COMPONENTES

agua
etanol
n propanol

CONSTANTES DE ANTOINE( SE
OBTIENEN DEL DATA BANK)
A
B
C
18.3036
18.9119
17.5439

3816.44
3803.98
3166.38

A12
-117.3381

A21
425.7681

Diagonal
0
1

1
0

-46.13
-41.66
-80.15

ETANOL
x1
0.0303
0.0606
0.0909
0.1212
0.1515
0.1818
0.2121
0.2424
0.2727
0.3030
0.3333
0.3636
0.3939
0.4242
0.4545
0.4848
0.5151

0.5454
0.5757
0.6000
0.6363
0.6666
0.6969
0.7272
0.7575
0.7878
0.8181

Molecule
ETANOL
AGUA
N-PRTOPANOL

r1
1.8701
3.0198
2.42
l1
-0.1396

q1
1.724
2.9160
1.3
l2
-1.5008

SISTEMA ETANOL,AGUA Y N-PROPANOL

1.0000
0.9000
0.8000
0.7000
0.6000
AGUA

Column G

0.5000

Column B

0.4000
0.3000
0.2000
0.1000
0.0000
0

0.1

0.2

0.3

0.4

0.5

ETANOL

0.6

0.7

0.8

0.9

AGUA
x3

x2
0.21
0.2200
0.23
0.2400
0.25
0.2600
0.27
0.2800
0.29
0.3000
0.31
0.3020
0.281
0.2750
0.262
0.2430
0.23

0.7597
0.7194
0.6791
0.6388
0.5985
0.5582
0.5179
0.4776
0.4373
0.3970
0.3567
0.3344
0.3251
0.3008
0.2835
0.2722
0.2549

ln(1)

R
8.3140
8.3140
8.3140
8.3140
8.3140
8.3140
8.3140
8.3140
8.3140
8.3140
8.3140
8.3140
8.3140
8.3140
8.3140
8.3140
8.3140

-0.4287397039
-0.3802362819
-0.3292861274
-0.275735322
-0.2193376328
-0.1598138157
-0.0968459197
-0.0300703802
0.0409304128
0.1166384882
0.1976131732
0.2386730969
0.2477258612
0.2948985022
0.324679869
0.3384787919
0.3684116612

ln(2)
0.23579919
0.24878727
0.26214425
0.27591264
0.29014273
0.30489437
0.3202393
0.33626423
0.35307492
0.3708017
0.389607
0.38198346
0.35544974
0.35200919
0.33880522
0.31749296
0.30580162

ln(3)
0.69069944
0.34838778
0.71548538
0.96160303
0.13965956
0.27300228
0.37386209
0.44931049
0.5036675
0.53962397
0.55881656
0.56277725
0.56054357
0.5509421
0.53757873
0.52349032
0.50341453

1
0.6513294456
0.6836998442
0.7194371366
0.7590137984
0.8030505362
0.8523024596
0.9076958534
0.9703772358
1.0417796085
1.1237131207
1.2184909577
1.2695634445
1.2811086825
1.3429900413
1.3835876457
1.4028119976
1.4454369468

0.2150
0.21
0.1950
0.17
0.1600
0.13
0.1000
0.09
0.0800
0.07

0.2396
0.2143
0.2050
0.1937
0.1734
0.1731
0.1728
0.1525
0.1322
0.1119

8.3140
8.3140
8.3140
8.3140
8.3140
8.3140
8.3140
8.3140
8.3140
8.3140

0.3929743509
0.4463152224
0.4576009927
0.466021655
0.5053712625
0.4848068441
0.4645860991
0.502450505
0.5408641969
0.5798313923

0.29201942
0.29379899
0.27957099
0.25200063
0.24714684
0.21419693
0.18234343
0.17886664
0.17597716
0.17368829

0.48187624
0.44872271
0.43052538
0.40530213
0.37030428
0.36000264
0.35014888
0.31377648
0.27541654
0.2351871

1.4813803928
1.5625439378
1.5802783347
1.5936415093
1.6576008112
1.6238613201
1.5913553891
1.6527664248
1.717490471
1.7857373163

z
10

0.0241040851
0.0495797705
0.0765475573
0.1051424881
0.1355164081
0.1678406631
0.2023093328
0.2391431317
0.2785941394
0.3209515781
0.3665489149
0.402398268
0.4286810524
0.4661918529
0.4981967808
0.5244805717
0.5558388696
0.5850040248
0.6245746224
0.6444476225
0.6704367077
0.7042024051
0.7137309091
0.7226947378
0.7546670225
0.7867976902
0.8190879205

