13-1
13-2
13-3
Table 13-3: Reid Vapor Pressure Blending Index Numbers for Gasoline and Turbine Fuels.
Vapor
Pressure,
psi
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
0 0.00 0.05
0.13
0.22
0.31
0.42
0.52 0.64 0.75
0.87
1 1.00 1.12
1.25
1.38
1.52
1.66
1.79 1.94 2.08
2.23
2 2.37 2.52
2.67
2.83
2.98
3.14
3.30 3.46 3.62
3.78
3 3.94 4.11
4.28
44.4
4.61
4.78
4.95 5.13 5.30
5.48
4 5.65 5.83
6.01
6.19
6.37
6.55
6.73 6.92 7.10
7.29
5 7.47 7.66
7.85
8.04
8.23
8.42
8.61 8.80 9.00
9.19
6 9.39 9.58
9.78
9.98
10.2
10.4
10.6 10.8 11.0
11.2
7 11.4 11.6
11.8
12.0
12.2
12.4
12.6 12.8 13.0
13.2
8 13.4 13.7
13.9
14.1
14.3
14.5
14.7 14.9 15.2
15.4
9 15.6 15.8
16.0
16.2
16.4
16.7
16.9 17.1 17.3
17.6
10 17.8 18.0
18.2
18.4
18.7
18.9
19.1 19.4 19.6
19.8
11 20.0 20.3
20.5
20.7
20.9
21.2
21.4 21.6 21.9
22.1
12 22.3 22.6
22.8
23.0
23.3
23.5
23.7 24.0 24.2
24.4
13 24.7 24.9
25.2
25.4
25.6
25.9
26.1 26.4 26.6
26.8
14 27.1 27.3
27.6
27.8
28.0
28.3
28.5 28.8 29.0
29.3
15 29.5 29.8
30.0
30.2
30.5
30.8
31.0 31.2 31.5
31.8
16 32.0 32.2
32.5
32.8
33.0
33.2
33.5 33.8 34.0
34.3
17 34.5 34.8
35.0
35.3
35.5
35.8
36.0 36.3 36.6
36.8
18 37.1 37.3
37.6
37.8
38.1
38.4
38.6 38.9 39.1
39.4
19 39.7 39.9
40.2
40.4
40.7
41.0
41.2 41.5 41.8
42.0
20 42.3 42.6
42.8
43.1
43.4
43.6
43.9 44.2 44.4
44.7
21 45.0 45.2
45.5
45.8
46.0
46.3
46.6 46.8 47.1
47.4
22 47.6 47.9
48.2
48.4
48.7
49.0
49.3 49.5 49.8
50.1
23 50.4 50.6
50.9
51.2
51.5
51.7
52.0 52.3 52.6
52.8
24 53.1 53.4
53.7
54.0
54.2
54.5
54.8 55.1 55.3
55.6
25 55.9 56.2
56.5
56.7
57.0
57.3
57.5 57.9 58.1
58.4
26 58.7 59.0
59.3
59.6
59.8
60.1
60.4 60.7 61.0
61.3
27 61.5 61.8 62.1I 62.4
62.7
63.0
63.3 63.5 63.8
64.1
28 64.4 64.7
65.0
65.3
65.6
65.8
66.1 66.4 66.7
67.0
29 67.3 67.6
67.9
68.2
68.4
68.8
69.0 69.3 69.6
69.9
30 70.2 Example:
40 101 Calculate the vapor-pressure of a gasoline blend as follows
(nC4) 51.6 138
Vapor
Vapor
Volume
(iC4) 72.2 210
Component
Volume
Pressure
Pressure
Fraction
(C3) 190.0 705
Fraction
psi
Blending
x
Index No.
VPBI
Equation:
VPBI = VP1.25
n-Butane
Light Straight Run
Heavy Refined
Total
0.050
0.450
0.500
1.000
51.6
6.75
1.00
7.45
138
10.9
1.00
12.3
6.90
4.90
0.50
12.3
From the brochure, 31.0API Iranian Heavy Crude Oil, by arrangement with Chevron
Research Company. Copyright 1971 by Chevron Oil Trading Company.
13-5
(BPDi)
n-butane
2
W
HSR gasoline
8
1250
LSR gasoline
6
750
C5+ FCC gasoline 18
620
Total for blend
2620 + W
(BPDi)
(RVPi)
(VPBIi)
Table 13-1 Table 13-3
52
139.64
1.0
1.0
11.1
20.3
4.4
6.37
(BPDi)(VPBIi)
139.64W
1250.00
15225.00
3949.40
139.64W + 20424.4
(BPDi)(VPBIi)
b.
Component
BPD
n-butane
HSR gasoline
LSR gasoline
C5+ FCC gasoline
Total for blend
2
8
6
18
165
1250
750
620
2785
Vol.
Frac.
0.0592
0.4488
0.2693
0.2226
BMON
Table 13-1
92.0
58.7
61.6
76.8
BRON
Table 13-1
93.0
62.3
66.4
92.3
MON x
Vol. frac.
4.85
26.34
16.59
17.10
64.9
RON x
Vol. frac.
5.51
27.96
17.88
20.55
71.9
BPD
Vol.
Frac.
0.054
0.408
0.245
0.202
.091
MON
RON
MON x Vol.
RON x
frac.
Vol. frac.
n-butane
165
92.0
93.0
4.97
5.022
HSR gasoline
1250
58.7
62.3
23.95
25.42
LSR gasoline
750
61.6
66.4
15.1
16.27
C5 FCC gasoline
620
76.8
92.3
15.51
18.64
MTBE
101
118
9.19
10.74
278.5
Total
3063.5
68.72
76.1
76.1
68.72
(vol. frac. x RON) (vol.frac. x MON)
PON of the blend =
=
= 72.4
2
2
BLENDING FOR OTHER PROPERTIES
Several methods exist for estimating the physical properties of a blend from those of
the blending stocks.
One of the most convenient methods of estimating properties, that do not blend
linearly, is to substitute for the true value of the inspection to be blended another
value (called blending factor or index) which has the property of blending
approximately linear.
