
Allarecorrectstatements

Question7.
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Theorderofwavelengthforelectron,protonand

movingwithkineticenergiesE,16Eand4Erespectivelyare:

[A]
[B]
[C]
[D]

Question8.
Inthefollowingunbalancedsequentialreactions:

Millimolesof

formedwhenstartedwith50mLof0.1M

through

followingsequenceofreactionsis:(Assuming%yeildofallthereactionsare100)
[A]
[B]
[C]
[D]

1
2
4
5

Question9.
Whichofthefollowingstatementisincorrect?
[A]
[B]
[C]
[D]

NumberofunpairedelectronsinCraresix
Chromiumingroundstateisdiamagnetic
Noangularnodearepresentinsorbitals
Zincingroundstateisdiamagnetic

Question10.
Whichofthefollowingstatementisincorrect?
[A]
[B]
[C]
[D]

CovalentcharacterinCuClismorethaninKCl
IoniccharacterisLiIislesserthaninKI
Beryliumhalidesgenerallyhavesignificantcovalentnature
PbCl4ismorestablethanPbCl2

Question11.
Readthefollowingthreereactionscarefully:
I.
II.

III.
Whichofthefollowingwouldbeincorrect?
[A]

IIis

[B]

IIIis

[C]

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[D]

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IandIIare

Question12.
Avesselcontaining1.0gofoxygenatapressureof10atmandatemperatureof47oC.Thepressuredropsto

ofitsoriginal

valueandtemperaturefallsto27oCduetoleakageofgas,themassofoxygenleakedoutwillbe:
[A]
[B]
[C]
[D]

0.22g
0.33g
0.11g
0.82g

Question13.
IfxmolofNaHC2O 4isoxidizedby0.4molof

inacidicmedium.MolesofCa(OH) 2requiredby2xmolofNaHC2O 4forits

completereactionis:
[A]
[B]
[C]
[D]

0.8
0.4
1.0
1.2

Question14.
Whichofthefollowingstatementsisincorrect?
[A]
[B]
[C]
[D]

Accordingtokineticgastheory,idealgashasnopotentialenergybuthasonlykineticenergy
Agasbelowitscriticaltemperaturecanbeliquefiedbyapplyingpressure.
IngeneralrealgasesatlowpressureshaveZ<1
Realgastendtobehaveideallywhenpressureishighandtemperatureislow

Question15.
TheenthalpychangeforwhichofthefollowingprocessesrepresentstheenthalpyofformationofAgCl?
[A]
[B]
[C]
[D]

Noneofthese

Question16.
Themagneticmomentof

(atomicnumber=25)is

B.M.Thenumberofunpairedelectronsandthevalueofx

respectivelyare:
[A]
[B]
[C]
[D]

4,3
3,4
3,2
5,2

Question17.
Whichofthefollowingmoleculehasmaximum(sp2s)

[A]
[B]
[C]
[D]
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Question18.
2moleseachofH2,SO 2andCH4arekeptinacontainer.Duetofaultinthevalveofcontainer,somegashaseffusedout.Whatwould
betheorderofpartialpressureofthesegasesinthecontainerwhenvalveisagainrepaired?
[A]
[B]
[C]
[D]

Question19.
Aquantityofhydrogengasoccupiesavolumeof30.0mLatacertaintemperatureandpressure.Whatvolumewouldhalfofthismassof
hydrogenoccupyattripletheabsolutetemperatureifthepressurewereoneninththatoftheoriginalgas?
[A]
[B]
[C]
[D]

270mL
90mL
405mL
135mL

Question20.
Whichofthemoleculewouldhavenonzerodipolemoment?
[A]
[B]
[C]
[D]

SF4
SO 3
CO 2
XeF4

Question21.
ThebonddissociationenergiesofgaseousH2,Cl2andHClare104,58and103kcalrespectivelytheenthalpyofformationofHClgas
wouldbe:
[A]
[B]
[C]
[D]

Question22.
Whichofthefollowingstatementis/arecorrect?
I.H2O 2hasbothpolarandnonpolarcovalentbonds.
II.Hbondsareactuallydipoledipoleinteractions
III.AllPFbondlengthsinPF5areidentical.
IV.DipolemomentofNH3islesserthanNF3.
[A]
[B]
[C]
[D]

I,II
I,III
III,IV
II,IV

Question23.
Atlowpressure,VanderWaal'sequationreducesto

.Thecompressibilityfactor(Z)maybewrittenas:

[A]

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[B]

[C]

[D]