-PROPANOL

0.8

Column G
Column B

0.9

2
1.26592007
1.28246918
1.29971402
1.31773274
1.33661824
1.35648171
1.37745735
1.39970883
1.42343778
1.44889573
1.47640046
1.46518785
1.42682221
1.42192159
1.40326999
1.37367957
1.35771294

3
1.99511051
1.41678154
2.04517914
2.61588645
1.14988227
1.31390324
1.45333671
1.56723119
1.65477906
1.71536171
1.74860191
1.75554131
1.75162437
1.73488668
1.71185696
1.68790872
1.6543605

SISTEMA
ISOBARICO
P(mmHg)
760.04
760.04
760.04
760.04
760.04
760.04
760.04
760.04
760.04
760.04
760.04
760.04
760.04
760.04
760.04
760.04
760.04

Pvp1
3.521E+02
3.530E+02
3.538E+02
3.547E+02
3.555E+02
3.564E+02
3.573E+02
3.581E+02
3.590E+02
3.598E+02
3.605E+02
3.611E+02
3.615E+02
3.617E+02
3.616E+02
3.610E+02
3.598E+02

5.20E+02
3.53E+02
3.65E+02
3.78E+02
3.91E+02
4.05E+02
4.19E+02
4.33E+02
4.48E+02
4.62E+02
4.75E+02
4.87E+02
4.95E+02
4.98E+02
4.95E+02
4.84E+02
4.63E+02

pvp2

pv3
7.79E+02
8.08E+02
8.34E+02
8.62E+02
8.91E+02
9.21E+02
9.52E+02
9.85E+02
1.02E+03
1.05E+03
1.08E+03
1.10E+03
1.12E+03
1.13E+03
1.12E+03
1.10E+03
1.05E+03

3.65E+02
3.80E+02
3.93E+02
4.07E+02
4.22E+02
4.38E+02
4.54E+02
4.70E+02
4.87E+02
5.03E+02
5.18E+02
5.31E+02
5.40E+02
5.44E+02
5.41E+02
5.28E+02
5.04E+02

1.33912902
1.34151422
1.3225623
1.28659685
1.28036711
1.2388666
1.20002624
1.19586125
1.19241082
1.18968467

1.6191094
1.56631027
1.53806537
1.49975556
1.4481752
1.4333332
1.41927883
1.3685838
1.31707918
1.26514545

760.04
760.04
760.04
760.04
760.04
760.04
760.04
760.04
760.04
760.04

0.97589591
0.95042023
0.92345244
0.89485751
0.86448359
0.83215934
0.79769067
0.76085687
0.72140586
0.67904842
0.63345109
0.59760173
0.57131895

0.0230371263
0.0474399576
0.0733336478
0.1008591248
0.1301756568
0.1614639357
0.1949298049
0.2308087931
0.2693716662
0.3109312724
0.3558510488
0.3913004396
0.4173646061

0.53380815

0.454673234

3.580E+02
3.554E+02
3.534E+02
3.603E+02
3.604E+02
3.602E+02
3.601E+02
3.595E+02
3.588E+02
3.580E+02

2
0.9769628737
0.9525600424
0.9266663522
0.8991408752
0.8698243432
0.8385360643
0.8050701951
0.7691912069
0.7306283338
0.6890687276
0.6441489512
0.6086995604
0.5826353939

4.31E+02
3.88E+02
3.58E+02
4.72E+02
4.73E+02
4.70E+02
4.67E+02
4.56E+02
4.44E+02
4.31E+02

12

9.79E+02
8.85E+02
8.19E+02
1.07E+03
1.07E+03
1.06E+03
1.06E+03
1.03E+03
1.01E+03
9.79E+02

21

1.04089703
1.04078831
1.04069285
1.04059512
1.04049559
1.04039492
1.04029404
1.04019432
1.04009761
1.04000649
1.03992442
1.03985607
1.03980766

0.8646391538
0.8649669198
0.8652548665
0.8655497472
0.8658502166
0.866154282
0.8664590712
0.8667605247
0.867052989
0.8673286911
0.8675770755
0.8677840034
0.8679306317