The Chevron Research Company has compiled factors or index numbers for,
Viscosities, Table 13-6
Flash points, Table 13-7
Aniline points, Error! Reference source not found.
Pour point, Error! Reference source not found.
Blending for Viscosity
Viscosity blending is more complicated than blending for the other properties.
It is not an additive property and it is necessary to use special techniques to estimate
the viscosity of a blend from the viscosities of its blending stocks.
The method most commonly accepted is the use of special charts developed by and
obtainable from ASTM.
The viscosity factor of the blend can be calculated using the equation:
(VF) blend = Xvi (VF)i
where, Xvi = Volume fraction.
(VF)i = Viscosity factor for component i (Table 13.4).
(VF)blend = Viscosity factor for the blend.
13-7
Example 13-4
Calculate the viscosity, flash point, aniline point, and pour point of the blend from the following
blending stocks.
Stock
bbls
A
B
C
Blend
5,000
3,000
2,000
10,000
ASTM 50%
temp (F)
575
425
500
Viscosity
430 SFS at 120 F
82.5 SUS at 130 F
2.15 cSt at 130 F
?
Flash point
(F)
100
90
130
?
Aniline
point (F)
70
160
40 (mixed)
?
Pour point
(F)
10
50
65
?
Solution:
a. Viscosity
Stock
A
B
C
Total
vol. frac.
of blend
0.5
0.3
0.2
1
Viscosity
Factor
(Table 13-6)
0.700
0.500
0.300
vol. frac. x
Factor
0.350
0.150
0.060
0.560
Table 13-6 gives the following viscosities for a blend with a factor of 0.56
39.5 cSt at 130 F
183 SUS at 130 F
25.7 SFS at 122 F
b. Flash point
Stock vol. frac. of blend
A
B
C
Total
0.5
0.3
0.2
1
Blending Index (
Table 13-7)
753
1,170
224
Table 13-7 gives a flash point for the blend of 99.5 F for a blending index of 772.
c. Aniline Point
Stock
vol. frac.
of blend
A
0.5
B
0.3
C
0.2
Total
1
70
160
40 (mixed)
Table 13-6 gives for a blending index of 345 an aniline point for the blend of 69.5 F or a mixed
aniline point of 115 F.
d. Pour Point
Stock
vol. frac.
of blend
A
0.5
B
0.3
C
0.2
Total
1
ASTM 50%
temp (F)
575
425
500
13-9
Blending Index
(Table 13-7)
8
61
98
vol. frac. x
index
4
18.3
19.6
41.9
Notice that for the Octane number and the pour point the property (not the index) is
calculated, therefore, there is no need to go back to the Table to get the desired property.
Blending for Freezing point
Index
210.1
238.8
272.4
310.8
353.8
402.0
459.4
523.6
595.3
678.5
774.5
881.8
1001.3
1144.5
1305.0
1484.2
1689.9
1929.7
2198.0
2496.8
2851.1
3252.2
3700.2
4209.2
4807.9
5478.5
6225.8
7102.2
8104.3
9224.3
10483
11979
13654
15523
17691
20194
22994
26109
29842
33576
bbls
5,000
3,000
2,000
10,000
Solution:
Freezing Point (F) using table
Stock vol. frac. Freezing point (F) Freezing Point vol. frac. x index
of blend
blending index
A
0.5
-55
7.5199
3.7600
B
0.3
-50
9.0135
2.7041
C
0.2
-51
8.6928
1.7386
Total
1
8.2027
Table gives a freezing point of -52.7 F for a blend with a factor of 8.2027
In terms of equations
British units
FPBIFi = 55.16793 (1.0368976)FPFi
FPBIm = Xvi (FPBI)i
FPFm = -111.1628+27.68212 ln (FPBIm)
FPFi = freezing point of component i in F
FPFm = freezing point of the blend in F
FPBIi = freezing point blending index for component i
FPBIm = freezing point blending index for the blend
Xvi = volume fraction of component i
Freezing Point (F) using equations
Stock vol. frac. Freezing point (F) Freezing Point vol. frac. x index
of blend
blending index
A
0.5
-55
7.5199
3.7600
B
0.3
-50
9.0135
2.7040
C
0.2
-51
8.6928
1.7386
Total
1
8.2026
Equation gives a freezing point of -52.9 F for a blend with a factor of 8.2026
13-12
In SI units
FPBIFi = 55.16793 (1.0368976)FPFi
FPBIm = Xvi (FPBI)i
FPFm = -111.1628+27.68212 ln (FPBIm)
FPFi = freezing point of component i in F
FPFm = freezing point of the blend in F
FPBIi = freezing point blending index for component i
FPBIm = freezing point blending index for the blend
Xvi = volume fraction of component i
Freezing Point (K) using table
Stock vol. frac. Freezing point (K) Freezing Point vol. frac. x index
of blend
blending index
A
0.5
225
7.5199
3.7600
B
0.3
227.8
9.0278
2.7083
C
0.2
227.2
8.7028
1.7406
Total
1
8.2089
Table gives a freezing point of 226.3 K (-52.7 F) for a blend with a factor of 8.2026
Freezing Point (K) using equation
Stock vol. frac. Freezing point (K) Freezing Point vol. frac. x index
of blend
blending index
A
0.5
-225
7.5580
3.7790
B
0.3
227.8
9.0712
2.7214
C
0.2
227.2
8.7233
1.7447
Total
1
8.2450
Equation gives a freezing point of 226.2 K (-52.8 F) for a blend with a factor of 8.2026
Smoke point
Stock
A
B
C
Blend
vol. frac.
of blend
0.5
0.3
0.2
1
Smoke Point
(mm)
25
22
21
Smoke Point x
vol. frac.