Question24.
KIreactswithH2SO 4toproduceI2andH2S.Thevolumeof0.2MH2SO 4requiredtoproduce3.4gofH2Sis:
[A]
[B]
[C]
[D]

5L
3.8L
4L
2.5L

Question25.
Usingfollowingdata,thebondenthalpyofPClbondinPCl3(g)wouldbe:
Hf (PCl3,g)=306kJ/mole

Hatomization(P,(s))=314kJ/mole

Hf (Cl,g)=121kJ/mole

[A]
[B]
[C]
[D]

123.66kJ/mole
371kJ/mole
19kJ/mole
202kJ/mol

Question26.
Whichofthefollowingorderofpropertiesiswrong?
[A]

Size:

[B]
[C]

Electronegativity:H<P<S<F
Polarisingpower:

[D]

Numberofelectrons:

Question27.
TheratioofthedeBrogliewavelengthofaprotonand
[A]
[B]
[C]
[D]

particleswillbe1:2iftheir:

Velocityareintheration1:8
Velocityareintheratio8:1
Kineticenergyareintheratio1:64
Kineticenergyareintheratio1:256

Question28.
Howmanyorbitalswouldhave(n+l)greaterthan3butlessthan6inamultielectronatom?
[A]
[B]
[C]
[D]

13
5
8
10

Question29.
FortwogasesofmolecularweightMAandMBattemperatureTAandTBifhasTAMB=TBMA,thenwhichofthefollowingpropertieshas
thesamemagnitudeforboththegases?
[A]

Density

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[B]
[C]
[D]

QuestionRevision

Pressure
K.Epermole
Rootmeansquarevelocity

Question30.
Giventhat:
I.

II.

Usingabovedata,the

[A]
[B]
[C]
[D]

forfollowingreactionis:

227.2kJ
272.3kJ
333.6kJ
53.2kJ

Question31.
Afoodpacketisreleasedfromahelicopterwhichisrisingsteadilyat2ms1.Aftertwoseconds,howfarisitbelowthehelicopter?Given
thatg=9.8ms2.
[A]
[B]
[C]
[D]

19.6m
9.8m
4.9m
39.2m

Question32.
Abusbeginstomovewithanaccelerationof1ms2.Amanwhowantstoboarditcanrunat9ms1.
Hecatchesitin8secondsifheisxmbehindthebuswhenitstarts.xwillbe:
[A]
[B]
[C]
[D]

8m
40m
104m
Noneofthese

Question33.
Ariver1kmwideisflowingat3kmh1.Aswimmerwhosevelocityinstillwateris4km/hcanswimonlyfor15min.Thedirectionwiththe
flowinwhichheshouldtrytoswim,inordertoreachtheoppositebankis:
[A]
[B]
[C]
[D]

Alongtheflow
Itisimpossibletodoso
37owiththeflow
90owiththeflow

Question34.
AlargemassMandasmallmassmhangatthetwoendsofastringthatpassesthroughathin,smoothtubeasshowninFigure.The
massmmovesaroundinacircularpathwhichliesinthehorizontalplane.Thelengthofthestringfromthemassmtothetopofthetube
is
istheanglethislengthmakeswiththevertical.FrequencyofrotationofthemassmsothatthemassMremains
stationaryis:

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[A]

[B]

[C]

[D]

Question35.
Aparticleofmass102kgismovingalongthepositivexaxisundertheinfluenceofaforce
,whereK=102Nm2.Attimet=0,itisatx=1.0manditsvelocityisv=0.Itsvelocitywhenitreachesx=0.50mis

F(x)=
:
[A]
[B]

1m/s
0.5m/s

[C]
[D]

1m/s

Question36.
Aballoonofmass
isrisingupwithanaccelerationg/2.Assumetheupthrustofairtobesame.Neglectairresistance.Thefraction
ofweightoftheballoonthatmustbedetachedinordertodoubleitsaccelerationis:
[A]
[B]
[C]
[D]

Question37.
Therearsideofatruckisopenandaboxof40kgmassisplaced5mawayfromtheopenendasshowninfigure.Coefficientoffriction
betweentheboxandthesurfacebelowis0.15.
Onastraightroad,thetruckstartsfromrestandaccelerateswith2ms2.Thedistanceoftruckfromstartingpoint,whentheboxfallsoff
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thetruckwillbe:(Ignorethesizeofthebox).