0.545326766 1.03978687

0.8679936

0.50180322

0.4866082407 0.5133917593 1.03980386 0.8679421392

0.47551943

0.5129055586 0.4870944414 1.03987058 0.8677400675

0.44416113

0.5443640515 0.4556359485 1.04000096 0.8673454114

0.41499598

0.5737048117 0.4262951883 1.04021019 0.8667125526

0.37542538
0.35555238
0.32956329
0.29579759
0.28626909
0.27730526
0.24533298
0.21320231
0.18091208

0.6136412536
0.6337536301
0.6601121283
0.694453549
0.7041641641
0.7133072247
0.7459814237
0.7789163774
0.8121152196

0.3863587464
0.3662463699
0.3398878717
0.305546451
0.2958358359
0.2866927753
0.2540185763
0.2210836226
0.1878847804

1.04051377
1.04074966
1.03994487
1.03994074
1.03995824
1.03997553
1.04004365
1.04012196
1.04021019

0.8657953434
0.8650834853
0.8675151765
0.8675276878
0.8674747098
0.8674223666
0.8672162284
0.8669793417
0.8667125526

4.68E+02
4.19E+02
3.85E+02
5.14E+02
5.15E+02
5.12E+02
5.09E+02
4.96E+02
4.83E+02
4.68E+02

y1

y2

y3

0.01350238 0.9862150953 0.0002825275

0.01927032 0.9809873405
1.268E+01
0.03143092 0.9687824687
1.890E+01
0.04572253 0.9544527609
2.498E+01
0.0625708 0.937572146
1.135E+01
0.08249042 0.9176254594
1.342E+01
0.10610019 0.8939934216
1.535E+01
0.1341366 0.8659390278
1.711E+01
0.16746203 0.8325993792
1.866E+01
0.20706032 0.7929901879
1.994E+01
0.25400755 0.7460349688
2.089E+01
0.29553895 0.7099772847
2.145E+01
0.32846896 0.6830229269
2.175E+01
0.37346563 0.6341490613
2.169E+01
0.40985171 0.5865285005
2.128E+01
0.433256 0.5392264777
2.053E+01
0.45363906 0.4779840322
1.927E+01

SUMA
0.9997174725
1.0002576562
1.0002133851
1.0001752887
1.0001429436
1.0001158838
1.0000936134
1.0000756233
1.000061412
1.0000505116
1.0000425205
1.0055162331
1.0114918878
1.0076146884
0.9963802069
0.9724824826
0.9316230934

0.45824258 0.4134356203
0.4597651 0.3349092732
0.44689529 0.2920139145
0.62980295 0.3506560592
0.6872445 0.3128150773
0.699658 0.3004047242
0.71124383 0.2888221191
0.75174399 0.2483359379
0.79094381 0.2091549856
0.82858617 0.1715381045

1.759E+01
1.537E+01
1.394E+01
1.779E+01
1.721E+01
1.693E+01
1.667E+01
1.571E+01
1.473E+01
1.374E+01

0.8716782005
0.7946743697
0.7389092067
0.9804590054
1.0000595751
1.0000627241
1.0000659537
1.0000799272
1.0000987943
1.0001242794

agua
etanol
n propanol

CONSTANTES DE ANTOINE(SE
OBTIENEN DEL DATA BANK)
A
B
C
18.3036
3816.44
-46.13
18.9119
3803.98
-41.66
17.5439
3166.38
-80.15

DATOS DE EQUILIBRIO LIQUIDOVAPOR(TOMADO DE LORA,1992)

agua
etanool n propanol
x1
x2
x3
0.09
0.56
0.3500
0.11
0.54
0.3500
0.19
0.48
0.3300
0.3
0.45
0.2500
0.4
0.39
0.2100
0.5
0.35
0.1500
0.6
0.3
0.1000
0.8
0.19
0.0100

LN Y1
3.09984731
3.68692559
2.12259152
0.86967542
0.36177156
0.13863471
0.08131559
0.44883083

PARAMETROS DE
WILSON(OBTENIDO DE TABLA DE
PRAUNITZ)
A12
A21
A31
975.49
276.76
1128.2
A13
A23
A32
1338.8
102.671
-40.8745

lny2
1.86800931
1.72039727
1.29471962
0.85698327
2.43958695
1.97240824
2.36012778
3.58298626

lny3
Y1
2.34378908
22.19
1.94845781 39.921922
2.91231317
8.352756
2.0342806
2.386136
1.31580329
1.435871
1.58968831
1.148704
2.69415857
1.084713
2.82322453
1.566480