12.5
6.6
4.2
23.3
13-13
Table 13-6 maybe digitized and the following equations are obtained,
For blend no. 1
X1 = log10 (visc.1)
(1)
0.17 + 0.5238 1
1 + 0.5124 1 0.01233 12
(2)
or
= (X1 + 0.3103)/10
= 0.291694 ()0.164017
1 = 1.05593 ()
(3)
for the viscosity in SUS use one of the following two equations
1 = 0.6068 + 0.047971
0.80755
12
(4)
or
1 =
97993438 + 103852082 1
1 + 118310078 1 3052999 12
(3)
or
VF1 = 0.5909 (X1 -1.4414)0.25372
for viscosity in SFS use
VF1 = 0.5008 X10.345
(5)
For blend no. 2, use the above equations 1 through 4. For example, Equations 1 and 2 would
become,
X2 = log10 (visc.2)
2 =
0.17 + 0.5238 2
1 + 0.5124 2 0.01233 22
13-14
VFblend
(6)
(7)
0.3148 + 1.796 ( )
1 1.26376 ( ) + 0.4498 ( )2
To calculate the viscosity of the blend in SUS use either of the following equations
log(. ) =
(8)
(9)
33.4177 ( )3.9746
log(. ) = 1.4123 +
3.7246 + ( )3.9746
(10)
(11)
Example 13-6: Blending for viscosity using above (Albahri Viscosity Blending equations)
visc.i
500
300
200
Total
VFi
0.691
0.669
0.651
Vi
vol frac x factor
0.3333
0.230
0.3333
0.223
0.3334
0.217
0.670
Viscosity
500 cSt at 130 F
300 cSt at 130 F
200 cSt at 130 F
Factor
(Table 13-6)
0.689
0.663
0.648
Table 13-6 gives 300 cSt at 130 F for a blend with a factor of 0.667
13-15
vol. frac. x
Factor
0.230
0.221
0.216
0.667
Example 13-7: Blending for viscosity using above (Albahri Viscosity Blending equations)
visc.i
500
300
200
Total
VFi
0.691
0.669
0.651
Vi
vol frac x factor
0.3333
0.230
0.3333
0.223
0.3334
0.217
0.670
Viscosity
500 cSt at 130 F
300 cSt at 130 F
200 cSt at 130 F
Factor
(Table 13-6)
0.689
0.663
0.648
vol. frac. x
Factor
0.230
0.221
0.216
0.667
Table 13-6 gives 300 cSt at 130 F for a blend with a factor of 0.667
Example 13-8: Convert the viscosity of an oil sample having 100 cSt to SUS and SFS
Solution: From the Table 13-6 the viscosity factor for 100 cSt is 0.613. This factor
corresponds to 460 SUS and 62 SFS at 122 F.
Numerical Method
From equation (3) get the viscosity factor
X1 = log (vcSt) = log (100) = 2
(9)
13-16
(11)
An alternate numerical method for calculating the pour point of distillate blending stocks.
The pour point blending index is given by the following equations instead of Table
In kelvin
PPBI(K)i = 255.565 + 4.9021110-6 exp [-0.016418 (PPK) - 0.0522346 (TbK)
+ 1.5751 10-4 (PPK)(TbK)] (PPK)1.67057 (TbK)2.37162
PPBI(K)i = pour point blending index for component i in Kelvin
PPK = pour point in kelvin
TbK = ASTM distillation curve 50% temperature in kelvin (average boiling point)
In Fahrenheit
PPBIFi = 0.1786 + 0.425117 exp [0.0147 (PPF+70) - 0.00887 (TbF) + 4.925 10-5 (PPF+70)(TbF)]
(PPF+70)0.1894 (TbF)0.5855
PPBIFi = pour point blending index for component i in F
PPF is pour point in F
TbF = ASTM distillation curve 50% temperature in F (average boiling point)
The procedure is to calculate the PPBI for each component using the equation then add to obtain the
pour point of the blend
PP = Xvi PPBIKi
Example 13-9
Applied to the previous example to calculate the pour point, the above equations will yield,
d. Pour Point (F eqn)
Stock
A
B
C
Total
vol. frac.
of blend
0.5
0.3
0.2
1
Pour Point
(F)
vol. frac. x
index
10
50
65
575
425
500
7.8
60.6
98.3
3.92
18.17
19.66
41.8
ASTM 50%
temp (F)
Pour
Point
(F)
ASTM 50%
temp (K)
Blending Index
(Table 13-7)
vol. frac.
x index
575.0
491.7
533.3
259.90
289.16
310.27
129.95
86.75
62.05
278.8
(K)
575
425
500
261.1
283.3
291.7
13-17
41.8
An alternate method for calculating the flash point of blending stocks.
The flash point blending index is given by the following equations instead of the Table
In British units: (FPBI)i = (0.3792866 + 2.085510-3 FPFi)-12.4108
In SI Units: (FPBI)i = (-0.5800437+ 3.753910-3 FPKi)-12.4108
FPFi = Flash point of component i in F
FPKi = Flash point of component i in Kelvin
Xvi = volume fraction of component i
(FPBI)m = Flash point index for the blend
(FPBI)m = Xvi (FPBI)i
The flash point is then calculated for the blend using the following equations
In British units: FPFm = [327.0522 -27.1872 ln(FPBIm)]/[1+ 0.071016 ln(FPBIm)
-2.766222-5 ln(FPBIm)2]
In SI units: FPKm = [437.250592356 + 4.0809276 ln(FPBIm)]/[1+ 0.0733857193 ln(FPBIm)
+ 1.40131821823232-4 ln(FPBIm)2]
Example 13-10
Applied to the previous example to calculate the flash point, the above equations will yield,
b. Flash point (F)
Stock vol. frac. of blend Flash point (F) Blending Index (Table 13-5) vol. frac. x index
A
0.5
100
730.7
365.3
B
0.3
90
1143.9
343.2
C
0.2
130
208.2
41.6
Total
1
750.2
from eqn Flash =
100.1
vol. frac. of
blend
0.5
0.3
0.2
1
311.2
K or
Flash point
(K)
311.1
305.6
327.8
100.1
13-18
Blending Index
(Table 13-5)
730.7
1144.0
208.2
An alternate numerical method for calculating the aniline point of distillate blending stocks.