[A]
[B]
[C]
[D]

20m
15m
5m
10m

Question38.
AsphericalmetalballAofmass0.5kgmovingwithaspeedof0.5ms1onasmoothlinearhorizontaltrackcollidesheadonwith
anotheridenticalballBatrest.Assumingthecollisiontobeperfectlyelastic,speedsofAandBafterthecollisionrespectivelywillbe:
[A]
[B]
[C]
[D]

0.5m/s,0.5m/s
0,1m/s
0,0.5m/s
0.5m/s,0

Question39.
Aheavyblockofmass300kgisbeingpulleduponaninclinedplaneofangle30obymeansofawirepassingoverapulleyand
connectedtoamotorasshowninfigure.Ifthepoweroutputofthemotoris5kWandtheblockmovesupwithaconstantvelocityof2
ms 1,coefficientoffrictionbetweentheblockandtheinclinedplaneis:(Takeg=10ms2).

[A]
[B]
[C]
[D]

0.39
0.5
0.3
Noneofthese

Question40.
Abodyofmass1kginitiallyatrestexplodesandbreaksintothreefragmentsofmassesintheratio1:1:3.Thetwopiecesofequal
massflyoffperpendiculartoeachotherwithaspeedof30ms1each.Thespeedwithwhichtheheavierfragmentfliesoffis:
[A]

10m/s

[B]
[C]
[D]

20m/s

Question41.
Abulletofmass0.01kgisfiredhorizontallyintoastationarywoodenblockofmass0.19kg,placeonahorizontalsurface.Thevalueof
betweentheblockandthesurfaceis0.25.Thebulletgetsembeddedintheblockandthecombinationmoves20mbeforecoming
torest.Thespeedwithwhichbulletstrikestheblockis:
[A]
[B]
[C]
[D]

200m/s
100m/s
20m/s
Noneofthese

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Question42.
Aballofmass0.2kgrestsonaverticalpostofheight5m.Abulletofmass0.01kg,travellingwithavelocityvm/sinhorizontaldirection,
penetratesthroughthecentreoftheball.Afterthecollision,theballandbullettravelindependently.Theballhitsthegroundatadistance
of20mandthebulletatadistanceof100mfromthefootofthepost.Theinitialvelocityvofthebulletis:

[A]

250m/s

[B]
[C]
[D]

400m/s
500m/s

Question43.
TwoparticlesofmassesMand4Maremovingwithequalkineticenergy.Theratiooftheirlinearmomentsis:
[A]
[B]
[C]
[D]

1:8
1:4
1:2
4:1

Question44.
Considerthefollowingstatement.Whenjumpingfromaheight,youshouldbendyourkneesasyoucometorestonground,insteadof
keepingyourlegsstiff.Whichofthefollowingrelationscanbebestusedinexplainingthisstatement?
[A]
[B]
[C]
[D]

Question45.
Amanofmass50kgisstandingatoneendonaboatoflength25mandmass200kg.Ifhestartsrunningandwhenhereachestheother
end,hehasavelocity2ms1withrespecttotheboat,thefinalvelocityoftheboatis:(inms1)
[A]

[B]

[C]

[D]

Question46.
Ashellinitiallyatrestexplodesintotwopiecesofequalmass.Noexternalforceactsontheshell.Thetwopieceswill:
[A]
[B]
[C]
[D]

Movewithdifferentspeedsindifferentdirections
Movewiththesamespeedinoppositedirections
Movewiththesamespeedinthesamedirection
Beatrest

Question47.
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Aballofmassmmoveswithspeedvanditcollidesnormallywithawallandisreflectedbacknormally.Ifthetimeofcontactwithwall
ist,thentheaverageforceexertedbyballonthewallis:
[A]

[B]
[C]

mvt

[D]

Question48.
Abulletisfiredfromagun.TheforceonthebulletisgivenbyF=6002
105twhereFisinnewtonandtinseconds.Theforceon
thebulletbecomeszeroassoonasitleavesthebarrel.Theaverageimpulseimpartedtothebulletis:
[A]
[B]
[C]
[D]

9Ns
1.8Ns
0.9Ns
0.3Ns

Question49.
Considerthefollowingtwostatements:
I.Linearmomentumofasystemofparticlesiszero.
II.Kineticenergyofasystemofparticlesiszero.
Then:
[A]
[B]
[C]
[D]

IdoesnotimplyIIandIIdoesnotimplyI
IimpliesIIbutIIdoesnotimplyI
IdoesnotimplyIIbutIIimpliesI
IimpliesIIandIIimpliesI