SINTEMA ETANOL, AGUA, N-PROPANOL

1
0.9
0.8
0.7
0.6
0.5

Column C

SINTEMA ETANOL, AGUA, N-PROPANOL

1
0.9
0.8
0.7
0.6
0.5
AGUA
0.4
0.3
0.2
0.1
0

Column C
Column L

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

ETANOL

SISTEMA
ISOBARICO

Y2
6.47539
5.58675
3.64997
2.35604
11.46830
7.18797
10.59230
35.98083

Y3
10.4206465
7.01785638
18.3993101
7.64674907
3.72774423
4.90222072
14.7930662
16.8310354

P
760
760
760
760
760
760
760
760

0
1

Column C

agua
T
pvp1
pvp2
pvp3
Y1
313.770482 57.0554287 138.706151 54.0754052 0.05401477
318.140754 71.7455132 173.006526 69.3568903 0.02918771
318.435131 72.8420231 175.55684 70.5062954 0.23733151
337.43636 181.722093 424.494569 188.117739 0.52581368
345.942262 263.530038 608.146289 278.916408 0.80339304
354.060322 368.616654 841.579128 397.019406 0.89742953
358.208775 434.635677 987.185293 471.751056 0.96721841
355.471437 390.057393 888.944317 421.252997 0.99506239

1
0

Column C
Column L

etanol
n-propanol
Y2
Y3
suma
0.47384878 0.47204912 0.99991267
0.42460571 0.5464967 1.00029013
0.56930826 0.19332949 0.99996926
0.3419565 0.13208303 0.9998532
0.04249824 0.15350153 0.99939282
0.04397245 0.05857338 0.99997535
0.02180448 0.01089037 0.99991326
0.00451462 0.00107191 1.00064893

SISTEMA ETANOL -AGUA -N PROPANOL

1
2
3

CONSTANTES DE ANTOINE(DATOS
TOMADOS DE DATA BANK)
Componentes
ANTA
ANTB
ANTC
ethanol
18.9119
3803.98
-41.68
water
18.3036
3816.44
-46.13
n propanol
17.5439
3166.38
-80.15

i
1
1
2

R
1.987
1.987
1.987

SISTEMA
ISOBARICO
Presion
T (K)
760
346.79748483
760
352.73058996
760
356.89599504

Parametos de interaccion del chemcad

j
Bij
Bji
2
-55.1581
670.441
3
-1.28794
28.3007
3
1005.23
223.596

x1
0
0.09
0.18

x2
0.56
0.51
0.46

x3
0.44
0.4
0.36

ALPHA 1J
0.3031
0.3007
0.485

T12
T21
-0.080045236 0.9729415689
-0.078698835 0.9565762046
-0.077780325 0.9454118109

1.987
1.987
1.987
1.987
1.987
1.987
1.987

760
760
760
760
760
760
760

356.13459891
354.59502761
352.07591118
349.2136532
346.23318353
343.18183536
339.5426185

0.27
0.36
0.45
0.54
0.63
0.72
0.81

0.41
0.36
0.31
0.26
0.21
0.16
0.11

0.32
0.28
0.24
0.2
0.16
0.12
0.08

-0.077946616 0.9474330492
-0.078285042 0.9515465889
-0.078845175 0.9583549407
-0.079491413 0.9662099001
-0.080175697 0.9745272984
-0.080888566 0.9831921571
-0.08175553 0.9937300079

1
0.9
0.8
0.7
0.6
fraccion molar agua

0.5
Column AM

0.4

Column E

0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
fraccion molar etanol

T13
T31
T23
T32
G12
G21
G13
G31
-0.001869054 0.0410698741 1.4587861621 0.3244817114 1.0245584212 0.7446070946 1.0005621825 0.9877262336
-0.001837615 0.0403790583 1.4342486485 0.3190237665 1.0241403902 0.7483097761 1.0005527237 0.9879314336
-0.001816168 0.0399077861 1.4175092434 0.3153003758 1.0238553088 0.7508462915 1.000546271 0.9880714448

olumn AM

olumn E

-0.001820051 0.0399931068 1.4205398 0.3159744706 1.023906915 0.7503864359 1.0005474392 0.9880460953