The aniline point blending index is given by the following equations instead of the Table
In British units:
APBIi = 49.11 (1 + 0.05 APFi)1.3004
In SI Units:
APBIi = 4852.435 + 14.7655 APKi +
73778706
2
(more accurate)
32
In SI units:
APKm =
(more accurate)
An alternate numerical method for calculating the mixed aniline point of distillate blending
stocks.
The mixed aniline point blending index is given by the following equations instead of the
Table
In British units:
MAPBIi =1090 + 2221 cos (0.005425 MAPFi + 3.7453)
13-19
(more accurate)
(740.124+8.8357 )
(more accurate)
(650.1+2.796 )
MAPFm = (1+2.184104
2)
7.166108
In SI units:
1
6 (ln( +1000))3 ]
+1000)5.05810
accurate)
1
[231.53+0.3032 ( +1000)]
MAPKm = [1+8.46104 (
2
8
+1000)7.5610 ( +1000)
MAPKm =
13-20
(least accurate)
(more
Example 13-11
Applied to the previous example to calculate the aniline point, the above equations will yield,
Aniline point (F)
Stock vol. frac. of blend Aniline point (F) Blending Index (Eq.) vol. frac. x index
A
0.5
70
347.2
173.6
B
0.3
160
855.2
256.6
C
0.2
40 (mixed)
-424.1
-84.8
Total
1
345.4
from eqn. aniline point =
69.6
from eqn. mixed aniline point =
F
115.2
0.5
0.3
0.2
1
294.4
344.4
277.8
A
B
C
Total
K or
319.6
Blending Index
(Eq.)
346.2
855.3
-242.0
69.5
K or
F
115.3
N1 + N2 + N3 = 300,000
Constraints:
N1 500,000
N2 400,000
N3 600,000
13-21
where
X1 = n1/(n1+n2+n3)
X2 = n2/(n1+n2+n3)
X3 = n3/(n1+n2+n3)
Solver solution indicates that
N1 = 0
N2 = 59,970
N3 = 240,030
Blend properties
API = 71.4 (giveaway)
ON = 95.2
RVP = 8.2 psig
Figure 13-4: Product blending using linear programming and the solver function of Microsoft Excel.
13-22
0.5
0.6
0.7
0.8
0.9
0.00
0.01
0.02
0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.000
0.056
0.097
0.128
0.154
0.006
0.061
0.100
0.131
0.156
0.013
0.065
0.104
0.134
0.159
0.019
0.069
0.107
0.137
0.161
0.025
0.074
0.110
0.139
0.163
0.030
0.078
0.114
0.142
0.165
0.036
0.082
0.117
0.144
0.167
0.041
0.086
0.120
0.147
0.169
0.046
0.089
0.123
0.149
0.172
0.051
0.093
0.126
0.152
0.174
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
0.176
0.290
0.342
0.375
0.398
0.416
0.431
0.443
0.453
0.194
0.297
0.346
0.378
0.400
0.418
0.432
0.444
0.454
0.210
0.303
0.350
0.380
0.402
0.419
0.433
0.445
0.455
0.224
0.309
0.353
0.383
0.404
0.421
0.434
0.446
0.456
0.236
0.314
0.357
0.385
0.406
0.422
0.436
0.447
0.456
0.247
0.320
0.360
0.387
0.408
0.423
0.437
0.448
0.457
0.257
0.325
0.363
0.390
0.410
0.425
0.438
0.449
0.458
0.266
0.329
0.366
0.392
0.411
0.426
0.439
0.450
0.459
0.275
0.334
0.369
0.394
0.413
0.428
0.440
0.451
0.460
0.283
0.338
0.372
0.396
0.414
0.429
0.442
0.452
0.461
0.462
0.515
0.543
0.561
0.575
0.585
0.594
0.601
0.608
0.470
0.519
0.545
0.563
0.576
0.586
0.595
0.602
0.608
0.477
0.522
0.547
0.564
0.577
0.587
0.596
0.603
0.609
0.483
0.525
0.549
0.566
0.578
0.588
0.596
0.603
0.610
0.489
0.528
0.551
0.567
0.579
0.589
0.597
0.604
0.610
0.494
0.531
0.553
0.568
0.580
0.590
0.598
0.605
0.611
0.499
0.533
0.555
0.570
0.581
0.591
0.599
0.605
0.611
0.503
0.536
0.557
0.571
0.582
0.592
0.599
0.606
0.612
0.508
0.538
0.558
0.572
0.583
0.592
0.600
0.607
0.612
0.511
0.541
0.559
0.573
0.584
0.593
0.601
0.607
0.613
10
20
30
40
50
60
70
80
90
0.613
0.648
0.667
0.680
0.689
0.697
0.703
0.708
0.713
0.618
0.651
0.669
0.681
0.690
0.698
0.704
0.709
0.714
0.623
0.653
0.670
0.682
0.691
0.698
0.704
0.709
0.714
0.627
0.655
0.671
0.683
0.692
0.699
0.705
0.710
0.715
0.631
0.657
0.673
0.684
0.692
0.700
0.705
0.710
0.715
0.634
0.659
0.674
0.685
0.693
0.700
0.706
0.711
0.715
0.637
0.661
0.675
0.686
0.694
0.701
0.706
0.711
0.716
0.640
0.662
0.676
0.687
0.695
0.701
0.707
0.712
0.716
0.643
0.664
0.678
0.688
0.696
0.702
0.707
0.712
0.716
0.646
0.666
0.679
0.688
0.696
0.702
0.708
0.713
0.717
cSt
1
2
3
4
5
6
7
8
9
cSt
10
20
30
40
50
60
70
80
90
cSt
100
200
300
400
500
600
700
800
900
13-23
cSt
1,000
2,000
3,000
4,000
5,000
6,000
7,000
8,000
9,000
100
200
300
400
500
600
700
800
900
0.717
0.743
0.757
0.767
0.775
0.780
0.785
0.790
0.793
0.721
0.745
0.758
0.768
0.775
0.781
0.786
0.790
0.794
0.724
0.747
0.759
0.769
0.776
0.781
0.786
0.790
0.794