Question50.
BlockAofmass2kgisplacedoverblockBofmass8kg.Thecombinationisplacedoveraroughhorizontalsurface.Coefficientof
frictionbetweenBandtheflooris0.5.CoefficientoffrictionbetweenAandBis0.4.Ahorizontalforceof10NisappliedonblockB.The
forceoffrictionbetweenAandBis:

[A]
[B]
[C]
[D]

Zero
50N
40N
100N

Question51.
Twomasses8kgand12kgareconnectedatthetwoendsofastringthatgoesoverafrictionlesspulley(Atwood'smachine).
Accelerationofthemassesandthetensioninthestringrespectivelywillbe:
(Takeg=10m/s 2)
[A]
[B]
[C]
[D]

8m/s 2,144N
4m/s 2,112N
6m/s 2,128N
2m/s 2,96N

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Question52.
Startingfromrest,thetimetakenbyabodyinslidingdownaroughinclinedplane,inclinedat45owiththehorizontal,istwicethetime
takentoslidedownasmoothplaneofsameinclinationandsamelength.Thenthecoefficientofkineticfrictionbetweenbodyandincline
is:
[A]
[B]
[C]
[D]

0.25
0.33
0.50
0.75

Question53.
TwomassesAandBof15kgand10kgareconnectedwithastringpassingoverafrictionlesspulleyfixedatthecornerofatable
(asshowninfigure).Thecoefficientoffrictionbetweenthetableandblockis0.4.
TheminimummassofC,thatmaybeplacedonAtopreventitfrommovingis:

[A]
[B]
[C]
[D]

10kg
5kg
Zero
15kg

Question54.
Considerelasticcollisionofaparticleofmassmmovingwithavelocityuwithanotherparticleofthesamemassatrest.Afterthe
collisiontheprojectileandthestruckparticlemoveindirectionsmakingangles
respectivelywiththeinitialdirectionof
motion.Thesumoftheangles
[A]
[B]
[C]
[D]

45o
90o
135o
180o

Question55.
Anelasticballisdroppedfromaheighthanditreboundsmanytimesfromthefloor.Ifthecoefficientofrestitutionise,thetimeinterval
betweenthesecondandthethirdimpact,is:
[A]

[B]

[C]

[D]

Question56.

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Apointmassmovingwithvelocity

strikesasmoothsurfaceandrebundswithavelocity

.Coefficientofrestitution

forthiscollisionmustbe:
[A]

[B]

[C]

[D]

Question57.
AstoneofmassmtiedatoneendofanidealstringiswhirledintoaverticalcircleofradiusL.Atonepointoftime,itsspeedisvand
increasingattherateof
m/severysecond.Thenpowerdevelopedbytheforceoftensionatthisinstantwillbe:
[A]
[B]
[C]
[D]

Zero
Noneofthese

Question58.
Consideracollisionoftwosphericalbodiesofequalmassof4kgeach.Oneismovingwithvelocity5m/sandtheotherisatrest.
Maximumpossibleenergyassociatedwithdeformationoftwobodieswillbe:
[A]
[B]
[C]
[D]

25J
50J
12.5J
Datainsufficent

Question59.
AbobofmassMissuspendedbyamasslessstringoflenghtL.ThehorizontalvelocityvatpositionAisjustsufficienttomakeitreach
thepointB.Theangle
atwhichthespeedofthebobishalfofthatatA,satisfies:

[A]

[B]

[C]

[D]

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Question60.
Thefigureshowsacircularpathofamovingparticle.Atsomeinstantvelocityofparticleisv=

.Throughwhichquandrantis

theparticlemovingatthisinstant,consideringclockwiseandanticlockwisemotionrespectively?

[A]
[B]
[C]
[D]

1stand4th
4thand2nd
2ndand3rd
3rdand4th

Question61.
If

,thenorthocenterof

is:

[A]

[B]

[C]
[D]

Datainsufficient

Question62.
Ifina

,Bistheorthocenterandifcircumcenterof

is

andvertexAis

thencoordinateofvertexC

is:
[A]
[B]
[C]
[D]

Question63.
AreaincludedbyL1:

andL2:

is:

[A]

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[B]

[C]

[D]

Question64.
Thepoint

istranslatedparalleltotheline

thecoordinatesof

byadistance4units.Ifitsnewposition

isinthirdquadrantthen

are:

[A]
[B]
[C]
[D]

Question65.
Statement1:Eachpointontheline

isatsamedistancefromthelines

and

.
Statement2:Locusofpointwhichisatequaldistancefromthetwogivenintersectinglinesistheanglebisectorsofthetwolines.
[A]
[B]
[C]
[D]