-0.001827953 0.0401667478 1.4267074621 0.3173463602 1.0240119498 0.7494514267 1.0005498167 0.9879945069
-0.001841032 0.0404541424 1.4369156078 0.3196169854 1.0241858173 0.7479064449 1.0005537517 0.9879091286
-0.001856122 0.0407857164 1.4486929915 0.3222366604 1.0243864492 0.7461279187 1.0005582917 0.9878106347
-0.0018721 0.041136811 1.4611637358 0.3250105614 1.0245989355 0.7442492966 1.000563099 0.9877063529
-0.001888746 0.0415025726 1.474155447 0.3279003425 1.0248203454 0.7422972253 1.0005681071 0.9875977265
-0.001908989 0.0419473971 1.4899554411 0.3314147775 1.0250896796 0.7399300936 1.0005741978 0.9874656355

G23
G32
1
0.4928692818 0.8543847754 0.4973652956 -0.401718423 -2.261342323 0.1146701594 0.3244817114
0
0.4987698089 0.8566494161 0.4904960518 -0.26814431 -1.183390754 0.3824952625 0.234717399 0.0404081919
0.5028356092 0.8581977894 0.4859976735 -0.179949858 -0.662137891 0.7004095277 0.1684314287 0.0885627354

0.5020970742 0.8579172595 0.4875190813 -0.121443015

0.5005973873 0.85734662 0.4901560111 -0.080639648
0.4981250795 0.856402984 0.4942692276 -0.052127969
0.4952878844 0.8553155787 0.4992803758 -0.032236638
0.4923012703 0.8541656604 0.5052476 -0.01859405
0.4892090421 0.8529693483 0.5128550185 -0.009566546
0.4854745616 0.8515166996 0.524945075 -0.003993181

-0.385628137 0.9806378317 0.1183271092 0.1493677581

-0.225190022 1.2024081542 0.0777423889 0.2278093028
-0.129120004 1.3675505981 0.0440481402 0.3330674556
-0.070746035 1.4863117317 0.0153965168 0.4804687921
-0.035592837 1.5699765973 -0.00937801 0.7000213974
-0.015223564 1.6291605943 -0.031089964 1.059399551
-0.004481694 1.6761008952 -0.050428353 1.7517545545

2
3
Pvp1
Pvp2
0
1.3833135045 1.4587861621
0
0
4.3007359624 629.31804706 273.2467182
0.2174906141 1.6365922847 1.0587817169 -0.051520445 0.0704267988 2.9378795247 798.26642231 349.32576256
0.2733920574 1.6995885995 0.7961761091 -0.113163495 0.1026305903 2.1938175596 938.27954275 412.7525953

0.2724713308 1.7162920829 0.6133102736 -0.19137744

0.246960374 1.7376125369 0.4745551053 -0.292897675
0.2118146582 1.8020596379 0.3655854744 -0.43021213
0.1734223091 1.9528456529 0.2773261427 -0.62460943
0.1349301144 2.2831898033 0.2042688114 -0.918778084
0.0978601584 3.0838220278 0.1427683225 -1.412532735
0.0629254125 5.8372022428 0.0903144867 -2.408662513

0.1144845291 1.7098700316 911.25954457 400.48882381

0.1138503589 1.3438085569 858.60504086 376.62168523
0.1057551882 1.041986026 777.93918956 340.14394669
0.0929804501 0.7754569295 694.07987473 302.34383551
0.0773131171 0.5287729446 614.94718917 266.80213467
0.0599225967 0.2982444534 541.92505431 234.12987459
0.0416282105 0.1026202687 464.50805454 199.64180338

Pvp3
y1
y2
y3
Y
289.77965523
0
0.2785159081 0.7215222962 1.0000382044
375.24994425 0.03615787 0.3836433716 0.5802311199 1.0000323616
446.94413677 0.1556478785 0.424597919 0.4644539505 1.044699748

Diagonal
x
0
0.1
0.2

y
1
0.9
0.8

433.05662293 0.3174686943 0.3708103645 0.3117770701 1.0000561289

406.06267175 0.4890285958 0.3099896346 0.2010364974 1.0000547278
364.90072449 0.6299237392 0.2500230263 0.1200699334 1.0000166989
322.3878476 0.7329924904 0.2019894995 0.0657889185 1.0007709085
282.57306273 0.8003094713 0.1683205024 0.0314562085 1.0000861822
246.13729359 0.8364154202 0.1520031294 0.0115909078 1.0000094574
207.88791299 0.8297835743 0.1686690185 0.002245633 1.0006982258

0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

0.7
0.6
0.5
0.4
0.3
0.2
0.1
0