0.727
0.748
0.761
0.770
0.777
0.782
0.787
0.791
0.794
0.730
0.750
0.762
0.770
0.778
0.782
0.787
0.791
0.795
0.733
0.751
0.763
0.771
0.778
0.783
0.787
0.791
0.795
0.735
0.752
0.764
0.772
0.778
0.783
0.788
0.792
0.795
0.737
0.754
0.765
0.772
0.779
0.784
0.788
0.792
0.796
0.739
0.755
0.765
0.773
0.779
0.784
0.789
0.792
0.796
0.741
0.756
0.766
0.774
0.780
0.785
0.790
0.793
0.796
cSt
10,000
20,000
30,000
40,000
50,000
60,000
70,000
80,000
90,000
1000
2000
3000
4000
5000
6000
7000
8000
9000
0.796
0.817
0.828
0.836
0.842
0.847
0.851
0.854
0.858
0.799
0.818
0.829
0.837
0.843
0.848
0.802
0.820
0.830
0.838
0.843
0.848
0.804
0.821
0.831
0.838
0.844
0.848
0.806
0.822
0.832
0.839
0.844
0.849
0.808
0.823
0.8330
.839
0.845
0.849
0.810
0.824
0.833
0.840
0.845
0.850
0.812
0.825
0.834
0.841
0.846
0.850
0.814
0.826
0.835
0.841
0.846
0.850
0.815
0.827
0.836
0.842
0.847
0.851
10,000,000
20,000,000
30,000,000
40,000,000
50,000,000
60,000,000
70,000,000
80,000,000
90,000,000
0.960
0.973
0.980
0.985
0.989
0.992
0.995
0.997
0.999
cSt
100,000
200,000
300,000
400,000
500,000
600,000
700,000
800,000
900,000
cSt
0.860
0.877
0.887
0.894
0.899
0.903
0.906
0.909
0.912
cSt
1,000,000
2,000,000
3,000,000
4,000,000
5,000,000
6,000,000
7,000,000
8,000,000
9,000,000
0.914
0.928
0.937
0.942
0.947
0.950
0.953
0.956
0.958
13-24
32
33
34
35
36
37
38
39
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
0.275
0.296
0.314
0.328
0.342
0.353
0.363
0.373
0.278
0.298
0.315
0.330
0.343
0.354
0.364
0.373
0.280
0.300
0.317
0.331
0.344
0.355
0.365
0.374
0.282
0.302
0.318
0.333
0.345
0.356
0.366
0.375
0.284
0.303
0.320
0.334
0.346
0.357
0.367
0.376
0.286
0.305
0.321
0.335
0.347
0.358
0.368
0.377
0.288
0.307
0.323
0.337
0.349
0.359
0.369
0.378
0.290
0.309
0.324
0.338
0.350
0.360
0.370
0.378
0.292
0.310
0.326
0.339
0.351
0.362
0.371
0.379
0.294
0.312
0.327
0.340
0.352
0.363
0.372
0.380
0.381
0.435
0.464
0.483
0.497
0.508
0.388
0.439
0.466
0.485
0.498
0.509
0.395
0.442
0.469
0.486
0.499
0.510
0.402
0.445
0.471
0.488
0.501
0.511
0.408
0.449
0.473
0.489
0.502
0.512
0.413
0.451
0.475
0.491
0.503
0.513
0.418
0.454
0.476
0.492
0.504
0.513
0.423
0.457
0.478
0.493
0.505
0.514
0.428
0.459
0.480
0.495
0.506
0.515
0.431
0.462
0.482
0.496
0.507
0.516
10
20
30
40
50
60
70
80
90
0.517
0.565
0.589
0.605
0.617
0.627
0.635
0.641
0.647
0.524
0.568
0.591
0.607
0.618
0.628
0.635
0.642
0.647
0.531
0.571
0.593
0.608
0.619
0.628
0.636
0.642
0.648
0.537
0.574
0.595
0.609
0.620
0.629
0.637
0.643
0.648
0.542
0.576
0.596
0.611
0.621
0.630
0.637
0.643
0.649
0.547
0.579
0.598
0.612
0.622
0.631
0.638
0.644
0.649
0.551
0.581
0.600
0.613
0.623
0.632
0.639
0.645
0.650
0.555
0.583
0.601
0.614
0.624
0.632
0.639
0.645
0.650
0.559
0.585
0.603
0.615
0.625
0.633
0.640
0.646
0.651
0.562
0.587
0.604
0.616
0.626
0.634
0.640
0.646
0.651
SUS
40
50
60
70
80
90
SUS
100
200
300
400
500
600
700
800
900
13-25
SUS
1,000
2,000
3,000
4,000
5,000
6,000
7,000
8,000
9,000
100
200
300
400
500
600
700
800
900
0.652
0.683
0.700
0.711
0.720
0.727
0.733
0.738
0.742
0.656
0.685
0.701
0.712
0.721
0.728
0.733
0.738
0.742
0.660
0.687
0.703
0.713
0.722
0.728
0.734
0.739
0.743
0.664
0.689
0.704
0.714
0.722
0.729
0.734
0.739
0.743
0.667
0.691
0.705
0.715
0.723
0.729
0.735
0.740
0.744
0.670
0.692
0.706
0.716
0.724
0.730
0.735
0.740
0.744
0.673
0.694
0.707
0.717
0.725
0.731
0.736
0.740
0.744
0.676
0.696
0.708
0.718
0.725
0.731
0.736
0.741
0.745
0.678
0.697
0.709
0.719
0.726
0.732
0.737
0.741
0.745
0.681
0.699
0.710
0.719
0.726
0.732
0.737
0.742
0.745
SUS
10,000
20,000
30,000
40,000
50,000
60,000
1000
2000
3000
4000
5000
6000
7000
8000
9000
0.746
0.770
0.783
0.792
0.799
0.804
0.749
0.771
0.784
0.793
0.799
0.805
0.752
0.773
0.785
0.793
0.800
0.805
0.755
0.774
0.786
0.794
0.800
0.806
0.758
0.776
0.787
0.795
0.801
0.806
0.760
0.777
0.788
0.795
0.802
0.807
0.762
0.778
0.789
0.796
0.802
0.807
0.764
0.779
0.790
0.797
0.803
0.807
0.766
0.781
0.790
0.797
0.803
0.808
0.768
0.782
0.791
0.798
0.804
0.808
SUS
SUS
70,000 0.809
80,000 0.813
90,000 0.816
100,000
200,000
300,000
400,000
500,000
600,000
700,000
800,000
900,000
SUS
0.819
0.838
0.849
0.856