Statement1isTrue,Statement2isTrueStatement2isacorrectexplanationforStatement1
Statement1isTrue,Statement2isTrueStatement2isNOTacorrectexplanationforStatement1
Statement1isTrue,Statement2isFalse
Statement1isFalse,Statement2isTrue

Question66.
If

and

betheangularpointsofa

thenincentreofthattriangleis:

[A]
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[B]
[C]
[D]

Question67.
Therangeofparameter'a'forwhichthevariableline

liesbetweenthecircles

and

withoutintersectingeithercircleis:
[A]
[B]
[C]
[D]

Question68.
Ontheportionofthestraightline

interceptedbetweentheaxes,asquareisconstructedonthesideofthelineawayfrom

theorigin.Thenthepointofintersectionofitsdiagonalshascoordinates:
[A]
[B]
[C]
[D]

Noneofthese

Question69.
Acirclewhosecentreliesinfirstquadrantpassesthrough

andcutoffequalchordsoflength4unitsalongthelines

:
[A]
[B]
[C]
[D]

Question70.
Thevalueofcforwhichtheset

and

containsonlyonepointin

commonis:
[A]
[B]
[C]
[D]

Question71.
Statement1:Notangentcanbedrawnfromthepoint

tothecircle

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Statement2:Thepowerofthepointofthecircle

withrespecttothepoint

isnegativethen

pointliesinsidethecircle.
[A]
[B]
[C]
[D]

Statement1isTrue,Statement2isTrueStatement2isacorrectexplanationforStatement1
Statement1isTrue,Statement2isTrueStatement2isNOTacorrectexplanationforStatement1
Statement1isTrue,Statement2isFalse
Statement1isFalse,Statement2isTrue

Question72.
Whichofthefollowingfunctionisneitherevennorodd?
(where[.]denotesthegreatestintegerfunction)

[A]

[B]

[C]
,where

[D]

isrealvaluefunction

Question73.
If

,definedby

definedby

,thenregardinggofwhich

ofthefollowingstatementisincorrect:
[A]

Domainof

[B]

Rangeof

is
is

[C]
[D]

Question74.
Ifdomainoffunctionfis

[A]

Domainof

[B]

Domainof

[C]

Domainof

[D]

Noneofthese

,thenwhichofthefollowingstatementsisincorrect.

is
isR(where[.]denotesthegreatestintegerfunction)
is

(where{.}denotesthefractionalpartofx)

Question75.
If

forallrealx,if

,thenthevalueof

[A]
[B]

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[C]
[D]

Noneofthese

Question76.
If
[A]
[B]
[C]
[D]

isperiodicfunction,thenamustbe:
Aninteger
Arationalnumber
Anirrationalnumber
Noneofthese

Question77.
Thefunction
[A]
[B]
[C]
[D]

isdefinedforallrealx,if

,then

is:

2010
2012
4

Question78.
If

,where

of

forwhich

isarealvaluedfunction,thentherange

isdefined.

[A]
[B]
[C]
[D]

Noneofthese

Question79.
Thefundamentalperiodofthefunction

is:(where[.]denotesthegreatest

integerfunction)
[A]
[B]
[C]
[D]

Noneofthese

Question80.
If
[A]
[B]
[C]
[D]

isapolynomialsatisfying

and

,then

isequalto:

16
17
19
21

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Question81.
Graphofquadraticexpression

isgiven,then:

[A]
[B]
[C]
[D]

Question82.
Valueofxwhichsatisfy

is:

[A]
[B]
[C]
[D]

Question83.
Valueof

sothatquadraticequation

hasonerootliesbetween1and2andanotherroot

liesbetween2and3is:
[A]
[B]
[C]
[D]

Question84.
If
[A]

arerootsof

,thenvalueof

is:

[B]
[C]
[D]

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Question85.
Leastvalueof
[A]
[B]

is:

4
6

[C]
[D]

Question86.
Thevalueoftheexpression

is:

[A]
[B]
[C]
[D]

1
2
Noneofthese

Question87.
Generalsolutionof

is:

[A]
[B]
[C]
[D]

Noneofthese

Question88.
Thecompletesolutionofinequality

is:

[A]
[B]
[C]
[D]

Question89.
If

then

istruefor:

[A]
[B]
[C]
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[D]

Question90.
Ifequation
[A]
[B]
[C]
[D]

isidentifyinxthenthevalueofris:

1
2
Notpossible

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