0.862
0.867
0.870
0.874
0.877
SUS
1,000,000
2,000,000
3,000,000
4,000,000
5,000,000
6,000,000
7,000,000
8,000,000
9,000,000
13-26
0.879
0.895
0.904
0.911
0.915
0.919
0.923
0.925
0.928
10,000,000
20,000,000
30,000,000
40,000,000
50,000,000
60,000,000
70,000,000
80,000,000
90,000,000
0.930
0.944
0.952
0.957
0.961
0.965
0.968
0.970
0.972
0.570
0.588
0.601
0.611
0.619
0.626
0.632
0.572
0.590
0.602
0.612
0.620
0.627
0.633
0.574
0.591
0.604
0.613
0.621
0.627
0.633
0.576
0.593
0.605
0.614
0.622
0.628
0.634
0.578
0.594
0.606
0.615
0.622
0.629
0.634
0.558
0.580
0.595
0.607
0.616
0.623
0.629
0.635
0.561
0.582
0.597
0.608
0.616
0.624
0.630
0.635
0.563
0.584
0.598
0.609
0.617
0.624
0.630
0.636
0.566
0.585
0.599
0.610
0.618
0.625
0.631
0.636
0.568
0.587
0.600
0.610
0.619
0.626
0.632
0.637
10
20
30
40
50
60
70
80
90
0.637
0.669
0.686
0.697
0.706
0.713
0.719
0.724
0.728
0.642
0.671
0.687
0.698
0.707
0.713
0.719
0.724
0.728
0.646
0.673
0.688
0.699
0.707
0.714
0.720
0.724
0.729
0.649
0.675
0.689
0.700
0.708
0.715
0.720
0.725
0.729
0.653
0.676
0.691
0.701
0.709
0.715
0.721
0.725
0.729
0.656
0.678
0.692
0.702
0.710
0.716
0.721
0.726
0.730
0.659
0.680
0.693
0.703
0.710
0.716
0.722
0.726
0.730
0.661
0.681
0.694
0.703
0.711
0.717
0.722
0.727
0.730
0.664
0.683
0.695
0.704
0.712
0.718
0.723
0.727
0.731
0.666
0.684
0.696
0.705
0.712
0.718
0.723
0.727
0.731
100
200
300
400
1000 0.732
2000 0.755
3000 0.769
0.735
0.757
0.770
0.738
0.759
0.771
0.741
0.760
0.772
0.743
0.761
0.773
4000
5000
6000
7000
8000
9000
Notes:
Values from this table are for 130 F, although the Saybolt Furol seconds are at
122 F. This table alone must not be used for any other temperatures. Values
from this table may be used interchangeably with values for kinematic and
Saybolt Universal viscosities if the latter are for 130 F.
20
30
40
50
60
70
80
90
SFS at
122 F
100
200
300
400
500
600
700
800
900
SFS at
122 F
0.778
0.784
0.790
0.795
0.798
0.802
500
0.746
0.763
0.773
600
700
800
900
0.748
0.764
0.775
0.750
0.764
0.775
0.752
0.766
0.776
0.754
0.767
0.777
For SFS at 210 F, assume SUS 10 x SFS and use the Saybolt Universal table.
13-27
0
168,000
86,600
46,000
25,200
14,200
8,240
4,890
2,970
1,840
1,170
753
495
331
224
154
108
76.3
54.7
39.7
29.1
21.6
16.1
12.2
9.31
7.16
5.56
4.35
3.43
2.72
2.17
1
157,000
81,200
43,300
23,800
13,500
7,810
4,650
2,830
1,760
1,120
722
475
318
216
149
104
73.8
52.9
38.4
28.2
20.9
15.7
11.9
9.07
6.98
5.42
4.24
3.35
2.66
2.12
2
147,000
76,100
40,700
22,400
12,700
7,410
4,420
2,700
1,680
1,070
692
456
305
305
144
101
71.4
51.3
37.3
27.4
20.3
15.2
11.6
8.83
6.80
5.29
4.14
3.27
2.60
2.08
3
137,000
71,400
38,300
21,200
12,000
7,030
4,200
2,570
1,600
1,020
662
438
294
200
138
97.1
69.0
49.6
36.1
26.6
19.7
14.8
11.2
8.60
6.63
5.16
4.04
3.19
2.54
2.03
4
128,000
67,000
36,100
20,000
11,400
6,670
4,000
2,450
1,530
978
635
420
283
193
134
93.8
66.7
48.0
35.0
25.8
19.2
14.4
10.9
8.37
6.47
5.03
3.95
3.12
2.48
1.99
5
120,000
62,900
34,000
18,900
10,800
6,330
3,800
2,330
1,460
935
609
404
272
186
129
90.6
64.5
46.5
33.9
25.0
18.6
14.0
10.6
8.16
6.30
4.91
3.86
3.05
2.43
1.95
6
112,000
59,000
32,000
17,800
10,200
6,010
3,620
2,230
1,400
896
584
388
261
179
124
87.5
62.4
45.1
32.9
24.3
18.1
13.6
10.4
7.95
6.15
4.79
3.76
2.98
2.37
1.90
7
105,000
55,400
30,100
16,800
9,680
5,700
3,441
2,120
1,340
857
560
372
252
172
120
84.6
60.4
43.6
31.9
23.6
17.6
13.3
10.1
7.74
5.99
4.68
3.68
2.91
2.32
1.86
8
98,600
52,100
28,400
15,900
9,170
5,420
3,280
2,020
1,280
821
537
358
242
166
116
81.7
58.4
42.3
30.9
22.9
17.1
12.9
9.82
7.55
5.84
4.56
3.59
2.85
2.27
1.82
9
92,400
49,000
26,800
15,000
8,690
5,150
3,120
1,930
1,220
786
515
344
233
160
112
79.0
56.5
40.9
30.0
22.2
16.6
12.5
9.56
7.85
5.70
4.45
3.51
2.78
2.22
1.79
Flash Point,
F
10
20
30
40
50
60
70
80
90
300
400
500
1.75
0.269
0.063
1.41
0.229
0.056
1.15
0.196
0.049
0.943
0.168
0.044
0.777
0.145
0.039
0.643
0.125
0.035
0.535
0.108
0.031
0.448
0.094
0.028
0.376
0.082
0.025
0.317
0.072
0.022
May be used to blend flash temperature, determined in any apparatus but, preferably, not to blend closed cup with
open cup determinations.
13-28
-5
-6
-7
-8
-9
-10
0
Aniline Point,
F
0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
Mixed Aniline
Point, F
0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
20.0
49.1
17.4
46.0
14.9
42.8
12.6
39.8
10.3
36.8
8.10
33.8
6.06
30.9
4.17
28.1
2.46
25.3
1.00
22.6
49.1
83.2
121
162
205
250
298
347
398
451
505
560
617
674
733
794
855
917
980
1,044
1,110
1,176
1,242
1,310
1,379
52.4
86.8
125
166
209
255
303
352
403
456
510
566
622
680
739
800
861
923
986
1,050
1,116
1,182
1,249
1,317
1,386
55.6
90.5
129
170
214
260
308
357
408
461
516
571
628
686
745
806
867
930
993
1,057
1,122
1,189
1,256
1,324
1,392
58.9
94.2
133
174
218
264
312
362
414
467
521
577
634
692
751
812
873
936
999
1,064
1,129
1,196
1,262
1,331
1,400
62.3
97.9
137
179
223
269
317
367
419
472
527
582
640
698
757
818
880
942
1,006
1,070
1,136
1,202
1,269
1,337
1,406
65.7
102
141
183
227
274
322
372
424
477
532
588
645
704
763
824
886
948
1,012
1,077
1,142
1,209
1,276
1,344
1,413
69.1
105
145
187
232
279
327
377
429
483
538
594
651
710
769
830
892
955
1,019
1,083
1,149
1,216
1,283
1,351
1,420
72.6
109
149
192
237
283
332
382
435
488
543
599
657
716
775
836
898
961
1,025
1,090
1,156
1,222
1,290
1,358
1,427
76.1
113
153
196
241
288
337
388
440
494
549
605
663
722
781
842
904
967
1,031
1,096
1,162
1,229
1,297
1,365
1,434
79.6
117
157
200
246
293
342
393
445
491
554
611
669
727
788
849
911
974
1,038
1,103
1,169
1,236
1,303
1,372
1,441
0
-736
-668
-593
-511
-425
-334
-239
-140
-38.3
66.8
175
285
399
514
632
1
-730
-660
-584
-503
-416
-324
-229
-130
-27.9
77.4
186
297
410
526
644
2
-723
-653
-577
-494
-407
-315
-219
-120
-17.5
88.1
197
308
422
538
656
3
-716
-646
-569
-486
-398
-306
-210
-110
-7.06
98.8
208
319
433
550
668
4
-709
-639
-561
-477
-389
-296
-200
-100
3.39
110
219
330
445
561
680
5
-703
-631
-552
-468
-380
-287
-190
-89.6
13.9
120
230
342
456
573
692
6
-696
-623
-544
-460
-371
-277
-180
-79.4
24.4
131
241
353
468
585
704
7
-689
-616
-536
-451
-361
-267
-170
-69.2
35.0
142
252
364
479
597
716
8
-682
-608
-528
-442
-352
-258
-160
-58.9
45.5
153
263
376
491
609
728
9
-675
-600
-519
-433
-343
-248
-150
-48.6
56.1
164
274
387
503
620
741
13-29
Pour
Point
70
65
60
55
50
45
40
35
30
25
20
15
10
5
0
-5
-10
-15
-20
-25
-30
-35
-40
-45
-50
-55
-60
-65
-70
300
350
375
400
425
450
475
500
525
550
575
600
625
650
675
700
133
114
99
88
72
60
52
44
37
32
27
23
20
17
14
12
10
8.8
7.5
6.4
5.5
4.6
4.0
3.3
2.8
2.5
2.1
1.8
1.5
131
111
94
79
68
56
48
41
34
29
24
20
17
15
12
10
8.8
7.4
6.3
5.3
4.5
3.7
3.2
2.7
2.3
1.9
1.6
1.4
1.1
129
109
92
77
66
54
46
39
32
27
23
19
16
14
11
9.5
8.0
6.8
5.7
4.7
4.0
3.3
2.8
2.4
2.0
1.7
1.4
1.2
0.99
128
107
90
75
63
52
44
37
31
26
21
18
15
13
10
8.7
7.3
6.1
5.1
4.2
3.6
2.9
2.5
2.1
1.7
1.4
1.2
1.0
0.84
127
105
87
73
61
50
42
35
29
24
20
17
14
12
9.6
8.0
6.6
5.5
4.6
3.7
3.2
2.6
2.2
1.8
1.5
1.2
1.0
0.85
0.71
125
103
85
71
59
48
40
33
27
23
19
16
13
11
8.7
7.2
5.9
4.9
4.1
3.3
2.8
2.3
1.9
1.5
1.3
1.1
0.87
0.72
0.60
123
101
82
68
56
46
38
32
26
21
17
14
12
9.7
7.9
6.5
5.3
4.4
3.6
2.9
2.4
2.0
1.6
1.3
1.1
0.90
0.74
0.60
0.50
120
98
80
66
54
44
36
30
24
20
16
13
11
8.8
7.1
5.8
4.7
3.9
3.2
2.5
2.1
1.7
1.4
1.1
0.93
0.77
0.62
0.50
0.42
118
96
77
63
52
42
34
28
23
18
15
12
9.8
7.9
6.3
5.1
4.1
3.4
2.8
2.2
1.8
1.4
1.2
0.98
0.78
0.65
0.52
0.41
0.36
115
94
74
61
49
40
32
26
21
17
14
11
8.8
7.1
5.6
4.5
3.6
3.0
2.4
1.9
1.5
1.2
1.0
0.82
0.66
0.55
0.43
0.34
0.30
113
91
72
58
47
38
30
24
19
15
12
10
8.0
6.3
5.0
3.9
3.2
2.6
2.1
1.7
1.3
1.0
0.86
0.68
0.56
0.46
0.36
0.28
0.25
110
88
69
56
44
35
28
23
18
14
11
9.0
7.1
5.6
4.4
3.4
2.8
2.2
1.8
1.4
1.1
0.90
0.73
0.58
0.47
0.37
0.30
0.23
0.20
108
85
67
53
42
33
26
21
16
13
10
8.1
6.3
5.0
3.8
3.0
2.5
1.9
1.5
1.2
0.96
0.75
0.62
0.48
0.38
0.30
0.24
0.18
0.15
105
82
64
50
39
31
24
19
15
12
9.1
7.2
5.6
4.4
3.4
2.7
2.2
1.7
1.3
1.0
0.80
0.62
0.51
0.38
0.31
0.24
0.19
0.14
0.11
103
79
62
48
37
29
22
18
14
11
8.3
6.4
5.0
3.8
3.0
2.4
1.9
1.4
1.1
0.90
0.67
0.51
0.41
0.31
0.25
0.19
0.14
0.10
0.08
100
76
60
46
35
27
21
16
13
10
7.5
5.8
4.5
3.5
2.7
2.1
1.6
1.2
0.94
0.72
0.56
0.43
0.33
0.25
0.20
0.15
0.10
0.07
0.05
Online Blending
Because of limited storage space, many refineries today (MAB refinery) have the
ability to use computer-controlled in-line product blending.
Inventories of blending stocks, together with cost and physical property data are
maintained in the computer.
When a certain volume of a given quality product is specified, the computer uses
linear programming models to optimize the blending operations (select the optimum
volume of blending components) to produce the required product at the lowest cost.
To ensure that the blended streams meet the desired specifications, stream analyzers,
such as boiling point, specific gravity, RVP, and research and motor octane are
installed to provide feedback control of blending streams and additives (if necessary).
Blending components to meet all critical specifications most economically is a trialand-error (iterative) procedure which is easily handled by a computer.
The large number of variables leads to a number of equivalent solutions that give the
approximate equivalent total overall cost or profit.
Optimization programs (like PIMS for example) permit the computer to provide the
optimum blend to minimize cost and maximize profit.
Both linear and nonlinear programming techniques are used.
13-30
Figure 13-5: Schematic representation of the online blending system for diesel product
Problems
1. Using values from Table 12.1, calculate the number of barrels of n-butane that have to
be added to a mixture of 1250 barrels of HSR gasoline, 750 barrels of LSR gasoline,
and 620 barrels of C 5 FCC gasoline to produce a 9 psi Reid vapor pressure. What are the
research and motor octane numbers of the blend?
2. For the blend of components in problem 1, what would be the posted octane number of the
9.0 psi RVP gasoline if 10 vol% MTBE was added to the gasoline mixture?
3. Calculate the amount of n-butane needed to produce a 12.5 psi RVP for a mixture of
2730 barrels of LSR gasoline, 2490 barrels of 94 RON reformate, 6100 barrels of heavy
hydrocrackate, and 3600 barrels of C 5 + FCC gasoline. How much ETBE must be added
to produce a 90 RON product? Calculate the RVP of the final blend.
4. What is the ash point of a mixture of 2500 barrels of oil with a ashpoint of 120F,
3750 barrels with a ashpoint of 35F, and 5000 barrels with a 150F ashpoint?
5. Calculate the pour point of the following mixture:
13-31
ASTM
Pour
Compone Barrel
50%
point,
nt
s
temp.,
F
A
5,200
57
10
F
5
B
3,000
42
50
C
6,500
50
65
5
D
3,250
55
45
0
0
6. What is the viscosity of a blend of 2000 barrels of oil with a viscosity of 75.5 cSt at 130F,
3000 barrels with 225 cSt at 130F, and 5000 barrels with 6500 cSt at 130F?
7. Calculate the octane numbers of the nal blend and amount of n-butane needed for
producing a 9.5 psi RVP gasoline from 5100 BPSD of LSR gasoline, 3000 BPSD light
hydrocrackate, 4250 BPSD alkylate, 10,280 BPSD heavy hydrocrackate, 14,500 BPSD
FCC C 5+ gasoline, 14,200 BPSD of 96 RON reformate, and 2500 BPSD of polymer
gasoline.
8. Recommend the best method for increasing the clear posted octane number of the pool
gasoline in problem 7 by 3 numbers. Estimate the cost involved. Assume any necessary
processing units are available and have the necessary capacity.
9. Calculate the number of barrels of n-butane that have to be added to a mixture of 1000
barrels of light thermal gasoline, 1000 barrels of polymer gasoline, and 1000 barrels of
C 4= alkylate to produce a gasoline product having 10 psi Reid vapor pressure.
10. What is the posted octane number and Reid vapor pressure of the gasoline product of
problem 3?
11. Calculate the clear octane numbers (RON and MON) and the amount of butane needed for
a 12.0 psi RVP gasoline produced from the following:
Belding component
LSR naphtha
Light hydrocrackate
C 5+ alkylate
Heavy hydrocrackate
Reformate (94 RON)
C 5+ FCC gasoline
BPSD
4,200
1,800
4,500
9,150
11,500
15,600
12. Recommend the best method (lowest capital cost) for increasing the posted octane number
of the pool gasoline in problem 11 by 5.5 octane numbers. Estimate the size of the unit
and its 1994 construction cost.
HW solve problems 3, 5, 6, 10
13-32